S Gio Dc o To TP H Ch Minh Trng THPT Trn Khai Nguyn

cng n tp thi hc k 2 nm hc 2008-2009

KHI 11 Phn A.Khi qut ni dung
Chng trnh thi hc k 2: Chng 5: Hidrocacbon no - Bi : Ankan - Bi : Xicloankan Chng 6: Hidrocacbon khng no - Bi : Anken - Bi : Ankadien - Bi : Ankin Chng 7: Hidrocacbon thm. Ngun hidrocacbon thin nhin . H thng ha v hidrocacbon - Bi: Benzen v ng ng .Mt s hidrocacbon thm khc - Bi: Ngun hidrocacbon thin nhin - Bi: H thng ha v hidrocacbon Chng 8: Dn xut v halogen Ancol Phenol - Bi: Dn xut halogen ca hidrocacbon - Bi: Ancol - Bi: Phenol Chng 9: Andehit Xeton Axit cacboxylic - Bi: Andehit Xeton

Phn B: Bi tp n luyn
Phn 1: Vit phn ng chng minh cc yu cu sau: Cu 1: Ancol c th tham gia phn ng tch H ca nhm OH v phn ng tch nhm OH . Mi tnh cht cht vit mt phn ng minh ha . Cu 2: Ty vo bc ancol m ancol khi tham gia phn ng oxi ha khng hon ton s to ra cc sn phm hu c khc nhau. Cu 3: Phenol c tnh axit nhng tnh axit rt yu. Cu 4: Ty vo tc nhn phn ng m phenol c th tham gia phn ng th nguyn t H ca nhm OH hay H trn vng benzen.Nu kt lun v s nh hng ca nhm chc v vng benzen trong phn t phenol. Cu 5: Andehit va c tnh oxi ha va c tnh kh . Vit phn ng minh ha cho nhn xt trn. Cu 6: Andehit axetic c th coi l sn phm trung gian gia axit hu c v ancol bc 1. Phn 2: Vit phn ng xy ra gia cc cht sau: Cu 7: Cho ancol metylic, phenol tc dng vi K,K2CO3, NaCl, NaOH, dung dch Br2 , HBr, CuO Cu 8: Cho etanol, p-crezol( 4-metyl phenol), ancol benzylic ln lt tc dng vi Na, KOH, ddBr2, CaCO3 Cu 9: axetilen , but -1-in, v andehit axetic , andehit fomic, propanal u c th tc dng vi H2 ; ddAgNO3/NH3 un nh. Cu 10: Khi cho etyl clorua , isopropyl bromua tc dng vi dung dch KOH long , KOH trong mi trng ancol un nng . Trng hp no xy ra phn ng tch , trng hp no xy ra phn ng th .Vit phn ng minh ha. Cu 11: Cho phenol vo nc dung dch b vn c , tip tc cho dd NaOH vo hn hp trn dung dch tr nn trong sut , thi kh CO2 vo dung dch va to thnh . Ta thy dung dch b vn c , khi un nng th dung dch tr nn trong sut .Vit phn ng minh ha. Phn 3:Vit phn ng theo yu cu , xc nh sn phm chnh ph , tn cc sn phm hu c to thnh. Cu 12: Tch hidro halogenua t 2 clo butan, 3 clo pentan, 2 clo 3 metyl butan. Cu 13: Tch nc to olefin t cc ancol sau: a) 2- metyl pentan -3 ol b) 3- metyl pentan -2 ol

c) 2,3 dimetyl butan -2 ol d) 2 metyl butan -2 ol e) ancol isobutylic Cu 14:Hidrat ha cc anken sau: a) but 1 en b) 2 metyl but 1 en c) 3 metyl but 1 en d) 2 metyl but 2 en e) 2,3 dimetyl but 2 en f) Pent 2 en g) Isobutilen Phn 4: ng phn v gi tn: Cu 15: Vit CTCT cc ng phn v gi tn tng cht. - Ancol c CTPT l C4H10O, C5H12O. - Ancol bc 1 ca C6H14O - ng phn thm ca C7H8O. Trong cc ng phn ca C7H8O hy cho bit: + Hp cht no thuc loi phenol, anco, ete? + Hp cht no tc dng c vi Na,vi KOH, c Na v KOH Cu 16: Vit CTCT cc ng phn dn xut halogen v gi tn tng cht. Dn xut halogen C3H7Cl, C3H6Br2 , C4H9Cl Cu 17: Vit CTCT cc ng phn andehit v gi tn Andehit c CTPT C4H8O, C5H10O , C6H12O .. Cu 18:Vit CTCT cc ng phn n chc , mch h v gi tn ca tng cht - C3H8O, C4H10O - Andehit v xeton : C3H6O, C4H8O Phn 5:Hon thnh cc chui phn ng sau: Cu 19: (1) (2) (3) (4) (5) (6) a) natri axetat metan axetilen benzen brom benzen A phenol (1) (2) (3) (4) b)nhm cacbua metan axetilen andehit axetic CH3COONH4 (6) (7) (8) ancol etylic buta -1,3-dien cao su (1) (2) (3) (4) (5) c)butan etan etyl clorua etanol etilen P.E (7) (6) (8) (9) etanol axit axetic CO2 (2)+ H2 (1) (3) (4) (5) d)t n X Y ancolZ A cao su Buna (1) (3) (5) (6) (4)+CuO,t0 e)tinh bt glucoz X X dietyl ete Y (1) (2) (3) (4) (5) (5)' (6) (7) (8) (9) f)etilen X Y Z metan B B1 C D M 2,4,6
tribrom phenol
(5)+ ddAgNO3 + NH3 (1) (2)+ NaOH (4)+CuO (6)+ NaOH (7)+ HCl g)toluen benzyl clorua X Y Z R Q (8)+C2H5OH A (1) (2) (3) h)natri axetat metan andehit fomic amoni cacbonat (4) (5) (6) ancol A andehit B amoni fomat (1) (2) (3) (4) (5) k)propan metan metyl clorua ancol metylic andehit fomic CO2 (1) (2) (3) (4) l)CH2=CH CH2Cl propyl clorua ancol A andehit B bc

(6)

m)butanmetanaxetilenandehit Xancol Y Acao su buadien o)t n ABCDE2,4,6-tribrom phenol Phn 6:iu ch v nhn bit: Cu 20: iu ch a) T natri axetat iu ch P.E, cao su Buna, etyl axetat, dietyl ete, phenol b) T t n iu ch P.E, etyl axetat, phenol, dimetyl ete, cao su Buna c) T etyl clorua iu ch P.E, dietyl ete, etyl axetat, phenol, andehit fomic d) T natri axetat iu ch metyl axetat

Cu 21: Nhn bit a) ancol etylic, fomol,stiren, phenol, benzen b) metanol, dd andehit axetic, phenol, ancol anlylic(CH2=CH-CH2-OH) . c) Ancol propylic, dung dch andehit propionic, phenol, stiren. d) Propan -1-ol , propan -2-ol, glixerol,phenol Phn 7: Mt s bi ton *Xc nh CTPT ca mt cht Cu 22: Cho 15g mt ancol X n chc no, mch h tc dng vi Na(d) thu c 2,8lit (ktc). a) Xc nh CTPT , CTCT v tn c th c ca ancol X. b) Khi ancol X tc dng vi CuO, un nng c sn phm G c kh nng to kt ta bc khi tc dng vi dung dch AgNO3 trong mi trng NH3 , un nh . Xc nh ng CTCT ca X. Cu 23: Oxi ha hon ton 5,75g mt ancol Y n no mch h bng CuO , em sn phm cho tc dng vi dung dch AgNO3 trong NH3, un nh thy to thnh 27g Ag.Bit rng cc phn ng xy ra hon ton. a)Xc nh CTCT ca Y. b)Khi cho 17,25g Y tc dng vi d axit axetic vi hiu sut l 25% th sn phm hu c thu c c khi lng l bao nhiu? Cu 24: Cho 8,7g mt ankanal (khc HCHO) tc dng vi dung dch AgNO3 trong mi trng NH3 , un nh thy to thnh 32,4g Ag . a)Xc nh tn ca ankanal. b)Tnh th tch H2 (ktc) cn dng hidro ha hon ton ankanal trn. *Xc nh CTPT ca hn hp cht ng ng k tip . Cu 26: Cho natri kim loi tc dng vi 11g hn hp hai ancol ng ng lin tip trong dy ng ng ca ancol etylic thy thot ra 3,36lit H2(ktc) .Xc nh CTPT v xc nh thnh phn khi lng ca tng cht trong hn hp ancol u. Cu 27: Cho 18,9g mt hn hp 2 ancol n chc no, mch h k tip nhau tc dng vi lng d Na thu c 3,92lit H2(ktc). a)Tnh khi lng mui thu c sau phn ng . b)Tm CTPT ca 2 ancol v thnh phn % theo khi khi lng ca chng . c)em oxi ha 18,9g hn hp ancol trn bng CuO sau em ton b sn phm hu c cho tc dung vi lng d dung dch AgNO3 trong NH3 th thu c 32,4gbc kim loi. Bit rng cc phn ng xy hon ton .Xc nh CTCT ng ca cc ancol. Cu 27:Ly 0,94gam hn hp hai andehit n chc no k tip nhau trong dy ng ng cho tc dng ht vi dung dch AgNO3/NH3 thu c 3,24g Ag. Xc nh CTCT , tn v thnh phn % theo khi lng ca tng cht trong hn hp . *Xc nh CTPT ca mt cht trong mt hn hp . Cu 28: Mt hn hp X gm mt andehit n no (khc HCHO), phenol -Nu cho 16,6g X tc dng vi Na d thu c 1,12lit kh H2(ktc). -Nu cho 33,2g X tc dng vi dung dch AgNO3/NH3 thu c 43,2g Ag. a)Xc nh thnh phn % ca tng cht . b)Tm CTPT , CTCT v tn ca andehit . c)Xc nh CTCT ng ca andehit , bit rng khi cho andehit tc dng vi lng d H2 thu c mt ancol c nhnh . Vit phn ng minh ha . Cu 29: Mt hn hp Y gm andehit axetic , phenol, v mt ancol n chc no, mch h . -Nu cho 23g Y tc dng vi Na th thu c 3,36lit H2(ktc). - trung ha 23g Y phi dng 100ml dung dch NaOH 1M. -Mt khc , khi cho 11,5g Y tc dng vi dung dch AgNO3/NH3 th thu c 10,8g Ag. a)Xc nh CTPT ca ancol. b)Tnh th tch khng kh cn dng t chy hon ton 23g Y, bit O2 chim 20% th tch khng kh . Cu 30: Cho m(g) hn hp gm HCHO v phenol tc dng vi ddAgNO3/NH3 thu c 43,2g Ag. Mt khc trung ha 2m(g) hn hp trn cn phi dng 150ml dung dch NaOH 2M. a)Xc nh thnh phn % khi lng tng cht ban u .

b)Hidro ha m(g) hn hp , em sn phm cho tc dng vi Na thu c bao nhiu lit kh H2 iu kin tiu chun. Cu 31: Cho mg hn hp X gm ancol propylic v mt andehit n no(khc HCHO) , mch h -Cho X tc dng vi Na(d) thu c 2,8lit H2(ktc). -em t chy ht X , dn ton b sn phm chy thu c cho i qua dung dch nc vi trong c d thi thu c 120g kt ta . -Khi cho X tc dng vi lng d dung dch AgNO3/NH3 th thu c 32,4g. Xc nh thnh phn % v CTPT ca andehit trn . *Xc nh thnh phn % ca hn hp Cu 32: Cho 0,92g mt hn hp gm C2H2 v CH3CHO tc dng va vi dung dch AgNO3/NH3 thu c 5,64g hn hp rn . Phn trm s mol ca tng cht trong hn hp . Cu 33: Cho hn hp Z gm C2H5OH, C6H5OH, glixerol. -Cho Z tc dng vi Na (d) thu c 8,4lit H2(ktc). -Nu trung ha Z cn phi dng 100ml dung dch KOH 1M. -Z ha tan c 7,35g Cu(OH)2. a)Tnh %m ca glixerol trong hn hp b)Nu cho Z tc dng vi dung dch Br2 thu c bao nhiu g kt ta ? Cu 34: hidro ha 8,8g hn hp gm 2 andehit n no, mch h cn va ng 4,48lit H2(ktc). Khi cho 8,8g hn hp trn tc dng vi lng d dung dch AgNO3/NH3 thu c 64,8g Ag. Xc nh CTCT v thnh phn % theo khi lng tng andehit trong hn hp .