ICECS-FA-1046-827

Evaluation of factors affecting performance of photocatalytic slurry reactor using nano

photocatalyst Titanum Dioxide in water treatment
Sara Madadi1, Morteza Sohrabi1, Sayed Javid Royaee2
1

Chemical Engineering Department, Amirkabir University of Technology, P.O. Box 15875-4413, Tehran, Iran
2

Refining Technology Development Division, Research Institute of Petroleum Industry, Tehran, Iran

Abstract
The above article is an overview of the possible applications of hybrid photocatalysis- membrane processes in water
purification and wastewater treatment are discussed. Different configurations of photocatalytic membrane reactors
(PMRs) is available that They include PMRs with photocatalyst immobilized on/in the membrane and reactors with
catalyst in suspension. In this paper slurry reactors are described and characterized . Advantages and disadvantages
of the hybrid photocatalysis-membrane processes in terms of permeate flux, membrane fouling and permeate quality
are discussed.
Keywords: photocatalytic membrane reactor, nano photocatalyst, TiO2 , UV

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ICECS-FA-1046-827

-1 -2

1 -
Sara.madady@gmail.com
2 -
sohrabi@aut.ac.ir
3 -
royaeesj@ripi.ir

.
( )PMR

.

TiO2

-
.

)1 : TiO2 )2
TiO2 (

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 ]212[ ) NF( .
. )..

.

.
.

MF UF .


( . )NF

[ ]1 .

PMR .

- Ollis

Palmisano Molinari ]22[ 2003 2005

[ . ]1

[ Auguliaro ]23 ]13[ 2006 .

)1 :

)2

)3

[ . ]1

PMR

PMR

..

() AOP .

( ) OH

]76[ )MF(]2117[ )UF(

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()1

)TiO2+hTiO2 (eCB-+hVB+

()2

TiO2(hVB+)+H2OTiO2+H++OH

[ . ]1

()3

TiO2(hVB+)+OHTiO2+OH.

()4

TiO2(eCB-)+O2TiO+O2.

( )

()5

() 6

()7

O2 +H HO2

HO2.+ HO2.H2O2+O2
.

OH + OH

TiO2(eCB-)+H2O2
.

()8

H2O2+ O2 OH + OH +O2

()9

H2O2+h2 OH.

[ ]1

()10

. :

Organic compound + OH degradation

product

)1
( )
)2
( )
)3
)4

()11
Organic compound + TiO2(hVB+) oxidation
product
()12
Organic compound + TiO2(eCB-) reduction
product

)5
)6
( )4

[ . ]1
UV
:

()
.


.

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 )5

)6
.

(CeO2 ZnO TiO2

)... V2O5 WO3 ZrO2 ().. ZnS CdS

( . )1

. TiO2

- ( )12-2

( 3/2 ) TiO2

H2O

OH

( )3-2
O2.-
( . )4
9-5 .
( ) OH.

( . )10



.

.
[. ]1

:
.
20 80 .

80

[. ]1

: pH pH

)1 :

[. ]1

)2 TiO2 )3 TiO2

)1 : )2 )3
)4

)1 ( ) TiO2
pH=6.8 . TiO2
( ) pH<6.8

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 ( . ) pH>6.8

pH>pzc pH<pzc

:)

)2 TiO2

[. ]1

( ) 0-20 mW/cm2
( )
-
- .)

) 3

( ) 25 mW/cm2

( )3

( )

H+ ( )5

( )9-6 .

.)

OH. OH.

TiO2
. pH
.
pH pH

.
TiO2 :

. UV
( . ) <390 nm 5

UV )365 nm
UV-A(max=355 ) UV-C( max=254 nm . UV
.

( )
.

O2.- (
TiO2 ) .
:


.
.
.


.

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 .


.

.
.

. :

3 5 .

( TiO2 0/1

) .

... .

)1 : )2

)3 . ...

)1 :
)2 .

.

.

.

.

.
)MF( )UF(
( )NF ( ) RO .


.

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 ) MF UF NF (
MF RO NF UF
.

.
cross flow dead end .
dead end
.
.
.
cross flow
.

hollow fiber flat sheet (

)... submerged .
PMR
( )3 (
)21 .
PMR . PMR
3
.
.

10-4
.

.

( ) submerged .
.
.

:1 [ ]1

.


.

. PMR (
) cross flow dead end batch continuous flow

: 2 [ ]1

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 : 3 () [ ]1

]2 [ 4

4 PMR NF
. PMR
[ . ]21
( ) h
) l (
( . ) b
. ( ) b 125
.
.
PMR
.

]4 [5

5 PMR

[ . ]4 .
UV

:
.
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( 5/5 21)

UV .

11( UV 253 /7)

. 4

UV

E.coliform . ()

. 250 .

( 11 253/7

TiO2 .

) .

TiO2 Fe2O3

E.coliform

.
UV
. PMR
[. ]1874

PMR 7
. PMR ) BPA (
[ . ]109
hollow fiber
. UV-A 4 8

. UV
.

]5 [6

6
[ . ]5

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 .
UV
5 1 UV

.
.

] 9[7

TMP
.

. .
PMR 8
3
15( UV 254 )
[ . ]8 ( 100
) 0/01515
UV .


.

PVDF PAN PTFE

UV .
( )RB5.

] 8[8

9 PMR
[.]11

TiO2/UV
.
( )1
)3( )2( TiO2
( )5 3 32 ( UV
254) ( )6

.

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 1 30 .

PFP1

( ) G TiO2

[ . ]1312

( )6
( )8 TiO2
( TiO2 . )9
(. ]11 [ )5

]12 [10

PMR

]11 [9

TiO2

PMR 10

.
[ . ]1312
PMR .
( )a-10 ( )b -10
.
( ) PFP1 UV
.
( PFP1
) ( . ) C

[ . ]15141
0/5 3 .
]16[ Geissen Xi
TiO2
( 0/054
) . 0/054 0/135
.
TiO2
.

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TiO2

. TiO2

TiO2 TiO2

TiO2

[ . ]17 TiO2 UV

[. ]161

[ . ]18

TiO2 )1 : ( PH

)2 ).. NOM . [ ]161

TiO2

pH . pH

[ . ]15141

6/9 TiO2

TiO2

0/135 60

16 pH ( 5)11

TiO2 .

0/08

.

50 TiO2
[ ]19 [ Molinari . ]151

TiO2 .
]16[11

NOM

. NOM TiO2

]17 [ Lee .

UV [.]109 1

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PMR

[ ]109

. ]10 [ Chin

TiO2 .

TiO2 [. ] 10

( 0/1 0/4 ) IF 70 90
.
IF
[. ]1091

Li
]20 [ Zhao .
-
.

PMR

COD 85/4 62/5

TiO2

100 76 2/5 -0/5

[ ]4

PMR

[ . ]21 1

. RO

. )1 : )2

)3 )...

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.
PMR )1 :
PMR )2 .

. PMR TiO2
. PMR

.
MF
NF UF TiO2 .

.
( )
PMR

. PMR
.

-
.

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