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as reportedbelow: a first order gasphasereactionproceeds of pore difrrsion resistance In the absence re= -106 moUs'cm3cat at Ce=10'smo{cm3; P=latm and T=400oC effectsdo not What size catalystpelleS shouldwe use(De=10'' cm'ls;to insure that pore resistance intrude to slow the rate ofreaction? Problem 2: by F)rous pellets ahut 3mm in is catalyzed hydrocarbon A liquid phasehydrogenationof an unsaturated reactant,hydrogen,and limitation to the respect diameter;the reaction is approximatelyfirst order with we hopeto achieveusefrrlreactionratesofthe order: -rrn: I 0{ moV(sec' cm3cat) fluid is estimatedto be From vaDor-liquid equilibrium datathe solubility of hydrogenin hydrocarbon to be propodonal to solubility this also expect we ideal behavior Aszuming Crn=10-5 moUcm"3at I ut . is estimated to be reactants of phase. diffi$ivity The effective pressure liquid the of hydrogenabove thJ liquid is a this since components, of the of concentration independent D"=2*10-5 cm2/sand ipproximately pore insure that to operate pressure we should which at the estimate information system. From this difrrsion efrectsare absent. Problem 3: . -v kinetics data of the enclosed interpretation,in terms of controlling resistance What is the most reasonable porous. isothermal Assume is the catalyst if know that we obtainedin a baskettype mixed reactor operationbehavior. Case Pellet Diameter leaving conc.ofreactant Spinning rate of baskets Measuredreactionrate high low high

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Problem 4: and activation energyfor the reactiondata given in the What can you tell aboutthe controlling resistances reactor? following table obtainedin a baskettype mixed Flow rate of gas CA,in CA,out Amount of catalyst Pellet Diameter Spinning Rateof Baskets Temp oC mm g gmol/L gmol/L Olri ) 2 8 9 5 4 2 3 l l l l l0 6 4 9 I 2 2 2 low high high low 344 344 372 372