CHEM1001 Lecture 23 Worksheet

1. How do we recognise energy? 2. First Law of Thermodynamics sunlight, light globes (incandescent, LED, fluorescent) exercise explosion, combustion electricity (battery, mains, photovoltaic, dynamo) appliances spring, rubber band balloon bursting, bicycle pump, pistons (combustion engine) kinetic energy (translation and rotational motion) melting, boiling 3. Endothermic or exothermic? (Demonstration) NH4Cl: exothermic. Heat flows out. Surroundings warm up CaCl2: endothermic. Heat flows in. Surroundings cool down. 4. Calculations with heat capacity (a) C = 0.900 J/K/g (0.2 1000) g + 4.184 J/K/g (1000 cm3 1 g cm-1) = 4364 J/K (b) T = (100 20) C or (373 293) K = 80 K (c) q = 4364 J/K 80 K = 349120 J or 350 kJ