Kha hc LTH m bo mn Ha Thy Ngc

L thuyt trng tm v ancol-phenol

L THUYT TRNG TM V ANCOL-PHENOL BI TP T LUYN

Cu 1: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); CH2-CH2-CH2OH (Y); HOCH2CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l: A. X, Y, R, T B. X, Z, T C. Z, R, T D. X, Y, Z, T (Trch thi tuyn sinh Cao ng 2007) Cu 2: Cho cc hp cht sau: (a) HOCH2-CH2OH (b) HOCH2CH2CH2OH (c) HOCH2-CH(OH)-CH2OH (d) CH3CH(OH)CH2OH (e) CH3-CH2OH (f) CH3-O-CH2CH3 Cc cht u tc dng c vi Na, Cu(OH)2l: A. (a), (b), (c) B. (c), (d), (f) C. (a), (c), (d) D. (c), (d), (e) (Trch thi tuyn sinh H C khi B 2009) Cu 3: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%: A. 2 B. 5 C. 3 D. 4 (Trch thi tuyn sinh Cao ng 2007) Cu 4: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21:2:4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l: A. 5 B. 4 C. 6 D. 3 (Trch thi tuyn sinh H C khi A 2009) Cu 5: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l: A. metyl axetat B. axit acrylic C. anilin D. phenol (Trch thi tuyn sinh H C khi A 2009) Cu 6: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l: A. 2 B. 3 C. 4 D. 1 (Trch thi tuyn sinh H C khi A 2008) Cu 7: Dy gm cc cht u tc dng vi ancol etylic l: A. HBr (to), Na, CuO (to), CH3COOH (xc tc) B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH C. NaOH, K, MgO, HCOOH (xc tc) D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O (Trch thi tuyn sinh Cao ng 2009) Cu 8: Trong thc t, phenol c dng sn xut: A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D B. nha rezol, nha rezit v thuc tr su 666 C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric D. nha rezit, cht dit c 2,4-D v thuc n TNT (Trch thi tuyn sinh Cao ng 2009) Cu 9: Dy gm cc cht u phn ng vi phenol l: A. nc brom, anehit axetic, dung dch NaCl B. dung dch NaCl, dung dch NaOH, kim loi Na C. nc brom, axit axetic, dung dch NaOH D. nc brom, anhirit axetic, dung dch NaOH (Trch thi tuyn sinh H C khi B 2007) Cu 10: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi:
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Kha hc LTH m bo mn Ha Thy Ngc

L thuyt trng tm v ancol-phenol

A. dung dch NaOH B. Na kim loi C. nc Br2 D. H2 (Ni, nung nng) (Trch thi tuyn sinh H C khi B 2008) Cu 11: Cho s phn ng: + Cl2 (1:1) + NaOH, d + HCl C6 H 6 X Y Z Fe, t o t o cao, P cao Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6 B. C6H4(OH)2, C6H4Cl2 C. C6H5OH, C6H5Cl D. C6H5ONa, C6H5OH (Trch thi tuyn sinh H C khi A 2007) Cu 12: Cho cc phn ng:
t HBr + C2H5OH C2H4 + Br2 C2H4 + HBr C2H6 + Br2 S phn ng to ra C2H5Br l: A. 4 B. 3 C. 2 (Trch thi tuyn sinh H C khi B 2008) Cu 13: Cho s chuyn ho: H2SO4 c + HBr Butan - 2 - ol X (anken) Y o
t
0

askt (1:1 )

D. 1

+ Mg, ete khan

Trong X, Y, Z l sn phm chnh. Cng thc ca Z l: A. (CH3)3C-MgBr B. CH3-CH2-CH2 -CH2-MgBr C. CH3-CH(MgBr)-CH2-CH3 D. (CH3)2CH-CH2-MgBr (Trch thi tuyn sinh H C khi B 2009) Cu 14: Cho s chuyn ho sau :
+NaOH (d-), t , p +HCl (d-) 2 Toluen X Y Z Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm: A. m-metylphenol v o-metylphenol B. benzyl bromua v o-bromtoluen C. o-bromtoluen v p-bromtoluen D. o-metylphenol v p-metylphenol (Trch thi tuyn sinh H C khi B 2008) Cu 15: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l: A. 3 B. 1 C. 4 D. 2 (Trch thi tuyn sinh H C khi B 2007) Cu 16: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l: A. 2 B. 4 C. 1 D. 3 (Trch thi tuyn sinh H C khi B 2007) Cu 17: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l: A. HOC6H4CH2OH B. CH3C6H3(OH)2 C. CH3OC6H4OH D. C6H5CH(OH)2 (Trch thi tuyn sinh Cao ng 2007) Cu 18: Cho X l hp cht thm, a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l: A. HO-C6H4-COOCH3 B. CH3-C6H3(OH)2 C. HO-CH2-C6H4-OH D. HO-C6H4-COOH (Trch thi tuyn sinh H C khi B 2009) +Br (1:1), Fe, t0
0

Hocmai.vn Ngi trng chung ca hc tr Vit

Tng i t vn: 1900 58-58-12

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Kha hc LTH m bo mn Ha Thy Ngc

L thuyt trng tm v ancol-phenol

Cu 19: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l: A. 2-metylbuten-3 (hay 2-metylbut-3-en) B. 2-metylbuten-2 (hay 2-metylbut-2-en) C. 3-metylbuten-2 (hay 3-metylbut-2-en) D. 3-metylbuten-1 (hay 3-metylbut-1-en) (Trch thi tuyn sinh H C khi A 2008) Cu 20: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l: A. (CH3)3COH B. CH3OCH2CH2CH3 C. CH3CH(OH)CH2CH3 D. CH3CH(CH3)CH2OH (Trch thi tuyn sinh H C khi A 2007)
Gio vin: V Khc Ngc Ngun: Hocmai.vn

Hocmai.vn Ngi trng chung ca hc tr Vit

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