156311177 Đề thi Đap an thi ĐH mon Hoa học Khối A B BGD ĐT 2008 2013

B GIO DC V O TO
CHNH THC
( thi c 6 trang)
THI TUYN SINH I HC NM 2013 Mn: HA HC; Khi A Thi gian lm bi: 90 pht, khng k thi gian pht M thi 193
H, tn th sinh:.......................................................................... S bo danh:............................................................................
Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Khi lng Ag thu c khi cho 0,1 mol CH3CHO phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng l A. 21,6 gam. B. 43,2 gam. C. 16,2 gam. D. 10,8 gam. Cu 2: Hn hp X gm 3,92 gam Fe, 16 gam Fe2O3 v m gam Al. Nung X nhit cao trong iu kin khng c khng kh, thu c hn hp cht rn Y. Chia Y thnh hai phn bng nhau. Phn mt tc dng vi dung dch H2SO4 long (d), thu c 4a mol kh H2. Phn hai phn ng vi dung dch NaOH d, thu c a mol kh H2. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 3,51. B. 4,05. C. 5,40. D. 7,02. Cu 3: T nilon-6,6 l sn phm trng ngng ca A. axit aipic v etylen glicol. B. axit aipic v hexametyleniamin. C. axit aipic v glixerol. D. etylen glicol v hexametyleniamin. Cu 4: iu kin thch hp xy ra cc phn ng sau: (b) C + 2H2 (a) 2C + Ca CaC2. CH4. (c) C + CO2 (d) 3C + 4Al 2CO. Al4C3. Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng A. (a). B. (c). C. (d). D. (b). Cu 5: Tin hnh cc th nghim sau: (a) Sc kh etilen vo dung dch KMnO4 long. (b) Cho hi ancol etylic i qua bt CuO nung nng. (c) Sc kh etilen vo dung dch Br2 trong CCl4. (d) Cho dung dch glucoz vo dung dch AgNO3 trong NH3 d, un nng. (e) Cho Fe2O3 vo dung dch H2SO4 c, nng. Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l A. 3. B. 4. C. 2. D. 5. Cu 6: Oxi ha hon ton 3,1 gam photpho trong kh oxi d. Cho ton b sn phm vo 200 ml dung dch NaOH 1M n khi phn ng xy ra hon ton, thu c dung dch X. Khi lng mui trong X l A. 16,4 gam. B. 14,2 gam. C. 12,0 gam. D. 11,1 gam. Cu 7: Tin hnh in phn dung dch cha m gam hn hp CuSO4 v NaCl (hiu sut 100%, in cc tr, mng ngn xp), n khi nc bt u b in phn c hai in cc th ngng in phn, thu c dung dch X v 6,72 lt kh (ktc) anot. Dung dch X ha tan ti a 20,4 gam Al2O3. Gi tr ca m l A. 25,6. B. 51,1. C. 50,4. D. 23,5. Cu 8: Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung dch AgNO3 trong NH3 d, un nng? A. vinylaxetilen, glucoz, axit propionic. B. vinylaxetilen, glucoz, anehit axetic. C. glucoz, imetylaxetilen, anehit axetic. D. vinylaxetilen, glucoz, imetylaxetilen.
Trang 1/6 - M thi 193
Cu 9: Trong iu kin thch hp, xy ra cc phn ng sau: (a) 2H2SO4 + C 2SO2 + CO2 + 2H2O. (b) H2SO4 + Fe(OH)2 FeSO4 + 2H2O. (c) 4H2SO4 + 2FeO Fe2(SO4)3 + SO2 + 4H2O. (d) 6H2SO4 + 2Fe Fe2(SO4)3 + 3SO2 + 6H2O. Trong cc phn ng trn, phn ng xy ra vi dung dch H2SO4 long l A. (d). B. (a). C. (c). D. (b). Cu 10: Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, NaCl v Na2SO4. B. HNO3, Ca(OH)2 v KNO3. C. NaCl, Na2SO4 v Ca(OH)2. D. HNO3, Ca(OH)2 v Na2SO4. Cu 11: Cho 100 ml dung dch amino axit X nng 0,4M tc dng va vi 80 ml dung dch NaOH 0,5M, thu c dung dch cha 5 gam mui. Cng thc ca X l B. NH2C3H5(COOH)2. A. NH2C3H6COOH. C. (NH2)2C4H7COOH. D. NH2C2H4COOH. Cu 12: Cht no sau y khng to kt ta khi cho vo dung dch AgNO3? A. HCl. B. K3PO4. C. KBr. D. HNO3. Cu 13: Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni. Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 8. Sc X vo lng d dung dch AgNO3 trong NH3 n phn ng hon ton, thu c hn hp kh Y v 24 gam kt ta. Hn hp kh Y phn ng va vi bao nhiu mol Br2 trong dung dch? A. 0,20 mol. B. 0,10 mol. C. 0,25 mol. D. 0,15 mol. Cu 14: trng thi c bn, cu hnh electron ca nguyn t Na (Z = 11) l B. 1s22s22p63s1. C. 1s22s22p63s2. D. 1s22s22p43s1. A. 1s22s22p53s2. Cu 15: Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l A. 2,33 gam. B. 0,98 gam. C. 3,31 gam. D. 1,71 gam. Cu 16: Hn hp X gm Ba v Al. Cho m gam X vo nc d, sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 (ktc). Mt khc, ha tan hon ton m gam X bng dung dch NaOH, thu c 15,68 lt kh H2 (ktc). Gi tr ca m l A. 16,4. B. 29,9. C. 24,5. D. 19,1. Cu 17: Dung dch axit axetic phn ng c vi tt c cc cht trong dy no sau y? A. NaOH, Cu, NaCl. B. Na, NaCl, CuO. C. NaOH, Na, CaCO3. D. Na, CuO, HCl. Cu 18: Cho s cc phn ng:
Y + Z; X + NaOH (dung dch)

1500o C
to
T + P; Y + NaOH (rn)
t o ,xt
t o ,CaO
Q + H2 ; Z. T Q + H2O Trong s trn, X v Z ln lt l: A. CH3COOCH=CH2 v CH3CHO. B. HCOOCH=CH2 v HCHO. D. CH3COOC2H5 v CH3CHO. C. CH3COOCH=CH2 v HCHO. Cu 19: Hn hp X cha ba axit cacboxylic u n chc, mch h, gm mt axit no v hai axit khng no u c mt lin kt i (C=C). Cho m gam X tc dng va vi 150 ml dung dch NaOH 2M, thu c 25,56 gam hn hp mui. t chy hon ton m gam X, hp th ton b sn phm chy bng dung dch NaOH d, khi lng dung dch tng thm 40,08 gam. Tng khi lng ca hai axit cacboxylic khng no trong m gam X l A. 15,36 gam. B. 9,96 gam. C. 12,06 gam. D. 18,96 gam. Cu 20: Thc hin cc th nghim sau: (a) Cho dung dch HCl vo dung dch Fe(NO3)2. (b) Cho FeS vo dung dch HCl. (c) Cho Si vo dung dch NaOH c. (d) Cho dung dch AgNO3 vo dung dch NaF. (e) Cho Si vo bnh cha kh F2. (f) Sc kh SO2 vo dung dch H2S.
Trong cc th nghim trn, s th nghim c xy ra phn ng l A. 5. B. 3. C. 6. D. 4. Cu 21: Kim loi st tc dng vi dung dch no sau y to ra mui st(II)? B. CuSO4. A. HNO3 c, nng, d. C. H2SO4 c, nng, d. D. MgSO4. Cu 22: Phenol phn ng c vi dung dch no sau y? A. NaCl. B. HCl. C. NaHCO3. D. KOH. Cu 23: Cho hn hp X gm 0,01 mol Al v a mol Fe vo dung dch AgNO3 n khi phn ng hon ton, thu c m gam cht rn Y v dung dch Z cha 3 cation kim loi. Cho Z phn ng vi dung dch NaOH d trong iu kin khng c khng kh, thu c 1,97 gam kt ta T. Nung T trong khng kh n khi lng khng i, thu c 1,6 gam cht rn ch cha mt cht duy nht. Gi tr ca m l A. 6,48. B. 3,24. C. 8,64. D. 9,72. Cu 24: Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X v hai kim loi trong Y ln lt l: A. Fe(NO3)2; Fe(NO3)3 v Cu; Ag. B. Cu(NO3)2; AgNO3 v Cu; Ag. C. Cu(NO3)2; Fe(NO3)2 v Cu; Fe. D. Cu(NO3)2; Fe(NO3)2 v Ag; Cu. Cu 25: ng vi cng thc phn t C4H10O c bao nhiu ancol l ng phn cu to ca nhau? A. 4. B. 3. C. 2. D. 5. Cu 26: Tn thay th (theo IUPAC) ca (CH3)3CCH2CH(CH3)2 l A. 2,2,4,4-tetrametylbutan. B. 2,4,4-trimetylpentan. C. 2,2,4-trimetylpentan. D. 2,4,4,4-tetrametylbutan. Cu 27: Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt (ktc) hn hp kh X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi tr ca m l A. 21,60. B. 18,90. C. 17,28. D. 19,44. Cu 28: Cht no sau y khi un nng vi dung dch NaOH thu c sn phm c anehit? A. CH3COOCH2CH=CH2. B. CH3COOC(CH3)=CH2. D. CH3COOCH=CHCH3. C. CH2=CHCOOCH2CH3. Cu 29: Lin kt ha hc gia cc nguyn t trong phn t HCl thuc loi lin kt A. cng ha tr c cc. B. hiro. C. cng ha tr khng cc. D. ion. Cu 30: Cho X l hexapeptit AlaGlyAlaValGlyVal v Y l tetrapeptit GlyAlaGlyGlu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit, trong c 30 gam glyxin v 28,48 gam alanin. Gi tr ca m l A. 73,4. B. 77,6. C. 83,2. D. 87,4. Cu 31: Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch NaOH d, un nng, thu c m gam glixerol. Gi tr ca m l A. 27,6. B. 4,6. C. 14,4. D. 9,2. Cu 32: Cho cc cn bng ha hc sau: 2HI (k). N2O4 (k). (b) 2NO2 (k) (a) H2 (k) + I2 (k) 2NH3 (k). 2SO3 (k). (d) 2SO2 (k) + O2 (k) (c) 3H2 (k) + N2 (k) nhit khng i, khi thay i p sut chung ca mi h cn bng, cn bng ha hc no trn khng b chuyn dch? A. (b). B. (a). C. (c). D. (d). Cu 33: Dung dch no sau y lm phenolphtalein i mu? A. axit axetic. B. alanin. C. glyxin. D. metylamin. Cu 34: Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X vo nc, thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam Ba(OH)2. Hp th hon ton 6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta. Gi tr ca m l A. 15,76. B. 39,40. C. 21,92. D. 23,64.
Cu 35: Ha tan hon ton 1,805 gam hn hp gm Fe v kim loi X bng dung dch HCl, thu c 1,064 lt kh H2. Mt khc, ha tan hon ton 1,805 gam hn hp trn bng dung dch HNO3 long (d), thu c 0,896 lt kh NO (sn phm kh duy nht). Bit cc th tch kh u o iu kin tiu chun. Kim loi X l A. Zn. B. Cr. C. Al. D. Mg. Cu 36: Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi clo theo t l mol 1 : 1, thu c ba dn xut monoclo l ng phn cu to ca nhau? A. neopentan. B. pentan. C. butan. D. isopentan. Cu 37: Ln men m gam glucoz to thnh ancol etylic (hiu sut phn ng bng 90%). Hp th hon ton lng kh CO2 sinh ra vo dung dch Ca(OH)2 d, thu c 15 gam kt ta. Gi tr ca m l A. 7,5. B. 15,0. C. 18,5. D. 45,0. Cu 38: Cho m gam Fe vo bnh cha dung dch gm H2SO4 v HNO3, thu c dung dch X v 1,12 lt kh NO. Thm tip dung dch H2SO4 d vo bnh thu c 0,448 lt kh NO v dung dch Y. Bit trong c hai trng hp NO l sn phm kh duy nht, o iu kin tiu chun. Dung dch Y ha tan va ht 2,08 gam Cu (khng to thnh sn phm kh ca N+5). Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 2,40. B. 4,06. C. 3,92. D. 4,20. Cu 39: Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gam X vo 360 ml dung dch NaOH 0,5M (d 20% so vi lng cn phn ng) n phn ng hon ton, thu c dung dch Y. C cn Y thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn va 7,84 lt O2 (ktc), thu c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l A. 13,2. B. 11,1. C. 12,3. D. 11,4. Cu 40: Bit X l axit cacboxylic n chc, Y l ancol no, c hai cht u mch h, c cng s nguyn t cacbon. t chy hon ton 0,4 mol hn hp gm X v Y (trong s mol ca X ln hn s mol ca Y) cn va 30,24 lt kh O2, thu c 26,88 lt kh CO2 v 19,8 gam H2O. Bit th tch cc kh o iu kin tiu chun. Khi lng ca Y trong 0,4 mol hn hp trn l A. 11,4 gam. B. 19,0 gam. C. 9,0 gam. D. 17,7 gam. II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (Phn A hoc Phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt X (ktc) vo bnh kn c sn mt t bt Ni. un nng bnh mt thi gian, thu c hn hp kh Y c t khi so vi H2 bng 10. Tng s mol H2 phn ng l A. 0,070 mol. B. 0,050 mol. C. 0,015 mol. D. 0,075 mol. Cu 42: Cho cc pht biu sau: (a) Trong bng tun hon cc nguyn t ha hc, crom thuc chu k 4, nhm VIB. (b) Cc oxit ca crom u l oxit baz. (c) Trong cc hp cht, s oxi ha cao nht ca crom l +6. (d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha. (e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom(III). Trong cc pht biu trn, nhng pht biu ng l: A. (b), (c) v (e). B. (a), (c) v (e). C. (b), (d) v (e). D. (a), (b) v (e). Cu 43: Dy cc cht u c kh nng tham gia phn ng thy phn trong dung dch H2SO4 un nng l: A. glucoz, tinh bt v xenluloz. B. saccaroz, tinh bt v xenluloz. C. glucoz, saccaroz v fructoz. D. fructoz, saccaroz v tinh bt. Cu 44: Cho cc cp oxi ha - kh c sp xp theo th t tng dn tnh oxi ha ca cc ion kim loi: Al3+/Al; Fe2+/Fe; Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau:
(a) Cho st vo dung dch ng(II) sunfat. (b) Cho ng vo dung dch nhm sunfat. (c) Cho thic vo dung dch ng(II) sunfat. (d) Cho thic vo dung dch st(II) sunfat. Trong cc th nghim trn, nhng th nghim c xy ra phn ng l: A. (a) v (b). B. (b) v (c). C. (a) v (c). D. (b) v (d). Cu 45: Cho X v Y l hai axit cacboxylic mch h, c cng s nguyn t cacbon, trong X n chc, Y hai chc. Chia hn hp gm X v Y thnh hai phn bng nhau. Phn mt tc dng ht vi Na, thu c 4,48 lt kh H2 (ktc). t chy hon ton phn hai, thu c 13,44 lt kh CO2 (ktc). Phn trm khi lng ca Y trong hn hp l A. 42,86 %. B. 57,14%. C. 85,71%. D. 28,57%. Cu 46: Cho 25,5 gam hn hp X gm CuO v Al2O3 tan hon ton trong dung dch H2SO4 long, thu c dung dch cha 57,9 gam mui. Phn trm khi lng ca Al2O3 trong X l A. 60%. B. 40%. C. 80%. D. 20%. Cu 47: Trong cc dung dch: CH3CH2NH2, H2NCH2COOH, H2NCH2CH(NH2)COOH, HOOCCH2CH2CH(NH2)COOH, s dung dch lm xanh qu tm l A. 4. B. 3. C. 1. D. 2. Cu 48: t chy hon ton hn hp X gm 0,07 mol mt ancol a chc v 0,03 mol mt ancol khng no, c mt lin kt i, mch h, thu c 0,23 mol kh CO2 v m gam H2O. Gi tr ca m l A. 2,70. B. 2,34. C. 8,40. D. 5,40. Cu 49: Th nghim vi dung dch HNO3 thng sinh ra kh c NO2. hn ch kh NO2 thot ra t ng nghim, ngi ta nt ng nghim bng: (a) bng kh. (b) bng c tm nc. (c) bng c tm nc vi. (d) bng c tm gim n. Trong 4 bin php trn, bin php c hiu qu nht l A. (d). B. (a). C. (c). D. (b). Cu 50: Cho phng trnh phn ng aAl + bHNO3 cAl(NO3)3 + dNO + eH2O. T l a : b l A. 1 : 3. B. 2 : 3. C. 2 : 5. D. 1 : 4. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho 12 gam hp kim ca bc vo dung dch HNO3 long (d), un nng n phn ng hon ton, thu c dung dch c 8,5 gam AgNO3. Phn trm khi lng ca bc trong mu hp kim l A. 45%. B. 55%. C. 30%. D. 65%. Cu 52: Cho cc pht biu sau: (a) x l thy ngn ri vi, ngi ta c th dng bt lu hunh. (b) Khi thot vo kh quyn, freon ph hy tng ozon. (c) Trong kh quyn, nng CO2 vt qu tiu chun cho php gy ra hiu ng nh knh. (d) Trong kh quyn, nng NO2 v SO2 vt qu tiu chun cho php gy ra hin tng ma axit. Trong cc pht biu trn, s pht biu ng l A. 2. B. 1. C. 4. D. 3. +Cl2 , d + dungdch NaOH, d Cu 53: Cho s phn ng Cr X Y. to Cht Y trong s trn l B. Na2Cr2O7. C. Cr(OH)2. D. Cr(OH)3. A. Na[Cr(OH)4]. Cu 54: Cho 13,6 gam mt cht hu c X (c thnh phn nguyn t C, H, O) tc dng va vi dung dch cha 0,6 mol AgNO3 trong NH3, un nng, thu c 43,2 gam Ag. Cng thc cu to ca X l A. CH2=C=CHCHO. B. CH3C CCHO. D. CH C[CH2]2CHO. C. CH CCH2CHO. Cu 55: Cho cc pht biu sau: (a) Glucoz c kh nng tham gia phn ng trng bc. (b) S chuyn ha tinh bt trong c th ngi c sinh ra mantoz.
(c) Mantoz c kh nng tham gia phn ng trng bc. (d) Saccaroz c cu to t hai gc -glucoz v -fructoz. Trong cc pht biu trn, s pht biu ng l A. 4. B. 2. C. 3. D. 1. Cu 56: Hn hp X gm ancol metylic, ancol etylic v glixerol. t chy hon ton m gam X, thu c 15,68 lt kh CO2 (ktc) v 18 gam H2O. Mt khc, 80 gam X ha tan c ti a 29,4 gam Cu(OH)2. Phn trm khi lng ca ancol etylic trong X l A. 23%. B. 16%. C. 8%. D. 46%. Cu 57: Cho phng trnh phn ng aFeSO4 + bK2Cr2O7 + cH2SO4 dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O. T l a : b l A. 6 : 1. B. 2 : 3. C. 3 : 2. D. 1 : 6. Cu 58: Trng hp no sau y khng xy ra phn ng? (a) CH2=CHCH2Cl + H2O (b) CH3CH2CH2Cl + H2O (c) C6H5Cl + NaOH (c) (d) C2H5Cl + NaOH A. (b). B. (a).
to t o cao, p cao to
; (vi C6H5 l gc phenyl) C. (d). D. (c).
Cu 59: Peptit X b thy phn theo phng trnh phn ng X + 2H2O 2Y + Z (trong Y v Z l cc amino axit). Thy phn hon ton 4,06 gam X thu c m gam Z. t chy hon ton m gam Z cn va 1,68 lt kh O2 (ktc), thu c 2,64 gam CO2; 1,26 gam H2O v 224 ml kh N2 (ktc). Bit Z c cng thc phn t trng vi cng thc n gin nht. Tn gi ca Y l A. lysin. B. axit glutamic. C. glyxin. D. alanin. Cu 60: Trng hp no sau y, kim loi b n mn in ha hc? A. Kim loi st trong dung dch HNO3 long. B. Thp cacbon trong khng kh m. C. t dy st trong kh oxi kh. D. Kim loi km trong dung dch HCl.
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HT ----------
B GIO DC V O TO THI CHNH THC P N THI TUYN SINH I HC NM 2013 Mn thi: HA HC; Khi A (p n c 02 trang)
M - p n 463 374
B B C D D D D B D C C C C A B A B D B A B C D C A D B C B C D A C D B B A A C A A A C C C D A A B D B A A B A B D D C A D B B C D C C C C B D A D B A A A A C B B D A D A B
Cu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43
617
D B D A A B C C C A D C A D D B A D C D C C D B C C C D A A B C B B D A D B B C D C B
531
D C B B B D D C A B C D C A A B D B B D B A B A A C C A D D A D C C D D C B A C A C D
286
B C D B B D B C A C B B C C D A B A D A B A B C C B D A A C B C D D B C D D C B A D C
193
A D B B B B B B D D A D D B C C C A C A B D C D A C A D A C D B D A C B B B C A D B B
Cu 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
617
C D C B A A B B D D B A A B A A A
531
C A B D C B B D B A A B C A D C A
M - p n 463 374
D B B A C A B C A D D A C B D D A B B B C C D C D C A C A D B D D C
286
A C A A C D D A B D D B A A C A D
193
C A D D D C D A C A C C A A A C B
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi A Thi gian lm bi: 90 pht, khng k thi gian pht M thi 296
Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO3 trong NH3 thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l A. 60%. B. 80%. C. 92%. D. 70%. Cu 2: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 4. B. 1. C. 2. D. 3. Cu 3: Cho cc phn ng sau: (a) H2S + SO2 (b) Na2S2O3 + dung dch H2SO4 (long) o t (c) SiO2 + Mg (d) Al2O3 + dung dch NaOH t l mol 1: 2 (g) SiO2 + dung dch HF (e) Ag + O3 S phn ng to ra n cht l A. 3. B. 6. C. 5. D. 4. Cu 4: t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 10,88%. C. 31,58%. D. 7,89%. Cu 5: Mt loi phn kali c thnh phn chnh l KCl (cn li l cc tp cht khng cha kali) c sn xut t qung xinvinit c dinh dng 55%. Phn trm khi lng ca KCl trong loi phn kali l A. 95,51%. B. 65,75%. C. 87,18%. D. 88,52%. Cu 6: Qung no sau y giu st nht? A. Xierit. B. Manhetit. C. Hematit . D. Pirit st. Cu 7: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l: A. (3), (1), (5), (2), (4). B. (4), (1), (5), (2), (3). C. (4), (2), (3), (1), (5). D. (4), (2), (5), (1), (3). Cu 8: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui (vi in cc tr) l: A. Ni, Cu, Ag. B. Ca, Zn, Cu. C. Li, Ag, Sn. D. Al, Fe, Cr.
Cu 9: Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c hn hp gm A. Al, Fe, Fe3O4 v Al2O3. B. Al2O3, Fe v Fe3O4. C. Al2O3 v Fe. D. Al, Fe v Al2O3. Cu 10: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l A. 13 gam. B. 20 gam. C. 15 gam. D. 10 gam. + Cu 11: Nguyn t R to c cation R . Cu hnh electron phn lp ngoi cng ca R+ ( trng thi c bn) l 2p6. Tng s ht mang in trong nguyn t R l A. 10. B. 11. C. 22. D. 23. Cu 12: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l A. CH4. B. C3H4. C. C4H10. D. C2H4. Cu 13: Cho 500 ml dung dch Ba(OH)2 0,1M vo V ml dung dch Al2(SO4)3 0,1M; sau khi cc phn ng kt thc thu c 12,045 gam kt ta. Gi tr ca V l A. 300. B. 75. C. 200. D. 150. Cu 14: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l A. 1,62. B. 1,44. C. 3,60. D. 1,80. Cu 15: Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2 0,5M; khi cc phn ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l A. 4,72. B. 4,48. C. 3,20. D. 4,08. Cu 16: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH). S cht trong dy c kh nng lm mt mu nc brom l A. 5. B. 4. C. 3. D. 2. Cu 17: Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol tan nhiu trong nc lnh. (b) Phenol c tnh axit nhng dung dch phenol trong nc khng lm i mu qu tm. (c) Phenol c dng sn xut phm nhum, cht dit nm mc. (d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen. (e) Cho nc brom vo dung dch phenol thy xut hin kt ta. S pht biu ng l A. 4. B. 2. C. 5. D. 3. Cu 18: Phn trm khi lng ca nguyn t R trong hp cht kh vi hiro (R c s oxi ha thp nht) v trong oxit cao nht tng ng l a% v b%, vi a : b = 11 : 4. Pht biu no sau y l ng? A. Phn t oxit cao nht ca R khng c cc. B. Oxit cao nht ca R iu kin thng l cht rn. C. Trong bng tun hon cc nguyn t ha hc, R thuc chu k 3. D. Nguyn t R ( trng thi c bn) c 6 electron s. Cu 19: X v Y l hai nguyn t thuc cng mt chu k, hai nhm A lin tip. S proton ca nguyn t Y nhiu hn s proton ca nguyn t X. Tng s ht proton trong nguyn t X v Y l 33. Nhn xt no sau y v X, Y l ng? A. n cht X l cht kh iu kin thng. B. m in ca X ln hn m in ca Y. C. Lp ngoi cng ca nguyn t Y ( trng thi c bn) c 5 electron. D. Phn lp ngoi cng ca nguyn t X ( trng thi c bn) c 4 electron. Cu 20: in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z.
Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi tr ca t l A. 0,8. B. 1,2. C. 1,0. D. 0,3. Cu 21: Pht biu no sau y l ng? A. Tt c cc peptit u c phn ng mu biure. B. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit. C. Mui phenylamoni clorua khng tan trong nc. D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai. Cu 22: Cho dy cc oxit: NO2, Cr2O3, SO2, CrO3, CO2, P2O5, Cl2O7, SiO2, CuO. C bao nhiu oxit trong dy tc dng c vi dung dch NaOH long? A. 7. B. 8. C. 6. D. 5. Cu 23: Hn hp X c khi lng 82,3 gam gm KClO3, Ca(ClO3)2, CaCl2 v KCl. Nhit phn hon ton X thu c 13,44 lt O2 (ktc), cht rn Y gm CaCl2 v KCl. Ton b Y tc dng va vi 0,3 lt dung dch K2CO3 1M thu c dung dch Z. Lng KCl trong Z nhiu gp 5 ln lng KCl trong X. Phn trm khi lng KCl trong X l A. 12,67%. B. 18,10%. C. 25,62%. D. 29,77%. Cu 24: Cho cc pht biu sau: (a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O. (b) Trong hp cht hu c nht thit phi c cacbon v hiro. (c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau. (d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag. (e) Saccaroz ch c cu to mch vng. S pht biu ng l A. 5. B. 3. C. 4. D. 2. Cu 25: Loi t no sau y c iu ch bng phn ng trng hp? A. T nitron. B. T visco. C. T xenluloz axetat. D. T nilon-6,6. Cu 26: Xt phn ng phn hy N2O5 trong dung mi CCl4 45oC: 1 N2O5 N2O4 + O2 2 Ban u nng ca N2O5 l 2,33M, sau 184 giy nng ca N2O5 l 2,08M. Tc trung bnh ca phn ng tnh theo N2O5 l B. 1,36.103 mol/(l.s). A. 2, 72.103 mol/(l.s). C. 6,80.103 mol/(l.s). D. 6,80.104 mol/(l.s). Cu 27: Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung dch H2SO4 long, sau phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung dch X l A. 4,83 gam. B. 5,83 gam. C. 7,33 gam. D. 7,23 gam. Cu 28: Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c dung dch X trong sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt ta; khi ht 300 ml hoc 700 ml th u thu c a gam kt ta. Gi tr ca a v m ln lt l A. 15,6 v 27,7. B. 23,4 v 35,9. C. 23,4 v 56,3. D. 15,6 v 55,4. Cu 29: Thc hin cc th nghim sau ( iu kin thng): (a) Cho ng kim loi vo dung dch st(III) clorua. (b) Sc kh hiro sunfua vo dung dch ng(II) sunfat. (c) Cho dung dch bc nitrat vo dung dch st(III) clorua. (d) Cho bt lu hunh vo thy ngn. S th nghim xy ra phn ng l A. 3. B. 1. C. 4. D. 2.
Cu 30: Cho s phn ng: xc tc (a) X + H2O Y (b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3 xc tc (c) Y E+Z nh sng (d) Z + H2O X+G cht dip lc X, Y, Z ln lt l: A. Xenluloz, fructoz, cacbon ioxit. B. Xenluloz, saccaroz, cacbon ioxit. C. Tinh bt, glucoz, etanol. D. Tinh bt, glucoz, cacbon ioxit. Cu 31: Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l mol): (a) X + 2NaOH X1 + X2 + H2O (b) X1 + H2SO4 X3 + Na2SO4 (c) nX3 + nX4 nilon-6,6 + 2nH2O (d) 2X2 + X3 X5 + 2H2O Phn t khi ca X5 l A. 174. B. 216. C. 202. D. 198. Cu 32: Cho cc cp oxi ho - kh c sp xp theo chiu tng dn tnh oxi ho ca dng oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l ng? B. Cu2+ oxi ho c Fe2+ thnh Fe3+. A. Fe2+ oxi ha c Cu thnh Cu2+. D. Cu kh c Fe3+ thnh Fe. C. Fe3+ oxi ha c Cu thnh Cu2+. Cu 33: Cho dy cc cht: Al, Al(OH)3, Zn(OH)2, NaHCO3, Na2SO4. S cht trong dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l A. 5. B. 4. C. 3. D. 2. Cu 34: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2? B. Dung dch NaOH, O2, dung dch KMnO4. A. Dung dch BaCl2, CaO, nc brom. D. H2S, O2, nc brom. C. O2, nc brom, dung dch KMnO4. Cu 35: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 7. C. 4. D. 5. Cu 36: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht Y l A. etylamin. B. propylamin. C. butylamin. D. etylmetylamin. Cu 37: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 8,16. B. 4,08. C. 2,04. D. 6,12. Cu 38: Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H2SO4 c thu c anken Y. Phn t khi ca Y l A. 42. B. 70. C. 28. D. 56. Cu 39: Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO3)2 thu c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh thot ra th ht 560 ml. Bit ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l A. 3,94 gam. B. 7,88 gam. C. 11,28 gam. D. 9,85 gam. Cu 40: Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, p-HO-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin sau? (a) Ch tc dng vi NaOH theo t l mol 1 : 1. (b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng. A. 3. B. 4. C. 1. D. 2.
II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn ring (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no, a chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8 gam N2 (o trong cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit trn thu c 11,44 gam CO2. Phn trm khi lng ca X trong hn hp ban u l A. 72,22%. B. 27,78%. C. 35,25%. D. 65,15%. Cu 42: Cho s chuyn ha sau: (a) C3H4O2 + NaOH X + Y (b) X + H2SO4 (long) Z + T (c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3 (d) Y + dung dch AgNO3/NH3 (d) F + Ag + NH4NO3 Cht E v cht F theo th t l A. HCOONH4 v CH3CHO. B. (NH4)2CO3 v CH3COONH4. C. HCOONH4 v CH3COONH4. D. (NH4)2CO3 v CH3COOH. Cu 43: Nhn xt no sau y khng ng? A. Vt dng lm bng nhm v crom u bn trong khng kh v nc v c mng oxit bo v. B. Crom l kim loi cng nht trong tt c cc kim loi. C. Nhm v crom u b th ng ha bi HNO3 c, ngui. D. Nhm v crom u phn ng vi dung dch HCl theo cng t l s mol. Cu 44: Cho 100 ml dung dch AgNO3 2a mol/l vo 100 ml dung dch Fe(NO3)2 a mol/l. Sau khi phn ng kt thc thu c 8,64 gam cht rn v dung dch X. Cho dung dch HCl d vo X thu c m gam kt ta. Gi tr ca m l A. 22,96. B. 11,48. C. 17,22. D. 14,35. Cu 45: Cho cc phn ng sau: (a) FeS + 2HCl FeCl2 + H2S (b) Na2S + 2HCl 2NaCl + H2S (c) 2AlCl3 + 3Na2S + 6H2O 2Al(OH)3 + 3H2S + 6NaCl (d) KHSO4 + KHS K2SO4 + H2S (e) BaS + H2SO4 (long) BaSO4 + H2S S phn ng c phng trnh ion rt gn S2- + 2H+ H2S l A. 1. B. 3. C. 2. D. 4. Cu 46: Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy ra hon ton thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l A. Mg(NO3)2 v Fe(NO3)2. B. Fe(NO3)3 v Mg(NO3)2. C. AgNO3 v Mg(NO3)2. D. Fe(NO3)2 v AgNO3. Cu 47: t chy hon ton mt lng ancol X to ra 0,4 mol CO2 v 0,5 mol H2O. X tc dng vi Cu(OH)2 to dung dch mu xanh lam. Oxi ha X bng CuO to hp cht hu c a chc Y. Nhn xt no sau y ng vi X? A. Trong X c 3 nhm -CH3. B. Hirat ha but-2-en thu c X. C. Trong X c 2 nhm -OH lin kt vi hai nguyn t cacbon bc hai. D. X lm mt mu nc brom. Cu 48: S amin bc mt c cng cng thc phn t C3H9N l A. 3. B. 1. C. 2. D. 4. Cu 49: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ho l A. 70%. B. 80%. C. 60%. D. 50%. Cu 50: Dung dch cht no sau y lm qu tm chuyn thnh mu hng? A. Axit aminoaxetic. B. Axit -aminopropionic. C. Axit -aminoglutaric. D. Axit ,-iaminocaproic.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

H 3O KCN Cu 51: Cho s chuyn ha: CH 3Cl X Y. to +
Cng thc cu to ca X, Y ln lt l: A. CH3NH2, CH3COONH4. B. CH3CN, CH3CHO. C. CH3NH2, CH3COOH. D. CH3CN, CH3COOH. Cu 52: Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch brom l A. 5. B. 4. C. 2. D. 3. Cu 53: Dung dch X gm CH3COOH 0,03M v CH3COONa 0,01M. Bit 25oC, Ka ca CH3COOH l 1,75.105, b qua s phn li ca nc. Gi tr pH ca dung dch X 25oC l A. 4,28. B. 4,04. C. 4,76. D. 6,28.
o o Cu 54: Cho E o pin(Zn-Cu) = 1,10V; E Zn 2+ /Zn = -0,76V v E Ag + /Ag = +0,80V. Sut in ng chun
ca pin in ha Cu-Ag l A. 0,46V. B. 0,56V. C. 1,14V. D. 0,34V. Cu 55: Cho cc pht biu sau v cacbohirat: (a) Tt c cc cacbohirat u c phn ng thy phn. (b) Thy phn hon ton tinh bt thu c glucoz. (c) Glucoz, fructoz v mantoz u c phn ng trng bc. (d) Glucoz lm mt mu nc brom. S pht biu ng l A. 1. B. 2. C. 3. D. 4. Cu 56: Nhn xt no sau y khng ng? A. BaSO4 v BaCrO4 hu nh khng tan trong nc. B. Al(OH)3 v Cr(OH)3 u l hiroxit lng tnh v c tnh kh. C. SO3 v CrO3 u l oxit axit. D. Fe(OH)2 v Cr(OH)2 u l baz v c tnh kh. Cu 57: Cho cc pht biu sau: (a) Kh CO2 gy ra hin tng hiu ng nh knh. (b) Kh SO2 gy ra hin tng ma axit. (c) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon. (d) Moocphin v cocain l cc cht ma ty. S pht biu ng l A. 3. B. 1. C. 2. D. 4. Cu 58: Cho 18,4 gam hn hp X gm Cu2S, CuS, FeS2 v FeS tc dng ht vi HNO3 (c nng, d) thu c V lt kh ch c NO2 ( ktc, sn phm kh duy nht) v dung dch Y. Cho ton b Y vo mt lng d dung dch BaCl2, thu c 46,6 gam kt ta; cn khi cho ton b Y tc dng vi dung dch NH3 d thu c 10,7 gam kt ta. Gi tr ca V l A. 38,08. B. 24,64. C. 16,8. D. 11,2. Cu 59: C cc cht sau: keo dn ure-fomanehit; t lapsan; t nilon-6,6; protein; si bng; amoni axetat; nha novolac. Trong cc cht trn, c bao nhiu cht m trong phn t ca chng c cha nhm -NH-CO-? A. 6. B. 4. C. 3. D. 5. Cu 60: Kh este no, n chc, mch h X bng LiAlH4 thu c ancol duy nht Y. t chy hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO2 v H2O l A. 24,8 gam. B. 16,8 gam. C. 18,6 gam. D. 28,4 gam.
----------------------------------------------------------
HT ----------
B GIO DC V O TO CHNH THC
P N THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi A
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
296
B D D D C B D A D A C B D B A C A A D C D C B D A B D A C D C C B
384
C C A B A B C C C B D A A B B A D D B B B D C A A D D D C B D D D
528
B D D A C D A B A C B C B C A C D C A D B A C C B D D D B B B B D
647
A D C A D D B B A B A A A A C B B A A C A D B D D D A D D D A C B
752
C D D D D A C A C C A B A C B D A B D C B B D D A A A B D B C B D
913
B B B C C D A B A B D C D A B C D D B D C A C D A C A D A B A B A
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
296
C B A B A B C B B D B A A C C B C D D A A C B D A C A
384
C A A B B D D C A B D C A D C D A B A C A C A C B B C
528
D A A A D C C B A C A D A A C B D C B C A C B D B D A
647
C B D D C A A D D C C C B B C D C C B B C B C B B A C
752
C A D B C B B B D C B A C A C A C D B C C D A A A B D
913
B D D D B A A C C C B C A A D D C C B C C B D A D A B
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
H, tn th sinh: .......................................................................... S bo danh: ............................................................................
Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp) n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3, HNO3 v Cu(NO3)2. B. KNO3, KCl v KOH. C. KNO3 v Cu(NO3)2. D. KNO3 v KOH. Cu 2: Pht biu no sau y l sai? A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo. B. m in ca brom ln hn m in ca iot. C. Tnh kh ca ion Br ln hn tnh kh ca ion Cl . D. Tnh axit ca HF mnh hn tnh axit ca HCl. Cu 3: t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l 28 28 28 28 A. V = (x + 30y). B. V = ( x 30y). C. V = (x + 62y). D. V = (x 62y). 55 95 95 55 Cu 4: Qung st manhetit c thnh phn chnh l A. FeCO3. B. Fe2O3. C. Fe3O4. D. FeS2. Cu 5: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l A. 50,4. B. 40,5. C. 44,8. D. 33,6. Cu 6: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 26,88 lt. C. 44,8 lt. D. 33,6 lt. Cu 7: Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH)2 0,0125M, thu c x gam kt ta. Gi tr ca x l A. 2,00. B. 1,00. C. 1,25. D. 0,75. Cu 8: Trong cc th nghim sau: (1) Cho SiO2 tc dng vi axit HF. (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si n cht tc dng vi dung dch NaOH.
(6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. S th nghim to ra n cht l A. 7. B. 6. C. 5. D. 4. Cu 9: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l: A. HCl, NaOH, Na2CO3. B. NaOH, Na3PO4, Na2CO3. C. KCl, Ca(OH)2, Na2CO3. D. HCl, Ca(OH)2, Na2CO3. Cu 10: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 7. B. 9. C. 3. D. 10. Cu 11: S ng phn amino axit c cng thc phn t C3H7O2N l A. 1. B. 2. C. 3. D. 4. + Cu 12: Khi so snh NH3 vi NH4 , pht biu khng ng l: A. Phn t NH3 v ion NH4+ u cha lin kt cng ha tr. B. Trong NH3 v NH4+, nit u c s oxi ha 3. C. NH3 c tnh baz, NH4+ c tnh axit. D. Trong NH3 v NH4+, nit u c cng ha tr 3. Cu 13: Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 2. B. 5. C. 4. D. 6. Cu 14: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 3. B. 1. C. 4. D. 2. 2+ + 2+ Cu 15: Cho dy cc cht v ion: Fe, Cl2, SO2, NO2, C, Al, Mg , Na , Fe , Fe3+. S cht v ion va c tnh oxi ho, va c tnh kh l A. 8. B. 5. C. 4. D. 6. Cu 16: Ho tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,788. B. 4,480. C. 1,680. D. 3,920. Cu 17: Hp cht no ca canxi c dng c tng, b bt khi gy xng? A. T hch cao nung (CaSO4.H2O). B. vi (CaCO3). C. V i sng (CaO). D. T hch cao sng (CaSO4.2H2O). Cu 18: Khi ni v peptit v protein, ph t biu no sau y l sai? A. Protein c phn ng mu biure vi Cu(OH)2 . B. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. C. T hy phn hon ton protein n gin thu c cc -amino axit. D. Tt c cc protein u tan trong nc to thnh dung dch keo. Cu 19: t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi z = y x ). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l A. axit oxalic. B. axit acrylic. C. axit aipic. D. axit fomic. Cu 20: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 81,54. B. 66,44. C. 111,74. D. 90,6.
Cu 21: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau. - Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc). - Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ho tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp X ln lt l: A. 0,39; 0,54; 1,40. B. 0,78; 1,08; 0,56. C. 0,39; 0,54; 0,56. D. 0,78; 0,54; 1,12. Cu 22: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 3. B. 4. C. 2. D. 1. Cu 23: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CHC-CH3, CH2=C=C=CH2. B. CH2=C=CH2, CH2=CH-CCH. C. CHC-CH3, CH2=CH-CCH. D. CH2=C=CH2, CH2=C=C=CH2. Cu 24: Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ho hc ca phn chua l A. Na2SO4.Al2(SO4)3.24H2O. B. K2SO4.Al2(SO4)3.24H2O. C. (NH4)2SO4.Al2(SO4)3.24H2O. D. Li2SO4.Al2(SO4)3.24H2O. Cu 25: Thc hin cc th nghim sau: (1) t dy st trong kh clo. (2) t nng hn hp bt Fe v S (trong iu kin khng c oxi). (3) Cho FeO vo dung dch HNO3 (long, d). (4) Cho Fe vo dung dch Fe2(SO4)3. (5) Cho Fe vo dung dch H2SO4 (long, d). C bao nhiu th nghim to ra mui st(II)? A. 2. B. 1. C. 4. D. 3. Cu 26: Cho cn bng ho hc: H2 (k) + I2 (k) 2HI (k); UH > 0. Cn bng khng b chuyn dch khi A. tng nhit ca h. B. gim nng HI. D. gim p sut chung ca h. C. tng nng H2. Cu 27: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit no, mch h, hai chc. B. anehit khng no, mch h, hai chc. C. anehit axetic. D. anehit fomic. Cu 28: Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 2,20 tn. B. 1,10 tn. C. 2,97 tn. D. 3,67 tn. Cu 29: Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng hp metyl metacrylat. B. Trng hp vinyl xianua. C. Trng ngng hexametyleniamin vi axit aipic. D. Trng ngng axit -aminocaproic. Cu 30: Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l A. 2,24 lt. B. 4,48 lt. C. 1,12 lt. D. 3,36 lt.
Cu 31: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l A. 59,46%. B. 42,31%. C. 26,83%. D. 19,64%. Cu 32: Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng mui khan thu c l A. 19,76 gam. B. 22,56 gam. C. 20,16 gam. D. 19,20 gam. Cu 33: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 5. B. 3. C. 4. D. 6. Cu 34: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,2. B. 0,3. C. 0,6. D. 0,8. Cu 35: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 0,224 lt v 3,750 gam. B. 0,112 lt v 3,750 gam. C. 0,224 lt v 3,865 gam. D. 0,112 lt v 3,865 gam. Cu 36: Khi lng ring ca canxi kim loi l 1,55 g/cm3. Gi thit rng, trong tinh th canxi cc nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l A. 0,185 nm. B. 0,196 nm. C. 0,155 nm. D. 0,168 nm. Cu 37: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 7,38 gam. B. Tng 2,70 gam. C. Tng 7,92 gam. D. Gim 7,74 gam. Cu 38: Tin hnh cc th nghim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO3)2. (2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (3) Sc kh H2S vo dung dch FeCl2. (4) Sc kh NH3 ti d vo dung dch AlCl3. (5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (6) Sc kh etilen vo dung dch KMnO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 6. B. 3. C. 5. D. 4. Cu 39: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 17,5. B. 14,5. C. 15,5. D. 16,5. Cu 40: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,72. B. 0,24. C. 0,48. D. 0,96.
_________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta A. Fe(OH)3. B. Fe(OH)2 v Cu(OH)2. C. Fe(OH)2, Cu(OH)2 v Zn(OH)2. D. Fe(OH)3 v Zn(OH)2. 2+ 3+ Cu 42: Cu hnh electron ca ion Cu v Cr ln lt l A. [Ar]3d9 v [Ar]3d14s2. B. [Ar]3d74s2 v [Ar]3d3. C. [Ar]3d9 v [Ar]3d3. D. [Ar]3d74s2 v [Ar]3d14s2. Cu 43: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 3. C. 4. D. 1. Cu 44: Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc cu to ca X, Y ln lt l A. H-COOH v HOOC-COOH. B. CH3-COOH v HOOC-CH2-CH2-COOH. C. CH3-CH2-COOH v HOOC-COOH. D. CH3 -COOH v HOOC-CH2 -COOH. Cu 45: X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O. X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH. B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO. C. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3. D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH. Cu 46: Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch glyxin. B. Dung dch alanin. C. Dung dch lysin. D. Dung dch valin. Cu 47: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d), sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l A. 48,15%. B. 51,85%. C. 58,52%. D. 41,48%. Cu 48: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l A. 486. B. 297. C. 405. D. 324. Cu 49: Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi nng ca chng trong kh quyn vt qu tiu chun cho php? A. CH4 v H2O. B. CO2 v CH4. C. N2 v CO. D. CO2 v O2. Cu 50: Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th A. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion Cl . B. cc dng xy ra qu trnh oxi ho ion Na+ v cc m xy ra qu trnh kh ion Cl . C. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion Cl . D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ho ion Cl .
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch Na2CrO4 l: A. Dung dch chuyn t mu vng sang khng mu. B. Dung dch chuyn t mu da cam sang mu vng. C. Dung dch chuyn t mu vng sang mu da cam. D. Dung dch chuyn t khng mu sang mu da cam. Cu 52: Cho s phn ng: + HCN trng hp ng trng hp CH CH X; X polime Y; X + CH2=CH-CH=CH2 polime Z. Y v Z ln lt dng ch to vt liu polime no sau y? A. T olon v cao su buna-N. B. T nilon-6,6 v cao su cloropren. C. T nitron v cao su buna-S. D. T capron v cao su buna. Cu 53: Dung dch X gm CH3COOH 1M (K a = 1, 75.105 ) v HCl 0,001M. Gi tr pH ca dung dch X l A. 1,77. B. 2,33. C. 2,43. D. 2,55. Cu 54: Cho dy chuyn ho sau: KOH/C2 H5OH + C2 H 4 + Br2 , as Benzen X Y Z (trong X, Y, Z l sn phm chnh). t l mol1:1 xt, t o to Tn gi ca Y, Z ln lt l A. benzylbromua v toluen. B. 2-brom-1-phenylbenzen v stiren. C. 1-brom-2-phenyletan v stiren. D. 1-brom-1-phenyletan v stiren. Cu 55: Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu 10 c l A. 8,15 gam. B. 7,09 gam. C. 7,82 gam. D. 16,30 gam. Cu 56: Pht biu no sau y v anehit v xeton l sai? A. Axetanehit phn ng c vi nc brom. B. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. C. Axeton khng phn ng c vi nc brom. D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn. Cu 57: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l A. 4. B. 6. C. 2. D. 5. Cu 58: Cho cc phn ng sau: Fe + 2Fe(NO3)3 3Fe(NO3)2 AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi l: A. Fe2+, Ag+, Fe3+. B. Ag+, Fe2+, Fe3+. C. Fe2+, Fe3+, Ag+. D. Ag+, Fe3+, Fe2+. Cu 59: Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt vo khng kh dung dch no sau y? A. Dung dch NaOH. B. Dung dch NaCl. C. Dung dch NH3. D. Dung dch H2SO4 long. Cu 60: Ho tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l A. 0,96. B. 1,24. C. 3,2. D. 0,64.
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HT ----------
P N THI TUYN SINH I HC NM 2011 Mn: HO HC; Khi: A
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
273
A D A C A D C B B B B D C D B B A D A A C B C B D D D A A D D A A
318
D A D A D C B B C C C C B C D A A D C B C D B C D D C B C B D D B
482
D A A A B C B B C D D D D D A C C A D B C B B B C D D B C A C A A
641
A A A D B D A B B B C A D B C B B A D D C A C B A C A A C C C D B
758
D D B C D D D A B C C B C C B D B C B D A A C C C B A A D B B C D
925
C C B D D D A C C D C C C A B B A B A A B C A A C D B D C A A B B
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
273
C D B A D D A B C B D C C B C B C C A B D C B A C C A
318
A D A C A D A B A B A D D B A A D A B C B C B A C A B
482
C B C A B C C A C B A A D D B D A A A D C D C B D B B
641
D C D B B A B C D B C D C D D B B C D A A D A A C C D
758
B A B D B A D B A A C B D C D A B A D D C A A A C A C
925
B B D B B D C D B A D C D B C B A D D C A A D C A D A
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dung dch H2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh iu ch t 75%) l A. 300 gam. B. 600 gam. C. 500 gam. D. 400 gam. Cu 2: Thc hin cc th nghim sau: (I) Sc kh SO2 vo dung dch KMnO4. (II) Sc kh SO2 vo dung dch H2S. (III) Sc hn hp kh NO2 v O2 vo nc. (IV) Cho MnO2 vo dung dch HCl c, nng. (V) Cho Fe2O3 vo dung dch H2SO4 c, nng. (VI) Cho SiO2 vo dung dch HF. S th nghim c phn ng oxi ho - kh xy ra l A. 6. B. 5. C. 4. D. 3. Cu 3: Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht vi lng d dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l A. kali v bari. B. liti v beri. C. natri v magie. D. kali v canxi. Cu 4: Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (1), (2), (4). B. (2), (3), (4). C. (1), (2), (3). D. (1), (3), (4). Cu 5: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v C2H5COOH. B. HCOOH v CH3COOH. C. C2H5COOH v C3H7COOH. D. CH3COOH v C2H5COOH. Cu 6: Pht biu no sau y ng? A. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit nng chy gim dn. B. Kim loi xesi c dng ch to t bo quang in. C. Kim loi magie c kiu mng tinh th lp phng tm din. D. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng. Cu 7: Cho s chuyn ho:
3 2 2 C 3 H 6 X Y Z T E (Este a chc).
dung dch Br
NaOH
CuO,t o
O ,xt
CH OH,t o ,xt
Tn gi ca Y l A. propan-1,2-iol.
B. propan-1,3-iol.
C. glixerol.
D. propan-2-ol.
Cu 8: Cho s chuyn ho:

+ NaOH d, t Y + HCl Z. 2 Triolein X Tn ca Z l A. axit oleic. B. axit linoleic. C. axit stearic. D. axit panmitic. Cu 9: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l A. 0,585. B. 0,620. C. 0,205. D. 0,328. Cu 10: Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha 0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l A. 12,80. B. 12,00. C. 6,40. D. 16,53. Cu 11: Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc dng c vi c 4 dung dch trn l A. NH3. B. KOH. C. NaNO3. D. BaCl2. Cu 12: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. Cu 13: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 10,56. B. 7,20. C. 8,88. D. 6,66. Cu 14: Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l A. C3H9N. B. C3H7Cl. C. C3H8O. D. C3H8. Cu 15: Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2 (k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l: A. (1), (3), (6). B. (2), (5), (6). C. (2), (3), (4). D. (1), (4), (5). + H d (Ni, to )
o
Cu 16: Cho cn bng: 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit th t khi ca hn hp kh so vi H2 gim i. Pht biu ng khi ni v cn bng ny l: A. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . B. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit . C. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit . D. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . Cu 17: C cc pht biu sau: (1) Lu hunh, photpho u bc chy khi tip xc vi CrO3. (2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5. (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. Cc pht biu ng l: A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (4). D. (1), (2), (4). Cu 18: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l A. 1. B. 2. C. 4. D. 3. Cu 19: Mt phn t saccaroz c A. mt gc -glucoz v mt gc -fructoz. B. mt gc -glucoz v mt gc -fructoz. C. hai gc -glucoz. D. mt gc -glucoz v mt gc -fructoz.
Cu 20: Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l A. 22,80. B. 34,20. C. 27,36. D. 18,24. Cu 21: Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung dch Y, tng khi lng cc mui c to ra l A. 13,70 gam. B. 12,78 gam. C. 18,46 gam. D. 14,62 gam. Cu 22: Hn hp kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X mt thi gian trong bnh kn (c bt Fe lm xc tc), thu c hn hp kh Y c t khi so vi He bng 2. Hiu sut ca phn ng tng hp NH3 l A. 25%. B. 50%. C. 36%. D. 40%. Cu 23: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l A. 5. B. 2. C. 3. D. 4. Cu 24: Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng ng l A. 0,08 v 4,8. B. 0,04 v 4,8. C. 0,14 v 2,4. D. 0,07 v 3,2. Cu 25: Pht biu ng l: A. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz. B. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit. C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m. D. Axit nucleic l polieste ca axit photphoric v glucoz. Cu 26: Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam kt ta. Gi tr ca m l A. 17,71. B. 16,10. C. 32,20. D. 24,15. Cu 27: t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l A. 5,42. B. 5,72. C. 4,72. D. 7,42. Cu 28: Pht biu khng ng l: A. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong cc hp cht. B. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung photphorit, ct v than cc 1200oC trong l in. C. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon. D. Hiro sunfua b oxi ho bi nc clo nhit thng. Cu 29: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,70. B. 0,50. C. 0,65. D. 0,55. + 2+ Cu 30: Cho dung dch X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl; 0,006 mol HCO3 v 0,001 mol NO3. loi b ht Ca2+ trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l A. 0,180. B. 0,120. C. 0,444. D. 0,222. Cu 31: Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tc dng c vi dung dch NaOH long nhit thng l A. 4. B. 5. C. 3. D. 6.
26 55 Cu 32: Nhn nh no sau y ng khi ni v 3 nguyn t: 26 13 X, 26 Y, 12 Z? A. X v Z c cng s khi. B. X, Z l 2 ng v ca cng mt nguyn t ho hc. C. X, Y thuc cng mt nguyn t ho hc. D. X v Y c cng s ntron. Cu 33: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en. Cu 34: Hn hp kh no sau y khng tn ti nhit thng? A. CO v O2. B. Cl2 v O2. C. H2S v N2. D. H2 v F2. Cu 35: Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th A. bn knh nguyn t tng, m in gim. B. bn knh nguyn t v m in u tng. C. bn knh nguyn t gim, m in tng. D. bn knh nguyn t v m in u gim.
Cu 36: Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO 2 4 v x mol OH . Dung dch Y c cha
+ ClO 4 , NO 3 v y mol H ; tng s mol ClO 4 v NO 3 l 0,04. Trn X v Y c 100 ml dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l A. 1. B. 12. C. 13. D. 2. Cu 37: Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. B. Phn ng cc dng u l s oxi ho Cl. C. u sinh ra Cu cc m. D. Phn ng xy ra lun km theo s pht sinh dng in. Cu 38: Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol l: A. CH3OH, C2H5CH2OH. B. CH3OH, C2H5OH. C. C2H5OH, C3H7CH2OH. D. C2H5OH, C2H5CH2OH. Cu 39: Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng Fe trn nhng khi b ho tan l A. 2x. B. 3x. C. 2y. D. y. Cu 40: C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 6. B. 9. C. 4. D. 3.
_________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 7 v 1,0. B. 8 v 1,5. C. 8 v 1,0. D. 7 v 1,5. Cu 42: in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l A. kh Cl2 v H2. B. kh Cl2 v O2. C. ch c kh Cl2. D. kh H2 v O2.
Cu 43: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l A. 9,5. B. 10,9. C. 14,3. D. 10,2. Cu 44: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 90%. B. 10%. C. 80%. D. 20%. Cu 45: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l A. 0,020. B. 0,030. C. 0,015. D. 0,010. Cu 46: Cht c dng ty trng giy v bt giy trong cng nghip l A. N2O. B. CO2. C. SO2. D. NO2. Cu 47: Cc cht va tc dng c vi dung dch HCl va tc dng c vi dung dch AgNO3 l: A. MgO, Na, Ba. B. Zn, Ni, Sn. C. Zn, Cu, Fe. D. CuO, Al, Mg. Cu 48: Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l A. axit propanoic. B. axit etanoic. C. axit metanoic. D. axit butanoic. Cu 49: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l A. 3/14. B. 4/7. C. 1/7. D. 3/7. Cu 50: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C3H8. B. C2H6. C. C3H4. D. C3H6. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Xt cn bng: N2O4 (k) 2NO2 (k) 25oC. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2 A. tng 9 ln. B. tng 3 ln. C. tng 4,5 ln. D. gim 3 ln. Cu 52: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylenterephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng l: A. (1), (3), (6). B. (1), (2), (3). C. (1), (3), (5). D. (3), (4), (5). Cu 53: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l A. C3H7COOH v C4H9COOH. B. CH3COOH v C2H5COOH. C. C2H5COOH v C3H7COOH. D. HCOOH v CH3COOH. Cu 54: in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l A. 1,344 lt. B. 2,240 lt. C. 1,792 lt. D. 2,912 lt. Cu 55: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng l A. 2,016 lt. B. 1,008 lt. C. 0,672 lt. D. 1,344 lt.
Cu 56: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH3-CH2-CH2-NH2. B. CH2=CH-CH2-NH2. C. CH3-CH2-NH-CH3. D. CH2=CH-NH-CH3. Cu 57: Trong s cc ngun nng lng: (1) thy in, (2) gi, (3) mt tri, (4) ho thch; nhng ngun nng lng sch l: A. (1), (2), (3). B. (1), (3), (4). C. (1), (2), (4). D. (2), (3), (4). Cu 58: Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l A. 2-metylbutan-3-on. B. metyl isopropyl xeton. C. 3-metylbutan-2-ol. D. 3-metylbutan-2-on. Cu 59: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l A. CH3-CH2-CH(OH)-CH3. B. CH3-CH2-CH2-OH. C. CH3-CH2-CH2-CH2-OH. D. CH3-CH(OH)-CH3. Cu 60: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn X (gi s phn ng xy ra hon ton). Phn trm khi lng ca Cu trong X l A. 85,88%. B. 14,12%. C. 87,63%. D. 12,37%.
----------------------------------------------------------
HT ----------
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
253
D C C B B B B C D C C B C A D D A D D D C A C A B B C A C D B A C
419
A D A B C C C B C B A A D D C D C C B A B B D C D A B B B A A C B
596
A A D D D B C D C D A A A C A C B D A B D D A A B B C B A C B A B
684
B D A C A B A A C D C C C C A A C C A D A D B D C C A C A D B B A
728
C D C C C A B A B B D B C C D B C D C A A A C C D A A D D B B A B
815
A B B D A B A A C B B C B D D A D A C D C C D A C D A C D A D C A
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
253
D C A A A D A A B B A D C B B D A B D B C B A A D C D
419
C A B A A A D A D C B C A C D B C D D D B D C D A D B
596
A D C C D C C B C C D D B A C D A B C A C B D B D B B
684
B B D D A B B D A A B B C C C B D D B D D D D C B B A
728
D B C A B D D C B B B C C A C D A A B A D D A D D A B
815
B A C C D B D C B B A C B B D B C A D D C B A D C B A
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
THI TUYN SINH I HC NM 2009 Mn thi: HO HC; Khi: A Thi gian lm bi: 90 pht, khng k thi gian pht . M thi 175
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l: A. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. D. Ba, Ag, Au. Cu 2: Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 20,125. B. 22,540. C. 12,375. D. 17,710. Cu 3: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 46,15%. B. 35,00%. C. 53,85%. D. 65,00%. Cu 4: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l A. 1,182. B. 3,940. C. 1,970. D. 2,364. Cu 5: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 3. B. 2. C. 1. D. 4. Cu 6: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. Cu 7: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l B. MnO2. C. CaOCl2. D. K2Cr2O7. A. KMnO4. Cu 8: Dy gm cc cht u tc dng c vi dung dch HCl long l: A. KNO3, CaCO3, Fe(OH)3. B. FeS, BaSO4, KOH. C. AgNO3, (NH4)2CO3, CuS. D. Mg(HCO3)2, HCOONa, CuO. Cu 9: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l A. NO v Mg. B. NO2 v Al. C. N2O v Al. D. N2O v Fe. Cu 10: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. D. C2H4(OH)2 v C3H6(OH)2. C. C2H4(OH)2 v C4H8(OH)2. Cu 11: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. CH3COOCH3 v CH3COOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5.
Cu 12: Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns2np4. Trong hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong oxit cao nht l A. 50,00%. B. 27,27%. C. 60,00%. D. 40,00%. Cu 13: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. Cu 14: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 15: Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Sau khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 13x - 9y. B. 46x - 18y. C. 45x - 18y. D. 23x - 9y. Cu 16: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. Cu 17: Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng A. 4. B. 2. C. 1. D. 3. Cu 18: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 4. B. 8. C. 5. D. 7. Cu 19: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: V V V V A. m = 2a . B. m = 2a . C. m = a + . D. m = a . 22,4 11,2 5,6 5,6 Cu 20: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 21: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l A. 101,68 gam. B. 88,20 gam. C. 101,48 gam. D. 97,80 gam. Cu 22: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 2,24. D. 1,12. Cu 23: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. Cu 24: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v IV. B. I, II v III. C. I, III v IV. D. II, III v IV. Cu 25: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 1,92. B. 3,20. C. 0,64. D. 3,84.
Cu 26: Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu2+, Cl-. S cht v ion c c tnh oxi ha v tnh kh l A. 7. B. 5. C. 4. D. 6. Cu 27: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. CH3COOH, C2H2, C2H4. B. C2H5OH, C2H4, C2H2. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH. Cu 28: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 20,0. B. 30,0. C. 13,5. D. 15,0. Cu 29: Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. Cu 30: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. Cu 31: Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l A. Fe(NO3)3 v Zn(NO3)2. B. Zn(NO3)2 v Fe(NO3)2. C. AgNO3 v Zn(NO3)2. D. Fe(NO3)2 v AgNO3. Cu 32: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 38,34. B. 34,08. C. 106,38. D. 97,98. Cu 33: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l B. C2H5OH v CH3OH. A. C2H5OH v CH2=CH-CH2-OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. Cu 34: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. Cu 35: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 360. B. 240. C. 400. D. 120. 2+ 2 2 6 2 6 6 Cu 36: Cu hnh electron ca ion X l 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc A. chu k 4, nhm VIIIA. B. chu k 4, nhm IIA. C. chu k 3, nhm VIB. D. chu k 4, nhm VIIIB. Cu 37: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l B. CnH2n+1CHO (n 0). A. CnH2n(CHO)2 (n 0). C. CnH2n-1CHO (n 2). D. CnH2n-3CHO (n 2).
Cu 38: Trng hp no sau y khng xy ra phn ng ho hc? A. Sc kh Cl2 vo dung dch FeCl2. B. Sc kh H2S vo dung dch CuCl2. C. Sc kh H2S vo dung dch FeCl2. D. Cho Fe vo dung dch H2SO4 long, ngui. Cu 39: X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 oC, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 4,05. B. 8,10. C. 18,00. D. 16,20. Cu 40: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa. C. CH2=CH-COONa, HCOONa v CHC-COONa. D. CH3-COONa, HCOONa v CH3-CH=CH-COONa. _________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l A. 4. B. 2. C. 5. D. 3. Cu 42: Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l A. 2,80 lt. B. 1,68 lt. C. 4,48 lt. D. 3,92 lt. Cu 43: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. Cu 44: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-COOH. B. HCOOH, HOOC-CH2-COOH. C. HCOOH, C2H5COOH. D. HCOOH, CH3COOH. Cu 45: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 3. B. 4. C. 5. D. 2. Cu 46: Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. xeton. C. amin. D. anehit. Cu 47: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn? A. 1,8. B. 1,5. C. 1,2. D. 2,0. Cu 48: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6.
Cu 49: Pht biu no sau y l ng? A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3-) v ion amoni (NH4+). B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3. C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK. D. Phn ur c cng thc l (NH4)2CO3. ZZ X N2O4 (k). Cu 50: Cho cn bng sau trong bnh kn: 2NO2 (k) YZZ (mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c A. H > 0, phn ng ta nhit. B. H < 0, phn ng ta nhit. C. H > 0, phn ng thu nhit. D. H < 0, phn ng thu nhit. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l A. 95,00%. B. 25,31%. C. 74,69%. D. 64,68%. Cu 52: Cho dy chuyn ho sau: +X + NaOH (d) Phenol Phenyl axetat Y (hp cht thm) to Hai cht X, Y trong s trn ln lt l: A. axit axetic, phenol. B. anhirit axetic, phenol. C. anhirit axetic, natri phenolat. D. axit axetic, natri phenolat. Cu 53: Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l 0,3M v 0,7M. Sau khi phn ng tng hp NH3 t trng thi cn bng t oC, H2 chim 50% th tch hn hp thu c. Hng s cn bng KC t oC ca phn ng c gi tr l A. 2,500. B. 3,125. C. 0,609. D. 0,500. Cu 54: Pht biu no sau y l ng? A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. C. Benzen lm mt mu nc brom nhit thng. D. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. Cu 55: Dy gm cc dung dch u tham gia phn ng trng bc l: A. Glucoz, mantoz, axit fomic, anehit axetic. B. Fructoz, mantoz, glixerol, anehit axetic. C. Glucoz, glixerol, mantoz, axit fomic. D. Glucoz, fructoz, mantoz, saccaroz. Cu 56: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. HCOOC(CH3)=CHCH3. B. CH3COOC(CH3)=CH2. C. HCOOCH2CH=CHCH3. D. HCOOCH=CHCH2CH3. Cu 57: Cho s chuyn ha:
KCN 3 X CH3CH2Cl Y to
H O+
Cng thc cu to ca X, Y ln lt l: A. CH3CH2NH2, CH3CH2COOH. B. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4. C. CH3CH2CN, CH3CH2CHO. Cu 58: Cho sut in ng chun ca cc pin in ho: Zn-Cu l 1,1V; Cu-Ag l 0,46V. Bit th in cc chun E o Ag+ Ag = +0,8V. Th in cc chun E o Zn 2+ Zn v E o Cu 2+ Cu c gi tr ln lt l A. -0,76V v +0,34V. B. -1,46V v -0,34V. C. +1,56V v +0,64V. D. -1,56V v +0,64V.
Cu 59: Dy gm cc cht v thuc u c th gy nghin cho con ngi l A. cocain, seduxen, cafein. B. heroin, seduxen, erythromixin. C. ampixilin, erythromixin, cafein. D. penixilin, paradol, cocain. Cu 60: Trng hp xy ra phn ng l A. Cu + Pb(NO3)2 (long) B. Cu + HCl (long) C. Cu + H2SO4 (long) D. Cu + HCl (long) + O2
----------------------------------------------------------
HT ----------
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32.
175
A A A C C A D D C C A D D A B D C B D C C D B C A B B D D D B C
327
C A C D A B A C B C D D D D D A A D D B B B D A C A A C C B C D
M thi 438 596

A C C C C D D B C D C A C B D B C B D B D B B C A A D D D A B B B C D D A D B D B A D D A B B D D C C C C C A C B A B B A A B B
742
B A A C D C D A B C A D B C A A B D A C C B C A A A C C D B B C
825
C B D C B C D D B A C D A B A D C C A B A B B A C A A A C D C D
Cu s 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
175
D B A D C C B A D D B A B A C B C B C C B B A A B A A D
327
A C B B C A C B D A A C C B D C C D A B A B A D B D B B
M thi 438 596

D D A C A B C A B A B D A B A A A B C C B D D A A C C D D C A A D C A C D A C D B C B D C A C A C B A A D B B D
742
B C D A B D B C C D D D A D B A A D D B D C B B D B C A
825
B C B A B D B A B D A D D D C D A B D C A C A C B B D C
B GIO DC V O TO
CHNH THC
( thi c 05 trang)
THI TUYN SINH I HC, CAO NG NM 2008 Mn thi: HO HC, khi A Thi gian lm bi: 90 pht. M thi 263
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137. PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44): Cu 1: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc. Cu 2: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 8,8. C. 7,4. D. 9,2. Cu 3: T hai mui X v Y thc hin cc phn ng sau:
t X X1 + CO 2 o
X1 + H 2 O X 2
X2 + Y X + Y1 + H 2 O
X 2 + 2Y X + Y2 + 2H 2 O
Hai mui X, Y tng ng l A. CaCO3, NaHSO4. B. BaCO3, Na2CO3. C. CaCO3, NaHCO3. D. MgCO3, NaHCO3. Cu 4: ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,23. B. 0,18. C. 0,08. D. 0,16. Cu 5: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s kh ion Cl-. B. s oxi ho ion Cl-. C. s oxi ho ion Na+. D. s kh ion Na+. Cu 6: S ng phn este ng vi cng thc phn t C4H8O2 l A. 5. B. 2. C. 4. D. 6. Cu 7: Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 57 ml. B. 50 ml. C. 75 ml. D. 90 ml. Cu 8: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l: A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. CH3COOH, C2H6, CH3CHO, C2H5OH. C. C2H6, C2H5OH, CH3CHO, CH3COOH. D. C2H6, CH3CHO, C2H5OH, CH3COOH. Cu 9: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5.
C. 4. D. 3.
Cu 10: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. HCHO. C. C4H9CHO. D. C2H5CHO. Cu 11: Pht biu ng l: A. Tnh axit ca phenol yu hn ca ru (ancol). B. Cao su thin nhin l sn phm trng hp ca isopren. C. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp. D. Tnh baz ca anilin mnh hn ca amoniac. Cu 12: Trong phng th nghim, ngi ta iu ch oxi bng cch A. in phn nc. B. nhit phn Cu(NO3)2. C. nhit phn KClO3 c xc tc MnO2. D. chng ct phn on khng kh lng. Cu 13: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 113 v 152. B. 121 v 114. C. 121 v 152. D. 113 v 114. Cu 14: Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l A. 0,45. B. 0,35. C. 0,25. D. 0,05. Cu 15: Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-. B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). Cu 16: Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. saccaroz. B. tinh bt. C. mantoz. D. xenluloz. Cu 17: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 4. B. 5. C. 7. D. 6. Cu 18: Pht biu ng l: A. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol). C. Khi thy phn cht bo lun thu c C2H4(OH)2. D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. Cu 19: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 2. B. 3. C. 5. D. 4. Cu 20: Cho cc phn ng sau: 4HCl + MnO2 MnCl2 + Cl2 + 2H2O. 2HCl + Fe FeCl2 + H2. 14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O. 6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 2. B. 1. C. 4. D. 3. Cu 21: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 3. B. 4. C. 2. D. 1.
Cu 22: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,448. B. 0,112. C. 0,224. D. 0,560. Cu 23: Cho s chuyn ho sau: C3H4O2 + NaOH X + Y X + H2SO4 long Z + T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l: A. HCHO, CH3CHO. B. HCHO, HCOOH. C. CH3CHO, HCOOH. D. HCOONa, CH3CHO. Cu 24: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l A. 0,55. B. 0,60. C. 0,40. D. 0,45. Cu 25: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,04 gam. B. 1,32 gam. C. 1,64 gam. D. 1,20 gam. Cu 26: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 8,64 gam. B. 6,84 gam. C. 4,90 gam. D. 6,80 gam. Cu 27: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l A. 19,70. B. 17,73. C. 9,85. D. 11,82. Cu 28: Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 4. B. 3. C. 2. D. 1. Cu 29: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 38,72. B. 35,50. C. 49,09. D. 34,36. Cu 30: Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l A. 10,8. B. 5,4. C. 7,8. D. 43,2. Cu 31: Hp cht trong phn t c lin kt ion l A. NH4Cl. B. NH3. C. HCl. D. H2O.
ZZ X 2SO3 (k); phn ng thun l phn ng to Cu 32: Cho cn bng ho hc: 2SO2 (k) + O2 (k) YZZ nhit. Pht biu ng l: A. Cn bng chuyn dch theo chiu thun khi tng nhit . B. Cn bng chuyn dch theo chiu nghch khi gim nng O2. C. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng. D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3. Cu 33: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 2. B. 4. C. 3. D. 5. Cu 34: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 20,40 gam. B. 18,60 gam. C. 18,96 gam. D. 16,80 gam.
Cu 35: Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri sang phi l A. F, O, Li, Na. B. F, Na, O, Li. C. F, Li, O, Na. D. Li, Na, O, F. Cu 36: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag) A. Fe, Cu. B. Cu, Fe. C. Ag, Mg. D. Mg, Ag. Cu 37: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. ho tan Cu(OH)2. B. trng ngng. C. trng gng. D. thy phn. Cu 38: Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. B. Cht Y tan v hn trong nc. C. Cht X thuc loi este no, n chc. D. un Z vi dung dch H2SO4 c 170oC thu c anken. Cu 39: Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l A. amophot. B. ure. C. natri nitrat. D. amoni nitrat. Cu 40: Cho cc phn ng sau:
t (1) Cu(NO3 ) 2 C, Pt (3) NH 3 + O 2 850
t (5) NH 4 Cl o
t (2) NH 4 NO 2 t (4) NH 3 + Cl 2 o
t (6) NH 3 + CuO
Cc phn ng u to kh N2 l: A. (2), (4), (6). B. (3), (5), (6). C. (1), (3), (4). D. (1), (2), (5). Cu 41: Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,746. B. 0,448. C. 1,792. D. 0,672. Cu 42: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l A. 3-metylbuten-1 (hay 3-metylbut-1-en). B. 2-metylbuten-2 (hay 2-metylbut-2-en). C. 3-metylbuten-2 (hay 3-metylbut-2-en). D. 2-metylbuten-3 (hay 2-metylbut-3-en). Cu 43: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 358,4. B. 448,0. C. 286,7. D. 224,0. Cu 44: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag) A. 59,4. B. 64,8. C. 32,4. D. 54,0.
PHN RING __________ Th sinh ch c lm 1 trong 2 phn: phn I hoc phn II Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50):
__________
Cu 45: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l A. 22,75 B. 21,40. C. 29,40. D. 29,43. Cu 46: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 47: Trong cc loi qung st, qung c hm lng st cao nht l A. hematit nu. B. manhetit. C. xierit. D. hematit . Cu 48: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 2. B. 3. C. 1. D. 4. Cu 49: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A. 2. B. 3. C. 5. D. 4. 2+ Cu 50: Bit rng ion Pb trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. c Pb v Sn u b n mn in ho. B. c Pb v Sn u khng b n mn in ho. C. ch c Pb b n mn in ho. D. ch c Sn b n mn in ho. Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56): Cu 51: oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v KOH tng ng l A. 0,015 mol v 0,04 mol. B. 0,015 mol v 0,08 mol. C. 0,03 mol v 0,08 mol. D. 0,03 mol v 0,04 mol. Cu 52: Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi lng A. c hai in cc Zn v Cu u tng. B. in cc Zn gim cn khi lng in cc Cu tng. C. in cc Zn tng cn khi lng in cc Cu gim. D. c hai in cc Zn v Cu u gim. Cu 53: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 2,25 gam. B. 1,80 gam. C. 1,82 gam. D. 1,44 gam. Cu 54: S ng phn xeton ng vi cng thc phn t C5H10O l A. 5. B. 6. C. 3. D. 4. Cu 55: Cho s chuyn ho qung ng thnh ng:
X,t 2 X 2 Y + CuFeS 2 Cu. +O ,t o +O ,t o o
Hai cht X, Y ln lt l: A. Cu2O, CuO. B. CuS, CuO. Cu 56: Tc nhn ch yu gy ma axit l A. CO v CH4. B. CH4 v NH3.
-----------------------------------------------
C. Cu2S, CuO. C. SO2 v NO2.
D. Cu2S, Cu2O. D. CO v CO2.
----------------------------------------------------- HT ----------
P N THI TUYN SINH I HC, CAO NG NM 2008 Mn: HA HC, khi A
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32.
263
B A C C D C C D D A B C C A D C B D A A B A C B B D C C A B A B
329
B D D C D C C A C D B A B C B B A A D C D D C A C B A A B D B D
M thi 518 605

D B A C A B C D A A D B A C C C C D A D B C A D D B D C A B B A D D B D D D C B A C A D D D C D B C C C A A B A D A C A A C A D
794
A D A C B D A A D B C C C C A C A B C D B B C A B C B A D D C A
931
B A D D C C C C D D B B A A A A D B D D D A D A B C A D D B B C
Cu s 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56.
263
B C A A D D D A D B B A A D B C D D B B A C D C
329
D A C D D C B B A C D C A C A B B D C B A A A B
M thi 518 605

B C B D A B B B C A D B D D A D C B A D A C C C B A A C B C C D B A B B D B B C A D B A B C B C
794
B B D C B C D D B A B D D A D B D C A D A B A C
931
C C B B D C D A B A D B C B A B A C C C A B A C
B GIO DC V O TO
CHNH THC
( thi c 6 trang)
THI TUYN SINH I HC NM 2013 Mn: HA HC; Khi B Thi gian lm bi: 90 pht, khng k thi gian pht M thi 279
Cho bit nguyn t khi ca cc nguyn t: H = 1; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Cs = 133; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Trong cc polime: t tm, si bng, t visco, t nilon-6, t nitron, nhng polime c ngun gc t xenluloz l A. si bng, t visco v t nilon-6. B. t tm, si bng v t nitron. C. si bng v t visco. D. t visco v t nilon-6. Cu 2: Pht biu no sau y l ng? A. Thnh phn chnh ca supephotphat kp gm hai mui Ca(H2PO4)2 v CaSO4. B. Ur c cng thc l (NH2)2CO. C. Supephotphat n ch c Ca(H2PO4)2. D. Phn ln cung cp nit cho cy trng. Cu 3: Hn hp X gm hai axit cacboxylic n chc, mch h, k tip nhau trong cng dy ng ng. t chy hon ton 4,02 gam X, thu c 2,34 gam H2O. Mt khc 10,05 gam X phn ng va vi dung dch NaOH, thu c 12,8 gam mui. Cng thc ca hai axit l A. CH3COOH v C2H5COOH. B. C2H5COOH v C3H7COOH. D. C2H3COOH v C3H5COOH. C. C3H5COOH v C4H7COOH. Cu 4: Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d), thu c dung dch X. Trong cc cht: NaOH, Cu, Fe(NO3)2, KMnO4, BaCl2, Cl2 v Al, s cht c kh nng phn ng c vi dung dch X l A. 4. B. 6. C. 5. D. 7. Cu 5: Cho cc pht biu sau: (a) Trong cc phn ng ha hc, flo ch th hin tnh oxi ha. (b) Axit flohiric l axit yu. (c) Dung dch NaF long c dng lm thuc chng su rng. (d) Trong hp cht, cc halogen (F, Cl, Br, I) u c s oxi ha: -1, +1, +3, +5 v +7. (e) Tnh kh ca cc ion halogenua tng dn theo th t: F, Cl, Br, I. Trong cc pht biu trn, s pht biu ng l A. 3. B. 5. C. 2. D. 4. Cu 6: Cho s phn ng: C2H2 X CH3COOH. Trong s trn mi mi tn l mt phn ng, X l cht no sau y? A. CH3COONa. B. HCOOCH3. C. CH3CHO. D. C2H5OH. Cu 7: Ha tan hon ton 1,28 gam Cu vo 12,6 gam dung dch HNO3 60% thu c dung dch X (khng c ion NH + ). Cho X tc dng hon ton vi 105 ml dung dch KOH 1M, sau lc b kt ta
4
c dung dch Y. C cn Y c cht rn Z. Nung Z n khi lng khng i, thu c 8,78 gam cht rn. Nng phn trm ca Cu(NO3)2 trong X l A. 28,66%. B. 29,89%. C. 30,08%. D. 27,09%.
Cu 8: Cho s phn ng: Al2(SO4)3 X Y Al. Trong s trn, mi mi tn l mt phn ng, cc cht X, Y ln lt l nhng cht no sau y? B. Al(OH)3 v NaAlO2. A. NaAlO2 v Al(OH)3. C. Al2O3 v Al(OH)3. D. Al(OH)3 v Al2O3. Cu 9: Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton hn hp gm X v Y ch to ra mt amino axit duy nht c cng thc H2NCnH2nCOOH. t chy 0,05 mol Y trong oxi d, thu c N2 v 36,3 gam hn hp gm CO2, H2O. t chy 0,01 mol X trong oxi d, cho sn phm chy vo dung dch Ba(OH)2 d, thu c m gam kt ta. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 11,82. B. 17,73. C. 23,64. D. 29,55. Cu 10: Hn hp X gm hiro, propen, axit acrylic, ancol anlylic (C3H5OH). t chy hon ton 0,75 mol X, thu c 30,24 lt kh CO2 (ktc). un nng X vi bt Ni mt thi gian, thu c hn hp Y. T khi hi ca Y so vi X bng 1,25. Cho 0,1 mol Y phn ng va vi V lt dung dch Br2 0,1M. Gi tr ca V l A. 0,3. B. 0,6. C. 0,4. D. 0,5. Cu 11: Pht biu no sau y khng ng? A. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni. B. Cc cht bo thng khng tan trong nc v nh hn nc. C. Cht bo b thy phn khi un nng trong dung dch kim. D. Cht bo l trieste ca etylen glicol vi cc axit bo. Cu 12: Trong cc cht: stiren, axit acrylic, axit axetic, vinylaxetilen v butan, s cht c kh nng tham gia phn ng cng hiro (xc tc Ni, un nng) l C. 5. D. 3. A. 4. B. 2. Cu 13: Cho gi tr m in ca cc nguyn t: F (3,98); O (3,44); C (2,55); H (2,20); Na (0,93). Hp cht no sau y l hp cht ion? A. NaF. B. CO2. C. CH4. D. H2O. Cu 14: Cho 200 ml dung dch Ba(OH)2 0,1M vo 300 ml dung dch NaHCO3 0,1M, thu c dung dch X v kt ta Y. Cho t t dung dch HCl 0,25M vo X n khi bt u c kh sinh ra th ht V ml. Bit cc phn ng u xy ra hon ton. Gi tr ca V l A. 80. B. 40. C. 160. D. 60. Cu 15: Ha tan hon ton x mol Fe vo dung dch cha y mol FeCl3 v z mol HCl, thu c dung dch ch cha mt cht tan duy nht. Biu thc lin h gia x, y v z l A. 2x = y + 2z. B. 2x = y + z. C. x = y 2z. D. y = 2x. Cu 16: Tn gi ca anken (sn phm chnh) thu c khi un nng ancol c cng thc (CH3)2CHCH(OH)CH3 vi dung dch H2SO4 c l A. 3-metylbut-2-en. B. 2-metylbut-1-en. C. 2-metylbut-2-en. D. 3-metylbut-1-en. Cu 17: Hai cht hu c X v Y, thnh phn nguyn t u gm C, H, O, c cng s nguyn t cacbon (MX < MY). Khi t chy hon ton mi cht trong oxi d u thu c s mol H2O bng s mol CO2. Cho 0,1 mol hn hp gm X v Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 28,08 gam Ag. Phn trm khi lng ca X trong hn hp ban u l A. 39,66%. B. 60,34%. C. 21,84%. D. 78,16%. Cu 18: in phn nng chy Al2O3 vi cc in cc bng than ch, thu c m kilogam Al catot v 89,6 m3 (ktc) hn hp kh X anot. T khi ca X so vi H2 bng 16,7. Cho 1,12 lt X (ktc) phn ng vi dung dch Ca(OH)2 d, thu c 1,5 gam kt ta. Bit cc phn ng xy ra hon ton. Gi tr ca m l A. 144,0. B. 104,4. C. 82,8. D. 115,2. Cu 19: Cho phng trnh ha hc ca phn ng: X + 2Y Z + T. thi im ban u, nng ca cht X l 0,01 mol/l. Sau 20 giy, nng ca cht X l 0,008 mol/l. Tc trung bnh ca phn ng tnh theo cht X trong khong thi gian trn l A. 4,0.104 mol/(l.s). B. 1,0.104 mol/(l.s). C. 7,5.104 mol/(l.s). D. 5,0.104 mol/(l.s).
Cu 20: S ng phn amin bc mt, cha vng benzen, c cng cng thc phn t C7H9N l A. 3. B. 2. C. 5. D. 4. Cu 21: Axit cacboxylic X hai chc (c phn trm khi lng ca oxi nh hn 70%), Y v Z l hai ancol ng ng k tip (MY < MZ). t chy hon ton 0,2 mol hn hp gm X, Y, Z cn va 8,96 lt kh O2 (ktc), thu c 7,84 lt kh CO2 (ktc) v 8,1 gam H2O. Phn trm khi lng ca Y trong hn hp trn l A. 15,9%. B. 29,9%. C. 29,6%. D. 12,6%. Cu 22: Th tch dung dch NaOH 0,25M cn cho vo 15 ml dung dch Al2(SO4)3 0,5M thu c lng kt ta ln nht l A. 210 ml. B. 60 ml. C. 90 ml. D. 180 ml. Cu 23: Ha tan hon ton hn hp gm 2,8 gam Fe v 1,6 gam Cu trong 500 ml dung dch hn hp HNO3 0,1M v HCl 0,4M, thu c kh NO (kh duy nht) v dung dch X. Cho X vo dung dch AgNO3 d, thu c m gam cht rn. Bit cc phn ng u xy ra hon ton, NO l sn phm kh duy nht ca N+5 trong cc phn ng. Gi tr ca m l A. 29,24. B. 30,05. C. 34,10. D. 28,70. Cu 24: Cho cc pht biu sau: (a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH. (b) Phn ng th brom vo vng benzen ca phenol (C6H5OH) d hn ca benzen. (c) Oxi ha khng hon ton etilen l phng php hin i sn xut anehit axetic. (d) Phenol (C6H5OH) tan t trong etanol. Trong cc pht biu trn, s pht biu ng l A. 4. B. 2. C. 3. D. 1. Cu 25: Hn hp X gm ancol metylic, etylen glicol. Cho m gam X phn ng hon ton vi Na d, thu c 2,24 lt kh H2 (ktc). t chy hon ton m gam X, thu c a gam CO2. Gi tr ca a l A. 2,2. B. 4,4. C. 8,8. D. 6,6. Cu 26: Mt loi nc cng khi un si th mt tnh cng. Trong loi nc cng ny c ha tan nhng hp cht no sau y? A. Ca(HCO3)2, Mg(HCO3)2. B. Ca(HCO3)2, MgCl2. C. CaSO4, MgCl2. D. Mg(HCO3)2, CaCl2. Cu 27: Amino axit X c phn t khi bng 75. Tn ca X l A. alanin. B. glyxin. C. valin. D. lysin. Cu 28: Cho 3,36 lt kh hirocacbon X (ktc) phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Cng thc phn t ca X l B. C3H4. C. C4H6. D. C2H2. A. C4H4. Cu 29: Hn hp X gm FeO, Fe2O3 v Fe3O4. Cho kh CO qua m gam X nung nng, sau mt thi gian thu c hn hp cht rn Y v hn hp kh Z. Cho ton b Z vo dung dch Ca(OH)2 d, n phn ng hon ton, thu c 4 gam kt ta. Mt khc, ha tan hon ton Y trong dung dch H2SO4 c, nng (d), thu c 1,008 lt kh SO2 (ktc, sn phm kh duy nht) v dung dch cha 18 gam mui. Gi tr ca m l A. 6,80. B. 7,12. C. 13,52. D. 5,68. Cu 30: Cacbohirat no sau y thuc loi isaccarit? A. Amiloz. B. Saccaroz. C. Glucoz. D. Xenluloz. Cu 31: Cho 0,76 gam hn hp X gm hai amin n chc, c s mol bng nhau, phn ng hon ton vi dung dch HCl d, thu c 1,49 gam mui. Khi lng ca amin c phn t khi nh hn trong 0,76 gam X l A. 0,58 gam. B. 0,31 gam. C. 0,45 gam. D. 0,38 gam. Cu 32: S proton v s ntron c trong mt nguyn t nhm ( 27 13 Al ) ln lt l A. 13 v 14. B. 13 v 15. C. 12 v 14. D. 13 v 13. Cu 33: Hp th hon ton 2,24 lt kh CO2 (ktc) vo 750 ml dung dch Ba(OH)2 0,2M, thu c m gam kt ta. Gi tr ca m l A. 29,55. B. 19,70. C. 9,85. D. 39,40.
Cu 34: Cho m gam mt oxit st phn ng va vi 0,75 mol H2SO4, thu c dung dch ch cha mt mui duy nht v 1,68 lt kh SO2 (ktc, sn phm kh duy nht ca S+6). Gi tr ca m l A. 24,0. B. 34,8. C. 10,8. D. 46,4. Cu 35: Khi ha tan hon ton m gam mi kim loi vo nc d, t kim loi no sau y thu c th tch kh H2 (cng iu kin nhit v p sut) l nh nht? A. K. B. Na. C. Li. D. Ca. Cu 36: Cho phn ng: FeO + HNO3 Fe(NO3)3 + NO + H2O. Trong phng trnh ca phn ng trn, khi h s ca FeO l 3 th h s ca HNO3 l A. 6. B. 8. C. 4. D. 10. Cu 37: Cht no sau y trong phn t ch c lin kt n? A. Metyl fomat. B. Axit axetic. C. Anehit axetic. D. Ancol etylic. Cu 38: Hn hp X gm hai kim loi kim v mt kim loi kim th. Ha tan hon ton 1,788 gam X vo nc, thu c dung dch Y v 537,6 ml kh H2 (ktc). Dung dch Z gm H2SO4 v HCl, trong s mol ca HCl gp hai ln s mol ca H2SO4. Trung ha dung dch Y bng dung dch Z to ra m gam hn hp mui. Gi tr ca m l A. 4,460. B. 4,656. C. 3,792. D. 2,790. Cu 39: Thy phn hon ton m1 gam este X mch h bng dung dch NaOH d, thu c m2 gam ancol Y (khng c kh nng phn ng vi Cu(OH)2) v 15 gam hn hp mui ca hai axit cacboxylic n chc. t chy hon ton m2 gam Y bng oxi d, thu c 0,3 mol CO2 v 0,4 mol H2O. Gi tr ca m1 l A. 14,6. B. 11,6. C. 10,6. D. 16,2. Cu 40: Dung dch X cha 0,12 mol Na+; x mol SO 2- ; 0,12 mol Cl v 0,05 mol NH + . Cho 300 ml
4
dung dch Ba(OH)2 0,1M vo X n khi cc phn ng xy ra hon ton, lc b kt ta, thu c dung dch Y. C cn Y, thu c m gam cht rn khan. Gi tr ca m l A. 7,190. B. 7,705. C. 7,875. D. 7,020. II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Amino axit X c cng thc H2NCxHy(COOH)2. Cho 0,1 mol X vo 0,2 lt dung dch H2SO4 0,5M, thu c dung dch Y. Cho Y phn ng va vi dung dch gm NaOH 1M v KOH 3M, thu c dung dch cha 36,7 gam mui. Phn trm khi lng ca nit trong X l A. 10,526%. B. 10,687%. C. 11,966%. D. 9,524%. Cu 42: Cho cc pht biu sau: (a) Hiro ha hon ton glucoz to ra axit gluconic. (b) iu kin thng, glucoz v saccaroz u l nhng cht rn, d tan trong nc. (c) Xenluloz trinitrat l nguyn liu sn xut t nhn to v ch to thuc sng khng khi. (d) Amilopectin trong tinh bt ch c cc lin kt -1,4-glicozit. (e) Sacaroz b ha en trong H2SO4 c. (f) Trong cng nghip dc phm, saccaroz c dng pha ch thuc. Trong cc pht biu trn, s pht biu ng l A. 2. B. 3. C. 5. D. 4. Cu 43: Thc hin cc th nghim sau: (a) Cho Al vo dung dch HCl. (b) Cho Al vo dung dch AgNO3. (c) Cho Na vo H2O. (d) Cho Ag vo dung dch H2SO4 long. Trong cc th nghim trn, s th nghim xy ra phn ng l A. 1. B. 2. C. 4. D. 3.
Cu 44: Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai mui? A. C6H5COOC6H5 (phenyl benzoat). B. CH3COO[CH2]2OOCCH2CH3. D. CH3COOC6H5 (phenyl axetat). C. CH3OOCCOOCH3. Cu 45: Cho phng trnh ha hc ca phn ng: 2Cr + 3Sn2+ 2Cr3+ + 3Sn. Nhn xt no sau y v phn ng trn l ng? A. Sn2+ l cht kh, Cr3+ l cht oxi ha. B. Cr l cht oxi ha, Sn2+ l cht kh. C. Cr l cht kh, Sn2+ l cht oxi ha. D. Cr3+ l cht kh, Sn2+ l cht oxi ha. Cu 46: Hirocacbon no sau y khi phn ng vi dung dch brom thu c 1,2-ibrombutan? A. But-1-en. B. Butan. C. Buta-1,3-ien. D. But-1-in. o Cu 47: Tin hnh ln men gim 460 ml ancol etylic 8 vi hiu sut bng 30%. Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml v ca nc bng 1 g/ml. Nng phn trm ca axit axetic trong dung dch thu c l A. 2,51%. B. 2,47%. C. 3,76%. D. 7,99%. Cu 48: Mt mu kh thi c cha CO2, NO2, N2 v SO2 c sc vo dung dch Ca(OH)2 d. Trong bn kh , s kh b hp th l A. 3. B. 4. C. 1. D. 2. Cu 49: Trong s cc dung dch c cng nng 0,1M di y, dung dch cht no c gi tr pH nh nht? A. NaOH. B. HCl. C. H2SO4. D. Ba(OH)2. Cu 50: Ha tan hon ton 24 gam hn hp X gm MO, M(OH)2 v MCO3 (M l kim loi c ha tr khng i) trong 100 gam dung dch H2SO4 39,2%, thu c 1,12 lt kh (ktc) v dung dch Y ch cha mt cht tan duy nht c nng 39,41%. Kim loi M l A. Zn. B. Ca. C. Mg. D. Cu. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Ha tan mt kh X vo nc, thu c dung dch Y. Cho t t dung dch Y n d vo dung dch ZnSO4, ban u thy c kt ta trng, sau kt ta tan ra. Kh X l A. NO2. B. HCl. C. SO2. D. NH3. Cu 52: Nhng mt thanh st vo dung dch hn hp cha 0,02 mol AgNO3 v 0,05 mol Cu(NO3)2. Sau khi cc phn ng xy ra hon ton, khi lng thanh st tng m gam (coi ton b kim loi sinh ra bm vo thanh st). Gi tr ca m l A. 2,00. B. 3,60. C. 1,44. D. 5,36. Cu 53: Hn hp X gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc, mch h. t chy hon ton 21,7 gam X, thu c 20,16 lt kh CO2 (ktc) v 18,9 gam H2O. Thc hin phn ng este ha X vi hiu sut 60%, thu c m gam este. Gi tr ca m l A. 9,18. B. 15,30. C. 12,24. D. 10,80. Cu 54: Trong mt bnh kn c cn bng ha hc sau: 2NO2 (k) R N2O4 (k). T khi hi ca hn hp kh trong bnh so vi H2 nhit T1 bng 27,6 v nhit T2 bng 34,5. Bit T1 > T2. Pht biu no sau y v cn bng trn l ng? A. Khi tng nhit , p sut chung ca h cn bng gim. B. Khi gim nhit , p sut chung ca h cn bng tng. C. Phn ng thun l phn ng ta nhit. D. Phn ng nghch l phn ng ta nhit. Cu 55: un si dung dch gm cht X v KOH c trong C2H5OH, thu c etilen. Cng thc ca X l A. CH3COOH. B. CH3CHCl2. C. CH3CH2Cl. D. CH3COOCH=CH2. Cu 56: Cht no di y khi cho vo dung dch AgNO3 trong NH3 d, un nng, khng xy ra phn ng trng bc? A. Mantoz. B. Fructoz. C. Saccaroz. D. Glucoz.
Cu 57: Ha tan hn hp X gm 11,2 gam Fe v 2,4 gam Mg bng dung dch H2SO4 long (d), thu c dung dch Y. Cho dung dch NaOH d vo Y thu c kt ta Z. Nung Z trong khng kh n khi lng khng i, thu c m gam cht rn. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 36. B. 20. C. 18. D. 24. Cu 58: Cho dy cht sau: isopren, anilin, anehit axetic, toluen, pentan, axit metacrylic v stiren. S cht trong dy phn ng c vi nc brom l A. 6. B. 4. C. 7. D. 5. Cu 59: Trng hp no sau y khng xy ra phn ng? A. Au + HNO3 c B. Ag + O3 D. Ag + HNO3 c C. Sn + HNO3 long Cu 60: T nitron (olon) l sn phm trng hp ca monome no sau y? A. CH2=CHCN. B. CH3COOCH=CH2. D. CH2=CHCH=CH2. C. CH2=C(CH3)COOCH3.
----------------------------------------------------------
HT ----------
B GIO DC V O TO THI CHNH THC P N THI TUYN SINH I HC NM 2013 Mn thi: HA HC; Khi B (p n c 02 trang)
M - p n 537 695
A D A A A B B D B B C B A A D B B D B A D B C B C C C D D C A D A C D B C C A B D B D C B B A A C D C C D A B D D B C A B C D B B A B B A D A D A C D C A D A C D A A A A C
Cu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43
279
C B D D D C A D B D D D A A B C C B B D B D B C C A B D B B B A B B A D D C A C A B D
362
C D C C B A C C C B B B B D A D A B B A D A C A A D A A A B C D C A B C D C D A C B D
753
B C B D A A A D A D C B A D D C A A B D B C D A A C B A B C C D B B A D D B C A B B A
864 D C B C C D C A C D B B C A A C B A A C C A C D B B D A D B A A D D C C B B D A A C D
Cu 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
279
C C A A A C C D A A C C C B D A A
362
B B C A C B A B D D D D C B D A D
M - p n 537 695
C C A B A D A C A D D C D A C C B B C C B A D C D C B D C D B B B D
753
B C D D C D C A B B D D C C C A C
864 D A D B A B C D C B A D A B B D B
B GIO DC V O TO
CHNH THC
( thi c 05 trang)
THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi B Thi gian lm bi: 90 pht, khng k thi gian pht M thi 359
Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Pht biu no sau y l ng? A. Tt c cc phn ng ca lu hunh vi kim loi u cn un nng. B. Trong cng nghip, nhm c sn xut t qung olomit. C. Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc. D. CrO3 tc dng vi nc to ra hn hp axit. Cu 2: t 5,6 gam Fe trong khng kh, thu c hn hp cht rn X. Cho ton b X tc dng vi dung dch HNO3 long (d), thu c kh NO (sn phm kh duy nht) v dung dch cha m gam mui. Gi tr ca m l A. 18,0. B. 22,4. C. 15,6. D. 24,2. Cu 3: Khi ni v kim loi kim, pht biu no sau y l sai? A. Cc kim loi kim c mu trng bc v c nh kim. B. Trong t nhin, cc kim loi kim ch tn ti dng hp cht. C. T Li n Cs kh nng phn ng vi nc gim dn. D. Kim loi kim c nhit nng chy v nhit si thp. Cu 4: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 2 : 3. B. 4 : 3. C. 3 : 2. D. 3 : 5. Cu 5: Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 4. B. 3. C. 6. D. 5. Cu 6: Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl? A. Kh hon ton glucoz thnh hexan. B. Cho glucoz tc dng vi Cu(OH)2. C. Tin hnh phn ng to este ca glucoz vi anhirit axetic. D. Thc hin phn ng trng bc. Cu 7: Cho dy chuyn ha sau: +H2 O +H2 +H2 O CaC2 X Z Y H SO , t o Pd/PbCO , t o
3
2 4
Tn gi ca X v Z ln lt l A. axetilen v ancol etylic. B. axetilen v etylen glicol. C. etan v etanal. D. etilen v ancol etylic. Cu 8: in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l A. 5,60. B. 11,20. C. 22,40. D. 4,48. Cu 9: Cc polime thuc loi t nhn to l A. t visco v t nilon-6,6. B. t tm v t vinilon. C. t nilon-6,6 v t capron. D. t visco v t xenluloz axetat. Cu 10: un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c
72,48 gam mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m l A. 51,72. B. 54,30. C. 66,00. D. 44,48. Cu 11: Cho s chuyn ho: + FeCl3 to + CO d, t o +T Fe(NO3)3 X Y Z Fe(NO3)3 Cc cht X v T ln lt l B. FeO v AgNO3. A. FeO v NaNO3. C. Fe2O3 v Cu(NO3)2. D. Fe2O3 v AgNO3. Cu 12: Cho cc th nghim sau: (b) Nhit phn KClO3 (xc tc MnO2); (a) t kh H2S trong O2 d; (d) t P trong O2 d; (c) Dn kh F2 vo nc nng; (g) Dn kh CO2 vo dung dch Na2SiO3. (e) Kh NH3 chy trong O2; S th nghim to ra cht kh l A. 5. B. 4. C. 2. D. 3. Cu 13: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 44,65. B. 50,65. C. 22,35. D. 33,50. Cu 14: Pht biu no sau y l sai? A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng. B. Cc nhm A bao gm cc nguyn t s v nguyn t p. C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c. Cu 15: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H2 (ktc). Gi tr ca V l A. 3,36. B. 11,20. C. 5,60. D. 6,72. Cu 16: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH3COOH v axit C2H5COOH l A. 9. B. 4. C. 6. D. 2. Cu 17: Pht biu no sau y l ng? A. Hn hp FeS v CuS tan c ht trong dung dch HCl d. B. Thi khng kh qua than nung , thu c kh than t. C. Photpho d bc chy trong khng kh iu kin thng. D. Dung dch hn hp HCl v KNO3 ho tan c bt ng. Cu 18: t chy hn hp gm 1,92 gam Mg v 4,48 gam Fe vi hn hp kh X gm clo v oxi, sau phn ng ch thu c hn hp Y gm cc oxit v mui clorua (khng cn kh d). Ha tan Y bng mt lng va 120 ml dung dch HCl 2M, thu c dung dch Z. Cho AgNO3 d vo dung dch Z, thu c 56,69 gam kt ta. Phn trm th tch ca clo trong hn hp X l A. 51,72%. B. 76,70%. C. 53,85%. D. 56,36%. Cu 19: Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic, mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc dng ht vi Na d, thu c 0,504 lt kh H2 (ktc). Phn hai cho phn ng trng bc hon ton thu c 9,72 gam Ag. Phn trm khi lng ancol b oxi ho l A. 50,00%. B. 62,50%. C. 31,25%. D. 40,00%. Cu 20: Nguyn t Y l phi kim thuc chu k 3, c cng thc oxit cao nht l YO3. Nguyn t Y to vi kim loi M hp cht c cng thc MY, trong M chim 63,64% v khi lng. Kim loi M l A. Zn. B. Cu. C. Mg. D. Fe. Cu 21: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml kh O2, thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc th tch kh v hi o cng iu kin. Cng thc phn t ca X l B. C4H10O. C. C3H8O. D. C4H8O. A. C4H8O2. + 2+ Cu 22: Mt dung dch gm: 0,01 mol Na ; 0,02 mol Ca ; 0,02 mol HCO3 v a mol ion X (b qua s in li ca nc). Ion X v gi tr ca a l 2 v 0,03. B. Cl v 0,01. C. CO 3 v 0,03. D. OH v 0,03. A. NO 3
Cu 23: Cho phn ng: N2 (k) + 3H2 (k) R 2NH3 (k); H = 92 kJ. Hai bin php u lm cn bng chuyn dch theo chiu thun l A. gim nhit v gim p sut. B. tng nhit v tng p sut. C. gim nhit v tng p sut. D. tng nhit v gim p sut. Cu 24: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l A. 0 gam. B. 24 gam. C. 8 gam. D. 16 gam. Cu 25: Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v NaOH 0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l A. 19,70. B. 23,64. C. 7,88. D. 13,79. Cu 26: Trng hp no sau y xy ra n mn in ho? A. Si dy bc nhng trong dung dch HNO3. B. t l st trong kh Cl2. C. Thanh nhm nhng trong dung dch H2SO4 long. D. Thanh km nhng trong dung dch CuSO4. Cu 27: Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch HNO3 1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N2O. T khi ca X so vi H2 l 16,4. Gi tr ca m l A. 98,20. B. 97,20. C. 98,75. D. 91,00. Cu 28: t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y i qua dung dch H2SO4 c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon l A. C2H4 v C3H6. B. C3H6 v C4H8. C. C2H6 v C3H8. D. C3H8 v C4H10. Cu 29: Cho cc cht ring bit sau: FeSO4, AgNO3, Na2SO3, H2S, HI, Fe3O4, Fe2O3 tc dng vi dung dch H2SO4 c, nng. S trng hp xy ra phn ng oxi ho - kh l A. 6. B. 3. C. 4. D. 5. Cu 30: Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban u l A. 0,168 gam. B. 0,123 gam. C. 0,177 gam. D. 0,150 gam. Cu 31: Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn va 0,5 mol H2. Dy ng ng ca X c cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n-3CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n-1CHO (n 2). Cu 32: Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ho tan cng s mol mi cht vo dung dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l A. Fe3O4. B. Fe(OH)2. C. FeS. D. FeCO3. Cu 33: un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi tr ca m l A. 40,60. B. 22,60. C. 34,30. D. 34,51. Cu 34: Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24 mol O2, thu c CO2 v 0,2 mol H2O. Cng thc hai axit l A. HCOOH v C2H5COOH. B. CH2=CHCOOH v CH2=C(CH3)COOH. D. CH3COOH v CH2=CHCOOH. C. CH3COOH v C2H5COOH. Cu 35: t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp cht rn Y. Cho Y vo nc d, thu c dung dch Z v 2,4 gam kim loi. Dung dch Z tc dng c vi ti a 0,21 mol KMnO4 trong dung dch H2SO4 (khng to ra SO2). Phn trm khi lng ca Fe trong hn hp X l A. 72,91%. B. 64,00%. C. 66,67%. D. 37,33%.
Cu 36: Ho tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu c gm dung dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit trong cc qu trnh trn, sn phm kh duy nht ca N +5 u l NO. Gi tr ca m l A. 12,8. B. 6,4. C. 9,6. D. 3,2. Cu 37: Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l D. C2H5COOC6H5. A. CH3COOCH2C6H5. B. HCOOC6H4C2H5. C. C6H5COOC2H5. Cu 38: Alanin c cng thc l B. CH3-CH(NH2)-COOH. A. C6H5-NH2. D. H2N-CH2-CH2-COOH. C. H2N-CH2-COOH. CaO, t o Cu 39: Cho phng trnh ha hc: 2X + 2NaOH 2CH4 + K2CO3 + Na2CO3 Cht X l B. CH2(COONa)2. C. CH3COOK. D. CH3COONa. A. CH2(COOK)2. Cu 40: Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 2,24. B. 4,48. C. 6,72. D. 3,36. II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn ca phn ring (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho dy cc cht sau: toluen, phenyl fomat, fructoz, glyxylvalin (Gly-Val), etylen glicol, triolein. S cht b thu phn trong mi trng axit l A. 6. B. 3. C. 4. D. 5. Cu 42: Cho phng trnh ha hc (vi a, b, c, d l cc h s): aFeSO4 + bCl2 cFe2(SO4)3 + dFeCl3 T l a : c l A. 4 : 1. B. 3 : 2. C. 2 : 1. D. 3 : 1. Cu 43: Cho m gam bt st vo dung dch hn hp gm 0,15 mol CuSO4 v 0,2 mol HCl. Sau khi cc phn ng xy ra hon ton, thu c 0,725m gam hn hp kim loi. Gi tr ca m l A. 16,0. B. 18,0. C. 16,8. D. 11,2. Cu 44: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 60. B. 24. C. 36. D. 40. Cu 45: C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O? A. 3. B. 5. C. 6. D. 4. Cu 46: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l A. mt ankan v mt ankin. B. hai ankaien. C. hai anken. D. mt anken v mt ankin. Cu 47: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l A. 3. B. 2. C. 4. D. 1. Cu 48: Pht biu no sau y l sai? A. Clo c dng dit trng nc trong h thng cung cp nc sch. B. Amoniac c dng iu ch nhin liu cho tn la. C. Lu hunh ioxit c dng lm cht chng nm mc. D. Ozon trong khng kh l nguyn nhn chnh gy ra s bin i kh hu. Cu 49: Pht biu no sau y l sai? A. Cr(OH)3 tan trong dung dch NaOH. B. Trong mi trng axit, Zn kh Cr3+ thnh Cr. C. Photpho bc chy khi tip xc vi CrO3. 2 D. Trong mi trng kim, Br2 oxi ha CrO 2 thnh CrO 4 .
Cu 50: Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton. Chia hn hp thu c sau phn ng thnh hai phn bng nhau. Phn mt phn ng va vi 300 ml dung dch NaOH 1M (long). ha tan ht phn hai cn va dung dch cha a mol HCl. Gi tr ca a l A. 0,9. B. 1,3. C. 0,5. D. 1,5. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l A. 6,480. B. 9,504. C. 8,208. D. 7,776. Cu 52: Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu en. Hin tng ny do cht no c trong kh thi gy ra? A. H2S. B. NO2. C. SO2. D. CO2. Cu 53: Cho phenol (C6H5OH) ln lt tc dng vi (CH3CO)2O v cc dung dch: NaOH, HCl, Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l A. 3. B. 4. C. 2. D. 1. Cu 54: Ho tan Au bng nc cng toan th sn phm kh l NO; ho tan Ag trong dung dch HNO3 c th sn phm kh l NO2. s mol NO2 bng s mol NO th t l s mol Ag v Au tng ng l A. 1 : 2. B. 3 : 1. C. 1 : 1. D. 1 : 3. Cu 55: Ngi ta iu ch H2 v O2 bng phng php in phn dung dch NaOH vi in cc tr, cng dng in 0,67A trong thi gian 40 gi. Dung dch thu c sau in phn c khi lng 100 gam v nng NaOH l 6%. Nng dung dch NaOH trc in phn l (gi thit lng nc bay hi khng ng k) A. 5,08%. B. 6,00%. C. 5,50%. D. 3,16%. Cu 56: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l A. 2-metylbutan-2-ol. B. 3-metylbutan-2-ol. C. 3-metylbutan-1-ol. D. 2-metylbutan-3-ol. Cu 57: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm ha xanh. Trn ln hai dung dch trn thu c kt ta. Hai cht X v Y tng ng l A. KNO3 v Na2CO3. B. Ba(NO3)2 v Na2CO3. C. Na2SO4 v BaCl2. D. Ba(NO3)2 v K2SO4. Cu 58: Trng hp no sau y to ra kim loi? A. t FeS2 trong oxi d. B. Nung hn hp qung apatit, x vn v than cc trong l ng. C. t Ag2S trong oxi d. D. Nung hn hp qung photphorit, ct v than cc trong l in. Cu 59: t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO2 (ktc) v 15,3 gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H2 (ktc). Gi tr ca m l A. 12,9. B. 15,3. C. 12,3. D. 16,9. Cu 60: Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l A. (1), (2) v (3). B. (1), (2) v (5). C. (1), (3) v (5). D. (3), (4) v (5).
----------------------------------------------------------
HT ----------
P N THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi: B
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
359
D D C B D C A A D A D B A C A B D C B D D A C B A D A B C C D C A
491
A B A A B C A A B C B C C C D D B D B A C A A C D B D C D C C D B
572
C C D A B A C B C B A B C C A D D B A D A A B D B D D D D A D A A
637
A A A C C C D A A C A B C B C A D A C C A B B C C B B D A B A C C
815
D B D D A A D D B D C C D A C D D B A B A A B D B C B B A B B C B
962
C C A A D A D A B C B C D A D C B D D C C D B D C C B D B C B B B
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
359
D C A D B C A B D A D B A C D B B B A B C C A B C B C
491
D B A C D A A B B D A D C C B A C B D C B B A A D D D
572
D A A A B C D C B C C A B B B B C D B C D A B C C D C
637
D D D D D B D D A D A C D B B B D B D C A B B A B C D
815
C A C A C B C D B C D A C A C B D A C D C A C D A A B
962
B A A D B C A D D A A C D A A B B B C D C A A A D B C
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
Cho bit nguyn t khi ca cc nguyn t: H = 1; He = 4; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Sr = 88; Ag = 108; Sn = 119; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 5. B. 2. C. 4. D. 6. Cu 2: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l: A. Bt Mg, dung dch BaCl2, dung dch HNO3. B. Kh Cl2, dung dch Na2CO3, dung dch HCl. C. Bt Mg, dung dch NaNO3, dung dch HCl. D. Kh Cl2, dung dch Na2S, dung dch HNO3. Cu 3: Cho s phn ng: xt, t o (1) X + O2 axit cacboxylic Y1. xt, t o (2) X + H2 ancol Y2. xt, t o Y3 + H2O. (3) Y1 + Y2 Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l A. anehit acrylic. B. anehit propionic. C. anehit metacrylic. D. anehit axetic. Cu 4: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c). (c) Sc kh Cl2 vo dung dch NaHCO3. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. (h) Cho PbS vo dung dch HCl (long). (i) Cho Na2SO3 vo dung dch H2SO4 (d), un nng. S th nghim sinh ra cht kh l A. 4. B. 6. C. 5. D. 2. Cu 5: Cho cc phn ng: (a) Sn + HCl (long) (b) FeS + H2SO4 (long) o o t t (c) MnO2 + HCl (c) (d) Cu + H2SO4 (c) (e) Al + H2SO4 (long) (g) FeSO4 + KMnO4 + H2SO4 + S phn ng m H ca axit ng vai tr cht oxi ho l A. 3. B. 5. C. 2. D. 6. Cu 6: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l A. 30%. B. 40%. C. 50%. D. 20%. Cu 7: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l: A. Na, K, Ca. B. Na, K, Ba. C. Li, Na, Mg. D. Mg, Ca, Ba. Cu 8: Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi cc phn ng kt thc th s mol NaOH phn ng l A. 0,14 mol. B. 0,08 mol. C. 0,16 mol. D. 0,06 mol.
Cu 9: Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh o cng iu kin nhit , p sut). T l V1 : V2 l A. 2 : 1. B. 1 : 2. C. 3 : 5. D. 5 : 3. Cu 10: Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. S pht biu ng l A. 2. B. 5. C. 4. D. 3.
Cu 11: Dung dch X gm 0,1 mol H+, z mol Al3+, t mol NO 3 v 0,02 mol SO 2 4 . Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l A. 0,020 v 0,012. B. 0,012 v 0,096. C. 0,020 v 0,120. D. 0,120 v 0,020. Cu 12: Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l A. 5. B. 6. C. 4. D. 3. Cu 13: hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l A. CH2=C(CH3)-CHO v OHC-CHO. B. OHC-CH2-CHO v OHC-CHO. C. H-CHO v OHC-CH2-CHO. D. CH2=CH-CHO v OHC-CH2-CHO. Cu 14: Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH (c, nng) l A. 4. B. 6. C. 3. D. 5. Cu 15: Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat. B. phenylamoni clorua, axit clohiric, anilin. C. anilin, axit clohiric, phenylamoni clorua. D. natri phenolat, axit clohiric, phenol. Cu 16: Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. - un nng phn 2 vi H2SO4 c 140oC to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Hiu sut phn ng to ete ca X, Y ln lt l A. 25% v 35%. B. 20% v 40%. C. 40% v 20%. D. 30% v 30%. Cu 17: Pht biu no sau y ng? A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t OH trong nhm COOH ca axit v H trong nhm OH ca ancol.
B. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn dng thuc th l nc brom. D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. Cu 18: Pht biu no sau y l sai? A. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. B. Tt c cc tinh th phn t u kh nng chy v kh bay hi. C. Tinh th nc , tinh th iot u thuc loi tinh th phn t. D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho tr. Cu 19: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A. 27. B. 24. C. 34. D. 31. Cu 20: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 2. B. 4. C. 5. D. 3. Cu 21: Trong t nhin clo c hai ng v bn:
35 17 37 17
37 17
Cl chim 24,23% tng s nguyn t, cn li l
Cl. Thnh phn % theo khi lng ca Cl trong HClO4 l A. 8,43%. B. 8,79%. C. 8,92%. D. 8,56%. Cu 22: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l A. 2. B. 4. C. 3. D. 1. Cu 23: Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (2), (1), (3). B. (3), (1), (2). C. (1), (2), (3). D. (2), (3), (1). Cu 24: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 3 : 4. B. 3 : 2. C. 4 : 3. D. 7 : 4. Cu 25: luyn c 800 tn gang c hm lng st 95%, cn dng x tn qung manhetit cha 80% Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr ca x l A. 1394,90. B. 1325,16. C. 1311,90. D. 959,59. Cu 26: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 31,45 gam. B. 31 gam. C. 32,36 gam. D. 30 gam.
Cu 27: Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0. Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (1), (2), (4), (5). B. (2), (3), (5). C. (2), (3), (4), (6). D. (1), (2), (4). Cu 28: Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam X? A. 10,56 gam. B. 3,36 gam. C. 7,68 gam. D. 6,72 gam. Cu 29: Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lt, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt ta. Gi tr ca x l A. 1,6. B. 1,2. C. 1,0. D. 1,4.
Cu 30: Thc hin cc th nghim vi hn hp bt gm Ag v Cu (hn hp X): (a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng). (b) Cho X vo mt lng d dung dch HNO3 (c). (c) Cho X vo mt lng d dung dch HCl (khng c mt O2). (d) Cho X vo mt lng d dung dch FeCl3. Th nghim m Cu b oxi ho cn Ag khng b oxi ho l A. (d). B. (a). C. (b). D. (c). Cu 31: Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng). B. Cu(OH)2 ( iu kin thng). C. Dung dch NaOH (un nng). D. H2 (xc tc Ni, un nng). Cu 32: Pht biu no sau y l sai? A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn. B. nhit thng, tt c cc kim loi kim th u tc dng c vi nc. C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thu tinh. D. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v. Cu 33: Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l A. 57,15%. B. 14,28%. C. 28,57%. D. 18,42%. Cu 34: Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi lng ca KMnO4 trong X l A. 74,92%. B. 72,06%. C. 27,94%. D. 62,76%. Cu 35: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l A. 7,3. B. 6,6. C. 3,39. D. 5,85. Cu 36: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 1. B. 2. C. 3. D. 4. Cu 37: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 75%. B. 72,08%. C. 27,92%. D. 25%. Cu 38: Ancol v amin no sau y cng bc? A. (CH3)3COH v (CH3)3CNH2. B. (C6H5)2NH v C6H5CH2OH. C. (CH3)2CHOH v (CH3)2CHNH2. D. C6H5NHCH3 v C6H5CH(OH)CH3. Cu 39: Cho dy cc oxit sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l A. 7. B. 5. C. 6. D. 8. Cu 40: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l A. anehit acrylic. B. anehit butiric. C. anehit propionic. D. anehit axetic. ________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A. 8. B. 7. C. 9. D. 5. Cu 42: Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X phn ng l A. 70%. B. 25%. C. 60%. D. 75%. Cu 43: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (ktc). Gi tr ln nht ca V l A. 22,4. B. 13,44. C. 5,6. D. 11,2. Cu 44: Cho cc pht biu sau: (a) Anehit va c tnh oxi ho va c tnh kh. (b) Phenol tham gia phn ng th brom kh hn benzen. (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt. (d) Dung dch axit axetic tc dng c vi Cu(OH)2. (e) Dung dch phenol trong nc lm qu tm ho . (g) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng l A. 4. B. 2. C. 5. D. 3. Cu 45: Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH? A. 3. B. 5. C. 4. D. 2. Cu 46: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l A. 20,80. B. 29,25. C. 48,75. D. 32,50. Cu 47: Trong qu gc chn rt giu hm lng A. vitamin A. B. ete ca vitamin A. C. -caroten. D. este ca vitamin A. Cu 48: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45. Cu 49: Pht biu no sau y l sai? A. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x. B. Thic c th dng ph ln b mt ca st chng g. C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh eczema, bnh nga. D. Nhm l kim loi dn in tt hn vng. Cu 50: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,24 mol. B. 0,36 mol. C. 0,60 mol. D. 0,48 mol. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A. 5,12. B. 3,84. C. 5,76. D. 6,40.
Cu 52: Thc hin cc th nghim sau: (a) Nhit phn AgNO3. (b) Nung FeS2 trong khng kh. (c) Nhit phn KNO3. (d) Cho dung dch CuSO4 vo dung dch NH3 (d). (e) Cho Fe vo dung dch CuSO4. (g) Cho Zn vo dung dch FeCl3 (d). (h) Nung Ag2S trong khng kh. (i) Cho Ba vo dung dch CuSO4 (d). S th nghim thu c kim loi sau khi cc phn ng kt thc l A. 3. B. 5. C. 2. D. 4. Cu 53: Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng bnh mt thi gian 830oC h t n trng thi cn bng: CO (k) + H2O (k) CO2 (k) + H2 (k) (hng s cn bng KC = 1). Nng cn bng ca CO, H2O ln lt l A. 0,08M v 0,18M. B. 0,018M v 0,008M. C. 0,012M v 0,024M. D. 0,008M v 0,018M. Cu 54: Cho s phn ng: +H2O +HCN X1 (1) CH3CHO X2. H+ ,t o
+Mg +HCl 2 Y3. Y2 (2) C2H5Br ete Y1 +CO
Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l A. axit 2-hiroxipropanoic v axit propanoic. B. axit 3-hiroxipropanoic v ancol propylic. C. axit axetic v axit propanoic. D. axit axetic v ancol propylic. Cu 55: Ho tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y. Thm H2SO4 (d) vo 20 ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l A. 68,4%. B. 9,12%. C. 31,6%. D. 13,68%. Cu 56: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu cho a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l A. 46,67%. B. 40,00%. C. 25,41%. D. 74,59%. Cu 57: Pht biu khng ng l: A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit. B. Etylamin tc dng vi axit nitr nhit thng to ra etanol. C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu. D. Metylamin tan trong nc cho dung dch c mi trng baz. Cu 58: Trong qu trnh hot ng ca pin in ho Zn Cu th A. nng ca ion Zn2+ trong dung dch tng. B. khi lng ca in cc Cu gim. C. nng ca ion Cu2+ trong dung dch tng. D. khi lng ca in cc Zn tng. Cu 59: Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,090 mol. B. 0,12 mol. C. 0,095 mol. D. 0,06 mol. Cu 60: Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz. (b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau. (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3. (d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (e) Trong dung dch, fructoz tn ti ch yu dng mch h. (g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ). S pht biu ng l A. 4. B. 5. C. 3. D. 2.
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HT ---------Trang 6/6 - M thi 153
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
153
C D A C C D B B B A C C D B D C A B C B C D A D B B B D D A B B C
429
B C C A B A C A D A A A D B A B A B B C C C D D D B C D D A D C A
517
A B A B B A A C D B B A A C D B C C C D D A A A D A C D A B B D C
638
D B D C B B A C D A B C C A D C B C A A A B D D D A B C D C A C A
794
D A A C A D B D B C A C B A B C D D C B B A D C D D C B A D C C B
846
A B D D C B C A C D B B C D B D D D D C B D C C B C D A C B B C B
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
153
B A B D D C A A D D A B A C C D B D A D A A C A A C C
429
B B B B D C A A B A D A B C B D A B D C D C C D C D C
517
B A D D B C C D D B C B B C C C A A C A C D B D B D D
638
A B A C D D C B A D B C B C B A B D B C A D C A D D B
794
D A C D A A A A C A A D B D B C B D A B C C D B B C B
846
A A A C A A A A C D B A A C C A D B A B D D C B B D A
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Sr = 88; Ag = 108; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7. D. CH3OCO-CH2-CH2-COOC2H5. Cu 2: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12. B. 0,14. C. 0,16. D. 0,18. Cu 3: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,015. B. 0,010. C. 0,020. D. 0,005. Cu 4: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch A. Pb(NO3)2. B. NaHS. C. AgNO3. D. NaOH. Cu 5: Pht biu no sa u y khng ng khi so snh tnh cht ha hc ca nhm v crom? A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui. B. Nhm c tnh kh mnh hn crom. C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. D. Nhm v crom u b n trong khng kh v trong nc. Cu 6: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. Cu 7: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ho tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l A. Cr2O3. B. FeO. C. Fe3O4. D. CrO. Cu 8: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 4. B. 7. C. 5. D. 6.
Cu 9: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. Cu 10: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C3H5COOH v 54,88%. B. C2H3COOH v 43,90%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12%. Cu 11: Cc cht m phn t khng phn cc l: A. HBr, CO2, CH4. B. Cl2, CO2, C2H2. C. NH3, Br2, C2H4. D. HCl, C2H2, Br2. 3+ Cu 12: Mt ion M c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l A. [Ar]3d54s1. B. [Ar]3d64s2. C. [Ar]3d64s1. D. [Ar]3d34s2. Cu 13: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8. Cu 14: Pht biu no sau y khng ng? A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht. B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh. C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng. D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng. Cu 15: Dy gm cc cht u tc dng vi H2 (xc tc Ni, to), to ra sn phm c kh nng phn ng vi Na l: A. C2H3CH2OH, CH3COCH3, C2H3COOH. B. C2H3CHO, CH3COOC2H3, C6H5COOH. C. C2H3CH2OH, CH3CHO, CH3COOH. D. CH3OC2H5, CH3CHO, C2H3COOH. Cu 16: Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat, cn li gm cc cht khng cha photpho. dinh dng ca loi phn ln ny l A. 48,52%. B. 42,25%. C. 39,76%. D. 45,75%. Cu 17: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,36. C. 0,54. D. 0,45. Cu 18: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 65,2%. B. 16,3%. C. 48,9%. D. 83,7%. Cu 19: Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH Phn ng ny chng t C6H5-CHO A. va th hin tnh oxi ho, va th hin tnh kh. B. ch th hin tnh oxi ho. C. ch th hin tnh kh. D. khng th hin tnh kh v tnh oxi ho. Cu 20: Ho tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 39,34%. B. 65,57%. C. 26,23%. D. 13,11%.
Cu 21: in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l A. 2,25. B. 1,50. C. 1,25. D. 3,25. Cu 22: Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit nhm l A. 80%. B. 90%. C. 70%. D. 60%. Cu 23: Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l A. CH4. B. C2H2. C. C3H6. D. C2H4. Cu 24: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l: A. glixerol, axit axetic, glucoz. B. lng trng trng, fructoz, axeton. C. anehit axetic, saccaroz, axit axetic. D. fructoz, axit acrylic, ancol etylic. Cu 25: Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn ng oxi ho - kh l A. 3. B. 5. C. 4. D. 6. Cu 26: Cc cht u khng b thu phn trong dung dch H2SO4 long nng l: A. t capron; nilon-6,6; polietilen. B. poli(vinyl axetat); polietilen; cao su buna. C. nilon-6,6; poli(etylen-terephtalat); polistiren. D. polietilen; cao su buna; polistiren. Cu 27: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,4. C. 0,3. D. 0,2. Cu 28: Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca x l A. 1,2. B. 0,8. C. 0,9. D. 1,0. Cu 29: Pht biu no sau y khng ng? A. Dung dch m c ca Na2SiO3 v K2SiO3 c gi l thy tinh lng. B. m chy magie c th c dp tt bng ct kh. C. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon. D. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho. Cu 30: C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni. S trng hp xut hin n mn in ho l A. 1. B. 4. C. 3. D. 2. Cu 31: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l A. metyl propionat. B. metyl axetat. C. etyl axetat. D. vinyl axetat. Cu 32: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l A. 4. B. 5. C. 8. D. 9. Cu 33: Ha tan hon ton 2,45 gam hn hp X gm hai kim loi kim th vo 200 ml dung dch HCl 1,25M, thu c dung dch Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X l A. Mg v Ca. B. Be v Mg. C. Mg v Sr. D. Be v Ca.
Cu 34: Cho cc cn bng sau: (I) 2HI (k) H2 (k) + I2 (k); (II) CaCO3 (r) CaO (r) + CO2 (k); (IV) 2SO2 (k) + O2 (k) 2SO3 (k). Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l A. 4. B. 3. C. 2. D. 1. Cu 35: Cho s chuyn ho:
+KOH +KOH 3 4 Y X Z. P2O5 Cc cht X, Y, Z ln lt l: A. K3PO4, K2HPO4, KH2PO4. B. KH2PO4, K2HPO4, K3PO4. C. K3PO4, KH2PO4, K2HPO4. D. KH2PO4, K3PO4, K2HPO4. Cu 36: t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 23,2. B. 12,6. C. 18,0. D. 24,0. Cu 37: Cho s chuyn ho sau:
(III) FeO (r) + CO (k) Fe (r) + CO2 (k);
+H PO
xt, t +Z 2 C 2 H 2 X Y Cao su buna-N. Pd, PbCO3 t o , xt, p
+H , t o
Cc cht X, Y, Z ln lt l: A. benzen; xiclohexan; amoniac. B. axetanehit; ancol etylic; buta-1,3-ien. C. vinylaxetilen; buta-1,3-ien; stiren. D. vinylaxetilen; buta-1,3-ien; acrilonitrin. Cu 38: t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l A. 14,56. B. 15,68. C. 11,20. D. 4,48. Cu 39: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 112,2. B. 165,6. C. 123,8. D. 171,0. Cu 40: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 5. B. 4. C. 6. D. 3. _________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Pht biu no sau y ng? A. Khi un C2H5Br vi dung dch KOH ch thu c etilen. B. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng. C. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi. D. un ancol etylic 140oC (xc tc H2SO4 c) thu c imetyl ete. Cu 42: Cho cc cp cht vi t l s mol tng ng nh sau: (a) Fe3O4 v Cu (1:1); (b) Sn v Zn (2:1); (c) Zn v Cu (1:1); (d) Fe2(SO4)3 v Cu (1:1); (e) FeCl2 v Cu (2:1); (g) FeCl3 v Cu (1:1). S cp cht tan hon ton trong mt lng d dung dch HCl long nng l A. 4. B. 2. C. 3. D. 5.
Cu 43: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc tc Ni, to)? A. 3. B. 5. C. 2. D. 4. Cu 44: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l A. HCOOH v CH3OH. B. CH3COOH v CH3OH. C. HCOOH v C3H7OH. D. CH3COOH v C2H5OH. 2+ + Cu 45: Dung dch X cha cc ion: Ca , Na , HCO3 v Cl, trong s mol ca ion Cl l 0,1. Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m l A. 9,21. B. 9,26. C. 8,79. D. 7,47. Cu 46: Hn hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dung dch HCl (d), sau phn ng thu c dung dch cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hn hp kh thu c sau phn ng li t t qua dung dch Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l A. 76,755. B. 73,875. C. 147,750. D. 78,875. Cu 47: Cho mt s nhn nh v nguyn nhn gy nhim mi trng khng kh nh sau: (1) Do hot ng ca ni la. (2) Do kh thi cng nghip, kh thi sinh hot. (3) Do kh thi t cc phng tin giao thng. (4) Do kh sinh ra t qu trnh quang hp ca cy xanh. (5) Do nng cao ca cc ion kim loi: Pb2+, Hg2+, Mn2+, Cu2+ trong cc ngun nc. Nhng nhn nh ng l: A. (1), (2), (3). B. (2), (3), (5). C. (1), (2), (4). D. (2), (3), (4). Cu 48: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. Cu 49: Hn hp bt X gm Cu, Zn. t chy hon ton m gam X trong oxi (d), thu c 40,3 gam hn hp gm CuO v ZnO. Mt khc, nu cho 0,25 mol X phn ng vi mt lng d dung dch KOH long nng, th thu c 3,36 lt kh H2 (ktc). Phn trm khi lng ca Cu trong X l A. 19,81%. B. 29,72%. C. 39,63%. D. 59,44%. Cu 50: Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l: A. (1), (3), (5), (6). B. (1), (2), (4), (6). C. (1), (2), (4), (5). D. (1), (4), (5), (6). B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 6,72. B. 8,96. C. 4,48. D. 10,08. Cu 52: Pht biu no sau y khng ng? A. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh chuyn thnh mui Cr(VI). B. Do Pb2+/Pb ng trc 2H+/H2 trong dy in ho nn Pb d dng phn ng vi dung dch HCl long ngui, gii phng kh H2. C. CuO nung nng khi tc dng vi NH3 hoc CO, u thu c Cu. D. Ag khng phn ng vi dung dch H2SO4 long nhng phn ng vi dung dch H2SO4 c nng.
Cu 53: Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng? A. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4. B. in li ca axit fomic s gim khi thm dung dch HCl. C. Khi pha long dung dch trn th in li ca axit fomic tng. D. in li ca axit fomic trong dung dch trn l 14,29%. Cu 54: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho mn s chuyn ho sau: +CH3COOH +H2 X Y H2 SO4 c Este c mi chui chn. o
Ni, t
Tn ca X l A. pentanal. B. 2-metylbutanal. C. 2,2-imetylpropanal. D. 3-metylbutanal. Cu 55: nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t nc, c c ri thm dung dch Na2S vo thy xut hin kt ta mu vng. Hin tng trn chng t nc thi b nhim bi ion A. Fe2+. B. Cu2+. C. Pb2+. D. Cd2+.
+CuO 2 2 X Y Z. Cu 56: Cho s phn ng: Stiren to H+ + o H ,t +H O +Br
Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l: A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br. B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH. C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH. D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3. Cu 57: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2. D. H2NCH2CH2CH2NH2. Cu 58: Cho s chuyn ho: Fe3O4 + dung dch HI (d) X + Y + H2O. Bit X v Y l sn phm cui cng ca qu trnh chuyn ho. Cc cht X v Y l A. Fe v I2. B. FeI3 v FeI2. C. FeI2 v I2. D. FeI3 v I2. Cu 59: t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l A. 7,85 gam. B. 7,40 gam. C. 6,50 gam. D. 5,60 gam. Cu 60: Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l A. xenluloz. B. mantoz. C. glucoz . D. s accaroz .
----------------------------------------------------------
HT ----------
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33.
M thi
174
A D A B C B C D A B B B C B A B C B A C C A D A C D D A B D A D D
268
D C D B A D C D C A B B B B B A A A B D D C B D B B A D B C B A D
395
A D C C A A C A D D D C B A C A B B A D C B B A B A D D D D D D C
519
D B A B C C A C A C C B A C D D D A D A D D C C B A B C C C A D B
641
D D B C A A D C A C B C B B A C B C D C B A C A B A B C D A C A D
937
D A B D A D B D C C D B C D B A A A C A D B C C C D D C C A C B A
Cu s 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
M thi
174
D C C D A A B C C B D C B A C C D B B A D D A D C A B
268
C A C C B A D D C D D A B D C A A C A B C A C C A C D
395
C C B B B B D A B A C C A D C A B D C D C A C A B B B
519
A A D D B D B C A C A B C B D A D B D B B C D B B A A
641
A C A D D D C D D B A A D D D B A C A B B B C C D B B
937
B C B C A D D D C B C D B B A D A B A A C D A B B A B
B GIO DC V O TO
CHNH THC
( thi c 06 trang)
THI TUYN SINH I HC NM 2009 Mn: HO HC; Khi: B Thi gian lm bi: 90 pht, khng k thi gian pht M thi 148
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; P =31; S = 32; Cl = 35,5; K = 39; Ca = 40; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; I = 127; Ba = 137; Au = 197. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit aipic. C. ancol o-hiroxibenzylic. D. axit 3-hiroxipropanoic. Cu 2: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l A. 4,05. B. 2,70. C. 1,35. D. 5,40. Cu 3: Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: A. N, Si, Mg, K. B. K, Mg, Si, N. C. K, Mg, N, Si. D. Mg, K, Si, N. Cu 4: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l A. hn hp gm BaSO4 v FeO. B. hn hp gm Al2O3 v Fe2O3. C. hn hp gm BaSO4 v Fe2O3. D. Fe2O3. Cu 5: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l A. 2,80. B. 2,16. C. 4,08. D. 0,64. Cu 6: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 13,0. B. 1,2. C. 1,0. D. 12,8. Cu 7: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l A. KClO3. B. KMnO4. C. KNO3. D. AgNO3. Cu 8: Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 ( ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l A. 5, 0.104 mol/(l.s). B. 5, 0.10 5 mol/(l.s). C. 1, 0.103 mol/(l.s). D. 2,5.10 4 mol/(l.s). Cu 9: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l A. 108,0. B. 75,6. C. 54,0. D. 67,5. Cu 10: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2. B. C2H4O2 v C3H6O2. C. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2.
Cu 11: Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s mol mui tng ng. t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu vng. Hai mui X, Y ln lt l: A. KMnO4, NaNO3. B. Cu(NO3)2, NaNO3. C. CaCO3, NaNO3. D. NaNO3, KNO3. Cu 12: C cc th nghim sau: (I) Nhng thanh st vo dung dch H2SO4 long, ngui. (II) Sc kh SO2 vo nc brom. (III) Sc kh CO2 vo nc Gia-ven. (IV) Nhng l nhm vo dung dch H2SO4 c, ngui. S th nghim xy ra phn ng ho hc l A. 2. B. 1. C. 3. D. 4. Cu 13: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. C2H5COOH v C2H5COOCH3. D. HCOOH v HCOOC3H7. C. HCOOH v HCOOC2H5. Cu 14: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 15: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v NH3. B. CH3OH v CH3NH2. C. CH3NH2 v NH3. D. C2H5OH v N2. Cu 16: Cho cc phn ng sau: (a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O. (b) HCl + NH4HCO3 NH4Cl + CO2 + H2O. (c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O. (d) 2HCl + Zn ZnCl2 + H2. S phn ng trong HCl th hin tnh kh l A. 2. B. 3. C. 1. D. 4. Cu 17: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. O=CH-CH2-CH2OH. B. HOOC-CHO. C. CH3COOCH3. D. HCOOC2H5. Cu 18: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 1. C. 2. D. 4. Cu 19: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. D. CH3-CH=CH-CH3. C. CH2=CH-CH2-CH3. Cu 20: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6. B. 48,3. C. 36,7. D. 57,0. Cu 21: Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l A. Na. B. Ca. C. Ba. D. K. Cu 22: Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). C. (3), (5), (6), (8), (9). D. (2), (3), (5), (7), (9). Cu 23: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 24: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 58,2%. B. 41,8%. C. 52,8%. D. 47,2%. Cu 25: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l A. 151,5. B. 137,1. C. 97,5. D. 108,9. Cu 26: Thc hin cc th nghim sau: (I) Cho dung dch NaCl vo dung dch KOH. (II) Cho dung dch Na2CO3 vo dung dch Ca(OH)2. (III) in phn dung dch NaCl vi in cc tr, c mng ngn. (IV) Cho Cu(OH)2 vo dung dch NaNO3. (V) Sc kh NH3 vo dung dch Na2CO3. (VI) Cho dung dch Na2SO4 vo dung dch Ba(OH)2. Cc th nghim u iu ch c NaOH l: A. II, III v VI. B. I, II v III. C. I, IV v V. D. II, V v VI. Cu 27: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. O=CH-CH=O. B. CH2=CH-CH2-OH. C. CH3COCH3. D. C2H5CHO. Cu 28: Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng mt phng trnh ion rt gn l: A. (1), (2), (3), (6). B. (1), (3), (5), (6). C. (2), (3), (4), (6). D. (3), (4), (5), (6). Cu 29: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l B. CH3-C6H3(OH)2. A. HO-C6H4-COOCH3. C. HO-CH2-C6H4-OH. D. HO-C6H4-COOH.
Cu 30: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 10,8 v 2,24. C. 17,8 v 2,24. D. 17,8 v 4,48. Cu 31: Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (2), (3), (4) v (5). B. (3), (4), (5) v (6). C. (1), (2), (3) v (4). D. (1), (3), (4) v (6). Cu 32: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3COOH, C2H5OH, HCOOH, CH3CHO. B. CH3CHO, C2H5OH, HCOOH, CH3COOH. C. CH3COOH, HCOOH, C2H5OH, CH3CHO. D. HCOOH, CH3COOH, C2H5OH, CH3CHO. Cu 33: Pht biu no sau y l ng? A. Photpho trng c cu trc tinh th nguyn t. B. th rn, NaCl tn ti di dng tinh th phn t. C. Nc thuc loi tinh th phn t. D. Kim cng c cu trc tinh th phn t. Cu 34: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l A. 52,2. B. 54,0. C. 58,0. D. 48,4. Cu 35: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. Cu 36: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 70,87%. B. HOOC-CH2-COOH v 54,88%. C. HOOC-COOH v 60,00%. D. HOOC-COOH v 42,86%. Cu 37: Pht biu no sau y l ng? A. T visco l t tng hp. B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Trng hp stiren thu c poli(phenol-fomanehit). D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. Cu 38: Cho cc hp cht sau: (a) HOCH2-CH2OH. (b) HOCH2-CH2-CH2OH. (c) HOCH2-CH(OH)-CH2OH. (d) CH3-CH(OH)-CH2OH. (e) CH3-CH2OH. (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l: A. (a), (b), (c). B. (c), (d), (f). C. (a), (c), (d). D. (c), (d), (e). Cu 39: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HOCH(CH3)CHO v HOOCCH2CHO. D. HCOOCH3 v HCOOCH2CH3. Cu 40: Th nghim no sau y c kt ta sau phn ng? A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. B. Cho dung dch NH3 n d vo dung dch AlCl3.
C. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). D. Thi CO2 n d vo dung dch Ca(OH)2. _________________________________________________________________________________ II. PHN RING [10 cu] Th sinh ch c chn lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 27,75. B. 24,25. C. 26,25. D. 29,75. Cu 42: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 17,8. B. 24,8. C. 10,5. D. 8,8. Cu 43: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Cu 44: Pht biu no sau y l ng? A. Saccaroz lm mt mu nc brom. B. Xenluloz c cu trc mch phn nhnh. C. Amilopectin c cu trc mch phn nhnh. D. Glucoz b kh bi dung dch AgNO3 trong NH3. Cu 45: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam. D. 1,72 gam. Cu 46: ng dng no sau y khng phi ca ozon? A. Ty trng tinh bt, du n. B. Cha su rng. C. iu ch oxi trong phng th nghim. D. St trng nc sinh hot. Cu 47: Cho s chuyn ho gia cc hp cht ca crom: + (Cl2 + KOH) + H2SO4 + (FeSO4 + H2 SO4 ) + KOH X Cr(OH)3 Y Z T Cc cht X, Y, Z, T theo th t l: A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3. B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3. D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3. C. KCrO2; K2Cr2O7; K2CrO4; CrSO4. Cu 48: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CH2-CH2-CHO. Cu 49: Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l A. KH2PO4 v K3PO4. B. KH2PO4 v K2HPO4. C. KH2PO4 v H3PO4. D. K3PO4 v KOH. Cu 50: Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 57,4. B. 28,7. C. 10,8. D. 68,2.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 15,3. B. 13,5. C. 8,1. D. 8,5. Cu 52: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l A. 0,56 gam. B. 1,44 gam. C. 0,72 gam. D. 2,88 gam. Cu 53: Pht biu no sau y khng ng? A. Glucoz tc dng c vi nc brom. B. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH. C. Glucoz tn ti dng mch h v dng mch vng. D. dng mch h, glucoz c 5 nhm OH k nhau. Cu 54: Cho cc th in cc chun: E o = 1, 66V; E o = 0, 76V; E o = 0,13V; Al3+ /Al Zn 2+ /Zn Pb 2+ /Pb
`
Eo = +0,34V. Trong cc pin sau y, pin no c sut in ng chun ln nht? Cu 2+ /Cu
A. Pin Zn Cu. B. Pin Zn Pb. C. Pin Al Zn. D. Pin Pb Cu. Cu 55: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l A. 0,03 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,06 v 0,02. Cu 56: Ngi ta iu ch anilin bng s sau: + HNO3 c Fe + HCl Benzen Anilin H SO c Nitrobenzen to
2 4
Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam. B. 55,8 gam. C. 93,0 gam. D. 111,6 gam. Cu 57: Phn bn no sau y lm tng chua ca t? A. KCl. B. NH4NO3. C. NaNO3. D. K2CO3. Cu 58: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 oC, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 oC l A. 1,00. B. 4,24. C. 2,88. D. 4,76. Cu 59: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 21,95% v 2,25. B. 78,05% v 2,25. C. 21,95% v 0,78. D. 78,05% v 0,78. Cu 60: Cho s chuyn ho:
+ Mg, ete khan + HBr 2 4 Butan-2-ol X (anken) Y Z Trong X, Y, Z l sn phm chnh. Cng thc ca Z l A. (CH3)3C-MgBr. B. CH3-CH2-CH2 -CH2-MgBr. C. CH3-CH(MgBr)-CH2-CH3. D. (CH3)2CH-CH2-MgBr.
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H SO c, to
HT ----------
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32.
148
D B B C C A A A B D A C A B A A D D D B C C D B A A D A C C D B
269
C A A C A C D A C B D A C C B B B B B B A D A B A C B D B D D B
M thi 475 637

B D D C A C D B D B C A D C A D C C A D B B B B A A C D A A B D B B A D D C A A D A C D A C D B C A D B C C A C A D B D B B A B
852
A D A D B B C C B C B A D A C D C D A A B A B D C C A A A B B D
958
C C C B D B D A A A A B C D C B B A C B D C A A B B B A A D B D
Cu s 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60.
148
C C B D D C A B C A A C A C D C B D D B B A D B B D D C
269
C C A C C D A A D D D A D A D B B D C C D A A B D A C C
M thi 475 637

B C C A C A A A B C D B D A D D C D D B C B C B C C B A D C C D B B C A C D B D C A A C A D A D C D B A C C B B
852
C D C D C B A D C D C A A C C D A B D B A D C D B B B D
958
C D C C A D B D C D C A D C A A A D C C D B B D D C A B
B GIO DC V O TO
CHNH THC
( thi c 05 trang)
THI TUYN SINH I HC, CAO NG NM 2008 Mn thi: HO HC, khi B Thi gian lm bi: 90 pht. M thi 195
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; Ba = 137. PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44): Cu 1: Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2 Pht biu ng l: A. Tnh kh ca Cl- mnh hn ca Br -. B. Tnh oxi ha ca Br2 mnh hn ca Cl2. 2+ D. Tnh oxi ha ca Cl2 mnh hn ca Fe3+. C. Tnh kh ca Br mnh hn ca Fe . Cu 2: Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l: A. P, N, F, O. B. N, P, F, O. C. P, N, O, F. D. N, P, O, F. Cu 3: Nguyn tc luyn thp t gang l: A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp. B. Dng cht kh CO kh oxit st thnh st nhit cao. C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp. D. Tng thm hm lng cacbon trong gang thu c thp. Cu 4: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH(CH3)-COOH. Cu 5: Cho s chuyn ho sau:
+ NaOH (d),t , p + HCl (d) 2 Y Toluen X Z. Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol. 2+ Cu 6: Mt mu nc cng cha cc ion: Ca , Mg2+, HCO3-, Cl-, SO42-. Cht c dng lm mm mu nc cng trn l A. Na2CO3. B. HCl. C. H2SO4. D. NaHCO3. Cu 7: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 8: Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 1. B. 3. C. 4. D. 2.
+ Br (1:1mol),Fe,to
Cu 9: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. Cu 10: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 11: Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k) A. a = 0,5b. B. a = b. C. a = 4b. D. a = 2b. Cu 12: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 9,75. B. 8,75. C. 7,80. D. 6,50. + 2+ 2+ 3+ 2+ Cu 13: Cho dy cc cht v ion: Cl2, F2, SO2, Na , Ca , Fe , Al , Mn , S2-, Cl-. S cht v ion trong dy u c tnh oxi ho v tnh kh l A. 3. B. 4. C. 6. D. 5. Cu 14: Phn ng nhit phn khng ng l
t A. 2KNO3 2KNO2 + O2. o o t B. NH4NO2 N2 + 2H2O. o o t t C. NH4Cl NH3 + HCl. D. NaHCO3 NaOH + CO2. Cu 15: Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l A. 3. B. 4. C. 5. D. 2. Cu 16: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l A. 8,88 gam. B. 13,92 gam. C. 6,52 gam. D. 13,32 gam. Cu 17: Thnh phn chnh ca qung photphorit l B. NH4H2PO4. C. Ca(H2PO4)2. D. CaHPO4. A. Ca3(PO4)2. Cu 18: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l B. C2H6O. C. CH4O. D. C4H8O. A. C3H8O. Cu 19: Cho cc phn ng: Ca(OH)2 + Cl2 CaOCl2 + H2O 2H2S + SO2 3S + 2H2O
t 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O 4KClO3 KCl + 3KClO4 O3 O2 + O S phn ng oxi ho kh l A. 5. B. 2. C. 3. D. 4. Cu 20: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. HCOOH3NCH=CH2. B. H2NCH2CH2COOH. C. CH2=CHCOONH4. D. H2NCH2COOCH3. o
Cu 21: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. A. CH4 v C2H4. Cu 22: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C6H8O6. B. C3H4O3. C. C12H16O12. D. C9H12O9. Cu 23: Cho cn bng ho hc: N2 (k) + 3H2 (k) U 2NH3 (k); phn ng thun l phn ng to nhit. Cn bng ho hc khng b chuyn dch khi A. thay i p sut ca h. B. thay i nng N2. C. thay i nhit . D. thm cht xc tc Fe. Cu 24: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l A. Na. B. K. C. Rb. D. Li. Cu 25: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 55 lt. B. 81 lt. C. 49 lt. D. 70 lt. Cu 26: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 11,5. B. 10,5. C. 12,3. D. 15,6. Cu 27: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3OOC(CH2)2COOC2H5. B. CH3COO(CH2)2COOC2H5. C. CH3COO(CH2)2OOCC2H5. D. CH3OOCCH2COOC3H7. Cu 28: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H+][OH-] = 10-14) A. 0,15. B. 0,30. C. 0,03. D. 0,12. Cu 29: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l B. CH3COOH. C. HCOOH. D. C3H7COOH. A. C2H5COOH. Cu 30: Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3NH2. B. CH3COOCH3. C. CH3OH. D. CH3COOH. Cu 31: Cho cc phn ng sau:
t H2S + O2 (d) Kh X + H2O
C,Pt Kh Y + H2O NH3 + O2 850 NH4HCO3 + HCl long Kh Z + NH4Cl + H2O Cc kh X, Y, Z thu c ln lt l: A. SO3, NO, NH3. B. SO2, N2, NH3. C. SO2, NO, CO2. D. SO3, N2, CO2. Cu 32: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO2 ( ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l A. 40%. B. 50%. C. 84%. D. 92%. Cu 33: Cho cc phn ng: t HBr + C2H5OH C2H4 + HBr o o
C2H4 + Br2 (1:1 mol) C 2 H 6 + Br2 askt C. 2. D. 1.

S phn ng to ra C2H5Br l A. 4. B. 3.
Cu 34: Tin hnh hai th nghim sau: - Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M; - Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so vi V2 l A. V1 = V2. B. V1 = 10V2. C. V1 = 5V2. D. V1 = 2V2. Cu 35: Polime c cu trc mng khng gian (mng li) l A. PE. B. amilopectin. C. PVC. D. nha bakelit. Cu 36: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l A. S. B. As. C. N. D. P. Cu 37: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. C. nc Br2. D. H2 (Ni, nung nng). Cu 38: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 4. C. 2. D. 5. Cu 39: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Cu 40: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 3. B. 6. C. 5. D. 4. Cu 41: Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht: A. K3PO4, K2HPO4. B. K2HPO4, KH2PO4. C. K3PO4, KOH. D. H3PO4, KH2PO4. Cu 42: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomiat. B. etyl axetat. C. n-propyl axetat. D. metyl axetat. Cu 43: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 85. B. 68. C. 45. D. 46. Cu 44: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch D. NH3(d). A. NaOH (d). B. HCl (d). C. AgNO3 (d). PHN RING __________ Th sinh ch c lm 1 trong 2 phn: phn I hoc phn II __________ Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50): Cu 45: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. Cu 46: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 1,0 lt. B. 0,6 lt. C. 0,8 lt. D. 1,2 lt. Cu 47: Cho cc phn ng: (1) O3 + dung dch KI
t (3) MnO2 + HCl c Cc phn ng to ra n cht l: A. (1), (2), (3). B. (1), (3), (4). o
t (2) F2 + H2O o
(4) Cl2 + dung dch H2S C. (2), (3), (4). D. (1), (2), (4).
Cu 48: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H6. B. C2H4. C. CH4. D. C3H8. Cu 49: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin. Cu 50: Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4; - Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 1. B. 2. C. 4. D. 3. Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56): Cu 51: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl(vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol. Cu 52: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 1. B. 3. C. 2. D. 4. Cu 53: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc ln thu ngn ri gom li l A. vi sng. B. ct. C. mui n. D. lu hunh. Cu 54: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. Cu 55: Cho sut in ng chun Eo ca cc pin in ho: Eo(Cu-X) = 0,46V; Eo(Y-Cu) = 1,1V; Eo(Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Z, Y, Cu, X. B. X, Cu, Z, Y. C. Y, Z, Cu, X. D. X, Cu, Y, Z. Cu 56: Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l A. 13,1 gam. B. 17,0 gam. C. 19,5 gam. D. 14,1 gam.
-----------------------------------------------
----------------------------------------------------- HT ----------
P N THI TUYN SINH I HC, CAO NG NM 2008 Mn: HA HC, khi B
Cu s 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32.
195
D C A C D A A B B D B A B D B B A B D D C A D A D C C D B A C D
268
B A B D D D D A D C A C A A D B C C A C B C B C D B A C B D A D
M thi 371 402

B D B C D D B B A C D D A D D A B D C C D A A C A B C A B C B B D D C A B A B A B B D C A A B C B D A B D B D C B C C A D A D B
659
D A C D D D C B C A B D C A C C C B A C C A C B D D B D C A A A
836
C B A C B D A D A A B D B A D B C A B C B D A D C B A A D B D A
Cu s 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56.
195
B A D C C C A D B A C B D C A A C B C B D C B A
268
D C D A B A B A D A B D A D C B B C B C B C C A
M thi 371 402

B A A C C D D D C D A B C B D B C C C A B A A A D D C C B D B A B D B C D A C A A C A C C C A D
659
A D A A B A A D C C A B B B D B B D D B B B D C
836
B C C D A B D D C A D C C A D C B C C B A D B C

156311177 Đề thi Đap an thi ĐH mon Hoa học Khối A B BGD ĐT 2008 2013

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156311177 Đề thi Đap an thi ĐH mon Hoa học Khối A B BGD ĐT 2008 2013

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B GIO DC V O TO

Y + Z; X + NaOH (dung dch)

; (vi C6H5 l gc phenyl) C. (d). D. (c).

Trang 6/6 - M thi 193

Trang 4/6 - M thi 296

B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

Trang 6/6 - M thi 296

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi A

H, tn th sinh: .......................................................................... S bo danh: ............................................................................

Trang 2/6 - M thi 273

Trang 3/6 - M thi 273

Trang 4/6 - M thi 273

Trang 5/6 - M thi 273

Trang 6/6 - M thi 273

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2011 Mn: HO HC; Khi: A

H, tn th sinh: .......................................................................... S bo danh: ............................................................................

Cu 8: Cho s chuyn ho:

Trang 2/6 - M thi 253

Trang 3/6 - M thi 253

Trang 5/6 - M thi 253

Trang 6/6 - M thi 253

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2010 Mn: HO HC; Khi: A

Trang 2/6 - M thi 175

Trang 4/6 - M thi 175

Trang 5/6 - M thi 175

Trang 6/6 - M thi 175

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2009 Mn: HO HC; Khi: A

M thi 438 596

M thi 438 596

Trang 2/5 - M thi 263

Trang 3/5 - M thi 263

Trang 4/5 - M thi 263

C. Cu2S, CuO. C. SO2 v NO2.

D. Cu2S, Cu2O. D. CO v CO2.

Trang 5/5 - M thi 263

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC, CAO NG NM 2008 Mn: HA HC, khi A

M thi 518 605

M thi 518 605

Trang 6/6 - M thi 279

Trang 5/5 - M thi 359

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2012 Mn: HO HC; Khi: B

H, tn th sinh: .......................................................................... S bo danh: ............................................................................

Trang 2/6 - M thi 153

Cl chim 24,23% tng s nguyn t, cn li l

HT ---------Trang 6/6 - M thi 153

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2011 Mn: HO HC; Khi: B

H, tn th sinh: .......................................................................... S bo danh: ............................................................................

Trang 1/6 - M thi 174

Trang 3/6 - M thi 174

(III) FeO (r) + CO (k) Fe (r) + CO2 (k);

xt, t +Z 2 C 2 H 2 X Y Cao su buna-N. Pd, PbCO3 t o , xt, p

Trang 4/6 - M thi 174

Trang 6/6 - M thi 174

B GIO DC V O TO CHNH THC

P N THI TUYN SINH I HC NM 2010 Mn: HO HC; Khi: B

Trang 3/6 - M thi 148