.

..: 07006

, 2012



.
.
.

,
.
.


1. ........................................................................................................... 6
2. E ....................................................................................... 9
2.1

.......................................................................................... 10

2.1.1 ............................................................... 10
2.1.2 ............................................................................. 10
2.1.3 ................... 10
2.1.4 () ......... 11
2.1.5 Stirling .............................. 13
2.1.6 ..................... 14
2.2 .......................................................................................... 17
2.2.1 .............................................................. 17
2.2.2 ..................................................................... 18
2.3 ........................................................................ 21
2.3.1 ................................................ 21
2.3.2 ............................................................................. 21
2.3.3 ...................................................................................... 23
2.3.4 ..................................................................................... 24
2.3.5 ................................................................. 26
2.4 .................................................................................. 29
2.4.1 .......................................................... 29
2.4.2 ..................................................................................... 29
2.4.3 ......................... 32
2.5 ......................................................................................................... 34

3.

2.5.1 .............................................................................. 34
2.5.2 ........................................................................... 34
2.5.3 ................................................................................ 36
..................................................... 37
3.1

...................................................................................... 38

3.1.1 (PEMFC) ....... 38

3.1.2 (AFC) ........................................................ 40
3.1.3 (PAFC) ....................................... 41
3.1.4 (MCFC) ..................... 42
3.1.5 (SOFC) .......................................... 43
3.2 ................................................................................. 44
3.2.1
3.2.2
3.2.3
3.2.4

......................................... 44
() ....... 45
.............................................. 45
............................................ 46

3.2.5 ............................................ 46
3.2.6 ............................. 47
3.3 .............................................................................. 49
3.3.1
3.3.2
3.3.3
3.3.4

4.

.................................................. 50
................................................... 50
............................................................... 52
............................................................................. 53
.............................................................. 55
4.1

................................................ 55

4.1.1 ..................................................................................... 55
4.1.2 ...................................................... 56
4.2 ............................................... 56
4.3

........................................................... 57

4.3.1
4.3.2
4.3.3
4.3.4

5.

......................................................... 57
..................................................... 57
............................................. 58
....................................................... 59
.... 61

6. - ......................................................................... 70
7. .................................................................................................. 73

 &
1 " " ................................................................................... 7
2 " " ........................................................................................ 10
3 " " ..................................................................................... 11
4 " " ........................................................................................................ 11
5 " " ............................................ 13
6 " Stirling" ........................................................................................................... 13
7 " " ......................................................................................................... 15
8 " " ......................................................................... 15
9 " " ....................... 16
10 " " ................................................................. 18
11 " " ............................................................. 19
12 " " ........................................................ 20
13 " " ............................................................................... 21
14 " " .................................................. 23
15 " " ....................................................................... 24
16 " Wave dragon system" ......................................................................................................... 25
17 "Pelamis wave energy converter" ......................................................................................... 25
18 " " .............................................................................................. 26
19 " " .................................................................................. 27
20 " " .............................................................. 28
21 " " ....................................... 30
22 " " .................................................................... 31
23 " " ................................................................... 31
24 " " .................................................................. 32
25 " " .................................................................. 33
26 " " ........................................................... 33
27 " " ......................... 35
28 " " ...................................................................................... 36
29 " PEMFC" .................................................................................................. 38
30 " AFC" ........................................................................................................ 40
31 " PAFC" ..................................................................................................... 41
32 " MCFC" .................................................................................................... 42
33 " SOFC" ..................................................................................................... 43
34 " " .......................................................................................... 47
35 " Hoffman" .......................................................................................................... 48
36 " " ............................................ 51
37 " Gratzel" ....................................................................................... 56
38 " " .................................. 59
39 " " ......................... 61
40 " " ........................... 62
41 " " ..................................... 63
42 " " ..................................................................................... 64
43 "GM HydroGen4" ................................................................................................................. 65

 44 "Toyota FCHV" ..................................................................................................................... 65

45 "Honda FCX Clarity" ............................................................................................................ 65
46 " " ........................................................................... 67
47 "H2moves.eu" ........................................................................................................................ 67
48 "Clean Hydrogen in European Cities" .................................................................................. 67
49 "Adel" .................................................................................................................................... 68
50 "Hydrosol 3D" ....................................................................................................................... 68

1 " 2011".................................................................. 6
2 " , " ................................................... 37
3 " " ......................................................................... 39
4 " FCH JU" .......................................................................................... 69

1.

.

, .


[1].
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7.
[1] T. Bak, J. Nowotny, M. Rekas, C.C. Sorrell, Review article Photoelectrochemical hydrogen generation from water using solar energy.
Materials-related aspects, International Journal of Hydrogen Energy, Vol.
27, Issue 10, Pages 991-1022, October 2002
[2] Carla Emery. : http://www.carlaemery.com/fossil-fuel.htm
[3] Wikipedia. :
http://el.wikipedia.org/wiki/__
[4] Concentrating Solar Power Systems. :
http://www.residentialsolarpanels.org/concentrating-solar-power-systems
[5] : http://africabusiness.com/2010/12/01/concentrating-solarpower/
[6] Solar Energy Topics. :
http://www.solarenergytopics.com/solar/parabolic_dish.html
[7] Wikipedia. : http://en.wikipedia.org/wiki/Solar_power_tower
[8] Climate Progress. :
http://thinkprogress.org/romm/2011/01/16/207337/how-to-use-solar-energyat-night-concentrated-solar-thermal-power-with-storage/
[9] . : http://www.solar-systems.gr/solar-panelpv-1.html
[10] Solar Power. : http://solarpower.com/how-does-solar-powerwork/
[11] World Wind Energy Association. : http://www.wwindea.org/
[12] . :
http://www.cres.gr/kape/index_gr.htm
[13] Wikipedia. : http://en.wikipedia.org/wiki/Wind_turbine
[14] Alternative energy news. : http://www.alternative-energynews.info/technology/wind-power/
[15] . :
http://offshorewind.net/Other_Pages/Turbine-Foundations.html
[16] Wikipedia. :
http://en.wikipedia.org/wiki/List_of_largest_power_stations_in_the_world
[17] . , : ,
2009
[18] Wikipedia. : http://en.wikipedia.org/wiki/Hydroelectricity
[19] Leo Rodrigues, Article Wave power conversion systems for electrical energy
production, Department of Electrical Engineering, Faculty of Science and
Technology of Nova University of Lisbon, March 2008
[20] Wikipedia. : http://en.wikipedia.org/wiki/Tidal_power

73

[21] Tidal power. :

http://www.esru.strath.ac.uk/EandE/Web_sites/0102/RE_info/Tidal%20Power.htm
[22] Ingvar B. Fridleifsson, Review article Geothermal energy for the benefit of
the people, Renewable and Sustainable Energy Reviews, Vol. 5, Issue 3,
Pages 299-312, September 2001
[23] Wikipedia. :
http://en.wikipedia.org/wiki/Geothermal_heat_pump
[24] Geoexchange. : http://www.geoexchange.gr/geothermia.php
[25] Ronald DiPippo, Geothermal energy Electricity generation and
environmental impact, Energy Policy, Vol. 19, Issue 8, Pages 798-807,
October 1991
[26] Kamil Erkan, Gwen Holdmann, Walter Benoit, David Blackwell, Review
article Understanding the Chena Hot Springs, Alaska, geothermal system
using temperature and pressure data from exploration boreholes,
Geothermics, Vol. 37, Issue 6, Pages 565-585, December 2008
[27] Peter McKendry, Review article Energy production from biomass (part 1):
overview of biomass, Bioresource Technology, Vol. 83, Issue 1, Pages 3746, May 2002
[28] Peter McKendry, Review article Energy production from biomass (part 2):
conversion technologies, Bioresource Technology, Vol. 83, Issue 1, Pages
47-54, May 2002
[29] Odile Bertoldi, Sebastien Berger, Article Report on Energy, Draft Version,
European Commission, ObservatoryNANO, August 2009
[30] . ,
, ,
, , 2007
[31] Wikipedia. : http://en.wikipedia.org/wiki/Fuel_cell
[32] Bellona Hydrogen Report. :
http://www.interstatetraveler.us/Reference-Bibliography/BellonaHydrogenReport.html
[33] Wikipedia. : http://en.wikipedia.org/wiki/Hydrogen_production
[34] Wikipedia. :
http://en.wikipedia.org/wiki/Plasma_arc_waste_disposal
[35] Wikipedia. : http://en.wikipedia.org/wiki/Electrolysis_of_water
[36] Wikipedia. : http://en.wikipedia.org/wiki/Hydrogen_storage
[37] , "

, ,
, , 2009

74

[38] Meng Ni, Dennis Y.C. Leung, Michael K.H. Leung, K. Sumathy, Review
article An overview of hydrogen production from biomass, Fuel Processing
Technology, Vol. 87, Issue 5, Pages 461-472, May 2006
[39] Hydrogen Energy and Fuel Cells: A vision of our future, Community
Research of the Europen Commission, 2003
[40] Raimund Bleischwitz and Nikolas Bader, The Policy for the Promotion of
Hydrogen and Fuel Cells in Europe: a Critical Assessment, Bruges European
Economic Policy briefings, No 19, September 2008
[41] Wikipedia. :
http://en.wikipedia.org/wiki/Category:Hydrogen_cars
[42] Fuel Cell and Hydrogen technologies in Europe, Financial and technology
outlook on the European sector ambition 2014-2020, 2011

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