2554

20-21 2554

(PLA) (PHBV)
Preparation of Poly(lactic acid) and (Poly[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyvalerate]
(PHBV) blends for Textile Industrials
1* 1 1 2
1 1 1
1
2

39 1 12110
E-mail: spiva@yahoo.com*

(PLA) (PHBV)


180-190 C 80 /
PLA:PHBV 100:0, 90:10, 80:20, 70:30, 60:40, 50:50
0:100 g/mol
6000 4000 2, 4, 6, 8 10 phr



PLA:PHBV 100:0, 95:5, 90:10, 85:15 80:20
210 235 C
9
450, 500 550 /


PLA:PHBV (80:20) PEG

2 PLA PHBV
151 168 C PEG
4000 g/mol

PLA:PHBV (80:20) PEG 4 phr

4000 g/mol Sonic velocity Modulus
1.79 C 36.82 grams/denier E

1.









(Polylactic acid, PLA)
(Polylactide)

(Ring-opening polymerization) 2 D- L-
PDLA PLLA
D- L- Poly(dl-lactide) PDLLA
(Methyl group)
Syndiotactic Atactic
PLLA PDLA

PDLLA PDLLA
PLLA
PDLA
Nature
Works PDLLA
PLLA PDLA [6,9]
( Poly[( R) -3hydroxybutyrate-co-( R) -3-hydroxyvalerate]) ( PHBV)
(Polyhydroxy alkanoate, PHA)
1160

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20-21 2554

Poly-3-hydroxybutyric acid (PHB) Poly-3hydroxyvaleric acid (PHV) PHB PHV

(glucose)
(Propionic acid) Tm 143 Tg
-4 C


[1]

( Poly[( R) -3-hydroxybutyrate-co-( R) -3hydroxyvalerate] ( PHBV)

[7-8]
2.
2.1
PLA 3001D Nature work co.,
Ltd 1.26 g/cm3 4-8 g/10
min 120,000 g/mol Tg
51 and 150 oC
PHBV
Y100P ENMAT co., Ltd , 900 MPa Tg
5-150 oC
2.2 PLA/PHBV
PLA:PHBV
100:0, 90:10 80:20, 70:30, 60:40, 50:50 0:100
(% ) PLA PHBV
80 oC 8

Hopper Die 180 190 oC
80 /

80 oC 8

PLA:PHBV
20200.03 cm
150 g 230 oC
4
6



Fourne Modular Melt Spinning

Machine PLA 3001D

PHBV Y100P
80 oC
12

(Dry-air Chip Dryer)

DSC

200, 220, 230 (Zone Extruder) 235 (Connecter) 235 C
(Die) 8 , Spin Pack
5 ( 0.5 mm (L/D = 2))


(Draw) 3:1
25 m/min
70 oC 75
m/min 1

1 ) )
Fourne Modular
Melt Spinning
2.3

PLA:PHBV 100:0, 90:10 80:20, 70:30, 60:40, 50:50
0:100 (% )
[2] 5-15 mg
(Pan)
30 - 250 oC
mW Heat Flux

2.4
(Melt Flow Index, MFI)
ASTM D 1238-98 [3]
PLA:PHBV 100:0, 90:10 80:20, 70:30, 60:40, 50:50
0:100 (% )
190 oC Piston 2.16 Kg

10 MFI
g/10min
[3-4]
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2.5
(Tensile Strength)
(Impact Strength)
PLA:PHBV 100:0, 90:10 80:20, 70:30, 60:40, 50:50
0:100 (% ) ASTM D 638-84
[3-5] ASTM D 256-84 [4]
3.
3.1

PLA:PHBV
2 (PLA PHBV)
PLA 151 oC
PHBV 175 oC
(Melting Temperature,
Tm) 2
90:10 80:20 PHBV
Tm Tm
PHBV
PLA

Tm

1
PLA/PHBV DSC
Tm (oC)

PLA:PHBV
Peak
Peak
(% )
1 (PLA)
2 (PHBV)
100:0
90:10
80:20
70:30
60:40
50:50
0:100

151.1
152.4
151.6
151.7
150.6
150.7
-

173.0
173.4
174.6
174.7
174.1
174.5

2 DSC
PLA:PHBV
3.2
PLA:PHBV
PHBV PLA PLA
8.46 g/10min
PHBV
PHBV PLA
2

PLA
PHBV
PLA Tm PHBV
PLA PHBV
PLA

3
PLA/PHBV
2
PLA/PBSA/PBAT PLA
49.03 MPa PHBV
10.24 MPa PHBV
PLA 2
PHBV
2
60:40 50:50
PLA:PHBV




DSC
2
2
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20-21 2554

PLA
PHBV PLA
3.18% PHBV
4.66% [10] PHBV
PHBV

2

60:40 50:50
2


PLA 2147.10
MPa PHBV 467.83 MPa
2
PHBV 90:10
80:20
2 PLA:PHBV

PLA:PHBV

(%) (MPa)
PLA
90:10
80:20
70:30
60:40
50:50
PHBV

49.03
43.58
35.27
37.38
26.28
24.6
10.24

(%)
3.18
2.91
2.34
2.80
2.69
2.77
4.66

(MPa)
2147.10
2106.10
2054.31
1869.45
1536.47
1419.95
467.83

4.
DSC
PLA:PHBV PLA Tm
151 oC PHBV Tm 175 oC
90:10 80:20
Tm
PLA 8.46
g/10min 90:10 80:20
(% ) 9.24 12.72 g/10min
PLA:PHBV (80:20) PEG
2, 4, 6, 8 10 phr
PEG 4 phr 4000 g/mol
12.78 g/10min

PLA:PHBV 90:10 80:20 43.58

MPa 35.27 MPa
2.91% 2.34%
2106.10 MPa 2054.31 MPa




2552

[1] . 2549.
. : .
[2] . 2545.
. :

[3] . Testing.2553.

[4] . 2544.

. :

[5]
(2547)
:
(- )
[6] D.S.Rosa,C.G.F.Guedes,C.M.Oliveira,M.I Felisberti,
Processing and Properties of Mixtures
of PHB-V with Post-consumer LDPE. J Polymer
Environ (2008) 16:230-240
[7] Wan Meng,Zhi-Cai Xing,Kyung-Hye Jung,Se-Yong
Kim,Jiang Yuan,Inn-kyu Kang,Sung Chul Yoon,Hong In
Shin, Symthesis of gelatin-containing PHBV nanofober
mats for biomedical application.J Mater Sci:Mater Med
(2008) 19:2799-2807.
[8] Soma Pal Shaha,A.Patra,A.K.Paul.2007.Studies on
intracellular degradation of polyhydroxyalkanoic acidpolyethylene glycol copolymer accumulated by
Azotobacter chroo coccum MAL-201. Journal of
BioTechnology 137.pp325-330.
[9] B.M.P.Ferreira,C.A.CZavaglia,E.A.R.Duek.2002.Films
of PLLA/PHBV Thermal morphological and mechanical
characterization. Journol of Applied Polymer
Science.Vol 86.Issue 11.pp 2898-2906.
[10] Derval dos Santos Rosa. Maria Regina Colil. Critina
das Gracas. Fassina Guedes and Tulio Redrigues.
1163

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Biodegradability of thermally Aged PHB, PHB-V and

PCl in soil compostage. Universidade Sao Francisco,
Rua Alexandre Brabosa, Brazil. Journol of Applied
Polymer Science.Vol.12, No.4, October 2004, pp.293245.

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