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TRNG CHUYN THPT L QU N

THI TH I HC LN TH NHT MN: HO HC

Thi gian lm bi: 90 pht;
M thi 132

thi c 5 trang

H, tn th sinh:.......................................................................... S bo danh:...............................................................................
Hc sinh nh ghi m thi vo t giy lm bi thi Cho bit khi lng mol nguyn t ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P=31; S = 32; Cl = 35,5; K = 39; Ca = 40; Mn=55; Cr = 52; Fe = 56; Cu = 64; Zn=65; Rb = 85; Sr = 88; Br = 80; Ag = 108; Sn = 119; I=127; Cs = 133; Ba = 137; Pb=207. -------------------------------------------------------------------------------------------------------------------------Cu 1: T C2H4, cht v c v iu kin y . S phn ng t nht to thnh natri axetat v etylen glicol l A. 6 B. 3. C. 4. D. 5. Cu 2: C cc pht biu sau: (1) S, P, C2H5OH u bc chy khi tip xc vi CrO3. (2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5. (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. S pht biu ng l A. 2 B. 4 C. 3 D. 1 Cu 3: in phn dd cha hn hp CuSO4 v KCl vi in cc tr, mng ngn xp, khi thy kh thot ra 2 in cc th ngng li thy c 448 ml kh (kc) thot ra anot. Dung dch sau in phn c th ha tan ti a 0,8 gam MgO. Khi lng dd sau in phn gim bao nhiu gam? A. 1,03 gam B. 2,89 gam C. 2,7 gam D. 2,95 gam Cu 4: Cho cc cht sau phn ng vi nhau tng i mt: dd HCl, dd CrCl3, dd NaOH, dd NH3, Cr2O3. S lng cc cp cht xy ra phn ng trong iu kin c l A. 6. B. 8. C. 7. D. 9. Cu 5: Pht biu no sau y l ng? A. Ancol o-hiroxibenzylic l sn phm trung gian trong qu trnh iu ch nha novolac t phenol v fomanehit. B. T nilon-6,6 thuc loi t poliamit, c iu ch bng phn ng ng trng hp cc monome tng ng. C. T visco, t xenluloz axetat, t nitron cng thuc loi t nhn to. D. Cao su buna-S thu c khi cho cao su buna tc dng vi lu hunh. Cu 6: Cho cc qu trnh ha hc : 1. Sc kh H2S vo dung dch FeCl3 2. Dung dch AlCl3 tc dng vi dung dch Na2S 3. Hidrat ha C2H4 4. Nhit phn CaOCl2 5. KF tc dng vi H2SO4 c, nng 6. in phn dung dch NaCl 7. Al4C3 tc dng vi dung dch HCl 8. n mn gang, thp trong khng kh m C bao nhiu qu trnh xy ra phn ng oxi ha kh? A. 7 B. 6 C. 5 D. 4 Cu 7: Cc cht kh sau: SO2, NO2, Cl2, N2O, H2S, CO2. Cc cht kh khi tc dng vi dung dch NaOH ( nhit thng) lun to ra 2 mui l A. SO2, CO2, H2S B. NO2, SO2 , CO2 C. Cl2, NO2 D. CO2, Cl2, N2O Cu 8: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l

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A. 137,1. B. 151,5. C. 97,5. D. 108,9. Cu 9: n cht kim loi Crom c cu trc tinh th vi phn rng trong tinh th chim 32%. Khi lng ring ca kim loi crom l 7,19 gam/cm3. Bn knh nguyn t crom (tng i )l( 1Ao = 10-8 cm) A. 1,2.10-8 cm B. 1,25A0 C. 1,68A0 D. 1,5.10-10m Cu 10: Ly 0,3 mol hn hp X gm H2NC3H5(COOH)2 v H2NCH2COOH cho vo 400 ml dung dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M thu c dung dch Z. Lm bay hi Z thu c m gam cht rn khan, gi tr ca m l A. 28,8 gam B. 31,8 gam C. 61,9 gam D. 55,2 gam Cu 11: Cht no dng nhn bit ra cc cht ring bit Na, Al, Mg, Al2O3 v trong qu trnh nhn bit chng cn dng ti thiu bao nhiu phn ng? A. dd Na2CO3 v 4 phn ng. B. dd NaOH v 2 phn ng. C. H2O v 3 phn ng. D. H2O v 2 phn ng. Cu 12: Cho cc cht sau: Al(OH)3, CH3COOH; K2S, H2O, NaHCO3, Zn(OH)2, Al, KHSO4, Zn, (NH4)2CO3. S cht c tnh lng tnh theo Bronsted l A. 7 B. 6 C. 5 D. 4 Cu 13: Cho m gam hn hp G gm Al, Fe, Cu, Mg nung trong bnh cha oxi sau mt thi gian thu c 2,63 gam hn hp H. Ha tan ht H trong dung dch HNO3 d, thu c 0,448 lt kh NO (sn phm kh duy nht, ktc ). S mol HNO3 tham gia phn ng l 0,14 mol, gi tr ca m l. A. 2,15 B. 2,36 C. 2,42 D. 2,47 Cu 14: Cho kh CO2, dung dch KHSO4 vo hai ng nghim cha dung dch natri phenolat. Cho dung dch NaOH, dung dch HCl vo hai ng nghim cha dung dch phenylamoni clorua. Hin tng dung dch b vn c s xy ra A. 3 ng nghim. B. 1 ng nghim. C. C 4 ng nghim. D. 2 ng nghim. Cu 15: Thc hin phn ng nhit nhm (khng c khng kh) m gam hn hp X gm Al v Fe3O4, hiu sut 100%. Chia cht rn Y thu c lm 2 phn, phn 1 c khi lng nh hn phn 2. Cho phn 2 tc dng dd HCl d, thu c 9,828 lt H2(kc). Nu bit phn 1 c cha 3,78 gam Fe, 3,06 gam Al2O3 v 1,4175 gam Al th gi tr ca m l A. 22,02 B. 43, 875 C. 16,51 D. 33,03 Cu 16: m gam Fe ngoi khng kh mt thi gian thu c 6,24 gam cht rn X gm Fe v cc oxit. Ho tan ht X trong 130 ml dd HNO3 4M(va ) thu c kh NO2(sn phm kh duy nht). Cho dd sau phn ng tc dng vi dd NaOH d, lc kt ta, em nung n khi lng khng i c a gam cht rn Y. Gi tr m v a ln lt l A. 5,6 v 8 gam B. 5,6 v 12 gam C. 11,2 v 12 gam D. 11,2 v 8 gam Cu 17: Cho cc pht biu sau: 1.Nguyn t cc nguyn t halogen u c 7 electron lp ngoi cng. 2.Cc nguyn t halogen ch c s oxi ha -1 trong m i hp cht. 3.Cc nguyn t halogen c m in gim dn theo th t: F > Cl > Br > I. 4.Cc hidro halogenua u l nhng cht kh, dung dch ca chng trong nc u c tnh axit mnh. 5.Tnh kh ca cc hidro halogenua tng dn theo th t: HF < HCl < HBr < HI. 6.Cc mu i bc halogenua u khng tan trong nc. 7.Trong t nhin cc halogen tn ti ch yu dng n cht. S pht biu sai l A. 2 B. 3 C. 5 D. 4 Cu 18: Cho hn hp X gm C3H7COOH, C4H8(NH2)2, HO-CH2-CH=CH-CH2OH. t chy hon ton m gam hn hp X, sn phm chy hp th hon ton vo dung dch Ca(OH)2 thy to ra 20g kt ta v dung dch Y. un nng dung dch Y thy xut hin kt ta. C cn dung dch Y ri nung cht rn thu c n khi lng khng i thu c 5,6 gam cht rn. Gi tr ca m l A. 8,2 B. 5,4 C. 8,8 D. 7,2

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Cu 19: C cc ha cht: K2Cr2O7, HCl, KMnO4, MnO2, NaCl, HClO, H2SO4, KClO3. Nhng ha cht c s dng iu ch Cl2 trong phng th nghim l A. K2Cr2O7, HCl, KMnO4, MnO2, KClO3. B. K2Cr2O7, HCl, KMnO4, MnO2, NaCl, HClO. C. K2Cr2O7, HCl, KMnO4, MnO2, NaCl, HClO, H2SO4. D. K2Cr2O7, HCl, KMnO4, MnO2, HClO. Cu 20: ng vi cng thc phn t C3H6O2 c x ng phn lm qu tm ha ; y ng phn tc dng c vi dd NaOH, nhng khng tc dng vi Na; z ng phn tc dng c vi dd NaOH v dd AgNO3/NH3 v t ng phn va tc dng c vi Na, va tc dng c vi dd AgNO3/NH3. Khng nh no sau y khng ng? A. z = 0 B. y = 2 C. x = 1 D. t = 2 Cu 21: Cho (1) Etanol; (2) Vinylaxetylen; (3) Isopren; (4) 2-phenyletanol-1. Tp hp no c th iu ch c cao su buna-S bng 3 phn ng? A. (3)+(4). B. (2)+(3). C. (1)+(3). D. (1)+(4). Cu 22: Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s este c th iu ch trc tip bng phn ng ca axit v ancol tng ng (c H2SO4 c lm xc tc) l A. 5 B. 3 C. 4 D. 2 Cu 23: Mt hn hp gm axit no n chc X v ancol no n chc Y c khi lng phn t bng nhau. Chia hn hp ra 2 phn bng nhau: Phn 1 tc dng vi Na d thu c 0,56 lt H2. t chy hon ton phn 2 sinh ra 2,688 lt kh CO2. CTPT v phn trm khi lng X, Y trong hn hp l (cc th tch kh o ktc) A. HCOOH 40% ; C2H5OH 60% B. CH3COOH 40% ; C3H7OH 60% C. CH3COOH 60% ; C3H7OH 40% D. HCOOH 60% ; C2H5OH 40% Cu 24: t chy hon ton hn hp Q gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch Ca(OH)2 0,02M thu c kt kt ta v khi lng dung dch tng 3,78 gam so vi ban u. Cho dung dch Ba(OH)2 va vo dung dch thu thm kt ta. Tng kt ta 2 ln l 18,85 gam. Bit rng s mol ca X bng 60% tng s mol ca X v Y c trong hn hp Q. Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l A. C4H6 v C2H2 B. C2H2 v C3H4 C. C2H2 v C4H6 D. C3H4 v C2H6 Cu 25: Cho m gam Fe tan ht trong 400ml dung dch FeCl3 1M thu c dung dch Y. C cn dung dch Y thu c 71,72 gam cht rn khan. ho tan m gam Fe cn ti thiu bao nhiu ml dung dch HNO3 1M (bit sn phm kh duy nht l NO)? A. 320 ml. B. 160 ml. C. 480 ml. D. 540 ml. Cu 26: Cho cc cht sau y phn ng vi nhau: (1) SO2 + Br2 + H2O (2) Br2 + HI (3) Br2 + H2O
(4) Cl2 + Br2 + H2O (6) PBr3 + H2O (4) Br2 + I2 + H2O (5) H2S + Br2
t (7) NaBr (rn) + H2SO4 (c)
o

S trng hp khng to ra HBr l A. 3 B. 2 C. 4 D. 1 Cu 27: Hn hp M gm axit X, ancol Y v este Z c to ra t X v Y, tt c u n chc; trong s mol X gp hai ln s mol Y. Bit 17,35 g M tc dng va vi dd cha 0,2 mol NaOH, ng thi thu c 16,4 g mui khan v 8,05 g ancol . Cng thc X, Y, Z l A. HCOOH, C3H7OH, HCOOC3H7. B. CH3COOH, C2H5OH, CH3COOC2H5. C. CH3COOH, CH3OH, CH3COOCH3. D. HCOOH, CH3OH, HCOOCH3. Cu 28: Trong cc cht sau: HCHO, CH3Cl, CH3COOCH3, CH3ONa, CH3OCH3, CO, CH2Cl2 c bao nhiu cht to ra metanol bng 1 phn ng ? A. 3 B. 6 C. 4 D. 5 Cu 29: Cht hu c Y1 trong phn t ch cha mt loi nhm chc, c phn trm khi lng C v H tng ng bng 49,315% v 6,85%, cn li l oxi. T khi hi ca Y1 so vi khng kh xp x bng

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5,034. Cho Y1 tc dng vi dung dch NaOH, sinh ra mt mui (Y2) v mt ancol (Y3). Nung mui Y2 vi hn hp vi ti xt thu c mt hirocacbon n gin nht. Cng thc Y2 v Y3 ln lt l A. NaOOCCH2COONa v CH3OH. B. CH3COONa v CH3CH2CH2OH C. CH3COONa v HOCH2CH2OH D. HCOONa v HOCH2CH2CH2CH2OH Cu 30: mnh tnh axit c xp tng dn theo dy sau : A. CH3COOH < HCOOH < H2CO3 < HClO B. H2CO3 < CH3COOH < HCOOH < HClO C. HCOOH < CH3COOH < H2CO3 < HClO D. HClO < H2CO3 < CH3COOH < HCOOH
CH 2 =CH CH 3 ( xt ) 1.O2 H 2O , H + HCN H 2 SO4 Cu 31: Trong s : Benzen A B D E F. 2. H O , H +
2 +

F l A. axeton B. axit metacrylic C. axit acrylic D. axit propionic Cu 32: Cho 200 ml dung dch X gm Ba(OH)2 0,5M v Na[Al(OH)4] 1,5M. Thm t t dung dch H2SO4 0,5M vo dung dch X cho n khi kt ta to thnh b tan mt phn, phn kt ta cn li em nung n khi lng khng i thu c 24,32 gam cht rn Z. Th tch dung dch H2SO4 dng l A. 0,67 lt. B. 1,1 lt C. 0,55 lt. D. 1,34 lt. Cu 33: Cho s bin ha sau: Al X Y Z Al. X, Y, Z ln lt l A. Al2(SO4)3, AlCl3, Al(OH)3 B. AlCl3, Al(OH)3, Al2O3 C. Al(NO3)3, AlCl3, Al2O3 D. Al(NO3)3, NaAlO2, Al2O3 Cu 34: Cho m gam hn hp bt X gm a mol Fe2O3, a mol Fe3O4, a mol FeO. Nu ho tan m gam X bng V lt dd HCl 2M th va . Nu dn 1 lung kh CO d qua ng s nung nng cha m gam X th phn ng xong ch cn li 33,6 gam Fe. Gi tr ca V l A. 0,8 B. 1,0 C. 1,2 D. 0,6 Cu 35: Hn hp A gm 1 ankan v 1 anken, t chy A thu c a mol H2O v b mol CO2. Hi t s T = a / b c gi tr trong khong no? A. 1 < T < 1,5 B. 1,5 < T < 2 C. 0,5 < T < 2 D. 1 < T < 2 Cu 36: Cho cc nhn nh sau: 1.Cc dd glixin, alanin, lysin u khng lm i mu qu. 2. Lin kt peptit l lin kt to ra gia 2 n v - aminoaxit 3. Cho Cu(OH)2 /NaOH vo dd protein s xut hin mu tm c trng. 4. Peptit l nhng hp cht cha cc gc -amino axit lin kt vi nhau bng nhng lin kt peptit. 5. Protein n gin c to thnh ch t cc -amino axit. 6. Protein phc tp to thnh t cc protein n gin cng vi thnh phn <<phi protein>>. S nhn xt ng l A. 4 B. 6 C. 3 D. 5 Cu 37: Ha tan hon ton hn hp gm Na2O, BaCl2, NaHCO3, KHCO3 c s mol mi cht bng nhau vo nc ri un nng nh. Sau khi kt thc th nghim c dung dch A. Dung dch A c pH A. > 7. B. 0 C. < 7 D. = 7 Cu 38: Cho tan hon ton 8,0 gam hn hp X gm FeS v FeS2 trong dd HNO3 va thu c kh NO v dd Y. Cho dd Ba(OH)2 vo dd Y tc dng ht vi cc cht trong dd Y. Kt ta to thnh em nung ngoi khng kh n khi lng khng i c 32,03 gam cht rn Z. Khi lng FeS2 trong X v th tch kh NO (ktc) thu c l A. 4,4 gam v 1,12 lt. B. 3,6 gam v 6,72 lt. C. 3,6 gam v 3,36 lt. D. 4,4 gam v 2,24 lt Cu 39: C th dng H2SO4 c lm kh c cc kh: A. O2, H2, NO2, H2S, Cl2 B. Cl2, SO2, CO2, NO2, H2S C. O2, H2, SO3, N2 D. N2, H2, SO2,CO2 Cu 40: linh ng ca nguyn t H trong nhm OH ca cc cht: ancol etylic, axit axetic, axit propionic, axit phenic, axit picric c sp xp theo th t tng dn A. ancol etylic, axit axetic, axit propionic, axit phenic, axit picric. B. ancol etylic, axit axetic, axit propionic, axit picric, axit phenic.

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C. ancol etylic, axit phenic, axit propionic, axit axetic, axit picric. D. ancol etylic, axit phenic, axit picric, axit axetic, axit propionic. Cu 41: Khi ng trng hp isopren vi acrilonitrin ta thu c polime B. Khi t chy m gam B bng oxi (va ) thu c hn hp cha 58,33% CO2 v th tch. T l mt xch isopren v acrilonitrin trong polime B tng ng l A. 2:1 B. 1:2 C. 3:1 D. 1:3 Cu 42: X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2? A. 3,375 mol B. 1,875 mol C. 2,8 mol D. 2,025 mol Cu 43: Khi in phn dung dch NiSO4 vi in cc Ni: Cho bit cc trnh no sau y xy ra in cc? A. Catt: S kh ion Ni2+; Ant s oxi ha Ni thnh ion Ni2+. B. Catt: S oxi ha Ni2+ ; Ant: S kh Ni thnh Ni2+. C. Catt: S oxi ha Ni2+ ; Ant: S kh ion H2O sinh ra O2. D. Catot: s kh ion Ni2+ ; Ant: S oxi ha phn t H2O sinh ra O2. Cu 44: un nng hn hp etanol v butan-2-ol vi H2SO4 m c th tng s cc cht: anken v ete ti a c th thu c l A. 4 B. 7 C. 6 D. 5 Cu 45: Trong s cc polime sau: si bng (1), t tm (2), len (3), t visco (4), t enang (5), t axetat (6), t nilon-6,6 (7). S t thuc loi poli peptit v poliamit l A. 3 B. 2 C. 1 D. 4
2 Cu 46: Cho dy bin ha sau: Xiclo propan X1 X2 X3 Khi cho 0,1 mol cht X3 tc dng vi AgNO3 d trong dung dch NH3, un nng th thu c khi lng Ag l A. 43,2 gam B. 10,8 gam C. 21,6 gam D. 32,4 gam Cu 47: Cho cc cht sau tc dng vi nhau trong dung dch

+ Br

+ NaOH du , t 0

+ CuO du ,t 0

1) KI + FeCl3 4) KI + H2O2

2) HI + FeO 5) Pb(NO3)2 + KI

3) KI + O3 + H2O 6) Cl2 + KI

7) KI + K2Cr2O7 + H2SO4 long S phn ng ha hc to ra sn phm I2 l A. 5. B. 4. C. 7. D. 6. Cu 48: x phng ho 10 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi dd cha 1,42 kg NaOH. Sau khi phn ng hon ton, mun trung ho NaOH d cn 500 ml dd HCl 1M. Khi lng x phng nguyn cht to ra l A. 11230,3 gam B. 10365,0 gam C. 10342,5 gam D. 14301,7 gam + Cu 49: Dung dch nc cha 0,005 mol Na ; 0,01 mol Cl ; 0,005 mol Mg2+ ; 0,01 mol Ca2+, a mol HCO3-. Tnh gi tr ca a v xc nh xem sau khi un si mt hi lu, nc cn cng khng ? A. 0,025 ; nc khng cn cng B. 0,025 ; nc cn cng C. 0,0125 ; nc khng cn cng D. 0,0125 ; nc cn cng Cu 50: Hp th ht 4,48(l) buta-1,3-ien(ktc) vo 250ml dd Brom1M, iu kin thch hp n khi brom mt mu hon ton thu c hn hp lng X( ch cha dn xut brom), trong khi lng sn phm cng 1,4 gp 4 ln khi lng sn phm cng 1,2. Khi lng sn phm cng 1,2 trong X l A. 6,42g B. 12,84g C. 1,605g D. 16,05g ---------------------------------------------------------- HT ----------

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P N THI TH I HC LN TH NHT
132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 1 B 2 C 3 D 4 A 5 A 6 C 7 C 8 B 9 B 10 C 11 C 12 C 13 A 14 A 15 D 16 A 17 D 18 C 19 A 20 A 21 D 22 B 23 C 24 C 25 A 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 26 B 27 B 28 D 29 C 30 D 31 B 32 D 33 B 34 A 35 D 36 D 37 A 38 B 39 D 40 C 41 D 42 B 43 A 44 B 45 D 46 A 47 A 48 C 49 B 50 A

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