Compui organici cu sulf

R-SH Thiols (R)3S+ Sulfonium R-SO2H Acides sulfiniques R-S-R Thioethers R-SO-R Sulfoxydes R-SO3H Acides sulfoniques R-S-S-R Disulfures R-SO2-R Sulfones R-SO2Cl Sulfochlorures Ar-SH Thiophenols R-CS-R Thiocetones R-SO2-NH2 Sulfonamides

Tioli i tiofenoli Metode de obinere

R CH=CH2 + H2S H2SO4 R CH CH3 SH

R-X + NaSH  R-SH + NaX R-X + KSCN  R-S-CN + KX R-S-CN + 2H2O  R-SH + CO2 + NH3 NH2 + NH2 H2O/OHXR S C R SH + CO2 + 2NH3 R X + S=C NH2 NH2

R OH + H2S
R OH P 2S5

ThO2

R SH + H2O

R SH [H] R SH + 2H2O + HCl R SO2Cl

Ar SO2Cl

[H]

Ar SH + 2H2O + HCl
Ar SH + KX + N2

Ar N = N X- + KSH

S Ar N = N X + R O C SNa
-

S Ar S C OR + NaX + N2

S OHAr S C OR + H2O Ar SH + COS + R OH

Proprieti chimice
R-SH + NaOH  R-SNa + H2O Ar-SH + NaOH  Ar-SNa + H2O R-SH + (CH3-COO)2Pb  (R-S)2Pb + 2CH3-COOH R-SNa + R-X  R-S-R + NaX
O O R C Cl + R SH R C S R + HCl 2R-SH + I2  R-S-S-R + 2HI

R-SH + [O]  R-SO2H + [O]  R-SO3H

R CH=O + R' SH BF3 R OH R' SH CH R -H2O S R' S R' CH S R'

S CH2 HgCl2 H2C SH + H 2O R CH=O + CH H2C SH S CH2 S CH2 + H2 CH S CH2 Ni

R CH3 + 2NiS + H3C CH3

Tioeteri Metode de obinere

R-X + R-SNa  R-S-R + NaX R-X + R-SNa  R-S-R + NaX R-CH=CH2 + R-SH  R-CH2-CH2-S-R

Proprieti
.. R S .. R' + "R X
.. R S .. R H2O2

R S R'XR"
R S R O O R S R O H2 O2 O R S R O

KMnO4 .. R S .. R

Acizi sulfonici
O HO S OH O O R S OH O O O H3C S OH C6H5 S OH O O acide acide methanesulfonique benzenesulfonique

Metode de obinere
RH + H2SO4(olum)  R-SO3H + H2O R-H + SO2 + 1/2O2 R-SO3H
SO3H + H2O

+ H2SO4

R-X + NaHSO3  R-SO3H + NaX R-X + Na2SO3  R-SO3Na + NaX R-SO3Na + HA  R-SO3H + NaA R-H + Cl2 + SO2  R-SO2Cl + HCl ; R-SO2Cl + H2O  R-SO3H + HCl R-SH + [O]  R-SO2H + [O]  R-SO3H

Proprieti chimice

R-SO3H + H2O ' R-SO3 + H3O+ R-SO3H + NaOH  R-SO3Na + H2O

R-SO3H + RNH2  R-SO3 + RNH3+ Ar-SO3H + H2O  ArH + H2SO4 Ar-SO3H + HNO2  Ar-NO2 + H2O Ar-SO3H + NaOH  Ar-OH (SN) Ar-SO3H + NaSH  Ar-SH (SN) Ar-SO3H + NaNH2  Ar-NH2 (SN) Ar-SO3H + NaCN  Ar-CN (SN) Ar-SO3H + HCOONa  Ar-COOH (SN)

Sulfocloruri
O R S Cl O O Ar S Cl O

Metode de obinere
R-SO3Na + PCl5  R-SO2-Cl + POCl3 + NaCl R-H + Cl2 + SO2  R-SO2Cl + HCl Initiation:
h 2 Cl . Cl Cl Propagation: R . + HCl R H + Cl . R SO . R . + SO
2 2

R SO2. + Cl2 Interruption: R SO . + Cl .

2

R SO2Cl + Cl .

R SO2Cl
R SO2 R

R SO2. + R .

Ar-H + HOSO2Cl  Ar-SO3H + HCl Ar-SO3H + HOSO2Cl  Ar-SO2Cl + H2SO4 Ar-NN]+ Cl + SO2  Ar-SO2Cl + N2

Proprieti chimice
R SO2Cl + H2O B R SO3H + HCl

R SO2Cl + R' OH
R SO2Cl + 2NH3

R SO3 R' + HCl

R SO2NH2 + NH4Cl

R SO2Cl + R' NH2

Ar SO2Cl + Ar H
R SO2Cl [H]

B
AlCl3

R SO2NH R' + HCl

Ar SO2 Ar + HCl

R SH + 2H2O + HCl

Ar SO2Cl

[H]

Ar SH + 2H2O + HCl

Sulfonamide
O R S NH2 O O R S NH R' O O R' R S N O R'
Ar SO2NH2 + NH4Cl

Metode de obinere
Ar SO2Cl + 2NH3

Ar SO2Cl + R NH2
Ar SO2Cl + R2NH

B
B

Ar SO2NHR + HCl
Ar SO2NR2 + HCl

Proprieti chimice
O .. Ar S N .. R O O .. Ar S = N R O
.. + Ar SO2NR .. ] Na + H2O
Ar SO2NHR + NaCl

Ar SO2NHR + NaOH
Ar SO2NR ] Na+ + HCl

Ar-SO2-NH2 + 2Cl2  Ar-SO2-NCl2 + 2HCl Ar-SO2-NCl2 + 2H2O  Ar-SO2-NH2 + 2HOCl

H 2N SO2NH2 H 2N SO2NHR H 2N SO2N