PT Process Manual v1.0 - VN

CNG NGH SN T CHU U: CNG NGH TIN X L
DAIMLER VIET N
G.COPIN: +33 (0)6 75 61 46 46 gcopin@ppg.com Nh my: Thnh ph H Ch Minh
Ch s dy chuyn ca Drr
Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi
S TAY HNG DN K THUT

GIAI ON TIN X L
Bn 1.0
Ngi vit G.COPIN Ngy vit 15/03/2013 Cp nht 15/03/2013 Trang 1/90
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Nh my: Thnh ph H Ch Minh
MC LC
Khu Vc 1 Khu Vc 2 Khu Vc 3 Khu Vc 4 Khu Vc 5 Khu Vc 6 Khu Vc 7 iu Khin T n Su t Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Phng n Cp Nht Phun Ty Du (D1) Nhng Ty Du (D2) Ra Nhng (R1) Ra Nhng (R2) Nhng Zircobond (Zr) Ra Nhng (R3) Ra Nhng (R4) Nc DI Lp Zircobond K Hoch Bo Tr B Kim T Do Cht Ch Th Mu Tng Ga Tr Kim Cht Ch Th Mu Kim T Do / Tng Ga Tr Kim Ph K Ch t H at ng B M t (Tensid) Residual Chemkleen CA Cleaner Load / TOC Cht Rn L Lng (<8m) Tng Ga Tr Kim Ra Nng NO 2 Nng Phosphat Nng Zirconium Nng ng Nng Fluorua Hm Lng Rn L Lng o Quang Ph Hm Lng Rn L Lng Lc Cp Nht S Tay 3 7 11 15 20 25 24 26 27 28 29 30 31 32 35 36 40 41 46 59 70 76 79 85 89
1.1 1.2 1.3 1.4 1.5 1.6 1.7 2.1 2.2 3.1 3.2 3.3 3.4 3.5 3.6
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 2/90
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Khu vc : 1
Th i gian x l
Chc nng: Ty du (D1)

Th tch 20 m3
Phun
Nc Nc DI
Cc thit b b sung: - B trao i nhit - Hydrocyclone - B lc bng (Lc hydrocyclone giai on 1 + 2 ) - Giy lc - Thit b tch du Nng B sung 3 10 Kg/m 200 Kg Chemkleen 166 M A-I707237-JK 7.3 L/m3 145 L 3 1.5 Kg/m 30 Kg A-O707253-JH Chemkleen 171/11 1.5 L/m3 30 L 5 Kg/m3 100 Kg Chemseal 6 3 4.5 L/m 90 L Tham kho bng s liu k thut A-M707201-QH Chemkleen CA Chemkleen CA i vi b ty du mi, b sung ha cht sau khi gia nhit (>50 C) v phi khuy trn u. Thm Chemkleen CA vo h thng tch du khi l ngdung dch ty / TOC tng dn (Khng thm Chemkleen CA nu lng dung dch ty / TOC < 1g/L) Khu vc Cam Thng s kim sot S ln Phng n v Khu vc Xanh n 10.5 11 11.5 12 Ph 1x/ca pH 2 2.5 5 6 Kim t do 1x/ca 1.1 im 17.5 20 Tng ga tr kim 1x/ca 1.2 im 50 52 58 60 Nhit 2x/ca C 1 1.25 2 2.5 Tensid [CK 171/11] 1x/ngy 1.4 g/L Residual chemkleen 0.25 0.5 1x/ngy 1.5 g/L CA 1.5 2 Dung dch ty/ TOC 1x/ngy 1.6 g/L Hm lng rn l 15 20 1x/ngy 1.7 mg/L lng (<8m) iu chnh thng s tng kim t do (+1pt) tngTensid (+0.1g/L) Ngi vit G.COPIN Ha cht Chemkleen 166 M Chemkleen 171/11 Chemkleen 171/11 Ngy vit 15/03/2013 Lng b sung 70Kg / 50L 7Kg / 7L 2Kg / 2L Cp nht 15/03/2013 Trang 3/90 Ha cht M s PPG
G.COPIN:
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Biu Phn ng Ty Du / pH
Chy pH k c chnh thng s li trong ngy
D liu log
Gi tr pH c nm trong vng ?
Kt thc Kim sot bnh thng
KHNG
Ch s thp
Ch s cao
Ch s kim t do thp ?
Ch s kim t do cao?
KHNG
KHNG
Kim tra s ngng kt ca b v tham kho dch v k thut
Tng lng ha cht thm vo
Trung ha vi ph gia acid
Dng thm ha cht
Lin h PPG
Trn thm 30 pht, sau kim tra li
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 4/90
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Biu Phn ng Ty Du / Kim T Do
Chy kim tra kim t do.
D liu log
Gi tr kim t d c nm trong vng?
KHNG
Ch s thp
Ch s cao
Dng thm ha cht
Trn thm 30 pht, sau kim tra li.
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 5/90
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Biu Phn ng Ty Du / Tng Ga Tr Kim
Chy kim tra tng gi tr kim t do.
D liu log
T ng gi tr ki m c n m trong kho ng?
KHNG
Ch s thp
Ch s cao
X b nu cn. Pha long 5% vi nc DI
Trn thm 1 gi, sau kim tra li.
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 6/90
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Khu vc : 2
Chc nng: Ty du (D2)
Nhng
Th i gian x l
Th tch 120 m3
Nc: Nc DI
Cc thit b b sung: - B trao i nhit - Hydrocyclone (X n b lc giai on 1) - Giy lc Nng B sung 15 Kg/m3 1800 Kg Chemkleen 166 M A-O707200-CF 3 11 L/m 1300 L 3 1.5 Kg/m 180 Kg A-O707253-CD Chemkleen 171/11 1.5 L/m3 180 L 5 Kg/m3 600 Kg Chemseal 6 4.5 L/m3 540 L i vi b mi, b sung ha cht sau khi gia nhit (>50 C) v phi khuy trn u. Khu vc Cam Khu vc Xanh 10.5 2.5 50 1 11 3 52 1.25 12 5.5 15 58 1.75 0.1 0.5 10 12.5 7 17.5 60 2 0.2 0.75 15 Ha cht M s PPG
Thng s kim sot pH Kim t do Tng ga tr kim Nhit Tensid [CK 171/11] Cht kh nh tng Dung dch ty/ TOC Hm lng rn l lng (<8m)
S ln 1x/ca 1x/ca 1x/ca 2x/ca 1x/ngy 1x/ngy 1x/ngy 1x/ngy
Phng n 1.1 1.2 1.4 1.5 1.6 1.7
n v pH im im C g/L g/L g/L mg/L
iu chnh thng s tng kim t do (+1pt) tng Tensid (+0.1g/L) Ngi vit G.COPIN
Ha cht Chemkleen 166 M Chemkleen 171/11 Chemkleen 171/11 Ngy vit 15/03/2013
Lng b sung 420Kg / 305L 42Kg / 42L 12Kg / 12L Cp nht 15/03/2013 Trang 7/90
G.COPIN:
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Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 8/90
G.COPIN:
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Biu Phn ng Ty Du / pH
Chy pH k c chnh thng s li trong ngy.
D liu log
KHNG
Ch s thp
Ch s cao
Kim t do thp ?
Kim t do cao ?
KHNG KHNG
Kim tra s ngng kt ca b v t vn dch v k thut
Trung ha vi ph gia acid
Dng thm ha cht
Lin h PPG
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 9/90
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Biu Phn ng Ty Du / Kim T Do
Chy kim tra kim t do.
D liu log
Gi tr kim t d c nm trong vng?
KHNG
Ch s thp
Ch s cao
Dng thm ha cht
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 10/90
G.COPIN:
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Biu Phn ng Ty Du / Tng Ga Tr Kim
D liu log
KHNG
Ch s thp
Ch s cao
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 11/90
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Khu vc : 3
Th i gian x l Cc thit b b sung:
Chc nng: Ra (R1)

Th tch 120 m3
Nhng
Nc: Nc DI
Ha cht
M s PPG
Nng Kg/m3 3 L/m
B sung Kg L
Thng s kim sot S l n pH dn in Tng ga tr kim 1x/ngy 1x/ngy 1x/ngy
Phng n 2.1
Khu vc Cam Khu vc Xanh 7 7.5 9.5 1500 1.5 10 2000 2
n v pH S/cm im
iu chnh thng s
Ha cht
Lng b sung Kg / L
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 12/90
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Chu k lm vic: 6 phtCng sut ti a: 8 sn phm/ gi
Biu Phn ng Ra / pH
D liu log
KHNG Ch s thp Ch s cao
iu chnh vi Zirco Buffer/M
Tng lu lng dng nc
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 13/90
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Biu Phn ng Ra / dn in
Chy my o dn in c chnh thng s li trong ngy
D liu log
dn in c nm trrong khong? C
Kt thc
KHNG Chy my o dn in cho dng nc vo
dn in KHNG c nm trong khong? C
Vn ngun nc phi c gii quyt trc.X ring tng b nu cn
Tng lu lng dng nc
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 14/90
G.COPIN:
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Biu Phn ng Ra / Tng Ga Tr Kim
D liu log
T ng gi tr ki m c n m trong kho ng
KHNG
Ch s thp
Ch s cao
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 15/90
G.COPIN:
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Khu vc : 4
Chc nng: Ra (R2)

Th tch 120 m3
Nhng
Nc Nc DI
Ha cht Ph gia ra Zirco
M s PPG A-I706008-JN
Nng 0.25 Kg/m3 0.20 L/m3
B sung 30 Kg 25 L
Thng s kim sot pH dn in Tng ga tr kim [Phosphate] [NO2]
S ln 1x/ngy 1x/ngy 1x/ngy 1x/ngy 1x/ngy
Phng n 2.1 3.1 2.2
Khu vc Cam Khu vc Xanh 6.5 7 9 300 0.5 40 80 9.5 400 0.6 50 90
n v pH S/cm im ppm ppm
30
40
iu chnh thng s tng [NO2] (+10ppm)
Lng b sung 5 Kg / 4 L
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 16/90
G.COPIN:
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Biu Phn ng Ra / pH
D liu log
Gi tr pH c nm trong vng?
C Kt thc
NO Ch s thp Ch s cao
iu chnh vi Zirco Buffer/M
Tng lu lng dng nc
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 17/90
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Biu Phn ng Ra / Dn in
Chy my o dn in c chnh thng s li trong ngy
D liu log
I dn in c nm trrong khong?
Kt thc
KHNG Chy my o dn in cho dng nc vo.
KHNG
dn in c nm trong khong?
V n ngu n n c ph i c gi i quy t tr c. L c ring tng b nu cn
Tng lu lng dng nc
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 18/90
G.COPIN:
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Biu Phn ng Ra / Tng Ga Tr Kim
Chy kim tra t ng ga tr ki m
D liu log
KHNG
Ch s thp
Ch s cao
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 19/90
G.COPIN:
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Biu Phn ng Ra / Ph Gia Ra Zircobond (NO2)
Kim tra ph gia ra Zircobond (ZRA)
D liu log
ZRA c nm trong thng s k thut v ch s n inh ?
C Kt thc Kim sot bnh thng
KHNG
Ch s c chiu hng gim Thm ph gia ra ZIRCOBOND bng my bm nh lng
Ch s c chiu hng tng Gim lng ph gia ra ZIRCOBOND thm vo bng my bm nh lng
Ch s di thong s k thut Thm ph gia ra ZIRCOBOND
Ch s vt qu 90 ppm X b nu cn. Pha long v phun trn b v i nc DI. Dng thm ph gia
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 20/90
G.COPIN:
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Khu vc : 5
Th i gian x l Cc thit b b sung: - B lc ti
Chc nng: Zircobond (ZR)

Th tch 120 m3
Nhng
Nc: Nc DI
Ha cht Zircobond ZC Zircobond SN Zirco Buffer/M Zircobond Zircobond Zircobond Zircobond Zircobond Fe2 R100 Control 1 Control 3 Control 4
M s PPG A-F706000-JH A-I706007-JH A-P706015-JH A-I706007-JH A-P706014-JH A-I706004-QH A-I706005-QH A-I706006-QH S ln 1x/ngy 1x/ngy 1x/ngy 1x/ngy 1x/ca 1x/ca 1x/ngy 1x/ca 1x/ngy Phng n 3.1 3.2 3.3 3.4 3.5
Nng B sung 11.7 Kg/m3 1400 Kg 11.3 L/m3 1350 L 3 6.5 Kg/m 780 Kg 6.4 L/m3 770 L 3 0.9 n 1.8 Kg/m 110 n 220 3 Kg 0.8 n 1.6 L/m 100 n 200 L 0.075 Kg/m3 9 Kg Cht n Ph gia ng Ph gia Zirconium Ph gia iu chnh Fluorua Khu vc Cam Khu vc Xanh 15 45 45 150 10 20 4.2 16 50 50 160 15 30 4.4 32 60 60 20 190 25 110 5 150 35 65 65 25 200 30 130 5.2 200 n v C m3/h m3/h ppm ppm ppm ppm pH ppm
Thng s kim sot Nhit Lu lng tun hon A Lu lng tun hon B [Phosphat] [Zirconium] [ng] [ Fluorua t do] pH [Rn l lng]
iu chnh thng s tng [Zirconium] (+16ppm) v [Copper] (+2.6ppm) tng [Copper] (+1ppm) tng [Zirconium] (+20ppm) tng pH t 4.0 n 4.4 gim [Fluorua t do] (-6.5ppm) Ngi vit G.COPIN
Ha cht Zircobond R100 Zircobond Control 1 Zircobond Control 3 Zirco Buffer/M Zircobond Control 4 Ngy vit 15/03/2013
Lng b sung 100 Kg / 95 L 1.2 Kg / 0.9 L 120 Kg / 115 L 6 kg / 5.5 L 12 kg / 9 L Trang 21/90
Cp nht 15/03/2013
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Biu Phn ng Zircobond / Zirconium V ng

Kim tra Zr v Cu D liu log Zr c nm trongvng iu khin? C Cu c nm trongvng iu khin? C Kt thc Duy tr lu lng thm IRCOBOND R100
KHNG KHNG
KHNG
Cu c nm trong vng iu khin ?
Cu th p Thm ph gia ZIRCOBOND CONTROL #1
Cu
cao
nh lng ZIRCOBOND CONTROL #3 thay cho ZIRCOBOND R100
C Trn thm t nht 30 pht, sau kim tra li
Zr <150ppm B sung ZIRCOBOND CONTROL #3
Zr <180ppm v Cu di thng s k thu t Tng lng ZIRCOBOND R100 thm vo bng my bm nh l ng
Zr cao Gim lng ZIRCOBOND R100 thm vo b ng bm nh lng v lng gn nu cn
Trn thm t nht 30 pht, sau kim tra li .
Zr v Cu u thp Tng lng ZIRCOBOND R100 thm vo bng my bm nh l ng
Zr th p v Cu cao B sung ZIRCOBOND CONTROL #3 v lng gn gim Cu nu cn
Zr v Cu u cao Dng thm Zircoboond R100.
Zr cao v Cu thp B sung ZIRCOBOND CONTROL #1 v lng gn gim Zr nu cn
Trn thm t nht 30 pht, sau kim tra li
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 22/90
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Nh my : Thnh ph H Ch Minh
Biu Phn ng Zircobond / Fluorua T Do

Chy kim tra gi tr Fluoride (FF) t do
D liu log
FF nm trong thng s k thu t v n nh trong 3 ch s lin t c?
Kt thc
KHNG
Ch s c chiu hng gim Gim lng ZIRCOBOND CONTROL #4 thm vo b ng bm nh l ng
Ch s c chiu hng tng Tng lng ZIRCOBOND CONTROL #4 thm vo b ng bm nh lng
Ch s di thng s k thut Dng thm ZIRCOBOND CONTROL #4 bng bm nh lng, Tham kho kim i din PPG
Ch s trn thng s k thut B sung ZIRCOBOND CONTROL #4
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 23/90
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Biu Phn ng Zircobond / pH

Chy pH k c chnh thng s li trong ngy D liu l log pH nm trong thng s k thut v n nh 3 ln ch s lin tip? C DONE Maintain ratio Zirco Buffer/M and Zircobond R100
KHNG
KHNG pH nm trong thng s k thu t?
pH c chiu hng gim and Zr v Cu trong thng s k thut pH th p, Zr v Cu trong thng s k thut Thm ZIRCO BUFFER/M v duy tr lng ZIRCOBON D R100 thm vo, tng l ng ZIRCO BUFER/M Tng lng ZIRCO BUFFER/M thm vo b ng my bm nh lng
pH thp, Zr v Cu cao lc kt thc Thm ZIRCO BUFFER/M V gim lng ZIRCOBOND R100 thm vo b ng bm nh lng
pH c chiu hng gim, Zr v Cu cao lc kt thc Gim lng ZIRCOBOND R100 thm vo bng bm nh lng
pH cao, Zr v Cu thp lc kt thc Thm ZIRCOBOND R100 v tng lng ZIRCOBOND R100 pH cao, Zr v Cu trong thng s k thut hoc cao lc kt thc Dng thm ZIRCO BUFFER/M. Khi ng li, khi pH nm trong thng s k thut,nhng gim lng thm vo bng bm nh lng Trn thm 30 pht, sau kim tra li
pH c chiu hng tng, Zr v Cu thp lc kt thc Tng lng ZIRCOBOND R100 thm vo pH c chiu hng tng , Zr v Metal A trong thng s k thut hoc cao lc kt thc Gim lng ZIRCO BUFFER/M thm vo b ng my bm nh lng.
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 24/90
G.COPIN:
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Khu vc : 6
Chc nng: Ra (R3)

Th tch 120 m3
Nhng
Nc: Nc DI
M s PPG A-I706008-JN
Nng 0.25 Kg/m3 0.20 L/m3
B sung 30 Kg 25 L
Thng s kim sot pH dn in [NO2]
S ln 1x/ngy 1x/ngy 1x/ngy
Phng n 2.2
Khu vc Cam Khu vc Xanh 5 30 5.5 40 8.5 400 80 9 450 90
n v pH S/cm ppm
iu chnh thng s tng[NO2] (+10ppm)
Lng b sung 5 Kg / 4 L
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 25/90
G.COPIN:
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Khu vc : 7
Chc nng: Ra (R4)

Th tch 120 m3
Nhng
Nc: Nc DI
Ha cht
M s PPG
Nng Kg/m3 L/m3
B sung Kg L
Thng s kim sot pH dn in S lng nm / vi khun
S ln 1x/ngy 1x/ngy 1x/tun
Phng n 5
Khu vc Cam Khu vc Xanh 5.5 7 35 10 7.5 40 1000
n v pH S/cm pg/ml
iu chnh thng s
Ha cht
Lng b sung
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 26/90
G.COPIN:
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Kim sot nc DI
Thng s kim sot dn in o nm/vi khun ATP S ln 1x/ngy 1x/tun Khu vc Cam Khu vc Xanh 8 1 10 100 n v S/cm pg/ml
Kim sot lp ZIRCOBOND

Thng s kim sot Trng lng mng nn HDG Trng lng mng nn EG Trng lng mng nn CRS Trng lng mng nn loi Al 6000 S ln Khu vc Cam Khu vc Xanh 30 30 10 20 50 50 20 30 170 170 90 180 190 190 100 200 n v
2x/tun 2x/tun 2x/tun 2x/tun
mg/m mg/m mg/m mg/m
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 27/90
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K hoch bo tr b
Giai on Khu vc 1 Phun t y d u Khu vc 2 Nhng ty d u Khu vc 3 Ra nhng Khu vc 4 Ra nhng S ln 1 4 tun 6 12 thng 4 8 tun 4 8 tun Quy trnh X sang WWT, v sinh b v thit b, lm y b t khu vc 2, chnh li mc nc b v thng s X sang WWT, v sinh b v thit b, b sung dung dch X sang WWT, v sinh b v thit b, lm y li X sang WWT, v sinh b v thit b, b sung nc X sang b d tr, v sinh b v thit b, lm y b t b d tr X sang WWT, v sinh b v thit b, b sung nc X sang WWT, v sinh b v thit b, lm y li
Khu vc 5 Nhng Zircobond 6 12 thng Khu vc 6 Ra nhng Khu vc 4 Ra nhng 4 8 tun 2 4 tun
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 28/90
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1.1 Kim tra kim t do (FA)

Thit b : ng pipet 10 ml Buret t ng 25 ml My khuy Cc Erlen 250 ml ng nghim100 ml Dung dch: Acid Hydrochloric 0.1 N (0.1 mol/L) Cht ch th mu Phenolphthalein Quy trnh: 1. Dng 1 ng pipe 10 ml , ht 10ml dung dch lc vo cc Erlen. 2. Dng ng nghim c vch ly 100 ml nc DI cho vo c c Erlen. 3. Nh 3-5 git cht ch th mu Phenolphthalein. Dung dch chuyn sang mu hng. 4. Dng burette cha HCl 0.1N, chun n khi mt mu hon ton. Th tch dung dch HCl 0.1N s dng l ch s kim t do .
Ch : Acid Sulfuric 1 N (0.5 mol/L) c th dng thay cho Acid Hydrochloric 1 N
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 29/90
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1.2 Kim tra tng ga tr kim (TA)

Thit b : ng pipet 10 ml Burette t ng 25 ml My khuy Cc Erlen 250 ml ng nghim100 ml Dung dch: Acid Hydrochloric 0.1 N (0.1 mol/L) Cht ch th mu Bromocresol Xanh Quy trnh: 1. Dng 1 ng pipe 10 ml , ht 10ml dung d ch lc vo cc Erlen. 2. Dng ng nghim c vch ly 100 ml nc DI cho vo cc Erlen. 3. Nh 3-5 git cht ch th mu Bromocresol Xanh. Dung dch chuyn sang mu xanh dng. 4. Dng burette cha HCl 0.1N, chun n khi mu vng n nh. Th tch dung dch HCl 0.1N s d ng l ch s tng gi tr kim t do .
Ngi vit G.COPIN
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1.3 Kim tra / tng Ga Tr Kim S dng pH k

Thit b: ng nghim 100 ml pH k c hiu chnh vi in cc Burette t ng 25 ml My khuy Cc beaker 250 ml Dung dch: Acid Hydrochloric 1 N (1 mol/L) Quy trnh: 1. Hiu chnh pH k 2. Lc mu ly t b vi giy lc v lm mt mu nhit phng. 3. Dng ng nghim c vch ly 100 ml mu cho vo cc beaker. 4. Dng burette thm Acid Hydrochloric 1N n khi pH ch gi tr pH=8.3 Th tch dung dch HCl 0.1N s dng l ch s kim t do . 5. Khng chnh burette v 0 v khng lm tht thot mu. 6. Tip tc trung ha vi Acid Hydrochloric 1N n khi pH=3.8 Th tch dung dch HCl 0.1N s d ng l ch s tng s kim t do .
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1.4 Cht Hot ng B Mt

Phng n ny c ra trong giai on u : SITA Dynotester + s c s dng , trong khi hin ti phng n ca PPG c ra cho cc phng n SITA Dynotester khc
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1.5 Dung dch Chemkleen CA d

Thit b: Cc Beaker 100ml (2) Cc Erlen 250 ml (2) Bnh nh mc 200ml, 250ml, 500ml, 1L ng Pipet 10 v 20 ml ng nghim chia vch 100 250 ml ng Burette 25 ml (2) Cn Cc cht th: Chloroforme tham kho ti li u: 22 720 291 t VWR hoc tng t Dimidium bromide tham kho ti li u: 234281-500mg t Sigma Aldrich Alcohol D (hoc ethanol) tham kho ti li u: SA-85-1460 t PPG Patent blue VF tham kho ti li u:198218-25G t Sigma Aldrich H2SO4 98% tham kho ti li u: 20 692 290 t VWR Chemkleen CA tham kho ti li u 967201 Chemkleen AN tham kho ti li u 967202 Chun b dung dch: Dung dch Chemkleen CA 10g/l : Dng ng pipet ly 10 ml dung dch Chemkleen CA vo bnh nh mc 1L, sau thm nc DI vo bnh n tng th tch l 1L v khuy u. Dung dch Chemkleen AN 10g/l: Dng ng pipet ly 10 ml dung dch Chemkleen AN vo bnh nh mc 1L, sau thm nc DI vo bnh n tng th tch l 1L v khuy u. Dung dch Alcohol D Nc DI (10% th tch/ th tch): Dng ng pipet ly 25 ml dung dch Alcohol D vo bnh nh mc 250ml, sau thm nc DI vo bnh n tng th tch l 250ml v khuy u.
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Cht ch th mu: Dung dch n 1: Cn 0.5 +/- 0.005g Dimidium bromide cho vo cc beaker 100 ml. Thm 30 ml dung dch Alcohol D Nc DI (10% th tch/ th tch), sau khuy u n khi tan hon ton. Dung dch n 2: Cn 0.25 +/- 0.005g Patent Blue VF cho vo cc beake 100 ml.. Thm 30 ml dung dch Alcohol D Nc DI (10% th tch/ th tch), sau khuy u n khi tan hon ton. Dung dch H2SO4 2.5 M: Cn 49.0 +/- 0.1g H2SO4 98% cho vo cc beaker 100 ml. Thm t t H2SO4 98% vo bnh nh mc 200ml cha 100ml nc DI . Sau thm nc DI vo bnh n tng th tch l 200ml v khuy u. (Ch : Khng c nc vo acid m c, s gy ra hin tng phun tro do phn ng ta nhit cc mnh)
Dung dch n 3: Trn dung dch n 1 v n 2 vo bnh nh mc 250ml Sau thm dung dch Alcohol D Nc DI (10% th tch/ th tch) vo bnh n tng th tch l 200ml v khuy u.Dung dch c mu xanh en. Trong bnh nh mc 500 ml: Dng ng pipette ly 20 ml dung dch n 3 Dng ng nghim chia vch , thm 200ml nc DI vo bnh Dng ng pipette ly 20 ml dung dch H2SO4 2.5 M Sau khi thm H2SO4, dung dch bnh c mu xanh l cy.. Thm nc DI vo bnh n tng th tch l 500ml Khuy u cht ch th ny vo bnh mu ti trnh nh sng. Cht ch th ny c th c gi ti a l 6 thng k t ngy pha ch. Xc nh nng cn li ca dung dch Chemkleen CA trong bn ty du sau khi c cn ni : Dng Pipette l y 20 ml dung dch trong b ty du sau khi c hin tng ni vo Cc Erlen 250 ml. Thm 20 ml dung d ch chloroform vo bnh chia Dng pipette thm 10 ml cht ch th mu (Xem hng dn pha ch trong ph lc) V thm 20 ml nc kh ion vo bnh chia Khuy mnh trong 5 giy. Ngi vit G.COPIN Ngy vit 15/03/2013 Cp nht 15/03/2013 Trang 34/90
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Nu b mt gia cc pha hu c v pha nc l khng mu, th khng c hin tng d nng dung dch Chemkleen CA, ngc li, nu b mt c mu xanh th c hin tng d nng dung dch Chemkleen CA. Lng d ny phi c chun . Lng d dung dch Chemkleen CA c trong b sch ,sau khi c hin tng ni, c trung ha bi dung dch Chemkleen AN 10g/l. Lc Cc Erlen sau khi thm dung dch Chemkleen AN 10 g/l v ch pha hu c v pha nc phn ly , n khi c th quan st mu sc b mt pha d dng trc khi tip tc chun . Khi b mt pha chuyn t mu xanh sang khng mu, xc nh th tch tng ng ca dung dch CK AN 10 g/l c thm vo bng ch s trn burret: Ch n v th tch l ml. Nu thm vt im tng ng th b mt pha chuyn sang mu hng. Cng thc tnh lng d dung dch Chemkleen CA Lng d CK CA g/l = 0.730*Th tch ( ml ) tng ng ca dung d ch CK AN 10g/l Nu lng d dung dch Chemkleen CA cao hn 3g/l , th phi dung dung dch Chemkleen AN trung ha lng d ny. Lng dung dch Chemkleen AN cn thm vo trung ha dung dch Chemkleen c tnh theo cng thc : CK AN thm vo g/l = Th tch (ml ) tng ng ca dung dch CK AN 10g/l / 2
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1.6 Lng dung dch ty / TOC

Xc nh lng du trong b lc bng dung dch Chemkleen CA I Thit b: Bnh nh mc 2000 ml. T sy. Pipette 10 ml (loi t ng) chnh v mc 5ml My khuy t v con c t Ming lt (Vd: Nhm).
II- Quy trnh : Ly 2000 ml dung dch trong b lc cho vo bnh nh mc 2000ml t con c t vo bnh nh mc , sau ln my khuy t. Dng Pipette 10 ml (loi t ng) ly 5ml dung dch Chemkleen CA cho vo bnh nh mc v khuy lin tc trong vng 30 pht. Sau khi khuy 30 pht, t bnh nh mc vo t sy 50C trong 3 gi. Sau 3 gi,ly ng pipet ht dung dch du trn c bnh nh mc v ln ming lt, c cn khi lng trc (W1). t ming lt cha mu vo t sy 180 C trong vng 30 pht, sau ly ra v lm ngui g n nhit phng, ghi li khi lng (W2) v tnh ton hm lng du. III- Cng thc : Du g/l = W2 W1 [g] / 2 W1= Khi lng ca [g] W2= Tng khi lng [g] sau khi sy v lm ngui nhit phng.
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1.7 Hm lng rn l lng(<8m)

Xc nh hm lng rn l lng trong dung dch ty du bng h thng lc. 1- Phm vi ng dng: Phng php ny p dng cho cc th nghim ti ch v phn tch b ty du v trong h thng tin x l t. Phng php ny m t cc quy trnh lc nh lng cc ht c kch thc trn 8m trong b ty du . 2- Nguyn l: Phng php ny xc nh lng ht trong b ty du m. Phng php ny s dng mt b lc tch ring cc ht ra khi cht lng. B lc c cn khi lng hai ln: trc khi lc, sau khi lc v sy kh. Bi s khc bit ca khi lng, phng php ny c th nh lng nng cht rn l lng trong b ty du v theo n v mg /lt. Mu th i din cho c b ty du m nn phi chn ly mu nhng v tr quan trng (V d: khng nn ly mu sau b lc). 3- Ccthit b cn thit: Cn k thut c th hiu chnh (+/- 1mg) L sy th nghim c th hiu chnh (105C +/- 3C) Cc nhm, ng knh khong 50 mm Giy lc Sartorius Stedim, ng knh 150mm , 84g/m, ti liu1288 H thng lc Bchner 150mm - Bnh nh mc - Phu lc Bchner 150mm - Vng m cho phu lc Bchner - Bm chn khng - ng cao su Bnh nh mc 1L Chai xt cha n c DI hoc RO Bnh ht m
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4- Quy trnh Chun b h thng lc: Sy kh t nht 8 gi trong l 105 C +/- 3 C loi khng kh m trong b lc. Sau khi sy, b lc trong bnh ht m. Ly mu dung dch trong b ty du: Dng bnh nh mc ly 1L mu dung dch trong b ty du Ghi ch ln cc cc: Ch thch mu vit tt bn di mi cc (v d cho cc ty du 1: D1) Cn khi lng ban u: Cn ming lc + c c s y kh v ghi khi lng li theo n v milligram (Mi = khi lng ban u) Lp rp h thng lc Ni ng cao su vi bnh chn khng v bm chn khng t vng m trn bnh chn khng t ph u l c Bchner l bnh chn khng Phu lc Bchner Bm chn khng ng cao su Vng m
Bnh chn khng
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t ming lc sy v cn ln cc:
Lm t ming lc bng chai xt nc DI hoc nc RO.
Bc ny gip chu lc ht khi bm chn khng hot ng v gip ming lc khng di chuyn trong khi lc.
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Chu k lm vic: 6 phtCng sut ti a: 8 sn phm/ gi
Lc: M van my bm hot ng v t t mu vo ming lc
Ra bnh chn khng v nc DI hoc RO ln mng lc t ming lc vo l 105 C +/- 3 C trong 3 gi Lm ngui cc + mng lc trong bnh ht m Cn khi lng cui: Cn khi lng mng lc + c c kh ghi khi lng li theo n v milligram (Mf = khi lng cui) 5- Ghi kt qu V= Th tch m u (lt) Mi= Kh i lng mng l c + c c trc khi l c (milligrams) Mf= Khi lng mng l c + c c trc sau l c (milligrams) Hm lng rn l lng= (Mf-Mi)/V n v mg/L
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2.1 Ra Tng Ga Tr Kim

Thit b: Burette t ng25 ml My khuy Cc Erlen 250 ml ng nghim 100 ml Dung dch: Acid Hydrochloric 0.1 N (0.1 mol/L) Bromocresol Xanh Quy trnh:
1. Dng ng nghim chia vch ly 100 ml mu cho vo cc Erlen. 2. Thm 3-5 git cht ch th mu (Bromocresol Xanh). Dung dch chuyn sang mu xanh . 3. Dng buret, trung ha dung dch vi 0.1N HCl cho n khi c mu vng n nh. Th tch dung dch HCl 0.1N s d ng l ch s tng kim t do
Ch : Acid Sulfuric 1 N (0.5 mol/L) c th dung thay cho Acid Hydrochloric 1 N
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2.2 Ra NO2
Xc nh nng ph gia ra Zirco bng nit k 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l trong h thng tin x l t. Phng php ny m t cc quy trnh nh lng ph gia ra Zirco c dng trc v sau b Zircobond. 2- Nguyn tc Phng php ny xc nh nng ca nitrit trong b ra. Trong ng Nit k, kh Nitrogen c sinh ra do phn ng gia nitrit v acid sulphamic d. Nng nitrit ph thuc vo th tch nitrogen thi ra trong ng Nit k 3- Thit b v thuc th nit k
Dao trn acid Sulfamic
m ca dao trn c th nh hng n acid sulfamic, v v y nn bo qun trong t kn hoc bnh ht m Ph gia ra Zirco Cn k thut (+/- 1mg) Bnh chn khng 1L Ngi vit G.COPIN Ngy vit 15/03/2013 Cp nht 15/03/2013 Trang 42/90
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4- Quy trnh Chun b: Thm dung dch b vo y ng Nit k phn tch
Ch : 1) Thm t t dung dch vo ng sau nghing ng loi tt c bt kh dc theo thn ng 2) Khi dung dch y bu ng Nit k th dng li
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B sung acid Sulfamic : Dng dao trn thm 2gr acid sulfamic vo bu ng Nit k
Dng ngn tay che ng ng Nit k li sau nghin ng phn tn u acid sulfamic t bu n cui ng. Khng c bt kh trong ng khi thao tc.
Acid phi c phn tn u n cui ng
Khi acid phn tn n cui n th nghin ngc li cho acid chy bu v ly ngn tay ra. ng nm ngang Sulfamic acid v nitrit phn ng v sinh ra kh nitrogen. Ch : Thao tc phi nhanh bo m chnh xc . Ngi vit G.COPIN Ngy vit 15/03/2013 Cp nht 15/03/2013 Trang 44/90
DAIMLER VIET NAM

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Thnh ph H Ch Minh Ch s dy chuyn ca Drr 5- Kt qu Ch cho phn ng hon ton, khng c kh to ra (khong 2 pht), sau c gi tr vch ng . Chu k lm vic: 6 Cng sut ti a: 8 sn phm/ gi
Kt qu
Ch : V c nhiu loi ng Nit k , nn ta c th hiu chnh v chia vch nh cc v d. Xem bn ph lc cho qu trnh hiu chnh.
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6- Ph lc Hiu chun ng Nit k Hiu chun quy trnh chun b dung dch: Cn 0.125gr +/- 0.005gr ph gia ra Zirco cho vo bnh nh mc 1L. Thm 1L nc DI hoc RO. y l dung dch hiu chnh NO2 30ppm. Cn 0.25gr +/- 0.005gr ph gia ra Zirco cho vo bnh nh mc 1L. Thm 1L nc DI hoc RO. y l dung dch hiu chnh NO2 60ppm. Cn 0.375gr +/- 0.005gr ph gia ra Zirco cho vo bnh nh mc 1L. Thm 1L nc DI hoc RO. y l dung dch hiu chnh NO2 90ppm. Hiu chun o dung dch hiu chnh NO2 30ppm, theo phng php phn 4. nh du cc bt kh trn ng, gii hn 30ppm o dung dch hiu chnh NO2 60ppm, theo phng php phn 4. nh du cc bt kh trn ng, gii hn 60ppm o dung dch hiu chnh NO2 90ppm, theo phng php phn 4. nh du cc bt kh trn ng, gii hn 90ppm
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3.1 Nng Phosphat

Xc nh Nng Phosphate bng phng php o quang ph 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l trong h thng tin x l t. Phng php ny m t cc quy trnh xc nh nng Phosphate trong b Zircobond hoc trong mu nc. 2- Nguyn l Axit ha dung dch vi axit sunfuric, orthophosphate phn ng vi amoni vanadate v amoni heptamolybdate (thuc th PA-H) to thnh mt phc mu vng cam ca molypden vanadate axit photphoric. Kt qu th nghim c xc nh ti 420 nm. 3- Thit b v cc cht th My o quang ph Hach DR 2800 hoc thit b tng t ng ly mu Hach Bnh nh mc 100 and 200ml ng Pipet: 1, 2, 5 and 10ml ng pipet chia v ch 2.4 ml Bnh xt tia v mng lc 1m Dung dch chun n c DI Phosphate 1000ppm (VWR 1.19898.0500) Cht th PA-H (VWR 1,14842,0001) Nc DI hoc RO
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4- Chun b cc dung dch chun Chun b dung dch PO4 mu hiu chnh: Mu n 1 (PO4 10 ppm): dng ng pipet ly 1 ml dung dch chun PO4 1000 ppm cho vo bnh nh mc 100ml. Thm n c DI hoc RO vo bnh n tng th tch 100ml . ng nht ha. Mu n 2 (PO4 20 ppm): dng ng pipet ly 2 ml dung dch chun PO4 1000 ppm cho vo bnh nh mc 100ml. Thm n c DI hoc RO vo bnh n tng th tch 100ml . ng nht ha. Mu n 3 (PO4 30 ppm): dng ng pipet ly 3 ml dung dch chun PO4 1000 ppm cho vo bnh nh mc 100ml. Thm n c DI hoc RO vo bnh n tng th tch 100ml . ng nht ha. Mu n 4 (PO4 40 ppm): dng ng pipet ly 4 ml dung dch chun PO4 1000 ppm cho vo bnh nh mc 100ml. Thm n c DI hoc RO vo bnh n tng th tch 100ml . ng nht ha. Mu n 5 (PO4 50 ppm): dng ng pipet ly 5 ml dung dch chun PO4 1000 ppm cho vo bnh nh mc 100ml. Thm n c DI hoc RO vo bnh n tng th tch 100ml . ng nht ha. Ngy ht hn: Ngy pha + 1 thng Cng thc tnh nng thc ca dung dch chun: PO4 ( ppm) = Nng PO4 (ppm) thm vo theo thng s k thut ca dung dch chun PO4* Th tch dung dch chun (ml) / Th tch bnh nh mc s dng Dung dch PO4 25 ppm kim tra qu trnh hiu chun: Dng ng pipet ly 5 ml dung dch chun PO4 1000 ppm cho vo bnh nh m c 200ml. Thm n c DI hoc RO vo bnh n tng th tch 200ml . ng nht ha. Cng thc tnh nng thc ca dung dch : PO4 (ppm) = Nng PO4 (ppm) thm vo theo thng s k thut ca dung dch chun PO4* 0.025 Ngy ht hn: Ngy pha + 1 thng Ngi vit G.COPIN Ngy vit 15/03/2013 Cp nht 15/03/2013 Trang 48/90
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5- Hiu chnh my o quang ph
Ch : sch ca cc cells l thng s quan trng bo m php o chnh xc . Bo m rng b mt ng ly mus mu phi sch c trong ln ngoi (Vd. Du tay cng c th nh hng n kt qu). Lun lun lau bn ngoi ca ng ly mus mu bng khn giy trc khi o bng my quang ph. Thao tc ny c thc hin mi ln khi dung cht th PA-H mi th nghim. hp th ca PO4 c o ti 420 nm.
Chun b mu trng: Dng pipet ly 10 ml nc DI hoc RO cho vo ng ly mu sau thm 2.4mL thuc th PA-H. ng nht Chun b mu: Dng pipet ly 10 ml dung dch cho vo ng ly mu sau thm 2.4mL thuc th PA-H. ng nht V d chun b mu n 1 (10 ppm PO4): Dng pipet ly 10 ml dung dch chun n 1 (PO4 10 ppm) cho vo ng ly mu sau thm 2,4 ml thuc th PA-H. ng nht 1) Bt my o quang ph bng cch nhn nt power 1/0
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2) Ch i u khi n t ng. Trong trng hp kt qu NOK, tham kho hng dn s dng.
3) Chn user programs trn menu chnh
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4) Chn chng trnh 953 sau nhn options hiu chnh
5) Nhn modifier
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6) Chn hiu chnh C=a + bA sau nhn modifier
7) Chn tiu chun o lng sau nhn OK
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Ch s dy chuyn ca Drr 8) Nhn + thm cc tiu chun
9) Nhp mu n 1, n v nng ppm (10ppm) sau nhn OK
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10) Chun b mu trng , t n trong my o quang ph sau nhn Zero
11) Chun b ng nghi m ch a mu n 1 (10ppm), t n trong my o quang ph sau nhn biu tng ng h m ngc 2 pht.Sau 2 pht nhn mesurer
Lp lai thao tc 8) n 11) cho cc mu (20ppm, 30ppm, 40ppm, 50ppm)
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12) Sau khi c ch s mu cui, nhn Esc thot
13) Nhn Save lu thng s hiu chnh
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Ch s dy chuyn ca Drr 5- o mu
Ch : sch ca cc ng ly mu l thng s quan trng bo m php o chnh xc . Bo m rng b mt ng ly mus mu phi sch c trong ln ngoi (Vd. Du tay cng c th nh hng n kt qu). Lun lun lau bn ngoi ca ng ly mus mu bng khn giy trc khi o bng my quang ph. Nu mu khng trong th phi lc v hm lng rn l lng c th nh hng n kt qu o quang ph.Cc thao tc sau c th p dng cho mu Zircobond, mu nc hoc dung dch iu chnh PO4 25ppm .
Chun b mu trng: Dng pipet ly 10 ml nc DI hoc RO cho ng ly mu sau thm 2.4mL thuc th PA-H. ng nht Chun b mu: Dng pipet ly 10 ml dung dch cho vo ng ly mu l sau thm 2.4mL thuc th PA-H. ng nht V d: Chun b dung dch iu chnh PO4 25ppm: Dng pipet ly 10 ml dung dch iu chnh PO4 25ppm cho vo cel , sau thm 2,4 ml thuc th PA-H. ng nht 1) Bt my o quang ph bng cch nhn nt power 1/0
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3) Chn user programs trn menu chnh
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4) Chn chng trnh 953 sau nhn start
5) Chnh mu trng, t n trong my o quang ph v nhn Zero
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6) Sau khi a v khng, my o quang ph hin th 0.00ppm PO4. Chun b ng nghim cha mu, t n trong my o quang ph sau nhn biu tng ng h m ngc 2 pht..
7) Sau 2 pht nhn mesurer. My o quang ph hin th trc tip k qu n ng PO4 (ppm)
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3.2 Nng Zirconium

Xc nh Nng Zirconium bng my o quang ph 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l v trong h thng tin x l t. The Phng php ny m t cc quy trnh th o mu nh lng nng t zirconium trong b Zircobond . 2- Nguyn l Phng php ny dng o lng zirconium trong b Zircobond. Dng cc cht th cho phn ng vi zirconium trong mi trng acid to ra mu nhn bit c trng. Thit b o dng bc sng nh sng xc nh lng mu. Cng mu t l thun vi nng zicronium. php o c chnh xc, thit b o phi c hiu chnh . Thit b o phi c hiu chnh khi dng cht th AR mi pha hoc mi mua. Phng php ny c th o ti a nng (ca dung dch pha long ) l 250 ppm. Nu ch s trn 250 ppm th cn pha long dung dch. 3- Thit b v cc cht th My o quang ph Hach DR 2800 hoc thit b tng ng pH k c iu chnh Cn k thut c iu chnh (+/- 1mg) ng ly mu Hach Cc beaker 1L and 500ml Bnh nh mc 50ml, 100ml v 1L ng Pipet: 1, 5 v 20ml Chai nha mu ti 1l trnh nh sng Bnh xt tia v mng lc1m hiu chnh v kim sot: Dung dch chun H2ZrF6 45% n c tham kho: ALFA39462.A3 t VWR hoc tng ng Cht th H: acid Hydrochloric 6,0Nr tham kho: 2611.5000 t VWR * Zirco Buffer M iu chnh pH Arsenezo III tham kho: A92775-1G t Sigma Aldrich * Nc DI hoc RO *Ch - Cn thn :Cht th H l cht n mn cc mnh v dung dch Arsenazo III l cht c.
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Ch s dy chuyn ca Drr 4- Chun b cc cht th
Zirco buffer M 100gr/L: Cn 10 +/- 0,1 gram Chemfil Buffer M cho vo bnh nh mc 100 ml Thm nc DI hoc RO cho n tng th tch bnh l 100 ml . Ngy ht hn: Ngy pha + 6 thng Cht th AR: Cn 0,20 +/- 0,01 gram Arsenezo III cho vo bnh nh mc 1l, sau ha tan thm 500 ml nc DI hoc RO v khuy Sau khi ha tan xong, thm nc DI hoc RO cho n tng th tch bnh l 1l Bo qun cht th ny trong chai nha mu ti 1l ,trnh nh sng . Cn thn: Cht th AR khng bn theo thi gian: Ngy ht hn: Ngy pha + 2 tun Dung dch Zirconium chun hiu chnh: Trong mi bnh nha (1000 ml): thm ~300 gram nc DI hoc RO Mu n1 (Zr 50 ppm ), thm 0,125 gram H2ZrF6 45% vo bnh nha th nht. Chnh pH n 4,6 +/0,2 bng dung dch Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k trn cc beaker nha v sau thm 500 gram nc DI hoc RO Mu n2 (Zr 100 ppm ), thm 0,250 gram H2ZrF6 45% vo bnh nha th hai. Chnh pH n 4,6 +/0,2 bng dung dch Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k trn cc beaker nha v sau thm 500 gram nc DI hoc RO Mu n3 (Zr 150 ppm ), thm 0,380 gram H2ZrF6 45% vo bnh nha th ba. Chnh pH n 4,6 +/0,2 bng dung dch Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k trn cc beaker nha v sau thm 500 gram nc DI hoc RO Mu n4 (Zr 200 ppm ), thm 0,500 gram H2ZrF6 45% vo bnh nha th t. Chnh pH n 4,6 +/0,2 bng dung dch Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k trn cc beaker nha v sau thm 500 gram nc DI hoc RO
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Mu n5 (Zr 250 ppm ), thm 0,630 gram H2ZrF6 45% vo bnh nha th nm. Chnh pH n 4,6 +/- 0,2 bng dung dch Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k trn cc beaker nha v sau thm 500 gram nc DI hoc RO Ngy ht hn: Ngy pha + 1 thng Ch : - Ghi li chnh xc khi lng H2ZrF6 45% cn c ca mi mu. Cn thn, Khi pH ti gi tr 3,5 th thm t t dung dch Chemfil Buffer M 100g/l chnh pH ln 4,6 +/-0,2 3 Cng thc tnh nng thc ca dung dch chun Zirconium: Nng Zr ( ppm)= ((khi lng H2ZrF6 45% cn (g) *0,45*91,2*1000))/(207,2*0,5)
Dung dch kim sot Zr 180ppm dng hiu chnh: Trong bnh nha 1000 ml: Thm ~300 gram nc DI hoc RO v sau thm 0,45 gram H2ZrF6 45%. iu chnh pH ti gi tr 4,6 +/- 0,2 bng Zirco Buffer M 100g/l. Dng nc DI hoc RO ra pH k v sau thm 500 gram nc DI hoc RO Cng thc tnh nng thc ca dung dch kim sot Zr: Nng Zr (ppm)= (khi lng H2ZrF6 45% cn (g)*0,45*91,2*1000)/(207,2*0,5) Ngy ht hn: Ngy pha + 1 thng Ch : - Ghi li chnh xc khi lng H2ZrF6 45% cn c ca mi mu. Cn thn, Khi pH ti gi tr 3,5 th thm t t dung dch Chemfil Buffer M 100g/l chnh pH ln 4,6 +/-0,2 Pha long mu trc khi o n ng zirconium : Pha long cc mu o (dung dch chun hiu chnh , dung dch kim sot Zr 180ppm, dung dch b Zircobond) 10 l n. Dng ng Pipet ly 5ml mu cho vo bnh nh mc 100ml, sau thm nc DI hoc RO cho n tng th tch bnh l 100 ml . Ch : Nu mu dung dch Zicrobond khng trong th phi lc
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5- Thit lp/Hiu chnh my o quang ph HACH DR2800 Ch : sch ca ng ly mu l thng s quan trng bo m php o chnh xc . Bo m rng b mt ng ly mu phi sch c trong ln ngoi (Vd. Du tay cng c th nh hng n kt qu). Lun lun lau bn ngoi ca ng ly mu bng khn giy trc khi o bng my quang ph. Thao tc ny c thc hin mi ln khi dng dung dch ch th (ARSENAZO III) mi th nghim. hp thu ca Zr c o ti 610 nm Chun b mu trng: Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 20 ml, sau trn u. Chun b mu Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 1 ml dung dch pha long 10 ln cho vo ng ly mu , sau trn u Vd: Chun b mu 1 (Zr 50 ppm ): Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 1 ml dung dch mu 1 (Zr 50 ppm ) pha long 10 ln cho vo ng ly mu , sau trn u 1) Bt my o quang ph bng cch nhn nt power 1/0
2)
Ch i u khi n t ng. Trong trng hp kt qu NOK, tham kho hng dn s dng.
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3)
Chn user programs trn menu chnh
4)
Chn c hng trnh 952 sau nhn options hiu chnh
5)
Nhn modifier
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6)
Chn hiu chnh C=a + bA sau nhn modifier
7)
Chn tiu chun o lng sau nhn OK
8)Nhn + thm tiu chun
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9)
Nhp mu n 1, n v nng ppm (50ppm) sau nhn OK
10)
Chun b ng cha m u tr ng, t n trong my o quang ph sau nhnZero
11) Chun b mu u tin (50ppm) v t vo my o quang ph. Thit lp ng h 3 pht, sau 3 pht nhn measurer. Ch , sau khi thm 1ml mu c pha long vo ng ly mu cha cht th H v AR, khng i ng h chy,m phi tnh thi gian phn ng chnh xc 3 pht k t khi thm mu vo. Lp lai thao tc 8) n 11) cho cc mu (100ppm, 150ppm, 200ppm, 250ppm)
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12) Sau khi o xong 5 mu, nhn quit
13) Lu li cc thng s hiu chnh
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6- o mu dung dch b Zircobond hoc dung dch kim sot Zr 180ppm Chun b mu trng: Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 20 ml, sau trn u. Chun b mu Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 1 ml dung dch pha long 10 ln cho vo ng ly mu , sau trn u Vd: Chun b mu dung dch kim sot (Zr 180 ppm ): Dng ng pipet ly 5 ml thuc th AR + 20 ml thuc th H + 1 ml dung dch mu dung dch kim sot (Zr 180 ppm pha long 10 ln cho vo ng ly mu , sau trn u 1) Bt my o quang ph bng cch nhn nt power 1/0
2) Ch i u khi n t ng. Trong trng hp kt qu NOK, tham kho hng dn s dng
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3) Chnuser programs trn menu chnh
4) Chn chng trnh 952 o Zirconium v nhn start
5) Chun b ng ch a m u tr ng, t n trong my o quang ph sau nhn Zero
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6) My o quang ph hin th 0.00ppm. Ly ng cha mu trng ra khi my quang ph v thm 1ml dung dch mu pha long 10 ln vo ng o qu trnh chun b mu trng, sau trn u. Ch y ng h v nh n measurer sau 3 pht. Ch , sau khi thm 1ml mu c pha long 10 ln vo ng ly mu cha cht th H v AR, khng i ng h chy,m phi tnh thi gian phn ng chnh xc 3 pht k t khi thm mu vo.
7) Kt qu hin th trn mng hnh, n v nng Zirconium l ppm. Khng c nhn 10 ln kt qu . H s pha long 10 ln c tch hp trong lc hiu chnh my.
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3.3 Nng ng
Xc nh nng ng bng my o quan ph 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l v trong h thng tin x l t. The Phng php ny m t cc quy trnh th o mu nh lng nng t ng trong b Zircobond . 2- Nguyn l ng phn ng vi bicinchoninate to ra hn hp mu hng, Cng mu ca hn hp t l thun vi nng ng. Bc sng o 560 nm . Vng nh hng ca phng php ny l 0 5ppm. 3- Thit b v cc cht th My o quang ph Hach DR 2800 hoc thit b tng ng ng ly mu Hach Bnh nh mc 50ml, 100ml ng Pipet: 2, 5 v 10ml Bnh xt tia v mng lc1m Dung dc h Cu mu 100ppm (128-42 Hach Lange) Cu Ver 2 pillows (21882-99 Hach Lange) Nc DI hoc RO 4- Chun b mu dung dch kim sot ng 2ppm : Dng Pipet ly 2 ml dung dch mu Cu 100 ppm vo bnh nh mc 100ml. Thm nc DI hoc RO cho n tng th tch bnh l 100 ml . ng nh t m u Dung dch pha long 50 ln ny cha ng 2ppm Ngy ht hn: Ngy pha + 1 thng
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5- Xc nh hm lng ng trong dung d ch ki m sot ng 2ppm ho c dung dich trong b Zircobond Ch : sch ca ng ly mu l thng s quan trng bo m php o chnh xc . Bo m rng b mt ng ly mu phi sch c trong ln ngoi (Vd. Du tay cng c th nh hng n kt qu). Lun lun lau bn ngoi ca ng ly mu bng khn giy trc khi o bng my quang ph. Chun b dung dch kim sot: Dng ng pipet ly 10 ml dung dch kim sot Cu 2ppm cho vo ng l y m u Chun b dung dch b Zircobond: Dng ng pipet ly 5ml dung dch b Zircobond cho vo bnh nh mc 100ml, sau thm nc DI or RO n tng th tch l 100. ng nht.Dung dc ny l dung dch b Zircobond pha long 10 ln. Nu mu khng trong th phi lc v hm lng rn l lng c th nh hng n kt qu o quang ph Dng pipet ly 10ml dung dc pha long 10 ln cho vo ng ly mu 1) Bt my o quang ph bng cch nhn nt power 1/0
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3) Chn stored programs trn menu chnh
4) Nhn select by program number
5) nh 135 sau nhn OK
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6) Chn chng trnh 135 Bicin. Copper 5.00mg/L sau nhn start
7) t ng cha mu vo my o quang ph sau nhn Zero
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8) My o quang ph hin th 0.00 mg/L Cu
o: Ly ng cha mu ra khi my o quang ph Thm cht th pillow CuVer 2 Trn u trong 15 giy Thay ng mu trong my o quang ph Thm nc DI hoc RO n khi t th tch tng l 100 ml. ng nh t. Chy ng h 2 pht (nhn biu tng ng h ,sau nhn OK)
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Ch s dy chuyn ca Drr Sau 2 pht, nhn measurer
9)
My o quang ph hin th ch s mg/L Cu
Ghi kt qu i vi dung dch kim sot ng 2ppm, My o cho kt qu trc tip v dung dch khng phi pha long, n v nng ngl mg/L - i vi dung dch trong b Zircobond , gi tr hin th phi nhn thm h s v dung dich b pha long 10 ln : Nng ng (mg/L) = kt qu hin th*10 -
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3.4 Nng Fluoriua t do

Xc nh nng Fluoriua t do v tng Fluoriua trong b Zircobond. 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l trong h thng tin x l t. Phng php ny m t cc quy trnh nh lng Fluoriua trong b Zircobond. 2- Nguyn l Phng php ny xc nh nng ca fluoriua t r o n g b Zircobond bng cch o in th. Mt bn in c c nh c cho vo dung d ch fluoriua m u sau c dng o nng fluoriua trong b. 3- Thit b v thuc th My o ion Mettler Toledo Seven Go SG8 hoc thit b tng ng. in cc Fluoride VWR SympHony 14002-788 F hoc thit b tng ng (VWR 6621053) ng pipet 2,10 v 50 ml Cc beaker nha 100ml Bnh nh mc 1L Bnh nh mc nha 100ml Chai nha ~200ml Nc DI hoc RO Sodium citrate (VWR 27830294) Fluoride chun 1000 mg (VWR 1,09869,0001)
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4- Quy trnh Chun b dung dch chun: Sodium citrate buffer: Cn 100g sodium citrate cho vo bnh nh mc 1L sau thm nc DI hoc RO nl tng th tch bnh. ng nht ha tan hon ton sau thm nc DI v RO cho n tng th tch bnh l 1L.. Dung dich chun 10 000 ppm: Pha long Fluoride chun 1 000mg vo bnh nh m c nh a100ml. thm nc DI v RO cho n tng th tch bnh l 100 ml, ng nht. Dung dich chun 1000 ppm: Dng pipet ly 10ml dung dch chun 10 000 ppm cho vo bnh nh mc nha 100 ml, sau thm nc DI v RO cho n tng th tch bnh l 100 ml Dung dich chun 100 ppm: Dng pipet ly 10ml dung dch chun 1 000 ppm cho vo bnh nh mc nha 100 ml, sau thm nc DI v RO cho n tng th tch bnh l 100 ml Dung dich chun 500 ppm: Dng pipet ly 5ml dung dch chun 1 000ppm cho vo bnh nh mc nha 100 ml, sau thm nc DI v RO cho n tng th tch bnh l 100 ml Chun b dung dch hiu chnh: Dung dch hiu chnh F1 10 000ppm Fluorides: Dng pipet ly 2 ml dung dch chun 10 000 ppm v dng ng nghim chia vch ly 50 ml dung dch sodium citrate buffer cho vo chai nha 200 ml, ng nht Dung dch hiu chnh F2 1 000ppm Fluorides: Dng pipet ly 2 ml dung dch chun 1 000 ppm v dng ng nghim chia vch ly 50 ml dung dch sodium citrate buffer cho vo chai nha 200 ml, ng nht Dung dch hiu chnh F3 100ppm Fluorides: Dng pipet ly 2 ml dung dch chun 100 ppm v dng ng nghim chia vch ly 50 ml dung dch sodium citrate buffer cho vo chai nha 200 ml, ng nht Dung dch hiu chnh F4 500ppm Fluorides: Dng pipet ly 2 ml dung dch chun 500 ppm v dng ng nghim chia vch ly 50 ml dung dch sodium citrate buffer cho vo chai nha 200 ml, ng nht
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Ch s dy chuyn ca Drr Hiu chnh my o ion:
Vic hiu chnh my o cn thc hin hng ngy. Tham kho hng dn s dng bit thm chi tit. Hiu chnh my o ion vi dung dch cc hiu chnh F1 (10 000 ppm), F2 (1000 ppm) v F3 (100 ppm). Sau khi hiu chnh, kim tra l i vi dung d ch hi u ch nh 500ppm .Gi tr phi nm trong khong 500ppm +/- 25ppm, nu gi tr nm ngoi khong th hiu chnh li. i vi mi ch s hiu chnh v dung dch kim sot, nhng in cc vo dung dch v i ch s n nh Vic o Fluorid b nh hng bi nhit .Thc hin hiu chnh v o phi cng nhit (20C hoc 25C). o tng lng fluorid: Dng pipet l y 2ml mu v 50 ml dung d ch sodium citrate buffer cho vo cc beaker nha 100ml. ng nht. Nhng in cc vo dung dch. i ch s n nh. Gi tr hin th l tng nng fluoride ( ppm) o lng fluorid t do: Nhng in cc trc tip vo mu dung dch b. i ch s n nh. Chia gi tr hin th cho 26. l nng fluoride ( ppm).
Bo qun in cc in cc trong dung dich chun fluoride 100 ppm Thm IonPlus A optimum results vo in cc khi mc nc thp in cc ny phi c gi trong iu kin trn t nht 1 ting trc khi bt u hiu chnh hoc o
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3.5 Hm lng rn l lng

Xc nh hm lng rn l lng trong b Zircobond b n g m y o q u a n g p h 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l v trong h thng tin x l t. Phng php ny m t cc quy trnh lc nh lng cc ht rn l lng (bn) c trong b Zircobond. 2- Nguyn l Phng php ny xc nh lng ht rn l lng trong b Zircobond. Phng php ny s dng mt b lc tch ring cc ht rn l lng ra khi cht lng. B lc c cn khi lng hai ln: trc khi lc, sau khi lc v sy kh. Bi s khc bit ca khi lng, phng php ny c th nh lng nng cht rn l lng trong b Zircobond v theo n v mg /lt hoc ppm Mu th i din cho c b Zircobond nn phi chn ly mu nhng v tr quan trng (V d: khng nn ly mu sau b lc). 3- Cc thit b cn thit My o quang ph Hach DR2800 hoc thit b tng ng ng ly mu Hach (t nht 2 ci) Nc DI hoc RO
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4- Quy trnh
Ch : sch ca cc ng ly mu l thng s quan trng bo m php o chnh xc . Bo m rng b mt ng ly mu mu phi sch c trong ln ngoi (Vd. Du tay cng c th nh hng n kt qu). Lun lun lau bn ngoi ca ng ly mu bng khn giy trc khi o bng my quang ph. Khng n mu trn bn th nghim lu trnh ln bn, lc u mu ng nht. Chun b mu trng v mu b: nc DI hoc RO vo ng mu ln ti vch du: y l mu trng. dung dch b vo ng mu ln ti vch du: y l mu b.
Ci t cu hnh my o quang ph Bt my o quang ph bng cch nhn nt power 1/0
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Ch i u khi n t ng. Trong trng hp kt qu NOK, tham kho hng dn s dng
Chn stored programs trn menu chnh
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Chn chng trnh 630 Solides suspension sau nhn start
Thit b hin th mg/L v chun b o
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Ch s dy chuyn ca Drr o: t mu trng vo my quang ph
t phia trn, sau nhn Zero
My o quang ph hin th 0 mg/L
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Thay ng cha mu trng bng ng cha mu cn o vo my o quang ph
t pha trn v nhn Measure
My o quang ph hin th kt qu theo n v mg/L
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3.6 Hm lng rn l lng Bng h thng lc

Xc nh hm lng rn l lng trong b Zircobond bng h thng lc. 1- Phm vi ng dng Phng php ny p dng cho cc th nghim ti ch v phn tch cc b tin x l v trong h thng tin x l t. Phng php ny m t cc quy trnh lc nh lng cc ht rn l lng (bn) c trong b Zircobond. 2- Nguyn l Phng php ny xc nh lng ht rn l lng trong b Zircobond. Phng php ny s dng mt b lc tch ring cc ht rn l lng ra khi cht lng. B lc c cn khi lng hai ln: trc khi lc, sau khi lc v sy kh. Bi s khc bit ca khi lng, phng php ny c th nh lng nng cht rn l lng trong b Zircobond v theo n v mg /lt. Mu th i din cho c b Zircobond nn phi chn ly mu nhng v tr quan trng (V d: khng nn ly mu sau b lc). 3- Cc thit b cn thit: Cn k thutc th hiu chnh (+/- 1mg) L sy th nghim c th hiu chnh (105C +/- 3C) Cc nhm, ng knh khong 50 mm giy lc si thy tinh WHATMAN GF/C 47mm Cat No 1822 047 H thng lc Bchner 50mm - Bnh nh mc - Phu lc Bchner 150mm - Vng m cho phu lc Bchner - Bm chn khng - ng cao su Bnh nh mc 1L Chai xt cha n c DI hoc RO Bnh ht m
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
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4- Quy trnh Chun b h thng lc: Sy kh t nht 8 gi trong l 105 C +/- 3 C loi khng kh m trong b lc. Sau khi sy, b lc trong bnh ht m. Ly mu dung dch trong b Zircobond: Dng bnh nh mc ly 1L mu dung dch trong b Zircobond Cn khi lng ban u: Cn ming lc + c c s y kh v ghi khi lng li theo n v milligram (Mi = khi lng ban u) Lp rp h thng lc Ni ng cao su vi bnh chn khng v bm chn khng t vng m trn bnh chn khng t ph u l c Bchner l bnh chn khng Phu lc Bchnerl Bm chn khng ng cao su Vng m
Bnh chn khng sk
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t ming lc sy v cn ln cc:
Lm t ming lc bng chai xt nc DI hoc nc RO.
Bc ny gip chu lc ht khi bm chn khng hot ng v gip ming lc khng di chuyn trong khi lc. Lc: M van my bm hot ng v t t mu vo ming lc
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Ra sch bnh nh mc vi DI hoc nc RO v nc ra trn ming lc. t ming lc trong l trong 3 gi 105 C +/- 3 C Lm ngui cc + ming lc trong bnh ht m Khi lng cui cng: Cn khi lng mng lc + c c kh ghi khi lng li theo n v milligram (Mf = khi lng cui) 5- Ghi kt qu V= Th tch m u (lt) Mi= Kh i lng mng l c + c c trc khi l c (milligrams) Mf= Khi lng mng l c + c c trc sau l c (milligrams) Hm lng rn l lng= (Mf-Mi)/V n v mg/L
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 89/90
G.COPIN:
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Cp Nht S Tay
Ngy 15/03/2013 Bn 1.0 Cp nht Bn u tin i din G.COPIN
Ngi vit G.COPIN
Ngy vit 15/03/2013
Cp nht 15/03/2013
Trang 90/90

PT Process Manual v1.0 - VN

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CNG NGH SN T CHU U: CNG NGH TIN X L

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

S TAY HNG DN K THUT

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Ngi vit G.COPIN

Ngy vit 15/03/2013

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Chc nng: Ty du (D1)

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Chy pH k c chnh thng s li trong ngy

Kt thc Kim sot bnh thng

Kim tra s ngng kt ca b v tham kho dch v k thut

Tng lng ha cht thm vo

Trung ha vi ph gia acid

Dng thm ha cht

Trn thm 30 pht, sau kim tra li

Ngi vit G.COPIN

Ngy vit 15/03/2013

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Biu Phn ng Ty Du / Kim T Do

Chy kim tra kim t do.

Gi tr kim t d c nm trong vng?

Kt thc Kim sot bnh thng

Tng lng ha cht thm vo

Dng thm ha cht

Trn thm 30 pht, sau kim tra li.

Ngi vit G.COPIN

Ngy vit 15/03/2013

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Biu Phn ng Ty Du / Tng Ga Tr Kim

Chy kim tra tng gi tr kim t do.

T ng gi tr ki m c n m trong kho ng?

Kt thc Kim sot bnh thng

Kt thc Kim sot bnh thng

X b nu cn. Pha long 5% vi nc DI

Trn thm 1 gi, sau kim tra li.

Ngi vit G.COPIN

Ngy vit 15/03/2013

CNG NGH SN T CHU U: CNG NGH TIN X L

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Nh my: Thnh ph H Ch Minh

Chu k lm vic: 6 pht Cng sut ti a: 8 sn phm/ gi

Chc nng: Ty du (D2)

S ln 1x/ca 1x/ca 1x/ca 2x/ca 1x/ngy 1x/ngy 1x/ngy 1x/ngy

Phng n 1.1 1.2 1.4 1.5 1.6 1.7

n v pH im im C g/L g/L g/L mg/L

CNG NGH SN T CHU U: CNG NGH TIN X L

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