CNG HA X HI CH NGHA VIT NAM

QCVN 07: 2009/BTNMT

QUY CHUN K THUT QUC GIA

V NGNG CHT THI NGUY HI
National Technical Regulation on Hazardous Waste
Thresholds

QCVN 07: 2009/BTNMT

H NI - 2009

QCVN 07: 2009/BTNMT

Li ni u

QCVN 07: 2009/BTNMT do Ban son tho quy chun

k thut quc gia v cht thi rn bin son, Tng cc
Mi trng, V Khoa hc v Cng ngh, V Php ch
trnh duyt v c ban hnh theo Thng t
s 25/2009/TT-BTNMT ngy 16 thng 11 nm 2009
ca B Ti nguyn v Mi trng.

QCVN 07: 2009/BTNMT

QUY CHUN K THUT QUC GIA

V NGNG CHT THI NGUY HI
National Technical Regulation on Hazardous Waste Thresholds

1. QUY NH CHUNG
1.1. Phm vi iu chnh
Quy chun ny quy nh ngng cht thi nguy hi i vi cc cht thi
v hn hp ca cc cht thi (tr cht thi phng x, cht thi th kh v
hi) c tn tng ng trong Danh mc cht thi nguy hi do B Ti nguyn v
Mi trng ban hnh.
1.2. i tng p dng
Quy chun ny p dng i vi: cc t chc, c nhn pht sinh cht
thi; cc n v c hot ng thu gom, vn chuyn, lu gi, x l, tiu hu,
chn lp cht thi; cc c quan qun l nh nc; n v ly mu, phn tch
v cc t chc, c nhn khc c hot ng lin quan n cht thi.
1.3. Gii thch t ng
Trong quy chun ny, cc t ng di y c hiu nh sau:
1.3.1. Cht thi nguy hi (CTNH) l nhng cht thi c tn (mi tn cht
thi tng ng vi mt m CTNH) trong Danh mc CTNH do B Ti nguyn
v Mi trng ban hnh (sau y gi tt l Danh mc CTNH), c chia
thnh hai loi sau:
a) L CTNH trong mi trng hp (c k hiu ** trong Danh mc
CTNH);
b) C kh nng l CTNH (c k hiu * trong Danh mc CTNH) c t nht
mt tnh cht nguy hi hoc mt thnh phn nguy hi vt ngng CTNH
theo quy nh ti Phn 2 ca Quy chun ny.
1.3.2. Ngng CTNH (cn gi l ngng nguy hi ca cht thi) l gii
hn nh lng tnh cht nguy hi hoc thnh phn nguy hi ca mt cht thi
lm c s phn nh, phn loi v qun l CTNH.

QCVN 07: 2009/BTNMT

1.3.3. Cht thi ng nht (homogeneous) l cht thi c thnh phn v

tnh cht ho-l tng i ng nht ti mi im trong khi cht thi.
1.3.4. Hn hp cht thi l hn hp ca t nht hai loi cht thi ng
nht, k c trng hp c ngun gc do kt cu hay cu thnh c ch nh
(nh cc phng tin, thit b thi). Cc cht thi ng nht cu thnh nn
hn hp cht thi c gi l cht thi thnh phn.
Hn hp cht thi m cc cht thi thnh phn c ho trn vi
nhau mt cch tng i ng nht v tnh cht ho-l ti mi im trong khi
hn hp cht thi th c coi l cht thi ng nht.
1.3.5. Tp cht bm dnh l cc cht lin kt cht trn b mt (vi
dy trung bnh khng qu 01 mm hoc hm lng khng qu 01% trn tng
khi lng cht thi, khng b ri ra trong iu kin bnh thng) ca cht thi
hoc hn hp cht thi nn dng rn v khng c coi l cht thi thnh
phn trong hn hp cht thi.
1.3.6. Hm lng tuyt i l hm lng phn trm (%) hoc phn triu
(ppm) ca mt thnh phn nguy hi trong cht thi. Ngng hm lng tuyt
i (Htc) l ngng CTNH tnh theo hm lng tuyt i.
1.3.7. Nng ngm chit (eluate/leaching) l nng (mg/l) ca mt
thnh phn nguy hi trong dung dch sau ngm chit, c thi ra t cht thi
khi tin hnh chun b mu phn tch bng phng php ngm chit. Ngng
nng ngm chit (Ctc) l ngng CTNH tnh theo nng ngm chit.
1.3.8. Phng php ngm chit l phng php EPA 1311 hoc ASTM
5233-92 quy nh ti Phn 4 ca Quy chun ny.
1.3.9. Dung dch ngm chit l dung dch c pha ch s dng cho
vic ngm chit cht thi theo phng php ngm chit.
1.3.10. Dung dch sau ngm chit l dung dch thu c t qu trnh
ngm chit mu cht thi theo phng php ngm chit.

2. QUY NH K THUT V NGNG CTNH

2.1. Nguyn tc chung
2.1.1. Mt cht thi c k hiu * trong Danh mc CTNH c phn nh
l CTNH nu c t nht mt trong cc iu kin sau y:
5

QCVN 07: 2009/BTNMT

a) C t nht mt tnh cht nguy hi vt ngng CTNH (nhit chp

chy, kim hoc axit tng ng vi cc mc gi tr quy nh ti ct
Ngng CTNH trong Bng 1);
b) C t nht mt thnh phn nguy hi v c hoc hu c m ng thi
gi tr hm lng tuyt i v gi tr nng ngm chit u vt ngng
CTNH (ln hn hoc bng mc gi tr ngng hm lng tuyt i (H tc) v
ngng nng ngm chit (Ctc) quy nh ti im 2.1.5).
Trng hp khng s dng c hai gi tr hm lng tuyt i hoc
nng ngm chit (i vi cc thnh phn nguy hi khng c c hai ngng
Htc v Ctc hoc khng c iu kin s dng c hai ngng) th vic phn nh
CTNH s ch p dng theo mt ngng c s dng.
2.1.2. Mt cht thi c k hiu * trong Danh mc CTNH c phn nh
khng phi l CTNH nu tt c cc tnh cht hoc thnh phn nguy hi u
khng vt ngng CTNH (hay cn gi l di ngng CTNH), c th nh
sau:
a) Nhit chp chy, kim hoc axit khng tng ng vi
cc mc gi tr quy nh ti ct Ngng CTNH trong Bng 1;
b) Tt c cc thnh phn nguy hi u c gi tr nh hn mt trong hai
ngng hm lng tuyt i (Htc) hoc ngng nng ngm chit (Ctc) quy
nh ti im 2.1.5.
2.1.3. Trng hp mt cht thi c phn nh l CTNH, bt k
thuc loi * hoc ** trong Danh mc CTNH th ch c phn loi theo tn v
m CTNH ca loi c cha mt (hoc mt nhm) thnh phn nguy hi nht
nh khi thnh phn ny (hoc t nht mt thnh phn trong nhm thnh phn)
vt ngng hm lng tuyt i (Htc) quy nh ti im 2.1.5; nu khng
vt ngng hm lng tuyt i (Htc) th khng phn loi theo thnh phn
nguy hi ny, hay mt cch biu kin, thnh phn nguy hi ny c coi l
khng c trong cht thi ( mc nguy hi).
2.1.4. Mt CTNH sau khi c x l m tt c cc tnh cht hoc thnh
phn nguy hi u di mt trong hai ngng H tc hoc Ctc th khng cn l
CTNH v khng phi qun l theo cc quy nh i vi CTNH.
2.1.5. Ngng hm lng tuyt i (Htc) v ngng nng ngm chit
(Ctc) c xc nh theo nguyn tc nh sau:
6

QCVN 07: 2009/BTNMT

a) Ngng nng ngm chit (Ctc, mg/l) c quy nh ti ct Nng

ngm chit, Ctc ca Bng 2 v 3;
b) Ngng hm lng tuyt i (H tc, ppm) c tnh bng cng thc
sau:
Htc =

H.(1+19.T)
20

Trong :
- H (ppm) l gi tr quy nh trong ct Hm lng tuyt i c s, H
ca Bng 2 v 3 ca Quy chun lm c s tnh ton gi tr Htc;
- T l t s gia khi lng thnh phn rn kh trong mu cht thi trn
tng khi lng mu cht thi.
2.2. Gi tr ngng CTNH
2.2.1. Cc tnh cht nguy hi
Bng 1: Cc tnh cht nguy hi
TT

Tnh cht nguy hi

Ngng CTNH

Tnh d bt chy

Nhit chp chy 60 0C

Tnh kim

pH 12,5

Tnh axt

pH 2,0

QCVN 07: 2009/BTNMT

2.2.2. Cc thnh phn nguy hi v c

Bng 2: Cc thnh phn nguy hi v c
Ngng CTNH
TT

Thnh phn nguy hi(1)

Cng thc
ho hc

Hm lng
tuyt i c
s, H (ppm)

Nng
ngm chit,
Ctc (mg/l)

Nhm kim loi nng v hp cht v c ca chng

(tnh theo nguyn t kim loi)
1

Antimon (Antimony)(2)

Sb

20

Asen (Arsenic)(#)

As

40

Bari (Barium) tr bari

sunphat (barium sulfate)

Ba

2.000

100

Bc (Silver)(#)(2)

Ag

100

Beryn (Beryllium)(#)

Be

0,1

Cadmi (Cadmium)(#)

Cd

10

0,5

Ch (Lead)(2)

Pb

300

15

Coban (Cobalt)

Co

1.600

80

Km (Zinc) (2)

Zn

5.000

250

10

Molybden (Molybdenum)
tr molybden disunphua
(molybdenum disulfide)

Mo

7.000

350

11

Nicken (Nickel)(2)

Ni

1.400

70

12

Selen (Selenium)(#)

Se

20

13

Tali (Thallium)

Ta

140

14

Thy ngn (Mercury)(#)

Hg

0,2

15

Crom VI (Chromium VI) (#)(2)

Cr

100

16

Vanadi (Vanadium)

Va

500

25

Cc thnh phn v c khc

17

Mui florua (Fluoride) tr

canxi florua (calcium
floride)

F_

3.600

18

Xyanua hot ng
(Cyanides amenable)(#)

CN-

30

19

Tng Xyanua
(Total cyanides)(4)

CN-

590

20

Aming (Abestos)(5)

10.000
8

180

QCVN 07: 2009/BTNMT

2.2.3. Cc thnh phn nguy hi hu c

Bng 3: Cc thnh phn nguy hi hu c
Ngng CTNH

TT

Thnh phn nguy hi(1)

S CAS(3)

Cng thc
ho hc

Hm
Nng
lng

tuyt
ngm
i
chit,
c s,
Ctc
H (ppm) (mg/l)

Cresol/Phenol
1a

o-Cresol (o-Cresol)

95-48-7

CH3C6H4OH

4.000

200

1b

m-Cresol (m-Cresol)

108-39-4

CH3C6H4OH

4.000

200

1c

p-Cresol (p-Cresol)

106-44-5

CH3C6H4OH

4.000

200

Tng Cresol(4)

CH3C6H4OH

4.000

200

2-4-Dimetyl phenol (2,4-Dimethyphenol)

105-67-9

C6H3(CH3)2OH

1.400

70

2-6-Dimetyl phenol (2,6-Dimethyphenol)

576-26-1

C6H3(CH3)2OH

400

20

Phenol (Phenol)

108-95-2

C6H5OH

20.000

1.000

Clophenol
5

2-Clophenol (2-Chlorophenol)

95-57-8

C6H5ClO

400

20

2,4-Diclophenol (2,4-Dichlorophenol)

120-83-2

C6H3Cl2OH

200

10

2,6-Diclophenol (2,6-Dichlorophenol)

87-65-0

C6H3Cl2OH

3.000

Pentaclophenol (Pentachlorophenol)

87-86-5

C6OHCl5

2.000

100

QCVN 07: 2009/BTNMT

Thnh phn nguy hi(1)

2,3,4,6-Tetraclophenol (2,3,4,6-Tetrachlorophenol)

S CAS(3)
58-90-2

Cng thc
hc
Cho
6HCl4OH

10

2,4,5-Triclophenol (2,4,5-Trichlorophenol)

95-95-4

11

2,4,6-Triclophenol (2,4,6-Trichlorophenol)(#)

TT
9

Ngng CTNH
2.000

100

C6H2Cl3OH

8.000

400

88-06-2

C6H2Cl3OH

40

Nitrophenol
12

2-Butyl-4,6-dinitrophenol
(2-sec-Butyl-4,6-dinitrophenol/Dinoseb)(#)

88-85-7

C10H12N2O5

70

3,5

13

2,4-Dinitrophenol (2,4-Dinitrophenol)

51-28-5

C6H3OH(NO2)2

140

14a

o-Nitrophenol (o-Nitrophenol)

88-75-5

C6H4OHNO2

10.000

14b

p-Nitrophenol (p-Nitrophenol)

100-02-7

C6H4OHNO2

10.000

14

Tng Nitrophenol(4)

C6H4OHNO2

10.000

Dn xut halogen ca hydrocacbon d bay hi

15

Bromdiclometan (Bromodichloromethane) (#)

75-27-4

CHBrCl2

0,3

16

Brommetan/Metyl bromua (Bromomethane/Methyl bromide)(#)

74-83-9

CH3Br

100

17

Cacbon tetraclorua (Carbon tetrachloride)(#)

56-23-5

CCl4

10

0,5

18

Clobenzen (Chlorobenzene)

108-90-7

C6H5Cl

1.400

70

19

Clodibrommetan (Chlorodibromomethane)

124-48-1

CHClBr2

3.000

20

Cloetan (Chloroethane)

75-00-3

C2H5Cl

1.000

21

Clorofom (Chloroform)(#)

67-66-3

CHCl3

100

22

Clometan/Methyl clorua (Chloromethane/Methyl chloride)

74-87-3

CH3Cl

1.000

10

QCVN 07: 2009/BTNMT

Ngng CTNH

Thnh phn nguydibromua

hi
1,2-Dibrometan/Etylen
(1,2-Dibromoethane/Ethylene dibromide)(#)

S CAS
106-93-4

Cng thc
ho
C2H4hc
Br2

24

Dibrommetan (Dibromomethane)

74-95-3

CH2Br2

20.000

25

Diclodiflometan (Dichlorodifluoromethane)

75-71-8

CCl2F2

1.400

700

26a

1,1-Dicloetan (1,1-Dichloroethane)(#)

75-34-3

C2H4Cl2

10

0,5

26b

1,2-Dicloetan (1,2-Dichloroethane)(#)

107-06-2

C2H4Cl2

10

0,5

26

Tng Dicloetan(#)(4)

C2H4Cl2

10

0,5

27

1,1-Dicloetylen (1,1-Dichloroethylene)(#)

75-35-4

C2H2Cl2

10

0,5

28a

m-Diclobenzen (m-Dichlorobenzene)(#)

541-73-1

m-C6H4Cl2

100

28b

o-Diclobenzen (o-Dichlorobenzene)(#)

95-50-1

o-C6H4Cl2

100

28c

p-Diclobenzen (p-Dichlorobenzene)(#)

106-46-7

p-C6H4Cl2

100

28

Tng Diclobenzen(#)(4)

100

29

1,3-Diclopropen (1,3-Dichloropropene)(#)

542-75-6

C3H4Cl2

20

30

cis-1,3-Diclopropylen (cis-1,3-Dichloropropylene)

10061-01-5

C3H4Cl2

3.000

31

trans-1,2-Dicloetylen (trans-1,2-Dichloroethylene)

156-60-5

C2H2Cl2

20.000

32

trans-1,3-Diclopropylen (trans-1,3-Dichloropropylene)

10061-02-6

C3H4Cl2

3.000

33

Metylen clorua (Methylene chloride)

75-09-2

CH2Cl2

1.000

50

34

1,1,1,2-Tetracloetan (1,1,1,2-Tetrachloroethane)(#)

630-20-6

C2H2Cl4

100

35

1,1,2,2-Tetracloetan (1,1,2,2-Tetrachloroethane)(#)

79-34-5

C2H2Cl4

40

36

Tetracloetylen (Tetrachloroethylene)(#)

127-18-4

C2Cl4

10

0,5

TT
23

(1)

(3)

11

0,2

0,01

QCVN 07: 2009/BTNMT

Thnh phn nguy hi(1)

Tribrommetan/Bromofom (Tribromomethane/Bromoform)

S CAS(3)
75-25-2

Cng thc
ho
hc
CHBr
3

38

1,1,1-Tricloetan (1,1,1-Trichloroethane)

71-55-6

39

1,1,2-Tricloethan (1,1,2-Trichloroethane)(#)

40
41

TT
37

Ngng CTNH
1.400

70

C2H3Cl3

6.000

300

79-00-5

C2H3Cl3

100

Tricloetylen (Trichloroethylene)(#)

79-01-6

C2HCl3

20

Vinyl clorua (Vinyl chloride)(#)

75-01-4

C2H3Cl

0,2

Hydrocacbon d bay hi
42

Benzen (Benzene)(#)

71-43-2

C6 H6

10

0,5

43

Etyl benzen (Ethyl benzene)

100-41-4

C6 H5 C2 H5

8.000

400

44

Toluen (Toluene)

108-88-3

C6H5CH3

20.000

1.000

45

Xylen-cc ng phn (tng nng ca o-, m-, p-xylen)

[Xylenes-mixed isomers (sum of o-, m-, and p-xylene
concentrations)]

1330-20-7

C6H4(CH3)2

20.000

1.000

Hydrocacbon thm a vng (PAH)

46

Antraxen (Anthracene)(#)

120-12-7

C14H10

100

47

Axenapten (Acenaphthene)

83-32-9

C12H10

4.000

48

Benzantraxen (Benz(a)anthracene)(#)

56-55-3

C18H12

100

49

Dibenz(a,h)antraxen (Dibenz(a,h)anthracene)(#)

53-70-3

C22H14

100

50

Benzo(j)fluoranten (Benzo(j)fluoranthene)

205-82-3

C20H12

3.000

51

Benzo(k)floanten (Benzo(k)fluoranthene)(#)

207-08-9

C20H12

100

52

Benzo(a)pyren (Benzo(a)pyrene)(#)

50-32-8

C20H12

100

12

200

QCVN 07: 2009/BTNMT

Ngng CTNH

TT
53

(1)
Thnh phn nguy hi
(#)
Crysen (Chrysene)

S CAS(3)
218-01-9

Cng thc
ho
hc
C18H
12

54

Floanten (Fluoranthene)

206-44-0

C16H10

3.000

150

55

Floren (Fluorene)

86-73-7

C13H10

3.000

150

56

Naptalen (Naphthalene)

91-20-3

C10H8

1.000

57

Phenantren (Phenanthrene)

85-01-8

C14H10

200

58

Pyren (Pyrene)(#)

129-00-0

C16H10

100

100

Phtalat
59

Butyl benzyl phtalat (Butyl benzyl phthalate)

85-68-7

C19H20O4

10.000

500

60

Dietyl phtalat (Diethyl phthalate)

84-66-2

C6H4(COOC2H5)2

20.000

1.000

61

Dietyl hexyl phtalat [Bis(2-ethylhexyl) phthalate]

117-81-7

C24H38O4

600

30

62

Dimetyl phtalat (Dimethyl phthalate)

131-11-3

C6H4(COOCH3)2

1.000

63

Di-n-butyl phtalat (Di-n-butyl phthalate)

84-74-2

C6H4(COOC4H9)2

8.000

64

Di-n-octyl phtalat (Di-n-octyl phthalate)

117-84-0

C6H4(COOC8H17)2

1.000

400

Ho cht bo v thc vt c clo (OCP)

65

Andrin (Aldrin)(#)

309-00-2

C12H8Cl6

10

0,5

66a

-BHC (-BHC)(#)

319-84-6

C6H6Cl6

0,3

66b

-BHC (-beta-BHC)(#)

319-85-7

C6H6Cl6

0,3

66c

-BHC (-BHC)(#)

319-86-8

C6H6Cl6

0,3

66d

-BHC/Lindan (-BHC/Lindane)(#)

58-89-9

C6H6Cl6

0,3

13

QCVN 07: 2009/BTNMT

Thnh phn nguy

hi(1)
(#)(4)
Tng BHC

S CAS(3)

Cng thc
ho
C6H6hc
Cl6

67

Clodan (Chlordane)(#)

57-74-9

68a

o,p'-DDD(#)

68b

TT
66

Ngng CTNH
6

0,3

C10H6Cl8

0,6

0,03

53-19-0

C14H10Cl4

20

p,p'-DDD(#)

72-54-8

C14H10Cl4

20

68c

o,p'-DDE(#)

3424-82-6

C14H8Cl4

20

68d

p,p'-DDE(#)

72-55-9

C14H8Cl4

20

68e

o,p'-DDT(#)

789-02-6

C14H9Cl5

20

68g

p,p'-DDT(#)

50-29-3

C14H9Cl5

20

68

Tng DDD, DDE, DDT(#)(4)

20

69

2,4-Diclophenoxyaxetic axit/2,4-D
(2,4-Dichlorophenoxyacetic acid/2,4-D)(#)

94-75-7

C6H3Cl2OCH2COOH

100

70

Dieldrin (Dieldrin)(#)

60-57-1

C12H8Cl6O

0,4

0,02

71a

Endosulfan I (Endosulfan I)(#)

959-98-8

C9H6Cl6O3S

0,2

71b

Endosulfan II (Endosulfan II)(#)

33213-65-9

C9H6Cl6O3S

0,2

71

Tng Endosulfan(#)(4)

C9H6Cl6O3S

0,2

72

Endosulfan sulfat (Endosulfan sulfate)(#)

1031-07-8

C9H6Cl6O4S

100

73

Endrin (Endrin)(#)

72-20-8

C12H8Cl6O

0,4

0,02

74

Endrin aldehyt (Endrin aldehyde)(#)

7421-93-4

C12H8Cl6O

0,4

0,02

75

Heptaclo (Heptachlor)(#)

76-44-8

C10H5Cl7

0,2

0,01

76

Heptaclo epoxit (Heptachlor epoxide)(#)

1024-57-3

C10H5Cl7O

0,8

0,04

14

QCVN 07: 2009/BTNMT

Thnh phn nguy hi(1)

Hexaclobenzen (Hexachlorobenzene)(#)

S CAS(3)
118-74-1

Cng thc
ho
hc
C6Cl
6

78

Hexaclobutadien (Hexachlorobutadiene)(#)

87-68-3

79

Hexaclocyclopentadien (Hexachlorocyclopentadiene)(#)

80

TT
77

Ngng CTNH
3

0,15

C4Cl6

0,4

77-47-4

C5Cl6

100

Hexacloetan (Hexachloroethane)(#)

67-72-1

C2Cl6

60

81

Hexaclophen (Hexachlorophene)(#)

70-30-4

C13H6Cl6O2

20

82

Isodrin (Isodrin)(#)

465-73-6

C12H8Cl6

10

83

Kepon (Kepone)(#)

143-50-0

C10H10O

40

84

Metoxyclo (Methoxychlor)

72-43-5

C16H15Cl3O

200

10

85

Mirex (Mirex)(#)

2385-85-5

C10Cl12

14

0,7

86

Pentaclobenzen (Pentachlorobenzene)(#)

608-93-5

C6HCl5

60

87

Toxaphen (Toxaphene)(#)

8001-35-2

C10H10Cl8

0,3

88

1,2,4-Triclobenzen (1,2,4-Trichlorobenzene)

120-82-1

C6H3Cl3

1.400

70

Ho cht bo v thc vt c photpho

89

Disulfoton (Disulfoton)(#)

298-04-4

C8H19O2PS3

0,1

90

Metyl paration (Methyl parathion)(#)

298-00-0

(CH3O)2PSOC6H4NO2

20

91

Phorat (Phorate)(#)

298-02-2

C7H17O2PS3

100

Ho cht bo v thc vt cacbamat

92

Paration (Parathion)

56-38-2

C10H14NO5PS

400

93

Propoxua (Propoxur)(#)

114-26-1

C11H15NO3

100

15

20

QCVN 07: 2009/BTNMT

TT

Thnh phn nguy hi(1)

S CAS(3)
Cc ho cht bo v thc vt khc

Cng thc
ho hc

Ngng CTNH

94

Silvex/2,4,5-TP (Silvex/2,4,5-TP)(#)

93-72-1

C9H7Cl3O3

20

95

2,4,5-Triclophenoxyaxetic axit/2,4,5-T
(2,4,5-Trichlorophenoxyacetic acid/2,4,5-T)(#)

93-76-5

C6H2Cl3OCH2COOH

100

Ete
96

Di-Clo etyl ete [bis(2-Chloroethyl)ether](#)

111-44-4

C4H8Cl2O

97

Clo metyl ete [bis (Chloromethyl) ether](#)

524-88-1

C2H4Cl2O

10

98

Di-Clo isopropyl ete [bis(2-Chloroisopropyl)ether](#)

39638-32-9

C6H12Cl2O

100

99

Dietyl ete (Diethyl ether)

60-29-7

C2H5OC2H5

20.000

Metyl clo metyl ete (Methyl chloromethyl ether)(#)

107-30-2

CH3OCH2Cl

10

100

0,3

PCB v Dioxin/Furan
101

PCB (Tng tt c ng phn PCB hoc tt c Aroclo)(#)

1336-36-3

102a

2,3,7,8-TCDD(#)

1746-01-6

C12H4Cl4O2

0,1

0,005

102b

1,2,3,7,8-PeCDD(#)

40321-76-4

C12H3Cl5O2

0,2

0,01

102c

1,2,3,4,7,8-HxCDD(#)

57653-85-7

C12H2Cl6O2

0,05

102d

1,2,3,6,7,8-HxCDD(#)

34465-46-8

C12H2Cl6O2

0,05

102

Tng Dioxin (TCDD, PeCDD, HxCDD)(#)(6)

0,1

0,005

103a

2,3,7,8-TCDF(#)

51207-31-9

C12H4Cl4O

0,05

103b

1,2,3,7,8-PeCDF(#)

57117-41-6

C12H3Cl5O

0,1

103c

2,3,4,7,8-PeCDF(#)

57117-31-4

C12H3Cl5O

0,2

0,01

16

QCVN 07: 2009/BTNMT

TT
103d

(1)
Thnh phn nguy hi
(#)
1,2,3,4,7,8-HxCDF

S CAS(3)
70648-26-9

Cng thc
hc
Cho
12H2Cl6O

103e

1,2,3,6,7,8-HxCDF(#)

57117-44-9

C12H2Cl6O

103

Tng Furan (TCDF, PeCDF, HxCDF)(#)(7)

Ngng CTNH
1

0,05

0,05

0,2

0,01

Du (tr loi c ngun gc thc phm)

104a

Du hydrocacbon <C10

1.000

50

104b

Du hydrocacbon C10-C16

3.000

150

104c

Du hydrocacbon C17-C34

5.000

250

104d

Du hydrocacbon C35

10.000

500

104

Tng du(8)

1.000

50

Hp cht c kim
105

Tng thu ngn hu c(#)

100

106

Tng ch hu c(#)

10
Hp cht silic hu c

107

Metyl etyl dimetoxy silan [Bis(1-methylethyl)-dimethoxysilane]

18230-61-0

C8H20O2Si

20.000

108

Bis(4-flophenyl) (metyl) (1H-1,2,4-triazol-1-ylmetyl) silan

[Bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-ylmethyl)silane]

85509-19-9

C16H15F2N3Si

1.000

C9H22O2Si

20.000

109

Isobutyl isopropyl dimetoxy silan (Isobutylisopropyldimethoxysilane) 111439-76-0

110

Tetraetyl silicat (Tetraethyl silicate)

78-10-4

(C2H5O)4Si

20.000

111

Trietoxy isobutyl silan (Triethoxyisobutylsilane)

17980-47-1

C10H24O3Si

20.000

17

QCVN 07: 2009/BTNMT

TT
112

(1)

(3)

Thnh phn nguy

hi silan
Tris(isopropenyloxy)
phenyl
[Tris(isopropenyloxy)phenyl silane](#)

S CAS
52301-18-5

Cng thc
ho hc

Ngng CTNH
100

Cc thnh phn hu c khc

113

Acrylamid (Acrylamide)(#)

79-06-1

C2H3CONH2

1,6

0,08

114

Acrylnitril (Acrylonitrile)(#)

107-13-1

C2H3CN

12

0,6

115

4-Aminodiphenyl (4-Aminodiphenyl)(#)

92-67-1

C12H9NH2

10

116

Anilin (Aniline

62-53-3

C6H5NH2

1.200

60

117

Axetonitril (Acetonitrile)

75-05-8

CH3CN

400

20

118

Axeton (Acetone)

67-64-1

C3 H6 O

8.000

400

119

Axetophenon (Acetophenone)

96-86-2

C8 H8 O

8.000

400

120

2-Axetylaminfloren (2-Acetylaminofluorene)

53-96-3

C15H13NO

200

10

121

Benzal clorua (Benzal chloride)(#)

98-87-3

C7H6Cl2

100

122

Benzidin (Benzidine) v mui ca chng(#)

92-87-5

C12H8(NH2)2

0,2

123

n-Butyl alcol (n-Butyl alcohol)

71-36-3

C4H7OH

10.000

124

Cacbon disulfua (Carbon disulphide)

75-15-0

CS2

8.000

125

p-Cloanilin (p-Chloroaniline)(#)

106-47-8

C6H4ClNH2

100

126

2-Clo-1,3-butadien (2-Chloro-1,3-butadiene)(#)

126-99-8

C4H5Cl

100

127

p-Clo-m-cresol (p-Chloro-m-cresol)

59-50-7

C7H7ClO

20.000

128

Cyclohexanon (Cyclohexanone)

108-94-1

C6H10O

20.000

129

1,2-Dibrom-3-clopropan (1,2-Dibromo-3-chloropropane)(#)

96-12-8

C3H5Br2Cl

10

18

0,01
400

1.000

QCVN 07: 2009/BTNMT

Ngng CTNH

TT
130

Thnh phn nguy hi(1)

3,3'-Diclobenzidin (3,3'-Dichlorobenzidine) v mui ca chng(#)

S CAS(3)
91-94-1

Cng thc
hc
Cho
12H10Cl2N2

131

4-Dimetylaminazobenzen (4-Dimethylaminoazobenzene)(#)

60-11-7

C14H15N3

10

132

1,4-Dinitrobenzen (1,4-Dinitrobenzene)(#)

100-25-4

C6H4(NO2)2

100

133

m-Dinitrobenzen (m-Dinitrobenzene)(#)

99-65-0

C6H4(NO2)2

134

4,6-Dinitro-o-cresol (4,6-Dinitro-o-cresol)(#)

534-52-1

CH3C6H2OH(NO2)2

100

135

1,2-Diclopropan (1,2-Dichloropropane)

78-87-5

C3H6Cl2

20.000

136a

2,4-Dinitrotoluen (2,4-Dinitrotoluene)(#)

121-14-2

CH3C6H3(NO2)2

0,15

136b

2,6-Dinitrotoluen (2,6-Dinitrotoluene) (#)

606-20-2

CH3C6H3(NO2)2

0,15

136c

2,3-Dinitrotoluen (2,3-Dinitrotoluene)(#)

602-01-7

CH3C6H3(NO2)2

0,15

136

Tng Dinitrotoluen(#)(4)

CH3C6H3(NO2)2

0,15

137

Di-n-propylnitrosamin (Di-n-propylnitrosamine)(#)

621-64-7

C6H14N2O

0,05

138

1,4-Dioxan (1,4-Dioxane)

123-91-1

C4H8O2

600

30

139

Diphenylamin (Diphenylamine)

122-39-4

(C6H5)2NH

1.800

90

140

1,2-Diphenylhydrazin (1,2-Diphenylhydrazine)(#)

122-66-7

C12H12N2

0,4

141

Etyl axetat (Ethyl acetate)

141-78-6

CH3COOC2H5

10.000

142

Etylenimin (Ethyleneimine) hay Aziridene (Aziriden)(#)

115-56-4

C2 H5 N

10

143

Etyl metacrylat (Ethyl methacrylate)

97-63-2

C6H10O2

15.000

144

Iodmetan (Iodomethane)

74-88-4

CH3I

1.000

145

Isobutyl alcol (Isobutyl alcohol)

78-83-1

C4H9OH

10.000

146

Metacrylnitril (Methacrylonitrile) (#)

126-98-7

C4 H5 N

19

16

0,8

0,4

0,4

QCVN 07: 2009/BTNMT

Ngng CTNH

TT
147

Thnh phn nguy hi(1)

Metanol (Methanol)

S CAS(3)
67-56-1

Cng thc
ho
hc
CH3OH

148

4,4-Metylen dicloanilin) [4,4-Methylene bis(2-chloroaniline)] (#)

101-14-4

C13H12Cl2N2

100

149

Metyl etyl keton (Methyl ethyl ketone)

78-93-3

C4 H8 O

4.000

200

150

Metyl isobutyl keton (Methyl isobutyl ketone)

108-10-1

C6H12O

4.000

200

151

-Naptylamin (-Naphthylamine)(#)

134-32-7

C10H9N

10

152

-Naptylamin (-Naphthylamine)(#)

91-59-8

C10H9N

10

153

o-Nitroanilin (o-Nitroaniline)

88-74-4

NO2C6H4NH2

3.000

154

p-Nitroanilin (p-Nitroaniline)

100-01-6

NO2C6H4NH2

3.000

155

Nitrobenzen (Nitrobenzene)(#)

98-95-3

C6H5NO2

40

156

4-Nitrobiphenyl (4-Nitrobiphenyl)(#)

92-93-3

C12H9NO2

10

157

5-Nitro-o-toluidin (5-Nitro-o-toluidine)

99-55-8

CH3NO2C6H3NH2

1.000

158

N-Nitrosodimetylamin (N-Nitrosodimethylamine)(#)

62-75-9

(CH3)2N2O

10

159

N-Nitroso-di-n-butylamin (N-Nitroso-di-n-butylamine)(#)

924-16-3

C8H18N2O

1,2

0,06

160

N-Nitrosometyletylamin (N-Nitrosomethylethylamine)(#)

10595-95-6

C3 H8 N2 O

0,4

0,02

161

N-Nitrosopyrolidin (N-Nitrosopyrrolidine)(#)

930-55-2

C4 H8 N2 O

0,2

162

Pentacloetan (Pentachloroethane)

76-01-7

C2HCl5

1.000

163

Pentaclonitrobenzen (Pentachloronitrobenzene)

82-68-8

C6NO2Cl5

200

164

Ptalic anhydrit (Phthalic anhydride)

85-44-9

C8H4O3

10.000

165

-Propilacton (-Propiolactone)(#)

57-57-8

C3H4O2

10

20

3.000

10

QCVN 07: 2009/BTNMT

Ngng CTNH

TT
166

(1)
Thnh phn nguy hi
(#)
Pyridin (Pyridine)

S CAS(3)
110-86-1

Cng thc
ho
C5Hhc
5N

167

Safrol (Safrole)(#)

94-59-7

C10H10O2

100

168

1,2,3-Triclopropan (1,2,3-Trichloropropane)

96-18-4

C3H5Cl3

400

21

80

4
20

QCVN 07: 2009/BTNMT

2.2.4. Ch thch:
(1)

Trong ngoc l tn ha cht theo ting Anh;

(2)

Trng hp cc ph liu kim loi ca antimon, bc, ch, km, nicken,

crom hoc ph liu hp kim c cha cc kim loi ny c lm sch, khng

ln tp cht, khng cha cc thnh phn nguy hi khc vt ngng CTNH,
dng thanh, khi, tm, on thanh, on ng, u mu, u tm, u ct,
phoi, si, mnh (khng phi dng bt), c tch ring cho mc ch ti ch,
ti s dng th cc kim loi ny khng tnh l thnh phn nguy hi v c trong
ph liu;
(3)

CAS l tn vit tt ca Chemical Abstracts Service Registry Numbers,

l s ng k tn cc ha cht;
(4)

Phi lun p dng gi tr tng i vi cc thnh phn ny;

(5)

Ch p dng i vi aming (bao gm cc loi chrysotile hay aming

trng, amosite hay aming nu, crocidolite hay aming xanh, tremolite,
anthophyllite v actinolite) trong cht thi dng bt, si, b, d vn; khng
p dng i vi vt liu aming-ximng thi;
(6)

Ch p dng gi tr tng trong trng hp khng p dng phn bit

theo tng nhm cht (TCDD, PeCDD, HxCDD);

(7)

Ch p dng gi tr tng trong trng hp khng p dng phn bit

theo tng nhm cht (TCDF, PeCDF, HxCDF);

(8)

Ch p dng gi tr tng trong trng hp khng p dng phn bit

theo s phn t C (cacbon);

(#)

Thnh phn nguy hi c bit (c tnh cht cc c hoc c kh nng

gy ung th hay gy t bin gen rt cao) vi ngng hm lng tuyt i

nh hn hoc bng 100 ppm.

3. QUY NH K THUT V LY MU, PHN TCH,

PHN NH V PHN LOI CTNH
3.1. Nguyn tc chung
3.1.1. Mi cht thi thuc loi ** hoc hn hp cht thi c cha t nht
mt cht thi thnh phn thuc loi ** trong Danh mc CTNH khng phi ly
mu, phn tch so snh vi ngng CTNH m phn nh ngay l CTNH
22

QCVN 07: 2009/BTNMT

hoc hn hp CTNH, tr trng hp phn tch cho mc ch khc, trong

c vic phn tch phn loi CTNH theo thnh phn nguy hi theo quy nh
ti im 2.1.3.
3.1.2. Mi cht thi thuc loi * hoc hn hp cht thi thuc loi * khi
cha chng minh c khng phi l CTNH th phi c qun l theo cc
quy nh i vi CTNH.
3.1.3. Nu mt dng cht thi pht sinh thng xuyn (c tnh cht lp
i lp li mt cch tng i n nh) t mt ngun thi nht nh (nh bn
thi t h thng x l nc thi) c tnh cht hoc thnh phn nguy hi lc
vt ngng, lc khng vt ngng (di ngng) CTNH ti cc thi im
ly mu khc nhau th phi phn nh chung dng cht thi l CTNH, tr
trng hp phn nh ring cho tng l cht thi ring l trong dng cht thi
.
3.1.4. Hn hp cht thi c t nht mt cht thi thnh phn l CTNH b
coi l CTNH (hay hn hp CTNH) v phi qun l theo cc quy nh i vi
CTNH.
3.2. Quy nh i vi n v ly mu, phn tch
3.2.1. n v ly mu, phn tch phi c cng nhn cht lng (i
vi cc phng php xc nh v cc thng s phn tch quy nh ti Quy
chun ny) hoc c c quan qun l nh nc v mi trng ch nh. Cc
kt qu phn tch ca n v cha c cng nhn m khng do c quan
qun l nh nc v mi trng ch nh ch c tnh cht tham kho, khng c
gi tr trc php lut.
3.2.2. n v ly mu, phn tch phi c trch nhim nh sau:
a) Phi chu trch nhim trc php lut v vic ly mu v kt qu
phn tch mu lm c s phn nh, phn loi CTNH;
b) Phi c cn b c nng lc tin hnh ly mu v lp bin bn ly
mu km theo (kt qu phn tch trn mu c ly bi ch ngun thi hoc
n v cha c cng nhn m khng do c quan qun l nh nc v mi
trng ch nh ch c tnh cht tham kho, khng c gi tr trc php lut);
c) Phi p dng ng nguyn tc ly mu v phng php xc nh quy
nh ti Quy chun ny.

23

QCVN 07: 2009/BTNMT

3.2.3. Trng hp c tranh chp do s khc bit gia kt qu phn tch

ca hai n v ly mu, phn tch th c quan qun l nh nc v mi trng
ch nh mt n v ly mu, phn tch th ba (c chnh thc cng nhn
cht lng) lm trng ti, ng thi yu cu hai n v ly mu, phn tch nu
trn tin hnh lp li kim tra i chiu.
3.3. Nguyn tc ly mu, phn tch, phn nh v phn loi CTNH
Ngoi quy nh c th v phng php ly mu nu trong cc phng
php xc nh quy nh ti Phn 4 ca Quy chun ny hoc cc phng php
ly mu khc c cng nhn trong nc hoc quc t, vic ly mu, phn
tch, phn nh v phn loi CTNH phi c tin hnh theo nguyn tc c
bn nh sau:
3.3.1. i vi cc cht thi ng nht th rn thuc loi *: ly t nht
03 mu i din ngu nhin cc v tr khc nhau trong khi cht thi (c tnh
n s phn b i din ca kch thc cc ht hoc phn t trong khi cht
thi) v s dng gi tr trung bnh ca kt qu phn tch so snh vi
ngng CTNH nhm phn nh c phi l CTNH hay khng.
3.3.2 i vi cht thi lng, bn thuc loi * hoc hn hp ca chng:
phi khy, trn u (nu c th) trc khi ly t nht 03 mu i din ngu
nhin cc v tr khc nhau v s dng gi tr trung bnh ca kt qu phn
tch so snh vi ngng CTNH nhm phn nh c phi l CTNH hay
khng.
3.3.3. i vi hn hp cht thi rn hoc hn hp gia cht thi rn v
cht thi lng, bn (ton b cc cht thi thnh phn u thuc loi *): s
dng ti a cc bin php c hc ph hp (cht, ct, bc, co, ly tm, trng
lc, thi kh... nhng khng c s dng nc hoc dung mi ra, tch)
tch ring cc cht thi thnh phn v ly mu i vi tng cht thi thnh
phn ny theo quy nh ti im 3.3.1 hoc 3.3.2; s dng gi tr trung bnh
ca kt qu phn tch i vi tng cht thi thnh phn so snh vi
ngng CTNH nhm phn nh c phi l CTNH hay khng. Trng hp
khng th tch ring cc cht thi thnh phn bng cc bin php c hc th
trn u khi cht thi (nu c th) v ly t nht 09 mu phn b u theo
cch chia u cc phn trong khi cht thi (mi phn ly 01 mu).
3.3.4. i vi cht thi rn thuc loi * c tp cht bm dnh: ly 03 mu
i din ngu nhin cc v tr khc nhau ca cht thi nn (cht thi ng
24

QCVN 07: 2009/BTNMT

nht th rn) m c tp cht bm dnh so snh vi ngng CTNH nhm

phn nh c phi l CTNH hay khng. Nu cht thi nn l hn hp cht thi
th phi tch ring cc cht thi thnh phn phn nh theo quy nh ti
im 3.3.3.
3.3.5. i vi vic phn nh chung mt dng cht thi pht sinh thng
xuyn t mt ngun thi nht nh c phi l CTNH hay khng th phi ly
mu vo t nht 03 ngy khc nhau, thi im ly mu ca mi ngy phi
khc nhau (u, gia v cui ca mt ca hoc m hot ng), mi ln t nht
03 mu ngu nhin cc v tr khc nhau.
3.3.6. i vi cc cht thi thuc loi ** hoc hn hp c t nht mt
cht thi thnh phn thuc loi ** th khng cn ly mu, phn tch m phn
nh lun l CTNH, nhng nu vn cn ly mu, phn tch cho cc mc ch
khc nh phn loi CTNH theo thnh phn nguy hi nh nu ti im 2.1.3 th
cng p dng nguyn tc quy nh t im 3.3.1 n 3.3.5.
3.3.7. i vi vic phn nh cht thi sau x l c cn l CTNH hay
khng th cng p dng cc nguyn tc quy nh t im 3.3.1 n 3.3.5.
3.4. Nguyn tc la chn cc tnh cht v thnh phn nguy hi
phn tch
Mt cht thi bt k ch cn c t nht mt tnh cht hoc mt thnh
phn nguy hi vt ngng CTNH th phn nh l CTNH. Do vy, nu ch
phn nh mt cht thi thuc loi * c phi CTNH hay khng, th trong qu
trnh la chn phn tch m pht hin ra mt tnh cht hoc mt thnh phn
nguy hi vt ngng CTNH th khng phi tin hnh phn tch cc tnh cht
hoc thnh phn nguy hi cn li, tr trng hp phn tch cho mc ch
khc. Vic la chn phn tch cc tnh cht hoc thnh phn nguy hi c
tin hnh nh sau:
3.4.1. i vi cc tnh cht nguy hi: Cn c vo c im ca ngun
thi v chng loi cht thi la chn c phn tch tnh d chy, tnh kim v
axit hay khng. Nu chc chn rng c im ngun thi v chng loi cht
thi khng th dn ti vic cht thi c cc cht d chy, kim hoc axit th
chuyn sang phn tch cc thnh phn nguy hi.
3.4.2. i vi cc thnh phn nguy hi v c: Khng nht thit phi
phn tch tt c cc thnh phn v c nu ti Bng 2. Cn cn c vo tnh
cht nguyn vt liu, nhin liu, quy trnh sn xut, c im ngun thi, qu
25

QCVN 07: 2009/BTNMT

trnh pht thi hoc hot ng c pht sinh cht thi xc nh cc thnh
phn nguy hi v c c th c trong cht thi phn tch. Nu nguyn vt
liu, nhin liu, quy trnh sn xut, c im ngun thi, qu trnh pht thi
hoc hot ng c pht sinh cht thi khng lin quan n cc cht c cha
thnh phn nguy hi v c no th khng phi phn tch thnh phn .
3.4.3. i vi cc thnh phn nguy hi hu c:
a) Sau khi tin hnh la chn theo quy nh ti im 3.4.1 v 3.4.2 m
vn cha phn nh c CTNH th mi phi tin hnh phn tch cc thnh
phn nguy hi hu c (tr trng hp bit chc chn s c mt ca mt
thnh phn hu c nht nh th c th b qua bc 3.4.1 v 3.4.2);
b) Khng nht thit phi phn tch tt c cc thnh phn hu c nu ti
Bng 3. Cn cn c vo tnh cht nguyn vt liu, nhin liu, quy trnh sn
xut, c im ngun pht thi, qu trnh pht thi hoc hot ng c pht
sinh ra cht thi xc nh cc thnh phn nguy hi hu c c th c trong
cht thi phn tch. Nu nguyn vt liu, nhin liu, quy trnh sn xut, c
im ngun thi, qu trnh pht thi hoc hot ng c pht sinh ra cht thi
khng lin quan n hoc khng c kh nng dn ti vic xut hin mt cch
khng ch nh (do phn ng ho hc ngu nhin) mt thnh phn nguy hi
hu c no th khng cn phn tch thnh phn .

4. PHNG PHP XC NH
4.1. Kt qu phn nh v phn loi CTNH ch c gi tr nu p dng
theo ng cc phng php xc nh sau y:
4.1.1. i vi tnh d bt chy: ASTM D3278-96: Phng php chun
xc nh im chp chy ca cht lng bng dng c cc kn (Standard test
method for flash point of liquids by small scale closed-cup apparatus).
4.1.2. i vi tnh kim v tnh axit: ASTM D4980-89: Phng php
chun xc nh pH trong cht thi (Standard test method for screening of pH in
waste).
4.1.3. i vi nng ngm chit, s dng mt trong hai phng php
chun b mu sau y trc khi tin hnh phn tch:

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a) ASTM D5233-92: Phng php chun xc nh mu cht thi n l

bng phng php ngm chit (Standard test method for single batch
extraction method for wastes).
b) EPA 1311: Phng php ngm chit c tnh TCLP (TCLP Method
1311 Toxicity characteristic leaching procedure).
4.1.4. i vi thnh phn xyanua: EPA SW-846 Phng php 9010
hoc 9012: Phn tch xyanua trong cht thi (Method 9010 or 9012:
Determination of Cyanide in wastes).
4.2. i vi vic phn tch dung dch sau ngm chit xc nh nng
ngm chit ca cc thnh phn nguy hi v vic phn tch cht thi xc
nh hm lng tuyt i ca cc thnh phn nguy hi c th p dng cc
phng php theo bt k quy chun k thut, tiu chun quc gia hoc tiu
chun quc t no c cng nhn.
4.3. Phng php ngm chit EPA 1311 v ASTM D5233-92 l cc
phng php chun b mu phn tch c p dng cho vic ngm chit cc
mu cht thi nhm xc nh kh nng r r cc thnh phn nguy hi trong
cht thi ra mi trng trong iu kin tng t iu kin t nhin (biu th
bng nng ngm chit c n v l mg/l), c chung nguyn l nh sau:
4.3.1. i vi cht thi c t hn 0,5% hm lng rn kh (cht thi
dng lng): sau khi lc qua mng lc si thu tinh 0,6 - 0,8 m, lng cht
lng thu c dng trc tip phn tch cc thnh phn nguy hi (khng cn
ngm chit lng cht rn b gi li).
4.3.2. i vi cht thi c t nht 0,5% hm lng rn kh (cht thi
dng bn hoc rn):
- Lng cht rn c tch khi lng cht lng bng vic lc qua
mng lc si thu tinh 0,6 - 0,8 m; lng cht lng tch ra c bo qun
phn tch sau.
- Lng cht rn (c th cn x l c hc nh bm, ct, nghin...
m bo ton b lng cht rn c lt qua sng c kch thc mt khng
vt qu 9,5 mm) c ngm chit bng dung dch ngm chit c tnh axit
(c pha ch t CH3COOH, nc v c th b sung NaOH t gi tr pH
4,93 0,05 hoc 2,88 0,05 tu theo loi thnh phn nguy hi cn phn tch)
c khi lng gp 20 ln khi lng cht rn trong khong thi gian 18 2h;
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QCVN 07: 2009/BTNMT

- Nu tng thch, lng cht lng tch ra ban u c trn vi dung

dch sau ngm chit lng cht rn phn tch mt ln; nu khng tng
thch th c phn tch ring v kt hp gi tr trung bnh theo cng thc sau:
Ctb =

(Vl.Cl + Vnc.Cnc)
(Vl + Vnc)

Trong :
+ Ctb (mg/l) l nng ngm chit trung bnh ca mt thnh phn nguy
hi trong mu cht thi;
+ Vl (l) l th tch lng cht lng tch ra ban u;
+ Cl (mg/l) l nng thnh phn nguy hi trong lng cht lng tch ra
ban u;
+ Vnc (l) l th tch dung dch sau ngm chit;
+ Cnc (mg/l) l nng thnh phn nguy hi trong dung dch sau ngm
chit.

5. T CHC THC HIN

5.1. Quy chun ny p dng thng nht ngng CTNH trong vic phn
nh v phn loi CTNH theo Danh mc CTNH do B Ti nguyn v Mi
trng ban hnh; thay th p dng cc Tiu chun Vit Nam TCVN
6706:2000 v Cht thi nguy hi Phn loi v TCVN 7629:2007 v Ngng
cht thi nguy hi.
5.2. Mt s trng hp c bit thng gp trong thc t c quy
nh c th nh sau:
5.2.1. i vi bao b thi: trc khi tin hnh ly mu, phn tch
phn nh, phn loi CTNH, cc thnh phn cht c cha cn li trong bao
b phi c loi b ti a khi vt liu bao b bng cc bin php c hc ph
hp (bc, tch, co i vi thnh phn rn, bn hoc trng lc, ly tm i
vi thnh phn bn, lng, nhng khng c s dng nc hoc ho cht
ra, tch, ty), m bo ch cn li cc thnh phn bm dnh (vi dy trung
bnh di 01 mm hoc hm lng di 01%). Ly mu, phn tch ring bit
cho vt liu bao b (c cc thnh phn bm dnh) v thnh phn cht c
cha tch ring ra c phi l CTNH hay khng theo quy nh ti Phn 3
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QCVN 07: 2009/BTNMT

ca Quy chun ny. Nu thnh phn cht c cha tch ring ra l

CTNH th phn nh lun ton b bao b l CTNH m khng cn phn tch vt
liu bao b. Nu thnh phn cht c cha ch cn li dng tp cht bm
dnh (vi dy trung bnh di 01 mm hoc hm lng di 01%) th khng
cn khu loi b bng cc bin php c hc m ly mu, phn tch lun.
5.2.2. i vi cc phng tin, thit b thi (v d phng tin giao
thng, thit b in, in t...): vic ly mu, phn tch phn nh, phn loi
CTNH phi c tin hnh cho tng cht thi thnh phn (b phn hoc vt
liu cu thnh nn phng tin, thit b, v d du my).
5.2.3. Mt cht thi ch c phn loi theo tn v m CTNH ca loi c
gc halogen hu c hoc c cha thnh phn halogen hu c (k c c clo
nh PCB) nu hm lng tuyt i ca ca t nht mt thnh phn halogen
hu c vt ngng CTNH.
5.2.4. Cc sn phm c thu hi, ti ch t cht thi lm nhin liu,
nguyn vt liu sn xut nh du m, dung mi, cn v cc ho cht: phi
m bo cc thnh phn kim loi nng (tr trng hp kim loi nng l thnh
phn chnh ca sn phm) v cc thnh phn halogen hu c di ngng
CTNH, ng k tiu chun c s v cht lng sn phm v t cc tiu
chun quc gia, quy chun k thut quc gia v cht lng sn phm (nu c)
theo quy nh hin hnh. Nu cn bt k mt thnh phn nguy hi l kim loi
nng hoc halogen hu c vt ngng CTNH th khng c coi l sn
phm m vn l CTNH.
5.2.5. Cht thi c x l bng bin php ho rn hoc n nh ho:
a) Tro x t hot ng thiu hu CTNH v cc cht thi v c khc: nu
khng c thnh phn kim loi nng no vt ngng nng ngm chit th
c th tn dng lm sn phm vt liu xy dng nu cng ho rn (b
tng ho hay cc bin php khc nh ng gch) khng thp hn mc 100;
hoc c coi l cht thi rn thng thng, c th chn lp trong bi chn
lp cht thi sinh hot hoc cht thi xy dng hp v sinh nu cng ho
rn thp hn mc 100;
b) Cht thi c thnh phn hu c sau khi ho rn hoc n nh ho
nu khng c thnh phn nguy hi no (tr aming th cho php hm lng
bt k) ng thi vt ngng hm lng tuyt i v ngng nng ngm

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QCVN 07: 2009/BTNMT

chit th c coi l cht thi rn thng thng, c th chn lp trong bi chn

lp cht thi sinh hot hoc cht thi xy dng hp v sinh;
c) Cht thi sau khi c ho rn hoc n nh ho nu c t nht mt
thnh phn nguy hi v c hoc hu c ng thi vt c ngng hm
lng tuyt i v ngng nng ngm chit th vn l CTNH, phi c
chn lp trong bi chn lp cht thi nguy hi.
5.3. Phi s dng bn cp nht mi nht ca cc phng php xc
nh nu ti Mc 4.1. Trng hp cc phng php xc nh ny c cc quy
chun k thut hoc tiu chun quc gia tng ng th p dng cc quy
chun, tiu chun .
5.4. C quan qun l nh nc v mi trng c trch nhim hng
dn, kim tra, gim st vic thc hin Quy chun ny./.

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