exp.

data

VFT linearization
a=
b=
r =
c=
0.636
0.636

Yi =

log n

537.6
550
580
600
650
700
750
800
850
900
950
1000
1050
1100
1150
1200
1250
1300
1350
1400
1450
1500

13.2580
12.7090
11.4837
10.7733
9.2081
7.9950
7.0288
6.2445
5.5953
5.0483
4.5803
4.1744
3.8184
3.5033
3.2220
2.9693
2.7408
2.5332
2.3438
2.1702
2.0106

y=

VFT 3 points

-1.652 3 points
14.970
0.99994877

T123
537.6
800.0
1200.0
L123
13.2580
6.2445
2.9693

SUM Xi
SUM Yi
SUM Xi
SUM Yi
SUM XiYi
N
DELTA X

A=
B=
To =

-1.652
4417.8
242.5
0.0268

Xi =

Yi,calc Yi,calc

dev Yi

Xi

13.318
12.714
11.437
10.705
9.189
8.004
7.053
6.272
5.620
5.067
4.592
4.180
3.819
3.500
3.216
2.962
2.733
2.525
2.337
2.164
2.006
1.861

0.0000
0.0029
0.0107
0.0151
0.0045
0.0010
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0001
0.0001
0.0003

1.0000
0.9210
0.7645
0.6814
0.5244
0.4161
0.3381
0.2802
0.2360
0.2015
0.1740
0.1518
0.1336
0.1184
0.1057
0.0950
0.0858
0.0779
0.0710
0.0650
0.0597

Tg/T (c-1)y
/(1-cy)
1.0000 1.0000
0.9849 0.9597
0.9503 0.8744
0.9285 0.8255
0.8782 0.7242
0.8331 0.6450
0.7924 0.5815
0.7555 0.5293
0.7219 0.4858
0.6911 0.4488
0.6628 0.4171
0.6368 0.3896
0.6127 0.3655
0.5904 0.3441
0.5697 0.3252
0.5504 0.3082
0.5323 0.2929
0.5154 0.2791
0.4995 0.2665
0.4846 0.2550
0.4705 0.2444
0.4572 0.2347

-1.575
4339.2
245.1
0.0428

linear regression

13.258
12.655
11.380
10.650
9.141
7.963
7.019
6.245
5.598
5.051
4.581
4.173
3.816
3.501
3.220
2.969
2.743
2.539
2.352
2.182
2.026

1700
2000
3000
4000
5000
1E+10
537.6

0.4109
0.3567
0.2477
0.1897
0.1538
0.0000
1.0000

0.2025
0.1679
0.1070
0.0785
0.0620
0.0000

1.379
0.861
-0.050
-0.477
-0.724
-1.652
13.317707

linear regression
10.5617
123.4101
6.5011
991.7608
79.8701
21
24.9738

XiYi

a
b
sY
sA
sB
r

Yi

sYi

-1.6523
14.9700
0.0268
0.0137
0.0246
0.9999

dXi =

dXi

Xi-<X>
13.2580
12.1965
10.0410
8.8929
6.6683
5.1571
4.0872
3.3055
2.7180
2.2659
1.9105
1.6263
1.3955
1.2056
1.0478
0.9151
0.8028
0.7069
0.6245
0.5533
0.4914

175.7746
161.5184
131.8744
116.0638
84.7887
63.9203
49.4040
38.9938
31.3075
25.4857
20.9790
17.4254
14.5802
12.2728
10.3812
8.8164
7.5119
6.4172
5.4933
4.7097
4.0424

0.0036
0.0000
0.0022
0.0047
0.0004
0.0001
0.0006
0.0008
0.0006
0.0003
0.0001
0.0000
0.0000
0.0000
0.0000
0.0001
0.0001
0.0001
0.0000
0.0000
0.0000

0.4971
0.4567
0.3714
0.3225
0.2212
0.1421
0.0786
0.0264
-0.0172
-0.0541
-0.0858
-0.1134
-0.1375
-0.1588
-0.1777
-0.1947
-0.2100
-0.2239
-0.2365
-0.2480
-0.2585

dYi =

dYi dXidYi

Yi-<Y>
0.2471
0.2086
0.1380
0.1040
0.0489
0.0202
0.0062
0.0007
0.0003
0.0029
0.0074
0.0128
0.0189
0.0252
0.0316
0.0379
0.0441
0.0501
0.0559
0.0615
0.0668

7.3813
6.8323
5.6070
4.8966
3.3314
2.1183
1.1521
0.3678
-0.2814
-0.8283
-1.2964
-1.7023
-2.0583
-2.3734
-2.6547
-2.9074
-3.1359
-3.3435
-3.5329
-3.7065
-3.8661

54.4840
46.6806
31.4383
23.9769
11.0983
4.4874
1.3274
0.1353
0.0792
0.6861
1.6806
2.8978
4.2365
5.6331
7.0473
8.4531
9.8337
11.1787
12.4814
13.7380
14.9467

3.6690
3.1206
2.0827
1.5793
0.7371
0.3010
0.0905
0.0097
0.0048
0.0448
0.1113
0.1930
0.2830
0.3769
0.4719
0.5662
0.6586
0.7485
0.8354
0.9191
0.9995

14.0
12.0
10.0
8.0
6.0
4.0
2.0
0.0
0.00

0.20

0.40

0.60

0.80

1.00

14.0

12.0

10.0

8.0

6.0

4.0

2.0

0.0
0

200

400

600

800

1000

1200

1400

1600

16.0
14.0
12.0
10.0
8.0
6.0
4.0

2.0
0.0
-2.0
-4.0
0.00

0.20

0.40

0.60

0.80

1.00