Bi tp (T tra cu cc hng s)

1. Tnh nng lng (kJ) ca 1 mol photon ca nh sng vi =650nm?

S. 184 kJ/mol
2. Tnh nng lng (kJ) ca 1 mol photon ca nh sng tm vi =400nm?
S. 299 kJ/mol
3. Hy tnh tn s (Hz), s sng (cm-1) v nng lng (J/photon, v J/mol photon) ca nh
sng trong vng trng thy c =562nm
S. 5,331014 Hz, 1,78104 cm-1, 3,5310-19 J/photon, 213kJ/mol
4. hp th ca dung dch c nng 2,3110-5M ca mt hp cht l 0,822 bc sng
266 nm trong mt cuvet c b dy l 1,00 cm. Hy tnh hp th mol bc sng 266 nm.
S. 3,56104 M-1cm-1
5. hp th A ca dung dch X v Y nguyn cht v hn hp X+Y vi cuvet c b dy 1,00
cm ti hai bc sng 420 nm v 505 nm c cc gi tr nh bng di y
Cht

Nng

A (ti 420 nm)

0,982
X
1,0010-4M
-4
Y
2,0010 M
0,326
X+Y (Cx+Cy)
0,820
Tnh nng X v Y trong hn hp

A(ti 505 nm)

0,216
1,262
0,908

6. Mt hp cht c khi lng mol l 292,16g/mol c ha tan trong bnh nh mc 5ml.

Ly 1,00 ml dung dch ny cho vo bnh nh mc 10 ml, pha long n vch mc. hp
th 340 nm l 0,427 cuvet 1,000 cm. hp th mol ca hp cht ny 340 nm l 6130
M-1cm-1.
Hy tnh nng ca hp cht ny trong cuvet, trong bnh nh mc 5 ml v hy tnh xem
bao nhiu miligam hp cht ny c s dng pha ch 5 ml ban u.
S. 6,9710-5M, 6,9710-4M v 1,02 mg
7. Mc nng lng chnh gia orbital 3p v 3s l 2,107 eV. Hy tnh bc sng ca bc x
hp th khi electron chuyn trng thi t 3s sang s3 (1eV = 1,6010-19J).
S. 590 nm