LTDH 2014

Nguyn Quc Oanh BI TP HA HC HAY 2013. TP 2

Duy Xuyn, Qung Nam

Cu 1 X l hn hp F eBr3 v M Br2 . Ly 0,1 mol X nng 25,84 gam tc dng vi dung dch AgN O3 d thu c 52,64 gam kt ta. Xc nh v khi lng F eBr3 trong X A.91,64 % B.41,77 % C.51,63 % D.60,71 % Cu 2 Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgN O3 /N H3 d thu c 43,2 g Ag . Cho 14,08 g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip v 8,256 g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l: A.C3 H7 OH v C4 H9 OH B.CH3 OH v C2 H5 OH C.C2 H5 OH v C3 H7 OH D.C4 H9 OH v C5 H11 OH Cu 3 t chy hon ton hn hp 2 axit X v Y thu c 0,4 mol CO2 v 0,3 mol H2 O. Mt khc hn hp 2 axit trn tc dng va vi 400 ml dung dch N aOH 1 M. Phn trm s mol ca axit c khi lng mol phn t nh hn l: A.33,33 % B.75 % C.50 % D.66,67 % 2 3+ Cu 4 Ha tan 1 g qung cromic trong axit, oxi ha Cr thnh Cr2 O7 . Sau khi phn hy ht lng d cht oxi ha, pha long dung dch thnh 100 ml dung dch. Ly 20 ml dung dch ny cho vo 25 ml dung dch F eSO4 trong H2 SO4 . Chun lng d F eSO4 ht 7,5 ml dung dch chun K2 Cr2 O7 0,015 M. Bit rng 25 ml dung dch F eSO4 tng ng vi 35 ml dung dch chun K2 Cr2 O7 . Thnh phn % ca Crom trong qung l ? A.10,725 % B.13,65 % C.21,45 % D.26 % Cu 5 Cho 17,9 g hn hp F e, Cu, Al vo bnh ng 200 g dung dch H2 SO4 24,01 % .Sau khi cc phn ng xay ra hon ton , ta thu c 9,6 g cht rn v c 5,6 lt kh (ktc) pht ra .Thm tip vo bnh 10,2 gam N aN O3 khi phn ng kt thc th th tch kh N O (ktc, sn phm kh duy nht ) v khi lng mui trong dung dch l: A.2,24 lt v 59,18 gam B.2,688 lt v 67,7 gam C.2,688 lt v 59,18 gam D.2,24 lt v 56,3 gam Cu 6 Tin hnh nhit phn hn hp X gm butan v heptan (t l 1:2 v s mol) th thu c hn hp Y (Gi s ch xy ra phn ng crackinh ankan vi hiu sut 100 %). Xc nh khi lng phn t ca Y: A.M = 43 B.32 M 43 C.25, 8 M 32 D. 25, 8 M 43 Cu 7 Nhit phn hon ton m gam mt mui amoni ca axitcabonic sau dn ton b sn phm vo 50 g dung dch H2 SO4 19,6 % ch to ra 1 mui axit c nng 21,49 %. Gi tr ca m l: A.7,9 B.9,6 C.14,4 D.11,25 Cu 8 Cho 2 dung dch H2 SO4 v HCOOH c cng nng mol/l v cc gi tr pH tng ng l X v Y . Thit lp mi quan h gia x v y bit rng c 50 phn t HCOOH th c 1 phn t HCOOH phn li: A.y = x-1 B.y = 10x C.y = x+2 D.y = 2x Cu 9 Hn hp X gm 0,1 mol anehit acrylic v 0,3 mol kh hiro. Cho hn hp X qua ng s nung nng c cha N i lm xc tc, thu c hn hp Y gm propanal, propan-1-ol, propenal v hiro. T khi hi ca hn hp Y so vi metan bng 1,55. S mol H2 trong h n hp Y bng bao nhiu? A.0,05 B.0,15 C.0,20 D.0,10 Cu 10 in phn dung dch cha m gam hn hp F eCl3 v CuCl2 vi in cc tr cho ti khi dung dch ht mu xanh th anot ca bnh in phn thu c 0,448 lt kh (ktc). Tip tc in phn dung dch thu c trn cho ti khi catot bt u si bt kh th anot li thu thm c 0,448 lt kh na (ktc). Gi tr ca m l: A.4,9 B.3,7 C.4,6 D.5,2 Phone: 0913472367 Mail: mtmm95@gmail.com Trang 1

LTDH 2014

Nguyn Quc Oanh

Duy Xuyn, Qung Nam

Cu 11 Thm dn dung dch KOH 33,6 % vo 40,3 ml dung dch HN O3 37,8 % (d=1.24 g/ml) n khi trung ha c dung dch A, lm lnh dung dch A thu c dung dch B c nng 11,6 % v c m gam mui tch ra (khng ngm nc). Gi tr ca m l: A.24,50 B.22,50 C.25,15 D.21,15 Cu 12 Mt hn hp M gm 1 axit n chc X v 1 ancol n chc Y (t l mol X : Y l 3 : 2) v 1 este Z c to nn t X v Y. Cho M tc dng va vi dung dch cha 0,4 mol N aOH to ra 37,6 gam mui v 13,8 gam ancol. Tn ca Z l: A.etyl propionat B.etyl acrylat C.metyl metacrylat D.metyl acrylat Cu 13 Hp th hon ton 7,84 lt CO2 (ktc) vo 200 ml dung dch hn hp N aOH 1 M v KOH x M. Sau phn ng lm bay hi nc ca dung dch thu c 37,5 gam cht rn. Xc nh x: A.0,5 B.1,8 C.1,5 D.1,0 Cu 14 X l mt -amino axit mch khng phn nhnh, trong phn t ngoi nhm amino v nhm cacboxyl khng c nhm chc no khc. Cho 0,1 mol X phn ng va ht vi 100 ml dung dch HCl 1 M thu c 18,35 gam mui. Mt khc 22,05 g X khi tc dng vi lng d dung dch N aOH to ra 28,65g mui khan. Cng thc cu to ca X l: A.HOOC CH2 CH2 CH (CH2 ) COOH B.HOOC CH2 CH (N H2 ) COOH C.HOOC CH2 CH2 CH2 CH (N H2 ) COOH D.H2 N CH2 CH2 CH (N H2 ) COOH Cu 15 Cho 18,3 gam hn hp X gm hai hp cht hu c n chc l dn xut ca benzen c cng cng thc phn t C7 H6 O2 tc dng ht vi dung dch AgN O3 /N H3 thu c 10,8 gam Ag . Vy khi cho 9,15 gam X ni trn tc dng vi 300 ml dung dch N aOH 1 M, ri c cn dung dch sau phn ng s thu c bao nhiu gam cht rn khan ? A.16,4 B.20,8 C.19,8 D.8,0 Cu 16 Cho m gam hn hp X gm: Andehit axetic, andehit acrylic v andehit oxalic tc dng vi dung dch AgN O3/N H 3 d , thu c 69,12 gam Ag . Mc khc t chy hon ton m gam hn hp X, thu c 37,86 gam hn hp CO2 v hi nc c t khi so vi H2 l 16,46 . Gi tr ca m l ? A.17,22 B.14,02 C.19,42 D.13,62 Cu 17 Cho m gam Al vo hn hp dung dch cha 0,15 mol F eCl3 v 0,12 mol CuCl2 . Sau khi kt thc phn ng, thu c 2,25m gam cht rn gm hai kim loi. Gi tr ca m l: A.3,48 B.3,36 C.3,6 D.3,86 Cu 18 t chy hon ton 24,12 gam hn hp X gm HCHO, HCOOH v mt andehit (khng no, hai chc, mch h c mt ni i) thu c 44 gam CO2 v 12,6 gam H2 O. Mt khc, hidro ha hon ton 24,12 gam hn hp X (xc tc N i), cn 12,992 lt H2 (ktc) . Nu cng cho lng hn hp X trn tc dng vi dung dch AgN O3 /N H3 d , th thu c bao nhiu gam kt ta ? A.151,2 B.146,88 C.142,5 D.138,24 Cu 19 Tripeptit X c cng thc sau C8 H15 O4 N3 . Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH 1 M. Khi lng cht rn thu c khi c cn dung dch sau phn ng l: A.31,9 gam B.35,9 gam C.28,6 gam D.22,2 gam Cu 20 Hn hp X gm hai ankin ng ng lin tip. 1,72 gam hn hp X lm mt mu va 16 gam Br2 trong CCl4 (sn phm cng l cc dn xut tetrabrom). Nu cho 1,72 gam hn hp X tc dng vi lng d dung dch AgN O3 trong amoniac th thu c m gam cht rn khng tan c mu vng nht. Gi tr ca m: A.10,14 B.9,21 C.7,63 D.7,07 Cu 21 Ankin X cha 87,8 % cacbon v khi lng. Bit X tc dng vi dung dch AgN O3 trong N H3 . S ng phn ca X tha mn tnh cht trn l: A.4 B.5 C.6 D.7

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LTDH 2014

Nguyn Quc Oanh

Duy Xuyn, Qung Nam

Cu 22 Cho m gam hn hp X (gm M g, Al, Zn v Cu) tc dng ht vi dung dch HN O3 thu c dung dch Y (khng c mui amoni) v 11,2 lt (ktc) hn hp kh Z (gm N2 , N O, N2 O v N O2 , trong N2 v N O2 c phn trm th tch bng nhau) c t khi i vi heli bng 8,9. S mol HN O3 phn ng l: A.3,4 mol B.3,0 mol C.2,8 mol D.3,2 mol Cu 23 Thy phn 445,05 gam peptit Val-Gly-Gly-Val-Gly thu c hn hp X gm 127,5 gam Gly; 163,8 gam Val; 39,6 gam Gly-Gly; 87 gam Val-Gly; 23,1 gam Gly-Val-Gly v m gam mt pentapeptit X1 . Gi tr ca m l A.77,400 B.4,050 C.58,050 D.22,059 Cu 24 Este X (cha C, H, O khng c nhm chc khc) c t khi vi meta bng 6,25.Cho 25 g X phn ng vi dung dch Y. C cn dung dch Y thu c 39 g rn khan Z. Phn trm khi lng ca oxi trong Z l: A.20,51 B.30,77 C.32 D.20,15 Cu 25 Hn hp X gm F e(N O3 )2 ; BaCl2 ; N H4 N O3 ha tan v nc thu c dung dch A, chia dung dch A thnh hai phn bng nhau. Phn I: Cho HCl (rt d) vo un nng thot ra 448 ml kh N O. Tip tc cho thm mt mu Cu d v dung dch A un nng thy thot ra tip 3136 ml kh N O. Cc kh o iu kin chun. Phn II: Cho N a2 CO3 (rt d) vo to ra 12,87 gam ta Thnh phn phn tm khi lng ca 3 mui ln lt theo th t l A.30,35 %; 31,48 %; 38,17 % B.35,27 %; 20,38 %; 44,35 % C.53,36 %; 30;83 %; 15,81 % D.35,13 %; 42,24 %; 22,53 % Cu 26 Cho a gam hn hp X gm mt axit no n chc v 14 este to ra bi axit no n chc B l ng ng k tip ca A v 1 ru no n chc. Cho a gam hn hp X tc dng va N aHCO3 , thu c 1,92 gam mui. Nu cho a gam hn hp X tc dng vi mt lng va N aOH un nng thu c 4,38 gam hn hp hai mui ca hai axit A v B v 0,03 mol ru, ru ny c t khi so vi H2 l 23. t chy hai mui bng mt lng oxi thu c mui N a2 CO3 , hi nc v 2,128 lt CO2 . Gi thit cc phn ng xy ra hon ton. Gi tr ca a A.3,98 gam B.4,12 gam C.3,56 gam D.2,06 gam Cu 27 C hai bnh in phan I v II. Bnh I ng dung dch (1) l NaOH c th tch 38 ml v nng 0,5 M Bnh II cha dung dch gm hai mui Cu(N O3 )2 ; N aCl tng khi lng cht tan l 258,2gam Mc ni tip bnh I v bnh II. in phn cho n khi bnh II c kh thot ra c hai in cc th dng li. Ly dung dch sau phn ng: Bnh I: nh lng xc nh thy nng N aOH sau in phn l 0,95 M Bnh II: em phn ng vi lng d F e, sau phn ng khi lng F e b tan l m (gam), v thot x lt kh N O duy nht.Gi tr ca m v x l: A.7,47; 2,99 B.11,2; 4,48 C.11,2; 6,72 D.16,8; 4,48 Cu 28 Hn hp X gm etanial, axetilen, propanial v vinyl fomat (trong s mol ca etanial v axetilen bng nhau). t chy hon ton m gam hn hp X cn dng va V lt O2 thu c 52,8 gam CO2 . Mt khc t chy hon ton 0,1V lt hn hp etan, propan cn 0,455V lt O2 thu c a gam CO2 . Tnh a: A.14,344 B.16,28 C.14,256 D.16,852 Cu 29 Hidro ha hon ton 0,3 mol hn hp X cha 2 andehit n chc, h (trong mi phn t khng cha qu 2 lin kt ) cn va 0,4 mol H2 v thu c hn hp 2 ancol no Y. t chy hon ton Y v sc sn phm chy vo 163,6 gam dung dch N aOH 40 % sau phn ng nng ca N aOH cn li l 12,72 %. Tn gi ca 2 andehit l: A.fomic acrylic B.fomic metacrylic C.axetic acylic D.axetic metacrylic

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LTDH 2014

Nguyn Quc Oanh

Duy Xuyn, Qung Nam

Cu 30 Cho hn hp kh CO, H2 qua m gam hn hp F e3 O4 v CuO (t l mol 1:2 )sau phn ng thu c 10,4 gam hn hp rn A.Ha tan hon ton A trong dung dch HN O3 d thu c 0,05 mol kh N O l sn phm kh duy nht. Gi tr ca m l: A.11,638 B.11,368 C.14,2 D.12,4 Cu 31 Hn hp kh X gm propen, etan, buta-1,3-ien, but-1-in c t khi so vi O2 l 1,5. t chy hon ton 0,05 mol hn hp X ri cho hp th ton b sn phm chy vo bnh dung dch Ba(OH )2 d th khi lng bnh tng thm m gam. Gi tr ca m l: A.10,4 gam B.5,2 gam C.13,1 gam D.7,3 gam Cu 32 Ha tan hon ton a gam hn hp gm Zn v Zn(OH )2 vi t l mol 1:2 trong 500 ml dung dch H2 SO4 x mol/lt (long), sau khi phn ng hon ton thu c dung dch A. Thm t t dung dch N aOH 1 M vo dung dch A, khi va ht 200 ml th bt u xut hin kt ta; khi ht 700 ml hoc 900 ml th u thu c b gam kt ta. Gi tr ca a v b ln lt l: A.26,3; 24,75 B.16,4; 49,5 C.26,3; 19,8 D.16,4; 24,75 Cu 33 Cho hn hp X gm ancol etylic v axit axetic. Bit: a gam X tc dng vi lng oxi d to ra 22 gam CO2 v 11,7 gam H2 O. a gam X tc dng vi lng va Na, to ra ( a + 5,5) gam mui. a gam X un nng vi H2 SO4 c to ra b gam etyl axetat (hiu sut phn ng t 60 %). Gi tr ca b l: A.8,80 B.5,82 C.8,25 D.5,28 Cu 34 Cho 33,6 g F e vo dung dch H2 SO4 c, nng sau khi phn ng xy ra hon ton thu c 2,24 lt kh duy nht SO2 v 14,4 gam cht rn. S mol axit tham gia phn ng l: A.0,8 B.0,4 C.0,6 D.1,2 Cu 35 Cho 3,76 gam hn hp X gm M g v M gO c t l mol tng ng l 14:1 tc dng va vi dung dch HN O3 th thu c 0,448 lt kh duy nht (ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T .Xc nh s mol HN O3 phn ng: A.0,28 B.0,32 C.0,36 D.0,34 Cu 36 Cho m gam hn hp X gm N a, Ca, K tc dng vi H2 O thu c dung dch Y v kh H2 . Cho ton b lng H2 thu c tc dng vi CuO d .Sau phn ng cho lng H2 O thu c hp th vo 63 gam dung dch H2 SO4 90 % th thy C % ca dung dch H2 SO4 cn 70 %. Cho ton b dung dch Y vo dung dch cha 0,6 mol AlCl3 thu c m gam kt ta. Cc phn ng xy ra hon ton. Gi tr ca m l: A.46,8 B.15,6 C.27,3 D.31,2 Cu 37 ha tan ht hn hp X gm Cr2 O3 , CuO; F e3 O4 cn va 550 ml HCl 2 M, sau phn ng thu c dung dch Y. Mt na dung dch Y ha tan ht ti a 2,9 gam N i. C cn na dung dch Y cn li thu c bao nhiu gam mui khan ? A.30,8 gam B.30,525 gam C.61,6 gam D.61,05 gam Cu 38 Cho x molhn hp kim loi Al, F e (c t l mol 1:1) tan ht trong dung dch cha y mol HN O3 (t l x:y = 3:17). Sau khi kim loi tan ht, thu csn phm kh Y duy nht v dung dch Z ch cha mui nitrat. Cho AgN O3 n d vo Z, thu c m gam rn. Gi tr ca m l: 54y 27y 108y 432y B. C. D. 17 17 17 17 o Cu 39 ha tan mt ming km trong dung dch HCl 200 C cn 27 pht. Nu thc hin th nghim 40o C th thi gian phn ng l 3 pht.Nu thc hin th nghim 55o C th thi gian phn ng l: A.44,36 giy B.34,64 giy C.64,43 giy D.43,64 giy A.

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LTDH 2014

Nguyn Quc Oanh

Duy Xuyn, Qung Nam

Cu 40 Nung 0,2 mol Al; 0,5 mol S trong mi trng khng c khng kh .Sau khi phn ng hon ton thu c hn hp rn X. Cho X phn ng vi H2 SO4 long d thu c hn hp kh Y. em t chy hon ton Y cn va V lt kh O2 (ktc). Gi tr V l: A.5,6 B.11,2 C.10,08 D.13,44 Cu 41 Ly 21,33 gam cao su isopren c lu ha em t chy hon ton bng oxi va , sau phn ng ngng t ht hi nc th cn li 34,272 lt kh (ktc). Trung bnh c bao nhiu mt xch isopren th c 1 cu ni isufua (S S ) ? A.20 B.46 C.18 D.23 Cu 42 Hn hp X gm andehit fomic, andehit oxalic, axit axetic, etilenglycol, glyxerol. Ly 4,52 gam X t chy hon ton ri cho sn phm i qua bnh 1 ng H2 SO4 (c, d). Bnh 2 ng 600 ml dung dch Ba(OH )2 0,2 M thy bnh 1 tng 2,88 gam, bnh 2 xut hin m gam kt ta. Xc nh m ? A.23,64 gam B.17,73 gam C.15,76 gam D.19,70 gam Cu 43 Ho tan hon ton 1 lng Ba vo 500 ml dung dch Al2 (SO4 )3 0,1 M. Sau phn ng thu c dung dch X, kt ta Y v kh Z. Khi lng dung dch gim so khi lng dung dch ban u l 19,59 g. Sc kh CO2 (d) vo X th thy xut hin m g kt ta .Gi tr ca m: A.1,56 B.3,84 C.5,5 D.7,8 Cu 44 Cho 5 g bt M g vo dung dch hn hp KN O3 v H2 SO4 un nh trong iu kin thch hp n khi phn ng xy ra hn ton thu c dung dch A cha m g mui, 1,792 lt hn hp kh B gm 2 kh khng mu trong c 1 kh ha nu trong khng kh v cn li 0,44 g cht rn khng tan. Bit t khi B so vi H2 l 11,5. Gi tr ca m l: A.27,96 B.29,72 C.31,08 D.36,04 Cu 45 Mt hn hp gm 2 ancol X v Y no, n chc hoc c mt lin kt i. Bit 16,2 g hn hp lm mt mu hon ton 500 g dung dch brom 5,76 %. Khi cho 16,2g hn hp trn tc dng vi N a d th th tch H2 thu c ti a l: A.2,016 lt B.4,032 lt C.8,064 lt D.6,048 lt Cu 46 Nung m g hn hp X gm bt st v lu hunh thu c hn hp Y gm F eS, F e, S . Chia Y thnh 2 phn bng nhau, cho phn 1 tc dng vi H2 SO4 long d, thy thot ra 2,8 lt hn hp kh (ktc). Cho phn 2 tc dng ht vi HN O3 c nng thy thot ra 16,464 lt kh ch c N O2 sn phm kh duy nht. Gi tr m l? A.14 B.17,84 C.8,92 D.7 Cu 47 Cho m g hn hp gm: metanol, etilenglicol, glixerol tc dng vi N a (d) thu 1 lng H2 bng lng H2 thot ra t phn ng in phn 538,8 ml dung dch N aC l 2 M in cc tr mng ngn xp n khi dung dch cha 2 cht tan c khi lng bng nhau, t chy m g hn hp X cn 0,79 mol O2 . Gi tr ca m l: A.22,1 B.15,2 C.21,4 D.19,8 Cu 48 Hn hp X gm 2 este u cha 2 lin kt trong phn t v hn km nhau 1 nguyn t C . un m g hn hp X vi lng va 100 g dung dch N aOH 10 %. C cn dung dch sau phn ng thu c 99,82 g hn hp hi v mt mui khan duy nht. Mt khc, t chy m g X thu c 1,13 mol CO2 . Cng thc este l ? A.CH3 COOCH = CH2 v CH3 COOCH2 CH = CH2 B.C2 H5 COOCH = CH2 v C2 H5 COOCH = CH CH3 C.CH2 CHCOOCH3 v CH2 = CH COOC2 H5 D.CH2 = CH COOCH2 CH3 v CH2 = CHCOOCH2 CH2 CH3 Cu 49 in phn dung dch hn hp HCl v 0,4 mol CuN O3 vi in cc tr, cng dng in khng i I = 10 A trong khong thi gian t s ng thi anot thu c hn hp kh. Nhng thanh F e vo dung dch sau phn ng n khi phn ng xy ra hon ton c kh N O duy nht thot ra ng thi thanh F e tng 1,2g. Gi tr ca t l? A.772 (s) B.1544 (s) C.2316 (s) D.386 (s) Phone: 0913472367 Mail: mtmm95@gmail.com Trang 5

LTDH 2014

Nguyn Quc Oanh

Duy Xuyn, Qung Nam

Cu 50 Cho s sau: etannol X. Hy cho bit trong cc cht sau: etilen, etylclorua, etanal, axt etanoic, natrietylat, buta - 1,3 - ien, glucozo. Bao nhiu cht c th l X: A.3 B.4 C.5 D.6

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