Corrosion

Corrosion

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z 1.
z 2.
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1.
z 2.
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z 3. Mechanical Stress
z 4. Erosion
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z
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Corrosion
Erosion

Corrosion
1.
Electrochemical Mechanical
z 2. H2O and Environment
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Corrosion

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Nonmetallic material
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z Ceramic + Molten Salts (high temp)
z Polymer + H2O => change structure and property
z Polymer + O2 and ultraviolet (Room temp)

z Galvanic cell

z Electrolytic cell

Why to Study Corrosion

z Economic (High Cost)

Electrochemical Mechanism
z Oxidation Reaction
z Reduction Reaction
z Both reaction above happened Simultaneous
z Oxidation-Reduction Reaction


1.

2
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2.

Zn
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Zn + 2HCl => ZnCl2 + H2

Zn + 2H+ => Zn2+ +H2
Oxidation Reaction
Zn => Zn2+ +2e2H+ +2e- => H2
Reduction Reaction

2e-

Oxidation Reaction
z e-
z +
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z Anodic reaction
z Local anodes

M+

e-

Reduction Reaction
z ez -
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z Cathodic reaction
z Local cathodes

M+

e-

Standard Electrode Half-Cell Potentials for Metals

Standard Reduction Potentials


z H2 = 0
z>

z <
z < 0
z E
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[A]

[B]

[A]

[B]


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Uniform Corrosion
Galvanic Corrosion
Pitting Corrosion

Q&A

z Oxidation Reaction
z E0 Cr 0

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EM +

0.0592
=E +
log Cion
n
0

E =
z E0 =
z n =
z Cion =
z 1M
z

EM +

0.0592
=E +
log Cion
n
0

25 Zn
ZnSO4 0.1M Ni
NiSO4 0.05 M

E=EZn+ENi


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ENi = E0+[0.0592/n]LogCion
=-(-0.250)+(0.592/2)Log[0.05]
0.288


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EZn = E0+[0.0592/n]LogCion
= -0.763+(0.592/2)Log[0.1]
-0.793


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ENi = 0.288
EZn = -0.793
E = EZn+ENi
E = -0.793+0.288
E = 0.505

Galvanic cell
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E0

 E0

[0.001]

[0.01]

Galvanic cell
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Zn HCl, Fe H2O

Galvanic cell
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Zn HCl, Fe H2O

Zn HCl
Zn
Zn2+

e-

H+

H2
e-

H+

Fe H2O
Zn

Fe2+
H2O
eeee-

OHO2

Fe(OH)2
+H2O
+O2

H2O
O2

OH-

Fe(OH)3


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FeFe2++2e O2++2H2O+4e-4OH2Fe+2H2O+O22Fe2+
2Fe2++4OH-2Fe(OH)2
2Fe(OH)2+H2O+1/2O22Fe(OH)3
Fe(OH)2
Fe(OH)3


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W=ItM/nF
I = (I=iA)
T =
M =
n =
F = 96,500


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W=ItM/nF
W=iAtM/nF

Passivative
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Passivative layer

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Passivation


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Passivative