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1.-I 2.-I 3.-I 4.-I use use use use a a a a car car car car as as as as a a a a mean of transportation. mean of transport. means of transportation. means of transport.
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as as as as
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It's always "as a means of" when you're talking about a way of doing something. "as a mean of" is only ever used when you are talking about averages e.g. "The value found as a mean of 38 measurements was ..."
Air, water and land transportation. Modes/methods of air, water and land transportation. Transportation by land, air and sea. Modes of transportation by air, land and sea.