2010/2009 :  

..2 : +

1/1
4...&'.II
/+

 

!#$

2+ 51 6$1  :10+1

?@1 ( H 3O + Cl ) &= <!+9 !5> 0> VS = 50 mL +89 #  :;

:E$F> ! C 1 5 . CaCO3 ( s ) ' <0> ! $ C = 0,04 mol.L1
. CaCO3 ( s) + 2 H 3 O + (aq) Ca 2+ (aq ) + CO2 ( g ) + 3H 2 O(l)
L5' 0$$' -H/  9 M N51 0>@ O' V (CO2 ) <$+ H I89 H1 6$$' .
.(1C< )Q5+ Q! C;5 Vm = 22,4 L.mol 1  + I85 +P
+

16
14

V(mL)

12
10
8
6
4
2
0
0

20

40

60

80

100

t(s)

. x max +P U$$ I ..$ M - -1

.<$+ H I89 O' C $! +85   0  -2
. mol.L1 .s 1 9' t = 50 s  +85   +P :9 -3
8 YF .0>@ O' [H 3O + ] @ [1 H1 6$1 WX 0> 5$ Y1 6$1 Z 0<+
: \! C;5+ U2$ $
t (s )

[H O ]
+

10
20
30
40
50
60
70
80
90
100
0,036 0,032 0,028 0,025 0,023 0,020 0,018 0,017 0,015 0,014
.0>@ O' [H 3O + ] H1 6$1 81 0<+ ] -4
. [H 3O + ] O' C $! +85   0  -5
.C $ ;] 0>[  H 3O + ]1 +P :9 -6
2

.C $ ;] 0> +P > -7

-.$

   51 :20+1$ ;  \

-1 > F >M> 0  :1b
 Cd+<H1 2C  Y'> 0' 1$ -/ F' + 5[. 2 ms / div Q! .

<3C
<2C
-1-1 T1 :9+  0' !b 0$$$> 0$F T2+  \PH$1 $ C.F
1 5$ -2-1  -Z + 5[ . If'f$ ! QC;5 10 s / div +.
! Q Q5+<9 .3C +P$ .
  51 -2$g:
' - +'M+ L ' h  1b  6Z>  -' I d = 1 m > Q! C.$> L
 L ' C.$+ If'f$ ' -/ F 5[ Q! C;5 2 ms / div Q! .Q5+
<.4C

<4C
> -1-2  CX+f  LF' YFM+ f  YF.\.$
-2-2 +P :9 X#$@> 0' t C.$+  .L
-3-2   U$$$ ;  \.
-4-2 l Q! C;5 C +.   -$g  +  \ .] H$$
+P X#$@>  t ?fM C! .5'&.
 -3 ?f YF 5 M> L $> 1b 1 M Q! C;5 . = 6,24 kHz
>1 Q! 05  hY ' + ' 0 C.$+  Q! L$ d = 100 cm :
. d = 110 cm d = 105 cm
> -1-3  1 $ .'8$
-2-3n U$$ .M+
-3-3   :9$ ;  \.

:30+1
 Fp n 2/ >  E$M \ Q! 0 = 435,9 nmp> EM > C>F<?
' !F @' n = 1,668 . i = 56,0
-1 IP :9@ i r r +! D  p+  . A = 60
-2
-1-2n :9 > MF  C+F$+ CXM p+.
bX > -2-2F  $' Q.1 $  0> E.$ -.Xr Q
+ -3-2  +M p+ > -.

'M[

:10+1
CVS
= 1.10 3 mol + .$ M
2
V (CO2 )
1 dV (CO2 )
. v(t ) =
: t x = n(CO2 ) =
+'
V S Vm
dt
Vm
dV
. v(50) = 1,28. 10 4 mol.L1 .s 1 : t a =
= 1,43. 10 4 L.s 1 : +'
dt
.!5+ pH H1 6$1 ! 5+! b> H1 6$$' & 0<+

. x max =

. v(t ) =
. [H 3O + ]1 / 2 = C

1 d H 3O
2
dt

-1
-2
-3
-4
-5

x max
= 0,02 mol.L1 -6
VS

. t1 / 2 = 60 s : 8 WX 0> -7

:20+1
-1
T1 = 7 * 2 = 14ms -1-1
1
1
. = =
= 40000 Hz -2-1
T 25. 10 6

. T2 = 2 ms

-2
M+ LF' : 1CX+ -1-2
\.$ :2CX+
. t = 3,2. 10 3 s -2-2
d
= 312,5 m.s 1
t
.@1 [   u.$ t .O

.v =

-3-2
-4-2
-3

.<+  -1-3
. = 5 cm -2-3
. v = * = 312 m.s 1 -3-3

:30+1
. r = 29,80 r = 30,2 i = 57,04 D = 53,04 -1
-2
. =

0
n

= 261,33 nm

-1-2

.?1 -2-2
.$' h!F$1 E!X 2Z M+ [   -3-2

 <+9 .