L THUYT ANKIN

Bi 1. C5H8 c s ng phn ankin l: A. 1 B. 2 C. 3 D. 4 Bi 2. Hirocacbon khng no hot ng ho hc hn hirocacbon no v trong phn t c cha A. lin kt kp km bn hn lin kt n. B. lin kt ni kp km bn hn lin kt , nn d t ra. C. lin kt ni kp km bn hn lin kt ni n. D. s nguyn t H cha bo ho. Bi 3. Dy no sau y khng phi l dy gm cc cht l ng ng ca nhau ? A. CH2=CH2 ; CH3CH=CH2 ; CH3C(CH3)=CH2 B. CH2=C=CH2 ; CH2=CHCH=CH2 ; CH2=CHCH2CH=CH2 C. CHCH ; CH3CCH ; CH3CCCH3 D. CH2=CHCH=CH2 ; CH2=C(CH3)CH=CH2 ; CH2=C(CH3)C(CH3)=CH2 Bi 4. Cht no sau y khng c ng phn hnh hc ? A. CH3CH=CHCl B. CH3CCl=CHCl C. CH3CCl=CCl2 D. CH3CCl=CClCCH Bi 5. Cht no sau y khi hiro ho khng thu c isopentan ? A. CH3CH(CH3)CCH B. CH3CH=C(CH3)CH3 C. CH2=CHCH=CHCH3 D. CH2=CHC(CH3)=CH2 Bi 6. Dng AgNO3/NH3 khng phn bit c cp cht no sau y ? A. But-1-in v but-2-in. B. But-1-in v but-1,3-ien. C. But-1-in v vinylaxetilen. D. But-1-in v but-2-en. Bi 7. Cho cc cht hu c : CH2=CHCH2CH3 (M) CHCCH2CH3 (N) CH2=C=CHCH3 (P) CH2=CHCH=CH2 (Q) CH2=C(CH3)CH3 (R) Nhng cht cho cng 1 sn phm cng hiro l A. M, N, P, Q B. M, N, R C. M, N, R D. Q, R Ba 8. Cht X c cng thc phn t C6H6, c cu to mch thng. Khi cho 0,15 mol X tc dng vi AgNO3/NH3 (ly d) thu c 43,8 gam kt ta. Cng thc ca X l A. CH2=C=CHCH2CCH B. CH2=CHCH=CHCCH C. CHCCH2CH2CCH D. CH3CCCH2CCH 3 Bi 9. T 1 m axetilen ( kc ) ngi ta iu ch vinyl clorua ri em trng hp th thu c bao nhiu kg PVC. Bit hiu sut ca mi phn ng ln lt l 80% v 90% : A. 2,2902 B. 2,2321 C. 2,5112 D. 2,009 Bi 10. t chy hn hp gm etan v etin thu c kh CO2 v hi nc theo t l th tch l 1 : 1 (o cng iu kin t0, p). T l netan : netin l A. 3 : 7 B. 2 : 3 C. 1 : 1 D. 3 : 2 + Bi 11. Hirocacbon X hp nc (xc tc H ) c A. Ancol no Y mt 1 phn t H2O cng c A. X c phn ng vi AgNO3/NH3 c kt ta. X, Y l A. C2H4 v C2H5OH B. C2H2 v C2H4(OH)2 C. C2H2 v C2H5OH D. C3H4 v C3H5(OH)3 Bi 12. Loi polime no sau y c ng phn hnh hc A. P.E B. Cao su Buna C. PVC D. P.P

Bi 13. Tn thng thng ca hp cht c cng thc : CH3 C C CH3 l A. imetylaxetilen B. but -3 in C. but -3 en D. but-2 in Bi 14. t chy mt loi polime ch thu c kh CO2 v hi H2O theo t l mol 1 : 1. Polime thuc loi A. polianken B. poli(vinyl clorua) C. poliankaien D. Poliankin Bi 15. P v Q l 2 hirocacbon c cng cng thc phn t C5H8 v c mch C phn nhnh. P c kh nng trng hp to polime c tnh n hi cao, Q c kh nng to kt ta khi cho qua dung dch AgNO3/ NH3. P v Q l A. penta-1,3-ien v 3-metylbut-1- in B. 2- metylbutaien v 3-metylbut- 1- in C. penta-1,3- ien v pent-1- in. D. 2- metylbutaien v pent- 1- in Bi 16. Q l hn hp gm mt ankan v mt ankin. T khi ca Q so vi hiro l 17,5. t chy hon ton mt lng bt k hn hp Q u thu c kh cacbonic v hi nc vi s mol bng nhau. Bit hn hp Q khng tc dng vi dung dch AgNO3/NH3. Cng thc cu to ca ankan v ankin ln lt l A. CH4, CHC-CH3 B. CH4, CH3-CC-CH3 C. C2H6, CHC-CH3 D. C2H6, CH3-CC-CH3 Bi 17. Hirocacbon Y c cng thc C5H8, cu to mch phn nhnh v c phn ng to kt ta vi dung dch AgNO3/NH3. Cng thc cu to ca Y l : A. CHC-CH2-CH2-CH3. B. CH2=C(CH3)-CH=CH2 C. CH3-C(CH3)=C=CH2 D. CHC-CH(CH3)-CH3. Bi 18. Bn hirocacbon T1, T2, T3, T4 mch h thuc cc dy ng ng khc nhau, c cng thc phn t ln lt l C3H8, C2H4, C3H4 v C4H6, trong T4 c th to kt ta vi dung dch AgNO3/NH3. Cng thc cu to tng ng ca cc cht T1, T2, T3, T4 l A. CH3-CH2-CH3; CH2=CH2; CH2=C=CH2; CHC-CH2-CH3. B. CH3-CH2-CH3; CH2=CH2; CHC-CH3; CHC-CH2-CH3. C. CH3-CH2-CH3; CH2=CH2; CHC-CH3; CH2=CH-CH=CH2. D. CH3-CH2-CH3; CH2=CH2; CHC-CH3; CH2=C=CH-CH3. Bi 19. C th phn bit nhanh 2 ng phn mch h, cha mt lin kt ba ca C4H6 bng thuc th l A. dung dch HCl B. dung dch AgNO3/NH3 C. dung dch Br2 D. dung dch KMnO4 Bi 20. Cht no sau y c gi l kh t n A. C2H4 B. C2H2 C. C2H6 D. C3H4 Bi 21. Khi cho metyl axetilen tc dng vi dd HCl. S lng sn phm ti a c th thu c l: ( khng tnh ng phn hnh hc ): A. 3 B. 4 C. 5 D. 6 Bi 22. Nhn xt no sau y ng A. Khi cng HX vo ankin lun cho hh sn phm B. Khi cng phn t HX d vo ankin i xng lun cho hh cha ti a 3 sn phm C. Khi cng HX vo ankin i xng cho sn phm chnh tun theo quy tc Maccopnhixcop D. Phn ng cng HX l phn ng oxy ho kh Bi 23. Khi hidro ho but-2-in bng lng H2 d vi xc tc l Pd/PbCO3 cho sn phm chnh l: A. butan B. trans-but-2-en C. Cis-but-2-en D. B hoc C

Sn phm chnh ca phn ng no sau y c ng phn hnh hc 1:1 1:1 A. CHCH + HCl B. CHC-CH3 + HCl 1:1 1:2 C. CH3-CC-CH3 + HBr D. CH3-CC-CH3 + 2H2 Bi 25. Phn ng no sau y axetilen ng vai tr l cht b kh A. Hidro ho B. Cng HX C. Halogen ho D. tc dng AgNO3/ dd NH3 Bi 26. Cho s phn ng A1 A2 A4 PVC . A1, A2, A3, A4 ln lt l: A. CHCH; CH2CH2; Cl2; vinyl clorua B. CaC2; CHCH; HCl; vinylclorua C. CH4; CHCH; HCl; vinyl clorua D. A hoc B hoc C Bi 27. phn bit C2H6; C2H4; C2H2 dng cp ho cht: A. H2; dd Br2 B. KMnO4; dd Br2 C. dd Br2; AgNO3/ dd NH3 D. O2; AgNO3/ dd NH Bi 28. tch cc ng phn ca butin dng cp ho cht: A. dd Br2; KOH c/ C2H5OH B. AgNO3/ dd NH3; HCl C. AgNO3/ dd NH3; NaOH D. Khng tch c Bi 29. Hh X gm C2H6; C2H4; C2H2 t chy hon ton X sau phn ng thu c Bi 24. nH O = nCO . Nhn xt no sau y ng: 2 2 A. VC H = VC H = VC H 2 6 2 4 2 2 B. VC H = VC H 2 2 2 4

C. nC H = nC H = nC H D. VC H = VC H 2 6 2 4 2 2 2 2 2 6 Bi 30. Cho axetilen tc dng vi dd HCl d cho sn phm chnh l : A. vinyl clorua B. cloeten C. 1,2-icloetan D. 1,1-icloetan Bi 31. Loi polime no sau y c ng phn hnh hc A. P.E B. Cao su Buna C. PVC D. P.P

BI TP ANKIN
Cu 1. Cht X c cng thc phn t C6H6, c cu to mch thng. Khi cho 0,15 mol X tc dng vi AgNO3/NH3 (ly d) thu c 43,8 gam kt ta. Cng thc ca X l A. CH2=C=CHCH2CCH B. CH2=CHCH=CHCCH C. CHCCH2CH2CCH D. CH3CCCH2CCH Cu 2. Dn 6,0 lt hn hp kh A gm hiro, etan v etin qua bt Ni/t0 n phn ng hon ton thu c 3,0 lt mt kh duy nht (cc th tch o cng iu kin). T khi hi ca A so vi H2 l A. 5 B. 7,5 C. 10 D. 12,5 Cu 3. t chy hon ton 4,48 lt (ktc) 2 hirocacbon ng ng c khi lng mol phn t hn km nhau 28 gam thu c 11,20 lt CO2 (ktc) v 5,4 gam H2O. CTPT v % th tch ca 2 hidrocacbon l: A. C2H2 25%; C4H6 75% B. C2H2 75%; C4H6 25% C. C2H4 30%; C4H8 70% D. C2H6 70%; C4H10 30% Cu 4. Dn V lt (ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng thu c hh kh Y. Dn hh Y qua dung dch AgNO3/NH3 (ly d) thu c 12 gam kt ta. Hh kh ra khi dung dch phn ng va vi 16 gam Br2 v cn li hh kh Z. t chy hon ton Z thu c 2,24 lt kh CO2 (ktc) v 7,2 gam H2O. Gi tr ca V bng A. 14,56 B. 8,96 C. 11,2 D. 13,44 Cu 5 Hn hp X gm hiro v mt ankin c t khi so vi hiro l 4,8. un nng X vi xc tc Ni c hn hp Y khng c kh nng lm mt mu dung dch Br2 v c t khi so vi H2 l 8,0. Cng thc phn t v % v th tch ca ankin trong X l A. C2H2, 20% B. C3H4, 20% C. C4H6, 63% D. C5H8, 63% Cu 6 Q l hn hp gm mt ankan v mt ankin. T khi ca Q so vi hiro l 17,5. t chy hon ton mt lng bt k hn hp Q u thu c kh cacbonic v hi nc vi s mol bng nhau. Bit hn hp Q khng tc dng vi dung dch AgNO3/NH3. Cng thc cu to ca ankan v ankin ln lt l A. CH4, CHC-CH3 B. CH4, CH3-CC-CH3 C. C2H6, CHC-CH3 D. C2H6, CH3-CC-CH3 Cu 7 t chy ht mt lng hn hp gm C4H10, C2H4, C3H6 v C4H6 cn V lt oxi (ktc) thu c 8,96 lt CO2 (ktc) v 7,2 g H2O. Gi tr ca V l: A. 13,44 lt B. 17,92 lt C. 8,96 lt. D. 15,68 lt Cu 8 Mt hn hp gm C2H2 v ankin X c t l mol l 1:1. Ly mt lng hn hp trn chia lm 2 phn bng nhau: - Phn (1): Tc dng va vi 8,96 lt H2 (ktc) to ra ankan. - Phn (2): Tc dng vi dung dch AgNO3/NH3 to ra 40,1g kt ta. Cng thc cu to ca X l: A. CHC-CH2-CH3 B. CH3-CC-CH3 C. CHC-CH3 D.CHC-CH2-CH2-CH3