Reversibel ADIABATIK ekspansi ke 1 atm

a. Volume akhir sistem

PV = konstan
CP

CV

P1 = 10 atm
V1 = 10 ltr

3
CV = R
2

C P CV =R

P2 = 1 atm
V2 = ?

P1V1 = P2V2
10 x 105/3 = 1 x V2 5/3
V2 = (10 x 105/3)3/5
= 39,81 ltr
b.

Kerja yang dilakukan system

W = - U = - n Cv (T2-T1)
mol

c.
d.

5
3

n=12,18

P2 x V2
= n R T2
1 x 39,81 = 12,18 x 0,0821 x T2
T2 =39,8 oK
W = U = - n Cv (T2-T1)
W = - 12,18 x 3/2 x 8,314 x (39,8 -100)
W = 9,15 kJ
Perubahan energi dalam (U) = - W =
9,15 kJ
H = n Cp (T2 T1)
H = 12,18 x 5/2 x 8,314 (39,8 - 100)
H = - 15,25 kJ