Gv: Nguyn NGc Dng

TRC NGHIM HIROCACBON

Cu 1.Cho hn hp X gm anken A v ankin B.Xc nh % s mol mi cht bit
50 ml X phn ng ti a vi 80ml H2. t chy hon ton m gam hh X ri hp th
tt c sn phm chy bng nc vI trong c 25 gam kt ta v mt dung dch c
khi lng gim 4,56gam so vi ban u v khi thm vo lng KOH d li thu c 5 g
kt ta. CTPT ca A v B ln lt l
A. C3H6 v C3H4
B. C2H4 v C2H2
C. C2H4 v C3H4 D. C3H6 v C2H2
Cu 2. C mt hn hp gm 2 hidrocacbon A v B th kh.Phn t khi ca B
ln hn PTK ca a l 24 vc. T khi ca B so vi H 2 bng 9/5 t khi ca A so vi
H2.Khi t chy Vlt hhp thu dc 11,2 lt CO2(ktc) v 8,1 gam nc. CTPT ca A,B
l
A. C2H6 v C3H6
B. C2H6 v C4H6
C. CH4 v C3H4 D. C2H4 v C4H4
Cu 3.Cho 1,568 hn hp X gm 2 hidrocacbon mch h vo bnh nc brom d.
Sauk hi phn ng hon ton ch cn li 448 ml kh thot ra v c 8 gam brom
phn ng.
Mt khc nu t chy hon ton lng X trn ri dn sn phm chy vo bnh nc
vi trong th c 15 gam kt ta. Lc b kt ta ri un nng,li thu thm ti a
2 gam kt ta. CTPT ca 2 hirocacbon ( cc kh ktc) l
A. C2H6 v C4H6
B. C2H2 v C2H4
C. C2H6 v C3H6 D. CH4 v C3H6
Cu 4. t 10ml mt hirocacbon bng 80 ml Oxi d.Sn phm thu c sau khi
cho nc ngng t cn 65 ml trong 25ml la Oxi. CTPT cua hircacbon l
A. C2H2
B. C3H4
C. C4H4
D. C4H6
Cu 5. t chy hon ton hn hp X gm hi ca hidrocacbon A v kh Oxi d
thu c hn hp kh v hi. Lm lnh hnc hp ny,th th tch gim 50%. Nu
cho hn hp cn lai qua dd KOH,th tch gim 83,3% s cn li . CTPT ca X l
A. CH4
B. C2H6
C. C4H8
D. C5H12
Cu 6. Trn hn hp X gm hidrocacbon A vi H2 d, dX/H2= 4,8. Cho X i qua Ni
nung nng n phn ng hon ton thu c hn hp Y c dY/H2 = 8 . CTPT ca X l
A. C2H4
B. C2H2
C. C3H4
D. C4H8
Cu 7.Cho hn hp X gm etilen v H2 c t khi so vi H2 bng 4,25. Dn X qua
Ni nung nng ( Hiu sut phn ng l 75%) thu c hn hp Y .T khi ca Y so vi
H2
A. 5,23
B. 4,26
C. 2,54
D. 5,28
Cu 8: Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i
qua bt niken nung nng n khi phn ng xy ra hon ton, thu c hn hp Y c
t khi so vi heli l 4. CTPT ca X l
A. C2H4
B. C3H6
C. C4H8
D. C5H10
Cu 9. Cho 0,42 lt hn hp kh B gm hai hidrocacbon mch h i rt chm
qua bnh ng nc Brom d. Sau phn ng xy ra hon ton thy c 0,28lt kh
i ra khi bnh v c 2 gam Brom tham gia phn ng. Cc th tch kh o
ktc. T khi ca B so vi H2 l 19. CTPT ca mi cht trong B l
A. C2H6 v C4H6
B. C3H8 v C2H2
C. CH4 v C2H2
D. A hoc B
Cu 10 . Dn hn hp kh A gm mt hirocacbon no v mt hircacbon khng
no vo bnh nc brom cha 10 gam brom. Sau khi brom phn ng ht th khi lng bnh tng ln 1,75 gam v thu c dung dch X , ng thi kh bay ra khi
1

Gv: Nguyn NGc Dng

bnh c khi lng 3,65 gam . t chy hon ton lng kh bay ra khi bnh thu c
10,78 gam CO2 . Cng thc phn t ca cc hirocacbon l
A. CH4 v C2H4
B. C2H6 v C2H4
C. C3H8 v C3H6
D. A hoc B
Cu 11 . Mt hn hp kh c khi lng 7,6 gam gm 2,24 lt mt hirocacbon
mch thng A v 1,12 lt mt ankin B ( ktc) . t chy hon ton hn hp trn ri
cho ton b sn phm chy hp th ht trong dung dch Ba(OH) 2 d th c
108,35 gam kt ta . Bit rng A v B hn km nhau mt nguyn t cacbon
trong phn t . CTPT ca A v B l
A. C4H8 v C3H4
B. C3H6 v C2H2
C. C2H4 v CH4
D. C3H4 v
C2H4
Cu 12 . Mt hn hp gm 2 hirocacbon mch h . Cho 1680 ml hn hp trn i
chm qua nc brom d. Sau khi phn ng hon ton cn li 1120 ml v lng brom
tham gia phn ng l 4 gam . Mt khc nu t chy hon ton 1680 ml hn hp
trn ri cho ton b sn phm chy hp th vo nc vi trong d th thu c 12,5 g
kt ta .Xc nh cng thc 2 hirocacbon.
A. CH4 v C2H4
B. CH4 v C3H6
C. C2H6 v C2H4
D. C3H8 v
C3H6
Cu 13. t chy 6,72 lt kh ( ktc) hai hirocacbon cng dy ng ng to
thnh 39,6 gam CO2 v 10,8 gam H2O .Cng thc phn t mi hirocacbon l
A. C2H2 v C3H4
B. C3H4 v C5H8
C. C2H2 v C4H6
D. C3H4 v
C4H6
Cu 14 . t chy hon ton 0,2 mol mt hirocacbon bng lng oxi va . Sau
phn ng thu c 17,92 lt hn hp kh 273oC v 3 atm . T khi hi ca hn hp
i vi hiro l 53/3 . Cng thc phn t ca cht hu c l
A. C4H4
B. C4H6
C. C3H4
D. C4H8
Cu 15 . t chy 8,8 gammt hn hp 2 ankan th kh thy sinh ra 13,44 lt
CO2 ( ktc)
a , Tnh tng s mol 2 ankan .
b, Tm cng thc phn t ca 2 ankan bit rng th tch 2 ankan trong
hn hp bng nhau .
A. 0,1 mol , C2H6 v C4H10
B. 0,2 mol ; CH4 v C3H8
C. 0,3 mol ; C2H6 v C4H10
D. 0,2 mol ; C2H6 v C4H10
Cu 16 . t chy hon ton 29,2 gam hn hp 2 ankan A v B . Sn phm sinh ra
cho vo dung dch Ba(OH)2 thy khi lng bnh tng 134,8 g .Nu A , B l ng
ng k tip , cng thc phn t A , B l
A. CH4 v C2H6
B. C2H6 v C3H8
C. C3H8 v C4H10 D. C4H10 v C5H12
Cu 17 . Mt hn hp X gm ankan A v anken B ( s nguyn t hiro trong
phn t A bng s nguyn t cacbon trong phn t B ) . Khi t chy 3g hn hp
X th thu c 5,4 g nc . Xc nh cng thc phn t A, B l
A. C2H6 v C6H6
B. CH4 v C4H8
C. CH4 v C4H4 D. C2H2 v C2H6
Cu 18 . Mt hn hp kh A, B lin tip dy ng ng ankin . Ly 14,7 g hn
hp chia lm 2 phn bng nhau :
Phn 1 : Tc dng ht 48g brom
Phn 2 : Dn qua dung dch AgNO3/ NH3 thu c kt ta . Cho vo dung dch
HCl d thu c mt kt ta khc nng 7,175 gam .
Tn gi ng ca A, B ln lt l
2

Gv: Nguyn NGc Dng

A. propin v but- 2- in B. propin v but 1 in
A v B

C. but -1-in v pen- 2- in

D.

Cu 19. Hn hp X gm mt olefin M v H2 c khi lng phn t trung bnh l

10,67. Cho hn hp X qua Ni nung nng c hn hp Y c t khi i vi H2 l 8.
CTPT ca M l
A. C2H4
B. C3H6
C. C4H8
D. C5H10
Cu 20. t chy hon ton 3,24g hn hp X gm 2 cht hu c A v B khc dy
ng ng trong A hn B 1 Cacbon, thu c nc v 9,24 g CO2. Bit t khi
ca X so vi H2 l 13,5. Cng thc phn t ca A v B l
A. C2H2 v CH4
B. C2H6 v HCOOH
C. CH4 v C2H6O
D. C2H2v
HCHO
Cu 21. Cho hn hp kh X gm hirocacbon A v oxi d trong bnh kn ri t
chy , sau khi lm lnh hn hp kh thu c nhn thy th tch gim 33,3 % so vi
hn hp thu c . Tip tc dn hn hp kh qua KOH th th tch b gim 75% s
cn li . CTPT ca A l
A. C2H2
B. C3H4
C. C3H6
D. C4H4
Cu 22. t chy hn hp 2 hirocacbon no l ng ng k tip bng oxi thu
c CO2 v H2O . T l th tch hn hp hirocacbon vi CO 2 l 22/24 . CTPT
ca mi hirocacbon trong hn hp l
A. C2H6 v C3H8
B. CH4 v C2H6
C. C3H8 v C4H10 D. C4H10 v C5H12
Cu 23. Khi Clo ho 60 gam hirocacbon no thu c 3 dn xut monoclo, iclo,
triclo. T l th tch ca 3 dn xut trng thi hi tng ng l 2 : 1: 3 . T
khi hi ca hn hp cc dn xut ny so vi khng kh l 3,62. CTPT ca
hirocacbon l
A. CH4
B. C3H8
C. C2H6
D. C4H10
Cu 24 . Trong mt bnh kn th tch 5,6 lt cha 3,36 lt H2 v 2,24 lt C2H4
(ktc) v bt Ni . t nng bnh mt thi gian ri lm lnh v 0 oC , p sut trong
bnh lc ny l P.
Nu cho hn hp kh sau phn ng qua nc brom thy c 0,8 gam brom tham gia
phn ng . p sut P sau phn ng ( th tch Ni khng ng k) l
A. 0,62 atm
B. 0,53 atm
C. 5,6 atm
D.
1,24 atm
Cu 25. t chy hon ton hn hp c t l s mol bng nhau ca C 8H8 v mt
hirocacbon B trong oxi thu c CO2 v hi H2O theo t l tng ng l 13/10
.Cho bit cht B l g ? Bit phn t khi di 152 vC
A. C3H8
B. C4H10
C. C5H10
D. C5H12
3
Cu 26. Cho 1232 cm hn hp gm ankan A v anken B th kh ( s nguyn t
H trong A v B nh nhau ) vo nc brom d thy khi lng bnh tng ln 1,4 gam . t
chy hon ton cht kh sau khi qua Br2 ri cho sn phm chy vo NaOH d thu
c 180 ml dung dch mui 0,5M . CTPT ca A v B
A. C2H6 v C2H4
B. C3H8 v C4H8
C. C3H8 v C2H4
D. C4H8 v
CH4
Cu 27. Hn hp X gm 0,15 mol CH4 ; 0,09 mol C2H2 v 0,2 mol H2 . Nung nng
hn hp X vi xc tc Ni thu c hn hp Y . Cho Y qua bnh ng dung dch brom
3

Gv: Nguyn NGc Dng

d ,cn li hn hp kh Z c phn t khi trung bnh l 16. tng khi lng ca
dung dch brom l 0,82g.Phn trm C2H6 trong hn hp Z
A. 22,22%
B. 66,67%
C. 18,96%
D. 33,33%
Cu 28. Cho hn hp A gm 2 hirocacbon X v Y mch h ( Y nhiu hn X mt
lin kt ).
Ly 161,28 ml lt A li qua bnh ng dung dch brom d thy c 1,92 gam brom
phn ng v khng c kh thot ra khi bnh . Mt khc t chy hon ton
313,6 ml A thu c 1,848 gam CO2 . CTPT ca X v Y ( cc kh ktc) l
A. C3H4 v C3H6
B. CH4 v C2H4
C. C2H4 v C3H4
D. C3H8 v
C2H2
Cu 29 . Trong mt bnh kn cha C2H4 (etilen) v H2 v mt t bt Ni ktc .
t nng bnh mt thi gian sau lm lnh ti 00C , p sut trong bnh l P atm,
t khi hi ca hn hp kh trong bnh trc v sau phn ng l 7,5 v 9 . Tnh p
sut P (Bit p sut trc phn ng l 1atm)
A. 2/7 atm
B. 1/3 atm
C. 5/6 atm
D. 6/7 atm
Cu 30.Hn hp X gm hai hirocacbon A v B ( A c s cacbon ln hn B, A v B
u phn ng vi dung dch Brm) . 8,96 lt hn hp X tc dng ht vi nc Brm
cn 64 gam Br2 . Mt khc em t chy 8,96 lt hn hp X tng s CO2 thu c
l 48,4 gam . Hiu s hi nc sinh ra ca A so vi A l 12,6 gam . Cng thc phn
t ca A v B l
A. C4H6 v C3H6
B. C4H6 v C3H8
C. C3H4 v C2H2
D. C3H6 v
C2H4
Cu 31. Hai anken A v B nu trn theo t l th tch bng nhau th 33,6 gam
hn hp tc dng va vi 96 gam brm . Nu A v B trn theo t l khi lng
bng nhau th 16,8 gam hn hp tc dng ht 7,168 lt H2 . Cng thc phn t
ca A v B l
A. C3H6 v C4H8
B. C3H6 v C5H10
C. C2H4 v C3H6
D. C2H4 v
C4H8
Cu 32. Mt hn hp kh X cha 0,15 mol H2 v 0,1 mol C2H4 . Cho hn hp X qua
Ni nung nng ta c hn hp kh Y . Cho Y qua dung dch brm thy c 0,8 gam
Br2 tham gia phn ng .Hiu sut phn ng hir ho v t khi ca hn hp Y
i vi oxi l
A. 95% v 0,625
B. 95% v 0,525
C. 80% v 0,896
D. 80% v
0,428

P N
1A
6C
11
16C
21B

2B
7A
12B
17B
22B

3C
8D
13C
18A
23C

4D
9D
14A
19A
24A

5D
10D
15D
20D
25D
4

Gv: Nguyn NGc Dng

26B
31B

27A
32A

28A

29C

30D