KIM TRA BI C

- Th in cc chun ca kim Ioi I g?

- Xc [nh E

Mg
2+
/Mg
.Bit E
0

Pin (Mg - H )
I 2,37 V ?

2

TIT 36: BI 20: DY IEN HA CA KIM LOAI (tit

3)
I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM
LOAI:
IV. DY TH IEN CUC CHUAN CA KIM
LOAI:
- Dy th in cc chun ca kim loi l
dy sp xp cc kim loi theo th t t!n"
d#n th in cc chun$
Dy th in cc
chun ca kim loi l
g?
Theo chiu t tri sang phi:
Tnh oxi ha ca ion kim loi v
tnh kh ca kim loi i!n "#i
nh$ th! no%
Li
+
K
+
Ba
2+
Ca
2+
Na
+
Mg
2+
Al
3+
Mn
2+
Zn
2+
Cr
3+
Fe
2+
Ni
2+
Sn
2+
Pb
2+
2H
+
Cu
2+
Fe
3+
Hg
2+
Ag
+
Pd
2+
Au
3+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb H
2
Cu Fe
2+
Hg Ag Pd Au
-%&'( -)&*% -)&*' -)&+, -)&,' -)&%, -(&-- -(&(+ -'&,- -'&,. -'&.. -'&)- -'&(. -'&(% '&''/'&%./'&,,/'&,*/'&+'/'&**/(&0'
/12nh oxi h3a ca ion kim loi cn" t!n"$
/12nh kh4 ca kim loi cn" "i5m$
!nh o"i h#a ca ion kim loi t$ng %&n
!nh kh' ca kim loi gi(m %&n
&o snh s' gi(ng v khc nhau gi)a
*+, "i-n ha ca kim loi v *+,
hot ".ng ha h/c ca kim loi%
1heo chi6u 7
'
8n/98
t0ng:

TIT 36:BI 20: DY IEN HA CA KIM LOAI (tit 3)

I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM LOAI:
IV. DY TH IEN CUC CHUAN CA KIM
LOAI:
1.So snh tnh oxi ha-kh:
Th in cc chun E
0
M
n+
/ M
cng l)n th:
+ Tnh oxi ho ca cation M
n+
cng mnh.
+ Tnh kh ca kim Ioi M cng yu
v nguc Ii.
1'a vo ,!u t( no "2
so snh tnh oxh 3 kh
ca cc c4p oxh 3 kh
v5i nhau%
;1 (: Tnh oxi ha ca ion 67 no
mnh nh8t9 tnh kh ca 67 no mnh
nh8t % i!t :
7
<
8"
)/
98"
= -)&%,>? 7
<
@l
%/
9@l
= -(&-->?
7
<
Au
)/
9Au
= '&%.>
*y +,t +a -uy lu.t /o /0nh
t!nh o"i h#a 1 kh' khi %a
2o th in cc chun?
- Da vo th in cc chun ca cp
oxh - kh so snh.
:p n ;T<:
= Tnh >?@ mnh nh8t:Au
BC
= Tnh kh mnh nh8t: Dg
V. NGHA DY TH IEN CUC CHUAN
CA KIM LOAI:

TIT 36:BI 20: DY IEN HA CA KIM LOAI (tit 3)

I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM LOAI:
IV. DY TH IEN CUC CHUAN CA KIM
LOAI:
1. So snh tnh oxi ha-kh:
2. Xc [nh chiu ca p oxi ha -kh:
3ui t4c
Ahi6u ca ph5n n" x5y Ba theo Cui
tc ?
;1): cho Dit:
7<
@"
/
9@"
= /'&+' >? 7<
Au
)/
9Au
= /'&%. >
>it ptp x5y Ba "iEa cc cFp oxi ho-
kh4$
2+ +
Cu Ag
Cu Ag

Cht OXH mnh
Cht OXH yu
Cht kh yu
Cht kh mnh
:p n ;TB:
BEg
C
C Au Au
BC
C BEg

TIT 36:BI 20: DY IEN HA CA KIM LOAI (tit 3)
I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM LOAI:
IV. DY TH IEN CUC CHUAN CA KL:
1. So snh tnh oxi ha-kh:
2. Xc [nh chiu ca p oxi ha - kh:
3.Xc [nh sut in ng chun ca pin
in ha:
E
o
pin
= E
o
(+)
- E
o
(- )
Ch : E
o
pin >0
BT3: !nh /u5t in 6ng chun ca
7in in h#a 8n19u: ;it<
7
'
Au
)/
9Au
= +0,34 > ? 7
<
Gn
)/
9Gn
= - 0,76>
=h4c li c>ng th?c
t!nh /u5t in 6ng 2
/u5t in 6ng chun
ca 7in in h#a@
:p n ;TF:
7
'
pin
= 7
'
Au
)/
9Au
- 7<
Gn
)/
9Gn

= '&%. H IH'&,-J = (&('>

TIT 36:BI 20: DY IEN HA CA KIM LOAI (tit 3)
I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM LOAI:
IV. DY TH IEN CUC CHUAN CA KL:
1. So snh tnh oxi ha-kh:
2. Xc [nh chiu ca p oxi ha - kh:
3. Xc [nh sut in ng chun ca pin
in ha:
4. Xc [nh th in cc chun ca cp
oxiha-kh:
- Khi bit E
0
pin
v th in cc chun ca
1 cp oxi ha-kh th tnh uc th
in cc chun ca cp oxi ha-kh
cn Ii.
BT4: Bit sut in ng chun ca pin
in ha Zn - Ag I 1,56 V v th in
cc chun ca cp oxi ha - kh Ag
+
/Ag
I +0,80 V. Hy xc [nh th in cc
chun ca cp Zn
2+
/Zn
V. NGHA CA DY TH IEN CUC
CHUAN CA KIM LOAI:
:p n ;TG:
7
'
pin
= 7
'

@"
/
9@"
H 7
'

Gn
)/
9Gn

K 7
'

Gn
)/
9Gn
= 7
'

@"
/
9@"
- 7
'
pin

= /'&+' H (&0- = H '&,- >

TIT 36: BI 20: DY IEN HA CA KIM LOAI (tit 3)
I. KHI NIEM V CAP OXI HO - KH:
II. PIN IEN HO:
III.TH IEN CUC CHUAN CA KIM LOAI:
IV. DY TH IEN CUC CHUAN CA KIM
LOAI:
So snh tnh oxi ha-kh.
Xc [nh chiu ca p oxi ha -kh.
Xc [nh sut in ng chun ca
pin in ha$
Xc [nh th in cc chun ca cp
oxi ha-kh
V. NGHA CA DY TH IEN CUC
CHUAN CA KIM LOAI:
1heo chi6u 7
'

8
n/
9 8
t0ng:
/12nh oxi h3a ca ion kim loi cn" mnh$
/12nh kh4 ca kim loi cn" yu $

Cu 1: Cho (1)
!

Fe
2+
" Fe
# $!%&& '( (2)
!

Na
+
" Na
# $2%)! '(
(3)
!

Cu
2+
" Cu
# +!%3& '((&)
!

Zn
2+
" Zn
# $!%)* '(
(+)
!
Fe
3+
" Fe
2+
# +!%)) '
A,1% 2% 3% &% +,
B,2% 1% 3% &% +,
C, 2% &% 1% 3% +,
D,+% 3% 1% &% 2,
CU HI TRC NGHI!
A2BCDEFGH
10

CU HI TRC NGHI!
A2BCDEFGH
10
@$ 8"
)/
/ )L
/
Cu 1: Aho 7
'
8"
)/
9 8"
= - )& %, >? 7
'

)L
/
9 L
= '&'' >?
8" / L
)
;$ )L
/
/ 8"
8"
)/
/ L
)
A$ 8" / L
)
8"
)/
/ )L
/
D$ 8"
)/
/ L
)
8" / )L
/
2

AMu (:12nh chNt chun" ca Oim loi$ P"uyQn nhMnR
AMu ):SuNt in Tn" chun ca kim loi "iUn" hay
khc so VWi suNt in Tn" ca kim loi$
V NH :
- Lm bi tp: 1Ban" (() SXO H () PA
- Chun b[:
/ Ahun DY tBZWc ph#n Di t[p 1Ban" ()0&()- SXO () PA


;\] 1^_:
12nh th in cc chun ca cFp oxi h3a H kh4 Pi
)/
9 Pi$
;it 7
'
_inI Pi-AuJ
= '&-' > V 7
'

Au
)/
9 Au
= /'&%. >$
X]`]:
1a c3: 7
'
_inI Pi-AuJ
= 7
'

Au
)/
9 Au
- 7
'
Pi
)/
9 Pi
7
'

Pi
)/
9 Pi
= 7
'

Au
)/
9 Au
- 7
'
_inI Pi-AuJ

= '&%. H '&-' = -'&)- >