De Thi LTDH Hoa Hoc Alpha.2006.Ban Alpha

20 e Luyen thi ai hoc Mon Hoa
TS. Nguyen Phi Hung
E 01
Cau 1 : Pha loang 10ml dd HCl vi nc thanh 250 ml.
Dd thu c co pH = 3. Hay tnh nong o mol/lt cua dd
HCl trc khi pha loang va pH cua dd o.
Cau 2 : 1. Trnh bay c che an mon khi thep tiep xuc
vi hi nc lan cac oxit nh CO2, SO2.
2. Neu phng phap ieu che cac kim loai Na, Fe,
Al t hon hp ran gom Na2SO4, Al2O3 va Fe2O3.
Viet phng trnh phan ng.
Cau 3 : Hay hoan thanh s o bien hoa sau :
15000C
Cau
Cau
Cau
Cau
CH4
B+C
?
B + H2O
D
?
D + O2
E
Xuc tac
E+B
I
nI
G
Trung hp
4 : Biet rang t capron va chat deo polimetylacrilat
eu co kha nang phan ng vi dd NaOH nong.
Giai thch bang phng trnh phan ng.
5 : Cho 2,88 g Cu vao 50 ml dd Cu(NO 3)2 0,5 M va H2SO4
1 M. Sau khi ket thuc phan ng, lay phan dung
dch em co can th c bao nhieu gam chat ran
khan?
6 : Cho lng d bot Fe tac dung vi 250 ml dung
dch HNO3 4 M un nong va khuay eu hon hp.
Phan ng xay ra hoan toan va giai phong ra kh
NO duy nhat. Sau khi phan ng ket thuc, em loc
bo ket tua, thu c dung dch A. Lam bay hi can
than dung dch A thu c m1 gam muoi khan. Nung
nong lng muoi khan o nhiet o cao e
phan ng nhiet phan xay ra hoan toan, thu c
m2 gam chat ran va V lt ( ktc) hon hp gom hai
kh.
1. Viet cac phng trnh phan ng xay ra.
2. Tnh cac khoi lng m1, m2 va the tch V.
7 : X la hp chat cha C, H, O. ot chay hoan
toan X bang O2 va u, nhan thay ty le so mol
CO2, H2O san pham va O2 phan ng la 6 : 4 : 7.
Trung tam Luyen thi ai hoc Alpha

141 Tran Cao Van - Quy Nhn. T: 056. 812. 286 746.
989

TS. Nguyen Phi Hung
1. Tm cong thc n gian cua X.

2. X la mot anehit mach h, khong mang nhom
chc khac. C 0,045 mol X phan ng het vi H 2
d, thay the tch H2 tac dung la 3,024 lt (ktc).
nh CTPT, viet cac CTCT mach thang co the co
cua X.
Cau 8 : A la mot aminoaxit mach cacbon khong phan
nhanh. Cho 0,1 mol A vao dd cha 0,25 mol HCl (d),
c dd B. e phan ng het vi dd B, can 300 ml
dd NaOH 1,5 M un nong. Neu co can dd sau cung,
th c 33,725 g chat ran khan. Viet CTCT co the
co cua A ./.
E 02
Cau 1 : Neu hien tng va viet cac phng trnh phan
ng xay ra khi:
1. Cho Na vao dd sat (II) sunfat.
2. Cho la Fe vao: a) dd H2SO4 loang; b) dd H2SO4 loang
lan mot t CuSO4.
3. Cho t t dung dch AlCl3 vao dung dch Na2CO3.
Cau 2 : Hay nhan biet (khong c dung them hoa
chat khac) 5 lo mat nhan ng 5 dung dch sau :
NaOH, KCl, MgCl2, CuCl2, AlCl3.
Cau 3 : Hay viet CTCT cac ong phan axit mach h
co cung CTPT C4H6O2. Trong cac ong phan nay,
chat nao c dung e ieu che thuy tinh hu
c, viet cac phng trnh phan ng ieu che thuy
tinh. Chat nao co ong phan cis-trans, viet CTCT
cua ong phan cis va trans.
Cau 4 : Cong thc n gian cua chat A la (C 3H4O3)m va
chat B la (C2H3O3)n. Hay bien luan e tm CTPT
cua A, B. Biet A la mot axit no a chc, con B la
mot axit no cha ong thi nhom chc OH. A va
B eu mach h. Hay viet CTCT cua B (khong
phan nhanh).
Cau 5 : Hoa tan hoan toan 1,92 g hon hp A gom kim
loai M (hoa tr 1) va kim loai R (hoa tr 3) vao
2

989

TS. Nguyen Phi Hung
nc thanh dung dch B va 1,344 lt kh (ktc). Chia

dd B lam hai phan bang nhau :
- Phan 1 cho tac dung vi dd HCl 0,9 M en khi co
ket tua ln nhat, roi giam con mot na, th a
dung 50 ml dd HCl.
- em co can phan 2 th c m gam hon hp ran
khan.
Xac nh hai kim loai M, R. Tnh m.
Cau 6 : Cho hon hp X gom Ag va Cu tan het trong
H2SO4 ac d, c dd Y va 1,008 lt kh SO 2 (ktc). Pha
loang dd Y thanh 500 ml dd Y 1. Nhung mot thanh Al
vao dd Y1 en khi the tch kh thoat ra la 6,72 lt
(ktc) va dd con lai ch cha mot muoi. Nhan
thay khoi lng thanh kim loai Al giam i 0,59 gam
(so vi ban au). Tnh nong o mol/lt moi muoi
trong dd Y1. (Biet rang kim loai sinh ra eu bam het
tren thanh Al).
Cau 7 : Hp chat hu c A co khoi lng phan t
nho hn khoi lng phan t cua benzen, ch
cha 4 nguyen to C, H, O, N, trong o phan tram
khoi lng hidro 9,09%, nit18,18%. ot chay 7,7
gam chat A, thu c 4,928 lt kh CO 2 o 27,30C; 1
atm.
1. Xac nh cong thc phan t cua A.
2. Cho 7,7 gam chat A tac dung het vi 200 ml dung
dch NaOH. Sau o em co can dung dch th thu
c 12,2 gam chat ran khan. Tnh nong o mol/lt
cua dung dch NaOH.
Cau 8: Mot chat hu c B mach h, khong nhanh,
gom 3 nguyen to C, H, O. Chat B ch cha cac
nhom chc co nguyen t hidro linh ong. Cho B
tac dung vi Na d thu c H 2 co so mol bang so
mol cua B.
1. Hoi trong B co the co loai nhom chc nao?
2. B phan ng vi CuO nung nong tao ra anehit.
Lay 13,5 gam B phan ng va u vi Na 2CO3, thu
c 16,8 gam muoi E va co kh CO 2 bay ra. Xac
nh cong thc cau tao cua B ./.
989

TS. Nguyen Phi Hung
E 03
Cau 1: 1. Neu nh ngha axit, baz theo Areniut,
Bronsted.
2. Viet cac phan ng e chng minh cac chat
Al(OH)3, NaHCO3, H2O la hp chat lng tnh theo
Bronsted.
Cau 2 : Xac nh cac chat va viet cac phng trnh
phan ng t s o
+dd FeCl
+H: , t0
Muoi
X
t0
Ran
X1
hh kh nau
o
Ran X2
o
+H2
O
dd X4
Kim loai
X3
X6
+X5
X5
Cau 3 : T metan va cac chat vo c can thiet, hay

viet cac phng trnh phan ng ieu che ru polivinylic.
Cau 4 : Amin bac nhat X dang RNH2 co ty khoi hi so
vi hidro bang 15,5. Hay goi ten va viet phng
trnh phan ng minh hoa tnh chat hoa hoc cua X.
Cau 5 : Lay 14,4 gam hon hp Y gom bot Fe va Fe xOy
hoa tan het trong dung dch HCl c 2,24 lt kh
2730C, 1 atm. Cho dung dch thu c tac dung vi
dung dch NaOH d. Loc lay ket tua, lam kho va
nung trong khong kh en khoi lng khong oi
c 16 gam chat ran.
1. Tnh % khoi lng cua cac chat trong hon hp Y.
2. Xac nh cong thc cua sat oxit.
Cau 6 : Dung dch A gom NaOH 0,2M va Ba(OH) 2 0,05M.
Dung dch B cha Al2(SO4)3 0,4M va H2SO4 x mol/lt.
1. Tnh pH cua dung dch A.
2. Cho 0,1 lt B vao 1 lt A. Ket thuc phan ng thay
co 16,33 g ket tua. Tnh x.
Cau 7 : ot chay hoan toan hon hp A gom 2 ru n
chc, mach h, ke tiep trong day ong ang thu
c kh CO2 va hi nc co ty le the tch tng
ng la 5 : 7.
1. Xac nh cong thc phan t cua 2 ru.
2. Tnh thanh phan % theo khoi lng cua 2 ru
trong hon hp A.
4

989

TS. Nguyen Phi Hung
Cau 8 : ot chay hoan toan 2,28 g chat hu c X can

3,36 lt O2 (ktc), ch thu c CO2 va hi H2O co ty
le the tch tng ng la 6 : 5. Neu un X vi dd
H2SO4 loang thu c axt hu c A (ty khoi hi so
vi H2 bang 36) va ru n chc B. Oxy hoa
khong hoan toan B thu c chat C co kha nang
cho phan ng trang gng. Tm CTPT, CTCT va goi
ten cua X ./.
E 04
Cau 1 : Can bang cac phan ng sau:
1. Al + HNO3 Al( NO3)3 + N2O + H2O
2. Cu2S + HNO3 Cu(NO3)2 + CuSO4 + NO + H2O
3. Cu2S.FeS2 + HNO3 Cu(NO3)2 + Fe(NO3)3 + H2SO4 + NO +
H 2O
4. Fe2+ + MnO4- + H+ Fe3+ + Mn2+ + H2O
Cau 2 : Trong mot bnh kn cha N 2O4, xay ra phan ng
thuan nghch sau:
N2O4
2NO2
(kh khong mau)
(kh mau nau)
Biet rang Kcb = 0,18 va khi can bang th [N 2O4] =
0,02 M.
1. Tnh nong o mol/lt ban au cua N2O4.
2. Khi ngam bnh vao nc a, thay mau nau
nhat dan. Hay cho biet phan ng thuan la thu
hay toa nhiet?
Cau 3 : 1. Phan biet phan ng trung hp, ong trung
hp, trung ngng. Cho v du minh hoa.
2. Viet cac phng trnh phan ng minh hoa tnh
chat hoa hoc cua axt acrylc.
Cau 4 : Xac nh cac chat va hoan thanh day
chuyen hoa sau:
0
Br2
O2 , xt
NaOH
CuO , t
NaOH
NaOH , CaO , t
C 3 H 6 +
A +
B +
D +
E +
F +
CH
Cau 5 : 1. Hay giai thch:
a) S hnh thanh thach nhu trong cac hang
ong.
b) Tac dung lam trong nc cua phen chua.

989

TS. Nguyen Phi Hung
c) Tac dung cua cac tam kem gan vao vo

tau bien bang thep (phan ngam di
nc bien).
2. Mot dd axt HA 0,1M co Ka = 2.10-5. Tnh pH cua dd
va o ien ly cua HA.
Cau 6 : Cho 115,3 g hon hp X gom MgCO 3 va RCO3 (R la
kim loai hoa tr 2 duy nhat) vao 500 ml dd H 2SO4
loang. Khi phan ng cham dt, c dd A, chat
ran B va 4,48 lt kh (ktc). Co can A, con lai 12 g
muoi khan. Nung B en khoi lng khong oi, c
chat ran B1 va 11,2 lt mot loai kh (ktc).
1. Tnh nong o mol/l cua dd H 2SO4 a dung, khoi
lng B va B1.
2. Xac nh kim loai R va khoi lng moi muoi
trong hon hp X, biet rang ty le mol 2 muoi
trong X la 5 : 2.
Cau 7: Hon hp A gom hai axit cacboxylic no n chc co
KLPT hn kem nhau 28 vC. Lay m gam hon hp A
tac dung vi Na d, thu c 2,016 lt kh H 2 54,60C
va 2 atm.
Mat khac ot chay hoan toan m gam hon hp A,
dan toan bo san pham chay qua bnh 1 cha P 2O5,
sau o qua bnh 2 cha 470,25 g dung dch Ba(OH) 2
20%. Sau phan ng khoi lng bnh 1 tang 14,4 g;
bnh 2 c dung dch B va khong co kh i ra khoi
bnh 2.
1. Tnh m.
2. Xac nh cong thc cau tao cua moi axit, oc
ten.
3. Tnh nong o phan tram cua chat tan co trong
dung dch B.
Cau 8 : ot chay toan toan 4,45 g este A, c ieu
che t aminoaxit X va ru metylic, ta c 3,15 g
H2O; 3,36 lt CO2 va 0,56 lt N2 (ktc). Ty khoi hi cua
A so vi khong kh bang 3,069.
1. Viet cong thc phan t va cong thc cau
tao cua A va X.
6

989

TS. Nguyen Phi Hung
2. Viet phng trnh phan ng trung ngng X thanh

polime ./.
E 05
Cau 1 : Mot loai muoi an b lan cac tap chat la
Na2SO4, NaBr, MgCl2, CaCl2 va CaSO4. Hay trnh bay
phng phap hoa hoc e thu c NaCl tinh khiet.
Cau 2 : Cho day sau ay (theo chieu tang tnh oxi hoa
cua ion) : Zn2+/Zn, Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+, Ag+/Ag.
Trong cac kim loai tren:
1. Kim loai nao phan ng c dd muoi Fe (III)?
2. Kim loai nao co kha nang ay Fe ra khoi dd
muoi Fe (III)?
3. Co the xay ra phan ng khong khi cho AgNO 3
tac dung vi dung dch Fe(NO3)2? Viet cac phng
trnh phan ng.
Cau 3 : So sanh va giai thch:
1. Tnh axt: etanol, phenol, axit propionic, axit axetic,
axit monocloaxetic, axit dicloaxetic, axit tricloaxetic.
2. Tnh baz: metylamin, amoniac, anilin, dimetylamin.
3. Nhiet o soi: dimetyl ete, axit axetic, etanol.
Cau 4 : A1 la ong phan mach h co CTPT C3H6O2. Cho
A1 tac dung vi dd NaOH, thu c muoi A2. Cho A2
tac dung vi dd H2SO4 thu c chat hu c A3. Cho
A3 tac dung vi dd AgNO 3/NH3 d thu c chat A4; A4
co kha nang tac dung vi dd NaOH va vi dd
H2SO4 loang eu co kh thoat ra. Xac nh va goi
ten cac chat A1, A2, A3, A4. Viet phng trnh phan
ng.
Cau 5 : Trong mot bnh kn the tch khong oi khi thay
oi nhiet o, cha a mol O 2 va 2a mol SO2
27,30C; 10 atm va co mat xuc tac ran V 2O5. Nung
nong bnh mot thi gian 409,50C cho en khi ap
suat trong bnh la p (atm). Lap bieu thc tnh p theo
hieu suat h (%) va xet xem p thay oi trong
khoang gia tr nao?
Cau 6 : Tnh khoi lng cac chat thoat ra ien cc
va nong o mol/lt cua cac chat trong dung dch
989

TS. Nguyen Phi Hung
sau khi ta ien phan 200 ml dd hon hp NiCl 2, CuSO4,

KCl lan lt co nong o 0,1 M; 0,05 M va 0,3 M vi
cng o dong ien 5 A trong thi gian t = 32
phut 10 giay, ien cc tr va hieu suat ien
phan la 100%. Bnh ien phan co mang ngan va
the tch dd coi nh khong thay oi trong qua trnh
ien phan.
Cau 7: 1. Mot hp chat n chc X mach h cha C, H,
O. Khi ot chay 1 mol X can va u 3 mol O 2. Xac
nh cong thc phan t, cong thc cau tao co
the co cua X.
2. Xac nh cong thc cau tao ung cua X biet
rang: khi oxi hoa het mot lng X bang oxi (co
xuc tac, t0) th nhan c hon hp Y co kha nang
phan ng trang gng va tac dung c vi dd
Na2CO3. Viet tat ca cac phng trnh phan ng xay
ra.
Cau 8: Hon hp X gom 2 este n chc, cha C, H, O.
Lay 0,25 mol X phan ng vi 250 ml dd NaOH 2M
un nong, thu c mot andehit no, mach h va
28,6 gam hai muoi hu c; khoi lng muoi nay
bang 1,4655 lan khoi lng muoi kia. e phan
ng het vi NaOH con d, can 150 ml dd HCl 1 M.
Biet phan tram khoi lng oxi trong andehit la
27,58%. nh CTCT 2 este ./.
E 06
Cau 1 : Cho hon hp gom FeS 2, Fe3O4, FeCO3 hoa tan het
trong HNO3 ac, un nong, c dd trong suot va
hon hp hai kh NO2, CO2. Them dd BaCl2 vao dd
tren, thay xuat hien ket tua trang khong tan
trong axit d. Viet cac phng trnh phan ng dang
phan t va dang ion thu gon.
Cau 2 : Neu cach tach cac muoi t hon hp gom
KCl, CaCl2, AlCl3, NH4Cl; biet rang lng muoi thu hoi
cung bang lng muoi trong hon hp ban au.

989

TS. Nguyen Phi Hung
Cau 3 : Viet CTCT cua tat ca cac ong phan mach

h co CTPT C3H6O2 va ch ro ong phan nao co
kha nang tham gia phan ng trang gng. V sao?
Cau 4 : un nong hai chat A, B co cung CTPT C 5H8O2
trong dd NaOH, c hon hp hai muoi natri cua hai
axit C3H6O2 (A1); C3H4O2 (B1) va hai san pham hu c
khac.
1. Xac nh CTCT cua A, B. Viet phng trnh phan
ng.
2. So sanh tnh chat hoa hoc cua A 1 va B1.
Cau 5 : Co 4 dd trong suot, moi dd cha hai loai ion
(khong trung vi dd khac) t cac ion sau: Ba 2+;
Ag+; CO32; NO3; 0,01 mol Al3+; 0,02 mol Cl; 0,03 mol K+;
0,04 mol SO42.
1. Xac nh 4 dd tren va khoi lng chat trong
moi dd.
2. Ch dung qu tm, neu cach phan biet 4 dd
tren.
Cau 6 : Nung 16,2 gam hon hp A gom cac oxt MgO, Al 2O3
va MO (M la kim loai co hoa tr 2 duy nhat) trong
mot ong s roi cho luong kh H2 i qua. ieu
kien th nghiem, H2 ch kh MO vi hieu suat
80%, lng hi H2O tao ra ch c hap thu 90% bi
15,3 gam dung dch H2SO4 90%, ket qua thu c
dung dch H2SO4 86,34%.
Chat ran con lai trong ong c hoa tan trong
mot lng va u dd axit HCl, thu c dd B va
con lai 2,56 gam kim loai M khong tan.
Lay 1/10 dd B cho tac dung vi NaOH d, loc lay
ket tua nung nhiet o cao ti khoi lng
khong oi th thu c 0,28 gam hh oxit.
Hay xac nh kim loai M va % khoi lng cac
chat co trong A.
Cau 7 : A, B la hai ru ong ang, trong o ru B
cha hn ru A k nguyen t cacbon. ot chay A
thu c a mol CO2 va b mol H2O. ot chay B thu
c a mol CO2 va b mol H2O.
989

TS. Nguyen Phi Hung
1. Hay tm cong thc chung cua cac ru A, B.

Biet (a/b) > (a/b).
2. Hay tm CTPT cua A, B. Biet ty le khoi lng
phan t cua ru nay so vi ru kia nam trong
khoang 1,30 va 1,35; khoi lng phan t cua
mot ru bang 92 vC.
Cau 8 : Hon hp X gom 2 este n chc, mach h, la
ong phan cua nhau. Cho a gam hon hp X tac
dung va u vi 150 ml dung dch NaOH 0,25 M thu
c muoi cua mot axit cacboxylic va hon hp hai
ru. Mat khac e ot chay hoan toan a gam
hon hp X can dung 4,2 lt O 2, thu c 3,36 lt CO2
(cac the tch kh o ktc). Xac nh cong thc
phan t va cong thc cau tao cua cac este ./.
E 07
Cau 1 : 1. Trnh bay nguyen tac, nguyen lieu, cac
phan ng chnh xay ra trong qua trnh luyen gang.
2. Hoa tan Fe3O4 bang dd H2SO4 loang d thu c dd
A. Viet phng trnh phan ng xay ra neu cho dung
dch A tac dung vi mot trong cac chat sau:
a) dd KMnO4; b) Nc Br2; c) dd KOH co mat
khong kh;
d) Cu;
e) Al;
f) HNO3
ac.
Cau 2 : Co 500 lt nc cng tam thi cha Ca(HCO 3)2
5.10-3 M va Mg(HCO3)2 2.10-3 M. Can cho bao nhieu
gam voi (CaO) vao 500 lt nc tren e cho o
cng con lai la be nhat?
Cau 3 : Cho dung dch HCl d vao 8,024 gam hon hp
LiHCO3 va K2CO3. Dan kh tao thanh vao 180 ml dung
dch Ca(OH)2 0,5 M. Tnh khoang gia tr khoi lng
ket tua thu c.
Cau 4 : Cho 220 ml dung dch HNO 3 tac dung vi 5 gam
hon hp Zn va Al. Sau khi phan ng xay ra hoan
toan thu c 0,896 lt (ktc) hon hp kh gom NO
va N2O (co ty khoi hi so vi hidro la 16,75), dung
dch A (khong cha NH 4NO3) va con lai 2,013 gam
10

989

TS. Nguyen Phi Hung
kim loai. Hoi sau khi co can can than dung dch A
th thu c bao nhieu gam muoi khan? Tnh nong
o mol/lt cua HNO3 trong dung dch ban au.
Cau 5 : 1. Viet cac phng trnh phan ng chuyen hoa
t ru n-propylic thanh ru iso propylic va ngc
lai.
2. Cho a mol CH3COOH phan ng vi a mol C2H5OH.
Viet phng trnh phan ng; tnh phan tram
CH3COOH a chuyen hoa khi phan ng at trang
thai can bang. Cho biet hang so can bang cua
phan ng K = 4.
Cau 6 : 1. Hon hp X gom benzen, phenol, anilin. Hay
trnh bay phng phap hoa hoc e tach rieng
tng chat nguyen chat.
2. Hoan thanh s o chuyen hoa sau :
t0 , xt
CH3COOH + C2H2
(A)

hp
n(A) trung
(B)

(B) +nNaOH
(C) + (D)

t0 , CaO
(C) + NaOH
(E) + (F)

0
(C)
(G) + (F)
t
Cau 7 : Cho 10,5 g mot andehit mach thang X co cong
thc R(CHO)a thc hien phan ng trang gng
(hieu suat 100%). Lay lng Ag thu c hoa tan
hoan toan vao dung dch H 2SO4 ac nong, thu
c kh Y co mui hac. Cho Y hap thu hoan toan
trong dd NaOH th thu c 12,6 g muoi trung hoa va
5,2 g muoi axt. Xac nh CTPT va CTCT cua X, biet
rang phan t lng cua X nho hn 130 vC.
Cau 8 : Cho 17,4 g mot hp chat hu c A ch

cha mot loai nhom nh chc tac dung het
vi dd NaOH tao muoi natri cua mot axit hu
c B va 0,1 mol ru C, ru nay co ty khoi
hi oi vi hydro la 31. Lay toan bo lng
ru C tao thanh cho tac dung het vi natri
thu c 2,24 lt kh (ktc). Xac nh CTPT, CTCT
cua A ./.

989
11

TS. Nguyen Phi Hung
E 08
Cau 1 : Cho hon hp ran gom cac oxit SiO 2, Al2O3, CuO,
Fe2O3. Trnh bay phng phap hoa hoc e thu c
tng oxt tinh khiet.
Cau 2 : A la mot loai oxt sat. Thc hien 2 th nghiem
vi lng A bang nhau:
A + H2SO4 loang va u ; A + H2SO4 ac va u
(tao kh SO2);
Nhan thay ty le so mol H2SO4 tham gia phan ng
trong hai th nghiem la 5 : 4.
Xac nh cong thc phan t cua A.
Cau 3 : 1. Cho V (ml) mot dd HCl co pH = 1. Them nc
vao dd nay cho ti khi pH cua dd bang 3 th the
tch dd bay gi la V (ml). Tnh V theo V.
2. Tnh lng Ca(OH)2 can thiet e lam ket tua
toan bo ion Ca2+ va Mg2+ trong cac dd sau :
a) dd cha 0,15 mol Ca(HCO3)2;
b) dd cha 0,2
mol Mg(HCO3)2.
Cau 4 : Cho 12,88 g hon hp Mg va Fe vao 700 ml dd
AgNO3. Sau khi cac phan ng hoan toan, thu c
chat ran C nang 48,72 g va dd D (khong cha ion
Fe3+). Cho dd NaOH d vao D, roi lay ket tua nung
trong khong kh en khoi lng khong oi thu c
14 g chat ran.
Tnh phan tram khoi lng cua moi kim loai trong
hon hp ban au va nong o mol/lt cua dd AgNO 3
a dung.
Cau 5 : 1. Hoan thanh cac phan ng theo s o sau
(di dang CTCT):
C3H4O2 + NaOH (A) + (B)
(A) + H2SO4 (loang) (C) + (D)
(C) + AgNO3 + NH3 + H2O Ag + NH4NO3 + (E)
(B) + AgNO3 + NH3 + H2O Ag + NH4NO3 + (F)
2. Co cac chat long sau: benzen, xiclohexen, anilin,
axit acrylic, axit fomic, axit propionic. Ch dung brom
va nc, hay phan biet chung.
12

989

TS. Nguyen Phi Hung
Cau 6 : Mot chat hu c A co cong thc C 3H9O2N. Cho A

phan ng vi dd NaOH, un nhe, thu c muoi B
va kh C (kh nay lam xanh giay quy tm tam t).
Cho B tac dung vi NaOH ran un nong thu c
CH4. Xac nh CTCT cua A, viet phng trnh phan
ng.
Cau 7 : Mot axit cacboxylic E mach khong phan nhanh,
cha 50% khoi lng cacbon. Xac nh CTPT va
CTCT co the co cua E.
Cau 8 : Hon hp M gom hai este A va B. Cho x gam hon
hp M tac dung va u vi150 ml dd NaOH 1M tao
ra dd N (co cha ru n chc C). Co can N c
15,5 g hon hp muoi natri cua hai axit n chc
lien tiep trong day ong ang cua axit acrylic.
ot chay hoan toan y gam ru C roi dan san
pham chay qua bnh ng dd Ba(OH) 2 d thay khoi
lng bnh tang z gam, ong thi xuat hien 2,774z
gam ket tua trang.
1. Xac nh cong thc ru C.
2. Xac nh CTPT va viet CTCT co the co cua A
va B.
3. Tnh thanh phan phan tram theo khoi lng
moi este trong M ./.
E 09
Cau 1 : Trnh bay phng phap hoa hoc e tach rieng
tng oxit t hon hp ran gom Na 2O; BaO; Al2O3.
Viet phng trnh phan ng.
Cau 2 : Hoan thanh cac phng trnh phan ng sau:
1.
KMnO4 + C6H12O6 + H2SO4 CO2 +
2.
Al + HNO3 NO + N2O +
(
n NO : n N 2 O = 3 : 1 )
3.
FeO + HNO3 NxOy +
4.
Fe3O4 + HNO3 NxOy +
Cau 3 : Tron t t 300 gam dd Ba(OH) 2 1,254% vao 500
ml dd cha 2 axit H3PO4 0,04 M va H2SO4 0,02 M. Tnh
khoi lng cua cac muoi tao thanh.
989
13

TS. Nguyen Phi Hung
Cau 4 : Cho hon hp A gom bot Al va mot oxit cua sat

FexOy. Thc hien phan ng nhiet nhom (gia s
FexOy ch b kh thanh Fe), thu c hon hp B co
khoi lng 19,82 g. Chia B thanh hai phan bang
nhau. un nong phan 1 vi lng d dd NaOH thay
giai phong ra 1,68 lt kh H2. Phan 2 cho tac dung
vi lng d dd axit HCl thay giai phong ra 3,472 lt
kh H2. Biet rang cac phan ng eu xay ra hoan
toan, the tch cac kh eu c o ktc.
1. Viet cac phng trnh phan ng xay ra.
2. Xac nh cong thc cua oxit sat, thanh phan
phan tram theo khoi lng cua cac chat trong
hon hp A va B.
Cau 5 : Chat A co CTPT la C 11H20O4. A tac dung vi NaOH
tao ra muoi cua axit hu c B mach thang va hai
ru la etanol va propanol-2.
1. Viet CTCT cua A, B va goi ten chung.
2. T B, viet phng trnh phan ng tao t nilon-6,6.
3. Hay giai thch tai sao t nilon-6,6 de b axit va
kiem pha huy?
Cau 6 : Cho cac chat sau: C 6H5OH; C2H5OH; CH3COOH;
C6H5ONa va C2H5ONa. Nhng cap chat nao tac
dung c vi nhau? Viet cac phng trnh phan
ng.
Cau 7 : Co 2 ru A, B (khong mang nhom chc khac).
ot chay hoan toan moi ru, eu thu c khoi
lng san pham mCO2 : m H 2O = 44 : 27 .
1. Xac nh CTCT cua A, B.
2. Viet cac phng trnh phan ng chuyen hoa
qua lai gia A va B.
Cau 8 : ot chay 1 mol ru A (no, mach h) can 4 mol
O2.
1. Xac nh CTPT ru A. Viet CTCT va ten goi
cua A, biet A khong hoa tan c Cu(OH) 2.
2. X la hp chat hu c mach h c ieu che
t ru A va axit B, trong X ch cha mot loai
nhom chc. Khi cho 16 g X tac dung het vi
14

989

TS. Nguyen Phi Hung
NaOH thu c 16,4 g muoi. Xac nh CTCT cua

X.
3. Tron 11,4 g ru A vi 15 g axit B, them mot t
H2SO4 ac lam xuc tac roi un nong mot thi
gian, thu c 16 g X. Tnh hieu suat cua phan
ng tren ./.
E 10
Cau 1 : 1. The nao la nc cng, nc cng tam
thi, nc cng vnh cu?
2. Trong so cac chat cho di ay: HCl; Ca(OH) 2;
Na2CO3; Na2SO4; Na3PO4; chat nao co the lam mem
nc cng?
Cau 2 : 1. Phan ng nhiet phan la g? Phan ng nhiet
phan co phai luon luon la phan ng oxi hoa
kh khong? Viet phng trnh phan ng nhiet
phan cac chat sau: NaNO 3; (NH4)2CO3 ; KClO3 ; KMnO4;
AgNO3; Fe(OH)3; CaCO3.
2. Viet 5 phan ng trc tiep theo s o Cl 2 HCl.
Cau 3 : Cho m gam hon hp X gom Na 2O va Al2O3 lac
vi nc en phan ng hoan toan ch thu c
200 ml dd A cha mot chat tan duy nhat co nong
o 0,5 M. Thoi kh CO 2 d vao dd A thu c a g ket
tua.
1. Tnh m, thanh phan % (theo khoi lng) cac chat
trong X.
2. Tnh a va the tch kh CO2 ( ktc) a phan ng.
Cau 4 : Cho M la hon hp Fe, FeO, Fe2O3.
1. Cho dong H2 (d) i qua 4,72 g hon hp M nung
nong thu c 3,92 g Fe. Mat khac cho 4,72 g hon
hp M vao lng d dd CuSO 4 thu c 4,96 g chat
ran. Tnh % khoi lng moi chat trong hon hp M.
2. Can dung toi thieu bao nhieu ml dd HCl 7,3% (d
= 1,03 g/ml) e hoa tan va u 4,72 g hon hp M?
Dung dch thu c luc nay goi la dd D.
989
15

TS. Nguyen Phi Hung
3. Cho dd D tac dung vi lng d dd AgNO 3. Tnh

khoi lng chat ran thu c.
(Biet rang cac phan ng xay ra hoan toan).
Cau 5 : Mot hon hp long gom benzen, phenol, anilin va
axit axetic. Trnh bay phng phap hoa hoc e tach
rieng tng chat.
Cau 6 : Hoan thanh cac phan ng : + H O
2
Polime thien nhien
A
+
0
H ,t
D (mot loai ng) + H2O

+B
H+,
Ni
t0
A + H2
E (Sorbitol)
Ni
B + H2
E
Cau 7 : ot chay hoan toan 2,92 g mot chat hu c A
bang O2, ch thu c CO2, H2O co so mol bang
nhau; va N2 co the tch < 0,896 lt (ktc). Biet rang
t khoi hi cua A so vi metan la 9,125.
1. Tm CTPT cua A.
2. Viet cac CTCT co the co cua A, neu A la mot
dipeptit tao bi hai phan t -amino axit.
Cau 8 : Cho hon hp hai chat hu c (cha C, H, O)
cung chc hoa hoc. Khi ot chay hoan toan 27,2
g hon hp nay phai dung va het 33,6 lt O 2 va
thu c 29,12 lt CO2. Cac the tch kh eu c o
ktc. Neu un nong 13,6 g hon hp au vi
lng d dd NaOH th thu c hon hp gom muoi
cua mot axit hu c n chc va 5,5 g hon hp 2
ru no n chc ke tiep nhau trong day ong
ang. Xac nh CTPT, CTCT va khoi lng moi
chat trong 13,6 g hon hp au ./.
E 11
(HH&D 28) - Thi gian lam bai: 180 phut
Cau I (H: 1,5 iem; C: 2 iem)
1. Hay chon cac chat thch hp A 1, A2, A3, khac nhau
va hoan thanh cac phng trnh phan ng sau:
16

989

TS. Nguyen Phi Hung
A 1 + A 2 + H 2O
NaAlO2 + H2
A 3 + A 4 + H 2O
Al(OH)3 + NH4 Cl
A 5 + A 6 + H 2O
Al(OH)3 + NaHCO3
Cu + A7 + A8
CuSO4 + Na2SO4 + K2SO4 +
NO + H2O
2. a) Viet cau hnh e- cua nguyen t clo (Z = 17). T
o cho biet tnh chat ac trng nhat cua clo.
b) Cho lng d dung dch AgNO 3 tac dung vi 100
ml dung dch hon hp NaF 0,05 M; NaCl 0,1 M. Viet
phng trnh phan ng xay ra va tnh khoi lng
ket tua thu c.
Cau II (H: 1,5 iem; C: 2 iem)
1. Viet cac phng trnh phan ng ieu che axit nitric
t amoniac. Co the ieu che c bao nhieu lt
dung dch HNO3 co nong o 48,4% (d = 1,3 kg/lt) t
5,6 m3 NH3 (ktc), biet rang hieu suat chung cua
ca qua trnh tren la 92%.
2. a) Cho biet pH cua dd thu c nh the nao (so
sanh vi 7) va giai thch trong cac trng hp sau:
- Them 100 ml dung dch H 2SO4 0,1 M vao 400 ml dung
dch NH3 0,05 M.
- Them 100 ml dung dch CH 3COOH 0,1 M vao
200 ml dung dch NaOH 0,05 M.
b) Tnh pH cua dd thu c khi them 1 lt dd H 2SO4 0,1
M vao 4 lt dd NaOH 0,0375 M.
Cau III (H: 1,5 iem; C: 2 iem)
1. Viet cac ptp chuyen hoa ru etylic thanh ru
metylic. Ghi ro cac ieu kien phan ng.
2. T toluen va cac chat vo c (KMnO 4, H2SO4 , HNO3
, Fe, HCl, H2O) ch qua 3 phan ng co the ieu
che axit meta-aminobenzoic. Viet cac phng trnh
phan ng xay ra (di dang CTCT) va tnh khoi
lng toluen can thiet e ieu che 27,4 gam axit
meta-aminobenzoic vi hieu suat gia thiet cua
tng phan ng lan lt la 94%, 70%, 95%.
Cau IV (H: 1,5 iem; C: 2 iem)

989
17

TS. Nguyen Phi Hung
Viet cac phng trnh phan ng (ghi ro ieu kien) e

thc hien day bien hoa:
NO2
OH
(C)
CH4
(A)
(B)
(D)
(E)
Br
(F)
NH2
Cau V (H: 2,5 iem) Hon hp X gom Fe va mot kim

loai R co hoa tr khong oi. Hoa tan hoan toan 6,6
gam hh X trong dd HCl d thu c 5,376 lt kh. Mat
khac, cung hoa tan 6,6 gam hh X trong dung dch HNO 3
(lay d 10% so vi lng can thiet) thu c 1,792 lt
hh kh Y gom N2O, NO va dd Z. T khoi cua hh Y so
vi H2 la 20,25. Cac the tch kh eu o ieu
kien tieu chuan.
1. Hay xac nh kim loai R va tnh % khoi lng tng
kim loai co trong hon hp X.
2. Cho dung dch Z tac dung vi 400 ml dung dch NaOH
1,72 M. Sau phan ng, loc, ra ket tua va nung
nhiet o cao en khoi lng khong oi, c m
gam chat ran. Tnh m.
Cau VI (H: 1,5 iem; C: 2 iem) A, B la hai chat hu
c n chc, mach h, eu cha C, H, O va la
ong phan cua nhau. ot chay hoan toan 0,1 mol
hh (A, B) can va u 6,72 lt kh oxi (ktc). Cac san
pham chay c hap thu het bang cach lan lt
cho i qua bnh (1) ng 100 gam dd H 2SO4 98%, roi
bnh (2) ng 1 lt dd Ba(OH) 2 0,2 M. Sau th nghiem,
thay nong o cua H2SO4 bnh (1) la 94,594% va
bnh (2) thu c 45,60 gam hon hp hai muoi. Xac
nh CTPT, CTCT va goi ten A, B. (Biet A phan ng
c vi Na, con B th khong phan ng) ./.
(Cho: H = 1; C = 12; N = 14; O = 16; F = 19; S = 32; Cl =
35,5; Na = 23; Mg= 24; Al = 27; Ca = 40; Fe = 56; Cu = 64;
Zn = 65; Ag = 108; Ba = 137.
Ghi chu: Th sinh ch thi cao ang khong lam cau V.)
18

989

TS. Nguyen Phi Hung

989
19

TS. Nguyen Phi Hung
E 12
Cau I (H: 1,5 iem; C: 2 iem)
Co hai ion XY32 va XY42 . Tong so proton trong
XY32 va XY42 lan lt la 40 va 48.

1. Xac nh X, Y va cac ion XY32 , XY42 .
2. Viet cac phng trnh phan ng minh hoa tnh chat
2
oxi hoa - kh cua XY3 va XY42 .
3. Bang phan ng hoa hoc, hay chng minh s co
mat cua cac ion XY32 va XY42 trong dung dch
hon hp muoi natri cua chung.
Cau II (H: 1,5 iem; C: 1,5 iem) Can them bao nhieu
lt dung dch NaOH 1,8 M vao 1 lt dung dch H 2SO4 1 M
e thu c cac dung dch mi co:
1. pH = 1
2. pH = 12
Biet rang, trong cac dung dch nc luon co tch
so nong o ion [H+].[OH-]=10-14 (mol/l)2.
Cau III (H: 2 iem; C: 2,5 iem)
1. Hp chat hu c A mach h, co cong thc phan
t C3H6O. T A co s o chuyen hoa:
(A)
H2 d
0
xt, t
(B)
H2SO4
ac 0
170 C
(C)
H2O
H+
(D)
Tm CTCT co the co cua A phu hp vi s o

chuyen hoa tren va viet phng trnh phan ng.
2. Cho glixerin, phenol, xenluloz. Viet phng trnh phan
ng (neu co) cua cac chat tren vi:
a) Dung dch axit vo c loang, un nong.
b) Dung dch HNO3 ac, d (co mat H2SO4 ac, un
nong). Goi ten cac san pham tao thanh.
Cau IV (H: 1 iem; C: 1,5 iem) Cho este X mach h
co cong thc C5H8O2. un X vi dd axit vo c loang,
c hai chat hu c Y va Z. Chat Y tham gia c
phan ng trang gng. Chat Z tac dung c vi
natri va khi tac dung vi hidro (xuc tac Ni, nung
nong) tao thanh ru isobutylic.
20

989

TS. Nguyen Phi Hung
1. Xac nh cong thc cau tao cua X va viet cac

phng trnh phan ng.
2. Viet cac phng trnh phan ng ieu che axit
metacrylic t Z va viet ptp trung hp axit o.
Cau V (H: 2 iem) Hon hp A gom Na2CO3 va BaCO3.
Hoa tan A trong 500 ml dd Ba(HCO3)2 c dd C va
phan khong tan B. Chia dd C thanh hai phan bang
nhau: phan 1 cho tac dung vi lng d dd CaCl 2 c
2 gam ket tua; phan 2 tac dung va het vi 40 ml
dd KOH 0,5 M.
Cho phan khong tan B tac dung vi dd HCl d.
Toan bo kh thoat ra c hap thu het vao 200 ml
dd Ba(OH)2 0,25 M. Sau phan ng, loc tach ket tua,
cho dd con lai tac dung vi dd NaOH d, thu c
1,97 gam ket tua. Tnh khoi lng tng chat trong
hon hp A va tnh nong o mol/lt cua dd Ba(HCO 3)2.
(Biet rang cac phan ng xay ra hoan toan).
Cau VI (H: 2 iem; C: 2,5 iem) Cho m gam este cua
mot axit cacboxylic n chc va mot ru no n
chc phan ng vi mot lng va u dung dch
NaOH un nong, thu c 11,1 gam chat X va p gam
chat Y. Hoa hi toan bo lng chat X thu c roi
dan qua ong ng CuO (d) nung nong, thu c san
pham hu c X1. Cho toan bo X1 tac dung het vi
dung dch amoniac co Ag2O (d) thu c 32,4 gam Ag
kim loai. Gia thiet cac phan ng xay ra hoan
toan.
1. Xac nh cong thc cau tao va goi ten X, biet X
co mach cacbon phan nhanh.
2. Cho Y phan ng vi dung dch H 2SO4 thu c hp
chat hu c Y1. ot chay hoan toan 2,96 gam Y1
roi cho san pham chay lan lc qua bnh (1) cha
lng d H2SO4 ac va bnh (2) cha lng d nc
voi trong th thay khoi lng bnh (1) tang 1,44 gam;
va bnh (2) thu c 18 gam ket tua. Tm cac
cong thc cau tao co the co cua Y 1 biet trong
phan t Y1 co cha vong benzen. Tnh m va p ./.
989
21

TS. Nguyen Phi Hung
Cho:H = 1; C = 12; O = 16; S = 32; Na = 23; Ca = 40; Ag =108;

Ba = 137.
Ghi chu: Th sinh ch thi cao ang khong lam cau V.
E 13
Cau I: 1. Neu nguyen tac chung ieu che kim loai t
cac hp chat cua chung. Cho v du minh hoa.
2. Trnh bay 3 phng phap ieu che Ag kim loai t
muoi AgNO3.
Cau II: 1. Phan biet 4 oxt kim loai sau ( dang ran)
bang phng phap hoa hoc: Na 2O; ZnO; Fe2O3 va CuO.
2. Mo ta hien tng va viet cac phan ng xay ra
khi o t t dung dch FeCl3 vao dung dch Na2CO3.
Cau III: 1. T kh thien nhien va cac chat vo c thch
hp hay trnh bay phng phap ieu che 2 ru 2
chc nang la buten-2-diol-1,4 va buten-3-diol-1,2.
Trong so 2 ru tren, chat nao co ong phan cistrans? Trnh bay cong thc cau tao cua cac ong
phan o.
2. e ieu che cac hp chat hu c co the s
dung nhng nguon nguyen lieu nao san co trong
thien nhien? Trong so o, nguon nguyen lieu nao
ton tai lau dai nhat?
Cau IV: 1. Cho s o chuyen hoa:
C11H21O4N (A)
(B)
NaOH
HCl
C5H7O4NNa2 (B) + C3H8O (C)

C5H10O4NCl (D)
CuO
(C)
C3H6O (E)
C3H6O2 (F)
O2/xt
Cho biet cong thc cau tao cac chat A, B, , F va
viet cac phng trnh phan ng thc hien day
chuyen hoa o, biet rang B la muoi cua mot
chat co ng dung quan trong trong i song.
22

989

TS. Nguyen Phi Hung
2. Tach va thu hoi tng chat t hon hp long gom

ru etylic, phenol, anilin va benzen.
Cau V: Mot mieng Ca co khoi lng m gam. Sau mot
thi gian e ngoai khong kh b bien oi thanh
mot hon hp X gom 4 chat: Ca, CaO, Ca(OH) 2 va
CaCO3 vi tong khoi lng la 2,7 g. e hoa tan
hoan toan hon hp X can dung t nhat 80 ml dung
dch HCl 1M va tao ra 0,55 lt hon hp kh Y (the tch
o 27,3oC va 0,896 atm). Hon hp Y co ty khoi
oi vi hydro la 11,5,
1. Tnh m.
2. Tnh khoi lng tng chat trong hon hp X.
3. em un hon hp X ngoai khong kh en khoi
lng khong oi la a gam. Tnh a.
Cau VI: Cho 4,48 lt hon hp X gom 2 olefin ke tiep nhau
trong mot day ong ang. Chia oi hon hp X: mot
phan em ot chay hoan toan, can 9,408 lt O2;
mot phan cho tac dung hoan toan vi H 2O (co
H2SO4 xuc tac), thu c hon hp Y. Oxi hoa hoan
toan hon hp Y bang CuO thu c hon hp Z. Cho
toan bo lng Z tham gia phan ng trang gng, roi
lay lng Ag tao ra tac dung het vi dung dch HNO 3
loang; tao ra 0,448 lt kh NO duy nhat.
Gia thiet cac phan ng xay ra vi hieu suat
100%, cac the tch kh o ieu kien tieu chuan.
1. Tm cong thc va tnh thanh phan % (ve the tch)
tng kh trong hh X.
2. Tnh % (ve khoi lng) tng chat trong hon hp
Y ./.
E 14
Cau I: 1. Cho day chuyen hoa:
1
Fe
2
FeCl2
3
4
FeCl3
Fe(NO3)3
6
7
Fe(OH)3

989
Fe2O3
23

TS. Nguyen Phi Hung
a) Viet cac phng trnh phan ng thc hien day

chuyen hoa o.
b) Cho biet trong so cac phan ng o, phan ng
nao la phan ng oxi hoa kh; phan ng nao la
phan ng trao oi?
2. Trnh bay phng phap tach rieng tng chat trong
hh ran X gom Fe, Fe2O3, Al.
Cau
II:
Co 2 loai phen ( dang bot):
K2SO4.Al2(SO4)3.24H2O va (NH4)2SO4.Fe2(SO4)3.24H2O
1. Dung phng phap hoa hoc chng minh thanh
phan cua tng loai phen tren.
2. Trnh bay phng phap ieu che Al t phen nhom
va ieu che Fe t phen sat noi tren.
Cau III: 1. Viet cac phng trnh phan ng thc hien s
chuyen hoa:
H-CHO
CH3-CHO
2. Khi ot chay lan lt tng ong ang cua ru
n chc A, thu c t le so mol gia CO 2 va H2O
tang dan theo day ong ang.
a) A thuoc day ong ang nao?
b) T kh thien nhien, hay viet cac phan ng
ieu che 3 ong ang au tien thuoc day o.
Cau IV: Cho day chuyen hoa:
A
+
NaOH
B +
C
CaO, t0
B
+ NaOH
CH4 + D
ot 0,1 mol C can 0,4 mol O 2 va tao ra so mol H 2O
va CO2 bang nhau.
1. Cho biet cong thc cac chat A, B, C va D; biet
rang A, C n chc.
2. Viet cac phan ng (ghi ay u ieu kien) e
chuyen hoa A thanh polimetylacrylat.
Cau V: Nhiet phan hoan toan a gam muoi CaCO 3 tao ra
15 lt kh CO2. Cho toan bo lng CO2 noi tren hap
thu vao 5 lt dung dch Ba(OH) 2 nong o 0,1 M tao ra b
gam ket tua. Them NaOH en d vao dung dch sau
phan ng lai tao them c gam ket tua na.
24

989

TS. Nguyen Phi Hung
1. Tnh a, b va c; biet rang trong ieu kien th nghiem,

khong kh co khoi lng rieng la 1,45 g/l.
2. Phai nhiet phan bao nhieu gam hon hp KMnO 4 va
KClO3 (co xuc tac) vi t le mol 1:1 e thu c
the tch O2 bang the tch CO2 noi tren?
Cau VI: Thuy phan hoan toan m gam este A (mach h,
ch cha mot loai chc) can 40 ml dung dch NaOH
1 M, thu c mot ru B va 3,52 g hon hp muoi
cua 2 axt hu c C va D. ot chay hoan toan mot
lng B thu c CO2 va H2O vi t le khoi lng
gia 2 san pham nay la 44/27. e trung hoa 10 g
axt C can mot lng dung dch NaOH 1M nhieu hn
200 ml.
1. Tm cong thc cau tao co the co cua este A. Tnh
m.
2. Trnh bay phng phap ieu che mot ong phan A
t xenluloz ./.
E 15
Cau I: Cho cac phan ng:
KMnO4
+ HCl
Kh A
+
H2SO4
+ CuS
Kh B
+
FeS
+ HCl
Kh C
+
Cho cac kh A, B, C tac dung vi nhau tng oi
mot trong nc.
1. Hay viet cac phng trnh phan ng noi tren.
2. Cho biet chung thuoc loai phan ng g? Neu ro
ieu kien xay ra cua tng loai phan ng o.
Cau II: Cho 2,16 g kim loai M tac dung vi dung dch
HNO3 loang, d tao ra 0,672 lt kh duy nhat la N 2O
(the tch o ktc).
1. Cho biet ten kim loai M.

989
25

TS. Nguyen Phi Hung
2. Viet phng trnh phan ng cua M khi un nong vi

dung dch HNO3 tao kh N2; va vi dung dch H2SO4 ac
tao kh SO2.
Cau III: 1. Viet cac phng trnh phan ng thc hien s
chuyen hoa t isoamylclorua thanh 2-metylbutanol-2.
Ghi ro ieu kien phan ng va cho biet hng
tng phan ng tuan theo cac quy tac nao?
2. Ch dung mot hoa chat, hay phan biet 4 chat:
CH3OH; C2H5OH, C3H7OH va C6H5OH.
Cau IV: Co 2 este ong phan:
C2H5OOC-COOC2H5
(A)
va
CH3OOC-CH2-CH2COOCH3 (B).
1. Trnh bay phng phap hoa hoc phan biet 2 este
o.
2. Viet cac phan ng thc hien s chuyen hoa t
(A) thanh (B) va ngc lai. Ghi ro ieu kien phan
ng.
Cau V: Nung 4 gam quang olomit (co cha a% tap
chat tr) en phan ng hoan toan tao ra m gam
chat ran va 4,48 lt kh CO2 nhiet o 1092oC va
1atm.
1. Tnh m.
2. Tnh khoi lng tng muoi MgCO3 va CaCO3, cho
biet a = 8.
3. Cho toan bo lng kh CO2 noi tren hap thu hoan
toan vao mot bnh cha 100ml dd Ba(OH)2 nong o
C mol/lt; thu c 3,94 gam ket tua. Tnh C.
4. Tron lan toan bo lng CO 2 thu c tren vi
2,688 lt kh G (the tch G o ktc) thu c hon hp
X co ty khoi oi vi hydro la 16. Cho viet G la kh
nao (Biet G co cha cacbon).
Cau VI: Kh hoan toan 3 gam hon hp A gom 3 hp
chat nitro n chc (bang hydro mi sinh t phan
ng cua Fe va dung dch HCl) thu c 1,8 gam hon
hp B gom 3 amin tng ng.
1. Tnh lng Fe va the tch dung dch HCl 1M toi thieu
can thiet cho phan ng tren, biet rang ch co
50% hydro mi sinh tham gia phan ng.
26

989

TS. Nguyen Phi Hung
2. Tm cong thc tng chat trong hon hp trc va

sau phan ng neu chung la cac hp chat no, ke
tiep nhau trong day ong ang.
3. Chng minh rang khi ot chay hon hp A, lng
CO2 sinh ra t ong ang ln nhat gap 3 lan t
ong ang be nhat ./.
E 16
Cau I: 1. Viet cac phng trnh phan ng co the xay
ra di dang phan t va dang ion:
a) CaCl2 + Na2CO3
b) KOH + BaCl2
c) MgSO4 + NaCl
d) NaHSO4
+
Ba(HCO3)2
e) BaCO3 + CaCl2
g) MgCO3
+
H2SO4
2. Co 2 lo khong dan nhan ng 2 dung dch KOH va
ZnSO4. Hay trnh bay cach phan biet chung ma
khong can dung them hoa chat.
Cau II: 1. Cho s o chuyen hoa:
Fe
+A
FeCl2
+B
FeCl3
+C
Fe(NO3)3
+D
Fe(NO3)2
Cho biet cong thc cac chat A, B, C, D va viet

cac phng trnh phan ng thc hien day chuyen hoa
tren.
2. Co 7 dd sau (cung nong o mol/l): HCl, Ba(OH) 2,
NaOH, NaCl, Na2CO3, NH4Cl, NaHCO3. Hay sap xep chung
theo trat t pH cua dung dch tang dan. Giai thch.
Cau III: 1. Hydro hoa 5 chat mach h A, B, C, D, E eu
thu c ru n-propyric. Cho biet cong thc cau tao
cua 5 chat tren va viet cac phng trnh phan
ng.
2. Trnh bay phng phap phan biet 5 chat tren ng
trong 5 lo khong dan nhan.
Cau IV: 1. Co 3 hp chat hu c no, eu cha C, H, O
va eu co khoi lng phan t 60:
- A va C eu tac dung c vi Na.
- B va C eu co phan ng trang gng.
989
27

TS. Nguyen Phi Hung
Cho biet cong thc cau tao cua A, B, C va viet

cac phng trnh phan ng the hien cac tnh chat
tren.
2. Viet cac phng trnh phan ng thc hien s
chuyen hoa t etyl fomiat thanh metyl axetat (cac
hoa chat vo c va cac ieu kien phan ng co
u).
Cau V: Cho 2,16 gam kim loai A tac dung hoan toan vi
dung dch HCl d thu c 2,688 lt hydro (ktc). Mat
khac cho 3,24 g A tac dung het vi dung dch HNO 3
loang, d (lng dung gap oi lng can thiet), thu
c dung dch B cha 27,96 g muoi va V lt kh NO
duy nhat (ktc).
1. Tm ten kim loai A. Tnh V.
2. Tnh the tch dd NaOH 1M can thiet e khi them
vao dd B e tao ra:
a) lng ket tua nhieu nhat;
b) lng ket tua
t nhat.
Cau VI: Cho mot este A tao thanh t mot axit n chc
va mot ru n chc. Lam bay hi 1,53 gam A
136,5oC; 1atm tao ra 0,504 lt hi. Mat khac em thuy
phan hoan toan 2,04 g A trong dung dch NaOH 1M roi
co can dung dch sau phan ng, thu c hi ru B
va 2,84 g chat ran khan.
1. Xac nh cong thc phan t va cac cong thc
cau tao co the co cua A.
2. un nong ru B vi H 2SO4 tao ra hydrocacbon C. Tnh
ty khoi cua C so vi hi A.
3. Tron lan 1 lt C vi V lt hydro tao ra hon hp D co
ty khoi oi vi hydro la 6. un nong hon hp D co
Ni lam xuc tac cho en khi phan ng hoan toan
tao hon hp E co ty khoi oi vi hydro la d. Tnh
V, d./.
28

989

TS. Nguyen Phi Hung
E 17
Cau I: Vit cc phng trnh phan ng theo dy bin ha sau:
FeCl2
(1)
Fe
(3)
(5)
(4)
(8)
(7)
(2)
FeCl3
Fe(OH)2
(6)
Fe(OH)3
(10)
Fe(NO3)3
Fe2O3
(9)
Cau II: 1. a) Hay anh gia gan ung pH (>7, =7, <7)
cua cac dung dch: Ba(NO3)2, NaOH, Na2CO3, HCl, NH4Cl.
b) Ch dung them quy tm, hay nhan biet moi
dung dch tren cha trong cac lo rieng biet. Viet
cac phng trnh phan ng.
2. Can bang phng trnh phan ng sau bang phng
phap thang bang electron:
Fe304 + HNO3
Fe(NO3)3 + NO + NO2 + H2O
Cho biet hon hp kh NO va NO 2 thu c co ty khoi
so vi hydro la 61/3.
Cau III: 1. T metan viet cac phng trnh phan ng
ieu che anilin, p-clonitrobenzen va m-clonitrobenzen
(cac chat vo c va ieu kien can thiet co u).
2. Bang phng phap hoa hoc hay nhan biet tng
chat: phenol, benzen va axit axetic cha trong cac lo
rieng biet. Viet cac phng trnh phan ng.
Cau IV: 1. Cho s o chuyen hoa di ay, hay xac
nh cong thc cau tao cac chat A, B, C, D, E, F. Viet
cac phan ng thc hien day bien hoa tren. Biet B
la muoi cua mot -aminoaxit co mach cacbon khong
phan nhanh.
C11H21O4N (A)
+ NaOH, to
C5H7O4NNa2 (B)
+ HCl
C5H10O4NCl (D)
C3H8O (C)
+ CuO, to
C3H6O (E)
+O
2,
xt
C3H6O2 (F)
2. Viet cac phan ng chuyen hoa 3-metylbutanol-1

thanh 2-metylbutanol-2.
989
29

TS. Nguyen Phi Hung
Cau V: Cho 9 gam hh A gom FeCO 3 va muoi cacbonat

cua hai kim loai thuoc pnc nhom II tac dung hoan
toan vi 400ml dd HNO3 1M, thu c dd B va 2,24 lt
hh kh C ( 27,3oC va 1,1 atm) gom 2 chat kh la CO 2
va NO, co t khoi oi vi hydro bang 21,3.
1. Xac nh hai kim loai tren, biet chung thuoc 2 chu
ky lien tiep trong bang tuan hoan.
2. Tnh khoi lng tng muoi cacbonat trong A.
3. Cho mot lng bot Cu d vao dd B roi lac hh cho
en phan ng hoan toan. Phan ng tao kh NO duy
nhat. Loc bo phan khong tan sau phan ng, thu
c dd D. Xac nh nong o mol/lt cua tng muoi
trong dd D. (Coi the tch dd khong oi trong qua trnh
phan ng).
Cau VI: ot chay hoan toan 1,52 gam chat hu c X
can 0,56 lt oxi (ktc), thu c hon hp kh gom CO 2,
N2 va hi nc. Sau khi lam ngng tu hi nc, hon
hp kh con lai co khoi lng la 1,6 gam va co t
khoi oi vi hydro la 20.
1. Tm CTPT cua X, biet CTPT cua X trung vi cong
thc n gian nhat cua no.
2. Viet CTCT cua X, biet X la muoi hnh thanh t
phan ng cua mot aminoaxit vi HNO3.
3. Cho 22,8 gam X tac dung het vi 200 ml dd NaOH 2M.
Co can hh sau phan ng, thu c chat ran khan Y
(qua trnh co can khong xay ra phan ng). Tnh
khoi lng tng chat trong Y./.
E 18
Cau I: 1. Trnh bay pp hoa hoc phan biet 2 dd loang
cha NaOH va AlCl3 ma khong dung them hoa
chat khac.
2. Trnh bay pp hoa hoc tach va thu hoi tng chat
t hh gom Al, Fe, Al2O3 va Fe2O3.
Cau II: 1. Viet 3 phan ng trc tiep tao thanh H 2SO4
va 3 phan ng trc tiep tao thanh HCl.
30

989

TS. Nguyen Phi Hung
2. Xac nh cac chat A, B, C, D va viet cac phng

trnh phan ng cho day bien hoa sau:
+ O /to
2
+ O /xt
2
+H O
2
+ Cu
+ Cl +H O
2 2
+ Al
D
B
D
A
C
Cau III: 1. T a voi, than a va cac chat vo c can
thiet, hay trnh bay phng phap ieu che: phenol, anilin,
metylaxetat va n-propylfomiat.
2. Hay phan biet 4 chat hu c noi tren bang
phng phap hoa hoc.
Cau IV: 1. Bang phng phap hoa hoc, hay chng
minh s co mat cua tng chat trong hon hp kh gom
C2H6, C2H4, C2H2, CO2 va SO2.
2. Xac nh cong thc cac chat va viet cac phng
trnh phan ng thc hien day chuyen hoa sau; biet
rang A, B, C, D la cac hydrocacbon; M, N, P, Q, R la
cac chat vo c.
A
to
+ M/xt
+ M/xt
+ N/askt
+P
+Q
+ R/xt
+P
+P
CaO, to
Cau V: Trong mot bnh kn (dung tch khong oi) cha hh

kh A gom N2 va NH3 co t khoi oi vi hydro la
11,25; 0oC; 4 atm. Nung nong bnh mot thi gian cho
NH3 b phan huy mot phan thanh N2 va H2.
1. Chng minh rang thanh phan % (theo the tch) cua
N2 khong thay oi trong suot qua trnh phan ng. Tnh %
o.
2. Sau thi gian t, trong bnh thu c hon hp kh B co
ty khoi oi vi hydro la 9.
a) Tnh ty le % cua NH3 a b phan huy.
b) Tnh thanh phan % (theo the tch) cua hon hp kh
B trong bnh.
c) Tnh ap suat gay ra bi hon hp kh B trong bnh
nhiet o 546oC.
3. Sau thi gian t, thu c hh kh C trong o NH 3 ch
chiem 10% ve the tch. Tnh % NH 3 a b phan huy
sau thi gian t.
989
31

TS. Nguyen Phi Hung
Cau VI: Hh A gom 3 este tao ra t cung mot axit va 3

ru ke tiep nhau trong day ong ang.
1. ot chay het mot lng hh A roi cho san pham
chay hap thu hoan toan vao mot bnh dd cha 0,02 mol
Ca(OH)2 th khoi lng bnh tang them 1,86 g; ay bnh co
1 g ket tua. Loc tach lay dd em un nong lai xuat
hien them toi a la m g ket tua na. Tnh m. Cho biet 3
este trong hh A thuoc loai nao (no, khong no; n chc, a
chc)?
2. em thuy phan hoan toan 2,22 g hh A trong 10 ml
dd NaOH 25% (d=1,2g/ml). Sau khi phan ng ket thuc, co
can dd thu c roi lay toan bo phan hi cho t t
qua bnh (1) cha Na d, sau phan ng khoi lng bnh (1)
tang them 9,85 g. Kh thoat ra khoi bnh (1) cho t t qua
bnh (2) ng CuO d nung nong, sau phan ng ket thuc,
khoi lng bnh (2) giam i 4,24 g.
a) Tnh the tch CO2, khoi lng H2O sinh ra va the tch
O2 can thiet neu ot chay hoan toan hh hi ru
tao ra khi thuy phan hh A noi tren.
b) Tm CTPT va viet CTCT tng este.
c) Chng minh rang neu ot chay hh este ban au th
lng CO2 tao ra t este ong ang ln nhat gap
oi lng CO2 tao ra t ong ang be nhat./.
E 19
Cau I: 1. Trnh bay nguyen tac, nguyen lieu va viet
cac phng trnh phan ng c ban xay ra trong qua
trnh luyen thep.
2. Hoan thanh cac phng trnh phan ng sau:
a) Fe2O3 + CO FexOy ; b) FexOy + H2SO4 loang ; c) FexOy +
HNO3 (tao NO)
Cau II: 1. Ch dung mot loai thuoc th, hay phan
biet 5 dung dch loang cha muoi: NaCl; AlCl 3; FeSO4;
CuSO4; va AgNO3.
2. Cho hon hp A gom cac kim loai Mg, Fe vao dung
dch B gom Cu(NO3)2 va AgNO3, lac eu cho en khi
phan ng xong th thu c hon hp ran C gom 3
32

989

TS. Nguyen Phi Hung
kim loai va dung dch D gom 2 muoi. Xac nh cac

chat co trong C va D. Viet phng trnh phan ng
theo th t xay ra.
Cau III: 1. Dung phan ng hoa hoc chng minh tnh
axit giam dan theo day:
HCl > CH3COOH > H2CO3 > C6H5OH >
C2H5OH
2. T axit axetic va cac chat vo c can thiet, viet
cac phng trnh phan ng e ieu che axit picric
(2,4,6-trinitrophenol) va dietylete.
Cau IV: 1. Xac nh cac chat va viet cac phng trnh
phan ng thc hien day chuyen hoa sau:
CH4
+X
askt
+Y
+Z
to
xt
xt
+T
xt
+Y
+Y
xt, to
CH4
2.Viet cong thc cau tao cua cac peptit tao ra khi
trung ngng ong thi 1 phan t glixin (axit
aminoaxetic) vi 2 phan t alanin (axit
aminopropionic).
Cau V: Cho 9,66 g hon hp A gom bot nhom va mot
loai sat oxit. Nung hon hp A en khi phan ng xong thu
c hon hp B. Chia hon hp B thanh 2 phan bang
nhau:
- Phan 1 cho tac dung va u vi 100 ml dd NaOH, thu
c 0,336 lt H2;
- Phan 2 cho tac dung va u vi 100 g dd HCl, thu
c 1,344 lt H2.
Cac phan ng xay ra hoan toan, cac the tch o
ieu kien tieu chuan.
1. Tm cong thc sat oxit va tnh khoi lng tng
chat trong hon hp A.
2. Tnh nong o mol/lt cua dd NaOH va nong o %
khoi lng chat tan cua dd HCl.
Cau VI: Cho 3,8 g hon hp X gom 2 este no cua cung
mot ru va 2 axit hu c ke tiep nhau trong day ong
ang. Chia hon hp X thanh 2 phan bang nhau:
- Phan 1 cho bay hi 109,2 oC va 1 atm, tao ra 0,6272
lt hi.
989
33

TS. Nguyen Phi Hung
- Phan 2 cho thuy phan hoan toan trong 50 ml dung

dch NaOH 1 M, sau o co can dung dch sau phan
ng, c 2,98 g chat ran.
1. Tm cong thc tng este va tnh khoi lng cua
chung trong hon hp X.
2. em ot chay hoan toan m g hh X roi cho toan bo
san pham chay hap thu vao mot dd cha 0,225
mol Ba(OH)2, tao ra 35,46 g ket tua. Tnh m./.
E 20
Thi gian lam bai: 180 phut
Cau I: 1. Co phan ng: X + H2SO4 ac nong
Fe2(SO4)3
+ SO2 + H2O
X co the la nhng chat nao? Viet cac phng trnh
phan ng o.
2. Ch dung quy tm, trnh bay phng phap nhan
biet cac dung dch: Na2CO3, NaOH, NaCl, HCl, BaCl2.
Cau II: A, B, C la 3 hp chat vo c cua cung mot kim
loai, khi ot chay nhiet o cao eu cho ngon la
mau vang. A tac dung B thu c C. Nung nong B
nhiet o cao c chat ran C, H 2O va kh D (la hp chat
cua cacbon). D tac dung A cho B hoac C.
1. Xac nh A, B, C, D. Viet cac phng trnh phan
ng.
2. Cho A, B, C tac dung dd CaCl 2; C tac dung dd AlCl 3.
Viet cac phng trnh phan ng xay ra (neu co).
Cau III: Viet CT tong quat cua este va phng trnh
phan ng oi vi moi trng hp sau:
a) Este + NaOH 1 muoi + 1 ru; e) Este + NaOH
1
muoi + 1 xeton;
b) Este + NaOH 1 muoi + 2 ru; f) Este + NaOH 1 muoi
+ 1 ru + nc;
c) Este + NaOH
2 muoi + 1 ru; g) Este + NaOH
2
muoi + nc;
d) Este + NaOH
1 muoi + 1 andehit; h) Este + NaOH
1
muoi duy nhat.
Cau IV: Co 6 hp chat hu c A, B, C, D, E, F eu no,
mach h, cha cac nguyen to C, H, O va eu co KLPT
34

989

TS. Nguyen Phi Hung
bang 74 vC. Cho 6 chat o tac dung vi Na, vi dd

NaOH va vi dd AgNO3 trong NH3 (phan ng trang gng)
thu c ket qua nh sau:
A
B
C
D
E
F
Na
+
+
+
+
NaOH
+
+
+
Phan ng trang
+
+
gng
Dau (+) la co phan ng; dau (-) la khong
co phan ng.
Hay xac nh cac cong thc cau tao co the co
cua A, B, C, D, E, F va goi ten (theo IUPAC).
Cau V: Cho hh A gom Al, Fe va Ba. Chia hh A thanh 3
phan bang nhau:
- Phan 1 cho tac dung vi H2O d, thu c 0,896 lt H2;
- Phan 2 cho tac dung vi dd NaOH d, thu c 1,568
lt H2;
- Phan 3 cho tac dung vi dd HCl 1M d (dung gap
oi lng can thiet), thu c dd B va 2,016 lt H 2.
Cac phan ng xay ra hoan toan, cac the tch o
ieu kien tieu chuan.
1. Tnh khoi lng m va % khoi lng cua hon hp A.
2. Tnh nong o mol/lt tng chat trong dd B.
3. Tnh the tch dd NaOH 1M can thiet them vao dd B
e:
a) Tao lng ket tua ln nhat;
b) Tao lng ket
tua be nhat.
Cau VI: ot chay hoan toan 1,6 g hp chat hu c A
(cha C, H, O). Dan toan bo san pham chay vao bnh
ng dd Ba(OH)2 d, thay khoi lng bnh tang them 4,16
g va co 13,79 g ket tua. Biet rang M A < 200 vC.
1. Xac nh cong thc phan t cua A.
2. Biet rang A ch cha mot loai nhom chc, khi cho
16 g A tac dung va u vi 200 g dd NaOH 4% th thu
c mot ru B va 17,8 g hh 2 muoi. Xac nh CTCT
cua A./.

989
35

TS. Nguyen Phi Hung
AP SO: e 1: Cau 1. 0,025 M; pH = 1,6; Cau 5. 10,35 g;

Cau 6. 2. m1 = 67,5 g; m2 = 30 g; V = 18,9 lt; Cau 7. 1. (C3H4O)n;
2. C6H8O2 (2 CTCT); Cau 8. C3H5(COOH)2NH2 (2 CTCT). e 2: Cau
3. (3 CTCT); Cau 4. A: C3H5(COOH)3; B: C2H2(OH)2(COOH)2; Cau 5.
M: Na; R: Al; m = 1,62 g; Cau 6. Ag2SO4: 0,036 M; CuSO4: 0,054 M;
Cau 7. 1. C2H7O2N; 2. 1 M; 1,175 M; Cau 8. 1. OH, COOH; 2.
HOCH2CH2COOH. e 3: Cau 4. X: CH3NH2; Cau 5. 1. Fe: 19,44 %;
FexOy: 80,56%; Fe3O4; Cau 6. 1. pH = 13,477; 2. x = 0,6 M hoac 0,2
M; Cau 7. 1. C2H5OH; C3H7OH; 2. C2H5OH: 43,40%; C3H7OH: 56,60%;
Cau 8. C6H10O2; CH2=CHCOOCH2CH2CH3. e 4: Cau 2. 1. 0,05 M;
thu nhiet; Cau 5. 2. pH = 2,85; = 1,414%; Cau 6. 1. H2SO4: 0,4
M; B: 110,5 g; B1: 88,5 g; 2. R: Ba; MgCO3: 16,8 g; BaCO3: 98,5 g; Cau
7. 1. m = 20,8; 2. Cap 1: HCOOH, C2H5COOH; Cap 2: CH3COOH,
C3H7COOH; 3. 14,51%; Cau 8. 1. A: C3H7O2N: H2NCOOCH3; X:
C2H5O2N: H2NCOOH. e 5: Cau 2. 1. Zn, Fe, Cu; 2. Zn; 3. Co;
Cau 4. A1: HCOOC2H5; Cau 5. p = (25/1,1)(1 h/300); 15,15 p
22,73 (atm); Cau 6. catot: 0,64 g Cu; 1,18 g Ni; 0,04 g H 2; anot:
3,55 g Cl2; CM K2SO4: 0,05 M; KOH: 0,2 M; Cau 7. 1. X: C2H6O (2
CTCT); C3H2O (1 CTCT); C3H4O2 (2 CTCT); 2. CH3CH2OH; Cau 8.
HCOOCH=CHCH3;
HCOOC6H5.
e
6:
Cau
4.
1.
A:
CH3CH2COOCH=CH2; B: CH2=CHCOOCH2CH3; Cau 5. 1. Al(NO3)3: 2,13
g; BaCl2: 2,08 g; K2CO3: 1.47 g; Ag2SO4: 12,48 g; Cau 6. 1. Cu; 2.
MgO: 12,35%; Al2O3: 62,96%; CuO: 24,69%; Cau 7. 1. CnH2n+2-z(OH)z;
A: C3H5(OH)3; B: C5H9(OH)3; Cau 8. C4H8O2 (HCOOC3H7). e 7: Cau
2. 252 g CaO; Cau 3. 5,8 g < mCaCO3 < 9 g; Cau 4. 13,527 g; HNO3:
1 M; Cau 5. 2. 66,67%; Cau 7. C4H6O (2 CTCT); Cau 8. A:
(C2H5COO)2C2H4. e 8: Cau 2. Fe3O4; Cau 3. 1. V = 100V; 2. a)
11,1 g; b) 29,6 g; Cau 4. Mg: 13,04%; Fe: 86,96%; AgNO 3: 0,6 M;
Cau 6. (CH3COO)-(CH3NH3)+; Cau 7. C3H4O2 (1 CTCT); C6H8O4 (2
CTCT); Cau 8. 1. C2H5OH; 2. A: C2H3COOC2H5 (1 CTCT); B:
C3H5COOC2H5 (3 CTCT); 3. A: 30,49%; B: 69,51%. e 9: Cau 3.
BaSO4: 2,33 g; BaHPO4: 0,932 g; Ba(H2PO4)2: 2,648 g; Cau 4. 2.
Fe2O3; A: 35,42% Al; 64,58% Fe 2O3; B: 41,17% Al2O3; 45,20% Fe;
13,63% Al; Cau 5. 1. A: C2H5OOC(-CH2-)4COOCH(CH3)2; B: HOOC(CH2-)4COOH; Cau 7. 1. A: C2H5OH; B: C2H4(OH)2; Cau 8. 1. A:
HOCH2CH2CH2OH; 2. X: CH3OOCCH2CH2CH2OOCCH3; 3. 80%. e 10:
Cau 3. 1. m = 8,2 g; X: 37,80% Na 2O; 62,2O% Al2O3; 2. a = 7,8 g; V
= 2,24 lt CO2; Cau 4. 1. M: 35,59% Fe; 30,51% FeO; 33,90% Fe 2O3;
2. 67, 96 ml dd HCl; 3. 67,65 g; Cau 7. 1. C5H10O3N2; 2. (2 CTCT);
Cau 8. C2H3COOCH3: 8,6 g; C2H3COOC2H5: 5 g. e 11: Cau I. 2.
1,435 g AgCl; Cau II. 1. 23,029 lt dd HNO3; 2. b) pH = 2; Cau III.
2. 29,44 g toluen; Cau V. 1. R: Al; X: 50,91% Fe; 49,09% Al; 2. m =
36
989

TS. Nguyen Phi Hung
6,84 g; Cau VI. A: CH2=CHCOOH; B: HCOOCH=CH2. e 12: Cau I.

1. X: S; Y: O; SO32-; SO42-; Cau II. 1. 1 lt; 2. 1,123 lt; Cau IV. 1. X:
HCOOCH2C(CH3)=CH2; Cau V. A: 6,36 g Na2CO3; 7,88 g BaCO3; CM:
0,04 M Ba(HCO3)2; Cau VI. 1. X: (CH3)2CHCH2OH; 2. Y1: C8H7COOH (5
CTCT); m = 30,6 g; p = 25,5 g. e 13: Cau IV. 1. A:
CH3CH2CH2OOCCH2CH2CH(NH2)COOCH2CH2CH3; Cau V. 1. m =1,6 g;
2. hh X: 0,4 g Ca; 0,56 g CaO; 0,74 g Ca(OH) 2; 1 g CaCO3; 3. a = 2,24
g; Cau VI. 1. hh X: 20% C2H4; 80% C2H4 (V); 2. hhY: 16,08% C2H5OH;
73,47% CH3CH(OH)CH3; 10,49% CH3CH2CH2OH (k/l). e 14: Cau III.
1. Ru no n chc; Cau IV. 1. C: C3H6O (2 CTCT); A: CH3COOC3H5
(2 CTCT); Cau V. 1. a = 75 g; b = c = 49,25 g; 2. 105,19 g; Cau VI.
1. A: HCOOCH2CH2OOCC3H5 (3 CTCT); m = 3,16 g. e 15: Cau II. 1.
Al; CauV. 1. m = 2,24 g; 2. MgCO3: 1,68 g; CaCO3: 2 g; 3. C = 0,3 M;
4. G: CO, C2H4; Cau VI. 1. mFe = 13,44 g; Vdd HCl = 0,48 lt; 2. A:
CH3NO2; C2H5NO2; C3H7NO2; B: CH3NH2; C2H5NH2; C3H7NH2. e 16:
Cau V. 1. Al; V = 0,896 lt; 2. a) 0,85 lt; b) 0,46 hoac 0,97 lt; Cau
VI. 1. A: CH3COOC3H7 (2 CTCT); 2. dC/A = 0,41; 3. V = 3 lt, d = 8. e
17: Cau V. 1. Mg, Ca; 2. A: 3,48 g FeCO3; 2,52 g MgCO3; 3 g CaCO3;
3. CM(ddD): Mg(NO3)2 0,075 M; Ca(NO3)2 0,075 M; Fe(NO3)2 0,075 M;
Cu(NO3)2 0,2 M; Cau VI. 1. C3H8O5N2; 2. CH3CH(NH3+NO3-)(COOH); 3.
CH3CH(NH2)(COONa): 16,65 g; NaNO3: 12,75 g; NaOH: 4 g. e 18:
Cau V. 1. %(V)N2 = 50% = const; 2. a) %(V)NH3p = 50%; b) %(V)B:
20% NH3; 50% N2; 30 % H2; c) PB = 15 atm; 3. %(V)NH3p = 10%; Cau
VI. 1. m = 1 g; 3 este no, n chc; 2. a) 1,344 lt CO2; 1,62 g H2O;
2,016 lt O2; b) HCOOH; HCOOC2H5; HCOOC3H7 (2 CTCT). e 19: Cau
V. 1. Fe3O4; A: 2,7 g Al; 6,96 g Fe 3O4; 2. CM(dd NaOH) = 0,5 M; C%(dd HCl) =
8,76%; Cau VI. 1. CH3COOC2H5: 1,76 g; C2H5COOC2H5: 2,04 g; 2. m =
3,8 g hoac 5,7 g. e 20: Cau V. 1. m = 10,71 g; A: 30,25% Al;
31,37% Fe; 38,38% Ba; 2. dd B: BaCl2 0,028 M; AlCl3 0,111 M; FeCl2
0,056 M; HCl 0,5 M; 3. a) 340 ml; b) 380 ml; Cau VI. 1. C7H12O4; 2.
(CH3COO)(C2H5COO)C2H4 hoac (HCOO)(C3H7COO)C2H4.
Chuc cac em thanh cong trong ky thi

ai hoc !

989
37

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20 e Luyen thi ai hoc Mon Hoa

TS. Nguyen Phi Hung

Trung tam Luyen thi ai hoc Alpha

20 e Luyen thi ai hoc Mon Hoa

1. Tm cong thc n gian cua X.

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nc thanh dung dch B va 1,344 lt kh (ktc). Chia

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Cau 3 : T metan va cac chat vo c can thiet, hay

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Cau 8 : ot chay hoan toan 2,28 g chat hu c X can

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c) Tac dung cua cac tam kem gan vao vo

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2. Viet phng trnh phan ng trung ngng X thanh

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sau khi ta ien phan 200 ml dd hon hp NiCl 2, CuSO4,

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Cau 3 : Viet CTCT cua tat ca cac ong phan mach

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1. Hay tm cong thc chung cua cac ru A, B.

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Cau 8 : Cho 17,4 g mot hp chat hu c A ch

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Cau 6 : Mot chat hu c A co cong thc C 3H9O2N. Cho A

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Cau 4 : Cho hon hp A gom bot Al va mot oxit cua sat

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NaOH thu c 16,4 g muoi. Xac nh CTCT cua

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3. Cho dd D tac dung vi lng d dd AgNO 3. Tnh

D (mot loai ng) + H2O

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Viet cac phng trnh phan ng (ghi ro ieu kien) e

Cau V (H: 2,5 iem) Hon hp X gom Fe va mot kim

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XY32 va XY42 lan lt la 40 va 48.

Tm CTCT co the co cua A phu hp vi s o

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1. Xac nh cong thc cau tao cua X va viet cac

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Cho:H = 1; C = 12; O = 16; S = 32; Na = 23; Ca = 40; Ag =108;

C5H7O4NNa2 (B) + C3H8O (C)

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20 e Luyen thi ai hoc Mon Hoa

2. Tach va thu hoi tng chat t hon hp long gom

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