S GIO DC-O TO K THI CHN HC SINH GII TNH CP THPT

H TNH NM HC 2012-2013
MN THI: HO HC LP 11
Thi gian lm bi: 180 pht
E CHINH THUC ( thi c 02 trang, gm 6 cu)
Cu I:
Nguyn t ca nguyn t R trng thi c bn c tng s electron cc phn lp s l! "#
a# $i%t c&u h'nh electron nguyn t ca R trng thi c bn( )c *+nh tn nguyn t R#
b# $i R c phn lp ,- *. b.o ho!( ho! tan ho!n to!n / ga/ /0t o)it ca R trong -ung -+ch 1
2
34
5
*6c( nng( -7 sinh ra 8(9: l;t <*i=u >i?n tiu chu@nA >h; 34
2
l! sn ph@/ >h -uy nh&t# Bo!n b0 l7Cng
>h; 34
2
trn phn Dng EFa * Ei 2 l;t -ung -+ch GHn4
5
thu *7Cc -ung -+ch B <coi thI t;ch -ung
-+ch >hJng thay *iA#
K $i%t cc ph7ng tr'nh ho hLc( t;nh / E! t;nh nMng *0 /olNl ca -ung -+ch GHn4
5
*. -Ong#
K B;nh p1 ca -ung -+ch B <bP Qua sR thy phn ca cc /uiA#
Si%t a)it 1
2
34
5
c G
aT
UVWX G
a2
U T8
K2
#
Cu II:
T# Bh/ T/l -ung -+ch HgYl
2
TH E!o T88 /l -ung -+ch N1
,
TH E! N1
5
Yl TH *7Cc T88 /l -ung
-+ch Z( hPi c >%t ta Hg<41A
2
*7Cc to th!nh hay >hJng[
Si%t\
2
Mg(OH)
T
UT8
KT8(]9
E!
,
b<N1 A
K
U T8
K5("9
#
2# B;nh p1 ca -ung -+ch thu *7Cc >hi tr0n l^n cc -ung -+ch sau\
a# T8/l -ung -+ch Y1
,
Y441 8(T8H Ei T8/l -ung -+ch 1Yl c p1 U 5(88
b# 29/l -ung -+ch Y1
,
Y441 c p1 U ,(88 Ei T9/l -ung -+ch G41 c p1 U TT(88
c# T8/l -ung -+ch Y1
,
Y441 c p1 U ,(88 Ei T8/l -ung -+ch a)it _o/ic <1Y441A c p1U,(88#
Si%t Ga ca Y1
,
Y441 E! 1Y441 l`n l7Ct l! T8
K5(":
E! T8
K,("9
<Ghi t;nh l&y ti cha s thD 2 sau -&u
ph@y >%t Qu cui cOngA#
Cu III:
T# Yho 2(T: ga/ hbn hCp gM/ Zl E! Hg tan h%t trong -ung -+ch a)it 1N4
,
lo.ng( *un nng nhc to
ra -ung -+ch Z E! 55d /l <*o ,95(] G E! ]dd //1gA hbn hCp >h; S gM/ 2 >h; >hJng /!u( >hJng
*i /!u trong >hJng >h;# Be >hi ca S so Ei o)i bfng 8("T: l`n te >hi ca Y4
2
so Ei nit# g!/
>han Z /0t cch c@n thhn thu *7Cc ch&t rin j( nung j *%n >hi l7Cng >hJng *i thu *7Cc ,(d5 ga/
ch&t rin k# B;nh >hi l7Cng j E! th!nh ph`n ph`n trl/ >hi l7Cng /bi >i/ loi trong hbn hCp ban
*`u#
2# Yho 28 ga/ hbn hCp Z gM/ meY4
,
( me( Yu( Zl phn Dng Ei :8 /l -ung -+ch Na41 2H *7Cc
2(:dd l;t hi*ro# Bh/ ti%p E!o b'nh sau phn Dng "58 /l -ung -+ch 1Yl TH E! *un nng *%n >hi
ngFng thot >h;( *7Cc hbn hCp >h; S( lLc tch *7Cc c6n Y <>hJng chDa hCp ch&t ca ZlA# Yho S h&p
thn tF tF E!o -ung -+ch n7c EJi trong -7 *7Cc T8 ga/ >%t ta# Yho Y phn Dng h%t Ei 1N4
,
*6c
nng -7 thu *7Cc -ung -+ch j E! T(T2 l;t /0t >h; -uy nh&t# Yho j phn Dng Ei -ung -+ch Na41 -7
*7Cc >%t ta k# Nung k *%n >hi l7Cng >hJng *i *7Cc / ga/ ch&t rin# B;nh >hi l7Cng /bi ch&t
trong Z( t;nh /( bi%t thI t;ch cc >h; *o *i=u >i?n tiu chu@n#
Cu IV:
ot chy ho!n to!n 8(85" /ol hbn hCp p gM/ , hi*rocacbon /ch h rMi cho to!n b0 sn ph@/ chy
h&p thn E!o 2 l;t -ung -+ch Ya<41A
2
8(8999H *7Cc >%t ta E! -ung -+ch H# g7Cng -ung -+ch H
n6ng hn -ung -+ch Ya<41A
2
ban *`u l! ,(T8d ga/# Yho -ung -+ch Sa<41A
2
-7 E!o -ung -+ch H
th&y c >%t ta l`n 2 )u&t hi?n# Bng >hi l7Cng >%t ta hai l`n l! 28(]9 ga/# YOng l7Cng hbn hCp p
trn tc -nng EFa * Ei T l;t -ung -+ch Sr
2
8(8]H# pc *+nh cJng thDc phn t( cJng thDc c&u to
ca cc hi*rocacbon bi%t c 2 ch&t c cOng s nguyn t cacbon( phn t >hi cc ch&t trong p *=u
bq hn T88 E! l7Cng hbn hCp trn tc -nng EFa * Ei T88/l -ung -+ch ZgN4
,
8(2H trong N1
,
*7Cc ,(Td ga/ T >%t ta#
T
Cu V:
T# 1Cp ch&t p c cJng thDc phn t Y
:
1
T8
tc -nng Ei hi*ro theo te l? /ol T\ T >hi c ch&t )rc tc#
Yho p tc -nng Ei -ung -+ch GHn4
5
trong 1
2
34
5
lo.ng( *un nng thu *7Cc 144Y<Y1
2
A
5
Y441#
a# pc *+nh cJng thDc c&u to( gLi tn p E! Ei%t ph7ng tr'nh phn Dng
b# $i%t ph7ng tr'nh phn Dng o)i ho p bfng -ung -+ch GHn4
5
trong n7c
2# ot chy ho!n to!n 8(82 /ol hbn hCp p gM/ , hi*rocacbon *Mng phn Z( S( Y# 1&p thn to!n b0
sn ph@/ chy E!o 9("9 l;t -ung -+ch Ya<41A
2
8(82H thu *7Cc >%t ta E! >hi l7Cng -ung -+ch tlng
ln 9(8d ga/# Yho Sa<41A
2
-7 E!o -ung -+ch thu *7Cc( >%t ta li tlng th/( tng >hi l7Cng >%t ta
2 l`n l! 25(,89 ga/#
a# pc *+nh cJng thDc phn t ca , hi*rocacbon
b# pc *+nh cJng thDc c&u to Z( S( Y bi%t\
K Y , ch&t *=u >hJng l!/ /&t /!u -ung -+ch bro/#
K Ghi *un nng Ei -ung -+ch GHn4
5
lo.ng trong 1
2
34
5
th' Z E! S *=u cho cOng sn ph@/ Y
]
1
:
4
:
csn Y cho sn ph@/ Y
d
1
:
4
5
#
K Ghi *un nng Ei bro/ c /6t b0t sit Z che cho /0t sn ph@/ /onobro/# Ysn ch&t S( Y /bi ch&t
cho 2 sn ph@/ /onobro/
$i%t ph7ng tr'nh ha hLc ca cc phn Dng )y ra
Cu VI:
T# Gh; N
2
4
5
>q/ b=n( b+ phn ly /0t ph`n theo ph7ng tr'nh\
N
2
4
5 <>h;A
2N4
2 <>h;A
<TA
BhRc nghi?/ cho bi%t cc s li?u sau >hi <TA *t ti trng thi cn bfng p su&t chung T at/\
Nhi?t *0 <8
o
YA ,9 59
h
M <gA
"2(598 ::(d88
<
h
M l! >hi l7Cng /ol trung b'nh ca hbn hCp >h; trng thi cn bfngA
a# B;nh *0 phn ly ca N
2
4
5
cc nhi?t *0 *. cho#
b# B;nh hfng s cn bfng G
p
ca <TA /bi nhi?t *0 trn#
c# Yho bi%t <TA l! phn Dng thu nhi?t hay tPa nhi?t# tii th;ch[
<Ghi t;nh l&y ti cha s thD , sau -&u ph@yA#
2# Y cc phn t p1
,
a# 1.y cho bi%t -ng h'nh hLc ca cc phn t u1
,
E! Zs1
,
#
b# 3o snh gc lin >%t 1p1 giaa hai phn t trn E! gii th;ch#
c# Nhang phn t n!o sau *y c phn t phn cRc [ tii th;ch ngin gLn
Sm
,
( N1
,
( 34
,
( um
,
#
Yho bi%t v
u
U T9( v
Zs
U ,,( v
4
U d( v
m
U ]( v
S
U 9( v
N
U "( v
3
U T:#
------------------ HET-----------------
- Th sinh khng c s! "#ng t$i %i&u (k' c( )(ng *& th+ng tu,n h-$n c.c ngu/0n t+ h-. h1c)2
- 3.n )4 c-i thi khng 5h(i gi(i thch g6 th0m#
- *1 7$ t0n th sinh8 2222222222222222222222222222222222222222222222222222222222222222229+ ).- "anh222222222222222222222222222222
2
HUNG DAN CHM
Cu 0,75+1,75(1+0,75)
I
2,5
aA Brong Eow nguyn t7w cuwa nguyn tJx R electron phn bJx Eayo caxc phn lxp s theo th7x t7z lay\ Ts
2
X
2s
2
X ,s
2
X 5s
T
U{ Yaxc cxu hiynh electron thowa /a|n lay
Ts
2
2s
2
2p
:
,s
2
,p
:
5s
T
U{ v U T] R lay Gali
Ts
2
2s
2
2p
:
,s
2
,p
:
,-
9
5s
T
U{ v U 25 R lay Yro/
Ts
2
2s
2
2p
:
,s
2
,p
:
,-
T8
5s
T
U{ v U 2] R lay *Jyng
bA $iy o)it cuwa Yu taxc -uzng Exi -ung -izch a)it sun_uric *lzc noxng tazo ra >hix 34
2
-o *ox lay *Jyng
<}A o)it <Yu
2
4A
A < 829 ( 8
2
m-% n
9:

Yu
2
4 V 21
2
34
5
-
t
2Yu34
5
V 34
2
V 21
2
4
8(829 8(829 </olA
U{ /UT55#8(829U,(: <gA
934
2
V 2GHn4
5
V 21
2
4 21
2
34
5
V G
2
34
5
V 2Hn34
5

8(829 8(8T 8(8T </olA
NJyng *Jz /olNl cuwa -ung -izch GHn4
5
lay 8(889 <HA
uh7ng triynh *izn li cuwa a)it sun_uric\ <~1
2
34
5
U8(889HA
1
2
34
5

1
V
V 134
5
K

8(889 8(889 8(889<HA
134
5
K
1
V
V 34
5
2K

Y \8(889 8(889 8 <HA
~ \ 8(889 K ) 8(889V) ) <HA
U{
2
T8
889 ( 8
A# 889 ( 8 <

+
;
; ;
U{

8T ( 8
T8 # dT ( 2
,
;
;

U{ ~1
V
U8(889V2(dT#T8
K,
U"(dT#T8
K,
<HA U{ p1U 2(T8"
0,75
0,5
0,5
0,75
II 1+3(1+1+1)
1. Ghi th/ T/l -ung -+ch HgYl
2
TH E!o T88/l -ung -+ch *?/ th'
+ 2
Mg
C
ban *`u
U T8
K2
<HA#
Ba c\
2
Mg(OH)
T
U ~Hg
2V
~41

2
U T8
KT8(]9
oI >%t ta Hg<41A
2
th' ~Hg
2V
~41

2
T8
KT8(]9
~41

2

[ ]
2
T8

10,95
2
10,95
10
Mg
10
U T8
Kd(]9
# 1ay ~41

T8
K5(5"9
jung -+ch\ N1
5
Yl TH V N1
,
TH#
cn bfng ch y%u l!\
N1
,
V 1
2
4
+
4
NH V 41

3
NH
K
U G
b
U T8
K5("9
T T
TK) TV) )
G
b
U
( )
x 1
x 1 x

+
U T8
K5("9
) U T8
K5("9
1ay ~41

U T8
K5("9

T8
K5(5"9
#
$hy >hi th/ T /l -ung -+ch HgYl
2
TH E!o T88/l -ung -+ch N1
,
TH E! N1
5
Yl TH th'
>hJng )u&t hi?n >%t ta Hg<41A
2
#
0,5
0,5
2.
a. Dung d|ch HCl c pH 4,0 H
+
] HCl] 10
-4
M
3au >hi tr0n\
,
5
9
1Yl
Y1 Y441
T8 #T8
Y 9#T8 H
28
8(T#T8
Y 8( 89H
28

1Yl 1
V
V Yl
K

9#T8
K9
H 9#T8
K9
H
,
Y1
,
Y441

Y1
,
Y44
K
V 1
V

Y 8(89H 8 9#T8
K9
H
Y ) ) )
~ 8(89K) ) 9#T8
K9
V )
( )
9
5(":
9#T8 ) )
T8
8( 89 )

) U d(]]T#T8
K5
H <nhhnA
) U K](::5#T8
K5
H<loiA
p1 U Klg~1
V
U Klg<9#T8
K9
V )A U ,(82,U,(82
b. Gi C
A
l nng d M cua dung d|ch CH
3
COOH
, ,
Y1 Y441 Y1 Y44 1
+
+
Y Y
Z
8 8
Y ) ) )
~ Y
Z
) ) )
$i p1 U ,(8 ) U T8
K,
H
( )
,
2
,
5(":
,
Z
:
, T(25 T8
Z
5(":
T8
T8
Y T8
T8
Y T8 T8 8( 89d9H
T8

+
jung -+ch G41 c p1 U TT(8 ~41
K
U ~G41 U
T5
,
TT
T8
T8 H
T8

3au >hi tr0n\
,
2
Y1 Y441
,
5
G41
, , 2
8( 89d9)29
Y 8( 8,:9:H ,( ::#T8 H
58
T8 )T9
Y ,( "9#T8 H
58
Y1 Y441 G41 Y1 Y44G 1 4

+ +
uhn Dng ,(::#T8
K2
,("9#T8
K5
8 8
3au phn Dng <,(::#T8
K2
,("9#T8
K5
A8 ,("9#T8
K5
,("9#T8
K5

Nn G
a
U )<)V,("9#T8
K5
AN<8(8,:229K)AUT8
K5(":
) U :(2TT#T8
K5
p1 U ,(28"U,(2T
c. Tuong t vi cu trn:
K jung -+ch Y1
,
Y441 c p1 U ,(8 Dng Ei
,
Y1 Y441
Y 8( 89d9H
K jung -+ch 1Y441 c p1 U ,(8 Dng Ei nMng *0 a)it _o/ic
( )
2
p1
:
p1 , 2(29 , ,
1Y441
,("9
1Y441
T8
T8
Y T8 T8 T8 T8 :( :2#T8 H
G T8

+ + +
3au >hi tr0n l^n\
,
Y1 Y441
,
,
1Y441
8( 89d9#T8
Y 8( 82]29H
28
:( :2#T8 #T8
Y ,( ,T#T8 H
28

So to!n *i?n t;ch \ ~1
V
U~Y1
,
Y44
K
V~1Y44
K

1
1
1
5
, ,
Y1 Y441 Y1 Y44 1
+
+
Y
Y
~
8(8,:229 ,("9#T8
K5
8
) ) )
8(8,:229 ) )V,("9#T8
K5
)
Ba c\ hU Y
T
G
aT
N<G
aT
VhAV Y
2
G
a2
N<G
a2
VhA
h
,
Vh
2
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aT
VG
a2
AVh<G
aT
G
a2
Y
T
G
aT
KY
2
G
a2
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T
G
aT
G
a2
VY
2
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a2
AU8
Ba c hU ](]]"#T8
K5
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III 1,5+2
1. Bheo gi thi%t th' S chDa N
2
E! N
2
4
Ba c
2 2 2
2 2 2
8( 55d#<]dd N ":8A N <8( 8d2#,95( ]A 8( 82 8( 8T
#55 #2d 8( 82#,2#8( "T:#55 N 2d 8( 8T
< : < < :
< : < <
n n n
n n n

+

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+


s mol e nhn d to ra 2 kh ny l : 0,01(10+8) 0,18 mol (I)
j c Zl<N4
,
A
,
( Hg<N4
,
A
2
c thI c N1
5
N4
,
#
N1
5
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N
2
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V tLi )( y l`n l7Ct l! s /ol ca Zl E! Hg ta c h? \
2" 25 2(T:
T82# 58 ,(d5
2
; /
;
/
+

'
+

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V BF <}( }}A suy ra phi c N1
5
N4
,
# BF * - -!ng t;nh *7Cc >%t Qu sau\
j gM/\ Zl<N4
,
A
,
<d(92 ga/A X Hg<N4
,
A
2
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5
N4
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hCp ban *`u c 98 l7Cng /bi >i/ loi#
0,25
0,5
0,75
2. V Ghi Z p7 Ei Na41 th' n
Na41
U 8(T2 /olXn
12
U 8(T2 /ol# 3uy ra Na41 -7
Zl V Na41 V 1
2
4 NaZl4
2
V ,N2 1
2
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2
#
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Na41 V 1Yl NaYl V 1
2
4
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2
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2
4
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2
V 1
2
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chin c Yu( c thI c meY4
,
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N4
2
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thI chDa meY4
,
Y c Yu E! c thI c me <meY4
,
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TH1: Fe du. tLi ) l! s /ol meY4
,
X y l! s /ol me b+ hsa tanX l! s /ol me -7( t l! s /ol
Yu ta c\ 116x + 56(y + z) + 64t 20 - 0,08.27 17,84 (I)
meY4
,
V 21Yl meYl
2
V Y4
2
V 1
2
4
Hol\ ) 2) ) )
me V 21Yl meYl
2
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2

Hol\ y 2y y y
3 /ol 1Yl U 2x + 2y 0,38 (II)
S c ) /ol Y4
2
V y /ol hi*ro# jRa E!o p7 ca S Ei n7c EJi trong x 0,1 mol (III)
Y c /ol me -7 V t /ol Yu 3z + 2t 1,12/22,4 (IV)
) U 8(T /olX y U 8(8] /olX U 8(8T /ol E! t U 8(8T /ol#
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,
V 8(T#9:U9(: ga/ me V 8(8T#:5U:(5 ga/ Yu V
8(8d#2"U2(T:ga/ Zl
V B;nh ti%p ta *7Cc gi tr+ ca /U/
Yu4
V/
me24,
U8(8T#d8V8(8T#T:8N2 U T(: ga/#
TH2: Fe ht Y che c Yu s /olYu U N4
2
U 8(829 /ol#
Z c 8(T#TT:UTT(: ga/ meY4
,
V 8(829#:5UT(: ga/ Yu V 8(8d#2"U2(T:ga/ ZlV <28KTT(:K
T(:K2(T:U5(:5Aga/ me
t;nh *7Cc / U/
Yu4
U8(829#d8U 2 ga/#
0,5
0,75
0,75
9
IV 2,5
Y
)
1
y
V / ZgN4
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V / N1
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Y
)
1
yK/
Zg
/
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N4
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#
8(82 /ol 8(82N/ /ol
/

U ,(Td U <8(82N/A<T2)VyVT8"/A T2)V y U 92/

jo H
1jY
T88 nn /UT( )U5( yU5#
$hy T ch&t Y
5
1
5
\ Y1
2
UY1KYY1\ 8(82 /ol
Ba c s *M
Y4
2
V Ya<41A
2
<8(TTT/olA
YaY4 <)A
,
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