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HI DNG
CHNH THC
polivinylanc
ol
Cao su
Buna
Xc nh cc cht A, B, C, D, E, F, G v vit cc phng trnh phn ng (ghi r
iu kin nu c).
Cu III (2 im)
1. Cho hn hp X gm FeCO3, FeS2 tc dng va vi dung dch HNO 3 c, nng thu
c dung dch Y (cha Fe(NO3)3; H2SO4) v 22,4 lt hn hp kh Z gm hai kh (ktc).
Pha long dung dch Y bng nc ct thu c 2 lt dung dch c pH = 1.
a. Vit phng trnh phn ng v tnh khi lng hn hp X.
1
G
H v tn th sinh:S bo danh:.......
Ch k gim th s 1:.............Ch k gim th s 2:
S Gio dc v o to
Hi Dng
=========
P N
K THI CHN HC SINH GII TNH HI DNG
CHNH THC
Cu
1
1
(1
)
2
(1
)
P N
a. Hin tng: c kt ta en
CuCl2 + H2S CuS + 2HCl
b. Hin tng: c kt ta keo trng v kh thot ra
2AlCl3 + 3H2O + 3Na2CO3 2Al(OH)3 + 3CO2 + 6NaCl
c. Hin tng: Cht rn tan, dung dch c mu xanh khi cho h tinh
bt vo
Fe3O4 +8HI 3FeI2 + I2 + 4H2O
I2 + h tinh bt mu xanh
d. Hin tng: ban u c kt ta xanh, sau kt ta tan to dung
dch xanh lam
CuSO4 + 2NH3 +2H2O Cu(OH)2 + (NH4)2SO4
Cu(OH)2 + 4NH3 [Cu(NH3)4](OH)2
Xc nh ng cc cht trong phng trnh c 0,25 im, nu cc
cht trong phng trnh sai tr 0,125im
Y: Cl2 +H2
2HCl
X
(X)
(Y)
Z: HCl + KOH
KCl + H2O
Y
(Y)
(A)
(Z)
X:
Z
5Cl2 +6K2SO4 + 2MnSO4 + 8H2O
10KCl + 2KMnO4 + 8H2SO4
(Z)
(Q)
(X)
t
X
K: 3Cl2 + 2Fe
2FeCl3
0
im
0,25
0,25
0,25
0,25
0
,25
0,25
0,25
(X)
(K)
L: FeCl3 + 3KOH
Fe(OH)3 + 3KCl
K
(K)
(A)
(L)
t
L
M: 2Fe(OH)3
Fe2O3 +3H2O
(L)
(M)
0
t
M
Fe: Fe2O3 + 3COd
2Fe + 3CO2
0
(M)
(B)
N: Fe + 2HCl
FeCl2 + H2
Fe
3
(Y)
(N)
0,25
(X)
(Y)
t
Y
X: 4HClc + MnO2
MnCl2 + Cl2 + 2H2O
(Y)
(D)
(X)
X
Z + P + H2O:
Cl2 + 2KOH
KCl + KClO + H2O
(X)
(A)
(Z)
(P)
1
2
2CH
-COOH
2
CH2-CO-NH-CH2NH
COOH
2
(1
NH2 )
0,25
+ H2 O
(Gly-Gly)
2CH3-CH-COOH
NH2
CH3-CH-CO-NH-CHNH2
COOH
CH
(Ala-Ala)
CH3-CH-COOH
0,25
CH2-COOH CH3-CH-COOH
+H2
N
NH2
CH2-COOH
+H2
N
0,25
+ H2O
CH3-CH-CO-NH-CH2NH2
COOH
(Ala-Gly)
+
H2O
CH2-CO-NH-CH-COOH +
H2O
NH2
CH
NH2
0,25
(Gly-Ala)
2 Al4C3A: Al4C3 + 12H2O 4Al(OH)3 + 3CH4
(1
(A)
)
AB:
1500 C
CH CH + 3H2
2CH4
LLN
0
(A)
BC:
(B)
xt
CH CH + CH3COOH
CH3COOCH=CH2
(B)
CD:
0,25
(C)
0,25
t ,p
nCH3COOCH=CH(CH
2
-xt
(C)
CH)nOOC-CH
(D)
Dpolivinylancol:
(CH2CH)nOOC-CH
t
+ nNaOH
(CH -
0
(D)
+ nCH3COONa
CH)n OH
polivinylancol
4
2+
H , Hg
CH3CHO
CH CH + H2O
80 C
BE:
(B)
EF:
0,25
(E)
0
Ni ,t
CH3CHO + H2
C2H5OH
(E)
(F)
Al O / ZnO
CH2=CH-CH=CH2 + H2 + 2H2O
2C2H5OH
450
FG:
2 3
(F)
G Cao su Buna:
0,25
(G)
t ,p
(CH
-CH=CH
nCH2=CH-CH=CH
2
2 xt
CH2)n
(G)
Cao su Buna
0
(1
)
0,25
a (0,5)
FeCO3 + 4HNO3
Fe(NO3)3 + CO2 + NO2 + 2H2O (1)
0,125
0,125
0,125 0,125
FeS2 + 18HNO3
Fe(NO3)3 + 2H2SO4 + 15NO2 + 7H2O (2)
0,05
0,05
0,1
0,75
V pH = 1=> [H+] = 0,1=> nH = 0, 2mol nH SO = 0,1mol
+
0,25
2 ( 2)
0,25
Fe + 4H+ + 2 NO3
Fe2+ + 2NO2 + 2H2O
0,05 0,2 0,1
Fe + 2Fe3+
3Fe2+
0,25
(1
(1)
men
2C2H5OH + 2CO2
C6H12O6
30 C
(2)
0,25
0,25
H SO
CH2=CH2 + H2O (3)
C2H5OH
170 C
2
(-CH2-CH2-)n
CH2=CH2
xt
Ta c: (C6H10O5)n 2nC2H4
56n (g)
162n (g)
m = 8,1 (tn)
2,8 (tn)
p ,t
(4)
0,25
1
(1
)
100
80
100 100
.
= 20,25 tn
80 50
x
RCln +
R + nHCl
n
H2
2
n
.y
2
n
. y = 0,14 (I)
2
0,25
(3)
(4)
n
.y
3
n
.y = 0,12 (II)
3
0,12
n
2
(1
0,25
(2)
Phn 2:
Fe + 4HNO3
Fe(NO3)3 + NO + 2H2O
x
x
3R + 4nHNO3
3R(NO3)n + nNO +2nH2O
0,25
n = 1 => MR = 9
n = 2 => MR = 18
n = 3 => MR = 27 => Kim loi R l Al; n = 3
=> x = 0,08 (mol); y = 0,04 (mol)
=> %mFe = 80,67% ; %mAl = 19,33%
Phn 3:
Sau phn ng khi lng cht rn tng = 8,64 5,56 = 3,08 gam
0,25
0,25
0,25
0,06(mol)
Fe + CuSO4
FeSO4 + Cu
(6)
z
z (mol) z
=> 2,76 + (64-56).z = 3,08 => z = 0,04 (mol)
=> nCuSO phn ng = 0,06 + 0,04 = 0,1 (mol) => V = 0,1lt = 100 ml
Tm B:
0,25
0,25
0,25
1
(1
)
nCO2 =
0,25
13, 44
10,8
21, 2
= 0, 6mol ; nH 2O =
= 0, 6mol; nNa2CO3 =
= 0, 2mol
22, 4
18
106
=>
nC = 0, 6 + 0, 2 = 0,8mol
nH = 2 0, 6 = 1, 2mol
nNa = 2 0, 2 = 0, 4mol
nO =
39, 2 12 0,8 1, 2 1 0, 4 23
= 1, 2mol
16
0,25
0,25
29,12
12, 6
10, 6
= 1,3mol ; nH 2O =
= 0, 7mol ; nNa2CO3 =
= 0,1mol =>
22, 4
18
106
nC = 1,3 + 0,1 = 1, 4mol
nH = 2 0, 7 = 1, 4mol
=>
2
(1
26 12 1, 4 1, 4 1 23 0, 2
= 0, 2mol
16
0,25
Tm A:
B(C, H, O, Na) + D(C, H, O, Na) + H2O (*)
Ta c: A + NaOH
0,25
0,25
3, 6
2 0, 6 1 = 2, 4mol
18
44,8 12 2, 2 2, 4 1
= 1, 0mol
16
0,25
0,25