6 Chuyen de Hoa Huu Co 11

Bin son v ging dy : Gio vin Nguyn Minh Tun T Ha Trng THPT Chuyn Hng Vng Ph Th
MC LC
Trang
Li gii thiu Phn 1: Gii thiu cc chuyn ha hu c 11

Chuyn 1 : i cng ha hu c Chuyn 2 : Hirocacbon no Chuyn 3 : Hirocacbon khng no Chuyn 4 : Hirocacbon thm Chuyn 5 : Dn xut halogen Phenol Ancol Chuyn 6 : Anehit Xeton Axit cacboxylic
2 3 134 3 17 18 32 33 57 58 68 69 102 103 134 135 139
Phn 2 : p n
Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Li gii thiu
B ti liu n thi i hc, cao ng mn ha hc
B ti liu trc nghim n thi i hc, cao ng mn ha hc do thy bin son g m 7 quyn :
Quyn 1 : Gii thiu 7 chuyn ha hc 10 Quyn 2 : Gii thiu 3 chuyn ha hc i cng v v c 11 Quyn 3 : Gii thiu 6 chuyn ha hc hu c 11 Quyn 4 : Gii thiu 4 chuyn ha hc hu c 12 Quyn 5 : Gii thiu 4 chuyn ha hc i cng v v c 12 Quyn 6 : Gii thiu 10 phng php gii nhanh bi tp ha hc Quyn 7 : Gii thiu 43 luyn thi trc nghim mn ha hc
Nu cn s gip hoc t vn v phng php hc tp mn ha hc cc em hy gi cho thy theo s in thoi 01689186513, thy lun sn sng gip cc em.
2 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
PHN 1: GII THIU CC CHUYN HA HU C 11

CHUYN 1 : I CNG HA HC HU C
BI TP TRC NGHIM
Cu 1: Hy chn pht biu ng nht v ho hc hu c trong s cc pht biu sau : A. Ho hc hu c l ngnh ho hc chuyn nghin cu cc hp cht ca cacbon. B. Ho hc hu c l ngnh ho hc chuyn nghin cu cc hp cht ca cacbon, tr cacbon (II) oxit, cacbon (IV) oxit, mu i cacbonat, xianua, cacbua. C. Ho hc hu c l ngnh ho hc chuyn nghin cu cc hp cht ca cacbon, tr cacbon (II) oxit, cacbon (IV) oxit. D. Ho hc hu c l ngnh ho hc chuyn nghin cu cc hp cht ca cacbon tr mu i cacbonat. Cu 2: Thnh phn cc nguyn t trong hp cht hu c A. nht thit phi c cacbon, thng c H, hay gp O, N sau n halogen, S, P... B. gm c C, H v cc nguyn t khc. C. bao gm t t c cc nguyn t trong bng tun hon. D. thng c C, H hay gp O, N, sau n halogen, S, P. Cu 3: Cp hp cht no sau y l hp cht hu c ? B. CH3Cl, C6H5Br. A. CO2, CaCO3. C. NaHCO3, NaCN. D. CO, CaC2. Cu 4: Dy cht no sau y l hp cht hu c ? A. (NH4)2CO3, CO2, CH4, C2H6. B. C2H4, CH4, C2H6O, C3H9N. C. CO2, K2CO3, NaHCO3, C2H5Cl. D. NH4HCO3, CH3OH, CH4, CCl4. Cu 5: Cho cc cht: CaC2, CO2, HCOOH, C2H6O, CH3COOH, CH3Cl, NaCl, K2CO3. S hp cht hu c trong cc cht trn l bao nhiu ? A. 4. B. 5. C. 3. D. 2. Cu 6: Cho dy cht : CH4 ; C6H6 ; C6H5OH ; C2H5ZnI ; C2H5PH2. Nhn xt no sau y ng ? A. Cc cht trong dy u l hirocacbon. B. Cc cht trong dy u l dn xut ca hirocacbon. C. Cc cht trong dy u l hp cht hu c. D. C c cht v c v hu c nhng u l hp cht ca cacbon. Cu 7: c im chung ca cc phn t hp cht hu c l : 1) Thnh phn nguyn t ch yu l C v H. 2) C th cha nguyn t khc nh Cl, N, P, O. 3) Lin kt ha hc ch yu l lin kt cng ho tr. 4) Lin kt ho hc ch yu l lin kt ion. 5) D bay hi, kh chy. 6) Phn ng ho hc xy ra nhanh. Nhm cc ng l : A. 4, 5, 6. B. 1, 2, 3. C. 1, 3, 5. D. 2, 4, 6.
Cu 8: Nhn xt no ng v cc cht hu c so vi cc cht v c ? A. tan trong nc ln hn. B. bn nhit cao hn. C. Tc phn ng nhanh hn. D. Nhit nng chy, nhit si thp hn. Cu 9: Phn ng ha hc ca cc hp cht hu c c c im l : A. thng xy ra rt nhanh v cho mt sn phm duy nht. B. thng xy ra chm, khng hon ton, khng theo mt hng nht nh. C. thng xy ra rt nhanh, khng hon ton, khng theo mt hng nht nh. D. thng xy ra rt chm, nhng hon ton, khng theo mt hng xc nh. Cu 10: Thuc tnh no sau y khng phi l ca cc hp cht hu c ? A. Kh nng phn ng ho hc chm, theo nhiu hng khc nhau. B. Khng bn nhit cao. C. Lin kt ho hc trong hp cht hu c thng l lin kt ion. D. D bay hi v d chy hn hp cht v c. Cu 11: Hp cht hu c c phn loi nh sau : A. Hirocacbon v hp cht hu c c nhm chc. B. Hirocacbon v dn xut ca hirocacbon. C. Hirocacbon no, khng no, thm v dn xut ca hirocacbon. D. Tt c u ng. Cu 12: Cc cht trong nhm cht no di y u l dn xut ca hirocacbon ? A. CH2Cl2, CH2BrCH2Br, NaCl, CH3Br, CH3CH2Br. B. CH2Cl2, CH2BrCH2Br, CH3Br, CH2=CHCOOH, CH3CH2OH. C. CH2BrCH2Br, CH2=CHBr, CH3Br, CH3CH3. D. HgCl2, CH2BrCH2Br, CH2=CHBr, CH3CH2Br. Cu 13: Hp cht (CH3)2C=CHC(CH3)2CH=CHBr c danh php IUPAC l : A. 1-brom-3,5-trimetylhexa-1,4-ien. B. 3,3,5-trimetylhexa-1,4-ien-1-brom. C. 2,4,4-trimetylhexa-2,5-ien-6-brom. D. 1-brom-3,3,5-trimetylhexa-1,4-ien. Cu 14: Hp cht (CH3)2C=CHC(CH3)3 c danh php IUPAC l : A. 2,2,4-trimetylpent-3-en. B. 2,4-trimetylpent-2-en. C. 2,4,4-trimetylpent-2-en. D. 2,4-trimetylpent-3-en. Cu 15: Hp cht CH2=CHC(CH3)2CH2CH(OH)CH3 c danh php IUPAC l : A. 1,3,3-trimetylpent-4-en-1-ol. B. 3,3,5-trimetylpent-1-en-5-ol. C. 4,4-imetylhex-5-en-2-ol. D. 3,3-imetylhex-1-en-5-ol. Cu 16: Ghp tn ct 1 vi cng thc ct 2 cho ph hp ? Ct 1 Ct 2 1) phenyl clorua a. CH3Cl 2) metylen clorua b. CH2=CHCl 3) anlyl clorua c. CHCl3 4) vinyl clorua d. C6H5Cl 5) clorofom e. CH2=CHCH2Cl f. CH2Cl2 A. 1-d, 2-c, 3-e, 4-b, 5-a. B. 1-d, 2-f, 3-b, 4-e, 5-c. C. 1-d, 2-f, 3-e, 4-b, 5-a. D. 1-d, 2-f, 3-e, 4-b, 5-c. 4 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 17: Ghp tn ct 1 v CTCT ct 2 cho ph hp : Ct 1 Ct 2 1. isopropyl axetat a. C6H5OOCCH3 2. allylacrylat b. CH3COOCH(CH3)2 3. phenyl axetat c. CH2=CHCOOCH=CH2 4. sec-butyl fomiat d. CH2=CHCOOCHCH=CH2 e. HCOOCH(CH3)CH2CH3 A. 1-b, 2-d, 3-a, 4-e. B. 1-b, 2-c, 3-a, 4-e. C. 1-d, 2-d, 3-a, 4-e. D. 1-b, 2-d, 3-a, 4-c. Cu 18: Cho hn hp cc ankan sau : pentan (si 36oC), heptan (si 98 oC), octan (si 126 oC), nonan (si 151oC). C th tch ring cc cht bng cch no sau y ? A. Kt tinh. B. Chng ct. C. Thng hoa. D. Chit. Cu 19: Nguyn t c chung ca php phn tch nh tnh cc nguyn t trong hp cht hu c l g ? A. t chy cht hu c pht hin hiro di dng hi nc. B. t chy hp cht hu c pht hin nit c mi ca tc chy. C. t chy cht hu c pht hin cacbon di dng mui than. D. Chuyn ha cc nguyn t C, H, N thnh cc cht v c n gin d nhn bit. Cu 20: Mun bit hp cht hu c c cha hiro hay khng, ta c th : A. t cht hu c xem c to cht b en hay khng. B. oxi ha hp cht hu c bng CuO, sau cho sn phm i qua nc vi trong. C. cho cht hu c tc dng vi dung dch H2SO4 c. D. oxi ha hp cht hu c bng CuO, sau cho sn phm i qua CuSO4 khan. Cu 21: Nung mt hp cht hu c X vi lng d cht oxi ha CuO ngi ta thy thot ra kh CO2, hi H2O v kh N2. Chn kt lun chnh xc nht trong cc kt lun sau : A. X chc chn cha C, H, N v c th c hoc khng c oxi. B. X l hp cht ca 3 nguyn t C, H, N. C. Cht X chc chn c cha C, H, c th c N. D. X l hp cht ca 4 nguyn t C, H, N, O. Cu 22: Pht biu no sau c dng nh ngha cng thc n gin nht ca hp cht hu c ? A. Cng thc n gin nht l cng thc biu th s nguyn t ca mi nguyn t trong phn t. B. Cng thc n gin nht l cng thc biu th t l ti gin v s nguyn t ca cc nguyn t trong phn t. C. Cng thc n gin nht l cng thc biu th t l phn trm s mol ca m i nguyn t trong phn t . D. Cng thc n gin nht l cng thc biu th t l s nguyn t C v H c trong phn t . Cu 23: Cho cht axetilen (C2H2) v benzen (C6H6), hy chn nhn xt ng trong cc nhn xt sau y : A. Hai cht ging nhau v cng thc phn t v khc nhau v cng thc n gin nht. B. Hai cht khc nhau v cng thc phn t v ging nhau v cng thc n gin nht. C. Hai cht khc nhau v cng thc phn t v khc nhau v cng thc n gin nht. D. Hai cht c cng cng thc phn t v cng cng thc n gin nht.
Cu 24: Theo thuyt cu to ha hc, trong phn t cc cht hu c, cc nguyn t lin kt v i nhau A. theo ng ha tr. B. theo mt th t nht nh. C. theo ng s oxi ha. D. theo ng ha tr v theo mt th t nht nh. Cu 25: Cu to ho hc l : A. S lng lin kt gia cc nguyn t trong phn t . B. Cc loi lin kt gia cc nguyn t trong phn t. C. Th t lin kt gia cc nguyn t trong phn t. D. Bn cht lin kt gia cc nguyn t trong phn t. Cu 26: bit r s lng nguyn t, th t kt hp v cch kt hp ca cc nguyn t trong phn t hp cht hu c ngi ta dng cng thc no sau y ? A. Cng thc phn t. B. Cng thc tng qut. C. Cng thc cu to. D. C A, B, C. Cu 27: Hin tng cc cht c cu to v tnh cht ho hc tng t nhau, chng ch hn km nhau mt hay nhiu nhm metylen (CH2) c gi l hin tng A. ng phn. B. ng v. C. ng ng. D. ng khi. Cu 28: Hai cht c cng thc : C6H5 - C - O - CH3 v CH3 - O - C - C6H5
O O
Nhn xt no sau y ng ? A. L cc cng thc ca hai cht c cng cng thc phn t nhng c cu to khc nhau. B. L cc cng thc ca hai cht c cng cng thc phn t nhng c cu to tng t nhau. C. L cc cng thc ca hai cht c cng thc phn t v cu to u khc nhau. D. Ch l cng thc ca mt cht v cng thc phn t v cu to u ging nhau. Cu 29: Trong cc dy cht sau y, dy no gm cc cht l ng ng ca nhau ? A. C2H6, CH4, C4H10. B. C2H5OH, CH3CH2CH2OH. C. CH3OCH3, CH3CHO. D. A v B ng. Cu 30: Cho cc cht sau y :
CH = CH2
CH3
CH2 -CH3
CH = CH2
CH3
CH3
(V)
(I)
(II)
(III)
(IV)
Cht ng ng ca benzen l : A. I, II, III. B. II, III.
C. II, V.
D. II, III, IV.
Cu 31: Cho cc cht sau y : (I) CH3CH(OH)CH3 (II) CH3CH2OH (III) CH3CH2CH2OH (IV) CH3CH2CH2OCH3 (V) CH3CH2CH2CH2 OH (VI) CH3OH Cc cht ng ng ca nhau l : A. I, II v VI. B. I, III v IV. C. II, III,V v VI. D. I, II, III, IV. Cu 32: Cho cc cht : C6H5OH (X) ; C6H5CH2OH (Y) ; HOC6H4OH (Z) ; C6H5CH2CH2OH (T). Cc cht ng ng ca nhau l : A. Y, T. B. X, Z, T. C. X, Z. D. Y, Z. Cu 33: Chn nh ngha ng phn y nht : A. ng phn l hin tng cc cht c cu to khc nhau. B. ng phn l hin tung cc cht c tnh cht khc nhau. C. ng phn l nhng hp cht khc nhau nhng c cng cht c cng CTPT. D. ng phn l hin tung cc cht c cu to khc nhau nn c tnh cht khc nhau. Cu 34: Nguyn nhn ca hin tng ng phn trong ha hc hu c l g ? A. V trong hp cht hu c, nguyn t cacbon lun c ha tr IV. B. V cacbon c th lin kt vi chnh n to thnh mch cacbon (thng, nhnh, nhnh hoc vng). C. V s thay i trt t trong lin kt gia cc nguyn t trong phn t . D. V trong hp cht hu c cha nguyn t hiro. Cu 35: Trong nhng dy cht sau y, dy no c cc cht l ng phn ca nhau ? A. C2H5OH, CH3OCH3. B. CH3OCH3, CH3CHO. C. CH3CH2CH2OH, C2H5OH. D. C4H10, C6H6. Cu 36: Cho cc cht :
Cc cht ng phn ca nhau l : A. II, III. B. I, IV, V. C. IV, V. D. I, II, III, IV, V. Cu 37: Cc cht hu c n chc Z1, Z2, Z3 c CTPT tng ng l CH2O, CH2O2, C2H4O2. Chng thuc cc dy ng ng khc nhau. Cng thc cu to ca Z3 l : A. CH3COOCH3. B. HOCH2CHO. C. CH3COOH. D. CH3OCHO. Cu 38: Nhng hp cht no sau y c ng phn hnh hc ? (I) CH3CCH (II) CH3CH=CHCH3 (III) (CH3)2CHCH2CH3 (IV) CH3CBr=CHCH3 (V) CH3CH(OH)CH3 (VI) CHCl=CH2 A. (II). B. (II) v (VI). C. (II) v (IV). D. (II), (III), (IV) v (V).
Cu 39: Cho cc cht sau : (1) CH2=CHCCH (2) CH2=CHCl (3) CH3CH=C(CH3)2 (4) CH3CH=CHCH=CH2 (5) CH2=CHCH=CH2 (6) CH3CH=CHBr Cht no sau y c ng phn hnh hc ? A. 2, 4, 5, 6. B. 4, 6. C. 2, 4, 6. D. 1, 3, 4. Cu 40: Nhng cht no sau y l ng phn hnh hc ca nhau ?
A. (I), (II). B. (I), (III). C. (II), (III). D. (I), (II), (III). Cu 41: Hp cht hu c no sau y khng c ng phn cis-trans ? A. 1,2-icloeten. B. 2-metyl pent-2-en. C. but-2-en. D. pent-2-en. Cu 42: Pht biu khng chnh xc l : A. Lin kt ba gm hai lin kt v mt lin kt . B. Cc cht c cng kh i lng phn t l ng phn ca nhau. C. Cc cht l ng phn ca nhau th c cng cng thc phn t . D. S xen ph trc to thnh lin kt , s xen ph bn t o thnh lin kt . Cu 43: Kt lun no sau y l ng ? A. Cc nguyn t trong phn t hp cht hu c lin kt vi nhau khng theo mt th t nht nh. B. Cc cht c thnh phn phn t hn km nhau mt hay nhiu nhm CH2, do tnh cht ha hc khc nhau l nhng cht ng ng. C. Cc cht c cng cng thc phn t nhng khc nhau v cng thc cu to c gi l cc cht ng ng ca nhau. D. Cc cht khc nhau c cng cng thc phn t c gi l cc cht ng phn ca nhau. Cu 44: Cho cng thc cu to sau : CH3CH(OH)CH=C(Cl)CHO. S oxi ha ca cc nguyn t cacbon tnh t phi sang tri c gi tr ln lt l : A. +1 ; +1 ; -1 ; 0 ; -3. B. +1 ; -1 ; -1 ; 0 ; -3. C. +1 ; +1 ; 0 ; -1 ; +3. D. +1 ; -1 ; 0 ; -1 ; +3. Cu 45: Hp cht cha mt lin kt trong phn t thuc loi hp cht A. khng no. B. mch h. C. thm. D. no hoc khng no. Cu 46: Trong cng thc CxHyOzNt tng s lin kt v vng l : A. (2x-y + t+2)/2. B. (2x-y + t+2). C. (2x-y - t+2)/2. D. (2x-y + z + t+2)/2. Cu 47: Vitamin A cng thc phn t C20H30O, c cha 1 vng 6 cnh v khng c cha lin kt ba. S lin kt i trong phn t vitamin A l : A. 7. B. 6. C. 5. D. 4.
Cu 48: Licopen, cng thc phn t C40H56 l cht mu trong qu c chua, ch cha lin kt i v lin kt n trong phn t. Hiro ha hon ton licopen c hirocacbon C40H82. Vy licopen c A. 1 vng ; 12 ni i. B. 1 vng ; 5 ni i. C. 4 vng ; 5 ni i. D. mch h ; 13 ni i. Cu 49: Metol C10H20O v menton C10H18O chng u c trong tinh du bc h. Bit phn t metol khng c ni i, cn phn t menton c 1 ni i. Vy kt lun no sau y l ng ? A. Metol v menton u c cu to vng. B. Metol c cu to vng, menton c cu to mch h. C. Metol v menton u c cu to mch h. D. Metol c cu t o mch h, menton c cu to vng. Cu 50: Trong hp cht CxHyOz th y lun lun chn v y 2x+2 l do : A. a 0 (a l tng s lin kt v vng trong phn t). B. z 0 (m i nguyn t oxi t o c 2 lin kt). C. m i nguyn t cacbon ch t o c 4 lin kt. D. cacbon v oxi u c ha tr l nhng s chn. Cu 51: Tng s lin kt v vng ng vi cng thc C5H9O2Cl l : A. 0. B. 1. C. 2. D. 3. Cu 52: Tng s lin kt v vng ng vi cng thc C5H12O2 l : A. 0. B. 1. C. 2. D. 3. Cu 53: Cng thc tng qut ca dn xut iclo mch h c cha mt lin kt ba trong phn t l : A. CnH2n-2Cl2. B. CnH2n-4Cl2. C. CnH2nCl2. D. CnH2n-6Cl2. Cu 54: Cng thc tng qut ca dn xut ibrom khng no mch h cha a lin kt l : A. CnH2n+2-2aBr2. B. CnH2n-2aBr2. C. CnH2n-2-2aBr2. D. CnH2n+2+2aBr2. Cu 55: Hp cht hu c c cng thc tng qut CnH2n+2O2 thuc loi A. ancol hoc ete no, mch h, hai chc. B. anehit hoc xeton no, mch h, hai chc. C. axit hoc este no, n chc, mch h. D. hiroxicacbonyl no, mch h. Cu 56: Ancol no, mch h c cng thc tng qut chnh xc nht l : A. R(OH)m. B. CnH2n+2Om. C. CnH2n+1OH. D. CnH2n+2-m(OH)m. Cu 57: Cng thc tng qut ca anehit n chc, mch h c 1 lin kt i C=C l : A. CnH2n+1CHO. B. CnH2nCHO. C. CnH2n-1CHO. D. CnH2n-3CHO. Cu 58: Anehit mch h c cng thc tng qut CnH2n-2O thuc loi A. anehit n chc, no. B. anehit n chc, cha mt lin kt i trong gc hirocacbon. C. anehit n chc, cha hai lin kt trong gc hirocacbon. D. anehit n chc, cha ba lin kt trong gc hirocacbon. Cu 59: Cng thc tng qut ca ancol n chc, mch h c hai lin kt i trong gc hirocacbon l : A. CnH2n-4O. B. CnH2n-2O. C. CnH2nO. D. CnH2n+2O. Cu 60: Anehit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l : A. 0. B. 1. C. 2. D. 3.
Cu 61: Cng thc phn t tng qut ca axit hai chc, mch h cha mt lin kt i trong gc hirocacbon l : A. CnH2n-4O4. B. CnH2n-2O4. C. CnH2n-6O4. D. CnH2nO4. Cu 62: Axit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l : A. 0. B. 1. C. 2. D. 3. Cu 63: Tng s lin kt v vng trong phn t axit benzoic (C6H5COOH) l : A. 3. B. 4. C. 5. D. 6. Cu 64: S lng ng phn ng vi cng thc phn t C6H14 l : A. 6. B. 7. C. 4. D. 5. Cu 65: S lng ng phn mch h ng vi cng thc phn t C5H10 l : A. 2. B. 3. C. 6. D. 5. Cu 66: S lng ng phn cu t o ng vi cng thc phn t C5H10 l : A. 7. B. 8. C. 9. D. 10. Cu 67: S lng ng phn mch h ng vi cng thc phn t C5H8 l : A. 7. B. 8. C. 9. D. 10. Cu 68: S lng ng phn cha vng benzen ng vi cng thc phn t C9H12 l : A. 7. B. 8. C. 9. D. 10. Cu 69: S lng ng phn cha vng benzen ng vi cng thc phn t C9H10 l : A. 7. B. 8. C. 9. D. 6. Cu 70: S lng ng phn ng vi cng thc phn t C3H5Br3 l : A. 3. B. 4. C. 5. D. 6. Cu 71: S lng ng phn ng vi cng thc phn t C3H5Cl l : A. 3. B. 4. C. 5. D. 6. Cu 72: Hp cht C4H10O c s ng phn ancol v tng s ng phn l : A. 7 v 4. B. 4 v 7. C. 8 v 8. D. 10 v 10. Cu 73: S lng ng phn mch h ng vi cng thc phn t C3H6O l : A. 2. B. 3. C. 4. D. 5. Cu 74: S lng ng phn mch h ng vi cng thc phn t C4H6O2 tc dng c v i NaHCO3 l : A. 2. B. 3. C. 4. D. 5. Cu 75: S lng ng phn ng vi cng thc phn t C4H11N l : A. 7. B. 8. C. 9. D. 10. Cu 76: c im chung ca cc cacbocation v cacbanion l : A. km bn v c kh nng phn ng rt km. B. chng u rt bn vng v c kh nng phn ng cao. C. c th d dng tch c ra khi hn hp phn ng. D. km bn v c kh nng phn ng cao. Cu 77: Phn ng CH3COOH + CH CH CH3COOCH = CH2 thuc loi phn ng no sau y ? A. Phn ng th. B. Phn ng cng. C. Phn ng tch. D. Khng thuc v ba loi phn ng trn.
Cu 78: Phn ng 2CH3OH CH3OCH3 + H2O thuc loi phn ng no sau y ? A. Phn ng th. B. Phn ng cng. C. Phn ng tch. D. Khng thuc v ba loi phn ng trn. Cu 79: Phn ng CH CH + 2AgNO3 + 2NH3 AgC CAg + 2NH4NO3 thuc loi phn ng no ? A. Phn ng th. B. Phn ng cng. C. Phn ng tch. D. Khng thuc v ba loi phn ng trn. Cu 80: Phn ng : CH 3 - CH 2 - CH - CH3 CH 3 - CH = CH - CH 3 + H 2 O thuc loi phn ng | OH no ? A. Phn ng th. B. Phn ng cng. C. Phn ng tch. D. Khng thuc v ba loi phn ng trn. Cu 81: Cng thc n gin nht ca hirocacbon M l CnH2n+1. M thuc dy ng ng no ? A. ankan. B. khng d kin xc nh. C. ankan hoc xicloankan. D. xicloankan. Cu 82: Hp cht X c CTGN l CH3O. CTPT no sau y ng vi X ? A. C3H9O3. B. C2H6O2. C. CH3O. D. Khng xc nh c. Cu 83: Cng thc thc nghim ca cht hu c c dng (CH3Cl)n th cng thc phn t ca hp cht l : A. CH3Cl. B. C2H6Cl2. C. C3H9Cl3. D. Khng xc nh c. Cu 84: Hp cht X c CTGN l C4H9ClO. CTPT no sau y ng vi X ? A. C4H9ClO. B. C8H18Cl2O2. C. C12H27Cl3O3. D. Khng xc nh c. Cu 85: CTGN ca 1 anehit no, a chc, mch h l C2H3O. CTPT ca n l : A. C8H12O4. B. C4H6O. C. C12H18O6. D. C4H6O2. Cu 86: Axit cacboxylic A c cng thc n gin nht l C3H4O3. A c cng thc phn t l : A. C3H4O3. B. C6H8O6. C. C18H24O18. D. C12H16O12. Cu 87: Mt axit no A c CTGN l C2H3O2. CTPT ca axit A l : A. C6H9O6. B. C2H3O2. C. C4H6O4. D. C8H12O8. Cu 88: Hirocacbon A c t kh i so vi He bng 14. CTPT ca A l : A. C4H10. B. C4H6. C. C4H4. D. C4H8. Cu 89: Mt hp cht hu c X c kh i lng phn t l 26. em t X ch thu c CO2 v H2O. CTPT ca X l : A. C2H6. B. C2H4. C. C2H2. D. CH2O. Cu 90: Mt hp cht hu c A c t kh i so vi khng kh bng bng 2. t chy hon ton A bng kh O2 thu c CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A ? A. 2. B. 1. C. 3. D. 4. Cu 91: Hp cht hu c X c cng thc phn t l CxHyOz. Kh i lng phn t ca X l 60 vC. C bao nhiu cng thc phn t ph hp vi X ? A. 1. B. 2. C. 3. D. 4. Cu 92: Mt hp cht hu c A c M = 74. t chy A bng oxi thu c kh CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A ? A. 4. B. 2. C. 3. D. 1.
Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng 11
Cu 93: Hp cht hu c X c cha C, H, Cl. MX = 76,5. Hy cho bit X c bao nhiu ng phn cu t o ? A. 2. B. 3. C. 4. D. 5. Cu 94: Hp cht hu c Y c t kh i hi so vi H2 l 37. Y tc dng c vi Na, NaOH v tham gia phn ng trng gng. Cng thc phn t ca Y l : A. C4H10O. B. C3H6O2. C. C2H2O3. D. C4H8O. Cu 95: Oxi ha hon ton 6,15 gam hp cht hu c X thu c 2,25 gam H2O ; 6,72 lt CO2 v 0,56 lt N2 (kc). Phn trm kh i lng ca C, H, N v O trong X ln lt l : A. 58,5% ; 4,1% ; 11,4% ; 26%. B. 48,9% ; 15,8% ; 35,3% ; 0%. C. 49,5% ; 9,8% ; 15,5% ; 25,2%. D. 59,1 % ; 17,4% ; 23,5% ; 0%. Cu 96: Hp cht X c thnh phn % v kh i lng : C (85,8%) v H (14,2%). Hp cht X l : A. C3H8. B. C4H10. C. C4H8. D. kt qu khc. Cu 97: Hp cht X c %C = 54,54% ; %H = 9,1%, cn li l oxi. Khi lng phn t ca X bng 88. CTPT ca X l : A. C4H10O. B. C5H12O. C. C4H10O2. D. C4H8O2. Cu 98: Mt hp cht hu c Z c % kh i lng ca C, H, Cl ln lt l : 14,28% ; 1,19% ; 84,53%. CTPT ca Z l : A. CHCl2. B. C2H2Cl4. C. C2H4Cl2. D. mt kt qu khc. Cu 99: Hp cht hu c A c thnh phn phn trm kh i lng cc nguyn t nh sau: C chi m 24,24% ; H chim 4,04% ; Cl chim 71,72%. A c bao nhiu cng thc cu t o ? A. 2. B. 3. C. 1. D. 4. Cu 100: Mt cht hu c A c 51,3% C ; 9,4% H ; 12% N ; 27,3% O. T kh i hi ca A so v i khng kh l 4,034. CTPT ca A l : A. C5H12O2N. B. C5H11O2N. C. C5H11O3N. D. C5H10O2N. Cu 101: Cht hu c A cha 7,86% H ; 15,73% N v kh i lng. t chy hon ton 2,225 gam A thu c CO2, hi nc v kh nit, trong th tch kh CO2 l 1,68 lt (ktc). CTPT ca A l (bit MA < 100) : A. C6H14O2N. B. C3H7O2N. C. C3H7ON. D. C3H7ON2. Cu 102: t chy hon ton 0,2 mol cht X cha (C, H, O) v cho sn phm chy ln lt i qua bnh 1 cha 100 gam dung dch H2SO4 96,48% v bnh 2 cha dung dch KOH d. Sau th nghi m thy nng H2SO4 bnh 1 gim cn 90%. Trong bnh 2 to ra 55,2 gam mu i. CTPT ca X l (bit X c cha 2 nguyn t oxi) : A. CH2O2. B. C3H6O2. C. C3H8O2. D. C2H4O2. Cu 103: Xc nh CTPT ca hirocacbon X, bit trong phn t ca X : mC = 4mH A. C2H6. B. C3H8. C. C4H10. D. Khng th xc nh. Cu 104: T l % kh i lng ca cacbon v hiro trong hirocacbon X l 92,3 : 7,7. Kh i lng phn t ca X ln gp 1,3 ln kh i lng ca axit axetic. CTPT ca X l : A. C6H6. B. C4H4. C. C6H12. D. C5H10. Cu 105: Phn tch hp cht hu c X thy c 3 phn kh i lng cacbon li c 1 phn kh i lng hiro, 7 phn kh i lng nit v 8 phn lu hunh. Trong CTPT ca X ch c 1 nguyn t S, v y CTPT ca X l : B. C2H2N2S. C. C2H6NS. D. CH4N2S. A. CH4NS. Cu 106: Cht hu c X c M = 123 v kh i lng C, H, O v N trong phn t theo th t t l v i 72 : 5 : 32 : 14. CTPT ca X l : A. C6H14O2N. B. C6H6ON2. C. C6H12ON. D. C6H5O2N. 12 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 107: Oxi ha hon ton 4,02 gam mt hp cht hu c X ch thu c 3,18 gam Na2CO3 v 0,672 lt kh CO2. CTGN ca X l : A. CO2Na. B. CO2Na2. C. C3O2Na. D. C2O2Na. Cu 108: t chy hon ton 5,80 gam cht X thu c 2,65 gam Na2CO3 ; 2,26 gam H2O v 12,10 gam CO2. Cng thc phn t ca X l : A. C6H5O2Na. B. C6H5ONa. C. C7H7O2Na. D. C7H7ONa. Cu 109: Phn tch 1,47 gam cht hu c Y (C, H, O) bng CuO th thu c 2,156 gam CO2 v lng CuO gim 1,568 gam. CTGN ca Y l : B. CH2O. C. C2H3O. D. C2H3O2. A. CH3O. Cu 110: Khi t chy hon ton mt amin n chc X, thu c 16,80 lt kh CO2 ; 2,80 lt N2 (cc th tch o ktc) v 20,25 gam H2O. CTPT ca X l : A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. Cu 111: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO2, 12,6 gam H2O v 69,44 lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chi m 20% th tch khng kh. X c cng thc l : A. C2H5NH2. B. C3H7NH2. C. CH3NH2. D. C4H9NH2. Cu 112: t chy hon ton 1,605 gam hp cht hu c A thu c 4,62 gam CO2 ; 1,215 gam H2O v 168 ml N2 (ktc). T kh i hi ca A so vi khng kh khng vt qu 4. Cng thc phn t ca A l : A. C5H5N. B. C6H9N. C. C7H9N. D. C6H7N. Cu 113: t chy hon ton hp cht hu c cha C, H, Cl sinh ra 0,22 gam CO2, 0,09 gam H2O. Mt khc khi xc nh clo trong hp cht bng dung dch AgNO3 ngi ta thu c 1,435 gam AgCl. T kh i hi ca hp cht so vi hiro bng 42,5. Cng thc phn t ca hp cht l : A. CH3Cl. B. C2H5Cl. C. CH2Cl2. D. C2H4Cl2. Cu 114: Phn tch 0,31gam hp cht hu c X ch cha C, H, N to thnh 0,44 gam CO2. Mt khc, nu phn tch 0,31 gam X ton b N trong X chuyn thnh NH3 ri dn NH3 va to thnh vo 100 ml dung dch H2SO4 0,4M th phn axit d c trung ha bi 50 ml dung dch NaOH 1,4M. Bit 1 lt hi cht X (ktc) nng 1,38 gam. CTPT ca X l : A. CH5N. B. C2H5N2. C. C2H5N. D. CH6N. Cu 115: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm chy vo nc vi trong c 20 gam kt ta. Lc b kt ta ri un nng phn nc l c li c 10 gam kt ta na. Vy X khng th l : A. C2H6. B. C2H4. C. CH4. D. C2H2. Cu 116: t chy hon ton mt hirocacbon X th kh. Sn phm chy thu c cho hp th ht vo 200 ml dung dch Ca(OH)2 1M thy c 10 gam kt ta xut hin v kh i lng bnh ng dung dch Ca(OH)2 tng 16,8 gam. Lc b kt cho nc lc tc dng vi dung dch Ba(OH)2 d li thu c kt ta, tng khi lng hai ln kt t a l 39,7 gam. CTPT ca X l : A. C3H8. B. C3H6. C. C3H4. D. Kt qu khc. Cu 117: t chy hon ton mt hp cht hu c X cn 6,72 lt O2 (ktc). Sn phm chy g m chy hp th ht vo bnh ng dung dch Ba(OH)2 thy c 19,7 gam kt ta xut hin v kh i lng dung dch gim 5,5 gam. Lc b kt ta un nng nc lc li thu c 9,85 gam kt ta na. CTPT ca X l : A. C2H6. B. C2H6O. C. C2H6O2. D. Khng th xc nh.
Cu 118: t chy hon ton 4,3 gam mt cht hu c A ch cha mt nhm chc, sau dn ton b sn phm chy hp th vo dung dch Ca(OH)2 d. Sau phn ng thu c 20 gam kt ta v kh i lng dung dch cn li gim 8,5 gam so vi trc phn ng. Bit MA < 100. CTPT ca A l : A. C4H8O2. B. C3H6O2. C. C4H10O2. D. C4H6O2. Cu 119: t chy hon ton mt hp cht hu c X (C, H, N) bng lng khng kh va (g m 1/5 th tch O2, cn li l N2) c kh CO2 , H2O v N2. Cho ton b sn phm chy qua bnh ng dung dch Ba(OH)2 d thy c 39,4 gam kt ta, kh i lng dung dch gim i 24,3 gam. Kh thot ra khi bnh c th tch 34,72 lt (ktc). Bit d X O 2 < 2. CTPT ca X l : A. C2H7N. B. C2H8N. C. C2H7N2. D. C2H4N2. Cu 120: t chy hon ton 5,8 gam mt hp cht hu c n chc X cn 8,96 lt kh O2 (ktc), thu c CO2 v H2O c s mol bng nhau. CTGN ca X l : A. C2H4O. B. C3H6O. C. C4H8O. D. C5H10O. Cu 121: t chy hon ton 7,6 gam cht hu c X cn 8,96 lt O2 (ktc). Bit n H2O : n CO2 = 4 : 3 . CTPT ca X l : A. C3H8O. B. C3H8O2. C. C3H8O3. D. C3H8. Cu 122: t chy hon ton 1,88 gam hp cht hu c Z (cha C, H, O) cn 1,904 lt kh O2 (ktc), thu c CO2 v H2O vi t l mol tng ng l 4 : 3. Cng thc phn t ca Z l : A. C4H6O2. B. C8H12O4. C. C4H6O3. D. C8H12O5. Cu 123: t chy hon ton 1,47 gam cht hu c X (ch cha C, H, O) bng 1,0976 lt kh O2 ( ktc) lng dng va th sau th nghim thu c H2O, 2,156 gam CO2. T m CTPT ca X, bit t kh i hi ca X so vi khng kh nm trong khong 3< dx < 4. A. C3H4O3. B. C3H6O3. C. C3H8O3. D. p n khc. Cu 124: t chy hon ton 6,66 gam cht X cn 9,072 lt kh oxi (ktc). Sn phm chy c dn qua bnh 1 cha H2SO4 c v bnh 2 cha Ca(OH)2 d thy bnh 1 tng 3,78 gam v bnh 2 tng m gam v to a gam kt ta. Bit MX < 250. Gi tr ca m, a v CTPT ca X l : A. 15,8 gam, 36 gam v C6H7O2. B. 8,2 gam, 20 gam v C6H7O2. C. 15,84 gam, 36 gam v C12H14O4. D. 13,2 gam, 39 gam v C6H7O2. Cu 125: t chy hon ton mt th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu kin nhit v p sut), sn phm thu c ch gm CO2 v H2O vi mCO2 : m H2O = 44 : 9. Bit MA < 150. A c cng thc phn t l : A. C4H6O. B. C8H8O. C. C8H8. D. C2H2. Cu 126: Phn tch x gam cht hu c X ch thu c a gam CO2 v b gam H2O. Bit 3a = 11b v 7x = 3(a + b). T kh i hi ca X so vi khng kh nh hn 3. CTPT ca X l : A. C3H4O. B. C3H4O2. C. C3H6O. D. C3H6O2. Cu 127: Phn tch a gam cht hu c A thu c m gam CO2 v n gam H2O. Cho bit 9m = 22n v 31a = 15(m+n). Xc nh CTPT ca A. Bit nu t d l t kh i hi ca A i vi khng kh th 2 < d <3. A. C3H6O. B. C3H6O2. C. C2H4O2. D. C2H4O. Cu 128: t chy hon ton m gam cht hu c A cha C, H, O kh i lng sn phm chy l p gam. Cho ton b sn phm ny qua dung dch nc vi trong c d th sau cng thu c t gam kt ta, bit p = 0,71t v 1,02t = m + p. CTPT ca A l : A. C2H6O2. B. C2H6O. C. C3H8O3. D. C3H8O. Cu 129: Khi t 1 lt kh X cn 5 lt O2 sau phn ng thu c 3 lt CO2 v 4 lt hi nc. Bit cc kh o cng iu kin nhit v p sut. CTPT ca X l : A. C2H6O. B. C3H8O. C. C3H8. D. C2H6. 14 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 130: Khi t 1 lt kh X cn 6 lt O2 thu c 4 lt CO2 v 5 lt hi H2O (cc th tch kh o cng iu kin nhit , p sut). CTPT ca X l : A. C4H10O. B. C4H8O2. C. C4H10O2. D. C3H8O. Cu 131: t chy ht 2,3 gam hp cht hu c X cn V lt O2 (ktc). Sn phm chy cho hp th ht vo bnh ng dung dch nc vi trong d thy c 10 gam kt ta xut hin v kh i lng bnh ng dung dch nc vi tng 7,1 gam. Gi tr ca V l : A. 3,92 lt. B. 3,36 lt. C. 4,48 lt. D. Kt qu khc. Cu 132: t chy hon ton 0,1 mol hp cht hu c X cn 7,84 lt O2 thu c 5,6 lt kh CO2 (ktc) , 4,5 gam H2O v 5,3 gam Na2CO3. CTPT ca X l : A. C2H3O2Na. B. C3H5O2Na. C. C3H3O2Na. D. C4H5O2Na. Cu 133: t chy hon ton 0,6 gam hp cht hu c X r i cho sn phm chy qua bnh ng dung dch Ca(OH)2 d thy c 2 gam kt ta v khi lng bnh tng thm 1,24 gam. T kh i ca X so vi H2 bng 15. CTPT ca X l : A. C2H6O. B. CH2O. C. C2H4O. D. CH2O2. Cu 134: t chy hon ton 3 gam hp cht hu c X thu c 4,4 gam CO2 v 1,8 gam H2O. Bit t kh i ca X so vi He (MHe = 4) l 7,5. CTPT ca X l : A. CH2O2. B. C2H6. C. C2H4O. D. CH2O. Cu 135: t 0,15 mol mt hp cht hu c thu c 6,72 lt CO2 (ktc) v 5,4 gam H2O. Mt khc t 1 th tch hi cht cn 2,5 th tch O2. Cc th tch o cng iu kin nhit , p sut. CTPT ca hp cht l : B. C2H6O. C. C2H4O2. D. C2H4O. A. C2H6O2. Cu 136: Phn tch 1,5 gam cht hu c X thu c 1,76 gam CO2 ; 0,9 gam H2O v 112 ml N2 o 0oC v 2 atm. Nu ha hi cng 1,5 gam cht X 127o C v 1,64 atm ngi ta thu c 0,4 lt kh cht X. CTPT ca X l : A. C2H5ON. B. C6H5ON2. C. C2H5O2N. D. C2H6O2N. Cu 137: t chy 1 lt hi hirocacbon vi mt th tch khng kh (lng d). Hn hp kh thu c sau khi hi H2O ngng t c th tch l 18,5 lt, cho qua dung dch KOH d cn 16,5 lt, cho hn hp kh i qua ng ng photpho d th cn li 16 lt. Xc nh CTPT ca hp cht trn bit cc th tch kh o cng iu kin nhit , p sut v O2 chim 1/5 khng kh, cn li l N2. A. C2H6. B. C2H4. C. C3H8. D. C2H2. Cu 138: t chy hon ton mt hirocacbon trong 0,5 lt hn hp ca n vi CO2 bng 2,5 lt O2 thu c 3,4 lt kh. Hn hp ny sau khi ngng t ht hi nc cn 1,8 lt, tip tc cho hn hp kh cn li qua dung dch kim d th cn li 0,5 lt kh. Cc th tch c o cng iu kin nhit , p sut. CTPT ca hirocacbon l : A. C4H10. B. C3H8. C. C4H8. D. C3H6. Cu 139: Cho 400 ml mt hn hp g m nit v mt hirocacbon vo 900 ml oxi (d) ri t. Th tch hn hp thu c sau khi t l 1,4 lt. Sau khi cho nc ngng t cn 800 ml h n hp, ng i ta cho li qua dung dch KOH thy cn 400 ml kh. Cc th tch kh u o cng iu kin nhit , p sut. Cng thc phn t ca cht hu c l : A. C3H8. B. C2H4. C. C2H2. D. C2H6. Cu 140: t chy 200 ml hi mt hp cht hu c X cha C, H, O trong 900 ml O2, th tch hn hp kh thu c l 1,3 lt. Sau khi ngng t hi nc ch cn 700 ml. Tip theo cho qua dung dch KOH d ch cn 100 ml kh bay ra. Cc th tch kh o cng iu kin nhit , p sut. CTPT ca Y l : A. C3H6O. B. C3H8O2. C. C3H8O. D. C3H6O2.
Cu 141: t chy hon ton 0,12 mol cht hu c X mch h cn dng 10,08 lt kh O2 (ktc). Dn ton b sn phm chy (g m CO2, H2O v N2) qua bnh ng dung d ch Ba(OH)2 d, thy kh i lng bnh tng 23,4 gam v c 70,92 gam kt ta. Kh thot ra khi bnh c th tch 1,344 lt (ktc). Cng thc phn t ca X l : B. C3H5O2N. C. C3H7O2N. D. C2H7O2N. A. C2H5O2N. Cu 142: t chy hon ton 0,1 mol cht X cn 6,16 lt kh O2 (ktc), thu c 13,44 lt (ktc) hn hp CO2, N2 v hi nc. Sau khi ngng t ht hi nc, cn li 5,6 lt kh (ktc) c t kh i so vi hiro l 20,4. Cng thc phn t ca X l : B. C3H7O2N. C. C3H9O2N. D. C4H9N. A. C2H7O2N. Cu 143: t chy 0,282 gam hp cht hu c X ch cha C, H, N, cho sn phm i qua cc bnh ng CaCl2 khan v KOH d. Thy bnh ng CaCl2 tng thm 0,194 gam cn bnh ng KOH tng thm 0,8 gam. Mt khc nu t chy 0,186 gam cht X th thu c 22,4 ml kh N2 ( ktc). Bit rng hp cht X ch cha mt nguyn t nit. Cng thc phn t ca hp cht X l : A. C6H6N2. B. C6H7N. C. C6H9N. D. C5H7N. Cu 144: t chy hon ton 0,4524 gam hp cht A sinh ra 0,3318 gam CO2 v 0,2714 gam H2O. un nng 0,3682 gam cht A vi vi ti xt chuyn tt c nit trong A thnh amoniac, ri d n kh NH3 vo 20 ml dung dch H2SO4 0,5 M. trung ho axit cn d sau khi tc dng vi NH3 c n dng 7,7 ml dung d ch NaOH 1M. Bit MA= 60. Cng thc phn t ca A l : B. C2H7N. C. C3H9N. D. CH4ON. A. CH4ON2. Cu 145: t chy hon ton 0,356 gam cht hu c X thu c 0,2688 lt kh CO2 (ktc) v 0,252 gam H2O. Mt khc nu phn hu 0,445 gam cht X th thu c 56 ml kh N2 (ktc). Bit rng trong X c mt nguyn t nit. CTPT ca X l : A. C2H5O2N. B. C3H5O2N. C. C3H7O2N. D. C2H7O2N. Cu 146*: t chy hon ton 0,01 mol cht hu c X cn va 0,616 lt O2. Sau th nghim thu c hn hp sn phm Y g m : CO2, N2 v hi H2O. Lm lnh ngng t hi H2O ch cn 0,56 lt hn hp kh Z (c t kh i hi vi H2 l 20,4). Bit th tch cc kh u o ktc. Cng thc phn t X l : A. C2H5ON. B. C2H5O2N. C. C2H7O2N. D. A hoc C. Cu 147: Mt hp cht hu c Y khi t chy thu c CO2 v H2O c s mol bng nhau v lng oxi cn dng bng 4 ln s mol ca Y. Cng thc phn t ca Y l : A. C2H6O. B. C4H8O. C. C3H6O. D. C3H6O2. Cu 148: t chy hon ton mt hp cht hu c n chc X thu c sn phm chy ch g m CO2 v H2O vi t l kh i lng tng ng l 44 : 27. Cng thc phn t ca X l : A. C2H6. B. C2H6O. C. C2H6O2. D. C2H4O. Cu 149: Trong mt bnh kn cha hi este no, n chc, mch h A (CnH2nO2) v mt lng O2 gp i lng O2 cn thit t chy ht A nhit 140oC v p sut 0,8 atm. t chy hon ton A ri a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. A c cng thc phn t l : A. C2H4O2. B. C3H6O2. C. C4H8O2. D. C5H10O2. Cu 150: Trn mt hirocacbon X vi lng O2 va t chy ht X, c hn hp A 0oC v p sut P1. t chy hon ton X, thu c hn hp sn phm B 218,4oC c p sut P2 gp 2 ln p sut P1. Cng thc phn t ca X l : A. C4H10. B. C2H6. C. C3H6. D. C3H8. Cu 151: t chy hon ton 1 mol cht X cn 5,5 mol O2, thu c CO2 v hi nc vi tng s mol bng 9. CTPT ca X l : A. C4H10O. B. C4H10O2. C. C4H10O3. D. C4H10. 16 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 152: Mt hp cht hu c g m C, H, O ; trong cacbon chim 61,22% v kh i lng. Cng thc phn t ca hp cht l : A. C3H6O2. B. C2H2O3. C. C5H6O2. D. C4H10O. Cu 153: t chy hon ton 1,18 gam cht Y (CxHyN) bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH)2 d, thu c 6 gam kt ta. Cng thc phn t ca Y l : A. C2H7N. B. C3H9N. C. C4H11N. D. C4H9N. Cu 154*: Khi t chy hon ton 15 miligam cht A ch thu c kh CO2 v hi nc, tng th tch ca chng quy v iu kin tiu chun l 22,4 mililt. Cng thc n gin nht ca A l : A. CH2. B. CH2O. C. CH3O. D. C3H4. Cu 155: Mt hp cht hu c A g m C, H, O c 50% oxi v kh i lng. Cng thc phn t ca A l : A. CH2O2. B. CH2O. C. CH4O. D. C3H4O.
CHUYN 2 :
HIROCACBON NO
BI TP TRC NGHIM V ANKAN
Cu 1: Trong cc nhn xt di y, nhn xt no sai ? A. Tt c cc ankan u c cng thc phn t CnH2n+2. B. Tt c cc cht c cng thc phn t CnH2n+2 u l ankan. C. Tt c cc ankan u ch c lin kt n trong phn t . D. Tt c cc cht ch c lin kt n trong phn t u l ankan. Cu 2: C bao nhiu ng phn cu to c cng thc phn t l C5H12 ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn. Cu 3: C bao nhiu ng phn cu to c cng thc phn t l C6H14 ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn. Cu 4: C bao nhiu ng phn cu to c cng thc phn t l C4H9Cl ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn. Cu 5: C bao nhiu ng phn cu to c cng thc phn t l C5H11Cl ? A. 6 ng phn. B. 7 ng phn. C. 5 ng phn. D. 8 ng phn. Cu 6: Hp cht X c cng thc cu t o thu gn nht l : Hy cho bit trong phn t X cc nguyn t C dng bao nhiu electron ho tr to lin kt CH. A. 10. B. 16. C. 14. D. 12. Cu 7: Phn trm kh i lng cacbon trong phn t ankan Y bng 83,33%. Cng thc phn t ca Y l : A. C2H6. B. C3H8. C. C4H10. D. C5H12. Cu 8: Cng thc n gin nht ca hirocacbon M l CnH2n+1. M thuc dy ng ng no ? A. ankan. B. khng d kin xc nh. C. ankan hoc xicloankan. D. xicloankan. Cu 9: Cho cc ankan sau :
CH 3 CH CH 2 CH 3 (1) | CH 3
CH 3 | CH 3 C CH 3 (2) | CH 3
CH 3 CH CH 3 | CH 3
(3)
CH 3 CH 3 CH 2 CH 3 (4)
CH 3 | CH 3 C CH 2 CH 3 (5) | CH 3
Tn thng thng ca cc ankan sau y c tn tng ng l : A. (1) : iso-pentan ; (2) : tert-butan ; (3) : iso-propan ; (4) : n-butan ; (5) : neo-hexan. B. (1) : iso-pentan ; (2) : neo-pentan ; (3) : iso-propan ; (4) : n-butan ; (5) : neo-hexan. C. (1) : iso-pentan ; (2) : neo-pentan ; (3) : sec-propan ; (4) : n-butan ; (5) : neo-hexan. D. (1) : iso-pentan ; (2) : neo-pentan ; (3) : iso-butan ; (4) : n-butan ; (5) : neo-hexan. 18 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 10: Cho cc cht : (X) (Y) (P) Tn thng thng ca cc ankan sau y c tn tng ng l : A. (X) : iso-butan ; (Y) : n-butan ; (P) : iso-butan ; (Q) : n-pentan. B. (X) : iso-pentan ; (Y) : n-butan ; (P) : iso-propan ; (Q) : n-pentan. C. (X) : iso-pentan ; (Y) : n-butan ; (P) : iso-butan ; (Q) : n-hexan. D. (X) : iso-pentan ; (Y) : n-butan ; (P) : iso-butan ; (Q) : n-pentan. Cu 11: Ankan CH3 CH CH 2 CH CH 2 CH 2 CH 3 c tn ca X l : | | CH3 CH3 A. 1,1,3-trimetylheptan. B. 2,4-imetylheptan. C. 2-metyl-4-propylpentan. D. 4,6-imetylheptan. Cu 12: Ankan CH3 CH CH CH3 c tn l : | | CH3 C 2 H5 A. 3,4-imetylpentan. B. 2,3-imetylpentan. C. 2-metyl-3-etylbutan. D. 2-etyl-3-metylbutan. Cu 13: Ankan CH 3 CH 2 CH CH 2 CH3 c tn l : | CH CH3 | CH3 A. 3- isopropylpentan. C. 3-etyl-2-metylpentan. B. 2-metyl-3-etylpentan. D. 3-etyl-4-metylpentan. (Q)
C 2H5 | Cu 14: Ankan CH 3 C CH 2 CH CH 2 CH 3 c tn l : | | CH 3 CH 3
B. 2,4-ietyl-2-metylhexan. D. 3-etyl-5,5-imetylheptan. C2H5 | Cu 15: Tn gi ca cht hu c X c CTCT : CH 3 CH CH CH3 l : | Cl A. 3-etyl-2-clobutan. C. 2-clo-3-etylpentan. B. 2-clo-3-metylpetan. D. 3-metyl-2-clopentan.
A. 2-metyl-2,4-ietylhexan. C. 3,3,5-trimetylheptan.
Cu 16: Tn gi ca cht hu c X c CTCT : CH 3 CH CH CH 2 CH 3 l : | | NO2 CH3 A. 4-metyl-3-nitropentan. C. 2-metyl-3-nitropentan. B. 3-nitro-4-metylpetan. D. 2-nitro-3-metylpentan.
Cu 17: Tn gi cu cht hu c X c CTCT : CH 3 CH CH CH 2 CH 3 l : | | NO2 Cl A. 3-clo-2-nitropentan. B. 2-nitro-3-clopetan. C. 3-clo-4-nitropentan. D. 4-nitro-3-clopentan. Cu 18: Cho ankan c CTCT l: (CH3)2CHCH2C(CH3)3. Tn gi ca ankan l : A. 2,2,4-trimetylpentan. B. 2,4-trimetylpetan. C. 2,4,4-trimetylpentan. D. 2-imetyl-4-metylpentan. Cu 19: Hp cht hu c X c tn gi l: 2-clo-3-metylpentan. Cng thc cu to ca X l: A. CH3CH2CH(Cl)CH(CH3)2. B. CH3CH(Cl)CH(CH3)CH2CH3. D. CH3CH(Cl)CH3CH(CH3)CH3. C. CH3CH2CH(CH3)CH2CH2Cl. Cu 20: 2,2,3,3-tetrametylbutan c bao nhiu nguyn t C v H trong phn t ? A. 8C,16H. B. 8C,14H. C. 6C, 12H. D. 8C,18H. Cu 21: Hp cht 2,2-imetylpropan c th t o thnh bao nhiu gc ha tr I ? A. 1 gc. B. 4 gc. C. 2 gc. D. 3 gc. Cu 22: Hp cht 2,3-imetylbutan c th to thnh bao nhiu gc ha tr I ? A. 6 gc. B. 4 gc. C. 2 gc. D. 5 gc. Cu 23: S gc ankyl ha tr I t o ra t isopentan l : A. 3. B. 4. C. 5. D. 6. Cu 24: Cc gc ankyl sau y c tn tng ng l :
CH 3 CH CH 2 (1) | CH 3
CH 3 CH CH 2 CH 3 (4) |
CH 3 | CH 3 C | CH 3 (2)
CH 3 CH (3) | CH 3
CH 3 CH 2 CH 2 CH 2 (5)
A. (1) : iso-butyl ; (2) : tert-butyl ; (3) : sec-propyl ; (4) : sec-butyl ; (5) : n-butyl. B. (1) : iso-butyl ; (2) : neo-butyl ; (3) : iso-propyl ; (4) : sec-butyl ; (5) : n-butyl. C. (1) : sec-butyl ; (2) : tert-butyl ; (3) : iso-propyl ; (4) : iso-butyl ; (5) : n-butyl. D. (1) : iso-butyl ; (2) : tert-butyl ; (3) : iso-propyl ; (4) : sec-butyl ; (5) : n-butyl. Cu 25: Ankan ha tan tt trong dung mi no sau y ? A. Nc. B. Benzen. C. Dung dch axit HCl. D. Dung d ch NaOH. Cu 26: Phn t metan khng tan trong nc v l do no sau y ? A. Metan l cht kh. B. Phn t metan khng phn cc. C. Metan khng c lin kt i. D. Phn t khi ca metan nh. Cu 27: iu kin thng hirocacbon no sau y th kh ? A. C4H10. B. CH4, C2H6. C. C3H8. D. C A, B, C. Cu 28: Trong cc cht di y, cht no c nhit si thp nht ? A. Butan. B. Etan. C. Metan. D. Propan.
Cu 29: Cho cc cht sau : C2H6 (I) C3H8 (II) n-C4H10 (III) i-C4H10 (IV) Nhit si tng dn theo dy l : A. (III) < (IV) < (II) < (I). B. (III) < (IV) < (II) < (I). C. (I) < (II) < (IV) < (III). D. (I) < (II) < (III) < (IV). Cu 30: Trong s cc ankan ng phn ca nhau, ng phn no c nhit si cao nht ? A. ng phn mch khng nhnh. B. ng phn mch phn nhnh nhiu nht. C. ng phn isoankan. D. ng phn tert-ankan. Cu 31: Cho cc cht sau : CH3CH2CH2CH2CH3 (I) CH3 CH 2 CH CH3 (II) | CH3 Th t tng dn nhit si ca cc cht l : A. I < II < III. B. II < I < III. Cu 32: Cho cc cht : CH3 C CH3 (III)
| CH3 CH3 |
C. III < II < I.
D. II < III < I.
CH3 CH2 CH CH2 CH3 (I) | CH3 CH3 CH2 CH CH3 (III) | CH3
Th t tng dn nhit si ca cc cht l : A. I < II < III. B. II < I < III. Cu 33: Cho cc cht sau : CH3CH2CH2CH3 (I) CH3 CH CH CH3 (III) | | CH3 CH3
CH3 | CH 3 C CH3 (II) | CH3
C. III < II < I.
D. II < III < I.
CH3CH2CH2CH2CH2CH3 (II) CH3 CH2 CH CH3 (IV) | CH3
Th t gim dn nhit nng chy ca cc cht l : A. I > II > III > IV. B. II > III > IV > I. C. III > IV > II > I. D. IV > II > III > I. Cu 34: Phn ng c trng ca hirocacbon no l : A. Phn ng tch. B. Phn ng th. C. Phn ng cng. D. C A, B v C. Cu 35: Cc ankan khng tham gia loi phn ng no ? A. Phn ng th. B. Phn ng cng. C. Phn ng tch. D. Phn ng chy. Cu 36: Sn phm ca phn ng th clo (1:1, nh sng) vo 2,2-imetylpropan l : (1) CH3C(CH3)2CH2Cl (2) CH3C(CH2Cl)2CH3 (3) CH3ClC(CH3)3 A. (1) ; (2). B. (2) ; (3). C. (2). D. (1).
Cu 37: Khi cho 2-metylbutan tc dng vi Cl2 theo t l mol 1:1 th to ra sn phm chnh l : A. 1-clo-2-metylbutan. B. 2-clo-2-metylbutan. C. 2-clo-3-metylbutan. D. 1-clo-3-metylbutan. Cu 38: Cho iso-pentan tc dng vi Br2 theo t l 1 : 1 v s mol trong iu kin nh sng khuch tn thu c sn phm chnh monobrom c cng thc cu to l : B. (CH3)2CHCH2CH2Br. A. CH3CHBrCH(CH3)2. C. CH3CH2CBr(CH3)2. D. CH3CH(CH3)CH2Br. Cu 39: Cho hn hp iso-hexan v Cl2 theo t l mol 1 : 1 ngoi nh sng th thu c sn phm chnh monobrom c cng thc cu to l : A. CH3CH2CH2CCl(CH3)2. B. CH3CH2CHClCH(CH3)2. C. (CH3)2CHCH2CH2CH2Cl. D. CH3CH2CH2CH(CH3)CH2Cl. Cu 40: Cho neo-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l : A. 2. B. 3. C. 5. D. 1. Cu 41: Hp cht Y c cng thc cu t o : CH3 CH CH2 CH3
CH3
Y c th t o c bao nhiu dn xut monohalogen ng phn ca nhau ? A. 3. B. 4. C. 5. D. 6. Cu 42: Iso-hexan tc dng vi clo (c chiu sng) c th to ti a bao nhiu dn xut monoclo ? A. 3. B. 4. C. 5. D. 6. Cu 43: Khi clo ha C5H12 vi t l mol 1:1 thu c 3 sn phm th monoclo. Danh php IUPAC ca ankan l : A. 2,2-imetylpropan. B. 2-metylbutan. C. pentan. D. 2-imetylpropan. Cu 44: khi clo ha mt ankan c cng thc phn t C6H14, ngi ta ch thu c 2 sn phm th monoclo. Danh php IUPAC ca ankan l : A. 2,2-imetylbutan. B. 2-metylpentan. C. n-hexan. D. 2,3-imetylbutan. Cu 45: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t . t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l : A. 3. B. 4. C. 2. D. 5. Cu 46: Khi clo ha hn hp 2 ankan, ngi ta ch thu c 3 sn phm th monoclo. Tn gi ca 2 ankan l : A. etan v propan. B. propan v iso-butan. C. iso-butan v n-pentan. D. neo-pentan v etan. Cu 47: Ankan no sau y ch cho 1 sn phm th duy nht khi tc dng vi Cl2 (as) theo t l mol (1 : 1): CH3CH2CH3 (a), CH4 (b), CH3C(CH3)2CH3 (c), CH3CH3 (d), CH3CH(CH3)CH3 (e) A. (a), (e), (d). B. (b), (c), (d). C. (c), (d), (e). D. (a), (b), (c), (e), (d).
Cu 48: C bao nhiu ankan l cht kh iu kin thng khi phn ng vi clo (c nh sng, t l mol 1:1) to ra 2 dn xut monoclo ? A. 4. B. 2. C. 5. D. 3. Cu 49: Dy ankan no sau y tha mn iu kin : m i cng thc phn t c mt ng phn khi tc dng vi clo theo t l mol 1 : 1 to ra 1 dn xut monocloankan duy nht ? A. CH4, C3H8, C4H10, C6H14. B. CH4, C2H6, C5H12, C8H18. C. CH4, C4H10, C5H12, C6H14. D. CH4, C2H6, C5H12, C4H10. Cu 50: Khi clo ha mt ankan thu c hn hp 2 dn xut monoclo v 4 dn xut iclo. Cng thc cu to ca ankan l : A. CH3CH2CH3. B. (CH3)2CHCH2CH2CH3. C. (CH3)2CHCH2CH3. D. CH3CH2CH2CH3. Cu 51: Khi clo ha mt ankan thu c hn hp 3 dn xut monoclo v 7 dn xut iclo. Cng thc cu to ca ankan l : A. CH3CH2CH2CH2CH2CH3. B. (CH3)2CHCH2CH2CH3. C. (CH3)3CCH2CH3. D. (CH3)2CHCH(CH3)2. Cu 52: Khi thc hin phn ng hiro ha hp cht X c CTPT C5H12 thu c hn hp 3 anken ng phn cu to ca nhau. Vy tn ca X l : A. 2,2-imetylpentan. B. 2-metylbutan. C. 2,2-imetylpropan. D. pentan. Cu 53: t chy mt hn hp g m nhiu hirocacbon trong cng mt dy ng ng nu ta thu c s mol H2O > s mol CO2 th CTPT chung ca dy l : A. CnHn, n 2. B. CnH2n+2, n 1 (cc gi tr n u nguyn). C. CnH2n-2, n 2. D. Tt c u sai. Cu 54: t chy cc hirocacbon ca dy ng ng no di y th t l mol H2O : mol CO2 gim khi s cacbon tng. A. ankan. B. anken. C. ankin. D. aren Cu 55: Khi t chy ankan thu c H2O v CO2 vi t l tng ng bin i nh sau : A. tng t 2 n + . B. gim t 2 n 1. C. tng t 1 n 2. D. gim t 1 n 0. Cu 56: Khng th iu ch CH4 bng phn ng no ? A. Nung mui natri malonat vi vi ti xt. B. Canxicacbua tc dng vi nc. C. Nung natri axetat vi vi ti xt. D. Nhm cacbua tc dng vi nc. Cu 57: Trong phng th nghim c th iu ch metan bng cch no sau y ? A. Nhit phn natri axetat vi vi ti xt. B. Crackinh butan. C. T phn ng ca nhm cacbua vi nc. D. A, C. Cu 58: Thnh phn chnh ca kh thin nhin l : A. metan. B. etan. C. propan. D. n-butan.
Cu 59: Trong cc phng trnh ha hc : Al4C3 C4H10 + 12H2O
3CH4 + 4Al(OH)3
C3H6 +
o o
(1) (2) (3) (4)

Crackinh
CH4
CH3COONa + NaOH
CaO, t CH4 + Na2CO3 CaO, t CH4 + 2Na2CO3
CH2(COONa)2 + 2NaOH
CH4 + NaOH + CO2 + H2 + H2O (5) CH3COONa Cc phng trnh ha hc vit sai l : A. (2), (5), (4). B. (2), (3), (4). C. (2), (3), (5). D. (5). Cu 60: Phn ng no sau y iu ch c CH4 tinh khit hn ?
pdd
A. Al4C3
+ 12H2O
3CH4 + 4Al(OH)3
o
CaO, t B. CH3COONa (rn) + NaOH (rn) CH4 + Na2CO3 Crackinh C. C4H10 C3H6 + CH4 Ni, t D. C + 2H2 CH4 Cu 61: Ankan Y phn ng vi brom to ra 2 dn xut monobrom c t kh i hi so vi H2 bng 61,5. Tn ca Y l : A. butan. B. propan. C. Iso-butan. D. 2-metylbutan. Cu 62: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t kh i hi i vi hiro l 75,5. Tn ca ankan l : A. 3,3-imetylhecxan. C. isopentan. B. 2,2-imetylpropan. D. 2,2,3-trimetylpentan Cu 63: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l : A. 3-metylpentan. B. 2,3-imetylbutan. C. 2-metylpropan. D. butan. Cu 64: Khi clo ha metan thu c mt sn phm th cha 89,12% clo v kh i lng. Cng thc ca sn phm l : A. CH3Cl. B. CH2Cl2. C. CHCl3. D. CCl4. Cu 65: Khi tin hnh phn ng th gia ankan X vi kh clo c chiu sng ngi ta thu c h n hp Y ch cha hai cht sn phm. T khi hi ca Y so vi hiro l 35,75. Tn ca X l : A. 2,2-imetylpropan. B. 2-metylbutan. C. pentan. D. etan. Cu 66: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t kh i ca Y so vi H2 bng 12. Cng thc phn t ca X l : A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 67: Khi crackinh hon ton mt ankan X thu c hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t kh i ca Y so vi H2 bng 14,5. Cng thc phn t ca X l : A. C6H14. B. C3H8. C. C4H10. D. C5H12 Cu 68: Craking 8,8 gam propan thu c hn hp A g m H2, CH4, C2H4, C3H6 v mt phn propan cha b craking. Bit hiu sut phn ng l 90%. Kh i lng phn t trung bnh ca A l : A. 39,6. B. 23,16. C. 2,315. D. 3,96.
o
Cu 69: Craking 40 lt n-butan thu c 56 lt hn hp A g m H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn n-butan cha b craking (cc th tch kh o cng iu kin nhit v p sut). Gi s ch c cc phn ng to ra cc sn phm trn. Hiu sut phn ng to hn hp A l : A. 40%. B. 20%. C. 80%. D. 60%. Cu 70: Craking n-butan thu c 35 mol hn hp A g m H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn butan cha b craking. Gi s ch c cc phn ng to ra cc sn phm trn. Cho A qua bnh nc brom d thy cn li 20 mol kh. Nu t chy hon ton A th thu c x mol CO2. a. Hiu sut phn ng to hn hp A l : A. 57,14%. B. 75,00%. C. 42,86%. D. 25,00%. b. Gi tr ca x l : A. 140. B. 70. C. 80. D. 40. Cu 71: Cho etan qua xc ( nhit cao) thu c mt hn hp X g m etan, etilen, axetilen v H2. T kh i ca hn hp X i vi etan l 0,4. Hy cho bit nu cho 0,4 mol hn hp X qua dung dch Br2 d th s mol Br2 phn ng l bao nhiu ? A. 0,24 mol. B. 0,16 mol. C. 0,40 mol. D. 0,32 mol. Cu 72: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6, H2. T kh i ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l : A. 0,48 mol. B. 0,36 mol. C. 0,60 mol. D. 0,24 mol. Cu 73: Khi t chy hon ton V lt hn hp kh g m CH4, C2H6, C3H8 (ktc) thu c 44 gam CO2 v 28,8 gam H2O. Gi tr ca V l : A. 8,96. B. 11,20. C. 13,44. D. 15,68. Cu 74: Khi t chy hon ton 7,84 lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 16,8 lt kh CO2 (ktc) v x gam H2O. Gi tr ca x l : A. 6,3. B. 13,5. C. 18,0. D. 19,8. Cu 75: t chy hon ton 2,24 lt hn hp A (ktc) gm CH4, C2H6 v C3H8 thu c V lt kh CO2 (ktc) v 7,2 gam H2O. Gi tr ca V l : A. 5,60. B. 6,72. C. 4,48. D. 2,24. Cu 76: Oxi ho hon ton 0,1 mol hn hp X gm 2 ankan. Sn phm thu c cho i qua bnh (1) ng H2SO4 c, bnh (2) ng dung dch Ba(OH)2 d th kh i lng ca bnh (1) tng 6,3 gam v bnh (2) c m gam kt ta xut hin. Gi tr ca m l : A. 68,95 gam. B. 59,1 gam. C. 49,25 gam. D. Kt qu khc. Cu 77: t chy hon ton 6,72 lt hn hp A (ktc) gm CH4, C2H6, C3H8, C2H4 v C3H6, thu c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Tng th tch ca C2H4 v C3H6 (ktc) trong hn hp A l : A. 5,60. B. 3,36. C. 4,48. D. 2,24. Cu 78: t chy hon ton hn hp A g m CH4, C2H2, C3H4, C4H6 thu c x mol CO2 v 18x gam H2O. Phn trm th tch ca CH4 trong A l : A. 30%. B. 40%. C. 50%. D. 60%. Cu 79: t chy hon ton m gam hn hp X gm hai hirocacbon thuc cng dy ng ng c n dng 6,16 lt O2 v thu c 3,36 lt CO2. Gi tr ca m l : A. 2,3 gam. B. 23 gam. C. 3,2 gam. D. 32 gam. Cu 80: t chy mt hn hp hirocacbon ta thu c 2,24 lt CO2 (ktc) v 2,7 gam H2O th th tch O2 tham gia phn ng chy (ktc) l : A. 5,6 lt. B. 2,8 lt. C. 4,48 lt. D. 3,92 lt.
Cu 81: t chy hon ton mt th tch kh thin nhin g m metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l : A. 70,0 lt. B. 78,4 lt. C. 84,0 lt. D. 56,0 lt. Cu 82: Craking m gam n-butan thu c hp A g m H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn butan cha b craking. t chy hon ton A thu c 9 gam H2O v 17,6 gam CO2. Gi tr ca m l : A. 5,8. B. 11,6. C. 2,6. D. 23,2. Cu 83: Khi tin hnh craking 22,4 lt kh C4H10 (ktc) thu c hn hp A g m CH4, C2H6, C2H4, C3H6, C4H8, H2 v C4H10 d. t chy hon ton A thu c x gam CO2 v y gam H2O. Gi tr ca x v y tng ng l : A. 176 v 180. B. 44 v 18. C. 44 v 72. D. 176 v 90. Cu 84: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc) cha 12% C2H2 ;10% CH4 ; 78%H2 (v th tch). Gi s ch xy ra 2 phn ng : 2CH4 C2H2 + 3H2 (1) CH4 C + 2H2 (2) Gi tr ca V l : A. 407,27. B. 448,00. C. 520,18. D. 472,64. Cu 85: Trn 2 th tch bng nhau ca C3H8 v O2 ri bt tia la in t chy hn hp. Sau ph n ng lm lnh hn hp ( hi nc ngng t) ri a v iu kin ban u. Th tch hn hp s n phm khi y (V2) so vi th tch hn hp ban u (V1) l : A. V2 = V1. B. V2 > V1. C. V2 = 0,5V1. D. V2 : V1 = 7:10. Cu 86: Hn hp kh A g m etan v propan. t chy hn hp A thu c kh CO2 v hi H2O theo t l th tch 11:15. Thnh phn % theo khi lng ca hn hp l : A. 18,52% ; 81,48%. B. 45% ; 55%. C. 28,13% ; 71,87%. D. 25% ; 75%. Cu 87: t chy 13,7 ml hn hp A g m metan, propan v cacbon (II) oxit, ta thu c 25,7 ml kh CO2 cng iu kin nhit v p sut. Thnh phn % th tch propan trong hn hp A v kh i lng phn t trung bnh ca hn hp A so vi nit l : A. 43,8% ; bng 1. B. 43,8 % ; nh hn 1. C. 43,8 % ; ln hn 1. D. 87,6 % ; nh hn 1. Cu 88: n gin ta xem xng l hn hp cc ng phn ca hexan v khng kh gm 80% N2 v 20% O2 (theo th tch). T l th tch xng (hi) v khng kh cn ly l bao nhiu xng c chy hon ton trong cc ng c t trong ? A. 1 : 9,5. B. 1 : 47,5. C. 1 : 48. D. 1 : 50 Cu 89: t chy hon ton mt hirocacbon X thu c 6,72 lt CO2 (ktc) v 7,2 gam nc. Cng thc phn t ca X l : A. C2H6. B. C3H8. C. C4H10. D. CH4. Cu 90: oxi ha hon ton m gam mt hirocacbon X cn 17,92 lt O2 (ktc), thu c 11,2 lt CO2 (ktc). CTPT ca X l : B. C4H10. C. C5H12. D. C2H6. A. C3H8. Cu 91: Np mt hn hp kh c 20% th tch ankan A v 80% th tch O2 (d) vo kh nhin k. Sau khi cho n ri cho hi nc ngng t nhit ban u th p sut trong kh nhin k gim i 2 ln. Cng thc phn t ca ankan A l : A. CH4. B. C2H6. C. C3H8 . D. C4H10. 26 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 92: Hirocacbon X chy cho th tch hi nc gp 1,2 ln th tch CO2 (o cng k). Khi tc dng vi clo to mt dn xut monoclo duy nht. X c tn l : A. isobutan. B. propan. C. etan. D. 2,2- imetylpropan. Cu 93: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo thu c 4 sn phm monoclo. Tn gi ca X l : A. 2-metylbutan. B. etan. C. 2,2-imetylpropan. D. 2-metylpropan. Cu 94: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm chy vo nc vi trong c 20 gam kt ta. Lc b kt ta ri un nng phn nc l c li c 10 gam kt ta na. Vy X khng th l : A. C2H6. B. C2H4. C. CH4. D. C2H2. Cu 95: t chy hon ton mt hirocacbon A. Sn phm thu c hp th hon ton vo 200 ml dung dch Ca(OH)2 0,2M thy thu c 3 gam kt ta. Lc b kt ta cn li phn dung dch thy kh i lng tng ln so vi ban u l 0,28 gam. Hirocacbon trn c CTPT l : A. CH4. B. C2H6. C. C3H8 . D. C4H10. Cu 96: t chy hon ton A. gam hp cht hu c A. Sn phm thu c hp th vo nc vi trong d th to ra 4 gam kt ta. Lc kt ta cn li bnh thy kh i lng bnh nc vi trong gi m 1,376 gam. A c cng thc phn t l : A. CH4. B. C5H12. C. C3H8 . D. C4H10. Cu 97: Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: nA : nB = 1 : 4. Kh i lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan A v B ln lt l : B. C5H12 v C6H14. C. C2H6 v C3H8. D. C4H10 v C3H8 A. C2H6 v C4H10. Cu 98: Mt hn hp 2 ankan lin tip trong dy ng ng c t kh i hi vi H2 l 24,8. a. Cng thc phn t ca 2 ankan l : A. C2H6 v C3H8. B. C4H10 v C5H12. C. C3H8 v C4H10. D. Kt qu khc. b. Thnh phn phn trm v th tch ca 2 ankan l : A. 30% v 70%. B. 35% v 65%. C. 60% v 40%. D. 50% v 50%. Cu 99: t chy hon ton hn hp X gm hai ankan k tip trong dy ng ng c 24,2 gam CO2 v 12,6 gam H2O. Cng thc phn t 2 ankan l : A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12 Cu 100: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c 7,84 lt kh CO2 (ktc) v 9,0 gam H2O. Cng thc phn t ca 2 ankan l : A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12. Cu 101: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng ng k tip cn dng 85,12 lt O2 (ktc), thu c 96,8 gam CO2 v m gam H2O. Cng thc phn t ca A v B l : A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12. Cu 102: t chy hon ton hn hp X gm 2 hirocacbon l ng ng lin tip, sau phn ng thu c VCO2 : VH2O = 1 : 1,6 (o cng k). X gm : A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H2 v C3H6. D. C3H8 v C4H10. Cu 103: Hn hp kh X g m 2 hirocacbon A v B l ng ng k tip. t chy X vi 64 gam O2 (d) ri dn sn phm thu c qua bnh ng Ca(OH)2 d thu c 100 gam kt ta. Kh ra kh i bnh c th tch 11,2 lt 0oC v 0,4 atm. Cng thc phn t ca A v B l : A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12
Cu 104: t chy hon ton hn hp g m hai hirocacbon c phn t lng km nhau 14 vC c m gam H2O v 2m gam CO2. Hai hirocacbon ny l : A. 2 anken. B. C4H10 v C5H12. C. C2H2 v C3H4. D. C6H6 v C7H8. Cu 105: t chy hon ton hn hp hai hirocacbon ng ng c khi lng phn t hn km nhau 28 vC, ta thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. CTPT ca 2 hirocacbon trn l : A. C2H4 v C4H8. B. C2H2 v C4H6. C. C3H4 v C5H8. D. CH4 v C3H8. Cu 106: Hn hp kh g m 2 hirocacbon no A v B thuc cng dy ng ng, c t kh i i v i H2 l 12. a. Kh i lng CO2 v hi H2O sinh ra khi t chy 15,68 lt hn hp ( ktc). A. 24,2 gam v 16,2 gam. B. 48,4 gam v 32,4 gam. C. 40 gam v 30 gam. D. Kt qu khc. b. Cng thc phn t ca A v B l : A. CH4 v C2H6. B. CH4 v C3H8. C. CH4 v C4H10. D. C A, B v C. Cu 107: X l hn hp 2 ankan. t chy ht 10,2 gam X cn 25,76 lt O2 (ktc). Hp th ton b sn phm chy vo nc vi trong d c m gam kt ta. a. Gi tr m l : A. 30,8 gam. B. 70 gam. C. 55 gam. D. 15 gam b. Cng thc phn t ca A v B l : A. CH4 v C4H10. B. C2H6 v C4H10. C. C3H8 v C4H10. D. C A, B v C. Cu 108: t chy hon ton hn hp X g m hai hirocacbon thuc cng dy ng ng r i hp th ht sn phm chy vo bnh ng nc vi trong d thu c 25 gam kt ta v kh i lng nc vi trong gim 7,7 gam. CTPT ca hai hirocacon trong X l : B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12. A. CH4 v C2H6. Cu 109: Hn hp X g m hai hirocacbon thuc cng dy ng ng. t chy hon ton hn hp X, sn phm chy thu c cho l i qua bnh (1) ng H2SO4 c, sau qua bnh (2) ng 250 ml dung dch Ca(OH)2 1M. Khi kt thc phn ng, kh i lng bnh (1) tng 8,1 gam v bnh (2) c 15 gam kt ta xut hin. CTPT ca hai hirocacbon trong X l : A. CH4 v C4H10. B. C2H6 v C4H10. C. C3H8 v C4H10. D. A hoc B hoc C. Cu 110: t chy hon ton hn hp 2 hirocacbon c kh i lng phn t hn km nhau 28 vC. Sn phm c hp th ton b vo nc vi trong d thu c 65 gam kt ta, lc kt ta thy kh i lng dung dch gim so vi ban u 22 gam. Hai hirocacbon thuc h : A. Xicloankan. B. Anken. C. Ankin. D. Ankan. Cu 111: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v t l s mol nc v CO2 i vi K, L, M tng ng l 0,5 : 1 : 1,5. Xc nh CT K, L, M (vit theo th t tng ng) : A. C2H4, C2H6, C3H4. B. C3H8, C3H4, C2H4. C. C3H4, C3H6, C3H8. D. C2H2, C2H4, C2H6. Cu 112: Nung m gam hn hp X g m 3 mu i natri ca 3 axit hu c no, n chc vi NaOH d, thu ccht rn D v hn hp Y g m 3 ankan. T kh i ca Y so vi H2 l 11,5. Cho D tc dng vi H2SO4 d thu c 17,92 lt CO2 (ktc). a. Gi tr ca m l : A. 42,0. B. 84,8. C. 42,4. D. 71,2. b. Tn gi ca 1 trong 3 ankan thu c l : A. metan. B. etan. C. propan. D. butan. 28 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
BI TP TRC NGHIM V XICLOANKAN

Cu 113: Hp cht X c cng thc cu t o thu gn nht l :
Hy cho bit hp cht X c bao nhiu nguyn t cacbon bc 2 ? A. 4. B. 5. C. 3. Cu 114: Cho cc cht sau :
D. 6.
CH3
(I) (II) (III) (IV) Nhng cht no l ng ng ca nhau ? A. I, III, V. B. I, II, V. C. III, IV, V. Cu 115: Hp cht X c cng thc cu t o thu gn nht l :
CH2 CH3
(V) D. II, III, V.
Hy cho bit cn bao nhiu ng phn cu to mch vng c cng thc phn t ging nh X ? A. 2. B. 5. C. 3. D. 4. Cu 116: Cho cc hp cht vng no sau : Xiclopropan (I) xiclobutan (II) xiclopentan (III) xiclohexan (IV) bn ca cc vng t ng dn theo th t no ? A. I < II < III < IV. B. III < II < I < IV. C. II < I < III < IV. D. IV < I < III < II. Cu 117: Hirocacbon X c CTPT C6H12 khng lm mt mu dung dch brom, khi tc dng v i brom t o c mt dn xut monobrom duy nht. Tn ca X l : A. metylpentan. B. 1,2-imetylxiclobutan. C. 1,3-imetylxiclobutan. D. xiclohexan. Cu 118: Xicloankan (ch c mt vng) A c t khi so vi nit bng 3. A tc dng vi clo c chiu sng ch cho mt dn xut monoclo duy nht, xc nh cng thc cu to ca A ?
CH3
CH 3
B. C. H3C D. H 3 C CH 3 . . . . Cu 119: Hai xicloankan M v N u c t kh i hi so vi metan bng 5,25. Khi tham gia phn ng th clo (as, t l mol 1:1) M cho 4 sn phm th cn N cho 1 sn phm th. Tn g i ca cc xicloankan N v M l : A. metylxiclopentan v imetylxiclobutan. B. Xiclohexan v metylxiclopentan. C. Xiclohexan v n-propylxiclopropan. D. C A, B, C u ng. Cu 120: C bao nhiu ng phn cu to ca xicloankan c thc phn t l C5H10 phn ng c vi H2 (to, Ni) ? A. 0. B. 2. C. 3. D. 4. Cu 121: C bao nhiu ng phn cu to ca xicloankan c thc phn t l C6H12 phn ng c vi H2 (to, Ni) ? A. 8. B. 10. C. 7. D. 9.
A.
CH3
Cu 122: C bao nhiu ng phn cu to ca xicloankan c thc phn t l C5H10 lm mt mu dung dch brom ? A. 0. B. 2. C. 3. D. 4. Cu 123: C bao nhiu ng phn cu to ca xicloankan c thc phn t l C6H12 lm mt mu dung dch brom ? A. 5. B. 2. C. 3. D. 4. o Cu 124: Cho cc cht : H2 (t , Ni), Cl2 (as), dung dch HCl, dung dch Br2, dung dch KMnO4. Cho xiclopropan v xiclobutan ln lt phn ng vi cc cht trn th s xy ra bao nhiu phn ng ? A. 8. B. 6. C. 7. D. 9. Cu 125: Hp cht X l 1-etyl-2-metylxiclopropan. Cho X tc dng vi H2 (Ni, to). S sn ph m cng ti a c th to ra l : A. 2. B. 3. C. 4. D. 1. Cu 126: Cho cc cht : (X) (Y) (P) (Q) Hy cho bit cht no trn c th l sn phm ca phn ng gia metylxiclopropan vi H2 (Ni, to). A. X, Y. B. P, Q. C. X, Q. D. Y, P. Cu 127*: Hp cht X l dn xut ca monoxiclopropan (c cha vng 3 cnh). Cho X cng H2 (Ni, t o) th thu c hn hp cc sn cng phm trong c hp cht Y. Cng thc cu t o thu gn nht ca Y l : Hy cho bit c my ng phn cu to tha mn X ? A. 2. B. 4. C. 5. D. 3. Cu 128: Dn hn hp kh A g m propan v xiclopropan i vo dung dch brom s quan st c hin tng no sau y : A. Mu ca dung dch nht dn, khng c kh thot ra. B. Mu ca dung d ch nht dn, v c kh thot ra. C. Mu ca dung dch mt hn, khng cn kh thot ra. D. Mu ca dung dch khng i. Cu 129: Cho phn ng : A + Br2 BrCH2CH2CH2Br A l cht no trong phn ng sau y ? A. propan. B. 1-brompropan. C. xiclopopan. D. A v B u ng. Cu 130: Hp cht X c CTPT C3H6, X tc dng vi dung dch HBr thu c mt sn phm hu c duy nht. Vy X l : A. propen. B. propan. C. ispropen. D. xicloropan. Cu 131: Xicloankan vng khng bn c phn ng cng m vng. Hp cht X l xicloankan, khi cho X tc dng vi dung dch Br2 th sn phm thu c c cng thc cu to l : CH3CHBrCH2CHBrCH3. X s l cht no sau y ? A. metyl xiclobutan. B. etylxiclopropan. C. 1,2-imetylxiclopropan. D. 1,1-imetylxiclopropan. 30 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 132: Xicloankan vng khng bn c phn ng cng m vng. Hp cht X l xicloankan, khi cho X tc dng vi dung dch Br2 th sn phm thu c c cng thc cu to l : CH3CHBrCH2CHBrCH2CH3. X s l cht no sau y ? A. 1,2-imetylxiclobutan. B. 1-etyl-2-metylxiclopropan. C. 1,3-imetylxiclobutan. D. etylxiclobutan. Cu 133: Metylxiclopropan phn ng vi dung dch Br2 t o ra hai sn phm, cng thc ca hai sn phm l : A. CH3CHBrCHBrCH3 v CH2BrCH2CHBrCH3. B. CH2BrCH(CH3)CH2Br v CH2BrCH2CHBrCH3. C. CH2BrCH(CH3)CH2Br v CH3CHBrCHBrCH3. D. CH3CHBrCHBrCH3 v CH2BrCHBrCH2CH3. Cu 134: Cht X c cng thc phn t l C5H10. X tc dng vi dung dch Br2 thu c 2 dn xut ibrom. Vy X l cht no sau y ? A. 1,1,2-trimetyl xiclopropan. B. 1,2-imetylxiclopropan. C. 2-metylbut-2- en. D. 2-metylbut-1- en. Cu 135: Cht X c cng thc phn t l C6H12. X khng tc dng vi dung dch KMnO4, X tc dng vi dung d ch Br2 thu c 1 dn xut ibrom duy nht. Vy X l cht no sau y ? A. 1,2,3-trimetyl xiclopropan. B. 1,1,2-trimetylxiclopropan. C. 2-metylpent-2-en. D. 2-metylpent-1-en. Cu 136: Xiclohexan c th c iu ch theo s :
X + Y
+H2 Ni, t0
Cng thc cu to ca X v Y ln lt l A. CH2=CHCH=CH2 v CHCH. B. CH2=CHCH=CH2 v CH2=CH2. C. CH3CH=CHCH3 v CH3CH3. D. CH3CH=CHCH3 v CH2=CH2. Cu 137: t chy ht a gam hn hp X g m 2 monoxicloankan th thu c 3,36 lt CO2 (ktc). Gi tr ca a l : A. 2,1. B. 2,4. C. 2,6. D. 3,0. Cu 138: t chy ht hn hp X gm 2 monoxicloankan th cn a lt O2 v thu c 3,36 lt CO2. Cc th tch kh u o ktc. Gi tr ca a l : A. 2,24. B. 4,48. C. 5,04. D. 5,16. Cu 139: Hp cht X l monoxicloankan vng bn v phn t c 2 nguyn t cacbon bc 1. t chy ht 0,1 mol hp cht X th kh i lng CO2 thu c ln hn khi lng H2O l 18,2 gam. S ng phn cu to tha mn X l : A. 2. B. 3. C. 4. D. 1. Cu 140: t chy 2,14 gam hn hp A gm hp cht ankan X v xicloankan Y (t l mol tng ng l 2 : 3) th thu c 3,36 lt CO2 (ktc). S nguyn t cacbon c trong phn t ca X v Y tng ng l : A. 3 v 4. B. 3 v 3. C. 2 v 4. D. 4 v 3.
Cu 141: Hn hp A g m hp cht ankan X v xicloankan Y (t l mol tng ng l 2 : 3) c t kh i so vi H2 bng 21,4. t chy 3,36 lt hn hp A th thu c a lt CO2 (ktc). Gi tr ca a l : A. 9,86. B. 8,9 6. C. 10,08. D. 4,4 8. Cu 142: t chy ht hn hp X gm butan, xiclobutan, xiclopentan v xiclohexan th thu c 0,375 mol CO2 v 0,40 mol H2O. Phn trm kh i lng ca butan c trong hn hp X l : A. 27,358. B. 27,36. C. 31,243. D. 26,13. Cu 143: Hp cht X l hirocacbon no phn t c 5 nguyn t cacbon. Khi cho X th clo iu kin nh sng, t l mol 1:1 th ch to ra 1 sn phm th. Hn hp A gm 0,02 mol X v 1 lng hirocacbon Y. t chy ht hn hp A thu c 0,11 mol CO2 v 0,12 mol H2O. Tn gi ca X, Y tng ng l : A. neopentan v etan. B. metylxiclobutan v etan. C. neopentan v metan. D. xiclopentan v metan.
CHUYN 3 : HIROCACBON KHNG NO

BI TP TRC NGHIM V ANKEN
Cu 1: Chn khi nim ng v anken : A. Nhng hirocacbon c 1 lin kt i trong phn t l anken. B. Nhng hirocacbon mch h c 1 lin kt i trong phn t l anken. C. Anken l nhng hirocacbon c lin kt ba trong phn t. D. Anken l nhng hirocacbon mch h c lin kt ba trong phn t. Cu 2: Hp cht C5H10 mch h c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 3: Hp cht C5H10 c bao nhiu ng phn anken ? A. 4. B. 5. C. 6. D. 7. Cu 4: S ng phn ca C4H8 l : A. 7. B. 4. C. 6. D. 5. Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 6: Hirocacbon A th tch iu kin thng, cng thc phn t c dng Cx+1H3x. Cng thc phn t ca A l : A. CH4. B. C2H6. C. C3H6. D. C4H8. Cu 7: Anken X c c im : Trong phn t c 8 lin kt xch ma. CTPT ca X l : A. C2H4. B. C4H8. C. C3H6. D. C5H10. Cu 8: Tng s lin kt n trong mt phn t anken (cng thc chung CnH2n) l : A. 3n. B. 3n +1. C. 3n2. D. 4n. Cu 9: Ba hirocacbon X, Y, Z l ng ng k tip, kh i lng phn t ca Z bng 2 ln kh i lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankin. B. ankan. C. ankaien. D. anken. Cu 10: Nhng hp cht no sau y c ng phn hnh hc (cis-trans) ? (I) CH3CH=CH2 (II) CH3CH=CHCl (III) CH3CH=C(CH3)2 (IV) C2H5C(CH3)=C(CH3)C2H5 (V) C2H5C(CH3)=CClCH3 A. (I), (IV), (V). B. (II), (IV), (V). C. (III), (IV). D. (II), III, (IV), (V). Cu 11: Cho cc cht sau : (I) CH2=CHCH2CH2CH=CH2 (II) CH2=CHCH=CHCH2CH3 (III) CH3C(CH3)=CHCH2 (VI) CH2=CHCH2CH=CH2 (VI) CH3C(CH3)=CHCH2CH3 (V) CH3CH2CH=CHCH2CH3 (VII) CH3CH=CHCH3 (VIII) CH3CH2C(CH3)=C(C2H5)CH(CH3)2 S cht c ng phn hnh hc l : A. 4. B. 1. C. 2. D. 3. Cu 12: Hp cht no sau y c ng phn hnh hc ? A. 2-metylbut-2-en. B. 2-clo-but-1-en. C. 2,3-iclobut-2-en. D. 2,3-imetylpent-2-en.
Cu 13: Cho cc cht sau : (1) 2-metylbut-1-en (2) 3,3-imetylbut-1-en (3) 3-metylpent-1-en (4) 3-metylpent-2-en Nhng cht no l ng phn ca nhau ? A. (3) v (4). B. (1), (2) v (3). C. (1) v (2). D. (2), (3) v (4). Cu 14: Anken X c cng thc cu t o: CH3CH2C(CH3)=CHCH3. Tn ca X l : A. isohexan. B. 3-metylpent-3-en. C. 3-metylpent-2-en. D. 2-etylbut-2-en. Cu 15: Hp cht 2,4-imeylhex-1-en ng vi CTCT no di y ? A. CH 3 CH CH 2 CH CH = CH 2 . B. CH 3 CH CH 2 C = CH 2 . | | | | CH3 CH 3 C 2 H5 CH 3 C. CH 3 CH 2 CH CH CH = CH 2 . | | CH 3 CH 3 D. CH 3 CH CH 2 CH 2 C = CH 2 . | | CH 3 CH 3
Cu 16: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, t o), cho cng mt sn phm l : A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis -but-2-en v xiclobutan. Cu 17: Hai cht X, Y c CTPT C3H6 v C4H8 v u tc dng c vi nc brom. X, Y l : A. Hai anken hoc xicloankan vng 3 cnh. C. Hai anken hoc xicloankan vng 4 cnh. B. Hai anken hoc hai ankan. D. Hai anken ng ng ca nhau. Cu 18: C hai ng nghim, m i ng cha 1 ml dung dch brom trong nc c mu vng nht. Thm vo ng th nht 1 ml hexan v ng th hai 1 ml hex-1-en. Lc u c hai ng nghim, sau yn hai ng nghim trong vi pht. Hin tng quan st c l : A. C s tch lp cc cht lng c hai ng nghim. B. Mu vng nht vn khng i ng nghim th nht C. ng nghim th hai c hai lp cht lng u khng mu. D. A, B, C u ng. Cu 19: p dng quy tc Maccopnhicop vo trng hp no sau y ? A. Phn ng cng ca Br2 vi anken i xng. C. Phn ng cng ca HX vo anken i xng. B. Phn ng trng hp ca anken. D. Phn ng cng ca HX vo anken bt i xng. Cu 20: Khi cho but-1-en tc dng vi dung dch HBr, theo quy tc Maccopnhicop sn phm no sau y l sn phm chnh ? A. CH3CH2CHBrCH2Br. C. CH3CH2CHBrCH3. B. CH2BrCH2CH2CH2Br. D. CH3CH2CH2CH2Br. Cu 21: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. 34 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 22: C bao nhiu anken th kh (kt) m khi cho m i anken tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. Cu 23: Cho 3,3-imetylbut-1-en tc dng vi HBr. Sn phm ca phn ng l : A. 2-brom-3,3-imetylbutan. B. 2-brom-2,3-imetylbutan. C. 2,2 -imetylbutan. D. 3-brom-2,2-imetylbutan. Cu 24: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l : A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 25: Anken thch hp iu ch ancol sau y (CH3CH2)3COH l : A. 3-etylpent-2-en. B. 3-etylpent-3-en. C. 3-etylpent-1-en. D. 3,3- imetylpent-1-en. Cu 26: Hirat ha hn hp X gm 2 anken thu c ch thu c 2 ancol. X gm cc cht : A. CH2=CH2 v CH2=CHCH3. B. CH2=CH2 v CH3CH=CHCH3. C. B hoc D. D. CH3CH=CHCH3 v CH2=CHCH2CH3. Cu 27: Cho etilen tc dng vi dung dch H2SO4 nhit thng. Sn phm l : A. CH3CH2OH. B. CH3CH2OSO3H. C. CH3CH2SO3H. D. CH2=CHSO4H. Cu 28: Cho etilen tc dng vi dung dch H2SO4 long, nng, sn phm chnh l : A. CH3CH2OH. B. CH3CH2SO4H. C. CH3CH2SO3H. D. CH2=CHSO4H. Cu 29: Cho hn hp tt c cc ng phn mch h ca C4H8 tc dng vi H2O (H+,t o) thu c ti a bao nhiu sn phm cng ? A. 2. B. 4. C. 6. D. 5 Cu 30: S cp ng phn cu to anken th kh (kt) tho mn iu kin : Khi hirat ho to thnh hn hp g m ba ancol l : A. 6. B. 3. C. 5. D. 4. Cu 31: S cp ng phn anken th kh (kt) tho mn iu kin : Khi hirat ho to thnh hn hp g m ba ancol l : A. 6. B. 7. C. 5. D. 8. Cu 32: Trng hp eten, sn phm thu c c cu to l : A. (CH2=CH2)n . B. (CH2CH2)n. C. (CH=CH)n. D. (CH3CH3)n . Cu 33: Oxi ho etilen bng dung dch KMnO4 thu c sn phm l : A. MnO2, C2H4(OH)2, KOH. C. K2CO3, H2O, MnO2. B. C2H5OH, MnO2, KOH. D. C2H4(OH)2, K2CO3, MnO2. Cu 34: Anken X tc dng vi dung dch KMnO4 trong mi trng axit, un nng to ra cc hp cht CH3CO CH3 v CH3COC2H5. Cng thc cu to ca X l : A. CH3CH2C(CH3)=C(CH3)2. B. CH3CH2C(CH3)=CH2. C. CH3CH2CH=CHCH3. D. CH3CH=C(CH3) CH2CH3.
Cu 35: Anken X tc dng vi dung dch KMnO4 trong mi trung axit, un nng to ra cc hp cht CH3COCH3 v CO2 v H2O. Cng thc cu to ca X l : A. CH3CH=CHCH3. B. (CH3)2C=CHCH3. C. (CH3)2C=C(CH3)2. D. (CH3)2C=CH2. Cu 36: Phn ng ca CH2 = CHCH3 vi kh Cl2 ( 500o C) cho sn phm chnh l : A. CH2ClCHClCH3. B. CH2=CClCH3. C. CH2=CHCH2Cl. D. CH3CH=CHCl. Cu 37: Mt hn hp A g m mt anken v mt ankan. t chy A thu c a mol H2O v b mol CO2. T s T = a/b c gi tr trong khong no ? A. 0,5 < T < 2. B. 1 < T < 1,5. C. 1,5 < T < 2. D. 1 < T < 2. Cu 38: X l hn hp gm 2 hirocacbon. t chy X c n CO2 = n H2 O . X c th gm : A. 1xicloankan v anken. B. 1ankan v 1ankin. C. 2 anken. D. A hoc B hoc C. Cu 39: Trong cc cch iu ch etilen sau, cch no khng c dng ? A. Tch H2O t ancol etylic. B. Tch H2 khi etan. C. Cho cacbon tc dng vi hiro. D. Tch HX khi dn xut halogen. Cu 40: iu ch etilen trong phng th nghim t C2H5OH, (H2SO4 c, 170oC) thng ln cc oxit nh SO2, CO2. Cht dng lm sch etilen l : A. Dung dch brom d. B. Dung dch NaOH d. C. Dung dch Na2CO3 d. D. Dung d ch KMnO4 long d. Cu 41: hirat ha 3-metylbutan-2-ol thu c my anken ? A. Mt. B. Hai. C. Ba. D. Bn. Cu 42: hirat ha butan-2-ol thu c my anken ? A. Mt. B. Hai. C. Ba. D. Bn. Cu 42: Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ? A. 3-metylbut-1-en. B. 2-metylbut-1en. C. 3-metylbut-2-en. D. 2-metylbut-2-en. Cu 44: Khi tch nc t ru (ancol) 3-metylbutanol-1 (hay 3-metylbutan-1-ol), sn phm chnh thu c l : A. 2-metylbuten-3 (hay 2-metylbut-3-en). B. 3-metylbuten-2 (hay 3-metylbut-2-en). C. 3-metylbuten-1 (hay 3-metylbut-1-en). D. 2-metylbuten-2 (hay 2-metylbut-2-en). Cu 45: 2-Metylbut-2-en c iu ch bng cch hiro clorua khi c mt KOH trong etanol ca dn xut clo no sau y ? A. 1-clo-3-metylbutan. B. 2-clo-2-metylbutan. C. 1-clo-2-metylbutan. D. 2-clopentan. Cu 46: Hp cht 2-metylbut-2-en l sn phm chnh ca phn ng tch t cht no ? A. 2-brom-2-metylbutan. B. 2-metylbutan-2-ol. C. 3-metylbutan-2-ol. D. Tt c u ng.
Cu 47: Phng php no sau y l tt nht phn bit kh CH4 v kh C2H4 ? A. Da vo t l v th tch kh O2 tham gia phn ng chy. B. S thay i mu ca nc brom. C. So snh khi lng ring. D. Phn tch thnh phn nh lng ca cc hp cht. Cu 48: phn bit etan v eten, dng phn ng no l thun tin nht ? A. Phn ng t chy. B. Phn ng cng vi hiro. C. Phn ng cng vi nc brom. D. Phn ng trng hp. Cu 49: Cho hn hp 2 anken l i qua bnh ng nc Br2 d thy kh i lng bnh nc Br2 tng 8 gam. Tng s mol ca 2 anken l : A. 0,1. B. 0,05. C. 0,025. D. 0,005. Cu 50: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau ph n ng khi lng bnh brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l : A. 0,05 v 0,1. B. 0,1 v 0,05. C. 0,12 v 0,03. D. 0,03 v 0,12. Cu 51: 2,8 gam anken A lm mt mu va dung dch cha 8 gam Br2. Hirat ha A ch thu c mt ancol duy nht. A c tn l : A. eten. B. but-2-en. C. hex-2-en. D. 2,3-imetylbut-2-en. Cu 52: Dn t t 8,4 gam hn hp X g m but-1-en v but-2-en l i chm qua bnh ng dung d ch Br2, khi kt thc phn ng thy c m gam brom phn ng. m c gi tr l : A. 12 gam. B. 24 gam. C. 36 gam. D. 48 gam. Cu 53: Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung d ch brom d thy c 1 cht kh bay ra, t chy hon ton kh ny thu c 5,544 gam CO2. Thnh phn % v th tch metan v olefin trong hn hp X l : A. 26,13% v 73,87%. B. 36,5% v 63,5%. C. 20% v 80%. D. 73,9% v 26,1%. Cu 54: t chy hon ton a gam hn hp eten, propen, but-2-en cn dng va b lt oxi ( ktc) thu c 2,4 mol CO2 v 2,4 mol nc. Gi tr ca b l : A. 92,4 lt. B. 94,2 lt. C. 80,64 lt. D. 24,9 lt. Cu 55: m gam hn hp g m C3H6, C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO2 (ktc). Nu hiro ho hon ton m gam h n hp trn r i t chy ht hn hp thu c V lt CO2 (ktc). Gi tr ca V l : A. 3,36. B. 2,24. C. 4,48. D. 1,12. Cu 56: t chy hon ton V lt (ktc) hn hp X gm CH4, C2H4 thu c 0,15 mol CO2 v 0,2 mol H2O. Gi tr ca V l : A. 2,24. B. 3,36. C. 4,48. D. 1,68. Cu 57: t chy hon ton 0,1 mol h m hp gm CH4, C4H10 v C2H4 thu c 0,14 mol CO2 v 0,23 mol H2O. S mol ca ankan v anken trong hn hp ln lt l : A. 0,09 v 0,01. B. 0,01 v 0,09. C. 0,08 v 0,02. D. 0,02 v 0,08. Cu 58: Cho 0,2 mol hn hp X g m etan, propan v propen qua dung dch brom d, thy kh i lng bnh brom tng 4,2 gam. Lng kh cn li em t chy hon ton thu c 6,48 gam nc. Vy % th tch etan, propan v propen ln lt l : A. 30%, 20%, 50%. B. 20%, 50%, 30%. C. 50%, 20%, 30%. D. 20%, 30%, 50%.
Cu 59: Chia hn hp g m C3H6, C2H4, C2H2 thnh hai phn u nhau : Phn 1: t chy hon ton thu c 2,24 lt CO2 (ktc). Phn 2: Hiro ho ri t chy ht th th tch CO2 thu c (ktc) l bao nhiu ? A. 1,12 lt. B. 2,24 lt. C. 4,48 lt. D. 3,36 lt. Cu 60: X l hn hp C4H8 v O2 (t l mol tng ng 1:10). t chy hon ton X c hn hp Y. Dn Y qua bnh H2SO4 c d c hn Z. T khi ca Z so vi hiro l : A.18. B. 19. C. 20. D. 21. Cu 61: Hn hp X gm C3H8 v C3H6 c t khi so vi hiro l 21,8. t chy ht 5,6 lt X (ktc) th thu c bao nhiu gam CO2 v bao nhiu gam H2O ? A. 33 gam v 17,1 gam. B. 22 gam v 9,9 gam. C. 13,2 gam v 7,2 gam. D. 33 gam v 21,6 gam. Cu 62: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T kh i ca X so vi kh H2 l : A. 12,9. B. 25,8. C. 22,2. D. 11,1 Cu 63: Thi 0,25 mol kh etilen qua 125 ml dung dch KMnO4 1M trong mi trng trung tnh (hiu sut 100%) khi lng etylen glicol thu c l : A. 11,625 gam. B. 23,25 gam. C. 15,5 gam. D. 31 gam. Cu 64: kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l : A. 2,240. B. 2,688. C. 4,480. D. 1,344. Cu 65: Hin nay PVC c iu ch theo s sau : C2H4 CH2ClCH2Cl C2H3Cl PVC. Nu hiu sut ton b qu trnh t 80% th lng C2H4 cn dng sn xut 5000 kg PVC l : A. 280 kg. B. 1792 kg. C. 2800 kg. D. 179,2 kg. Cu 66: Kh i lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu sut phn ng t 40% l : A. 56 gam. B. 84 gam. C. 196 gam. D. 350 gam. Cu 67: Hn hp X g m metan v anken, cho 5,6 lt X qua dung dch brom d thy kh i lng bnh brom t ng 7,28 gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l : A. C4H8. B. C5H10. C. C3H6. D. C2H4 Cu 68: Cho 2,24 lt anken l i qua bnh ng dung dch brom th thy kh i lung bnh tng 4,2 gam. Anken c cng thc phn t l : A. C2H4. B. C3H6. C. C4H8. D. C4H10. Cu 69: Cho 1,12 gam anken cng hp va vi brom thu c 4,32 gam sn phm cng hp. Cng thc phn t ca anken l : A. C3H6. B. C4H8. C. C5H10. D. C6H12. Cu 70: 0,05 mol hirocacbon X lm mt mu va dung dch cha 8 gam brom cho ra sn ph m c hm lng brom t 69,56%. Cng thc phn t ca X l : A. C3H6. B. C4H8. C. C5H10. D. C5H8. Cu 71: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phn ng thy khi lng bnh brom tng 22,4 gam. Bit X c ng phn hnh hc. CTCT ca X l : B. CH3CH=CHCH3. A. CH2=CHCH2CH3. C. CH3CH=CHCH2CH3. D. (CH3)2C=CH2. 38 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 72: Cho hirocacbon X phn ng vi brom (trong dung d ch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v kh i lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l : A. but-1-en. B. but-2-en. C. Propilen. D. Xiclopropan. Cu 73: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho h n hp X i qua bnh ng nc brom d, kh i lng bnh t ng ln 9,8 gam. Thnh phn phn trm v th tch ca mt trong 2 anken l : A. 50%. B. 40%. C. 70%. D. 80%. Cu 74: Dn 3,36 lt (ktc) hn hp X g m 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh t ng thm 7,7 gam. a. CTPT ca 2 anken l : A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. b. Thnh phn phn % v th tch ca hai anken l : A. 25% v 75%. B. 33,33% v 66,67%. C. 40% v 60%. D. 35% v 65%. Cu 75: Dn 3,36 lt (ktc) hn hp X gm 2 anken l vo bnh nc brom d, thy kh i lng bnh tng thm 7,7 gam. CTPT ca 2 anken l : A. C2H4 v C4H8. B. C3H6 v C4H8. C. C4H8 v C5H10. D. A hoc B. o Cu 76: Cho 10 lt hn hp kh (54,6 C; 0,8064 atm) gm 2 olefin l i qua bnh dung dch brom d thy kh i lng bnh brom tng 16,8 gam. CTPT ca 2 anken l (Bit s C trong cc anken khng vt qu 5) : A. C2H4 v C5H10. B. C3H6 v C5H10. C. C4H8 v C5H10. D. A hoc B. Cu 77: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho X qua nc Br2 d thy kh i lng bnh Br2 tng 15,4 gam. CTPT v s mol m i anken trong hn hp X l : A. 0,2 mol C2H4 v 0,3 mol C3H6. B. 0,2 mol C3H6 v 0,2 mol C4H8. C. 0,4 mol C2H4 v 0,1 mol C3H6. D. 0,3 mol C2H4 v 0,2 mol C3H6. Cu 78: Mt hn hp X g m ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, kh i lng bnh brom tng ln 2,8 gam ; th tch kh cn li ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v kh i lng ca hn hp X l : A. C4H10, C3H6 ; 5,8 gam. B. C3H8, C2H4 ; 5,8 gam. C. C4H10, C3H6 ; 12,8 gam. D. C3H8, C2H4 ; 11,6 gam. Cu 79: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh ktc. Cho hn hp X i qua nc Br2 d th th tch kh Y cn li bng na th tch X, cn kh i lng Y bng 15/29 khi lng X. CTPT A, B v thnh phn % theo th tch ca hn hp X l : A. 40% C2H6 v 60% C2H4. B. 50% C3H8v 50% C3H6. C. 50% C4H10 v 50% C4H8. D. 50% C2H6 v 50% C2H4. Cu 80: Hirocacbon X cng HCl theo t l mol 1:1 to sn phm c hm lng clo l 55,04%. X c cng thc phn t l : A. C4H8. B. C2H4. C. C5H10. D. C3H6. Cu 81: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh ph n phn trm v kh i lng clo l 45,223%. Cng thc phn t ca X l : A. C3H6. B. C4H8. C. C2H4. D. C5H10.
Cu 82: Hn hp X gm hai anken k tip nhau trong dy ng ng. t chy hon ton 5 lt X cn va 18 lt kh oxi (cc th tch kh o cng iu kin nhit v p sut). a. Cng thc phn t ca hai anken l : A. C2H6 v C4H3. B. C3H6 v C4H8. C. C4H8 v C5H10. D. A hoc B. b. Hirat ha mt th tch X trong iu kin thch hp thu c hn hp ancol Y, trong t l v kh i ancol bc mt so vi ancol bc 2 l 28 : 25. Thnh phn phn trm kh i lng ca m i ancol trong hn hp Y l : A. C2H5OH : 53,49% ; iso C3H7OH : 34,88% ; n C3H7OH : 11,63%. B. C2H5OH : 53,49% ; iso C3H7OH : 11,63% ; n C3H7OH : 34,88%. C. C2H5OH : 11,63% ; iso C3H7OH : 34,88% ; n C3H7OH : 53,49%. D. C2H5OH : 34,88% ; iso C3H7OH : 53,49% ; n C3H7OH : 11,63%. Cu 83: Hn hp X gm 2 olefin ng ng k tip. t chy 5 lt X cn va 18 lt O2 cng iu kin. Dn 0,5 lt X vo H2O c xc tc thch hp thu c hn hp Y trong t l v s mol cc ru bc I so vi ru bc II l 7 : 3. % khi lng ru bc II trong Y l : A. 34,88%. B. 53,57%. C. 66,67%. D. 23,07%. Cu 84: Cho hn hp X gm etilen v H2 c t khi so vi H2 bng 4,25. Dn X qua bt niken nung nng (hiu sut phn ng 75%) thu c hn hp Y. T kh i ca Y so vi H2 (cc th tch o cng iu kin) l : A. 5,23. B. 3,25. C. 5,35. D. 10,46. Cu 85: Cho H2 v 1 olefin c th tch bng nhau qua Niken un nng ta c hn hp A. Bit t kh i hi ca A i vi H2 l 23,2. Hiu sut phn ng hiro ho l 75%. Cng thc phn t olefin l : A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 86: Hn hp kh X g m H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T kh i ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t kh i ca Y so vi H2 bng 13. Cng thc cu to ca anken l : A. CH3CH=CHCH3. B. CH2=CHCH2CH3. C. CH2=C(CH3)2. D. CH2=CH2. Cu 87: Cho hn hp X g m anken v hiro c t kh i so vi heli bng 3,33. Cho X i qua bt niken nung nng n khi phn ng xy ra hon ton, thu c hn hp Y c t kh i so vi heli l 4. CTPT ca X l : A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 88: Hn hp kh X g m H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l : A. 20%. B. 25%. C. 50%. D. 40%. Cu 89: X, Y, Z l 3 hirocacbon k tip trong dy ng ng, trong MZ = 2MX. t chy hon ton 0,1 mol Y ri hp th ton b sn phm chy vo 2 lt dung dch Ba(OH)2 0,1M c mt lng kt ta l : A. 19,7 gam. B. 39,4 gam. C. 59,1 gam. D. 9,85 gam. Cu 90: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong kh i lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Z, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l : A. 20. B. 40. C. 30. D. 10.
Cu 91: Hn hp X gm propen v mt ng ng ca n c t l th tch l 1:1. t 1 th tch hn hp X cn 3,75 th tch oxi (cng k). Vy B l : A. eten. B. propan. C. buten. D. penten. Cu 92: t chy hon ton 0,05 mol mt anken A thu c 4,48 lt CO2 (ktc). Cho A tc dng vi dung dch HBr ch cho mt sn phm duy nht. CTCT ca A l : A. CH2=CH2. B. (CH3)2C=C(CH3)2. C. CH2=C(CH3)2. D. CH3CH=CHCH3. Cu 93: t chy hon ton 10 ml hirocacbon X cn va 60 ml kh oxi, sau phn ng thu c 40 ml kh cacbonic. Bit X lm mt mu dung dch brom v c mch cacbon phn nhnh. CTCT ca X l : A. CH2=CHCH2CH3. B. CH2=C(CH3)2. C. CH2=C(CH2)2CH3. D. (CH3)2C=CHCH3. Cu 94: Mt hn hp kh g m 1 ankan v 1 anken c cng s nguyn t C trong phn t v c cng s mol. Ly m gam hn hp ny th lm mt mu va 80 gam dung dch 20% Br2 trong dung mi CCl4. t chy hon ton m gam h n hp thu c 0,6 mol CO2. Ankan v anken c cng thc phn t l : A. C2H6 v C2H4. B. C4H10 v C4H8. C. C3H8 v C3H6. D. C5H12 v C5H10. Cu 95: Hn hp X g m 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc t chy hon ton hn hp X dng ht 24,64 lt O2 (ktc). Cng thc phn t ca 2 anken l : A. C2H4 v C3H6. B. C2H4 v C4H8. C. C3H6 v C4H8. D. A v B u ng. Cu 96: X l hn hp gm hirocacbon A v O2 (t l mol tng ng 1:10). t chy hon ton X c hn hp Y. Dn Y qua bnh H2SO4 c d c hn Z c t khi so vi hiro l 19. A c cng thc phn t l : A. C2H6. B. C4H8. C. C4H6. D. C3H6. Cu 97: t chy hon ton 0,1 mol anken X thu c CO2 v hi nc. Hp th hon ton sn phm bng 100 gam dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH ch cn 5%. Cng thc phn t ng ca X l : A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 98: Mt hn hp A g m 2 hirocacbon X, Y lin tip nhau trong cng dy ng ng. t chy 11,2 lt hn hp X thu c 57,2 gam CO2 v 23,4 gam CO2. CTPT X, Y v khi lng ca X, Y l : A. 12,6 gam C3H6 v 11,2 gam C4H8. B. 8,6 gam C3H6v 11,2 gam C4H8. C. 5,6 gam C2H4 v 12,6 gam C3H6. D. 2,8 gam C2H4 v 16,8 gam C3H6. Cu 99: em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu c CO2 v nc c khi lng hn km nhau 6,76 gam. CTPT ca 2 anken l : A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. Cu 100: t chy hon ton 8,96 lt (ktc) hn hp hai anken l ng ng lin tip thu c m gam H2O v (m + 39) gam CO2. Hai anken l : A. C2H4 v C3H6. B. C4H8 v C5H10. C. C3H6 v C4H8. D. C6H12 v C5H10. Cu 101: Hn hp kh A iu kin tiu chun g m hai olefin. t chy 7 th tch A cn 31 th tch O2 (ktc). Bit olefin cha nhiu cacbon chim khong 40% 50% th tch hn hp A. Cng thc phn t ca hai elefin l : A. C2H4 v C3H6. B. C3H6 v C4H8. C. C2H4 v C4H8. D. A hoc C ng.
Cu 102: Mt hn hp X g m 2 hirocacbon A, B c cng s nguyn t cacbon. A, B ch c th l ankan hay anken. t chy 4,48 lt (ktc) hn hp X thu c 26,4 gam CO2 v 12,6 gam H2O. CTPT v s mol ca A, B trong hn hp X l : A. 0,1 mol C3H8 v 0,1 mol C3H6. B. 0,2 mol C2H6 v 0,2 mol C2H4. C. 0,08 mol C3H8 v 0,12 mol C3H6. D. 0,1 mol C2H6 v 0,2 mol C2H4. Cu 103: Mt hn hp X gm 1 anken A v 1 ankin B, A v B c cng s nguyn t cacbon. X c kh i lng l 12,4 gam, c th tch l 6,72 lt. Cc th tch kh o ktc. CTPT v s mol A, B trong hn hp X l : A. 0,2 mol C2H4 v 0,1 mol C2H2. B. 0,1 mol C3H6 v 0,1 mol C3H4. C. 0,2 mol C3H6 v 0,1 mol C3H4. D. 0,1 mol C2H4 v 0,2 mol C2H2. Cu 104: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) : A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6.
B. BI TP TRC NGHIM V ANKAIEN V TECPEN

Cu 105: Ankaien l : A. hirocacbon c 2 lin kt i C=C trong phn t. B. hirocacbon mch h c 2 lin kt i C=C trong phn t. C. hirocacbon c cng thc l CnH2n-2 trong phn t. D. hirocacbon, mch h c cng thc l CnH2n-2 trong phn t. Cu 106: Ankaien lin hp l : A. ankaien c 2 lin kt i C=C lin nhau. B. ankaien c 2 lin kt i C=C cch nhau 2 n i n. C. ankaien c 2 lin kt i C=C cch nhau 1 lin kt n. D. ankaien c 2 lin kt i C=C cch xa nhau. Cu 107: S ng phn thuc loi ankaien ng vi cng thc phn t C5H8 l : A. 4. B. 5. C. 6. D. 7. Cu 108: C5H8 c bao nhiu ng phn ankaien lin hp ? A. 2. B. 3. C. 4. D. 5. Cu 109: Trong cc hirocacbon sau : propen, but-1-en, but-2-en, penta-1,4-ien, penta-1,3-ien. Nhng hirocacbon no c ng phn cis - trans ? A. propen, but-1-en. B. penta-1,4-ien, but-1-en. C. propen, but-2-en. D. but-2-en, penta-1,3- ien. Cu 110: Trong phn t buta-1,3-ien, cacbon trng thi lai ho : A. sp. B. sp2. C. sp3. D. sp3d2. Cu 111: Cng thc phn t ca buta-1,3-ien (ivinyl) v isopren (2-metylbuta-1,3-ien) ln lt l : A. C4H6 v C5H10. B. C4H4 v C5H8. C. C4H6 v C5H8. D. C4H8 v C5H10.
Cu 112: Hp cht no trong s cc cht sau c 9 lin kt xch ma v 2 lin kt ? A. Buta-1,3-ien. B. Penta-1,3- ien. C. Stiren. D. Vinyl axetilen. Cu 113: Hp cht no trong s cc cht sau c 7 lin kt xch ma v 3 lin kt ? A. Buta-1,3-ien. B. Tuloen. C. Stiren. D. Vinyl axetilen. Cu 114: Ankaien CH2=CHCH=CH2 c tn gi quc t l : A. ivinyl. B. 1,3-butaien. C. butaien-1,3. D. buta-1,3-ien. Cu 115: Ankaien CH2=CHCH=CH2 c tn gi thng thng l : A. ivinyl. B. 1,3-butaien. C. butaien-1,3. D. buta-1,3-ien. Cu 116: CH2=C(CH3)CH=CH2 c tn gi thay th l : A. isopren. B. 2-metyl-1,3-butaien. C. 2-metyl-butaien-1,3. D. 2-metylbuta-1,3-ien. Cu 117: CH2=C(CH3)CH=CH2 c tn thng gi l : A. isopren. B. 2-metyl-1,3-butaien. C. 2-metyl-butaien-1,3. D. 2-metylbuta-1,3-ien.
Ni, t Cu 118: A (Ankaien lin hp) + H2 isopentan. Vy A l : A. isopren. B. 2-metyl-1,3-butaien. C. 2-metyl-buta-1,3-ien. D. 2-metylpenta-1,3-ien. Cu 119: 1 mol buta-1,3-ien c th phn ng ti a vi bao nhiu mol brom ? A. 1 mol. B. 1,5 mol. C. 2 mol. D. 0,5 mol. Cu 120: Cho 1 mol ivinyl tc dng vi 2 mol brom. Sau phn thu c : A. 1 dn xut brom. B. 2 dn xut brom. C. 3 dn xut brom. D. 4 dn xut brom. Cu 121: Cho 1 mol isopren tc dng vi 2 mol brom. Sau phn thu c : A. 1 dn xut brom. B. 2 dn xut brom. C. 3 dn xut brom. D. 4dn xut brom. Cu 122: ivinyl tc dng vi brom theo t l mol 1:1 to ra sn phm : A. cng 1,2 v cng 1,3. B. cng 1,2 v cng 2,3. C. cng 1,2 v cng 3,4. D. cng 1,2 v cng 1,4. Cu 123: Isopren tc dng cng brom theo t l mol 1:1 to ra sn phm : A. cng 1,2; cng 3,4 v cng 1,4. B. cng 1,2 ; cng 2,3 v cng 14. C. cng 1,2 ; cng 3,4 v cng 2,3. D. cng 1,2 v cng 1,4. Cu 124: ivinyl tham gia phn ng vi dung dch Br2 theo t l mol 1:1 to ra ti a bao nhiu s n phm ? A. 4. B. 1. C. 3. D. 2. Cu 125: Isopren tham gia phn ng vi dung dch Br2 theo t l mol 1:1 to ra ti a bao nhiu sn phm ? A. 4. B. 1. C. 3. D. 2. o Cu 126: ivinyl tc dng cng Br2 theo t l mol 1:1, -80 C to ra sn phm chnh l : A. 3,4-ibrom-but-1-en. B. 3,4-ibrom-but-2-en. C. 1,4-ibrom-but-2-en. D. 1,4-ibrom-but-1-en.
o
Cu 127: ivinyl tc dng cng Br2 theo t l mol 1:1, 40oC to ra sn phm chnh l : A. 3,4-ibrom-but-1-en. B. 3,4-ibrom-but-2-en. C. 1,4-ibrom-but-2-en. D. 1,2-ibrom-but-3-en. Cu 128: ivinyl tc dng cng HBr theo t l mol 1:1, -80 oC to ra sn phm chnh l : A. 3-brom-but-1-en. B. 3-brom-but-2-en. C. 1-brom-but-2-en D. 2-brom-but-3-en. Cu 129: ivinyl tc dng cng HBr theo t l mol 1:1, 40 oC to ra sn phm chnh l : A. 3-brom-but-1-en. B. 3-brom-but-2-en. C. 1-brom-but-2-en. D. 2-brom-but-3-en. Cu 130: Cho phn ng gia buta-1,3-ien v HBr -80oC (t l mol 1:1), sn phm chnh ca phn ng l : A. CH3CHBrCH=CH2. B. CH3CH=CHCH2Br. C. CH2BrCH2CH=CH2. D. CH3CH=CBrCH3. Cu 131: Cho phn ng gia buta-1,3-ien v HBr 40oC (t l mol 1:1), sn phm chnh ca phn ng l : A. CH3CHBrCH=CH2. B. CH3CH=CHCH2Br. C. CH2BrCH2CH=CH2. D. CH3CH=CBrCH3. Cu 132: Isopren tham gia phn ng vi dung dch HBr theo t l mol 1:1 to ra ti a bao nhiu sn phm cng ? A. 8. B. 5. C. 7. D. 6. Cu 133: Cht no sau y khng phi l sn phm cng gia dung dch brom v isopren (theo t l mol 1:1) ? A. CH2BrC(CH3)BrCH=CH2. B. CH2BrC(CH3)=CHCH2Br. C. CH2BrCH=CHCH2CH2Br. D. CH2=C(CH3) CHBrCH2Br. Cu 134: Ankaien A + brom (dd) CH3C(CH3)BrCH=CHCH2Br. Vy A l : A. 2-metylpenta-1,3-ien. B. 2-metylpenta-2,4-ien. C. 4-metylpenta-1,3-ien. D. 2-metylbuta-1,3-ien. Cu 135: Ankaien B + Cl2 CH2ClC(CH3)=CHCHClCH3. Vy A l : A. 2-metylpenta-1,3-ien. B. 4-metylpenta-2,4-ien. C. 2-metylpenta-1,4-ien. D. 4-metylpenta-2,3-ien. Cu 136: Cho Ankaien A + brom (dd) 1,4-ibrom-2-metylbut-2-en. Vy A l : A. 2-metylbuta-1,3-ien. C. 3-metylbuta-1,3-ien. B. 2-metylpenta-1,3-ien. D. 3-metylpenta-1,3-ien. Cu 137: Trng hp ivinyl t o ra cao su Buna c cu to l : A. (C2HCHCHCH2)n. B. (CH2CH=CHCH2)n. C. (CH2CHCH=CH2)n. D. (CH2CH2CH2CH2)n. Cu 138: ng trng hp ivinyl v stiren thu c cao su buna-S c cng thc cu to l : A. (CH2CH=CHCH2CH(C6H5) CH2)n. B. (CH2CHCHCH2CH(C6H5) CH2)n. C. (CH2CHCH=CH2CH(C6H5) CH2)n. D. (CH2CH2CH2CH2CH(C6H5) CH2)n .
Cu 139: ng trng hp ivinyl v acrylonitrin (vinyl xianua) thu c cao su buna-N c cng thc cu to l : A. (C2HCHCHCH2CH(CN)CH2)n. B. (CH2CH2CH2CH2CH(CN)CH2)n. C. (CH2CHCH=CH2CH(CN)CH2)n. D. (CH2CH=CHCH2CH(CN)CH2)n . Cu 140: Trng hp isopren to ra cao su isopren c cu to l : A. (C2HC(CH3) CHCH2)n. C. (CH2C(CH3) CH=CH2)n . B. (CH2C(CH3)=CHCH2)n. D. (CH2CH(CH3) CH2CH2)n . Cu 141: Sn phm trng hp ca: CH2=C(CH3)CCl=CH2 c tn gi l : A. Cao subuNa. B. Cao isopren. C. Cao subuNa-S. D. Cao cloropren. Cu 142: hiro ho hirocacbon no A thu c ivinyl. Vy A l : A. n-butan. B. iso butan. C. but-1-en. D. but-2-en. Cu 143: hiro ho hirocacbon no A thu c isopren. Vy A l : A. n-pentan. B. iso-pentan. C. pen-1-en. D. pen-2-en.
t ,xt Cu 144: Cht hu c X cha C, H, O ivinyl + ? + ? Vy X l : A. etanal. B. etanol. C. metanol. D. metanal. Cu 145: 4,48 lt (ktc) mt hirocacbon A tc dng va vi 400 ml dung dch brom 1M c sn phm cha 85,56% Br v khi lng. CTPT ca A l : A. C2H6. B. C3H6. C. C4H6. D. C4H8. Cu 146: Mt hirocacbon A cng dung dch brom to dn xut B cha 92,48% brom v kh i lng. CTCT B l : A. CH3CHBr2. B. CHBr2CHBr2. C. CH2BrCH2Br. D. CH3CHBrCH2Br. Cu 147: t chy hon ton m gam hn hp gm buta-1,3-ien v isopren thu c 0,9 mol CO2 v 12,6 gam nc. Gi tr ca m l : A. 12,1 gam. B. 12,2 gam. C. 12,3 gam. D. 12,4 gam. Cu 148: t a gam hn hp g m buta-1,3-ien v isopren thu c 20,16 lt CO2 (ktc) v 12,6 gam nc. Th tch oxi cn dng ktc l : A. 28 lt. B. 29 lt. C. 18 lt. D. 27 lt. Cu 149: t chy 0,05 mol cht A (cha C, H) thu c 0,2 mol H2O. Bit A trng hp cho B c tnh n h i. Vy A l : A. buta-1,3-ien. B. 2-metylbuta-1,3-ien. C. 2-metylbuta-1,2-ien. D. 2-metylpenta-1,3-ien. Cu 150: Tn gi ca nhm hirocacbon khng no c cng thc chung l (C5H8)n (n 2) l : A. ankaien. B. cao su. C. anlen. D. tecpen. Cu 151: Caroten (licopen) l sc t mu ca c rt v c chua chn, cng thc phn t ca caroten l : B. C40H56. C. C10H16. D. C30H50. A. C15H25.
o
Cu 152: Oximen c trong tinh du l hng qu, limonen c trong tinh du chanh. Chng c cng cng thc phn t l : A. C15H25. B. C40H56. C. C10H16. D. C30H50. Cu 153: Vitamin A cng thc phn t C20H30O, c cha 1 vng 6 cnh v khng c cha lin kt ba. S lin kt i trong phn t vitamin A l : A. 7. B. 6. C. 5. D. 4. Cu 154: Licopen, cng thc phn t C40H56 l cht mu trong qu c chua, ch cha lin kt i v lin kt n trong phn t. Hiro ha hon ton licopen c hirocacbon C40H82. Vy licopen c A. 1 vng ; 12 ni i. B. 1 vng ; 5 ni i. C. 4 vng ; 5 ni i. D. mch h ; 13 ni i. Cu 155: Metol C10H20O v menton C10H18O chng u c trong tinh du bc h. Bit phn t metol khng c ni i, cn phn t menton c 1 ni i. Vy kt lun no sau y l ng ? A. Metol v menton u c cu to vng. B. Metol c cu t o vng, menton c cu to mch h. C. Metol v menton u c cu to mch h. D. Metol c cu t o mch h, menton c cu to vng.
BI TP TRC NGHIM V ANKIN

Cu 156: Ankin l hirocacbon : A. c dng CnH2n-2, mch h. B. c dng CnH2n, mch h. C. mch h, c 1 lin kt ba trong phn t . D. A v C u ng. Cu 157: Dy ng ng ca axetilen c cng thc chung l : A. CnH2n+2 (n 2). B. CnH2n-2 (n 1). C. CnH2n-2 (n 3). D. CnH2n-2 (n 2). Cu 158: Cu no sau y sai ? A. Ankin c s ng phn t hn anken tng ng. B. Ankin tng t anken u c ng phn hnh hc. C. Hai ankin u dy khng c ng phn. D. Butin c 2 ng phn v tr nhm chc. Cu 159: Trong phn t ankin hai nguyn t cacbon mang lin kt ba trng thi lai ho : A. sp. B. sp2. C. sp3. D. sp3d2. Cu 160: Trong phn t axetilen lin kt ba gia 2 cacbon gm : A. 1 lin kt pi () v 2 lin kt xch ma ( ). B. 2 lin kt pi () v 1 lin kt xch ma ( ). C. 3 lin kt pi (). D. 3 lin kt xch ma ( ). Cu 161: Cc ankin c ng phn v tr lin kt ba khi s cacbon trong phn t ln hn hoc bng : A. 2. B. 3. C. 4. Cu 162: Cc ankin bt u c ng phn mch C khi s C l : A. 2. B. 3. C. 4. D. 5. D. 5.
Cu 163: Mt trong nhng loi ng phn nhm chc ca ankin l : A. ankan. B. anken. C. ankaien. D. aren. Cu 164: C4H6 c bao nhiu ng phn mch h ? A. 5. B. 2. C. 3. D. 4. Cu 165: C bao nhiu ankin ng vi cng thc phn t C5H8 ? A. 1. B. 2. C. 3. D. 4. Cu 166: Trong phn t ankin X, hiro chim 11,111% khi lng. C bao nhiu ankin ph hp ? A. 1. B. 2. C. 3. D. 4. Cu 167: A, B l 2 ankin ng ng th kh, trong iu kin thng. T kh i hi ca B so vi A bng 1,35.Vy A, B l : A. etin ; propin. B. etin ; butin. C. propin ; butin. D. propin ; pentin. Cu 168: A, B, C l 3 ankin k tip nhau trong dy ng ng c tng khi lng 162 vC. Cng thc A, B, C ln lt l : A. C2H2 ; C3H4 ; C4H6. B. C3H4 ; C4H6 ; C5H8. C. C4H6 ; C3H4 ; C5H8. D. C4H6 ; C5H8 ; C6H10. Cu 169: Cho ankin X c cng thc cu to sau: CH3C C CH CH3 Tn ca X l : CH
3
A. 4-metylpent-2-in. C. 4-metylpent-3-in.
B. 2-metylpent-3-in. D. 2-metylpent-4-in.
CH3 | Cu 170: Cho hp cht sau : CH 3 C C CH | CH3 Tn gi ca hp cht theo danh php IUPAC l : A. 2,2-imetylbut-1-in. B. 2,2-imetylbut-3-in. C. 3,3-imetylbut-1-in. D. 3,3-imetylbut-2-in. Cu 171: Mt cht c cng thc cu t o : CH3CH2CCCH(CH3)CH3 Tn gi ca hp cht theo danh php IUPAC l : A. 5-metylhex-3-in. B. 2-metylhex-3-in. C. Etylisopropylaxetilen. D. C A, B v C. Cu 172: Cht c cng thc cu to : CH3C(CH3)=CHCCH c tn gi l : A. 2-metylhex-4-in-2-en. B. 2-metylhex-2-en-4-in. C. 4-metylhex-3-en-1-in. D. 4-metylhex-1-in-3-en. Cu 173: Cho hp cht sau : CH3C(CH3)CCHCH3 Tn gi ca hp cht theo danh php IUPAC l : A. 2-metylpen-3-in B. 4-metylpen-2-in C. 2-metylpen-2-in D. C A, B v C u ng Cu 174: Theo IUPAC ankin CH3C CCH2CH3 c tn gi l : A. etylmetylaxetilen. B. pent-3-in. C. pent-2-in. D. pent-1-in.
Cu 175: Theo IUPAC ankin CH CCH2 CH(CH3)CH3 c tn gi l : A. isobutylaxetilen. B. 2-metylpent-2-in. C. 4-metylpent-1-in. D. 2-metylpent-4-in. Cu 176: Theo IUPAC ankin CH3C CCH(CH3)CH(CH3)CH3 c tn gi l : A. 4-imetylhex-1-in. B. 4,5-imetylhex-1-in. C. 4,5-imetylhex-2-in. D. 2,3-imetylhex-4-in. Cu 177: Theo IUPAC ankin CH3CH(C2H5)C CCH(CH3)CH2CH2CH3 c tn gi l : A. 3,6-imetylnon-4-in. B. 2-etyl-5-metyloct-3-in. C. 7-etyl-6-metyloct-5-in. D. 5-metyl-2-etyloct-3-in. Cu 178: Ankin CH CCH(C2H5)CH(CH3)CH3 c tn gi l : A. 3-etyl-2-metylpent-4-in. B. 2-metyl-3-etylpent-4-in. C. 4-metyl-3-etylpent-1-in. D. 3-etyl-4-metylpent-1-in. Cu 179: chuyn ho ankin thnh anken ta thc hin phn ng cng H2 trong iu kin c xc tc : A. Ni, to. B. Mn, t o. C. Pd/ PbCO3, to. D. Fe, to. Cu 180: Hn hp A g m hiro v cc hirocacbon no, khng no. Cho A vo bnh c niken xc tc, un nng bnh mt thi gian ta thu c hn hp B. Pht biu no sau y sai ? A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v s mol nc khi t chy hon ton hn hp B. B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon ton hn hp B. C. S mol A S mol B = S mol H2 tham gia phn ng. D. Kh i lng phn t trung bnh ca hn hp A bng kh i lng phn t trung bnh ca hn hp B. Cu 181: Cht no trong 4 cht di y c th tham gia c 4 phn ng : Phn ng chy trong oxi, phn ng cng brom, phn ng cng hiro (xc tc Ni, to), phn ng th vi dung dch AgNO3 /NH3 ? A. etan. B. etilen. C. axetilen. D. xiclopropan.
t , xt Cu 182: Cho phn ng : C2H2 + H2O A A l cht no di y ? A. CH2=CHOH. B. CH3CHO. C. CH3COOH. Cu 183: Cho dy chuyn ho sau : CH4 A B C Cao su Buna. Cng thc phn t ca B l : A. C4H6. B. C2H5OH. C. C4H4. Cu 184: Cho s phn ng C3H6 (X) (Y) (Z) (T) Axeton X, Y, Z, T ln lt l : A. CH3CH2CH2Cl, CH3CH=CH2, CH3CHBrCH2Br, CH3CCH. B. CH3CHClCH3, CH3CH=CH2, CH3CHBrCH2Br, CH3CCH. C. C2H4, C2H4Br2, C2H2, CH3CCH. D. C A, B.
o
D. C2H5OH.
D. C4H10.
Cu 185: C chui phn ng sau:

B HCl D N + H2 D E (spc) Xc nh N, B, D, E bit rng D l mt hidrocacbon mch h, D ch c 1 ng phn. A. N : C2H2 ; B : Pd ; D : C2H4 ; E : CH3CH2Cl. B. N : C4H6 ; B : Pd ; D : C4H8 ; E : CH2ClCH2CH2CH3. C. N : C3H4 ; B : Pd ; D : C3H6 ; E : CH3CHClCH3. D. N : C3H4 ; B : Pd ; D : C3H6 ; E : CHCH2CH2Cl. Cu 186: Ankin B c cha 90% C v kh i lng, mch thng, c phn ng vi AgNO3/NH3. Vy B l : A. axetilen. B. propin. C. but-1-in. D. but-2-in. Cu 187: Ankin C4H6 c bao nhiu ng phn cho phn ng th kim loi (phn ng vi dung dch cha AgNO3/NH3) ? A. 4. B. 2. C. 1. D. 3. Cu 188: C bao nhiu ng phn ankin C5H8 tc dng c vi dung dch AgNO3/NH3 to kt ta ? A. 3. B. 2. C. 4. D. 1. Cu 189: Ankin C6H10 c bao nhiu ng phn phn ng vi dung d ch AgNO3/NH3 ? A. 3. B. 4. C. 5. D. 6. Cu 190: Trong s cc hirocacbon mch h sau : C4H10, C4H6, C4H8, C3H4, nhng hirocacbon no c th t o kt ta vi dung dch AgNO3/NH3 ? A. C4H10 ,C4H8. B. C4H6, C3H4. C. Ch c C4H6. D. Ch c C3H4. Cu 191: Cho s phn ng sau : CH3CCH + AgNO3/NH3 X + NH4NO3 X c cng thc cu to l ? A. CH3CAgCAg. B. CH3CCAg. C. AgCH2CCAg. D. A, B, C u c th ng. Cu 192: Cho cc phng trnh ha hc :
KOH
CH3CCH CH3CCH
+ H2O
Hg , t CH3CH2CHO (spc)
o o
2+
(1) (2) (3) (4)
t + AgNO3 + NH3 CH3CCAg + NH4NO3
CH3CCH + 3CH3CCH
2H2
Ni,t o xt,t ,p
0
CH3CH2CH3
CH3
H3C
CH3
Cc phng trnh ha hc vit sai l : A. (3). B. (1). Cu 193: Cho cc phn ng sau:
askt (1) CH4 + Cl2 1:1
C. (1), (3).
o
D. (3), (4).
t , xt (2) C2H4 + H2 t , xt (4) 3C2H2

o
t , xt (3) 2C2H2
o
(5) C2H2 + AgNO3/NH3 S phn ng l phn ng oxi ho kh l : A. 2. B. 3.
t , xt (6) Propin + H2O

o
C. 4.
D. 5.
Cu 194: Cho phn ng : CHCH + KMnO4 KOOCCOOK + MnO2 + KOH + H2O H s cn bng trong phng trnh ha hc ca phn ng trn ln lt l : A. 3; 8; 3; 8; 2; 4. B. 3; 8; 2; 3; 8; 8. C. 3; 8; 8; 3; 8; 8. D. 3; 8; 3; 8; 2; 2. Cu 195: Cho phn ng : RCCR + KMnO4 + H2SO4 RCOOH + RCOOH + MnSO4 + K2SO4 + H2O H s cn bng trong phng trnh ha hc ca phn ng trn ln lt l : A. 5; 6; 7; 5; 5; 6; 3; 4. B. 5; 6; 9; 5; 5; 6; 3; 4. C. 5; 6; 8; 5; 5; 6; 3; 4. D. 5; 6; 9; 5; 5; 6; 3; 5. Cu 196: Phn ng sau : CH3CCH + KMnO4 + H2SO4 Cho sn phm l : A. CH3CHOHCH2OH, MnSO4, K2SO4, H2O. B. CH3COOH, CO2, MnSO4, K2SO4, H2O. C. CH3CHOHCH2OH, MnO2, K2SO4, H2O. D. CH3COOH, MnSO4, K2SO4, H2O. Cu 197: phn bit cc kh propen, propan, propin c th dng thuc th l : A. Dung dnh KMnO4. B. Dung dch Br2. C. Dung d ch AgNO3/NH3. D. Dung d ch Br2, dung dch AgNO3/NH3. Cu 198: phn bit but-1-in v but-2-in ngi ta dng thuc th sau y ? A. Dung d ch hn hp KMnO4 + H2SO4. B. Dung dch AgNO3/NH3. C. Dung dch Br2. D. C A, B, C. Cu 199: phn bit 3 kh C2H4, C2H6, C2H2 ngi ta dng cc thuc th l : A. dung dch KMnO4. B. H2O, H+. C. dung dch AgNO3/NH3 sau l dung dch Br2. D. C B v C. Cu 200: nhn bit cc bnh ring bit ng cc kh khng mu sau y: SO2, C2H2, NH3 ta c th dng ho cht no sau y ? A. Dung d ch AgNO3/NH3. B. Dung dch Ca(OH)2 C. Qu tm m. D. Dung d ch NaOH Cu 201: lm sch etilen c ln axetilen ta cho hn hp i qua dung dch no sau y ? A. Dung d ch brom d. B. Dung dch KMnO4 d. C. Dung d ch AgNO3/NH3 d. D. cc cch trn u ng. Cu 202: Hn hp X g m 3 kh C2H4, C2H6, C2H2. thu c C2H6, ngi ta cho X ln lt l i chm qua : A. dung dch KMnO4. B. dung d ch AgNO3/NH3; dung dch Br2. C. dung dch Br2. D. C A, B, C. Cu 203: Cht no sau y khng iu ch trc tip c axetilen ? A. Ag2C2. B. CH4. C. Al4C3. D. CaC2.
Cu 204: Bit 8,1 gam hn hp kh X g m : CH3CH2CCH v CH3CCCH3 c th lm mt mu va m gam Br2 trong dung dch. Gi tr ca m l : A. 16 gam. B. 32 gam. C. 48 gam. D. 54. Cu 205: Mt hn hp g m etilen v axetilen c th tch 6,72 lt (ktc). Cho hn hp qua dung dch brom d phn ng xy ra hon ton, lng brom phn ng l 64 gam. Phn % v th tch etilen v axetilen ln lt l : A. 66% v 34%. B. 65,66% v 34,34%. C. 66,67% v 33,33%. D. Kt qu khc. Cu 206: X l hn hp gm 2 hirocacbon mch h (thuc dy ng ng ankin, anken, ankan). Cho 0,3 mol X lm mt mu va 0,5 mol brom. Pht biu no di y ng ? A. X c th gm 2 ankan. B. X c th gm2 anken. C. X c th gm1 ankan v 1 anken. D. X c th gm1 anken v mt ankin. Cu 207: Mt hn hp X g m 1 ankin A v H2 c V = 15,68 lt (ktc) cho qua Ni nung nng, ph n ng hon ton cho ra hn hp Y c V = 6,72 lt (Y c H2 d). Th tch ca A trong X v th tch H2 d (ktc) l : A. 4,48 lt ; 2,24 lt. B. 4,48 lt ; 4,48 lt. C. 3,36 lt ; 3,36 lt. D. 1,12 lt ; 5,6 lt. Cu 208: Hn hp A g m C2H2 v H2, t kh i ca A so vi hiro l 5,8. Dn A (ktc) qua bt Ni nung nng cho n khi cc phn ng xy ra hon ton ta c hn hp B. Phn trm th tch m i kh trong hn hp A v t kh i ca B so vi hiro l : A. 40% H2; 60% C2H2; 29. B. 40% H2; 60% C2H2 ; 14,5. C. 60% H2; 40% C2H2 ; 29. D. 60% H2; 40% C2H2 ; 14,5. Cu 209: Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2 (Ni, to). Sau khi phn ng x y ra hon ton thu c 16 lt hn hp kh (cc kh u o cng iu kin nhit p sut). Th tch ca CH4 v C2H2 trc phn ng l : A. 2 lt v 8 lt. B. 3 lt v 7 lt. C. 8 lt v 2 lt. D. 2,5 lt v 7,5 lt. Cu 210: Hn hp X g m ba kh C3H4, C2H2, H2. Cho X vo bnh kn dung tch 9,7744 lt 25oC, p sut trong bnh l 1 atm, cha mt t bt Ni. Nung nng bnh mt thi gian thu c hn hp kh Y vi dX/Y = 0,75. S mol H2 tham gia phn ng l : A. 0,75. B. 0,3. C. 0,15. D. 0,1. Cu 211: Hn hp A g m H2, C3H8, C3H4. Cho t t 12 lt A qua bt Ni xc tc. Sau phn ng c 6 lt kh duy nht (cc kh o cng iu kin). T khi hi ca A so vi H2 l : A. 11. B. 22. C. 26. D. 13. Cu 212: Hn hp ban u gm 1 ankin, 1 anken, 1 ankan v H2 vi p sut 4 atm. un nng bnh vi Ni xc tc thc hin phn ng cng sau a bnh v nhit ban u c hn hp Y, p sut hn hp Y l 3 atm. T kh i hn hp X v Y so vi H2 ln lt l 24 v x. Gi tr ca x l : A. 18. B. 34. C. 24. D. 32. Cu 213: Hn hp X gm hiro v mt hirocacbon. Nung nng 14,56 lt hn hp X (ktc), c Ni xc tc n khi phn ng hon ton thu c hn hp Y c kh i lng 10,8 gam. Bit t kh i ca Y so vi metan l 2,7 v Y c kh nng lm mt mu dung dch brom. Cng thc phn t ca hirocacbon l : A. C3H6. B. C4H6. C. C3H4. D. C4H8. Cu 214: Dn 17,4 gam hn hp kh X g m propin v but-2-in l i tht chm qua bnh ng dung dch AgNO3/NH3 d thy c 44,1 gam kt ta xut hin. Phn trm th tch ca m i kh trong X l : A. C3H4 80 % v C4H6 20 %. B. C3H4 25 % v C4H6 75 %. C. C3H4 75 % v C4H6 25 %. D. Kt qu khc. Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng 51
Cu 215: Cht hu c X c cng thc phn t C6H6 mch thng. Bit 1 mol X tc dng vi AgNO3 d trong NH3 to ra 292 gam kt ta. CTCT ca X c th l : A. CH CCCCH2CH3. C. CHCCH2CH=C=CH2. B. CHCCH2CCCH3. D. CHCCH2CH2CCH. Cu 216: Mt hirocacbon A mch thng c CTPT l C6H6. Khi cho A tc dng vi dung dch AgNO3/NH3 d thu c hp cht hu c B c MB MA= 214 vC. CTCT ca X c th l : A. CHCCH2CH2CCH. B. CH3C CCH2CCH. C. CHCCH(CH3) CCH. D. CH3CH2CCCCH. Cu 217: Mt mol hirocacbon X t chy cho ra 5 mol CO2, 1 mol X phn ng vi 2 mol AgNO3/NH3. Xc nh CTCT ca X ? B. CH2=CHCH2C CH. A. CH2=CHCH=CHCH3. C. HC CCH2C CH. D. CH2=C =CHCH=CH2. Cu 218: t chy 2 gam hirocacbon A (kh trong iu kin thng) c CO2 v 2 gam H2O. Mt khc 2,7 gam A tc dng vi dung dch AgNO3/NH3 d c m gam k t ta. Gi tr m l : A. 8,05 gam. B. 7,35 gam. C. 16,1 gam. D. 24 gam. Cu 219: Dn 4,032 lt (ktc) hn hp kh A g m C2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dc AgNO3 trong NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2 gam kt ta. Kh i lng bnh 2 tng thm 1,68 gam. Th tch ( ktc) ca cc kh trong hn hp A ln lt l : A. 0,672 lt ; 1,344 lt ; 2,016 lt. B. 0,672 lt ; 0,672 lt ; 2,688 lt. C. 2,016 ; 0,896 lt ; 1,12 lt. D. 1,344 lt ; 2,016 lt ; 0,672 lt. Cu 220: un nng hn hp kh g m 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y l i t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z (ktc) c t kh i so vi O2 l 0,5. Kh i lng bnh dung dch brom tng l : A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam. Cu 221: Cho 4,96 gam gm CaC2 v Ca tc dng ht vi nc c 2,24 lt (ktc) hn hp kh X. Dn X qua bt Ni nung nng mt thi gian c hn hp Y. Cho Y qua bnh ng brom d thy thot ra 0,896 lt (ktc) hn hp Z. Cho t kh i ca Z so vi hiro l 4,5. tng khi lng bnh nc brom l A. 0,4 gam. B. 0,8 gam. C. 1,2 gam. D. 0,86 gam. Cu 222: un nng hn hp X g m 0,1 mol C3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc c hn hp Y. Dn ton b Y qua bnh ng dung dch KMnO4 d, thy thot ra 6,72 lt hn hp kh Z (ktc) c t kh i so vi H2 l 12. Bnh ng dung d ch KMnO4 tng s gam l : A. 17,2. B. 9,6. C. 7,2. D. 3,1. Cu 223: Hn hp X g m C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tc thch hp, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom th y kh i lung bnh t ng 10,8 gam v thot ra 4,48 lt kh Z (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l : A. 33,6 lt. B. 22,4 lt. C. 16,8 lt. D. 44,8 lt. Cu 224: t chy hon ton 0,1 mol ankin c 3,6 gam H2O. Nu hiro ho hon ton 0,1 mol ankin ri t chy th lng nc thu c l : A. 4,2 gam. B. 5,2 gam. C. 6,2 gam. D. 7,2 gam. Cu 225: t chy hon ton V lt mt ankin thu c 10,8 gam H2O. Nu cho tt c sn ph m chy hp th ht vo bnh ng nc vi trong th kh i lng bnh tng 50,4 gam. Gi tr ca V l : A. 3,36 lt. B. 2,24 lt. C. 6,72 lt. D. 4,48 lt. 52 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 226: Mt hn hp g m 2 ankin khi t chy cho ra 13,2 gam CO2 v 3,6 gam H2O. Kh i lng brom c th cng vo hn hp trn l : A. 16 gam. B. 24 gam. C. 32 gam. D. 4 gam. Cu 227: t chy hon ton m gam hn hp C2 H6, C3H4, C3H8, C4H10 thu c 35,2 gam CO2 v 21,6 gam H2O. Gi tr ca m l : A. 14,4. B. 10,8. C. 12. D. 56,8. Cu 228: t chy 1 hirocacbon A c 22,4 lt kh CO2 (ktc) v 27 gam H2O. Th tch O2 (ktc) (l) tham gia phn ng l : A. 24,8. B. 45,3. C. 39,2. D. 51,2. Cu 229: Hn hp X gm 0,1 mol C2H2; 0,15 mol C2H4 ; 0,2 mol C2H6 v 0,3 mol H2. un nng X vi bt Ni xc tc mt thi gian c hn hp Y. t chy hon ton hn hp Y c s gam CO2 v H2O ln lt l : A. 39,6 v 23,4. B. 3,96 v 3,35. C. 39,6 v 46,8. D. 39,6 v 11,6. Cu 230: Chia hn hp g m C3H6, C2H4, C2H2 thnh 2 phn u nhau. - Phn (1) : em t chy hon ton thu c 22,4 lt CO2 (ktc). - Phn (2) : em hiro ho hon ton ri t chy th th tch CO2 thu c l : A. 22,4 lt. B. 11,2 lt. C. 44,8 lt. D. 33,6 lt. Cu 231: Hn hp X c t khi so vi H2 l 21 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng kh i lng ca CO2 v H2O thu c l : A. 18,60 gam. B. 18,96 gam. C. 20,40 gam. D. 16,80 gam. Cu 232: Hn hp X c t kh i so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l : A. 18,60 gam. B. 18,96 gam. C. 20,40 gam. D. 16,80 gam. Cu 233: t chy hon ton mt th tch g m C2H6 v C2H2 thu c CO2 v nc c t l s mol l 1 : 1. Phn trm th tch ca m i kh trong hn hp u l : A. 50% v 50%. B. 30% v 70%. C. 25% v 75%. D. 70% v 30%. Cu 234: t chy hon ton hn hp M g m mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn % v s mol ca X v Y trong hn hp M ln lt l : A. 35% v 65%. B. 75% v 25%. C. 20% v 80%. D. 50% v 50%. Cu 235*: Dn V lt (ktc) hn hp X g m axetilen v hiro c khi lng l m gam i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3 thu c 12 gam kt ta. Kh i ra kh i dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z c 2,24 lt kh CO2 (ktc) v 4,5 gam H2O. a. Gi tr ca V l : A. 11,2. B. 13,44. C. 5,60. D. 8,96. b. Gi tr ca m l : A. 5,6 gam. B. 5,4gam. C. 5,8 gam. D. 6,2 gam. Cu 236*: Cho hn hp X g m CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th kh i lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l : A. 40%. B. 20%. C. 25%. D. 50%.
Cu 237*: Mt hn hp X gm C2H2, C3H6, CH4. t chy hon ton 11 gam hn hp X thu c 12,6 gam H2O. Nu cho 11,2 lt hn hp X (ktc) qua dung dch brom d thy c 100 gam brom phn ng. Thnh phn % th tch ca X ln lt l : A. 50%; 25% ; 25%. B. 25% ; 25; 50%. C.16% ; 32; 52%. D. 33,33%; 33,33; 33,33%. Cu 238*: A l hn hp gm C2H6, C2H4 v C3H4. Cho 6,12 gam A tc dng vi lng d dung dch AgNO3/NH3 c 7,35 gam kt ta. Mt khc 2,128 lt A (ktc) phn ng va vi 70 ml dung dch Br2 1M. % C2H6 ( theo khi lng) trong 6,12 gam A l : A. 49,01%. B. 52,63%. C. 18,3%. D. 65,35%. Cu 239: Khi iu ch axetilen bng phng php nhit phn metan c hn hp A gm axetilen, hiro, metan. Bit t khi ca A so vi hiro l 5. Vy hiu sut chuyn ha metan thnh axetilen l : A. 60%. B. 70%. C. 80%. D. 90%. Cu 240: Cho canxi cacbua k thut (ch cha 80% CaC2 nguyn cht) vo nc d, th thu c 3,36 lt kh (ktc). Kh i lng canxi cacbua k thut dng l : A. 9,6 gam. B. 4,8 gam C. 4,6 gam. D. 12 gam Cu 241: C 20 gam mt mu CaC2 (c ln tp cht tr) tc dng vi nc thu c 7,4 lt kh axetilen (20oC, 740 mmHg). Cho rng phn ng xy ra hon ton. tinh khit ca mu CaC2 l : A. 64%. B. 96%. C. 84%. D. 48%. Cu 242: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC 3 theo s trn th cn V m kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) : A. 224,0. B. 448,0. C. 286,7. D. 358,4. Cu 243: Hn hp kh X g m anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c kh i lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l : A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,1 mol C3H6 v 0,2 mol C3H4. C. 0,2 mol C2H4 v 0,1 mol C2H2. D. 0,2 mol C3H6 v 0,1 mol C3H4. Cu 244: X, Y, Z l 3 hirocacbon th kh trong iu kin thng, khi phn hu m i cht X, Y, Z u to ra C v H2, th tch H2 lun gp 3 ln th tch hirocacbon b phn hu v X, Y, Z khng phi l ng phn. CTPT ca 3 cht l : A. C2H6, C3H6, C4H6. B. C2H2, C3H4, C4H6. C. CH4, C2H4, C3H4. D. CH4, C2H6, C3H8. Cu 245: X l mt hirocacbon khng no mch h, 1 mol X c th lm mt mu ti a 2 mol brom trong nc. X c % khi lng H trong phn t l 10%. CTPT X l : A. C2H2. B. C3H4. C. C2H4. D. C4H6. Cu 246: A l hirocacbon mch h, th kh (kt), bit 1 mol A tc dng c ti a 2 mol Br2 trong dung dch to ra hp cht B (trong B brom chim 88,88% v kh i lng. Vy A c cng thc phn t l : B. C2H2. C. C4H6. D. C3H4. A. C5H8. Cu 247: 4 gam mt ankin X c th lm mt mu ti a 100 ml dung dch Br2 2M. CTPT X l : A. C5H8. B. C2H2. C. C3H4. D. C4H6. o Cu 248: 25 C v p sut 1atm, 4,95 gam hn hp kh g m hai hirocacbon thuc cng mt dy ng ng k tip chim th tch 3,654 lt. Nu cho 14,95 gam hn hp kh X hp th vo bnh ng dung dch brom d th c 48 gam Br2 b mt mu. Hai hirocacbon l : A. C2H2 v C3H4. B. C4H6 v C5H8. C. C3H4 v C4H6. D. C A, B, C. 54 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 249: X l mt hirocacbon kh (ktc), mch h. Hiro ho hon ton X thu c hirocacbon no Y c khi lng phn t gp 1,074 ln kh i lng phn t X. Cng thc phn t X l : A. C2H2. B. C3H4. C. C4H6. D. C3H6. Cu 250: Cho 28,2 gam hn hp X g m 3 ankin ng ng k tip qua mt lng d H2 (to, Ni) phn ng xy ra hon ton. Sau phn ng th tch th tch kh H2 gim 26,88 lt (ktc). CTPT ca 3 ankin l : A. C2H2, C3H4, C4H6. B. C3H4, C4H6, C5H8. C. C4H6, C5H8, C6H10. D. C A, B u ng. Cu 251: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H2 c hn hp Y. Khi cho Y qua Pt nung nng th thu c kh Z c t kh i i vi CO2 bng 1 (phn ng cng H2 hon ton). Bit rng VX = 6,72 lt v VH 2 = 4,48 lt. CTPT v s mol A, B trong hn hp X l (Cc th tch kh o kc) : A. 0,1 mol C2H6 v 0,2 mol C2H2. B. 0,1 mol C3H8 v 0,2 mol C3H4. C. 0,2 mol C2H6 v 0,1 mol C2H2. D. 0,2 mol C3H8 v 0,1 mol C3H4. Cu 252: Mt hn hp X g m 1 ankin v H2 c V = 8,96 lt (ktc) v mX = 4,6 gam. Cho hn hp X i qua Ni nung nng, phn ng hon ton cho ra hn hp kh Y, c t kh i d Y X = 2. S mol H2 phn ng ; kh i lng ; CTPT ca ankin l : A. 0,16 mol ; 3,6 gam ; C2H2. B. 0,2 mol ; 4 gam ; C3H4. C. 0,2 mol ; 4 gam ; C2H2. D. 0,3 mol ; 2 gam ; C3H4. Cu 253: Hn hp X g m 1 ankin th kh v hiro c t kh i hi so vi CH4 l 0,425. Nung nng hn hp X vi xc tc Ni phn ng hon ton thu c hn hp kh Y c t kh i hi so vi CH4 l 0,8. Cho Y i qua bnh ng dung dch brom d, khi lng bnh t ng ln bao nhiu gam ? A. 8. B. 16. C. 0. D. Khng tnh c. Cu 254: Hn hp X g m propin v mt ankin A c t l mol 1:1. Ly 0,3 mol X tc dng vi dung dch AgNO3/NH3 d thu c 46,2 gam kt ta. A l : A. But-1-in. B. But-2-in. C. Axetilen. D. Pent-1-in. Cu 255: Mt hn hp 2 hirocacbon thuc cng dy ng ng (ankan, anken, ankin) t chy cho ra 26,4 gam CO2 v 8,1 gam H2O. Dy ng ng, tng s mol ca 2 hirocacbon v th tch H2 (ktc) dng bo ha hai hirocacbon trn l : A. Ankin ; 0,2 mol ; 8,96 lt H2. B. Anken ; 0,15 mol ; 3,36 lt H2. C. Ankin ; 0,15 mol ; 6,72 lt H2. D. Anken ; 0,1 mol ; 4,48 lt H2. Cu 256: Trong mt bnh kn cha hirocacbon A th kh (kt) v O2 (d). Bt tia la in t chy ht A a hn hp v iu kin ban u trong % th tch ca CO2 v hi nc ln lt l 30% v 20%. Cng thc phn t ca A v % th tch ca hirocacbon A trong hn hp l : A. C3H4 v 10%. B. C3H4 v 90%. C. C3H8 v 20%. D. C4H6 v 30%. Cu 257: t chy hon ton V lt (ktc) mt ankin thu c 7,2 gam H2O. Nu cho tt c sn phm chy hp th ht vo bnh ng nc vi trong d th kh i lng bnh tng 33,6 gam. a. V c gi tr l : A. 3,36 lt. B. 6,72 lt. C. 2,24 lt. D. 4,48 lt. b. Ankin l : B. C5H8. C. C4H6. D. C2H2. A. C3H4. Cu 258: t chy hon ton mt ankin X th kh thu c H2O v CO2 c tng khi lng l 23 gam. Nu cho sn phm chy i qua dung dich Ca(OH)2 d, c 40 gam kt ta. Cng thc phn t ca X l : A. C3H4. B. C2H2. C. C4H6. D. C5H8.
Cu 259: t chy mt hirocacbon M thu c 17,6 gam CO2 v 3,6 gam H2O. Xc nh dy ng ng ca M, CTPT, CTCT ca M. Lng cht M ni trn c th lm mt mu bao nhiu lt nc brom 0,1M ? A. Anken, C3H6, CH3CH=CH2 ; 2 lt. B. Ankin, C3H4, CH3C CH ; 4 lt. C. Anken, C2H4, CH2=CH2 ; 2 lt. D. Ankin, C2H2, CH CH ; 4 lt. 3 Cu 260: t chy mt hirocacbon M thu c s mol nc bng s mol CO2 v s mol CO2 4 nh hn 5 ln s mol M. Xc nh CTPT v CTCT ca M bit rng M cho kt ta vi dung dch AgNO3/NH3. A. C4H6 v CH3CH2C CH. B. C4H6 v CH2=C=CHCH3. C. C3H4 v CH3C CH. D. C4H6 v CH3C CCH3. Cu 261: t chy hon ton 5,4 gam mt hirocacbon A ri cho sn phm chy i qua bnh 1 ng dung dch H2SO4 c, d ; bnh 2 ng dung dch Ba(OH)2 d thy khi lng bnh 1 tng 5,4 gam; bnh 2 tng 17,6 gam. A l cht no trong nhng cht sau ? (A khng tc dng vi dung dch AgNO3/NH3) A. But-1-in. B. But-2-in. C. Buta-1,3-ien. D. B hoc C. Cu 262: t chy mt hirocacbon A thu c s mol nc bng 4/5 s mol CO2. Xc nh dy ng ng ca A bit A ch c th l ankan, ankaien, ankin v A c mch h. C bao nhiu ng phn ca A cng nc c xc tc cho ra 1 xeton v bao nhiu ng phn cho kt ta vi dung dch AgNO3/NH3. Cho kt qu theo th t A. Ankin, ankaien, C5H8 ; 3 v 2 ng phn. B. Ankin, C4H6 ; 1 v 1 ng phn. C. Ankin, C5H8 ; 2 v 1 ng phn. D. Anken, C4H10 ; 0 v 0 ng phn. Cu 263: t chy mt hn hp X gm 2 hirocacbon ng ng k tip thu c 22 gam CO2 v 5,4 gam H2O. Dy ng ng, CTPT v s mol ca A, M l : A. ankin ; 0,1 mol C2H2 v 0,1 mol C3H4. B. anken ; 0,2 mol C2H4 v 0,2 mol C3H6. C. anken ; 0,1 mol C3H6 v 0,2 mol C4H8. D. ankin ; 0,1 mol C3H4 v 0,1 mol C4H6. Cu 264: t chy hon ton 2 hirocacbon mch h lin tip trong dy ng ng thu c 44 gam CO2 v 12,6 gam H2O. Hai hirocacbon l : A. C3H8, C4H10. B. C2H4, C3H6. C. C3H4, C4H6. D. C5H8, C6H10. Cu 265: Hn hp kh X gm hai hirocacbon k tip nhau trong dy ng ng. Oxi ho hon ton m gam hn hp X, sn phm chy cho i qua bnh (1) ng dung dch H2SO4 c. Bnh (2) ng dung dch NaOH d th thy kh i lng bnh (1) tng 9 gam v bnh (2) tng 30,8 gam. Ph n trm th tch ca hai kh l : A. 50%; 50%. B. 25%; 75%. C. 15%; 85%. D. 65%; 65%. Cu 266: t chy m gam hirocacbon A th kh trong iu kin thng c CO2 v m gam H2O. t chy hon ton 0,1 mol hirocacbon B l ng ng k tip ca A ri hp th ton b sn phm chy vo bnh nc vi trong d thy khi lng bnh t ng x gam. Gi tr x l : A. 29,2 gam. B. 31 gam. C. 20,8 gam. D. 16,2 gam. Cu 267: Trong mt bnh kn dung tch 6 lt c cha hn hp X gm hai hirocacbon thuc cng dy ng ng, H2 v mt t bt Ni c th tch khng ng k 19,68oC v 1atm. Nung nng bnh mt thi gian thu c hn hp kh Y. Bt tia la in t chy ht Y thu c 15,4 gam CO2 v 7,2 gam nc. Phn trm th tch ca m i kh trong X l : A. C3H4 : 20%, C4H6 : 20% v H2 : 60%. B. C2H2 : 10%, C4H6 : 30% v H2 : 60%. C. C2H2 : 20%, C3H4 : 20% v H2 : 60%. D. C A v B u ng. 56 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 268: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o trong cng iu kin nhit v p sut). Cng thc phn t ca X l : A. C2H4. B. CH4. C. C2H6. D. C3H8. Cu 269: X l hn hp kh g m 2 hirocacbon. t chy 1 lt hn hp X c 1,5 lt CO2 v 1,5 lt hi H2O (cc th tch kh o cng iu kin). CTPT ca 2 hirocacbon l : A. CH4, C2H2. B. C2H6, C2H4. C. C3H8, C2H6. D. C6H6, C2H4. Cu 270: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v t l s mol nc v CO2 i vi K, L, M tng ng l 0,5 ; 1 ; 1,5. CTPT ca K, L, M (vit theo th t tng ng) l : B. C3H8, C3H4, C2H4. A. C2H4, C2H6, C3H4. C. C3H4, C3H6, C3H8. D. C2H2, C2H4, C2H6. Cu 271: Trong bnh kn cha hirocacbon X v hiro. Nung nng bnh n khi phn ng hon ton thu c kh Y duy nht. cng nhit , p sut trong bnh trc khi nung nng g p 3 ln p sut trong bnh sau khi nung. t chy mt lng Y thu c 8,8 gam CO2 v 5,4 gam nc. Cng thc phn t ca X l : A. C2H2. B. C2H4. C. C4H6. D. C3H4. Cu 272: Cho 17,92 lt hn hp X g m 3 hirocacbon kh l ankan, anken v ankin ly theo t l mol 1:1:2 l i qua bnh ng dung dch AgNO3/NH3 ly d thu c 96 gam kt t a v hn hp kh Y cn li. t chy hon ton hn hp Y thu c 13,44 lt CO2. Bit th tch o ktc. Kh i lng ca X l : A. 19,2 gam. B. 1,92 gam. C. 3,84 gam. D. 38,4 gam. Cu 273: Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h l i t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v m bnh tng thm 6,7 gam. CTPT ca 2 hirocacbon l : B. C2H2 v C3H8. C. C2H2 v C4H8. D. C2H2 v C4H6. A. C3H4 v C4H8. Cu 274: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2 (ktc). CTPT ca hai hirocacbon l : A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. Cu 275: t chy hon ton m gam hirocacbon th kh, mch h, nng hn khng kh thu c 7,04 gam CO2. Sc m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l : A. 2 gam. B. 4 gam. C. 10 gam D. 2,08 gam. Cu 276: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04 gam CO2. Sc m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l : A. 2 gam. B. 4 gam. C. 2,08 gam. D. A hoc C.
CHUYN 4 :
HIROCACBON THM
BI TP TRC NGHIM V BENZEN, ANKYLBENZEN V MT S HIDROCACBON THM KHC

Cu 1: Trong phn t benzen, cc nguyn t C u trng thi lai ho : A. sp. B. sp2. C. sp3. D. sp2d. Cu 2: Trong phn t benzen : A. 6 nguyn t H v 6 nguyn t C u nm trn 1 mt phng. B. 6 nguyn t H nm trn cng mt mt phng khc vi mt phng ca 6 nguyn t C. C. Ch c 6 nguyn t C nm trong cng mt mt phng. D. Ch c 6 nguyn t H nm trong cng mt mt phng. Cu 3: Trong vng benzen m i nguyn t C dng 1 obitan p cha tham gia lai ho to ra : A. 2 lin kt pi ring l. B. 2 lin kt pi ring l. C. 1 h lin kt pi chung cho 6 C. D. 1 h lin kt xigma chung cho 6 C. Cu 4: Cho cc cng thc :
H
(1)
(2)
(3)
Cu to no l ca benzen ? A. (1) v (2). B. (1) v (3). C. (2) v (3). D. (1) ; (2) v (3). Cu 5: Ankylbenzen l hirocacbon c cha A. vng benzen. B. gc ankyl v vng benzen. C. gc ankyl v hai vng benzen. D. gc ankyl v mt vng benzen. Cu 6: Dy ng ng ca benzen (gm benzen v ankylbenzen) c cng thc chung l : A. CnH2n+6 (n 6). B. CnH2n-6 (n 3). C. CnH2n-6 (n 6). D. CnH2n-6 (n 6). Cu 7: Trong cc cu sau, cu no sai ? A. Benzen c CTPT l C6H6. B. Cht c CTPT C6H6 phi l benzen. C. Cht c cng thc n gin nht l CH khng ch l benzen. D. Benzen c cng thc n gin nht l CH. Cu 8: Cu no ng nht trong cc cu sau y ? A. Benzen l mt hirocacbon. B. Benzen l mt hirocacbon no. C. Benzen l mt hirocacbon khng no. D. Benzen l mt hirocacbon thm. Cu 9: Stiren c cng thc phn t C8H8 v c cng thc cu to : C6H5CH=CH2. Cu no ng khi ni v stiren ? A. Stiren l ng ng ca benzen. B. Stiren l ng ng ca etilen. C. Stiren l hirocacbon thm. D. Stiren l hirocacbon khng no. Cu 10: Cht no sau y c th cha vng benzen ? A. C10H16. B. C9H14BrCl. C. C8H6Cl2. D. C7H12. 58 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 11: Cht no sau y khng th cha vng benzen ? A. C8H10. B. C6H8. C. C8H10. D. C9H12. Cu 12: Cng thc tng qut ca hirocacbon l CnH2n+2-2a. i vi stiren (C8H8), gi tr ca n v a ln lt l : A. 8 v 5. B. 5 v 8. C. 8 v 4. D. 4 v 8. Cu 13: Cng thc tng qut ca hirocacbon l CnH2n+2-2a. i vi naphtalen (C10H8), gi tr ca n v a ln lt l : A. 10 v 5. B. 10 v 6. C. 10 v 7. D. 10 v 8. Cu 14: C 5 cng thc cu to :
CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
CH3
l cng thc ca my cht ? A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. Cu 15: Cho cc cht : (1) C6H5CH3 (2) p-CH3C6H4C2H5 (3) C6H5C2H3 (4) o-CH3C6H4CH3 Dy g m cc cht l ng ng ca benzen l : A. (1) ; (2) v (3). B. (2) ; (3) v (4). C. (1) ; (3) v (4). D. (1) ; (2) v (4). Cu 16: C7H8 c s ng phn thm l : A. 1. B. 2. C. 3. D. 4. Cu 17: ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen ? A. 2. B. 3. C. 4. D. 5. Cu 18: ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen ? A. 6. B. 7. C. 8. D. 9. Cu 19: S lng ng phn ch cha vng benzen ng vi cng thc phn t C9H10 l : A. 7. B. 8. C. 9. D. 6. Cu 20: A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A l : A. C3H4. B. C6H8. C. C9H12. D. C12H16. Cu 21: C 4 tn gi : o-xilen; o-imetylbenzen; 1,2-imetylbenzen; etylbenzen. l tn ca m y cht ? A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. Cu 22: m-Xilen c cng thc cu t o nh th no ? CH3 CH2 CH3 A.
CH3
B.
CH3
CH3
CH3
C.
D.
CH3
Cu 23: CH3C6H4C2H5 c tn gi l : A. etylmetylbenzen. C. p-etylmetylbenzen. Cu 24: Cht (CH3)2CHC6H5 c tn gi l : A. propylbenzen. C. iso-propylbenzen. Cu 25: Iso-propylbenzen cn gi l : A.Toluen. B. Stiren. Cu 26: Cho hirocacbon thm : CH
3
B. metyletylbenzen. D. p-metyletylbenzen. B. n-propylbenzen. D. imetylbenzen. C. Cumen. D. Xilen.
Tn gi ca hirocacbon trn l : A. m-etyltoluen. C. 1-etyl-3-metylbenzen. Cu 27: Cho hirocacbon thm :
C 2H5
B. 3-etyl-1-metylbenzen. D. A, B, C u ng.
CH=CH2
CH3
Tn gi ca ca hirocacbon trn l : A. m-vinyltoluen. C. m-metylstiren. Cu 28: Cht
B. 3-metyl-1-vinylbenzen. D. A, B, C u ng. c tn l g ?
CH2 CH2 CH2 CH3
CH3 CH2 CH3 A. 1-butyl-3-metyl-4-etylbenzen. C. 1-etyl-2-metyl-4-butylbenzen.

Cu 29: Cht
B. 1-butyl-4-etyl-3-metylbenzen. D. 4-butyl-1-etyl-2-metylbenzen. c tn l g ?
CH3 CH3 CH2
CH3
A. 1,4-imetyl-6-etylbenzen. C. 2-etyl-1,4-imetylbenzen. B. 1,4-imetyl-2-etylbenzen. D. 1-etyl-2,5-imetylbenzen.
Cu 30: Cu to ca 4-cloetylbenzen l :
C 2 H5
C2H5
C 2H 5
C 2H 5 Cl
A.
Cl
B.
Cl
C.
D.
Cl
Cu 31: iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen ? A. v tr 1,2 gi l ortho. B. v tr 1,4 gi l para. C. v tr 1,3 gi l meta. D. v tr 1,5 gi l ortho. Cu 32: Mt ankylbenzen A c cng thc C9H12, cu t o c tnh i xng cao. Vy A l : A. 1,2,3-trimetyl benzen. B. n-propyl benzen. C. iso-propyl benzen. D. 1,3,5-trimetyl benzen. Cu 33: Mt ankylbenzen A (C12H18) cu to c tnh i xng cao. Tn gi ca A l : A. 1,3,5-trietylbenzen. B. 1,2,4-tri etylbenzen. C. 1,2,3-tri metylbenzen. D. 1,2,3,4,5,6-hexaetylbenzen. Cu 34: Cho cc cht (1) benzen ; (2) toluen; (3) xiclohexan; (4) hex-5-trien; (5) xilen; (6) cumen. Dy g m cc hirocacbon thm l : A. (1) ; (2) ; (3) ; (4). B. (1) ; (2) ; (5) ; (6). C. (2) ; (3) ; (5) ; (6). D. (1) ; (5) ; (6) ; (4). Cu 35: Gc C6H5CH2 v gc C6H5 c tn gi l : A. phenyl v benzyl. B. vinyl v anlyl. C. anlyl v vinyl. D. benzyl v phenyl. Cu 36: Hot tnh sinh hc ca benzen, toluen l : A. Gy hi cho sc khe. B. Khng gy hi cho sc khe. C. Gy nh hng tt cho sc khe. D. Ty thuc vo nhit c th gy hi hoc khng gy hi. Cu 37: Tnh cht no sau y khng phi ca ankylbenzen ? A. Khng mu sc. B. Khng mi v. C. Khng tan trong nc. D. Tan nhiu trong cc dung mi hu c. Cu 38: Phn ng chng minh tnh cht no; khng no ca benzen ln lt l : A. th, cng. B. cng, nitro ho. C. chy, cng. D. cng, brom ho. Cu 39: Phn ng no sau y khng xy ra ? A. Benzen + Cl2 (as). B. Benzen + H2 (Ni, p, to). C. Benzen + Br2 (dd). D. Benzen + HNO3 ()/H2SO4 (). Cu 40: Tnh cht no khng phi ca benzen ? A. D th. B. Kh cng. C. Bn vi cht oxi ha. D. Km bn vi cc cht oxi ha. Cu 41: Tnh cht no khng phi ca benzen ? A. Tc dng vi Br2 (to, Fe). B. Tc dng vi HNO3 ()/H2SO4 (). C. Tc dng vi dung dch KMnO4. D. Tc dng vi Cl2 (as).
Cu 42: Phn ng ca benzen vi cc cht no sau y gi l phn ng nitro ha ? A. HNO3 m c. B. HNO2 c/H2SO4 c. C. HNO3 long/H2SO4 c. D. HNO3 c/H2SO4 c. Cu 43: Tnh cht no khng phi ca toluen ? A. Tc dng vi Br2 (to, Fe). B. Tc dng vi Cl2 (as). o C. Tc dng vi dung dch KMnO4, t . D. Tc dng vi dung dch Br2. Cu 44: Mt ankylbenzen A (C9H12), tc dng vi HNO3 c (H2SO4 c) theo t l mol 1:1 to ra 1 dn xut mononitro duy nht. Vy A l : A. n-propylbenzen. B. p-etylmetylbenzen. C. iso-propylbenzen D. 1,3,5-trimetylbenzen. Cu 45: Khi trn vng benzen c sn nhm th X, th nhm th hai s u tin th vo v tr o- v p-. Vy X l nhng nhm th no ? B. OCH3, NH2, NO2. A. CnH2n+1, OH, NH2. C. CH3, NH2, COOH. D. NO2, COOH, SO3H. Cu 46: Khi trn vng benzen c sn nhm th X, th nhm th hai s u tin th vo v tr m - . Vy X l nhng nhm th no ? B. OCH3, NH2, NO2. A. CnH2n+1, OH, NH2. C. CH3, NH2, COOH. D. NO2, COOH, SO3H. Cu 47: Cho s :
Nhm X, Y ph hp s trn l : A. X(CH3), Y(NO2). C. X(NH2), Y(CH3). Cu 48: Cho s :
B. X(NO2), Y(CH3). D. A, C u ng.
Nhm X, Y ph hp s trn l : A. X(CH3), Y(Cl). B. X(CH3), Y(NO2). C. X(Cl), Y(CH3). D. A, B, C u ng. Cu 49: C2H2 A B m-brombenzen. A v B ln lt l : A. Benzen ; nitrobenzen. B. Benzen ; brombenzen. C. Nitrobenzen ; benzen. D. Nitrobenzen ; brombenzen. Cu 50: C2H2 A B o-bromnitrobenzen. Cng thc ca A l : A. Benzen ; nitrobenzen. B. Benzen ; brombenzen. C. Benzen ; aminobenzen. D. Benzen ; o-ibrombenzen.
HNO3 ac / H2 SO4 ac Cl2 ,Fe,t C,600 C X Y Z Cu 51: Cho s : Axetilen
0 o
CTCT ph hp ca Z l : A. NO 2
Cl
B.
NO 2
C.
NO 2
D. A, B u ng.
Cl
Cu 52: So vi benzen, toluen + dung dch HNO3()/H2SO4() : A. D hn, to ra o nitro toluen v p nitro toluen. B. Kh hn, to ra o nitro toluen v p nitro toluen. C. D hn, to ra o nitro toluen v m nitro toluen. D. D hn, to ra m nitro toluen v p nitro toluen. Cu 53: Cho cc cht sau :
Cl
Kh nng ca phn ng th trn vng benzen t ng theo th t : A. (I) < (IV) < (III) < (V) < (II). B. (II) < (III) < (I) < (IV) < (V). C. (III) < (II) < (I) < (IV) < (V) D. (II) < (I) < (IV) < (V) < (III). Cu 54: Tin hnh th nghim cho nitrobenzen tc dng vi HNO3 ()/H2SO4 (), nng ta thy : A. Khng c phn ng xy ra. B. Phn ng d hn benzen, u tin v tr meta. C. Phn ng kh hn benzen, u tin v tr meta. D. Phn ng kh hn benzen, u tin v tr ortho.
H 2 SO4 Cu 55: 1 mol nitrobenzen + 1 mol HNO3 B + H2O. B l : to
A. m-initrobenzen. B. o-initrobenzen. C. p-initrobenzen. D. B v C u ng. Cu 56: Nitro ho benzen bng HNO3 c/H2SO4 c nhit cao nhn c sn phm no l ch yu? A. 1,2-initrobenzen. B. 1,3-inotrobenzen. C. 1,4-initrobenzen. D. 1,3,5-trinitrobenzen. Cu 57: Chn nguyn liu iu ch hp cht 1,3,5-trinitrobenzen trong s cc dy nguyn liu sau : A. Benzen, HNO3 c, H2SO4 c. B. Toluen, HNO3 c, H2SO4 c. C. Benzen, HNO3. D. Cu A, B ng. Cu 58: Toluen + Cl2 (as) xy ra phn ng : A. Cng vo vng benzen. B. Th vo vng benzen, d dng hn. C. Th nhnh, kh khn hn CH4. D. Th nhnh, d dng hn CH4.
as Cu 59: 1 mol Toluen + 1 mol Cl2 A . A l : A. C6H5CH2Cl. B. p-ClC6H4CH3. C. o-ClC6H4CH3. D. B v C u ng. Cu 60: Cho benzen + Cl2 (as) ta thu c dn xut clo A. Vy A l : A. C6H5Cl. B. p-C6H4Cl2. C. C6H6Cl6. D. m-C6H4Cl2.
Ni, p,t Cu 61: A + 4H2 etylxiclohexan. Cu t o ca A l : A. C6H5CH2CH3. B. C6H5CH3. C. C6H5CH2CH=CH2. D. C6H5CH=CH2. Cu 62: Sn phm chnh khi oxi ha cc ankylbenzen bng KMnO4 /H+ l : A. C6H5COOH. B. C6H5CH2COOH. C. C6H5CH2CH2COOH. D. CO2. Cu 63: Stiren khng phn ng c vi nhng cht no sau y ? A. dung dch Br2. B. khng kh H2, Ni, t o. C. dung dch KMnO4. D. dung dch NaOH. Cu 64: Phn ng no sau y khng dng iu ch benzen ? A. tam hp axetilen. B. kh H2 ca xiclohexan. C. kh H2, ng vng n-hexan. D. tam hp etilen. Cu 65: Phn ng no khng iu ch c toluen ?
o
AlCl3 , t A. C6H6 + CH3Cl C. Tch hiro t metylxiclohexan.
B. Tch hiro chuyn n-heptan thnh toluen. D. tam hp propin. B. metylxiclohexen. D. n-heptan. D. etan.
xt,t Cu 66: A toluen + 4H2. Vy A l : A. metylxiclohexan. C. n-hexan.

+
H Cu 67: Benzen + X etylbenzen. Vy X l : A. axetilen. B. etilen. C. etyl clorua.
trung hp Cu 68: Cho phn ng A 1,3,5-trimetylbenzen. A l : A. axetilen. B. metylaxetilen. C. etylaxetilen. D. imetylaxetilen. Cu 69: ng dng no benzen khng c : A. Lm dung mi. B. Tng hp monome. C. Lm thuc n. D. Dng trc tip lm dc phm. Cu 70: Thuc n TNT c iu ch trc tip t : A. benzen. B. metylbenzen (toluen). C. vinyl benzen. D. p-xilen. Cu 71: phn bit benzen, toluen, stiren ta ch dng 1 thuc th duy nht l : A. dung dch brom. B. Br2 (Fe). C. dung dch KMnO4. D. dung dch Br2 hoc dung dch KMnO4. Cu 72: phn bit c cc cht hex-1-in, toluen, benzen ta dng 1 thuc th duy nht l : A. dung dch AgNO3/NH3. B. dung d ch brom. C. dung dch KMnO4. D. dung dch HCl.
Cu 73: Mt hn hp X gm 2 aren A, R u c M < 120, t kh i ca X i vi C2H6 l 3,067. CTPT v s ng phn ca A v R l : A. C6H6 (1 ng phn) ; C7H8 (1 ng phn). B. C7H8 (1 ng phn) ; C8H10 (4 ng phn). C. C6H6 (1 ng phn) ; C8H10 (2 ng phn). D. C6H6 (1 ng phn) ; C8H10 (4 ng phn). Cu 74: Kh i lng ring ca ancol etylic v benzen ln lt l 0,78 g/ml v 0,88 g/ml. Kh i l ng ring c a m t h n h p g m 600 ml ancol etylic v 200 ml benzen (cc gi tr c o trong cng iu kin v gi s khi pha trn th tch hn hp bng tng th tch cc cht pha trn) l A. 0,805 g/ml. B. 0,795 g/ml. C. 0,826 g/ml. D. 0,832 g/ml. Cu 75: Lng clobenzen thu c khi cho 15,6 gam C6H6 tc dng ht vi Cl2 (xc tc bt Fe) v i hiu sut phn ng t 80% l : A. 14 gam. B. 16 gam. C. 18 gam. D. 20 gam. Cu 76: Cho 100 ml bezen (d = 0,879 g/ml) tc dng vi mt lng va brom l ng (xc tc bt st, un nng) thu c 80 ml brombenzen (d = 1,495 g/ml). Hiu sut brom ha t l : A. 67,6%. B. 73,49%. C. 85,3%. D. 65,35% Cu 77: Hn hp C6H6 v Cl2 c t l mol 1 : 1,5. Trong iu kin c xc tc bt Fe, to, hiu sut 100%. Sau phn ng thu c cht g ? bao nhiu mol ? A.1 mol C6H5Cl ; 1 mol HCl ; 1 mol C6H4Cl2. B. 1,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5mol C6H4Cl2 . C. 1 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2. D. 0,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2. Cu 78: Mt hp cht hu c c vng benzen c CTGN l C3H2Br v M = 236. G i tn hp cht ny bit rng hp cht ny l sn phm chnh trong phn ng gia C6H6 v Br2 (xc tc Fe). A. o-hoc p-ibrombenzen. B. o-hoc p-ibromuabenzen. C. m-ibromuabenzen. D. m-ibrombenzen. Cu 79: Nitro ha benzen c 14,1 gam hn hp hai cht nitro c khi lng phn t hn km nhau 45 vC. t chy hon ton hn hp hai cht nitro ny c 0,07 mol N2. Hai cht nitro l : A. C6H5NO2 v C6H4(NO2)2. B. C6H4(NO2)2 v C6H3(NO2)3. C. C6H3(NO2)3 v C6H2(NO2)4. D. C6H2(NO2)4 v C6H(NO2)5. Cu 80: Nitro ho bezen thu c hn hp 2 cht hu c X v Y, trong Y nhiu hn X mt nhm NO2. t chy hon ton 12,75 gam hn hp X, Y thu c CO2, H2O v 1,232 lt N2 (ktc). Cng thc phn t v s mol X trong hn hp l : A. C6H5NO2 v 0,9. B. C6H5NO2 v 0,09. C. C6H4(NO2)2 v 0,1. D. C6H5NO2 v 0,19. Cu 81: A c cng thc phn t l C8H8, tc dng vi dung dch KMnO4 nhit thng to ra ancol 2 chc. 1 mol A tc dng ti a vi : A. 4 mol H2 ; 1 mol brom. B. 3 mol H2 ; 1 mol brom. C. 3 mol H2 ; 3 mol brom. D. 4 mol H2 ; 4 mol brom. Cu 82: A l dn xut benzen c cng thc nguyn (CH)n. 1 mol A cng ti a 4 mol H2 hoc 1 mol Br2 (dd). Vy A l : A. etylbenzen. B. metylbenzen. C. vinylbenzen. D. ankylbenzen.
Cu 83: A l hirocacbon c %C (theo khi lng) l 92,3%. A tc dng vi dung dch brom d cho sn phm c %C (theo khi lng) l 36,36%. Bit MA < 120. Vy A c cng thc phn t l : A. C2H2. B. C4H4. C. C6H6. D. C8H8. Cu 84: Tin hnh trng hp 10,4 gam stiren c hn hp X gm polistiren v stiren (d). Cho X tc dng vi 200 ml dung dch Br2 0,15M, sau cho dung KI d vo thy xut hin 1,27 gam iot. Hiu sut trng hp stiren l : A. 60%. B. 75%. C. 80%. D. 83,33%. Cu 85: hiro ho etylbenzen ta c stiren; trng hp stiren ta c polistiren vi hiu sut chung 80%. Kh i lng etylbenzen cn dng sn xut 10,4 tn polisitren l : A.13,52 tn. B. 10,6 tn. C. 13,25 tn. D. 8,48 tn. Cu 86: Cho benzen vo 1 l ng Cl2 d ri a ra nh sng. Sau khi phn ng xy ra hon ton thu c 5,82 kg cht sn phm. Tn ca sn phm v kh i lng benzen tham gia phn ng l : A. Clobenzen ; 1,56 kg. B. Hexacloxiclohexan ; 1,65 kg. C. Hexacloran ; 1,56 kg. D. Hexaclobenzen ; 6,15 kg. Cu 87: Dng 39 gam C6H6 iu ch toluen. Kh i lng toluen to thnh l : A. 78 gam. B. 46 gam. C. 92 gam. D. 107 gam. Cu 88: iu ch benzen bng cch trng hp hon ton 5,6 lt axetilen (ktc) th khi lng benzen thu c l : A. 26 gam. B. 13 gam. C. 6,5 gam. D. 52 gam. Cu 89: Th tch khng kh (ktc) cn dng t chy hon ton 0,1 mol benzen l (bit trong khng kh O2 chim 20% th tch) : A. 84 lt. B. 74 lt. C. 82 lt. D. 83 lt. Cu 90: t chy ht m gam 2 ng ng ca benzen A, B thu c 4,05 gam H2O v 7,728 lt CO2 (ktc). Gi tr ca m v s tng s mol ca A, B l : A. 4,59 v 0,04. B. 9,18 v 0,08. C. 4,59 v 0,08. D. 9,14 v 0,04. Cu 91: t chy ht 9,18 gam 2 ng ng ca benzen A, B thu c 8,1 gam H2O v V lt CO2 (ktc). Gi tr ca V l : A. 15,654. B. 15,465. C. 15,546. D. 15,456. Cu 92: t chy hon ton 0,1 mol CxHy thu c 20,16 lt CO2 (ktc) v 10,8 gam H2O (l ng). Cng thc ca CxHy l : A. C7H8. B. C8H10. C. C10H14. D. C9H12. Cu 93: 1,3 gam cht hu c A chy hon ton thu c 4,4 gam CO2 v 0,9 gam H2O. T kh i hi ca A i vi oxi l d tha mn iu kin 3 < d < 3,5. Cng thc phn t ca A l : A. C2H2. B. C8H8. C. C4H4. D. C6H6. Cu 94: t chy hon ton 1,3 gam A (CxHy) to ra 0,9 gam H2O. Cng thc nguyn ca A l : A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n. Cu 95: Cho a gam cht A (CxHy) chy thu c 13,2 gam CO2 v 3,6 gam H2O. Tam hp A thu c B, mt ng ng ca ankylbenzen. Cng thc phn t ca A v B ln lt l : A. C3H6 v C9H8. B. C2H2 v C6H6. C. C3H4 v C9H12. D. C9H12 v C3H4. Cu 96: t 0,13 gam m i cht A v B u cng thu c 0,01 mol CO2 v 0,09 gam H2O. T kh i hi ca A so vi B l 3; t kh i hi ca B so vi H2 l 13. Cng thc ca A v B ln lt l : A. C2H2 v C6H6. B. C6H6 v C2H2. C. C2H2 v C4H4. D. C6H6 v C8H8.
Cu 97: t chy hon ton hi A (CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi. Cng thc phn t ca A l : A. C7H8. B. C8H10. C. C10H14. D. C9H12. Cu 98: t chy hon ton 6 gam cht hu c A, ng ng ca benzen thu c 10,08 lt CO2 (ktc). Cng thc phn t ca A l : A. C9H12. B. C8H10. C. C7H8. D. C10H14. Cu 99: t chy ht 2,295 gam 2 ng ng ca benzen A, B thu c CO2 v 2,025 gam H2O. Dn ton b lng CO2 vo 250 ml dung dch NaOH 1M thu c m gam mu i. Gi tr ca m v thnh phn ca mu i l : A. 16,195 (2 mu i). B. 16,195 (Na2CO3). C. 7,98 (NaHCO3) D. 10,6 (Na2CO3). Cu 100: t chy ht 9,18 gam 2 ng ng k tip thuc dy ca benzen A, B thu c H2O v 30,36 gam CO2. Cng thc phn t ca A v B ln lt l : B. C8H10 ; C9H12. C. C7H8 ; C9H12. D. C9H12 ; C10H14. A. C6H6 ; C7H8. Cu 101: t chy hon ton m gam A (CxHy), thu c m gam H2O. Cng thc nguyn ca A l : A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n. Cu 102: t chy hon ton m gam hirocacbon A, thu c m gam H2O. Cng thc phn t ca A (150 < MA < 170) l : A. C4H6. B. C8H12. C. C16H24. D. C12H18. Cu 103: A (CxHy) l cht lng iu kin thng. t chy A to ra CO2 v H2O v m CO2 : m H2O = 4,9 : 1. Cng thc phn t ca A l : A. C7H8. B. C6H6. C. C10H14. D. C9H12. Cu 104: t X thu c mCO2 : m H2 O = 44 : 9 . Bit X lm mt mu dung dch brom. X l : A. C6H5C2H3. B. CHCHCH=CH2. C. CHCH. D. A hoc B hoc C. Cu 105: t chy hon ton mt th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu kin nhit v p sut), sn phm thu c ch gm CO2 v H2O vi m CO2 : m H2O = 44 : 9. Bit MA < 150. A c cng thc phn t l : A. C4H6O. B. C8H8O. C. C8H8. D. C2H2. Cu 106: t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon ton 5,06 gam X thu c mt th tch hi ng bng th tch ca 1,76 gam oxi trong cng iu kin. Nhn xt no sau y l ng i vi X ? A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung d ch KMnO4 un nng. B. X tc dng vi dung dch Br2 to kt ta trng. C. X c th trng hp thnh PS. D. X tan tt trong nc. Cu 107: A, B, C l ba cht hu c c %C, %H (theo khi lng) ln lt l 92,3% v 7,7%, t l khi lng mol tng ng l 1: 2 : 3. T A c th iu ch B hoc C bng mt phn ng. C khng lm mt mu nc brom. t 0,1 mol B ri dn ton b sn phm chy qua bnh ng dung dch nc vi trong d. a. Khi lng bnh t ng hoc gim bao nhiu gam ? A. Tng 21,2 gam. B. Tng 40 gam. C. Gim 18,8 gam. D. Gim 21,2 gam. b. Khi lng dung dch tng hoc gim bao nhiu gam ? A. Tng 21,2 gam. B. tng 40 gam. C. gim 18,8 gam. D. gim 21,2 gam.
Cu 108: Chn cu ng nht trong cc cu sau : A. Du m l mt cht. B. Du m l mt hn hp nhiu cht. C. Du m l mt hn hp t nhin ca nhiu loi hirocacbon. D. Du m si nhit cao v xc nh. Cu 109: Thnh phn chnh ca kh thin nhin l kh no trong s cc kh sau ? A. H2. B. CO. C. CH4 . D. C2H4. Cu 110: Vin than t ong c to nhiu l nh vi mc ch no sau y ? A. Trng p mt. B. c th treo khi phi. C. gim trng lng. D. than tip xc vi nhiu khng kh gip than chy hon ton. Cu 111: Nhin liu no dng trong i sng hng ngy sau y c coi l sch nht ? A. Du ha. B. Than. C. Ci. D. Kh (gas). Cu 112: t 100 lt kh thin nhin cha 96% CH4, 2% N2, 2% CO2 (v s mol). Th tch kh CO2 thi vo khng kh l : A. 94 lt. B. 96 lt. C. 98 lt. D. 100 lt. Cu 113: Khi t 1,12 lt kh thin nhin cha CH4, N2, CO2 cn 2,128 lt oxi. Cc th tch kh o cng iu kin. Phn trm th tch CH4 trong kh thin nhin l : A. 93%. B. 94%. C. 95%. D. 96%. Cu 114: t chy V lt kh thin nhin cha 96% CH4, 2% N2, 2% CO2 v th tch. Ton b sn phm chy c dn qua dung dch Ca(OH)2 d thy t o ra 4,9 gam kt ta. Gi tr ca V (ktc) l : A. 1,12 lt. B. 2,24 lt. C. 3,36 lt. D. 4,48 lt. Cu 115: Bit 1 mol kh etilen chy hon ton to ra mt nhit lng l 1423 kJ. Nhit lng to ra khi t chy 1 kg etilen l : A. 50821,4 kJ. B. 50281,4 kJ. C. 50128,4 kJ. D. 50812,4 kJ. Cu 116: Bit 1 mol kh axetilen chy hon ton to ra mt nhit lng l 1320 kJ. Nhit lng to ra khi t chy 1 kg axetilen l A. 50679,2 kJ. B. 50976,2 kJ. C. 50697,2 kJ. D. 50769,2 kJ.
CHUYN 5 : DN XUT HALOGEN PHENOL ANCOL

BI TP TRC NGHIM V DN XUT HALOGEN
Cu 1: Cht no sau y l dn xut halogen ca hirocacbon ? A. ClCH2COOH. B. C6H5CH2Cl. C. CH3CH2MgBr. D. CH3COCl. Cu 2: Cht no khng phi l dn xut halogen ca hirocacbon ? A. CH2 = CHCH2Br. B. ClBrCHCF3. C. Cl2CHCF2OCH3. D. C6H6Cl6. Cu 3: Cng thc tng qut ca dn xut iclo mch h c cha mt lin kt ba trong phn t l : A. CnH2n-2Cl2. B. CnH2n-4Cl2. C. CnH2nCl2. D. CnH2n-6Cl2. Cu 4: Cng thc tng qut ca dn xut ibrom khng no mch h cha a lin kt l : A. CnH2n+2-2aBr2. B. CnH2n-2aBr2. C. CnH2n-2-2aBr2. D. CnH2n+2+2aBr2. Cu 5: S ng phn ca C4H9Br l : A. 4. B. 2. C. 3. D. 5. Cu 6: S ng phn dn xut halogen bc I c CTPT C4H9Cl l : A. 5. B. 3. C. 4. D. 2. Cu 7: S ng phn ca C3H5Cl3 l : A. 5. B. 6. C. 3. D. 4. Cu 8: S ng phn ng vi cng thc phn t ca C2H2ClF l : A. 2. B. 3. C. 5. D. 4. Cu 9: S ng phn mch h (k c ng phn hnh hc) ca cht c CTPT l C3H5Br l : A. 2. B. 3. C. 4. D. 5. Cu 10: S lng ng phn ng vi cng thc phn t C3H5Cl l : A. 3. B. 4. C. 5. D. 6. Cu 11: Mt hp cht hu c X c % khi lng ca C, H, Cl ln lt l : 14,28% ; 1,19% ; 84,53%. a. CTPT ca X l : A. CHCl2. B. C2H2Cl4. C. C2H4Cl2. D. mt kt qu khc. b. S CTCT ph hp ca X l : A. 2. B. 3. C. 4. D. 5. Cu 12: Dn xut halogen khng c ng phn cis-trans l : A. CHCl=CHCl. B. CH2=CHCH2F. C. CH3CH=CBrCH3. D. CH3CH2CH=CHCHClCH3.
Cu 13: Hy ghp cc cht k hiu bi cc s ct 2 vo cc loi dn xut halogen ct 1. Ct 1 Ct 2 a. Dn xut halogen loi ankyl 1. CH2=CHCH2C6H4Br b. Dn xut halogen loi anlyl 2. CH2=CHCHBrC6H5 3. CH2=CHBrCH2C6H5 4. CH3C6H4CH2CH2Br A. 4-b ; 2-a ; 1-c ; 3-d. B. 4-a ; 2-d ; 1-c ; 3-b. C. 4-a ; 2-b ; 1-d ; 3-c. D. 4-a ; 2-b ; 1-c ; 3-d. Cu 14: Danh php IUPAC ca dn xut halogen c cng thc cu t o : ClCH2CH(CH3)CHClCH3 l: A. 1,3-iclo-2-metylbutan. B. 2,4-iclo-3-metylbutan. C. 1,3-iclopentan. D. 2,4-iclo-2-metylbutan. Cu 15: Hp cht (CH3)2C=CHC(CH3)2CH=CHBr c danh php IUPAC l : A. 1-brom-3,5-trimetylhexa-1,4-ien. B. 3,3,5-trimetylhexa-1,4-ien-1-brom. C. 2,4,4-trimetylhexa-2,5-ien-6-brom. D. 1-brom-3,3,5-trimetylhexa-1,4-ien. Cu 16: Cho cc cht sau: C6H5CH2Cl ; CH3CHClCH3 ; Br2CHCH3 ; CH2=CHCH2Cl. Tn g i ca cc cht trn ln lt l : A. Benzyl clorua ; isopropyl clorua ; 1,1-ibrometan ; anlyl clorua. B. Benzyl clorua ; 2-clopropan ; 1,2-ibrometan ;1-cloprop-2-en. C. Bhenyl clorua ; isopropylclorua ; 1,1-ibrometan ; 1-cloprop-2-en. D. Benzyl clorua ; n-propyl clorua ; 1,1-ibrometan ; 1-cloprop-2-en. Cu 17: Ghp tn ct 1 vi cng thc ct 2 cho ph hp ? Ct 1 Ct 2 a. CH3Cl 1. phenyl clorua 2. metylen clorua b. CH2=CHCl 3. allyl clorua c. CHCl3 4. vinyl clorua d. C6H5Cl 5. clorofom e. CH2=CH-CH2Cl f. CH2Cl2 A. 1-d, 2-c, 3-e, 4-b, 5-a. B. 1-d, 2-f, 3-b, 4-e, 5-c. C. 1-d, 2-f, 3-e, 4-b, 5-a. D. 1-d, 2-f, 3-e, 4-b, 5-c. Cu 18: Benzyl bromua c cng thc cu t o no sau y? c. Dn xut halogen loi phenyl d. Dn xut halogen loi vinyl A. C.
CHBr CH3
Br
B. CH3 D.
CH2Br
Br
Cu 19: Cho cc dn xut halogen sau : (1) C2H5F (2) C2H5Br Th t gim dn nhit si l : A. (3) > (2) > (4) > (1). C. (1) > (2) > (3) > (4).
(3) C2H5I
(4) C2H5Cl
B. (1) > (4) > (2) > (3). D. (3) > (2) > (1) > (4).
Cu 20: Nh dung dch AgNO3 vo ng nghim cha mt t dn xut halogen CH2=CHCH2Cl, lc nh. Hin tng xy ra l : A. Thot ra kh mu vng lc. B. xut hin kt ta trng. C. khng c hin tng. D. xut hin kt ta vng. Cu 21: Thy phn dn xut halogen no sau y s thu c ancol ? A. CH3CH2Cl. B. CH3CH=CHCl. C. C6H5CH2Cl. D. A v C. Cu 22: un si dn xut halogen X vi nc mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X l : A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Br. D. A hoc C. Cu 23: un si dn xut halogen X vi dung dch NaOH long mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X khng th l : A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Cl. D. C6H5Cl. Cu 24: Cho 5 cht : (1) CH3CH2CH2Cl (2) CH2=CHCH2Cl (3) C6H5Cl (4) CH2=CHCl (5) C6H5CH2Cl un tng cht vi dung dch NaOH long, d, sau gn ly lp nc v axit ho bng dung dch HNO3, sau nh vo dung dch AgNO3 th cc cht c xut hin kt ta trng l : A. (1), (3), (5). B. (2), (3), (5). C. (1), (2), (3), (5). D. (1), (2), (5). Cu 25: Kh nng phn ng th nguyn t clo bng nhm OH ca cc cht c xp theo chiu tng dn t tri sang phi l : A. Anlyl clorua, phenyl clorua, propyl clorua. B. Anlyl clorua, propyl clorua, phenyl clorua. C. Phenyl clorua, anlyl clorua, propyl clorua. D. Phenyl clorua, propyl clorua, anlyl clorua. Cu 26: un cht sau vi dung dch NaOH c, nng, d (to cao, p cao).
Cl CH2 Cl
Sn phm hu c thu c l : A.
HO CH2 Cl
B.
HO
CH2
Cl
C. HO
CH2
ONa
D. NaO
CH2
ONa
Cu 27: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (long, d, to) ta thu c cht no ? A. HOC6H4CH2OH. B. ClC6H4CH2OH. C. HOC6H4CH2Cl. D. KOC6H4CH2OH. Cu 28: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (c, d, to, p) ta thu c cht no? A. KOC6H4CH2OK. B. HOC6H4CH2OH. C. ClC6H4CH2OH. D. KOC6H4CH2OH.
Cu 29: Thy phn dn xut halogen no sau y s thu c ancol ? (1) CH3CH2Cl. (2) CH3CH=CHCl. (3) C6H5CH2Cl. (4) C6H5Cl. A. (1), (3). B. (1), (2), (3). C. (1), (2), (4). D.(1), (2), (3), (4). Cu 30: Khi un nng dn xut halogen X vi dung dch NaOH to thnh hp cht anehit axetic. Tn ca hp cht X l : A. 1,2- ibrometan. B. 1,1- ibrometan. C. etyl clorua. D. A v B ng. Cu 31: X l dn xut clo ca etan. un nng X trong NaOH d thu c cht hu c Y va tc dng vi Na va tc dng vi Cu(OH)2 nhit thng. Vy X l : A. 1,1,2,2-tetracloetan. B. 1,2-icloetan. C. 1,1-icloetan. D. 1,1,1-tricloetan. Cu 32: Trong s cc ng phn ca C3H5Cl3 c th c bao nhiu ng phn khi thu phn trong mi trng kim cho sn phm phn ng c c vi Na v dung dch AgNO3/NH3 to ra Ag ? A. 1. B. 4. C. 3. D. 2. Cu 33: Hp cht X c cng thc phn t C3H5Cl3. Thy phn hon ton X thu c cht Y. Y tcdng c vi Na gii phng H2 v c phn ng trng gng. X c cng thc cu t o l : A. CH 2Cl CHCl CH 2 Cl B. CH 3 CHCl CHCl 2 CH 3 CH 2 CCl3 CH 3 CCl 2 CH 2 Cl C. CH 3 CHCl CHCl 2 CHCl2 CH 2 CH 2 Cl D. CH 2Cl CH 2 CHCl2 CH 2Cl CHCl CH 2 Cl
Cu 34: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c, to cao, p cao thu c cht Y c CTPT l C7H6O. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 1. C. 4. D. 2. Cu 35: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c (to cao, p cao) thu c cht Y c CTPT l C7H7O2Na. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 5. C. 4. D. 2. Cu 36: Cho phn ng sau :
t CH3CCl3 + NaOH d (X) + NaCl + H2O Cng thc cu to ph hp ca X l : A. CH3C(OH)3. B. CH3COONa. C. CH3COOH. D. CH3CHCl(OH)2. Cu 37: Cho phn ng sau : t CH3CHCl2 + NaOH d (X) + NaCl + H2O Cng thc cu to ph hp ca X l : A. CH3CH(OH)2. B. CH3CHO. C. CH3COOH. D. CH3CHCl(OH). Cu 38: Cho s :
o o
Cu(OH)2 NaOH d (X) dung dch xanh lam. C4H8Cl2 CTPT ph hp ca X l : A. CH2ClCH2CH2CH2Cl. B. CH3CHClCH2CH2Cl. C. CH3CH2CHClCH2Cl. D. CH3CH(CH2Cl)2.
Cu 39: Cho s phn ng sau:

Cl2 / 500 C Cl2 / H 2O NaOH Propen A B C Cng thc cu to ph hp ca C l : A. CH3CH2CH2OH. B. CH2=CHCH2OH. C. CH2OHCHOHCH2OH. D. CH3CHOHCH2OH. Cu 40: Cho s :
o
KOH, H 2O Cl2 + Cl2 A glixerol B C3H6 as, 500 o C to
Cc cht A, B tng ng l : A. X: CH2=CHCH2Cl, Y: CH2ClCHClCH2Cl. B. X: CH2ClCHClCH3, Y: CH2ClCHClCH2 Cl. C. X: CH2ClCHClCH3, Y:CH2=CHCH2Cl. D. X: CHCl2CH=CH2, Y: CH2ClCHClCHCl2. Cu 41: S no c th sn xut c glixerol (G) ?
Cl 2 Cl 2 NaOH CH2=CHCH2Cl G A. CH3CH=CH2 CH2ClCHClCH2Cl 500 0 C
Cl2 Cl 2 NaOH B. CH3 CH = CH2 CH2 CH = CH2 CH2 CH CH2 G H2 O 5000 C | | | | OH Cl Cl Cl
C. C3H5(OCOR)3 + 3NaOH D. C A, B, C. Cu 42: Cho s phn ng sau :
C3H5(OH)3
3RCOONa
CH3
Br2/as
Br2/Fe, to
dd NaOH
NaOH n/c, to, p
X, Y, Z, T c cng thc ln lt l A. p-CH3C6H4Br, p-CH2BrC6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH. B. CH2BrC6H5, p-CH2Br-C6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH. C. CH2Br-C6H5, p-CH2Br-C6H4Br, p-CH3C6H4OH, p-CH2OHC6H4OH. D. p-CH3C6H4Br, p-CH2BrC6H4Br, p-CH2BrC6H4OH, p-CH2OHC6H4OH. Cu 43: Cho s :
Cl2 (1:1) HCl NaOH d , t cao, p cao C6H6 (benzen) X Z Y Hai cht hu c Y, Z ln lt l : A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu 44: Cho s phn ng sau : CH4 X Y Z T C6H5OH (X, Y, Z, T l cc cht hu c khc nhau). T l : B. C6H5NH2. C. C6H5NO2. D. C6H5ONa. A. C6H5Cl.
o
Cu 45: Cho s chuyn ho : Benzen A B C Axit picric Cht B l : A. phenylclorua. B. o Crezol. Cu 46: Cho s phn ng :
o
C. Natri phenolat.
D. Phenol.
+ Cl 2 ,500 C + NaOH Ancol anlylic X Y X l cht no sau y ? A. Propan. B. Xiclopropan. C. Propen. D. Propin. Cu 47: Sn phm chnh ca phn ng tch HBr ca CH3CH(CH3)CHBrCH3 l : A. 2-metylbut-2-en. B. 3-metylbut-2-en. C. 3-metyl-but-1-en. D. 2-metylbut-1-en. Cu 48: Sn phm chnh to thnh khi cho 2-brombutan tc dng vi dung dch KOH/ancol, un nng l : A. Metylxiclopropan. B. But-2-ol. C. But-1-en. D. But-2-en. Cu 49: Sn phm chnh ca phn ng sau y l cht no ? KOH / ROH, t CH3CH2CHClCH3 A. CH3CH=CHCH3. B. CH2CHCH(OH)CH3. C. CH3CH2CH=CH2. D. C A v C. Cu 50: S tch hiro halogenua ca dn xut halogen X c CTPT C4H9Cl cho 3 olefin ng phn, X l cht no trong nhng cht sau y ? A. n-Butyl clorua. B. Sec-butyl clorua. C. Iso-butyl clorua. D. Tert-butyl clorua. Cu 51: Cho s sau :
o
Mg, ete + HCl 2 A C C2H5Br B Cht C c cng thc l : A. CH3COOH. B. CH3CH2COOH. C. CH3CH2OH. D. CH3CH2CH2COOH. Cu 52: Cho bt Mg vo ietyl ete khan, khuy mnh, khng thy hin tng g. Nh t t vo etyl bromua, khuy u th Mg tan dn thu c dung dch ng nht. Cc hin tng trn c gii thch nh sau : A. Mg khng tan trong ietyl ete m tan trong etyl bromua. B. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh etyl magiebromua tan trong ete. C. Mg khng tan trong ietyl ete nhng tan trong hn hp ietyl ete v etyl bromua. D. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh C2H5Mg tan trong ete. Cu 53: un nng 13,875 gam mt ankyl clorua Y vi dung dch NaOH, tch b lp hu c, axit ha phn cn li bng dung dch HNO3, nh tip vo dung dch AgNO3 thy to thnh 21,525 gam kt ta. CTPT ca Y l : A. C2H5Cl. B. C3H7Cl. C. C4H9Cl. D. C5H11Cl.
CO
Cu 54: un nng 1,91 gam hn hp X gm C3H7Cl v C6H5Cl vi dung dch NaOH long va , sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng, thu c 1,435 gam kt t a. Kh i lng C6H5Cl trong hn hp u l : A. 1,125 gam. B. 1,570 gam. C. 0,875 gam. D. 2,250 gam. Cu 55: un nng 3,57 gam hn hp A g m propylclorua v phenylclorua vi dung dch KOH long, va , sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 2,87 gam kt ta. Kh i lng phenylclorua c trong hn hp A l : A. 2,0 gam. B. 1,57 gam. C. 1,0 gam. D. 2,57 gam. Cu 56: Hn hp X g m 0,1 mol anlyl clorua ; 0,3 mol benzyl bromua ; 0,1 mol hexyl clorua ; 0,15 mol phenyl bromua. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l : A. 28,7. B. 57,4. C. 70,75. D. 14,35. Cu 57: un nng 27,40 gam CH3CHBrCH2CH3 vi KOH d trong C2H5OH, sau khi phn ng xy ra hon ton thu c hn hp kh X g m hai olefin trong sn phm chnh chim 80%, sn phm ph chim 20%. t chy hon ton X thu c bao nhiu lt CO2 (ktc) ? Bit cc phn ng xy ra vi hiu sut phn ng l 100%. A. 4,48 lt. B. 8,96 lt. C. 11,20 lt. D. 17,92 lt. Cu 58: un si 15,7 gam C3H7Cl vi h n hp KOH/C2H5OH d, sau khi lo i tp cht v dn kh sinh ra qua dung d ch brom d thy c x gam Br2 tham gia phn ng. Tnh x nu hiu sut phn ng ban u l 80%. A. 25,6 gam. B. 32 gam. C. 16 gam. D. 12,8 gam. Cu 59: Da nhn to (PVC) c iu ch t kh thin nhin theo s : CH4 C2H2 CH2=CHCl [CH2CHCl]n. Nu hiu sut ca ton b qu trnh iu ch l 20%, mun iu ch c 1 tn PVC th th tch kh thin nhin (cha 80% metan) iu kin tiu chun cn dng l : B. 4450 m3. C. 4480 m3. D. 6875 m3. A. 4375 m3.
BI TP TRC NGHIM V ANCOL

Cu 60: Dy ng ng ca ancol etylic c cng thc l : A. CnH2n + 2O. B. ROH. C. CnH2n + 1OH. D. Tt c u ng. Cu 61: Cng thc no di y l cng thc ca ancol no, mch h ? A. R(OH)n. B. CnH2n + 2O. C. CnH2n + 2Ox. D. CnH2n + 2 x (OH)x. Cu 62: Cng thc tng qut ca mt ancol bt k l : A. R(OH)n. B. CnH2n + 2O. C. CnH2n + 2Ox. D. CnH2n + 2 2a x (OH)x. Cu 63: Ancol no, n chc c 10 nguyn t H trong phn t c s ng phn l : A. 5. B. 3. C. 4. D. 2. Cu 64: Mt ancol no n chc c %H = 13,04% v kh i lng. Cng thc ca ancol l : A. C6H5CH2OH. B. CH3OH. C. C2H5OH. D. CH2=CHCH2OH. Cu 65: Mt ancol no n chc c % v kh i lng ca oxi l 50%. Cng thc ca ancol l : A. C3H7OH. B. CH3OH. C. C6H5CH2OH. D. CH2=CHCH2OH.
Cu 66: X l ancol mch h c cha 1 lin kt i trong phn t. kh i lng phn t ca X nh hn 60. CTPT ca X l : A. C3H6O. B. C2H4O. C. C2H4(OH)2. D. C3H6(OH)2. Cu 67: C bao nhiu ng phn c cng thc phn t l C4H10O ? A. 6. B. 7. C. 4. D. 5. Cu 68: C bao nhiu ancol thm, cng thc C8H10O ? A. 5. B. 6. C. 7. D. 8. Cu 69: S ng phn ancol ng vi CTPT C5H12O l : A. 8. B. 7. C. 5. D. 6. Cu 70: S ng phn ancol ti a ng vi CTPT C3H8Ox l : A. 4. B. 5. C. 6. D. 7. Cu 71: C bao nhiu ru mch h c s nguyn t C < 4 ? A. 8. B. 6. C. 9. D. 7. Cu 72: Mt ancol no c cng thc thc nghim l (C2H5O)n. CTPT ca ancol c th l : A. C2H5O. B. C4H10O2. C. C4H10O. D. C6H15O3. Cu 73: Hp cht X c CTGN l CH3O. CTPT no sau y ng vi X ? A. C3H9O3. B. C2H6O2. C. CH3O. D. Khng xc nh c. Cu 74: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu : Tng kh i lng ca cacbon v hiro gp 3,625 ln kh i lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l : A. 3. B. 4. C. 2. D. 1. Cu 75: Bc ca ancol l : A. Bc cacbon ln nht trong phn t . B. Bc ca cacbon lin kt vi nhm OH. C. S nhm chc c trong phn t. D. S cacbon c trong phn t ancol. Cu 76: Bc ancol ca 2-metylbutan-2-ol l : A. Bc 4. B. Bc 1. C. Bc 2. D. Bc 3. Cu 77: Cc ancol (CH3)2CHOH ; CH3CH2OH ; (CH3)3COH c bc ancol ln lt l : A. 1, 2, 3. B. 1, 3, 2. C. 2, 1, 3. D. 2, 3, 1. Cu 78: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm kh i lng cacbon bng 68,18% ? A. 2. B. 3. C. 4. D. 5. Cu 79: C bao nhiu ancol bc 3, c cng thc phn t C6H14O ? A. 1. B. 2. C. 3. D. 4. Cu 80: Cc ancol c phn loi trn c s A. s lng nhm OH. B. c im cu to ca gc hirocacbon. C. bc ca ancol. D. Tt c cc c s trn. Cu 81: Cho cc hp cht : (1) CH3CH2OH (2) CH3C6H4OH (3) CH3C6H4CH2OH (4) C6H5OH (5) C6H5CH2OH (6) C6H5CH2CH2OH. Nhng cht no sau y l ru thm ? A. (2) v (3). B. (3), (5) v (6). C. (4), (5) v (6). D. (1), (3), (5) v (6). 76 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 82: Chn pht biu sai : A. Ancol etylic l hp cht hu c, phn t c cha cc nguyn t C, H, O. B. Ancol etylic c CTPT l C2H6O. C. Cht c CTPT C2H6O ch c th l ancol etylic. D. Khi t chy ancol etylic thu c CO2 v H2O. Cu 83: Cu no sau y l ng ? A. Hp cht CH3CH2OH l ancol etylic. B. Ancol l hp cht hu c trong phn t nhm OH. C. Hp cht C6H5CH2OH l phenol. D. Tt c u ng. CH3 | Cu 84: Cht CH3 C OH c tn l g ? | CH3 A. 1,1-imetyletanol. B. 1,1-imetyletan-1-ol. C. isobutan-2-ol. D. 2-metylpropan-2-ol. Cu 85: Ancol iso-butylic c cng thc cu to no ? A. CH 3 CH 2 CH OH B. CH 3 CH CH 2 OH | | CH3 CH3
OH | C. CH 3 C CH3 | CH 3
D. CH 3 CH CH 2 CH 2 OH | CH3
Cu 86: Gi tn hp cht c CTCT nh sau theo danh php IUPAC : CH3 CH = C CH 2 OH | C 2H5 A. 4-hiroxi-3-etylbut-2-en. B. 1-hiroxi-2-etylbut-2-en. C. 3-etylbut-2-en-ol-4 . D. 2-etylbut-2-en-1-ol. Cu 87: Gi tn hp cht c CTCT nh sau theo danh php thng : CH2=CHCH2OH A. 1-hiroxiprop-2-en. B. 3-hiroxiprop-1-en. C. Ancol anylic. D. prop-2-en-1-ol. Cu 88: Tn IUPAC ca ru iso amylic l : A. 2-metylbutan-1-ol. B. 2-etylpropan-1-ol. C. 2 -metylbutan- 4-ol. D. 3-metylbutan-1-ol. Cu 89: Tn quc t ca hp cht c cng thc CH3CH(C2H5)CH(OH)CH3 l : A. 4-etyl pentan-2-ol. B. 2-etyl butan-3-ol. C. 3-etyl hexan-5-ol. D. 3-metyl pentan-2-ol.
Cu 90: Cho cc loi lin kt hiro sau : (1) ... O H ... O H... | | CH3 H (3) ... O H ... O H... | | CH3 CH3
(2) ... O H ... O H... | | H CH3 (4) ... O H ... O H... | | H H
A. (1) v (2). B. (1), (2), (3) v (4). C. (1), (2) v (3). D. (1) v (3). a. Trong dung d ch nc v ancol metylic c nhng loi lin kt hiro no ? A. (1) v (2). B. (1), (2), (3) v (4). C. (1), (2) v (3). D. (1) v (3). b. Loi lin kt hiro no bn nht ? A. (1). B. (2). C. (3). D. (4). c. Loi lin kt hiro no km bn nht ? A. (1). B. (2). C. (3). D. (4). Cu 91: Lin kt H no sau y biu din sai ? A. ... O H ... O H B. ... O H ... O H | | | | C2H5 H C2H5 C2H5 C.
HO ... H O | | CH2 CH2
D. H - C - OH ... H - C- OH || || O O
Cu 92: Ancol etylic tan t t trong nc v c nhit si cao hn hn so vi ankan v cc dn xut halogen c khi lng phn t xp x vi n v : A. Trong cc hp cht trn ch c ancol etylic tc dng vi Na. B. Trong cc hp cht trn ch c ancol etylic c lin kt hiro vi nc. C. Trong cc hp cht trn ch c ancol etylic c lin kt hiro lin phn t . D. B v C u ng. Cu 93: Mt chai ng ancol etylic c nhn ghi 25o c ngha l : A. c 100 ml nc th c 25 ml ancol nguyn cht. B. c 100 gam dung dch th c 25 ml ancol nguyn cht. C. c 100 gam dung dch th c 25 gam ancol nguyn cht. D. c 75 ml nc th c 25 ml ancol nguyn cht. Cu 94: Pha a gam ancol etylic (d = 0,8 g/ml) vo nc c 80 ml ancol 25o. Gi tr a l : A. 16. B. 25,6. C. 32. D. 40. Cu 95: Cho cc cht sau : (1) CH3CH2OH (2) CH3CH2CH2OH (3) CH3CH2CH(OH)CH3 (4) CH3OH Dy no sau y sp xp cc cht ng theo th t tan trong nc tng dn ? A. (1) < (2) < (3) < (4). C. (4) < (1) < (2) < (3). B. (2) < (3) < (1) < (4). D. (3) < (2) < (1) < (4).
Cu 96: Cht hu c no sau y l cht lng iu kin thng ? A. CH3Cl. B. CH3OH. C. CH3OCH3. D. A, B. C u ng. Cu 97: Cht no sau y c nhit si cao nht ? A. CH3CH2OH. B. CH3CH2CH2OH. C. CH3CH2Cl. D. CH3COOH. Cu 98: Cht no sau y c nhit si thp nht ? A. CH3CH2CH2CH2CH2OH B. CH 3 - CH - CH 2 - CH 2 - OH | CH3
C. CH 3 - CH 2 - CH 2 - CH - OH | CH3
CH3 | D. CH3 - CH 2 - C - OH | CH3
Cu 99: A, B, C l 3 cht hu c c cng cng thc CxHyO. Bit % O (theo khi lng) trong A l 26,66%. Cht c nhit si thp nht trong s A, B, C l : A. propan-2-ol. B. propan-1-ol. C. etylmetyl ete. D. propanal. Cu 100: Ancol etylic c ln mt t nc, c th dng cht no sau y lm khan ancol ? A. CaO. B. CuSO4 khan. C. P2O5. D. tt c u c. Cu 101: phn bit ancol etylic tinh khit v ancol etylic c ln nc, c th dng cht no sau y ? A. Na. B. CuO, to C. CuSO4 khan. D. H2SO4 c. Cu 102: Dy gm cc cht u tc dng vi ancol etylic l : A. HBr (to), Ba, CuO (to), CH3COOH (xc tc), CH3OH (H2SO4 c, nng). B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). D. Na2CO3, CuO (to), CH3COOH (xc tc), (CHCO)2O. Cu 103: Cho cc cht sau : (1) Dung dch HCl c (2) Dung dch H2SO4 c ngu i (3) Nc brom (4) Dung dch H2SO4 c, nng (5) Na (6) CuO (to, xt) (7) CH3COOH (8) O2 (to) Nhng cht no tc dng c vi ancol etylic ? A. Tt c cc cht trn. B. (1), (2), (4), (5), (6), (7) v (8) C. (4), (5), (6), (7) v (8) D. (1), (2), (5) v (7). Cu 104: Cho cc phn ng sau :
H 2 SO4 c CH3COOC2H5 C2H5OH + CH3COOH 1 H2 C2H5OH + Na C2H5ONa + 2 H 2 SO4 c 2C2H5OH 140 0 C
H2O (1) (2) (3) (4) D. (2) (4).
CH3OCH3
0
+ H2O
t C2H5OH + CuO CH3CHO + Cu + H2O Cc phn ng lm phn ct lin kt OH ca ancol etylic l : A. (1) (2) (3) (4). B. (2) (4). C. (2) (3) (4).
Cu 105: Cho cc phn ng :

H 2 SO4 c CH3COOC2H5 C2H5OH + CH3COOH C2H5OH + HCl C2H5Cl + HCl
+ H2O (1) (2) (3) (4)
2C2H5OH C2H5OH
H2 SO4 c C 2H5OC2H5 140 0 C H2 SO4 c C2H4 170 0 C
+ H2O
H2 O
Cc phn ng lm phn ct lin kt CO ca ancol etylic l : A. (1), (2), (3), (4) B. (2), (3), (4) C. (2), (4) D. (1), (3), (4) Cu 106: Cho cc hp cht sau : (a) HOCH2CH2OH (b) HOCH2CH2CH2OH (c) HOCH2CH(OH)CH2OH (d) CH3CH(OH)CH2OH (e) CH3CH2OH (f) CH3OCH2CH3 (g) CH3CHOHCH2OH (h) CH2OH(CHOH)2CH2OH Cc cht u tc dng c vi Na, Cu(OH)2 l : A. (a), (b), (c). (g), (h). B. (c), (d), (f), (g), (h). C. (a), (c), (d), (g), (h). D. (c), (d), (e), (g), (h). Cu 107: Cho s :
NaOH d (X) dung dch xanh lam C4H8Br2 CTPT ph hp ca X l A. CH2BrCH2CH2CH2Br. B. CH3CHBrCH2CH2Br. C. CH3CH2CHBrCH2Br. D. CH3CH(CH2Br)2. Cu 108: Cho cc phng trnh ha hc sau :
t CH3C(CH3)2OH + CuO CH3C(CH3)2CHO + Cu + H2O CH3CHCl2 + 2NaOH CH3CH(OH)2 + 2NaCl CH3CH(OH)CH2(OH) + 2NaOH CH3CH(ONa)CH2ONa + 2H2O
0
(1) (2) (3)
H 2CH 3 CH CH 2 | | OH OH + Cu(OH)2 (4) CH 2 O] O CH 2 | | Cu ^ O CH + 2H 2 O CH O | | H CH 3 CH 3
Cc phng trnh ha hc vit sai l : A. (1), (2), (3) B. (1), (2), (4) C. (2), (4) D. (1), (3), (4) Cu 109: Kh nng phn ng este ho vi axit hu c ca ancol gim dn theo th t : A. Ancol bc I > ancol bc II > ancol bc III. B. Ancol bc II > ancol bc III > ancol bc I. C. Ancol bc III > ancol bc II > ancol bc I. D. Ancol bc II > ancol bc I > ancol bc III. Cu 110: Khi un nng hn hp ancol etylic v ancol isopropylic vi H2SO4 c 140oC c th thu c s ete ti a l : A. 2. B. 4. C. 5. D. 3. 80 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 111: un nng hn hp gm 3 ancol l AOH, BOH v ROH vi H2SO4 c 140oC th thu c ti a bao nhiu ete ? A. 3. B. 4. C. 5. D. 6. Cu 112: Khi un nng hn hp g m C2H5OH v C3H7OH vi H2SO4 c 140oC c th thu c s ete ti a l : A. 6. B. 4. C. 5. D. 3. Cu 113: un nng hn hp n ancol n chc khc nhau vi H2SO4 c 140oC th s ete thu c ti a l :
n2 n(n + 1) 2n(n + 1) . B. . C. . D. n! 2 2 2 Cu 114: un nng mt ancol X vi H2SO4 c nhit thch hp thu c mt olefin duy nht. Cng thc tng qut ca X l (vi n > 0, n nguyn) : A. CnH2n + 1OH. B. ROH. C. CnH2n + 2O. D. CnH2n + 1CH2OH. Cu 115: Cho cc ru : (1) CH3CH2OH (2) CH3CHOHCH3 (3) CH3CH2CHOHCH3 (4) CH3C(CH3)2CH2 OH (5) CH3C(CH3)2 OH (6) CH3CH2CHOHCH2CH3 Nhng ru no khi tch nc to ra mt anken duy nht ? A. (1), (2), (4), (5). B. (2), (3), (6). C. (5). D. (1), (2), (5), (6). Cu 116: Khi un nng butan-2-ol vi H2SO4 c 170oC th nhn c sn phm chnh l : A. but-2-en. B. ibutyl ete. C. ietyl ete. D. but-1-en. Cu 117: Ancol X n chc, no, mch h c t kh i hi so vi hiro bng 37. Cho X tc dng v i H2SO4 c un nng n 180oC thy to thnh mt anken c nhnh duy nht. X l : A. propan-2-ol. B. butan-2-ol. C. butan-1-ol. D. 2-metylpropan-2-ol. Cu 118: Khi tch nc ca ancol C4H10O c hn hp 3 anken ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu t o thu gn ca ancol l : A. CH3CHOHCH2CH3. B. (CH3)2CHCH2OH. C. (CH3)3COH. D. CH3CH2CH2CH2OH. Cu 119: Hp cht hu c X c cng thc phn t l C5H12O, khi tch nc to hn hp 3 anken ng phn (k c ng phn hnh hc). X c cu t o thu gn l : A. CH3CH2CHOHCH2CH3. B. (CH3)3CCH2OH. C. (CH3)2CHCH2CH2OH. D. CH3CH2CH2CHOHCH3. Cu 120: C bao nhiu ancol C5H12O khi tch nc ch to mt anken duy nht? A. 1. B. 2. C. 3. D. 4. Cu 121: Khi un nng 2 trong s 4 ancol CH4O, C2H6O, C3H8O vi xc tc, nhit thch hp, sn phm thu c ch cha 1 olefin duy nht th 2 ancol l : A. CH4O v C2H6O. B. CH4O v C3H8O. C. A, B ng. D. C3H8O v C2H6O. Cu 122: Ch ra dy cc cht khi tch nc to 1 anken duy nht ? A. Metanol ; etanol ; butan -1-ol. B. Etanol; butan -1,2-iol ; 2-metylpropan-1-ol. C. Propanol-1; 2-metylpropan-1-ol; 2,2 imetylpropan-1-ol. D. Propan-2-ol ; butan -1-ol ; pentan -2-ol.
A.
Cu 123: C bao nhiu ng phn ng vi cng thc phn t C8H10O, u l dn xut ca benzen, khi tch nc cho sn phm c th trng hp to polime ? A. 1. B. 2. C. 3. D. 4. Cu 124: A l ancol n chc c % O (theo khi lng) l 18,18%. A cho phn ng tch nc to 3 anken. A c tn l : A. Pentan-1-ol. B. 2-metylbutan-2-ol. C. pentan-2-ol. D. 2,2-imetyl propan-1-ol. Cu 125: Cho s chuyn ha :
HCl NaOH But-1-en + A +
H 2SO 4 c , 170 C + E
o
Tn ca E l : A. Propen.
B. ibutyl ete.
C. But-2-en.
D. Isobutilen.
Cu 126: Cho s :
H 2 SO4 Br2 KOH / ROH C 4 H 9 OH A B C Cao su Buna >1700 C
CTCT ph hp ca X l : A. CH 3 CH 2 CH 2 CH 2 OH
CH3 | B. CH3 C OH | CH3

D. C A, B, C
C. CH 3 CH 2 CH CH 3 | OH
Cu 127: Sn phm ca phn ng sau y l cht no ?

H 2 SO4 c CH3CH(OH)CH(OH)CH3 170 0 C
A. CH3CH(OH)CH=CH2. B. CH3COCH(OH)CH3. C. CH2=CHCH=CH2. D. CH3CH=C(OH)CH3. Cu 128: un nng t t hn hp etanol v propan-2-ol vi H2SO4 c c th thu c ti a s sn phm hu c l : A. 3. B. 2. C. 5. D. 4. Cu 129: Ancol no n chc tc dng c vi CuO to anehit l : A. ancol bc 2. B. ancol bc 3. C. ancol bc 1. D. ancol bc 1 v ancol bc 2. Cu 130: A, B, D l 3 ng phn c cng cng thc phn t C3H8O. Bit A tc dng vi CuO un nng cho ra andehit, cn B cho ra xeton. Vy D l : A. Ancol bc III. B. Cht c nhit si cao nht. C. Cht c nhit si thp nht. D. Cht c kh nng tch nc to anken. Cu 131: C bao nhiu ancol thm, cng thc C8H10O khi tc dng vi CuO un nng cho ra anehit? A. 2. B. 3. C. 4. D. 5. 82 Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 132: Ancol no b oxi ha to xeton ? A. propan-2-ol. C. 2-metyl propan-1-ol. Cu 133: Cho cc cht : (1) CH 3 CH CH3 | OH (3) CH 3 CH CH 2 OH | CH3 (5) CH 3 CH CH 2 OH | NH2
B. butan-1-ol. D. propan-1-ol. (2) CH 3 C(CH 3 ) 2 OH (4) CH 3 CH CH 2 CH 2 OH | OH
Cht no khi b oxi ha bi CuO to ra sn phm c nhm chc anehit ? A. (1), (2), (4). B. (3), (4), (5). C. (2), (3), (4). D. (2), (4), (5). Cu 134: Mt cht X c CTPT l C4H8O. X lm mt mu nc brom, tc dng vi Na. Sn ph m oxi ha X bi CuO khng phi l anehit. Vy X l : A. but-3-en-1-ol. B. but-3-en-2-ol. C. 2-metylpropenol. D. tt c u sai. Cu 135: X, Y, Z l 3 ancol lin tip trong dy ng ng, trong MZ = 1,875MX. X c c im l : A. Tch nc to 1 anken duy nht. B. Ha tan c Cu(OH)2. C. Cha 1 lin kt trong phn t . D. Khng c ng phn cng chc hoc khc chc. Cu 136: X l ru no sau y, bit rng khi un X vi dung dch KMnO4 (d) c mt H2SO4 ta thu c 1 sn phm hu c duy nht l axit axetic ? A. CH3CH2OH. B. CH 3 - CH - CH 2 - CH 3 | OH D. CH 3 C(CH 3 ) 2 OH C. CH 3 C(CH 3 )2 CH 2 OH Cu 137: H s cn bng ng ca cc cht trong phn ng sau y l phng n no ? C2H5CH2OH + KMnO4 + H2SO4 C2H5COOH + MnSO4 + K2SO4 + H2O A. 4, 5, 7, 4, 5, 12. B. 5, 4, 4, 5, 4, 2, 9. C. 5, 4, 8, 5, 4, 2, 13. D. 5, 4, 6, 5, 4, 2, 11. Cu 138: Cho phng trnh ha hc : CH2=CHCH2OH + KMnO4 + H2SO4 Sn phm ca phn ng l : A. CH2(OH)CH(OH)CH2OH, MnSO4, K2SO4, H2O. B. CO2, HOOCCOOH, MnO2, K2SO4, H2O. C. CH2(OH)CH(OH)CH2OH, MnO2, K2SO4, H2O. D. CO2, HOOCCOOH, MnSO4, K2SO4, H2O.
Cu 139: t chy hon ton a mol ancol A c b mol CO2 v c mol H2O. Bit a = c b. Kt lun no sau y ng ? A. A l ancol no, mch vng. B. A l ancol no, mch h. C. A l ancol cha no. D. A l ancol thm. Cu 140: t chy mt ancol X c n H2O > n CO2 . Kt lun no sau y l ng nht ? A. X l ancol no, mch h. B. X l ankaniol. C. X l ankanol n chc. D. X l ancol n chc mch h. Cu 141: Khi t chy ng ng ca ancol n chc thy t l s mol n CO 2 : n H 2O tng dn. Ancol trn thuc dy ng ng ca A. ancol khng no. B. ancol no. C. ancol thm. D. khng xc nh c. Cu 142: Trong phng th nghim, ngi ta thng dng phng php no sau y iu ch ancol etylic ? A. Cho glucoz ln men ru. B. Thy phn dn xut halogen trong mi trng kim. C. Cho C2H4 tc dng vi dung dch H2SO4 long, nng. D. Cho CH3CHO hp H2 c xc tc Ni, un nng. Cu 143: Khng th iu ch ancol etylic bng phn ng no sau y ? A. Cho hn hp kh etilen v hi nc i qua thp cha H3PO4. B. Ln men glucoz. C. Cho etilen tc dng vi dung d ch H2SO4 long nng. D. Cho axetilen tc dng vi dung d ch cha H2SO4 long, nng v HgSO4. Cu 144: Phn ng no sau y dng iu ch ancol etylic trong cng nghip ? A. C2H5Cl + NaOH C2H5OH + NaCl B. C2H4 + H2O
Men r -u
H 2 SO4 long C2H5OH
+
H C. (C6H10O5)n + nH2O
nC6H12O6
2C2H5OH + 2CO2 C6H12O6 D. C B v C Cu 145: Cho s phn ng : Isopentan (A) (B) Xc nh CTCT ph hp ca B. Bit A, B l cc sn phm chnh. A. CH 3 CH CH 2 CH 2 OH B. CH3 CH CH CH3 | | | CH 3 CH 3 OH
C. CH 2 CH CH 2 CH 3 | | OH CH 3
OH | D. CH 3 C CH 2 CH 3 | CH 3
Cu 146: Hirat ha 2-metyl but-2-en thu c sn phm chnh l : A. 2-metyl butan-2-ol. B. 3-metyl butan-1-ol. C. 3-metyl butan-2-ol. D. 2-metyl butan-1-ol.
Cu 147: Hirat ha propen v mt olefin A thu c 3 ancol c s C trong phn t khng qu 4. Tn ca A l : A. etilen. B. but-2-en. C. isobutilen. D. A, B u ng. Cu 148: Anken thch hp iu ch 3-etylpentan-3-ol bng phn ng hirat ha l : A. 3,3-imetyl pent-2-en. B. 3-etyl pent-2-en. C. 3-etyl pent-1-en. D. 3-etyl pent-3-en. Cu 149: X l hn hp gm hai anken ( th kh trong k thng). Hirat ha X c hn hp Y gm 4 ancol (khng c ancol bc III). X gm A. propen v but-1-en. B. etilen v propen. D. propen v 2-metylpropen. C. propen v but-2-en. Cu 150: Phng php iu ch ancol etylic t cht no sau y l phng php sinh ha ? A. Anehit axetic. B. Etylclorua. C. Tinh bt. D. Etilen. Cu 151: Cho s chuyn ha sau (m i mi tn l mt phng trnh phn ng) : Tinh bt X Y Z Metyl axetat Cc cht Y, Z trong s trn ln lt l : A. CH3COOH, CH3OH. B. C2H4, CH3COOH. C. C2H5OH, CH3COOH. D. CH3COOH, C2H5OH. Cu 152: Cho s chuyn ho : Glucoz X Y CH3COOH Hai cht X, Y ln lt l : A. CH3CH2OH v CH=CH. B. CH3CH2OH v CH3CHO. C. CH3CHO v CH3CH2OH. D. CH3CH(OH)COOH v CH3CHO. Cu 153: Cho s phn ng : (X) (A) (B) Cao su Buna CTPT ph hp ca X l : A. C2H4 C. (C6H10O5)n B. C2H5OH D. C6H12O6 Cu 154: Vi m i mi tn l mt phn ng v cc sn phm u l sn phm chnh th s chuyn ha no sau y sai ? A. C2H5OH CH3COOH CH3COONa CH4 C CO CH3OH. B. CH4 C2H2 C6H6 C6H5Cl C6H5OH. C. C2H5OH C4H6 C4H8 C4H9Cl CH3CH2CH(CH3)OH. D. C2H5OH C4H6 C4H10 C3H6 C3H7Cl CH3CH2CH2OH. Cu 155: Cho Na tc dng va vi 1,24 gam hn hp 3 ancol n chc X, Y, Z thy thot ra 0,336 lt kh H2 (kc). Kh i lng mui natri ancolat thu c l : A. 2,4 gam. B. 1,9 gam. C. 2,85 gam. D. 3,8 gam. o Cu 156: Cho 0,1 lt cn etylic 95 tc dng vi Na d thu c V lt kh H2 (ktc). Bit rng ancol etylic nguyn cht c khi lng ring l 0,8 g/ml. Gi tr ca V l : A. 43,23 lt. B. 37 lt. C. 18,5 lt. D. 21,615 lt. Cu 157: Cho Na d vo 1 dung dch cn (C2H5OH + H2O), thy khi lng H2 bay ra bng 3% kh i lng cn dung. Dung d ch cn c nng C% ca C2H5OH l : A. 68,57%. B. 70,57%. C. 72,57%. D. 75,57%.
Cu 158: Cho Na phn ng hon ton vi 18,8 gam hn hp hai ancol no, n chc k tip nhau trong dy ng ng sinh ra 5,6 lt H2 (ktc). CTPT ca hai ancol l : A. CH3OH, C2H5OH. B. C2H5OH, C3H7OH. C. C3H7OH, C4H9OH. D. C4H9OH, C5H11OH. Cu 159: Cho hn hp gm 1,6 gam ancol A v 2,3 ancol ru B l hai ru no n chc k tip nhau trong dy ng ng tc dng vi Na c 1,12 lt H2 (ktc). CTPT ca hai ancol l : A. C2H5OH, C3H7OH. B. C3H7OH, C4H9OH. C. CH3OH, C2H5OH. D. Kt qu khc. Cu 160: Cho 7,8 gam hn hp 2 ancol n chc k tip nhau trong dy ng ng tc dng ht vi 4,6 gam Na c 12,25 gam cht rn. CTPT ca hai ancol l : B. C2H5OH v C3H7OH. A. CH3OH v C2H5OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 161: 13,8 gam ancol A tc dng vi Na d gii phng 5,04 lt H2 ktc, bit MA < 100. Vy A c cng thc cu t o thu gn l : A. CH3OH. B. C2H5OH. C. C3H6(OH)2. D. C3H5(OH)3. Cu 162: Cho 12,8 gam dung dch ancol A (trong nc) c nng 71,875% tc dng vi lng Na d thu c 5,6 lt kh (ktc). Cng thc ca ancol A l : A. CH3OH. B. C2H4 (OH)2. C. C3H5(OH)3. D. C4H7OH. Cu 163: Ancol A tc dng vi Na d cho s mol H2 bng s mol A dng. t chy hon ton A c mCO2 = 1,833m H2 O . A c cu to thu gn l : A. C2H4(OH)2. B. C3H6(OH)2. C. C3H5(OH)3. D. C4H8(OH)2. Cu 164: Ancol no mch h A cha n nguyn t C v m nhm OH trong cu to phn t. Cho 7,6 gam A tc dng ht vi Na cho 2,24 lt H2 (ktc). Mi quan h gia n v m l : A. 2m = 2n + 1. B. m = 2n + 2. C. 11m = 7n + 1. D. 7n = 14m + 2. Cu 165: C hai th nghim sau : Th nghim 1: Cho 6 gam ancol, mch h, n chc A tc dng vi m gam Na, thu c 0,075 gam H2. Th nghim 2: Cho 6 gam ancol, mch h, n chc A tc dng vi 2m gam Na, thu c khng ti 0,1 gam H2. A c cng thc l : A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H7OH. Cu 166: Cho 30,4 gam hn hp g m glixerol v mt ru n chc, no A phn ng vi Na th thu c 8,96 lt kh (ktc). Nu cho hn hp trn tc dng vi Cu(OH)2 th ho tan c 9,8 gam Cu(OH)2. Cng thc ca A l : A. C2H5OH. B. C3H7OH. C. CH3OH. D. C4H9OH. Cu 167: Mt ru n chc A tc dng vi HBr cho hp cht hu c B c cha C, H, Br trong Br chim 58,4 % khi lng. CTPT ca ru l : A. C2H5OH. B. C3H7OH. C. CH3OH. D. C4H9OH. Cu 168: Mt ancol n chc X mch h tc dng vi HBr c dn xut Y cha 58,4% brom v kh i lng. un X vi H2SO4 c 170oC c 3 anken. Tn X l : A. pentan-2-ol. B. butan-1-ol. C. butan-2-ol. D. 2-metylpropan-2-ol.
Cu 169: un nng ancol A vi hn hp NaBr v H2SO4 c thu c cht hu c B, 12,3 gam hi cht B chim mt th tch bng th tch ca 2,8 gam N2 cng nhit 560oC, p sut 1 atm. Oxi ho A bng CuO nung nng thu c hp cht hu c c kh nng lm mt mu dung dch nc brom. CTCT ca A l : B. C2H5OH. C. CH3CHOHCH3. D. CH3CH2CH2OH. A. CH3OH. Cu 170: un mt ancol A vi dung dch hn hp gm KBr v H2SO4 c th trong hn hp sn phm thu c c cht hu c B. Hi ca 12,5 gam cht B ni trn chim 1 th tch ca 2,80 gam nit trong cng iu kin. Cng thc cu to ca A l : A. C2H5OH. B. CH3CH2CH2OH. C. CH3OH. D. HOCH2CH2OH. Cu 171: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng thu c 11 gam este. Hiu sut ca phn ng este ho l : A. 55%. B. 50%. C. 62,5%. D. 75%. o Cu 172: Trn 20 ml cn etylic 92 vi 300 ml axit axetic 1M thu c hn hp X. Cho H2SO4 c vo X ri un nng, sau mt thi gian thu c 21,12 gam este. Bit kh i lng ring ca ancol etylic nguyn cht l 0,8 gam/ml. Hiu sut phn ng este ho l : A. 75%. B. 80%. C. 85%. D. Kt qu khc. Cu 173: Cht hu c X mch h c to ra t axit no A v etylen glicol. Bit rng a gam X th hi chim th tch bng th tch ca 6,4 gam oxi cng iu kin nhit v p sut ; a gam X phn ng ht vi xt to ra 32,8 gam mu i. Nu cho 200 gam A phn ng vi 50 gam etilenglicol ta thu c 87,6 gam este. Tn ca X v hiu sut phn ng to X l : A. Etylen glicol iaxetat ; 74,4%. B. Etylen glicol ifomat ; 74,4%. C. Etylen glicol iaxetat ; 36,3%. D. Etylen glicol ifomat ; 36,6%. Cu 174: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. a. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. b. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 175: un nng 132,8 gam hn hp ru n chc vi H2SO4 c 140oC thu c 111,2 gam hn hp 6 ete c s mol bng nhau. S mol m i ete l : A. 0,4 mol. B. 0,2 mol. C. 0,8 mol. D. Tt c u sai. Cu 176: un nng hn hp X gm 0,1 mol CH3OH v 0,2 mol C2H5OH vi H2SO4 c 140oC, khi lng ete thu c l : A. 12,4 gam. B. 7 gam. C. 9,7 gam. D. 15,1 gam. Cu 177: un 1 mol hn hp C2H5OH v C4H9OH (t l mol tng ng l 3:2) vi H2SO4 c 140oC thu c m gam ete, bit hiu sut phn ng ca C2H5OH l 60% v ca C4H9OH l 40%. Gi tr ca m l A. 24,48 gam. B. 28,4 gam. C. 19,04 gam. D. 23,72 gam. o Cu 178: un nng ancol n chc X vi H2SO4 c 140 C thu c Y. T khi hi ca Y i vi X l 1,4375. X l : A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH.
Cu 179: Thc hin phn ng tch nc mt ru n chc X iu kin thch hp. Sau khi ph n ng xy ra hon ton thu c cht hu c Y c t kh i i vi X l 37/23. Cng thc phn t ca X l : A. CH3OH. B. C3H7OH. C. C4H9OH. D. C2H5OH. Cu 180: un nng hn hp X gm 2 ancol n chc lin tip trong dy ng ng vi H2SO4 c 140oC. Sau phn ng c hn hp Y gm 5,4 gam nc v 19,4 gam 3 ete. Hai ancol ban u l : A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 181: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l : A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 182: un nng hn hp X gm 2 ancol n chc no (c H2SO4 c lm xc tc) 140oC. Sau khi phn ng c hn hp Y gm 21,6 gam nc v 72 gam ba ete c s mol bng nhau. Cng thc 2 ancol ni trn l : B. CH3OH v C3H7OH. A. CH3OH v C2H5OH. C. C2H5OH v C3H7OH. D. CH3OH v C4H9OH. Cu 183: un nng hn hp X gm 2 ancol n chc no (c H2SO4 c lm xc tc) 140oC. Sau khi phn ng c hn hp Y gm 5,4 gam nc v 18 gam ba ete. Cng thc 2 ancol ni trn l : B. CH3OH v C4H9OH. A. CH3OH v C2H5OH. C. CH3OH v C3H7OH. D. A hoc B hoc C. Cu 184: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp g m cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l : A. C2H5OH v CH2=CHCH2OH. B. C2H5OH v CH3OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CHCH2OH. Cu 185: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp g m cc ete. Ly m gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 9 gam H2O. Hai ancol l : A. C2H5OH v C4H9OH. B. CH3OH v C3H7OH. C. C2H5OH v C3H7OH. D. A hoc B hoc C. Cu 186: Khi un hn hp hai ru n chc bn vi H2SO4 c 140oC thu c hn hp 3 ete trong 1 ete c cng thc phn t l C5H10O. Cng thc phn t 2 ru c th l : A. CH4O, C4H6O. B. C2H4O, C3H8O. C. CH4O, C4H8O. D. C2H6O, C3H8O. Cu 187: un nng 7,8 gam mt hn hp X gm 2 ru no, n chc c t l mol l 3 : 1 v i H2SO4 c 140oC thu c 6 gam hn hp Y gm 3 ete. Bit phn ng xy ra hon ton. CTPT ca 2 ru l : A. CH3OH v C2H5OH. C. CH3OH v C3H7OH. B. C2H5OH v C3H7OH. D. Kt qu khc.
Cu 188: Hn hp X gm 3 ru A, B, C. Hiro ho hon ton X thu c hn hp Y g m 2 ru no. Kh nc hon ton hn hp Y iu kin thch hp thu c hn hp c t kh i hi so vi H2 l 17,5. CTPT ca 3 ru trong X l : A. C2H5OH; C3H5OH; C3H7OH. B. C2H5OH; C3H3OH; C3H5OH. C. C2H5OH; C3H3OH; C3H7OH. D. C A, B, C. Cu 189: hirat ha 14,8 gam ancol thu c 11,2 gam anken. CTPT ca ancol l : A. C2H5OH. B. C3H7OH. C. C4H9OH. D. CnH2n + 1OH. Cu 190: Khi un nng mt ancol n chc no A vi H2SO4 c iu kin nhit thch hp thu c sn phm B c t kh i hi so vi A l 0,7. Vy cng thc ca A l : A. C4H7OH. B. C3H7OH. C. C3H5OH. D. C2H5OH. Cu 191: un nng mt ru (ancol) n chc X vi dung dch HSO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t kh i hi ca X so vi Y l 1,6428. Cng thc phn t ca X l : B. C2H6O. C. CH4O. D. C4H8O. A. C3H8O. Cu 192: Khi un nng m1 gam ru X vi H2SO4 c lm xc tc nhit thch hp thu c m2 gam cht hu c Y. T kh i ca Y so vi X l 28/37. Gi s hiu sut phn ng t 100%. Cng thc phn t ca X l A. C2H5OH. B. C3H7OH. C. C4H9OH. D. CH3OH. o o Cu 193: un nng V ml ancol etylic 95 vi H2SO4 c 170 C c 3,36 lt kh etilen (ktc). Bit hiu sut phn ng l 60% v ancol etylic nguyn cht c d = 0,8 g/ml. Gi tr ca V (ml) l : A. 8,19. B. 10,18. C. 12. D. 15,13. Cu 194: Oxi ha 6 gam ancol no X thu c 5,8 gam anehit. CTPT ca ancol l : A. CH3CH2OH. B. CH3CH(OH)CH3. C. CH3CH2CH2OH. D. Kt qu khc. Cu 195: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t kh i hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l : B. CH3COCH3. A. CH3CHOHCH3. D. CH3CH2CHOHCH3. C. CH3CH2CH2OH. Cu 196: Cho m gam ancol n chc, no, mch h qua bnh ng CuO (d) nung nng. Sau khi phn ng xy ra hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp thu c c t khi hi i vi H2 l 19. Gi tr m l : A. 1,48 gam. B. 1,2 gam. C. 0,92 gam. D. 0,64 gam. Cu 197: Cho m gam ancol n chc no (h) X qua ng ng CuO (d) nung nng. Sau khi phn ng hon ton thy khi lng cht rn trong ng gim 0,32 gam. Hn hp hi thu c (gm hi anehit v hi nc) c t khi so vi H2 l 15,5. Gi tr m l A. 1,2 gam. B. 1,16 gam. C. 0,92 gam. D.0,64 gam. Cu 198: Dn m gam hi ancol n chc A qua ng ng CuO (d) nung nng. Sau khi phn ng hon ton thy khi lng cht rn trong ng gim 0,5m gam. Ancol A c tn l : A. metanol. B. etanol. C. propan-1-ol. D. propan-2-ol. Cu 199: Dn hi C2H5OH qua ng ng CuO nung nng c hn hp X gm anehit, ancol d v nc. Cho X tc dng vi Na d c 4,48 lt H2 ktc. Khi lng hn hp X l (bit ch c 80% ancol b oxi ha) : A. 13,8 gam B. 27,6 gam. C. 18,4 gam. D. 23,52 gam.
Cu 200: Dn hi C2H5OH qua ng ng CuO nung nng c 11,76 gam hn hp X gm anehit, ancol d v nc. Cho X tc dng vi Na d c 2,24 lt H2 ( ktc). % ancol b oxi ho l : A. 80%. B. 75%. C. 60%. D. 50%. Cu 201: Oxi ho m gam etanol thu c hn hp X g m axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Kh i lng etanol b oxi ho to ra axit l : A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. Cu 202*: Oxi ha 4 gam ancol n chc A bng oxi khng kh (c xc tc v un nng) thu c 5,6 gam hn hp anehit, ancol d v nc. A c cng thc l : B. C2H5OH. C. C3H5OH. D. C3H7OH. A. CH3OH. Cu 203*: Oxi ha 6 gam ancol n chc A bng oxi khng kh (c xc tc v un nng) thu c 8,4 gam hn hp anehit, ancol d v nc. Phn trm A b oxi ha l : A. 60%. B. 75%. C. 80%. D. 53,33%. Cu 204: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d, thu c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120 ml. Hiu sut phn ng oxi ho ancol etylic l : A. 42,86%. B. 66,7%. C. 85,7%. D. 75%. Cu 205*: Oxi ho 9,2 gam ancol etylic bng CuO un nng thu c 13,2 gam hn hp g m anehit, axit, ancol d v nc. Hn hp ny tc dng vi Na sinh ra 3,36 lt H2 ( ktc). Phn trm ancol b oxi ho l : A. 25%. B. 50%. C. 75%. D. 90%. Cu 206: t chy hon ton m gam ancol n chc A c 6,6 gam CO2 v 3,6 gam H2O. Gi tr m l : A. 10,2 gam. B. 2 gam. C. 2,8 gam. D. 3 gam. Cu 207: t chy hon ton a gam hn hp gm metanol v butan-2-ol c 30,8 gam CO2 v 18 gam H2O. Gi tr a l : A. 30,4 gam. B. 16 gam. C. 15,2 gam. D. 7,6 gam. Cu 208: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2( ktc) v a gam H2O. Biu thc lin h gia m, a v V l : V V V V A. m = 2a . B. m = 2a . C. m = a + . D. m = a . 22, 4 11, 2 5, 6 5, 6 Cu 209: t chy hon ton 0,4 mol hn hp X gm ancol metylic, ancol etylic v ancol isopropylic ri hp th ton b sn phm chy vo nc vi trong d c 80 gam kt ta. Th tch oxi (ktc) ti thiu cn dng l : A. 26,88 lt. B. 23,52 lt. C. 21,28 lt. D. 16,8 lt. Cu 210: Ancol X tch nc ch to mt anken duy nht. t chy mt lng X c 11 gam CO2 v 5,4 gam H2O. X c th c bao nhiu cng thc cu to ph hp ? A. 2. B. 3. C. 4. D. 5. Cu 211: t chy mt ancol n chc, mch h X thu c CO2 v hi nc theo t l th tch VCO2 : VH 2O = 4 : 5 . CTPT ca X l : A. C4H10O. B. C3H6O. C. C5H12O. D. C2H6O.
Cu 212: t chy mt ancol a chc thu c H2O v CO2 c t l mol n H 2O : n CO2 = 3 : 2 . Vy ancol l : A. C3H8O2. B. C2H6O2. C. C4H10O2. D. tt c u sai. Cu 213: Khi t chy mt ancol a chc thu c nc v kh CO2 theo t l khi lng m H2 O : m CO2 = 27 : 44 . CTPT ca ancol l : B. C2H6O2. C. C3H8O2. D. C4H8O2. A. C5H10O2. Cu 214: t chy hon ton 5,8 gam ancol n chc X thu c 13,2 gam CO2 v 5,4 gam H2O. CTPT ca X l : B. C2H5OH. C. C3H5OH. D. C3H3OH. A. C4H7OH. Cu 215: t chy hon ton 1 th tch hi ancol no n chc A thu c CO2 v H2O c t ng th tch gp 5 ln th tch hi ancol A dng ( cng iu kin). Vy A l : A. C2H5OH. B. C4H9OH. C. CH3OH. D. C3H7OH. Cu 216: Ba ancol X, Y, Z u bn v c kh i lng phn t khc nhau. t chy m i cht u sinh ra CO2 v H2O theo t l mol n CO 2 : n H 2O = 3 : 4. Vy CTPT ba ancol l : A. C2H6O ; C3H8O ; C4H10O. B. C3H8O ; C3H8O2 ; C3H8O3. C. C3H8O ; C4H10O ; C5H10O. D. C3H6O ; C3H6O2 ; C3H6O3. Cu 217: t chy ru A bng O2 va nhn thy: nCO2 : nO2 : nH2O = 4 : 5: 6. A c cng thc phn t l : B. C2H6O2. C. C3H8O. D. C4H10O. A. C2H6O. Cu 218: t chy ancol ch cha mt loi nhm chc A bng O2 va nhn thy : nCO2 : nO2 : nH2O = 6: 7: 8. A c c im l : A. Tc dng vi Na d cho nH2 = 1,5nA. B. Tc dng vi CuO un nng cho ra hp cht a chc. C. Tch nc to thnh mt anken duy nht. D. Khng c kh nng ha tan Cu(OH)2. Cu 219: Ancol n chc A chy cho m H2O : m CO2 = 9 :11 . t chy hon ton 1 mol A ri hp th ton b sn phm chy vo 600 ml dung dch Ba(OH)2 1M th lng kt ta l : A. 11,48 gam. B. 59,1 gam. C. 39,4 gam. D. 19,7 gam. Cu 220: t chy hon ton ancol X c CO2 v H2O c t l mol tng ng l 3 : 4, th tch oxi cn dng t chy X bng 1,5 ln th tch CO2 thu c (o cng k). CTPT ca X l : A. C3H8O. B. C3H8O2. C. C3H8O3. D. C3H4O. Cu 221: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l : A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C3H7OH. Cu 222: X l mt ancol no, mch h. t chy 0,05 mol X cn 4 gam oxi. X c cng thc l : A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C4H8(OH)2. Cu 223: t chy hon ton mt lng hn hp 2 ancol no n chc X, Y l ng ng lin tip thu c 11,2 lt CO2 cng vi lng hn hp trn cho phn ng vi Na d th thu c 2,24 lt H2 ( ktc). Cng thc phn t ca 2 ancol trn l : A. C2H5OH; C3H7OH. B. CH3OH; C3H7OH. C. C4H9OH; C3H7OH. D. C2H5OH ; CH3OH.
Cu 224*: X l hn hp 2 ancol n chc, cng dy ng ng, c t l khi lng 1 : 1. t chy ht X c 21,45 gam CO2 v 13,95 gam H2O. Vy X gm 2 ancol l : A. CH3OH v C2H5OH. B. CH3OH v C4H9OH. C. CH3OH v C3H7OH. D. C2H5OH v C3H7OH. Cu 225: t chy hon ton a gam ancol X ri hp th ton b sn phm chy vo bnh nc vi a+b trong d thy khi lng bnh tng b gam v c c gam kt ta. Bit b = 0,71c v c = . X c 1,02 cu t o thu gn l : A. C2H5OH. B. C2H4(OH)2. C. C3H5(OH)3. D. C3H6(OH)2. Cu 226: t chy hn hp X gm 2 ancol c s mol bng nhau thu c hn hp CO2 v H2O theo l mol tng ng 2 : 3. Hai ancol trong hn hp X l : A. CH3OH v C2H5OH. C. C2H5OH v C2H4(OH)2. B. C3H7OH v C3H6(OH)2. D. C2H5OH v C3H7OH. Cu 227: t chy mt lng ancol A cn va 26,88 lt O2 ktc, thu c 39,6 gam CO2 v 21,6 gam H2O. A c cng thc phn t l : B. C3H8O. C. C3H8O2. D. C4H10O. A. C2H6O. Cu 228: Cho hn hp X g m hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l : A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. C. C2H4(OH)2 v C4H8(OH)2. D. C2H4(OH)2 v C3H6(OH)2. Cu 229: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z g m hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Th tch dung dch thay i khng ng k) : A. C4H9OH v C5H11OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C2H5OH v C4H9OH. Cu 230: t chy hon ton hn hp M g m hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l : A. C3H6O, C4H8O. B. C2H6O, C3H8O. C. C2H6O2, C3H8O2. D. C2H6O, CH4O. Cu 231: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th t o thnh dung d ch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l : A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. Cu 232: Kh CO2 sinh ra khi ln men ru mt lng glucoz c dn vo dung dch Ca(OH)2 d to c 40 gam kt ta. Kh i lng ancol etylic thu c l : A. 18,4 gam. B. 16,8 gam. C. 16,4 gam. D. 17,4 gam. Cu 233: Nu hiu sut phn ng ln men l 80% th khi lng glucoz dng l bao nhiu gam ? A. 45 gam. B. 90 gam. C. 36 gam. D. 40 gam.
Cu 234: Cho m gam tinh bt ln men thnh C2H5OH vi hiu sut 81%, hp th ht lng CO2 sinh ra vo dung dch Ca(OH)2 c 55 gam kt ta v dung dch X. un nng dung dch X li c 10 gam kt ta na. Gi tr m l : A. 75 gam. B. 125 gam. C. 150 gam. D. 225 gam. o Cu 235: Th tch ancol etylic 92 cn dng l bao nhiu iu ch c 2,24 lt C2H4 (ktc). Cho bit hiu sut phn ng t 62,5% v d = 0,8 g/ml. A. 8 ml. B. 10 ml. C. 12,5ml. D. 3,9 ml. Cu 236: i t 150 gam tinh bt s iu ch c bao nhiu ml ancol etylic 46o bng phng php ln men ancol ? Cho bit hiu sut phn ng t 81% v d = 0,8 g/ml. A. 46,875 ml. B. 93,75 ml. C. 21,5625 ml. D. 187,5 ml. Cu 237: Kh i lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v kh i lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 238: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 d to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l : A. 60. B. 58. C. 30. D. 48. Cu 239: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt t a. Khi lng dung dch sau phn ng gim 3,4 gam so vi kh i lng dung dch nc vi trong ban u. Gi tr ca m l : A. 20,0. B. 30,0. C. 13,5. D. 15,0.
BI TP TRC NGHIM V PHENOL V BI TP TNG HP CHUYN 5

Cu 240: Ba dng ng phn (ortho, meta, para) c A. phenol. B. benzen. C. crezol. Cu 241: Cho cc cht : (1) C6H5NH2 (2) C6H5OH (3) C6H5CH2OH (4) C6H5CH2CH2OH
OH
D. etanol.
CH3
(5)
CH3
(6)
OH
(7)
(8)
CH2 OH
CH2
CH3 OH CH3
Nhng cht no trong s cc cht trn c cha nhm chc phenol ? A. Tt c cc cht trn. B. (5), (6), (7), (8). C. (1), (2), (3), (4). D. (2), (5), (7), (8).
Cu 242: Cho cc cht sau : (1) HOC6H4CH2OH (2) CH3OC6H4OH (3) HOC6H4OH (4) CH3OC6H4CH2OH Cht no l poliphenol ? A. (3). B. (1). C. (2). D. (4). Cu 243: Gi tn hp cht c CTCT nh sau theo danh php IUPAC :
A. 1-hiroxi-3-metylbenzen. B. m-metylphenol. C. m-crezol. D. C A, B, C. Cu 244: Gi tn hp cht c CTCT nh sau theo danh php IUPAC :
A. 3-hiroxi-5-clotoluen. C. 4-clo-3-metylphenol.
B. 2-clo-5-hirotoluen. D. 3-metyl-4-clophenol.
Cu 245: Gi tn hp cht c cng thc cu to nh sau :
A. 3-metyl-4-hiroxiphenol. C. 3,5-ihiroxitoluen. Cu 246: Cho cc cht : (1) axit picric (3) xiclohexanol (5) 4-metylphenol Cc cht thuc loi phenol l : A. (1), (3), (5), (6). C. (1), (2), (4), (5).
B. 4-hiroxi-3-metylphenol. D. 2,5-ihiroxi-1-metylbenzen. (2) cumen (4) 1,2-ihiroxi-4-metylbenzen (6) -naphtol B. (1), (2), (4), (6). D. (1), (4), (5), (6).
Cu 247: Hy chn cu pht biu sai : A. Phenol l cht rn kt tinh d b oxi ho trong khng kh thnh mu hng nht. B. Phenol c tnh axit yu nhng mnh hn H2CO3 . C. Khc vi benzen phenol phn ng d dng vi dung dch Br2 nhit thng t o ra kt ta trng. D. Nhm OH v gc phenyl trong phn t phenol c nh hng qua li ln nhau. Cu 248: Trong hn hp etanol v phenol, lin kt H bn hn c l : A. ... O H ... O H... B. ... O H ... O H... | | | | C2H5 C2H5 C6H5 C2H5 C. ... O H ... O H... | | C2H5 C6H5 D. ... O H ... O H... | | C6H5 C6H5
Cu 249: So vi etanol, nguyn t H trong nhm OH ca phenol linh ng hn v : A. Mt electron vng benzen tng ln, nht l cc v tr o v p. B. Lin kt CO ca phenol bn vng. C. Trong phenol, cp electron cha tham gia lin kt ca nguyn t oxi tham gia lin hp vo vng benzen lm lin kt OH phn cc hn. D. Phenol tc dng d dng vi nc brom to kt ta trng 2,4,6-tri brom phenol. Cu 250: Cho cc gc sau : NH2, OCH3, COCH3, CN Cc gc lm gim tnh axit ca phenol l : A. OCH3, NH2, CONH2. C. CN, OCH3, NH2. B. OCH3, NH2. D. NH2, COCH3. Cu 251: Th t tng dn mc linh ca nguyn t H trong nhm -OH ca cc hp cht sau phenol, etanol, nc l : A. etanol < nc < phenol. C. nc < phenol < etanol. B. etanol < phenol < nc. D. phenol < nc < etanol.
Cu 252: Cho cc cht : (1) p-crezol, (2) m-crezol, (3) o-crezol. Tnh axit tng dn theo dy no ? A. (1) < (2) < (3). B. (3) < (2) < (1). C. (3) < (1) < (2). D. (2) < (1) < (3). Cu 253: Cho cc cht : (1) p-NO2C6H4OH, (2) m-NO2C6H4OH, (3) o-NO2C6H4OH. Tnh axit tng dn theo dy no trong s cc dy sau y ? A. (1) < (2) < (3). B. (1) < (3) < (2). C. (3) < (1) < (2). D. (2) < (3) < (1). Cu 254: Cho cc cht : (1) phenol, (2) p-nitrophenol, (3) p-crezol, (4) p-aminophenol. Tnh axit tng dn theo dy no ? A. (3) < (4) < (1) < (2). B. (4) < (1) < (3) < (2). C. (4) < (3) < (1) < (2). D. (4) < (1) < (2) < (3). Cu 255: Cho cc cht sau :
(3) CH 3 CH CH 3 (4) H2O | OH (5) C6H5OH (6) CH3C6H4OH (7) HOC6H5NO2 Dy cc cht c sp xp theo chiu tng dn tnh axit l : A. (1) < (2) < (3) < (4) < (5) < (6) < (7). B. (3) < (2) < (1) < (4) < (6) < (5) < (7). C. (4) < (1) < (2) < (3) < (5) < (6) < (7). D. (4) < (1) < (2) < (3) < (6) < 5 < (7). Cu 256: Sp xp cc cht sau theo th t lc axit gim dn : etanol (X), phenol (Y), axit benzoic (Z), axit p-nitrobenzoic (T), axit axetic (P) A. X > Y > Z > T > P. B. X > Y > P > Z > T. C. T > Z > P > Y > X. D. T > P > Z > Y > X. Cu 257: Hp cht A tc dng c vi Na nhng khng phn ng c vi NaOH. A l cht no trong cc cht sau ? ( u l dn xut ca benzen) A. C6H5CH2OH. B. p-CH3C6H4OH. C. p-HOCH2C6H4OH. D. C6H5OCH3. Cu 258: Hiro trong nhm OH ca phenol c th c thay th bng Na trong cc phn ng : A. Cho Na tc dng vi phenol. B. Cho NaOH tc dng vi phenol. C. A v B ng. D. cho Na2CO3 tc dng vi phenol. Cu 259: C bao nhiu hp cht hu c C7H8O va tc dng vi Na, va tc dng vi NaOH ? A. 1. B. 2. C. 3. D. 4. Cu 260: Cho cc cht thm c cng thc phn t l C8H10O. a. C bao nhiu cht c kh nng phn ng vi Na, khng phn ng vi NaOH ? A. 5. B. 6. C. 7. D. 8. b. C bao nhiu cht va c kh nng phn ng vi Na, va c kh nng phn ng vi NaOH ? A. 7. B. 8. C. 9. D. 6. c. C bao nhiu cht va khng c kh nng phn ng vi Na v NaOH ? A. 4. B. 5. C. 6. D. 7. Cu 261: A l hp cht hu c cng thc phn t l C7H8O2. A tc dng vi NaOH theo t l 1 : 2. Vy A thuc loi hp cht no di y ? A. iphenol. B. Axit cacboxylic C. Este ca phenol. D. Va ancol, va phenol. Cu 262: Cht c cng thc phn t no di y c th tc dng c c Na, c NaOH ? A. C5H8O. B. C6H8O. C. C7H10O. D. C9H12O. Cu 263: Cho cc cht sau y : (1) phenol ; (2) ancol benzylic ; (3) glixerol ; (4) natri phenolat. Nhng cht no tc dng c vi dung dch NaOH ? A. Ch c (1). B. (1) (2) (4). C. (3) (4). D. (1) (2). Cu 264: Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH, C6H5Cl vo dung dch NaOH long un nng. Hi my cht c phn ng ? A. C bn cht. B. Mt cht. C. Hai cht. D. Ba cht. Cu 265: Cho dy cc cht : Phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l : A. 4. B. 3. C. 1. D. 2. (1) CH3OH (2) C2H5OH
Cu 266: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c (to cao, p cao) thu c cht Y c CTPT l C7H7O2Na. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 5. C. 4. D. 2. Cu 267: Ba hp cht thm X, Y, Z u c cng thc phn t C7H8O. X tc dng vi Na v NaOH ; Y tc dng vi Na, khng tc dng NaOH ; Z khng tc dng vi Na v NaOH Cng thc cu to ca X, Y, Z ln lt l : A. C6H4(CH3)OH ; C6H5OCH3 ; C6H5CH2OH. B. C6H5OCH3 ; C6H5CH2OH ; C6H4(CH3)OH. C. C6H5CH2OH ; C6H5OCH3 ; C6H4(CH3)OH. D. C6H4(CH3)OH ; C6H5CH2OH ; C6H5OCH3. Cu 268: Cho cc cht sau : (1) HOC6H4CH2OH (2) CH3OC6H4OH (3) HOC6H4OH (4) CH3OC6H4CH2OH Cht no c th phn ng vi c Na, dung dch NaOH v dung d ch HBr c ? A. (3). B. (1). C. (2). D. (4). Cu 269: Hp cht thm A c cng thc phn t l C8H8O2. A tc dng c Na, NaOH, tham gia phn ng trng gng. Vy cng thc cu to ph hp ca A l : A.
HO CH CH2
B.
HO
CHCHO OH
CH2CHO
C.
CH2COOH
D. HO
Cu 270: Cho 3 cht sau : (1) CH3CH2OH (2) C6H5OH (3) HOC6H4NO2 Nhn xt no sau y khng ng ? A. C ba cht u c H linh ng. B. C ba cht u phn ng vi baz iu kin thng. C. Cht (3) c H linh ng nht. D. Th t linh ng ca H c sp xp theo chiu tng dn (1) < (2) < (3). Cu 271: Phn ng no sau y ni ln nh hng ca nhm C6H5 i vi nhm OH ? 2C6H5OH + 2Na 2C6H5ONa + C6H5OH + NaOH C6H5ONa + H2 H2O (1) (2)
A. Ch c (2). B. (2), (3). C. (1), (2). D. (1), (3). Cu 272: Cho 2 phn ng : (1) 2CH3COOH + Na2CO3 2CH3COONa + H2O + CO2 (2) C6H5ONa + CO2 + H2O C6H5OH + NaHCO3 Hai phn ng trn chng t lc axit theo th t CH3COOH, H2CO3, C6H5OH, HCO3 l : A. Tng dn. B. Gim dn. C. Khng thay i. D. Va tng va gim.
Cu 273: Phn ng : C6H5OH + CO2 + H2O C6H5ONa + NaHCO3 Phn ng trn to ra NaHCO3 m khng t o ra mui Na2CO3 l v l do no sau y ? A. Nu sinh ra Na2CO3 th Na2CO3 s phn ng vi CO2 t o ra mu i NaHCO3 B. Tnh axit H2CO3 > C6H5OH > HCO3C. Nu sinh ra th Na2CO3 s phn ng vi C6H5OH to NaHCO3 v C6H5ONa D. C A, B, C Cu 274: Sc kh CO2 vo dung dch cha 2 cht l CaCl2 v C6H5ONa thy vn c. Nguyn nhn l do to thnh : B. Phenol kt tinh. A. CaCO3 kt ta. C. Ca(HCO3)2 v Ca(C6H5O)2. D. C A v B. Cu 275: Hin tng ln lt xy ra khi nh vi gi t dung dch HCl c vo ng nghim cha mt t dung dch HCOONa v mt t dung dch C6H5ONa ri lc mnh l : A. C s phn lp ; dung dch trong sut ha c. B. Dung d ch trong sut ha c. C. C phn lp ; dung dch trong sut. D. Xut hin s phn lp c 2 ng nghim. Cu 276: Cho cc cp cht sau : (1) CH3COOH, C6H5OH (2) CH3COOH, C2H5OH (3) C6H5OH, C2H5OH (4) CH3ONa, C6H5OH (5) CH3COOH, C2H5ONa (6) C6H5OH, C2H5ONa Cc cp c th phn ng c vi nhau l : A. (1) v (2). B. (1) v (3). C. (1), (2), (3) v (4). D. (2), (4), (5) v (6). Cu 277: C bao nhiu phn ng xy ra khi cho cc cht C6H5OH ; NaHCO3 ; NaOH ; HCl tc dng vi nhau tng i mt ? A. 3. B. 4. C. 5. D. 6.
Cu 278: Trong cc pht biu sau : (1) C2H5OH v C6H5OH u phn ng d dng vi CH3COOH. (2) C2H5OH c tnh axit yu hn C6H5OH. (3) C2H5ONa v C6H5ONa phn ng hon ton vi nc cho ra C2H5OH v C6H5OH. Pht biu sai l : A. Ch c (1). C. (1), (2). B. Ch c (2). D. (1), (3). Cu 279: Chn phn ng sai ? A. Phenol + dung d ch brom Axit picric + axit bromhiric.
t B. Ru benzylic + ng (II) oxit Anehit benzoic + ng + nc.
o
t C. Propanol-2 + ng (II) oxit Axeton + ng + nc. D. Etilen glycol + ng (II) hiroxit Dung dch mu xanh thm + nc.
o
Cu 280: Trong cc pht biu sau : (1) Phenol c tnh axit mnh hn etanol v nhn benzen ht electron ca nhm OH bng hiu ng lin hp, trong khi nhm C2H5 li y electron vo nhm OH. (2) Phenol c tnh axit mnh hn etanol v c minh ha bng phn ng phenol tc dng v i dung dch NaOH cn C2H5OH th khng. (3) Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dung dch C6H5ONa ta s thu c kt ta C6H5OH. (4) Phenol trong nc cho mi trng axit, lm qu tm ho . Pht biu ng l : A. (1). B. (2), (3). C. (3), (4). D. (1), (2), (3). Cu 281: Nguyn nhn no sau y lm cho phenol tc dng d dng vi dung d ch brom ? A. Ch do nhm -OH ht electron. B. Ch do nhn benzen ht electron. C. Ch do nhn benzen y electron. D. Do nhm -OH y electron vo nhn benzen v nhn benzen ht electron lm tng mt electron cc v tr o- v p-. Cu 282: nh hng ca nhm OH n gc C6H5 trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. D. H2 (Ni, nung nng). C. nc Br2. Cu 283: Sn phm ca phn ng gia phenol v dung d ch Br2 l cht no sau y ?
Cu 284: Kh nng phn ng th brom vo vng benzen ca cht no cao nht trong ba cht benzen, phenol v axit benzoic ? A. Benzen. B. Phenol. C. Axit benzoic. D. C ba phn ng nh nhau. Cu 285: Cho cc cht v cc dung dch sau : (1) dung dch HCl (2) dung dch brom (3) dung dch NaOH (4) Na (5) CH3COOH (6) CH3OH Nhng cht no tc dng c vi phenol ? A. (1), (2), (3). B. (4), (5), (6). C. (3), (4), (5). D. (2), (3), (4). Cu 286: Dy gm cc cht u phn ng vi phenol l : A. Dung d ch NaCl, dung dch NaOH, kim loi Na. B. Nc brom, axit axetic, dung dch NaOH. C. Nc brom, anhirit axetic, dung dch NaOH. D. Nc brom, anehit axetic, dung dch NaOH. Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng 99
Cu 287: Phenol phn ng c vi dy cht no sau y : A. (CH3CO)2O, Na2CO3, NaOH, Na, dung dch Br2, HNO3. B. HCHO, Na2CO3, dung dch Br2, NaOH, Na. C. HCHO, HNO3, dung dch Br2, NaOH, Na. D. C A, B, C. Cu 288: Cho s phn ng :
Cl 2 (1:1) HCl NaOH d , t cao, p cao Z C6H6 (benzen) X Y Hai cht hu c Y, Z ln lt l : A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu 289: Cho s phn ng sau : CH4 X Y Z T C6H5OH (X, Y, Z, T l cc cht hu c khc nhau). T l : A. C6H5Cl. B. C6H5NH2. C. C6H5NO2. D. C6H5ONa. Cu 290: Cho s chuyn ho : Benzen A B C Axit picric Cht B l : A. phenylclorua. B. o-Crezol. C. Natri phenolat. D. Phenol. Cu 291: Dng cch no sau y phn bit phenol lng v ancol etylic ? A. Cho c 2 cht tc dng vi Na. B. Cho c 2 cht tc dng vi NaOH. C. Cho c 2 cht th vi giy qu tm. D. Cho c 2 cht tc dng vi nc brom. Cu 292: Ha cht no di y dng c th dng phn bit 2 l mt nhn cha dung dch phenol v benzen ? (1) Na (2) dung dch NaOH (3) nc brom A. (1) v (2). B. (1) v (3). C. (2) v (3). D. (1), (2) v (3). Cu 293: C 3 cht lng ring bit : Ancol, axit axetic v phenol. Dng ha cht no sau y phn bit 3 cht lng ? A. Na. B. Dung dch NaOH. C. Dung dch Br2. D. Dung d ch Br2 v dung d ch Na2CO3. Cu 294: phn bit phenol v ru benzylic, c th dng thuc th no ? A. Dung d ch Br2. B. Na. C. Dung dch NaOH. D. A hoc C. Cu 295: Ha cht no di y c th dng phn bit cc l mt nhn cha cc dung dch : C6H5ONa, NaCl, BaCl2, Na2S, Na2CO3 l : A. Dung dch NaOH. B. Dung dch HCl. C. Na. D. Dung d ch KCl. Cu 296: C 3 cht lng C2H5OH, C6H6, C6H5NH2 v 3 dung dch NH4HCO3, KAlO2, C6H5OK. nhn bit m i dung d ch trn ch dng A. dung dch KOH. B. dung d ch HCl. C. dung dch Ba(OH)2. D. dung dch BaCl2. Cu 297: Phng php ch yu iu ch phenol trong cng nghip hin nay l : A. T benzen iu ch ra phenol. B. Tch t nha than . C. Oxi ha cumen thu c phenol. D. C 3 phng php trn.
o
100Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 298: Phenol khng c dng trong ngnh cng nghip no ? A. Cht do. B. Dc phm. C. Cao su. D. Thuc n. Cu 299: t chy hon ton 5,80 gam cht X thu c 2,65 gam Na2CO3 ; 2,26 gam H2O v 12,10 gam CO2. Cng thc phn t ca X l : B. C6H5ONa. C. C7H7O2Na. D. C7H7ONa. A. C6H5O2Na. Cu 300: Mt hp cht X cha ba nguyn t C, H, O c t l kh i lng mC : m H : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l : A. 3. B. 6. C. 4. D. 5. Cu 301: Cho 15,5 gam hn hp 2 phenol A v B lin tip nhau trong dy ng ng ca phenol tc dng va vi 0,5 lt dung dch NaOH 0,3M. Cng thc phn t ca 2 phenol v % kh i lng ca hn hp ln lt l : A. C7H7OH (69,68%) v C8H9OH (30,32%). B. C6H5OH (69,68%) v C7H7OH (30,32%). C. C6H5OH (30,32%) v C7H7OH(69,68%). D. Kt qu khc. Cu 302: X l hn hp gm phenol v ancol n chc A. Cho 25,4 gam X tc dng vi Na (d) c 6,72 lt H2 ( ktc). A l : B. C2H5OH. C. C3H5OH. D. C4H9OH. A. CH3OH. Cu 303: A l hp cht c cng thc phn t C7H8O2. A tc dng vi Na d cho s mol H2 bay ra bng s mol NaOH cn dng trung ha cng lng A trn. Cng thc cu to thu gn ca A l : A. C6H7COOH. B. HOC6H4CH2OH. C. CH3OC6H4OH. D. CH3C6H3(OH)2. Cu 304: Khi t chy 0,05 mol X (dn xut benzen) thu c di 17,6 gam CO2. Bit 1 mol X phn ng va vi 1 mol NaOH hoc vi 2 mol Na. X c cng thc cu to thu gn l : A. CH3C6H4OH. B. CH3OC6H4OH. C. HOC6H4CH2OH. D. C6H4(OH)2. Cu 305: Cho X l hp cht thm ; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l : A. HOC6H4COOCH3. B. CH3C6H3(OH)2. C. HOC6H4COOH. D. HOCH2C6H4OH. Cu 306: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X tc dng c vi NaOH theo t l s mol 1 : 2. Cng thc cu to thu gn ca X l : A. C6H5CH(OH)2. B. CH3C6H3(OH)2. C. CH3OC6H4OH. D. HOCH2C6H4OH. Cu 307: Cho Na tc dng vi dung dch A gm phenol v xiclohexanol trong hexan (lm dung mi) ngi ta thu c 3136 cm3 kh (ktc). Mt khc nu cho nc brom phn ng vi cng mt lng dung dch A nh trn th thu c 59,58 gam kt ta trng. Tnh % kh i lng ca phenol v xiclohexanol trong A. A. 16,92 gam v 20 gam. B. 16,92 gam v 15 gam. C. 16,92 gam v 10 gam. D. 16,92 gam v 16 gam.
Cu 308: Trung ho 5,48 gam hn hp g m axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c kh i lng l A. 6,84 gam. B. 4,90 gam. C. 6,80 gam. D. 8,64 gam. Cu 309: Mt hn hp X gm ancol etylic v phenol tc dng vi Na d cho ra hn hp hai mu i c tng kh i lng l 25,2 gam. Cng lng hn hp y tc dng va vi 100 ml dung dch NaOH 1M. S mol ca cht trong hn hp X v th tch H2 bay ra (kc) trong phn ng gia X v Na l : A. 0,2 mol ancol ; 0,1 mol phenol ; 3,36 lt H2. B. 0,18 mol ancol ; 0,1 mol phenol ; 5,376 lt H2. C. 0,1 mol ancol ; 0,1 mol phenol ; 2,24 lt H2. D. 0,2 mol ancol ; 0,2 mol phenol ; 4,48 lt H2. Cu 310: Th tch dung dch KMnO41M cn thit oxi ho ht 27 gam p-crezol trong mi trng H2SO4 l : A. 0,208 lt. B. 0,3 lt. C. 0,35 lt. D. Kt qu khc. Cu 311: A l cht hu c c cng thc phn t CxHyO. t chy hon ton 0,1 mol A ri hp th ton b sn phm chy vo nc vi trong thy c 30 gam kt ta. Lc b kt ta em un nng phn nc l c thy c 20 gam kt ta na. Bit A va tc dng Na, va tc dng NaOH. Cng thc phn t ca A l : A. C6H6O. B. C7H8O. C. C7H8O2. D. C8H10O. Cu 312: X l hn hp gm phenol v metanol. t chy hon ton X c s mol CO2 bng s mol H2O. Vy % khi lng metanol trong X l : A. 25%. B. 59,5%. C. 50,5%. D. 20%. Cu 313: T 400 gam bezen c th iu ch c ti a bao nhiu gam phenol. Cho bit hiu sut ton b qu trnh t 78%. A. 376 gam. B. 312 gam. C. 618 gam. D. 320 gam. Cu 314: iu ch axit picric, ngi ta cho 14,1 gam phenol tc dng vi HNO3 c, H2SO4 c. Bit lng axit HNO3 ly d 25% so vi lng cn thit. S mol HNO3 cn dng v kh i lng axit picric to thnh l : A. 0,5625 mol ; 34,75 gam. C. 0,5625 mol ; 34,35 gam. B. 0,45 mol ; 42,9375 gam. D. 0,45 mol ; 42,9375 gam.
CHUYN 6 : ANEHIT XETON AXIT CACBOXYLIC

BI TP TRC NGHIM V ANEHIT - XETON
Cu 1: Mt anehit c cng thc tng qut l CnH2n + 2 2a m (CHO)m. Cc gi tr n, a, m ln lt c xc nh l : A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 2: Cng thc phn t tng qut ca anehit mch h (n 1) hoc xeton mch h (n 3) l : A. CnH2n +2-2a-2bOb. B. CnH2n-2O2. C. CnH2n + 2-2bOb. D. CnH2nO2. Cu 3: Hp cht hu c mch h c cng thc chung l CnH2nO c th thuc dy ng ng no sau y ? A. Ru no, n chc. B. Anehit no, n chc. C. Xeton no, n chc. D. A hoc B ng. Cu 4: Cng thc tng qut ca anehit n chc, mch h c 1 lin kt i C=C l : B. CnH2nCHO. C. CnH2n-1CHO. D. CnH2n-3CHO. A. CnH2n+1CHO. Cu 5: Anehit mch h c cng thc tng qut CnH2n-2O thuc loi A. anehit n chc no. B. anehit n chc cha mt lin kt i trong gc hirocacbon. C. anehit n chc cha hai lin kt trong gc hirocacbon. D. anehit n chc cha ba lin kt trong gc hirocacbon. Cu 6: Nhn xt no di y khng ng ? A. Tt c cc anehit no, n chc, mch h u c cc ng phn thuc chc xeton v chc ancol. B. Tt c cc xeton no n chc, mch h u c cc ng phn thuc chc anehit v chc ancol. C. Tt c cc ancol n chc, mch h c mt lin kt i u c cc ng phn thuc chc anehit v chc xeton. D. Tt c cc ancol n chc, mch vng no u c cc ng phn thuc chc anehit v chc xeton. Cu 7: Trong cc cht c cng thc cu t o cho di y, cht no khng phi l anehit ? A. HCH=O. B. O=CHCH=O. C. CH3COCH3. D. CH3CH=O. Cu 8: C bao nhiu ng phn cu to C5H10O c kh nng tham gia phn ng trng gng ? A. 2. B. 3. C. 4. D. 5. Cu 9: C bao nhiu xeton c cng thc phn t l C5H10O ? A. 1. B. 2. C. 3. D. 4. Cu 10: C bao nhiu ng phn cu to C6H12O tham gia phn ng trng gng ? A. 6. B. 7. C. 8. D. 9. Cu 11: C bao nhiu ancol C5H12O khi tc dng vi CuO un nng cho ra anehit ? A. 1. B. 2. C. 3. D. 4.
Cu 12: CTGN ca 1 anehit no, a chc, mch h l C2H3O. a. CTPT ca n l : A. C8H12O4. B. C4H6O. C. C12H18O6. D. C4H6O2. b. Anehit c s ng phn l : A. 2. B. 4. C. 1. D. 3. Cu 13: Hp cht c CTPT C4H8O c bao nhiu ng phn cu to mch h (khng k ng phn hnh hc). A. 10. B. 8. C. 7. D. 9. Cu 14: Trong cng iu kin nhit v p sut, 1 lt hi anehit A c khi lng bng khi lng 1 lt CO2. A l : A. anehit fomic. B. anehit axetic. C. anehit acrylic. D. anehit benzoic. Cu 15: CTPT ca ankanal c 10,345% H theo khi lng l : A. HCHO. B. CH3CHO. C. C2H5CHO. D. C3H7CHO. Cu 16: (CH3)2CHCHO c tn l : A. isobutyranehit. B. anehit isobutyric. C. 2-metyl propanal. D. A, B, C u ng. Cu 17: Tn ng ca cht CH3CH2CH2CHO l g ? A. Propan-1-al. B. Propanal. C. Butan-1-al. D. Butanal. Cu 18: Anehit propionic c cng thc cu to l : A. CH3CH2CH2CHO. B. CH3CH2CHO. C. CH 3 CH CH3 . D. HCOOCH2CH3. | CH 3 Cu 19: Gi tn hp cht c CTCT nh sau theo danh php IUPAC : CH3 CH CH2 CH CHO | | C2H5 C2 H 5 A. 2,4-dietylpentanal. B. 2-metyl-4-etylhexanal. C. 2-etyl-4-metylhexanal. D. 2-metyl-5-oxoheptan. Cu 20: Gi tn hp cht c CTCT nh sau theo danh php IUPAC : CH3 CH CH CHO | | OH Cl A. 1-clo-1-oxo-propanol-2. C. 2-clo-3-hiroxibutanal. B. 3-hiroxi-2-clobutanal. D. 2-hiroxi-1-clo-1-oxopropan. Cu 21: Gi tn hp cht c CTCT nh sau theo danh php thng thng :
CHO NO2
Cl
A. 4-clo-2-nitro-1-fomylbenzen. B. Anehit 2-nitro-4-clobenzoic. C. Anehit 4-clo-2-nitrobenzoic. D. Anehit 4-clo-6-fomylbenzoic.
Cu 22: Cht CH3CH2CH2COCH3 c tn l g ? A. Pentan-4-on. B. Pentan-4-ol. C. Pentan-2-on. D. Pentan-2-ol. Cu 23: Gi tn hp cht c CTCT nh sau theo danh php IUPAC. CH2=CHCH2COCH(CH3)CH3 A. iso-propylallylxeton. C. 2-metylhexen-5-on-3. B. Allyliso-propylxeton. D. 5-metylhexen-1-on-4. Cu 24: Gi tn hp cht c CTCT nh sau theo danh php thng thng. CH3CH2CH2COCH2CCH A. Heptin-1-on-4. C. n-propylpropin-2-ylxeton. B. Heptin-6-on-4. D. Propin-2-in-propylxeton. Cu 25 Trong cc pht biu sau, pht biu no sai khi ni v anehit fomic ? A. iu kin thng HCHO l cht kh mi cay xc, khng tan trong nc. B. Th hin tnh oxi ha khi tc dng vi cc cht kh nh H2 (xt : Ni). C. Th hin tnh kh khi gp cc cht oxi ha nh dung d ch AgNO3/NH3. D. HCHO c kh nng tham gia phn ng trng hp v trng ngng. Cu 26: Trong cc pht biu sau, pht biu no sai khi ni v anehit fomic ? A. Phn t HCHO c cu to phng, cc gc HCH v HCO u 120o. Tng t lin kt i C=C, lin kt i C=O gm 1 lin kt v mt lin kt km bn, tuy nhin, khc vi lin kt C=C, lin kt C=O phn cc mnh. B. Fomon hay fomalin l dung dch cha khong 37% - 40% HCHO trong ru. C. Tng t ancol etylic anehit fomic tan rt tt trong nc v trong nc HCHO tn ti ch yu dng HCH(OH)2 (do phn ng cng nc) d tan. Mt khc, nu cn phn t HCHO th phn t ny cng to c lin kt hiro vi nc. D. Khc vi ancol etylic v tng t metyl clorua, anehit l cht kh v khng c lin kt hiro gia cc phn t. Cu 27: Anehit benzoic C6H5CHO c th tham gia cc phn ng sau : C6H5CHO +
t , Ni H2 C6H5CH2OH
o o
t , xt C6H5CHO + O2 C6H5COOH Cu no ng khi ni v phn ng trn ? A. Anehit benzoic ch b oxi ha. B. Anehit benzoic ch b kh. C. Anehit benzoic khng b oxi ha, khng b kh. D. Anehit benzoic va b oxi ha, va b kh. Cu 28: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z ; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. no, hai chc. B. khng no (cha mt ni i C=C), hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc.
Cu 29: Nhn xt no sau y l ng ? A. Anehit v xeton u lm mt mu nc brom. B. Anehit v xeton u khng lm mt mu nc brom. C. Xeton lm mt mu nc brom cn anehit th khng. D. Anehit lm mt mu nc brom cn xeton th khng. Cu 30: Trong cc pht biu sau y, pht biu no sai ? A. Ch c anehit fomic mi phn ng vi dung dch AgNO3/NH3 v Cu(OH)2/NaOH theo t l mol 1 : 4. B. Anehit v xeton u c phn ng vi hiro xianua to thnh sn phm l xianohirin. C. Anehit l sn phm trung gian gia ancol v axit cacboxylic. D. Lin kt i trong nhm cacbonyl (C=O) ca anehit phn cc mnh hn lin kt i (C=C) trong anken. Cu 31: Anehit A (ch cha mt loi nhm chc) c %C v %H (theo khi lng) ln lt l 55,81 v 6,97. Ch ra pht biu sai A. A l anehit hai chc. B. A cn c ng phn l cc axit cacboxylic. C. A l anehit no. D. Trong phn ng trng gng, mt phn t A ch cho 2 electron. Cu 32: Cht no sau y phn ng vi anehit fomic cho kt ta mu gch ? B. AgNO3/NH3. C. Cu(OH)2/NaOH. D. KMnO4, to. A. NaHSO3. Cu 33: Hp cht X khi un nh vi dung d ch AgNO3/NH3 c sn phm Y. Cho Y tc dng v i dung dch HCl hoc dung dch NaOH th sn phm kh thu c u l cht kh v c. X l cht no sau y ? A. HCHO. B. HCOOH. C. HCOONH4 . D. A, B, C u ph hp. Cu 34: Cho cc phn ng : HCHO + H2

Ni, t 0
CH3OH
(1) (2)
HC HO + NaHSO3
H CH OH
|
SO3Na
HCHO + 4AgNO3 + 6NH3 + 2H2O (NH4)2CO3 + 2NH4NO3 + 4Ag (3)
(4)
Cc phn ng m trong HCHO th hin tnh oxi ha v tnh kh l : A. (1), (2), (3), (4). B. (1), (3), (4). C. (1), (2), (4). D. (1), (3). Cu 35: Cho cc cht : HCN, H2, dung dch KMnO4, dung dch Br2/H2O, dung d ch Br2/CH3COOH a. S cht phn ng c vi (CH3)2CO iu kin thch hp l : A. 2. B. 3. C. 4. D. 5. b. S cht phn ng c vi CH3CH2CHO iu kin thch hp l : A. 4. B. 2. C. 3. D. 5. 106Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 36: Trong nhiu tinh du tho mc c nhng anehit khng no to nn mi thm cho cc tinh du ny. V d tinh du qu c anehit xiamic C6 H5CH=CHCHO, trong tinh du x v chanh c xitronelal C9H17CHO. C th dng cht no sau y tinh ch cc anehit ni trn ? A. AgNO3/NH3. B. H2/Ni, to. C. Cu(OH)2/NaOH. D. Dung d ch bo ha NaHSO3 sau ti t o bng HCl. Cu 37: H s cn bng ca phng trnh ha hc di y l phng n no ? R(CHO)x + AgNO3 + NH3 + xH2O R(COONH4)x + NH4NO3 + Ag A. 1, x, 2x, x, 1, x, 2x. B. 1, 2x, 3x, x, 1, 2x, 2x. C. 1, 4x, 6x, 2x, 1, 4x, 2x. D. C 3 u sai. Cu 38: Cho bit h s cn bng ca phng trnh ha hc sau l phng n no ? CH3CHO + KMnO4 + H2SO4 CH3COOH + MnSO4 + K2SO4 + H2O A. 5, 2, 4, 5, 2, 1, 4. B. 5, 2, 2, 5, 2, 1, 2. C. 5, 2, 3, 5, 2, 1, 3. D. C 3 u sai. Cu 39: Cho s phn ng : CH2=CHCHO + K2Cr2O7 + H2SO4 Sn phm ca phn ng l phng n no ? A. CH2=CHCOOH, Cr2(SO4)3, K2SO4, H2O. B. CH2OHCH(OH)COOH, Cr2(SO4)3, K2SO4, H2O. C. CO2, HOOCCOOH, Cr2(SO4)3, K2SO4, H2O. D. CO2, Cr2(SO4)3, K2SO4, H2O. Cu 40: t chy hon ton p mol anehit X c q mol CO2 v t mol H2O. Bit p = q t. Mt khc 1 mol X trng gng c 4 mol Ag. X thuc dy ng ng ca anehit A. n chc, no, mch h. C. hai chc cha no (1 ni i C=C). B. hai chc, no, mch h. D. nh chc cha no (1 ni ba CC). Cu 41: Anehit a chc A chy hon ton cho nCO2 n H2O = n A . A l : A. Anehit no, mch h. B. Anehit cha no. C. Anehit thm. D. Anehit no, mch vng. Cu 42: t chy anehit A c nCO2 = n H2O . A l : A. Anehit no, mch h, n chc. B. Anehit n chc, no, mch vng. C. Anehit n chc c 1 ni i, mch h. D. Anehit no 2 chc, mch h. Cu 43: t chy hon ton mt hp cht hu c X thu c CO2 v H2O c cng s mol. X thuc nhm hp cht no ? A. Anken hay ru khng no c 1 ni i trong phn t . B. Anehit no n chc hoc xeton no n chc. C. Axit cacboxylic no n chc hoc este no n chc. D. C A, B, C. Cu 44: CH3CHO c th t o thnh trc tip t A. CH3COOCH=CH2. B. C2H2. C. C2H5OH. D. Tt c u ng.
Cu 45: Qu trnh no sau y khng to ra anehit axetic ? A. CH2=CH2+ H2O (to, xc tc HgSO4). B. CH2=CH2 + O2 (to, xc tc). C. CH3COOCH=CH2 + dung dch NaOH (to). D. CH3CH2OH + CuO (to). Cu 46: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l : A. C2H5OH, C2H2, CH3COOC2H5. B. HCOOC2H3, C2H2, CH3COOH. C. C2H5OH, C2H4, C2H2. D. CH3COOH, C2H2, C2H4. Cu 47: Phng php no sau y c dng trong cng nghip sn xut HCHO ? A. Oxi ha metanol nh xc tc Cu hoc Pt. B. Oxi ha metan nh xc tc NO. C. Thy phn CH2Cl2 trong mi trng kim. D. A v B. Cu 48: Axeton l nguyn liu tng hp nhiu dc phm v mt s cht do, mt lng l n axeton dng lm dung mi trong sn xut t nhn to v thuc sng khng khi. Trong cng nghip, axeton c iu ch bng phng php no sau y ? A. Oxi ho ru isopropylic. B. Chng khan g. C. Nhit phn CH3COOH/xt hoc (CH3COO)2Ca. D. Oxi ho cumen (isopropyl benzen). Cu 49: ng dng no sau y ca anehit fomic ? A. iu ch dc phm. B. Tng hp phm nhu m. C. Cht dit trng, ty u. D. Sn xut thuc tr su. Cu 50: C bao nhiu cht c CTPT l C4H8O, mch h khi tc dng vi H2 d (Ni) to thnh ancol isobutylic ? A. 1. B. 2. C. 3. D. 4. Cu 51: C bao nhiu cht hu c mch h khi tc dng vi H2 d (Ni, to) to thnh ancol isobutylic ? A. 1. B. 2. C. 3. D. 4. Cu 52: Hiro ha hp cht X mch h c CTPT l C4H6 O, c ancol butylic. S cng thc cu to c th c ca X l : A. 5 B. 6. C. 3. D. 4. o Cu 53: Th tch H2 (0 C v 2 atm) va tc dng vi 11,2 gam anehit acrylic l : A. 4,48 lt. B. 2,24 lt. C. 0,448 lt. D. 0,336 lt. Cu 54: Hiro ha hon ton 2,9 gam mt anehit A c 3,1 gam ancol. A c cng thc phn t l : A. CH2O. B. C2H4O. C. C3H6O. D. C2H2O2. Cu 55: Cho 14,6 gam hn hp 2 anehit n chc, no lin tip tc dng ht vi H2 to 15,2 gam hn hp 2 ancol. a. Tng s mol 2 ancol l : A. 0,2 mol. B. 0,4 mol. C. 0,3 mol. D. 0,5 mol. b. Kh i lng anehit c KLPT ln hn l : A. 6 gam. B. 10,44 gam. C. 5,8 gam. D. 8,8 gam. 108Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 56: Cho 7 gam cht A c CTPT C4H6O tc dng vi H2 d c xc tc to thnh 5,92 gam ancol isobutylic. a. Tn ca A l : A. 2-metyl propenal. B. 2-metylpropanal. C. but-2-en-1-ol. D. but-2-en-1-al. b. Hiu sut ca phn ng l : A. 85%. B. 75%. C. 60%. D. 80%. Cu 57: Mt hp cht hu c X cha C, H, O. Khi t chy hon ton 0,03 mol X cho 2,016 lt CO2 (ktc). Mt khc hiro ha hon ton 0,015 mol X cn 3,36 lt H2 (0oC, 2atm) v c ru no Y. Bit X tc dng c vi AgNO3/NH3 cho kt ta Ag. CTCT ca X l : B. CH2=CHCHO. C. CH3CHO. D. CH2 CHCHO. A. C2H5CHO. Cu 58: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh t o CH3CH(CN)OH t C2H4 l : A. 70%. B. 50%. C. 60%. D. 80%. Cu 59: Cho 1,97 gam dung dch fomalin tc dng vi dung dch AgNO3/NH3 d thu c 10,8 gam Ag. Nng % ca anehit fomic trong fomalin l : A. 49%. B. 40%. C. 50%. D. 38,07%. Cu 60: Cho hn hp metanal v hiro i qua ng ng Ni nung nng. Dn ton b hn hp sau phn ng vo bnh nc lnh lm ngng t hon ton hi ca cht lng v ho tan cc cht kh c th tan c, khi kh i lng ca bnh ny tng thm 8,65 gam. Ly dung dch trong bnh ny em un nng vi AgNO3/NH3 c 32,4 gam Ag (phn ng xy ra hon ton). Kh i lng metanal ban u l : A. 8,25 gam. B. 7,60 gam. C. 8,15 gam. D. 7,25 gam. Cu 61: Oxi ha 48 gam ancol etylic bng K2Cr2O7 trong H2SO4 c, tch ly sn phm hu c ra ngay kh i mi trng v dn vo dung dch AgNO3/NH3 d thy c 123,8 gam Ag. Hiu sut ca phn ng oxi ha l : A. 72,46 %. B. 54,93 %. C. 56,32 %. D. Kt qu khc. Cu 62: Cho 10,4 gam hn hp gm metanal v etanal tc dng vi mt lng va dAgNO3/NH3 thu c 108 gam Ag. Kh i lng metanal trong hn hp l : A. 4,4 gam. B. 3 gam. C. 6 gam. D. 8,8 gam. Cu 63: Cho 1,74 gam anehit oxalic tc dng va vi dung dch AgNO3 trong NH3 to ra m gam bc kt ta. Gi tr ca m l : A. 6,48 gam. B. 12,96 gam. C. 19,62 gam. D. 19,44. Cu 64: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm kh i lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l : A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HCOOCH3 v HCOOCH2CH3. D. HOCH(CH3)CHO v HOOCCH2CHO. Cu 65: Hp cht hu c A (CxHyOz) c M < 90 vC. A tham gia phn ng trng bc v c th tc dng vi H2/Ni, to sinh ra mt ancol c cacbon bc bn trong phn t . Cng thc cu t o ca A l : B. (CH3)2CHCHO. A. (CH3)2CHCH2CHO. C. (CH3)3CCHO. D. (CH3)3CCH2 CHO.
Cu 66: Cho 7,2 gam ankanal A phn ng hon ton vi dung dch AgNO3/NH3 sinh ra mu i axit B v 21,6 gam bc kim loi. Nu cho A tc dng vi H2/Ni, to thu c ancol n chc, c mch nhnh. CTCT ca A l : A. CH3CH2CH2CHO. B. (CH3)2CHCH2CHO. C. CH3CH(CH3) CH2CHO. D. (CH3)2CHCHO. Cu 67: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l : A. C3H7CHO. B. HCHO. C. C4H9CHO. D. C2H5CHO. Cu 68: Cho 6,6 gam mt anehit n chc, mch h phn ng vi lng d AgNO3/NH3 un nng, lng Ag sinh ra cho tc dng vi HNO3 lo ng thu c 2,24 lt NO (duy nht ktc). Cng thc cu to ca X l : A. CH3CHO. B. HCHO. C. C2H5CHO. D. CH2=CHCHO. Cu 69: Cho 25,2 gam mt anehit n chc A phn ng hon ton vi dung dch AgNO3/NH3 (d). Lng Ag sinh ra phn ng ht vi dung d ch HNO3 long c 6,72 lt NO (ktc). A c cng thc phn t l : A. C2H4O. B. C3H6O. C. C3H4O. D. C4H8O. Cu 70: t chy hon ton mt anehit X thu c s mol CO2 bng s mol H2O. Nu cho X tc dng ht vi lng d Ag2O/NH3 th s mol Ag thu c gp 4 ln s mol X phn ng . Cng thc phn t X l : A. C2H5CHO. B. HCHO. C. (CHO)2. D. C2H3CHO. Cu 71: Hn hp X g m hai cht hu c A, B (cha C, H, O) l ng phn ca nhau. Bit 14,5 gam hi X chim th tch ng bng th tch ca 8 gam O2 o cng iu kin nhit p sut. Nu cho 14,5 gam X tc dng vi dung dch AgNO3/NH3 d th thu c 10,8 gam kt ta bc. % kh i lng ca m i cht trong X l : A. 85% v 15%. B. 20% v 80%. C. 75% v 25%. D. 50% v 50%. Cu 72: 1,72 gam hn hp anehit acrylic v anehit axetic tham gia phn ng cng va 1,12 lt H2 (ktc). Cho thm 0,696 gam anehit B l ng ng ca anehit fomic vo 1,72 gam hn hp 2 anehit trn r i cho hn hp thu c tham gia phn ng trng bc hon ton c 10,152 gam Ag. Cng thc cu to ca B l : A. CH3CH2CHO. B. C4H9CHO. C. CH3CH(CH3)CHO. D. CH3CH2CH2CHO. Cu 73: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NHo 3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t ) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l : A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n(CHO)2 (n 0). Cu 74: Dn 4 gam hi ancol n chc A qua ng ng CuO, nung nng. Ngng t phn hi thot ra c hn hp X. Cho X tc dng vi lng d dung dch AgNO3/NH3 c 43,2 gam bc. A l : A. Ancol metylic. B. Ancol etylic. C. Ancol anlylic. D. Ancol benzylic. Cu 75: 8,6 gam anehit m ch khng nhnh A tc dng vi lng (d) dung dch AgNO3/NH3 to 43,2 gam Ag. A c cng thc phn t l : A. CH2O. B. C3H4O. C. C4H8O. D. C4H6O2. Cu 76: Cho bay hi ht 5,8 gam mt hp cht hu c X thu c 4,48 lt hi X 109,2oC v 0,7 atm. Mt khc khi cho 5,8 gam X phn ng ca AgNO3/NH3 d to 43,2 gam Ag. CTPT ca X l A. C2H2O2. B. C3H4O2. C. CH2O. D. C2H4O2. 110Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 77: Cho 5,8 gam anehit A tc dng ht vi mt lng d AgNO3/NH3 thu c 43,2 gam Ag. CTPT ca A l : A. CH3CHO. B. CH2=CHCHO. C. OHCCHO. D. HCHO. Cu 78: Cho 8,7 gam anehit X tc dng hon ton vi lng dung dch AgNO3/NH3 (d) c 64,8 gam Ag. X c cng thc phn t l : A. CH2O. B. C2H4O. C. C2H2O2. D. C3H4O. Cu 79: Hp cht A cha 1 loi nhm chc v phn t ch cha cc nguyn t C, H, O trong oxi chim 37,21% v kh i lng, 1 mol A trng gng hon ton cho 4 mol Ag. Vy A l : B. HCHO. C. CH3CHO. D. OHCCH2CHO. A. C2H4(CHO)2. Cu 80: Cho 0,1 mol mt anehit X tc dng ht vi dung dch AgNO3/NH3 (d) c 43,2 gam Ag. Hiro ha hon ton X c Y. Bit 0,1 mol Y tc dng va vi Na va c 12 gam rn. X c cng thc phn t l : A. CH2O. B. C2H2O2. C. C4H6O. D. C3H4O2. Cu 81: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l : A. HCHO. B. OHCCHO. C. CH3CHO. D. CH3CH(OH)CHO. Cu 82: X l hn hp gm 2 anehit ng ng lin tip. Cho 0,1 mol X tc dng vi lng d dung dch AgNO3/NH3 c 25,92 gam bc. Phn trm s mol anehit c s cacbon nh hn trong X l : A. 20%. B. 40%. C. 60%. D. 75%. Cu 83: Cho 0,94 gam hn hp hai anehit n chc, no k tip nhau trong dy ng ng cho tc dng ht vi dung dch AgNO3/NH3 thu c 3,24 gam Ag. Cng thc phn t hai anehit l : A. C3H7CHO v C4H9CHO. B. CH3CHO v HCHO. C. C2H5CHO v C3H7CHO. D. CH3CHO v C2H5CHO. Cu 84: X l hn hp 2 ancol n chc ng ng lin tip. Cho 0,3 mol X tc dng hon ton vi CuO un nng c hn hp Y gm 2 anehit. Cho Y tc dng vi lng dung dch AgNO3/NH3 c 86,4 gam Ag. Hn hp X gm A. CH3OH v C2H5OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C3H5OH v C4H7OH. Cu 85: Cho 0,1 mol hn hp X g m hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l : A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. Cu 86: Mt hn hp g m 2 anehit c tng s mol l 0,25 mol. Khi cho hn hp ny tc dng v i dung dch AgNO3/NH3 d thu c 86,4 gam Ag v kh i lng dung dch AgNO3/NH3 gim i 76,1 gam. Vy 2 anehit l : A. HCHO v CH3CHO. B. HCHO v C2H5CHO. C. HCHO v C3H7CHO. D. CH3CHO v C2H5CHO. Cu 87: Cho 0,1 mol hn hp 2 anehit n chc, lin tip trong dy ng ng tc dng vi lng d AgNO3/NH3 thu c 37,8 gam Ag. Cng thc phn t ca 2 anehit v s mol tng ng l : A. CH2O : 0,075 v C2H4O : 0,025. B. CH2O : 0,025 v C2H4O : 0,075. C. C2H4O : 0,025 v C3H6O : 0,075. D. C2H4O : 0,075 v C3H6O : 0,025.
Cu 88: Hn hp X gm 2 ancol no, n chc, mch h. Cho 2,76 gam X tc dng vi Na d thu c 0,672 lt kh (ktc). Mt khc oxi ho hon ton 2,76 gam X bng CuO, nung nng thu c hn hp anehit. Cho lng anehit ny tc dng vi dung dch AgNO3/NH3 d thu c 19,44 gam kt ta. Cng thc ca 2 ru l : A. CH3OH v C2H5OH. B. CH3OH v CH3CH2CH2OH. C. CH3OH v CH3CH(CH3)OH. D. C2H5OH v CH3CH2CH2CH2OH. Cu 89: Hn hp X g m ancol metylic v mt ancol no, n chc, mch h M. Cho 2,76 gam X tc dng vi Na d thu c 0,672 lt kh (ktc). Mt khc oxi ho hon ton X bng CuO nung nng thu c hn hp Y. Cho ton b Y tc dng vi dung dch AgNO3/NH3 thu c 12,96 gam kt ta. Cng thc cu to M l : A. C2H5OH. B.CH3CH2CH2OH. C. CH3CH(CH3)OH. D.CH3CH2CH2CH2 OH. Cu 90: Hn hp M g m hai ancol n chc. Chia 30,4 gam M thnh 2 phn bng nhau. Phn 1 tc dng vi Na d thu c 0,15 mol kh. Cho phn 2 phn ng hon ton vi CuO nung nng thu c hn hp M1 cha hn hp 2 anhit. Ton b lng M1 phn ng ht vi AgNO3/NH3 thu c 0,8 mol Ag. Cng thc ca 2 ancol l : A. CH3OH v C2H5OH B. CH3OH v CH3CH2CH2OH C. C2H5OH v CH3CH2CH2OH D. C2H5OH v CH3CH(OH)CH3 Cu 91: Cho m gam hn hp X g m hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t kh i hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l : A. 7,8. B. 8,8. C. 7,4. D. 9,2. Cu 92*: 17,7 gam hn hp X g m 2 anehit n chc phn ng hon ton vi dung dch AgNO3 trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong hn hp X l : A. C2H3CHO v HCHO. B. C2H5CHO v HCHO. C. CH3CHO v HCHO. D. C2H5CHO v CH3CHO. Cu 93: X l hn hp 2 anehit n chc. Chia 0,12 mol X thnh hai phn bng nhau : - t chy ht phn 1 c 6,16 gam CO2 v 1,8 gam H2O. - Cho phn 2 tc dng vi lng d dung dch AgNO3/NH3 c 17,28 gam bc. X gm 2 anehit c cng thc phn t l : A. CH2O v C2H4O. B. CH2O v C3H6O. C. CH2O v C3H4O. D. CH2O v C4H6O. Cu 94: Dn m gam hi ancol etylic qua ng ng CuO d un nng. Ngng t phn hi thot ra c hn hp X gm anehit, ancol etylic v H2O. Bit mt na lng X tc dng vi Na (d) gi i phng 3,36 lt H2 ( ktc), cn mt na lng X cn li tc dng vi d dung dch AgNO3/NH3 to c 25,92 gam Ag. a. Gi tr m l : A. 13,8 gam B. 27,6 gam C. 16,1 gam D. 6,9 gam b. Hiu sut phn ng oxi ho ancol etylic l : A. 20%. B. 40%. C. 60%. D. 75%. Cu 95: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l : A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. 112Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 96: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c kh i lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l : A. 13,5. B. 8,1. C. 8,5. D. 15,3. Cu 97: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l : A. HCOOC2H5. B. CH3COOCH3. C. HOOCCHO. D. OHCCH2CH2OH. Cu 98: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung d ch NH3, un nng. Sau khi cc phn ng xy ra hon ton, kh i lng Ag t o thnh l : A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 99: Mt hp cht hu c A gm C, H, O c 50% oxi v kh i lng. Ngi ta cho A qua ng ng 10,4 gam CuO nung nng thu c sn phm cha 2 cht hu c v 8,48 gam cht rn. Mt khc cho hn hp 2 cht hu c trn tc dng vi dung dch AgNO3 (d) trong NH3 to ra hn hp 2 mu i v 38,88 gam Ag. Kh i lng ca A cn dng l : A. 1,28 gam. B. 4,8 gam. C. 2,56 gam. D. 3,2 gam. Cu 100: Oxi ha 1,8 gam HCHO thnh axit vi hiu sut H% thu c h n hp X. Cho X tham gia phn ng trng gng thu c 16,2 gam Ag. Gi tr ca H l : A. 60. B. 75. C. 62,5. D. 25. Cu 101: Hn hp A g m anehit fomic v anehit axetic. Oxi ho hon ton hn hp A thu c hn hp B gm 2 axit. T kh i hi ca B so vi A l d. Khong gi tr ca d l : A. 0,9 < d < 1,2. B. 1,5 < d < 1,8. C. 1,36 < d < 1,53. D. 1,36 < d < 1,48. Cu 102: Oxi ha 1,76 gam mt anehit n chc c 2,4 gam mt axit tng ng. Anehit l : A. Anehit acrylic. B. Anehit axetic. C. Anehit fomic. D. Anehit propionic. Cu 103: em oxi ha 2,61 gam anehit X th thu c 4,05 gam axit cacboxylic tng ng. V y cng thc ca anehit l : A. OHCCHO. B. CH3CHO. C. C2H5CHO. D. HCHO. Cu 104: Oxi ha 17,4 gam mt anehit n chc c 16,65 gam axit tng ng (H = 75%). Anehit c cng thc phn t l : A. CH2O. B. C2H4O. C. C3H6O. D. C3H4O. Cu 105: t chy hon ton mt lng aehit A cn va 2,52 lt O2 (ktc), c 4,4 gam CO2 v 1,35 gam H2O. A c cng thc phn t l : A. C3H4O. B. C4H6O. C. C4H6O2. D. C8H12O. Cu 106: t chy a mol mt anehit A thu c a mol CO2. Anehit ny c th l : A. CH3CHO. B. HCHO. C. C2H5CHO. D. A, B, C u ng. Cu 107: t chy hon ton 1 anehit A mch h, no. Sau phn ng thu c CO2 v H2O theo t l nA : nCO2 : nH2O = 1 : 3 : 2 . Vy A l : A. CH3CH2CHO. C. HOCCH2CH2CHO. B. OHCCH2CHO. D. CH3CH2CH2CH2CHO.
Cu 108: X, Y, Z, T l 4 anehit no h n chc ng ng lin tip, trong MT = 2,4MX. t chy hon ton 0,1 mol Z ri hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 d thy khi lng dung dch tng hay gim bao nhiu gam ? A. Tng 18,6 gam. B. Tng 13,2 gam. C. Gim 11,4 gam. D. Gim 30 gam. Cu 109: t chy hon ton mt anehit n chc no, mch h A cn 17,92 lt O2 (ktc). Hp th ht sn phm chy vo nc vi trong c 40 gam kt ta v dung dch X. un nng dung dch X li c 10 gam kt ta na. Cng thc phn t A l : B. C2H4O. C. C3H6O. D. C4H8O. A. CH2O. Cu 110: t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO2. Mt khc hiro ho hon ton m gam X cn 0,2 mol H2 (Ni, to) sau phn ng thu c hn hp 2 ancol no,n chc. t chy hon ton hn hp 2 ancol ny th s mol H2O thu c l bao nhiu ? A. 0,3 mol. B. 0,4 mol. C. 0,6 mol. D. 0,8 mol. Cu 111: Hn hp A g m 2 anehit no, n chc. Hiro ho hon ton 0,2 mol A ri ly sn ph m B em t chy hon ton thu c 12,6 gam H2 O. Nu t chy hon ton 0,1 mol A th th tch CO2 thu c ( ktc) l : A. 11,2 lt. B. 5,6 lt. C. 6,72 lt. D. 7,84 lt. Cu 112: X l hn hp gm mt ancol n chc, no, mch h A v mt anehit no, mch h n chc B (A v B c cng s cacbon). t chy hon ton 13,4 gam X c 0,6 mol CO2 v 0,7 mol H2O. S nguyn t C trong A, B u l : A. 1. B. 2. C. 3. D. 4. Cu 113: Cho hn hp kh X g m HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l : A. 35,00%. B. 65,00%. C. 53,85%. D. 46,15%. Cu 114: t chy hon ton 1 mol hn hp X gm 1 ancol n chc v mt anehit n chc c n 76,16 lt O2 (ktc) to ra 54 gam H2O. T kh i hi ca X i vi H2 l : A. 32,4. B. 36,5. C. 28,9. D. 25,4. Cu 115: t chy hon ton 1,46 gam hn hp 2 anehit no, n chc ng ng k tip thu c 1,568 lt CO2 (ktc). a. CTPT ca 2 anehit l : A. CH3CHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H5CHO v C3H7CHO. D. Kt qu khc. b. Kh i lng gam ca m i anehit l : A. 0,539 v 0,921. B. 0,88 v 0,58. C. 0,44 v 1,01. D. 0,66 v 0,8. Cu 116: Hiro ho hon ton hn hp M g m hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < My), thu c hn hp hai ancol c kh i lng ln hn kh i lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm kh i lng ca X ln lt l : A. HCHO v 50,56%. B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%. Cu 117: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l : A. 10,5. B. 8,8. C. 24,8. D. 17,8. 114Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 118: Cho hn hp g m khng kh (d) v hi ca 24 gam metanol i qua bt Cu nung nng, thu c 40 ml fomalin 36% c khi lng ring 1,1 g/ml. Hiu sut ca qu trnh trn l : A. 70,4%. B. 80,4%. C. 65,5%. D. 76,6%. Cu 119: Tin hnh oxi ha 2,5 mol ru metylic thnh fomanehit bng CuO ri cho fomanehit tan ht vo nc thu c 160 gam dung dch fomalin 37,5%. Hiu sut ca phn ng oxi ha l bao nhiu ? A. 90%. B. 80%. C. 70%. D. 60%. Cu 120: Hirat ho axetilen thu c hn hp A gm 2 cht hu c, t kh i hi ca A so vi H2 l 20,2. Hiu sut ca phn ng hirat ho axetilen l : A. 70%. B. 80%. C. 75%. D. 85%. Cu 121: Cho 0,92 gam hn hp gm C2H2 v CH3CHO tc dng vi dung dch Ag2O/NH3 thu c 5,64 gam hn hp cht rn. Phn trm kh i lng ca C2H2 v CH3CHO ln lt l : A. 40% v 60%. B. 60% v 40%. C. 25,73% v 74,27%. D. 28,26% v 71,74%. Cu 122: Hirat ho 3,36 lt C2H2 ( ktc) thu c hn hp A (Hiu sut phn ng 60%). Cho hn hp sn phm A tc dng ht vi dung dch AgNO3/NH3 d thu c m gam cht rn. Gi tr m l : A. 19,44. B. 33,84. C. 14,4. D. 48,24. Cu 123: Mt hp cht hu c c CTTQ l CxHyOz c t khi hi so vi CH4 l 4,25. Bit 0,2 mol X tc dng ht vi 0,6 mol AgNO3/NH3 thu c 43,2 gam Ag. Cng thc cu t o ca X l : A. HC CCH2CHO. B. CH3C CCHO. C. CH2=C=CHCHO. D. HCOOCH2C CH. Cu 124: Hp cht hu c X c cha cc nguyn t C, H, O. T kh i hi ca X so vi H2 l 41. Bit X c cu to mch khng nhnh v 1 mol X phn ng va ht vi 1,5 mol Ag2O trong dung dch amoniac. CTCT ca X l : A. CH3CCCH2CHO. B. OHCCH2CCCHO. C. CHCCH2CH2CHO. D. OHCCCCHO.
BI TP TRC NGHIM AXIT CACBOXYLIC V BI TP TNG HP CHUYN 6

Cu 125: Mt axit cacboxylic c cng thc tng qut l CnH2n + 2 2a m (COOH)m. Cc gi tr n, a, m ln lt c xc nh l : A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 126: Cng thc phn t tng qut ca axit cacboxylic mch l : A. CnH2n +2-2a-2bO2b. B. CnH2n-2O2b. C. CnH2n + 2-2bO2b. D. CnH2nO2b. Cu 127: Hp cht hu c mch h c cng thc chung l CnH2nO2 c th thuc dy ng ng no sau y ? A. Ru no, n chc. B. Anehit no, hai chc. C. Xeton no, hai chc. D. Axit cacboxylic no, n chc.
Cu 128: Mt axit c cng thc chung C2H2n-2O4, l loi axit no sau y ? A. Axit a chc cha no. B. Axit no, 2 chc. C. Axit a chc no. D. Axit cha no hai chc. Cu 129: Phn t axit hu c c 5 nguyn t cacbon, 2 nhm chc, mch h cha no c 1 lin kt i mch cacbon th CTPT l : B. C5H8O4. C. C5H10O4. D. C5H4O4. A. C5H6O4. Cu 130: A l axit no h, cng thc CxHyOz. Mi lin h gia x, y, z l : A. y = 2x z +2. B. y = 2x + z 2. C. y = 2x. D. y = 2x z. Cu 131: A l axit cacboxylic mch h, cha no (1 ni i C=C), cng thc CxHyOz. Mi lin h gia x, y, z l : A. y = 2x. B. y = 2x + 2 z. C. y = 2x z. D. y = 2x + z 2. Cu 132: Axit khng no, n chc, c mt lin kt i trong gc hirocacbon c cng thc ph hp l : A. CnH2n+1-2kCOOH (n 2). B. RCOOH. C. CnH2n-1COOH (n 2). D. CnH2n+1COOH (n 1). Cu 133: Cho axit hu c mch h, c cng thc nguyn l (C2H3O)n. CTPT ca axit l : A. C4H6O2. B. C8H12O4. C. C12H18O6. D. C A, B, C. Cu 134: Axit cacboxylic A c cng thc n gin nht l C3H4O3. A c cng thc phn t l : A. C3H4O3. B. C6H8O6. C. C18H24O18. D. C12H16O12. Cu 135: Mt axit no A c cng thc n gin nht (CTGN) l C2H3O2. a. CTPT ca axit A l : A. C6H9O6. B. C2H3O2. C. C4H6O4. D. C8H12O8. b. S ng phn mch h thuc ca A l : A. 4. B. 3. C. 5. D. tt c u sai. Cu 136: CTGN ca mt axit hu c X l CHO. t chy 1 mol X thu c di 6 mol CO2. CTCT ca X l : A. CH3COOH. B. CH2=CHCOOH. C. HOOCCH=CHCOOH. D. Kt qu khc. Cu 137: Mt hp cht c thnh phn l 40% C ; 6,7% H v 53,3% O. Hp cht c CTGN l : A. C6H8O. B. C2H4O. C. CH2O. D. C3H6O. Cu 138: A l ancol n chc no h, B l axit cacboxylic no h n chc. Bit MA = MB. Pht biu ng l : A. A, B l ng phn. B. A, B c cng s cacbon trong phn t. C. A hn B mt nguyn t cacbon. D. B hn A mt nguyn t cacbon. Cu 139: Axit cacboxylic mch h c CTPT C4H6O2 c bao nhiu ng phn ? A. 4. B. 3. C. 2. D. 1. Cu 140: Axit cacboxylic A mch h c CTPT C5H8O2. A c bao nhiu CTCT c th c ng phn cis trans ? A. 4. B. 3. C. 2. D. 1. Cu 141: C bao nhiu ng phn l axit cacboxylic, c cha vng benzen, c cng thc phn t l C9H8O2 ? A. 3. B. 4. C. 5. D. 6. 116Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 142: Axit no sau y c ng phn hnh hc ? A. CH2=CHCOOH B. CH3CH=CHCOOH C. CH2=CH(CH3)COOH D. C A, B, C Cu 143: Hp cht CH3CH2(CH3)CH2CH2CH(C2H5)COOH c tn quc t l : A. Axit 2-etyl-5-metyl hexanoic. B. Axit 2-etyl-5-metyl nonanoic. C. Axit 5-etyl-2-metyl hexanoic. D. Tn gi khc. Cu 144: Hp cht c CTCT nh sau :
CH3 CH CH 2 CH COOH | | C2H5 C 2H 5

Tn hp cht theo danh php IUPAC l : A. 2,4-ietylpentanoic. B. 2-metyl-4-etylhexanoic. C. 2-etyl-4-metylhexanoic. D. 2-metyl-5-cacboxiheptan. Cu 145: Cho hp cht sau : HOOC(CH2)4COOH Tn hp cht theo danh php thng thng l : A. Axit propanicacboxylic-1,3. B. Axit sucxinic. C. Axit glutaric. D. Axit aipic. CH 2 = CH CH = CH COOH Cu 146: Cho axit : | CH3 CH2 CH2 Tn axit theo danh php IUPAC l : A. 4-n-propylpentaien-2,4-oic. C. 2-n-propylpentaien-1,3-oic. Cu 147: Cht no sau y l axit terephtalic ? B. 4-n-propylpentaien-2,4-cacboxylic-1. D. 2-n-propylpentaien-1,3-cacboxylic-4.
Cu 148: Cht no sau y l axit acrylic ? A. CH2=CHCOOH. C. CH2=CH(CH3)COOH. Cu 149: Cht no sau y l axit metacrylic ? A. CH2=CHCOOH. C. CH2=CH(CH3)COOH. Cu 150: Cht no sau y l axit stearic ? A. CH3(CH2)14COOH. C. CH3(CH2)16COOH.
B. CH3CH(OH) COOH. D. HOOCCH2COOH. B. CH3CH(OH) COOH. D. HOOCCH2COOH. B. HOOCCH=CHCOOH. D. CH3(CH2)7CH=CH(CH2)COOH.
Cu 151: Pht biu no sau y ng ? A. Nh t o c lin k t hiro vi H2O, ba axit u y ng ng axit ankanoic tan v hn vo trong nc, cc axit khc ch tan c hn hoc khng tan. B. Do nh hng y electron ca nhm OH ln nhm C=O, phn ng cng vo lin kt i C= O rt kh thc hin. C. Khc vi anehit v tng t ru (c lin kt hiro), cc axit cacboxylic l cht rn hoc lng nhit thng v c nhit si tng i cao. D. A, B, C u ng. Cu 152: Cht c nhit si cao nht l : B. C2H5OH. C. CH3COOH. D. C2H6. A. CH3CHO. Cu 153: Cht no sau y c nhit si cao nht ? A. Propanol-1. B. Anehit propionic. C. Axeton. D. Axit propionic. Cu 154: Cht no sau y c nhit si thp nht ? A. Axit fomic. B. Axit axetic. C. Axit propionic. D. Axit iso-butylic. Cu 155: Nhit si ca m i cht tng ng trong dy cc cht sau y, dy no hp l nht ? C2H5OH HCOOH CH3COOH o o A. 118,2 C 78,3 C 100,5oC B. 118,2oC 100,5oC 78,3oC C. 100,5oC 78,3oC 118,2oC D. 78,3oC 100,5oC 118,2oC Cu 156: Ch ra th t t ng dn nhit si ca cc cht ? A. CH3CHO ; C2H5OH ; CH3COOH. C. C2H5OH ; CH3COOH ; CH3CHO. B. CH3CHO ; CH3COOH ; C2H5OH. D. CH3COOH ; C2H5OH ; CH3CHO. Cu 167: Nhit si ca cc cht c sp xp theo th t tng dn l : A. CH3OH < CH3CH2COOH < NH3 < HCl. B. C2H5Cl < CH3COOH < C2H5OH. C. C2H5Cl < CH3COOCH3 < C2H5OH < CH3COOH. D. HCOOH < CH3OH < CH3COOH < C2H5F. Cu 158: Dy no sau y sp xp ng theo chiu tng dn nhit si ? A. HCOOH < CH3CH2OH < CH3CH2Cl. B. C2H5Cl < C4H9Cl < CH3CH2OH < CH3COOH. C. CH3COOH < C4H9Cl < CH3CH2OH. D. CH3CH2OH < C4H9Cl < HCOOH. Cu 159: Cho cc cht CH3CH2COOH (X) ; CH3COOH ( Y) ; C2H5OH ( Z) ; CH3OCH3 (T). Dy gm cc cht c sp xp tng dn theo nhit si l : A. T, X, Y, Z. B. T, Z, Y, X. C. Z, T, Y, X. D. Y, T, Z, X. Cu 160: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l : A. IV > I > III > II. B. IV > III > I > II. C. II > III > I > IV. D. I > II > III > IV.
Cu 161: Gim n l dung dch axit axetic c nng l : A. 2% 5%. B. 5 9%. C. 9 12%. D. 12 15%. Cu 162: in li ca 3 dung dch CH3COOH 0,1M ; CH3COOH 0,01M v HCl c sp xp theo th t tng dn l : A. CH3COOH 0,01M < HCl < CH3COOH 0,1M. B. CH3COOH 0,01M < CH3COOH 0,1M < HCl. C. HCl < CH3COOH 0,1M < CH3COOH 0,01M. D. CH3COOH 0,1M < CH3COOH 0,01M < HCl. Cu 163: Cho cc cht : CH2=CHCOOH (1), CH3CH2COOH (2), CH3COOH (3). Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : A. (1) < (2) < (3). C. (2) < (1) < (3). B. (2) < (3) < (1). D. (3) < (1) < (2). Cu 164: Cho cc cht : (1) CH3COOH ; (2) CH2ClCOOH ; (3) CH2FCOOH Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : A. (2) < (1) < (3). B. (3) < (2) < (1). C. (2) < (3) < (1). D. (1) < (2) < (3). Cu 165: Cho cc cht : (1) CH3CH2COOH ; (2) CH2=CHCOOH ; (3) CHCCOOH. Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : A. (1) < (2) < (3). B. (1) < (3) < (2). C. (2) < (3) < (1). D. (3) < (1) < (2). Cu 166: Cho cc cht : (1) CH3CH=CHCH2COOH ; (2) CH2=CH(CH2)2COOH ; (3) C2H5CH=CHCOOH. Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : A. (1) < (2) < (3). B. (2) < (1) < (3). C. (3) < (2) < (1). D. (2) < (1) < (3). Cu 167: Cho cc cht : (1) CHCl2COOH ; (2) CH2ClCOOH ; (3) CCl3COOH Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : A. (3) < (2) < (1). B. (1) < (2) < (3). C. (2) < (1) < (3). D. (3) < (1) < (2). Cu 168: Cho 3 axit : ClCH2COOH , BrCH2COOH, ICH2COOH. Dy sp xp theo th t tng dn tnh axit l : A. ClCH2COOH < ICH2COOH < BrCH2COOH. B. ClCH2COOH < BrCH2COOH < ICH2COOH. C. ICH2COOH < BrCH2COOH < ClCH2COOH. D. BrCH2COOH < ClCH2COOH < ICH2COOH. Cu 169: Cho cc cht : (1) HOOCCH2CH2COOH ; (2) HOOCCH2COOH ; (3) HOOCCOOH. Dy sp xp ng theo th t gim dn tnh axit ca cc cht l : A. (1) < (2) < (3). B. (2) < (1) < (3). C. (3) < (2) < (1). D. (2) < (1) < (3). Cu 170: Gi tr pH ca cc axit CH3COOH, HCl, H2SO4 c sp xp theo th t tng dn l : A. H2SO4, CH3COOH, HCl. B. CH3COOH, HCl , H2SO4. C. H2SO4, HCl, CH3COOH. D. HCl, CH3COOH, H2SO4. Cu 171: Dy sp xp ng theo th t tng dn tnh axit ca cc cht l : (1) p-metylbenzoic ; (2) axit p-aminobenzoic ; (3) axit p-nitrobenzoic ; (4) axit benzoic A. (4) < (1) < (3) < (2). B. (1) < (4) < (2) < (3). C. (1) < (4) < (3) < (2). D. (2) < (1) < (4) < (3).
Cu 172: Th t tng dn tnh axit ca cc axit o-nitrobenzoic (1), axit p-nitrobenzoic (2), axit mnitrobezoic (3) l dy no ? A. (1) < (2) < (3). B. (3) < (2) < (1). C. (2) < (1) < (3). D. (2) < (3) < (1). Cu 173: Th t sp xp theo th t tng dn tnh axit ca CH3COOH ; C2H5OH ; CO2 v C6H5OH l : A. C6H5OH < CO2 < CH3COOH < C2H5OH. B. CH3COOH < C6H5OH < CO2 < C2H5OH. C. C2H5OH < C6H5OH < CO2 < CH3COOH. D. C2H5OH < CH3COOH < C6H5OH < CO2. Cu 174: Cho cc cht sau : H2O, C2H5OH, CH3COOH, HCOOH, C6H5OH. Chiu t ng dn linh ng ca nguyn t H (chiu tnh axit tng dn) trong cc nhm chc ca 4 cht l : A. H2O, C2H5OH, C6H5OH, HCOOH, CH3COOH. B. H2O,C2H5OH, C6H5OH, CH3COOH, HCOOH. C. C2H5OH, H2O, C6H5OH, CH3COOH, HCOOH. D. C2H5OH, H2O, C6H5OH, HCOOH, CH3COOH. Cu 175: Xp theo th t phn cc tng dn ca lin kt OH trong phn t ca cc cht sau : C2H5OH (1), CH3COOH (2), CH2=CHCOOH (3), C6H5OH (4), CH3C6H4OH (5), C6H5CH2OH (6) l: A. (1) < (6) < (4) < (5) < (3) < (2). B. (6) < (1) < (5) < (4) < (2) < (3). C. (1) < (6) < (5) < (4) < (2) < (3). D. (1) < (6) < (4) < (5) < (2) < (3). Cu 176: Trong dy ng ng ca cc axit n chc no, HCOOH l axit c mnh trung bnh, cn li l axit yu (in li khng hon ton). Dung dch axit axetic c nng 0,001 mol/l c pH l : A. 3 < pH < 7. B. < 3. C. 3. D. 10-3 Cu 177*: Cho 0,1 mol m i cht sau vo nc thu c 1 lt dung dch tng ng : C2H5ONa (1) ; CH3COONa (2) ; C6H5ONa (3) ; C2H5COOK (4) ; Na2CO3 (5). Th t tng dn pH ca cc dung dch trn l : A. 2, 4, 3, 5, 1. B. 2, 4, 5, 3, 1. C. 1, 5, 3, 4, 2. D. 1, 3, 5, 4, 2. Cu 178*: Cho cc cht : (I) CH3COONa ; (II) ClCH2COONa ; (III) CH3CH2COONa ; (IV) NaCl. So snh s thy phn ca cc dung dch cng nng mol/l ca cc mu i trn : A. (I) < (II) < (III) < (IV). B. (IV) < (III) < (II) < (I). C. (IV) < (II) < (I) < (III). D. (IV) < (II) < (III) < (I). Cu 179: trung ha 0,2 mol hn hp X gm 2 axit cacboxylic cn 0,3 mol NaOH. Hn hp X gm c A. 2 axit cng dy ng ng. B. 1 axit n chc, 1 axit hai chc. C. 2 axit a chc. D. 1 axit n chc, 1 axit a chc. Cu 180: Trong cc phn ng este ha gia ancol v axit hu c th cn bng s chuyn dch theo chiu thun khi ta A. dng cht ho nc tch nc. B. chng ct ngay tch este ra. C. cho ancol d hoc axit d. D. tt c u ng.
Cu 181: t chy hon ton hn hp X gm 2 axit cacboxylic c mol CO2 = mol H2O. Hn hp X gm A. 1 axit n chc, 1 axit a chc. B. 1 axit no, 1 axit cha no. C. 2 axit n chc, no, m ch vng D. 2 axit no, mch h, n chc. Cu 182: t chy hon ton axit cacboxylic A bng lng va oxi c hn hp (kh v hi) c t khi so vi H2 l 15,5. A l axit A. n chc no, mch h. B. n chc c 1 ni i (C=C), mch h. C. a chc no, mch h. D. axit no,mch h, hai chc, Cu 183: t chy ht 1 th tch hi axit A thu c 2 th tch CO2 o cng iu kin, A l : A. HCOOH. B. HOOCCOOH. C. CH3COOH. D. B v C ng. Cu 184: Axit axetic tc dng c vi dung d ch no ? A. natri etylat. B. amoni cacbonat. C. natri phenolat. D. C A, B, C. Cu 185: Axit claiic C17H33COOH l mt axit khng no, ng phn ca axit oleic. Khi oxi ho mnh axit claidic bng KMnO4 trong H2SO4 ct lin kt i CH=CH thnh hai nhm COOH ngi ta c hai axit cacboxylic c mch khng phn nhnh C9H18O2 (X), C9H16O4 (Y). CTCT ca hai axit claidic l : A. CH3[CH2]4CH=CH[CH2]9COOH. B. CH3[CH2]7CH=CH[CH2]7COOH. C. CH3[CH2]9CH=CH[CH2]5COOH. D. CH3[CH2]8CH=CH[CH2]6COOH. Cu 186: C cc phng trnh ha hc sau :
NH 3 HCOOH + Ag2O
o
CO2 + 2Ag + H2O (HCOO)2Cu + H2O
(1) (2)
t thng HCOOH + Cu(OH)2

o
t cao (3) HCOOH + 2Cu(OH)2 Cu2O + 3H2O + CO2 HCOOH + CaCO3 (HCOO)2Ca + CO2 + H2O (4) HCOOH + CHCH HCOOCH=CH2 (5) Phng trnh ha hc no ng ? A. (1), (4). B. (4), (5). C. (1), (2), (3). D. C 5 phn ng u ng. Cu 187: Cho cc phng trnh ha hc :
pdd C6H5COOH + NaHCO3 C6H5COONa + CO2 + H2O mnx pdd 2CH2=CHCOONa + 2H2O CH2=CHCH=CH2 + 2CO2 + H2 + 2NaOH mnx
(1) (2) (3) (4)
CaO,t HCOONa + NaOH Na2CO3 + H2 CH3CCl3 + 3NaOH d CH3COOH + 3NaCl + H2O Phng trnh ha hc no sai ? A. (2), (3), (4). B. (1), (3), (4). C. (2), (4). D. (1), (4). Cu 188: Cho s phn ng : CH2=CHCOOH + HCl Sn phm ca phn ng l : A. CH2=CHCOCl. B. CH2ClCH2COOH. C. CH3CHClCOOH. D. CH2ClCH2COCl.
0
Cu 189: Cho phn ng : C6H5CH=CH2 + KMnO4 C6H5COOK + K2CO3 + MnO2 + KOH + H2O Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ha hc ca phn ng trn l : A. 27. B. 31. C. 24. D. 34. Cu 190: Axit cacboxylic n chc mch h phn nhnh (A) c % O (theo khi lng) l 37,2. Ch ra pht biu sai ? A. A lm mt mu dung dch brom. B. A l nguyn liu iu ch thy tinh hu c. C. A c ng phn hnh hc. D. A c hai lin trong phn t. Cu 191: Axit fomic v axit axetic khc nhau im no ? A. Phn ng vi baz. B. Phn ng vi dung dch AgNO3 trong amoniac. C. Phn ng vi cc kim loi hot ng. D. Thnh phn nh tnh. Cu 192: Pht biu no sau y ng khi ni v axit fomic v axit axetic ? A. Hai axit trn u tc dng vi Mg, Na2CO3, CuO, dung dch AgNO3/NH3. B. Tnh axit ca axit fomic mnh hn axit axetic. Axit fomic tc dng vi Cu(OH)2/NaOH, un nng t o ra Cu2O, cn axit axetic khng c phn ng ny. C. Hai axit trn u c iu ch t CH4 qua mt phn ng. D. Nhit si ca axit fomic cao hn nhit si ca axit axetic. Cu 193: Hai hp cht hu c X v Y c cng CTPT C3H4O2. X tc dng vi CaCO3 t o ra CO2. Y tc dng vi dung d ch AgNO3/NH3 t o Ag. CTCT thu gn ph hp ca X, Y ln lt l : A. HCOOCH=CH2, CH3COOCH3. B. CH3CH2COOH, HCOOCH2CH3. C. HCOOCH=CH2, CH3CH2COOH. D. CH2=CHCOOH, OHCCH2CHO. Cu 194: Cho chui phn ng :
CH 3OH C2H6O X Axit axetic + Y CTCT ca X, Y ln lt l : A. CH3CHO, CH3CH2COOH. B. CH3CHO, CH3COOCH3. C. CH3CHO, CH2(OH)CH2CHO. D. CH3CHO, HCOOCH2CH3. Cu 195: Cho s phn ng sau :
2 , xt CH CH 2HCHO Butin-1,4-iol H Y Y v Z ln lt l : A. HOCH2CH2CH2CH3 ; CH2=CHCH=CH2. B. HOCH2CH2CH2CH2OH ; CH2=CHCH2CH3. C. HOCH2CH2CH2CH2OH ; CH2=CHCH=CH2. D. HOCH2CH2CH2CH2OH ; CH3CH2CH2CH3. Cu 196: Cho s chuyn ha sau :
H 2O - Z
2 , Mn 2 , as Hirocacbon A Br HOOCCH2COOH B NaOH C CuO D O CTCT ca A l :
2+
A.
B. C3H8.
C. CH2=CHCH3.
D. CH2=CHCOOH.
Cu 197: Cho chui phn ng sau :

/H 2 O 2 , Ni 2 , as 2 , Cu C3H6 H B1 Cl B2 (spc) OH B4 B3 O CTCT ca l : A. CH3COCH3. B. A v C ng. C. CH3CH2CHO. D. CH3CHOHCH3. Cu 198: Xt cc chui bin ha sau :
-
- H 2 O, - H 2 , xt 2 , Ni A H B C Cao su Buna. CTCT ca A l : A. OHCCH2CH2CHO. B. CH3CHO. C. OHC (CH2)2CH2OH. D. A, B, C u ng. Cu 199: Xt cc chui bin ha sau :
2 , Ni A H B C Cao su Buna. CTCT ca A l : A. OHCCH2CH2CHO. B. CH3CHO. C. HOC (CH2)2CH2OH. D. A, B, C u ng. Cu 200: Cho s chuyn ha sau :
/H 2 O 2 , as C2H6 Br B A OH CTCT ca D l : A. CH3CH2OH. B. CH3CHO. Cu 201: Cho s chuyn ha sau :

-
2 , Cu O C
2 , Mn O D
2+
C. CH3COCH3.
D. CH3COOH.
Cu(OH)2 , NaOH Br2 2 SO 4 C2H4 A4 H A1 NaOH A2 CuO A3 A5 Chn cu tr li sai : A. A5 c CTCT l HOOCCOOH. B. A4 l mtianehit. C. A2 l mt iol. D. A5 l mt iaxit. Cu 202: Cho chui bin ha sau :
a. Cht A c th l : A. natri etylat. B. anehit axetic. C. etyl axetat. D. A, B, C u ng. b. Cht B c th l : A. etilen. B. tinh bt. C. glucoz. D. A, B, C u sai. c. Cht C c th l : A. etanal. B. axetilen. C. etylbromua. D. A, C u ng. Cu 203: Khi ru lu ngy ngoi khng kh s c v chua chng t to ra axit no sau y ? A. Axit lactic. B. Axit acrylic. C. Axit axetic. D. Axit oxalic. Cu 204: C th iu ch CH3COOH t A. CH3CHO. B. C2H5OH. C. CH3CCl3. D. Tt c u ng. Cu 205: Trong cng nghip ngi ta c th iu ch CH3COOH bng phng php no sau y ? A. Ln men gim. B. Oxi ha anehit axetic. C. i t metanol. D. C A, B, C.
Cu 206: Cho cc cht : CaC2 (I), CH3CHO (II), CH3COOH (III), C2H2 (IV). S chuyn ha ng iu ch axit axetic l : A. I IV II III. B. IV I II III. C. I II IV III. D. II I IV III. Cu 207: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l : A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. Cu 208: Cho s chuyn ha : CH3CH2Cl + KCN X (1) ; X + H3O+ (un nng) Y(2) Cng thc cu to ca X, Y ln lt l : A. CH3CH2NH2, CH3CH2COOH. B. CH3CH2CN, CH3CH2CHO. C. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4. Cu 209: Cho s phn ng sau :
+ H3 O , t H2 SO4 , t p, t , xt + HCN CH3CH=O C A B C3H4O2 C3H4O2 c tn l : A. Axit axetic. B. Axit metacrylic. C. Axit acrylic. D. Anehit acrylic. Cu 210: Cho s sau :
o o o +
CO2 Mg, ete khan HCl A B C2H5Br C Cht C c cng thc l : A. CH3COOH. B. CH3CH2COOH. C. CH3CH2OH. D. CH3CH2CH2COOH. Cu 211: Pht biu no sau y khng ng ? A. Anehit va c tnh kh, va c tnh oxi ha. B. Trong dy ng ng ca axit fomic, khi phn t kh i tng dn th tnh axit cng tng dn. C. Phn t CH3COOH v C2H5OH u c nguyn t H linh ng trong nhm -OH, song ch c CH3COOH th hin tnh axit. D. Axit fomic tham gia c phn ng trng gng do trong phn t c cha nhm chc CHO. Cu 212: Pht biu ng l : A. Axit cha no khi chy lun cho s mol CO2 ln hn s mol H2O. B. Anehit tc dng vi H2 (xc tc Ni) lun t o ancol bc nht. C. Anehit va c tnh kh va c tnh oxi ha. D. A, B, C u ng. Cu 213: Pht biu no sau y khng ng ? A. Anehit va c tnh kh, va c tnh oxi ha. B. Trong dy ng ng ca axit fomic, khi phn t kh i tng dn th tnh axit cng tng dn. C. Phn t CH3COOH v C2H5OH u c nguyn t H linh ng trong nhm OH, song ch c CH3COOH th hin tnh axit. D. Axit fomic tham gia c phn ng trng gng do trong phn t c nhm chc CHO.
Cu 214: Trong cc pht biu sau : (1) C2H5OH v C6H5OH u phn ng d dng vi CH3COOH. (2) C2H5OH c tnh axit yu hn C6H5OH. (3) C2H5ONa v C6H5ONa phn ng hon ton vi nc cho ra C2H5OH v C6H5OH. Pht biu sai l : A. Ch c (1). C. (1), (2). B. Ch c (2). D. (1), (3). Cu 215: Cho cc cht sau : (1) CH2=CHCH2OH ; (2) CH3CH2CHO ; (3) CH3COCH3. Pht biu ng l : A. (1), (2), (3) l cc ng phn. B. (3) tc dng vi H2 (xc tc Ni) to 1 ancol bc 2. C. (1), (2) tc dng vi H2 (xc tc Ni) u to ra 1 ancol. D. A, B, C u ng. Cu 216: Cho cc cht sau: (1) CH2=CHCH2OH ; (2) OHCCH2CHO ; (3) HCOOCH=CH2 Pht biu ng l : A. (1), (2), (3) tc dng c vi Na. B. Trong A, B, C c 2 cht cho phn ng trng gng. C. (1), (2), (3) l cc ng phn. D. (1), (2), (3) chy u cho s mol H2O b hn s mol CO2. Cu 217: Hp cht hu c E mch h c CTPT C3H6O3 c nhiu trong sa chua. E c th tc dng vi Na v Na2CO3, cn khi tc dng vi CuO nung nng th to ra hp cht hu c khng tham gia phn ng trng gng. CTCT ca E l : A. CH3COOCH2OH. B. CH3CH(OH)COOH. C. HOCH2COOCH3. D. HOCH2CH2COOH. Cu 218: Ba cht hu c X, Y, Z mch khng phn nhnh cng CTPT C2H4O2 v c tnh cht sau : - X tc dng c vi Na2CO3 gii phong CO2. - Y tc dng c vi Na v c phn ng trng gng. - Z tc dng c vi dung dch NaOH, khng tc dng c vi Na. Cc cht X, Y, Z l : A. X : HCOOCH3, Y : CH3COOH, Z : CH2(OH)CHO. B. X : CH3COOH, Y : CH2(OH)CHO, Z : HCOOCH3. C. X : CH2(OH)CHO, Y : CH3COOH, Z : HCOOCH3. D. X : CH3COOH, Y : HCOOCH3, Z : CH2(OH)CHO. Cu 219: Cho 4 hp cht c CTPT l M : C3H6O ; N : C3H6O2 ; P : C3H4O ; Q : C3H4O2. Bit M v P cho phn ng trng gng ; N v Q phn ng c vi dung dch NaOH ; Q phn ng vi H2 t o thnh N ; oxi ha P thu c Q. a. M v P theo th t l : B. C2H5CHO ; CH2=CHCHO. A. C2H5COOH ; CH2=CHCOOH. C. CH2=CHCOOH ; C2H5COOH. D. CH2=CHCHO ; C2H5CHO. b. N v Q theo th t l : A. C2H5COOH ; CH2=CHCOOH. B. CH2=CHCOOH ; C2H5COOH. C. C2H5CHO ; CH2=CHCHO. D. CH2=CHCHO ; C2H5CHO.
Cu 220: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na ; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu t o ca X v Y ln lt l : A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2OCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. Cu 221: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l : A. Ancol o-hiroxibenzylic. B. Axit aipic. C. Axit 3-hiroxipropanoic. D. Etylen glicol. Cu 222: Cht A c ngun gc t thc vt v thng gp trong i sng (cha C, H, O), mch h. Ly cng s mol ca A cho phn ng ht vi Na2CO3 hay vi Na th thu c s mol CO2 bng 3/4 s mol H2. Cht A l : A. Axit malic : HOOCCH(OH) CH2COOH. B. Axit xitric : HOOCCH2C(OH)(COOH)CH2COOH. C. Axit lauric : CH3(CH2)10COOH. D. Axit tactaric : HOOCCH(OH)CH(OH)COOH. Cu 223: Cho dy cc cht : HCHO, CH3COOH, HCOONa, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l : A. 3. B. 6. C. 4. D. 5. Cu 224: Cho cc cht sau : phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l : A. 4. B. 3. C. 2. D. 1. Cu 225: Cho cc cp cht sau : (1) CH3COOH, C6H5OH (2) CH3COOH, C2H5OH (3) C6H5OH, C2H5OH (4) CH3ONa, C6H5OH (5) CH3COOH, C2H5ONa (6) C6H5OH, C2H5ONa Cc cp c th phn ng c vi nhau l : A. (1) v (2). B. (1) v (3). C. (1), (2), (3) v (4). D. (2), (4), (5) v (6). Cu 226: C bao nhiu phn ng xy ra khi cho cc cht C6H5OH ; NaHCO3 ; NaOH ; HCl tc dng vi nhau tng i mt ? A. 3. B. 4. C. 5. D. 6. Cu 227: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l : A. CH3COOH, CH3COOCH3. B. (CH3)2CHOH, HCOOCH3. C. HCOOCH3, CH3COOH. D. CH3COOH, HCOOCH3. Cu 228: Cho tt c cc ng phn mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi : Na, NaOH, NaHCO3. S phn ng xy ra l : A. 2. B. 5. C. 4. D. 3. Cu 229: Cho cc cht sau : CH3CH2CHO (1) ; CH2=CHCHO (2) ; CHCCHO (3) ; CH2=CHCH2OH (4) ; (CH3)2CHOH (5). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l : A. (2), (3), (4), (5). B. (1), (2), (4), (5). C. (1), (2), (3). D. (1), (2), (3), (4).
Cu 230: Cho cc hp cht hu c : C2H4 ; C2H2 ; CH2O ; CH2O2 (mch h) ; C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. a. S cht tc dng c vi dung dch AgNO3/NH3 to ra Ag l : A. 2. B. 4. C. 3. D. 5. b. S cht tc dng c vi dung dch AgNO3/NH3 to ra kt ta l : A. 2. B. 4. C. 3. D. 5. Cu 231: C th phn bit 3 l mt nhn cha : HCOOH ; CH3COOH ; C2H5OH vi ha cht no di y ? A. dd AgNO3/NH3. B. NaOH. C. Na. D. Cu(OH)2/OH-. Cu 232: Ch dng thuc th no di y c th phn bit 4 l mt nhn cha : Fomon ; axit fomic ; axit axetic ; ancol etylic ? A. dd AgNO3/NH3. B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 233: Ch dng thuc th no di y c th phn bit 4 l mt nhn cha : Etylen glicol ; axit fomic ; fomon ; ancol etylic ? A. dd AgNO3/NH3 B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 234: Ch dng qu tm v nc brom c th phn bit c nhng cht no sau y ? A. Axit fomic ; axit axetic ; axit acrylic ; axit propionic. B. Axit axetic; axit acrylic; anilin; toluen; axit fomic. C. Ancol etylic; ancol metylic; axit axetic; axit propionic. D. Ancol etylic; ancol metylic ; phenol ; anilin. Cu 235: phn bit 3 mu ha cht ring bit : Phenol, axit acrylic, axit axetic bng mt thuc th, ngi ta dng thuc th l : A. Dung d ch Na2CO3. B. CaCO3. C. Dung d ch Br2. D. Dung d ch AgNO3/NH3. Cu 236: phn bit axit propionic v axit acrylic ta dng A. dung dch Na2CO3. B. dung dch Br2. C. dung dch C2H5OH. D. dung dch NaOH. Cu 237: C th phn bit CH3CHO v C2H5OH bng phn ng vi A. Cu(OH)2/NaOH. B. Na. C. AgNO3/NH3. D. Tt c u ng. Cu 238: phn bit 3 dung dch ring bit : Axit axetic, axit acrylic, axit fomic ngi ta dng theo th t cc thuc th sau : A. Dung d ch Br2/CCl4. B. Dung dch Br2/H2O. C. Dung d ch Na2CO3. D. Dung d ch AgNO3/NH3 d. Cu 239: phn bit HCOOH v CH3COOH ta dng thuc th l : A. Na. B. dd AgNO3/NH3. C. CaCO3. D. NaOH. Cu 240: Trng gng hon ton hp cht hu c X bng AgNO3/NH3 thu c hn hp sn ph m ch gm cc cht v c. X c cu to l : A. HCHO. B. HCOONH4. C. HCOOH. D. Tt c u ng. Cu 241: C th phn bit HCOOCH3 v CH3COOH bng thuc th no ? A. AgNO3/NH3 B. CaCO3. C. Na. D. Tt c u ng. Cu 242: Cht to c kt ta gch khi un nng vi Cu(OH)2 l : C. HCOOH. D. Tt c u ng. A. HCHO. B. HCOOCH3.
Cu 243: Ch dng mt ha cht no sau y phn bit cc dung dch : Ancol etylic, glixerol, fomalin ? A. Cu(OH)2, toC. B. Na. C. AgNO3 / NH3. D. A, B, C u ng. Cu 244: Cho 3 gi bt l natri axetat, natri phenolat, bari axetat. Dng thuc th no sau y c th phn bit c 3 gi bt ? A. dd H2SO4. B. Qu tm. C. CO2. D. dd NaOH. Cu 245: C 5 bnh ng 5 cht lng sau : Dung dch HCOOH, dung d ch CH3COOH, ancol etylic, glixerol v dung dch anehit axetic. Dng nhng ha cht no sau y phn bit c 5 cht l ng trn ? A. AgNO3/NH3, qu tm. C. Nc brom,Cu(OH)2. B. AgNO3/NH3, Cu(OH)2. D. Cu(OH)2, Na2CO3. Cu 246: trung ha 40 ml gim n cn 25 ml dung dch NaOH 1M. Bit khi lng ring ca gim l 1 g/ml. Vy mu gim n ny c nng l : A. 3,5%. B. 3,75%. C. 4%. D. 5%. Cu 247: trung ha hon ton 4,8 gam hn hp X g m hai axit hu c A, B cn a mol NaOH thu c 6,78 gam mu i. Gi tr ca a l : A. 0,05 mol. B. 0,07 mol. C. 0,09 mol. D. Kt qu khc. Cu 248: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 400 ml dung dch NaOH 1M. Tng khi lng mu i thu c sau phn ng l : A. 3,54 gam. B. 4,46 gam. C. 5,32 gam. D. 11,26 gam. Cu 249: Cho 24,6 gam hn hp CH3COOH, HOOCCOOH, C6H5OH tc dng va vi 300 ml dung dch KOH 1M. Tng khi lng mu i thu c l : A. 16,2 gam. B. 30,3 gam. C. 36 gam. D. Kt qu khc. Cu 250: Cho 2,46 gam hn hp g m HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dung dch NaOH 1M. Tng khi lng mu i khan thu c sau khi phn ng l : A. 3,52 gam. B. 6,45 gam. C. 8,42 gam. D. 3,34 gam. Cu 251: Trung ha 9 gam axit cacbonxylic A bng NaOH va c cn dung dch c 13,4 gam mui khan. A c cng thc phn t l : A. C2H4O2. B. C2H2O4. C. C3H4O2. D. C4H6O4. Cu 252: Trung ha 2,7 gam axit cacboxylic A cn va 60 ml dung dch NaOH 1M. A c cng thc phn t l : A. C2H4O2. B. C3H4O2. C. C4H6O4. D. C2H2O4. Cu 253: Mun trung ha 6,72 gam mt axit hu c A cn dng 200 gam dung dch NaOH 2,24%. CTCT ca A l : A. CH3COOH. B. CH3CH2COOH. C. HCOOH. D. CH2=CHCOOH. Cu 254: Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va r i c cn dung dch sau phn ng c 2,46 gam mui khan. Axit l : A. HCOOH. B. CH2=CHCOOH. C. CH3CH2COOH. D. CH3COOH. Cu 255: Axit hu c A c thnh phn nguyn t gm 40,68% C ; 54,24% O. trung ha 0,05 mol A cn 100 ml dung dch NaOH 1M. CTCT ca A l : A. HOOCCH2CH2COOH. B. HOOCCH(CH3)CH2COOH. C. HOOCCH2COOH. D. HOOCCOOH.
Cu 256: trung ho dung dch cha 8,3 gam 1 axit hu c A cn 500 ml dung dch NaOH 0,2 M. Trong dung dch ancol B 94% (theo khi lng) t s mol ancol : nc l 86 : 14. Cng thc ca A v B l : A. C4H8(COOH)2 v C2H5OH. B. C6H4(COOH)2 v CH3OH. C. C4H8(COOH)2 v CH3OH. D. C6H4(COOH)2 v C2H5OH. Cu 257: A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X. trung ha ht X cn 90 ml dung dch NaOH 1M. A, B ln lt l : A. Axit propionic, axit axetic. B. Axit axetic, axit propionic. C. Axit acrylic, axit propionic. D. Axit axetic, axit acrylic. Cu 258: Cho 13,8 gam axit A tc dng vi 16,8 gam KOH, c cn dung dch sau phn ng thu c 26,46 gam cht rn. cng thc cu to thu gn ca A l : A. C3H6COOH. B. C2H5COOH. C. CH3COOH. D. HCOOH. Cu 259*: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l : A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH. Cu 260: Cho 16,6 gam hn hp gm HCOOH, CH3COOH tc dng ht vi Mg thu c 3,36 lt H2 (ktc). Kh i lng CH3COOH l : A. 12 gam. B. 9 gam. C. 6 gam. D. 4,6 gam. Cu 261: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mu i. Kh i lng ca axit c s nguyn t cacbon t hn c trong X l : A. 3,0 gam. B. 4,6 gam. C. 7,4 gam. D. 6,0 gam. Cu 262: Cho 0,1 mol axit hu c X tc dng vi 11,5 gam h n hp Na v K thu c 21,7 gam cht rn v thy thot ra 2,24 lt kh H2 (ktc). Cng thc cu to ca X l : A. (COOH)2. B. CH3COOH. C. CH2(COOH)2. D. CH2=CHCOOH. Cu 263*: Cho Na d tc dng vi a gam dung dch CH3COOH. Kt thc phn ng, thy kh i 11a lng H2 sinh ra l . Vy nng C% dung dch axit l : 240 A. 10%. B. 25%. C. 4,58%. D. 36%. Cu 264: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mu i ca axit hu c. Cng thc cu t o thu gn ca X l : A. CH2=CHCOOH. B. CH3COOH. C. HCCCOOH. D. CH3CH2COOH. Cu 265: un nng 6 gam CH3COOH vi 9,2 gam C2H5OH (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn cn bng th c 5,5 gam este. Hiu sut phn ng este ha l : A. 55%. B. 62,5%. C. 75%. D. 80%. Cu 266: X l hn hp gm HCOOH v CH3COOH (t l mol 1:1). Ly 21,2 gam X tc dng vi 23 gam C2H5OH (xc tc H2SO4 c, un nng) thu c m gam hn hp este (hiu sut este ha u t 80%). Gi tr m l : A. 40,48 gam. B. 23,4 gam. C. 48,8 gam. D. 25,92 gam. Cu 267: Hn hp X g m axit HCOOH v CH3 COOH (t l mol 1:1). Hn hp Y g m hai ancol CH3OH v C2H5OH (t l mol 3 : 2). Ly 11,13 gam hn hp X tc dng vi 7,52 gam hn hp Y (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut cc phn ng u bng 80%). Gi tr m l : A. 11,616. B. 12,197. C. 14,52. D. 15,246. Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng 129
Cu 268: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l : A. CH3COOH, H% = 68%. B. CH2=CHCOOH, H%= 78%. C. CH2=CHCOOH, H% = 72%. D. CH3COOH, H% = 72%. Cu 269: Cht hu c X mch h c to ra t axit no A v etylen glicol. Bit rng a gam X th hi chim th tch bng th tch ca 6,4 gam oxi cng iu kin nhit v p sut ; a gam X phn ng ht vi xt t o ra 32,8 gam mui. Nu cho 200 gam A phn ng vi 50 gam etilenglicol ta thu c 87,6 gam este. Tn ca X v hiu sut phn ng t o X l : A. Etylen glicol iaxetat ; 74,4%. B. Etylen glicol ifomat ; 74,4%. C. Etylen glicol iaxetat ; 36,3%. D. Etylen glicol ifomat ; 36,6%. Cu 270: Oxi ho anehit OHCCH2CH2CHO trong iu kin thch hp thu c hp cht hu c X. un nng hn hp g m 1 mol X v 1 mol ancol metylic vi xc tc H2SO4 c thu c 2 este Z v Q (MZ < MQ) vi t l kh i lng mZ : mQ = 1,81. Bit ch c 72% ancol chuyn thnh este. S mol Z v Q ln lt l : A. 0,36 v 0,18. B. 0,48 v 0,12. C. 0,24 v 0,24. D. 0,12 v 0,24. Cu 271: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. a. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) : A. 0,342. B. 2,925. C. 2,412. D. 0,456. b. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) : A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 272: t chy hon ton 0,1 mol axit n chc cn V lt O2 ktc, thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr V l : A. 6,72 lt. B. 8,96 lt. C. 4,48 lt. D. 5,6 lt. Cu 273: t chy hon ton mt axit A thu c 0,2 mol CO2 v 0,15 mol H2O. A c cng thc phn t l A. C3H4O4. B. C4H8O2. C. C4H6O4. D. C5H8O4. Cu 274: t chy ht 10 ml th tch hi mt hp cht hu c A cn dng 30 ml O2, sn ph m thu c ch g m CO2 v H2O c th tch bng nhau v u bng th tch O2 phn ng. CTPT ca A l : A. C2H4O2. B. C3H6O3. C. C3H6O2. D. C4H8O2. Cu 275: t chy hon ton 4,38 gam mt axit E no, mch thng thu c 4,032 lt CO2 (ktc) v 2,7 gam H2O. CTCT ca E l : A. CH3COOH. B. C17H35COOH. C. HOOC(CH2)4COOH. D. CH2=C(CH3)COOH. Cu 276: t chy hon ton 0,44 gam mt axit hu c, sn phm chy cho hp th hon ton vo bnh 1 ng P2O5, bnh 2 ng dung dch KOH. Sau th nghim thy kh i lng bnh 1 tng 0,36 gam v bnh 2 tng 0,88 gam. CTPT ca axit l : A. C4H8O2. B. C5H10O2. C. C2H6O2. D. C2H4O2. Cu 277: Cc sn phm thu c khi t chy hon ton 3 gam axit hu c X c dn ln lt qua bnh 1 ng H2SO4 c v bnh 2 ng dung dch NaOH. Sau th nghim thy kh i lng bnh 1 tng 1,8 gam v kh i lng bnh 2 tng 4,4 gam. CTCT ca A l : A. HCOOH. B. C2H5COOH. C. CH3COOH. D. A hoc B hoc C. 130Ti khng s tht bi v ti hiu: Tht bi l ngi bn ng hnh trn con ng i ti nhng thnh cng
Cu 278: Chia 0,3 mol axit cacobxylic A thnh hai phn bng nhau : - t chy phn 1 c 19,8 gam CO2. - Cho phn 2 tc dng hon ton vi 0,2 mol NaOH, thy sau phn ng khng cn NaOH. Vy A c cng thc phn t l : A. C3H6O2. B. C3H4O2. C. C3H4O4. D. C6H8O4. Cu 279: t chy hon ton 2,22 gam mt axit hu c no A thu c 1,62 gam H2O. CTCT ca A l : A. C3H7COOH. B. C2H5COOH. C. HCOOH. D. CH3COOH. Cu 280: Z l mt axit hu c. t chy 0,1 mol Z cn 6,72 lt O2 (ktc). CTCT ca Z l : A. CH3COOH. B. CH2=CHCOOH. C. HCOOH. D. Kt qu khc. Cu 281: t chy ht 1 th tch hi axit hu c A c 3 th tch hn hp CO2 v hi nc khi o cng iu kin. CTCT ca A l : A. HCOOH. B. CH3COOH. C. HOOCCOOH. D. HOOCCH2COOH. Cu 282: t chy hon ton 0,1 mol axit cacboxylic A thu c cha n 8 gam hn hp CO2 v H2O. A c tn l : A. Axit fomic. B. Axit axetic. C. Axit acrylic. D. Axit oxalic. Cu 283: X l hn hp 2 axit cacboxylic no, h, phn t mi axit cha khng qu 2 nhm COOH. t chy hon ton 9,8 gam X c 11 gam CO2 v 3,6 gam H2O. Hai axit trong hn hp X l : A. HCOOH v CH3COOH. B. HCOOH v HOOCCH2COOH. C. HCOOH v HOOCCOOH. D. CH3COOH v HOOCCH2COOH. Cu 284: trung ha a mol axit cacboxylic A cn 2a mol NaOH. t chy hon ton a mol A thu c 3a mol CO2. A c cng thc phn t l : B. C3H6O2. C. C6H10O4. D. C3H4O4. A. C3H4O2. Cu 285: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol A c 2a mol CO2. A l : A. CH3COOH. B. HOOCCOOH. C. Axit n chc no. D. Axit n chc khng no. Cu 286: Hn hp X g m 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt CO2 (kc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. CTCT ca 2 axit l : A. HCOOH v C2H5COOH. B. CH3COOH v C2H5COOH. C. HCOOH v HOOCCOOH. D. CH3COOH v HOOCCH2COOH. Cu 287: t chy hon ton 3,12 gam axit cacboxylic A c 3,96 gam CO2. Trung ha cng lng axit ny cn 30 ml dung dch NaOH 2M. A c cng thc phn t l : A. C2H4O2. B. C4H6O2. C. C3H4O2. D. C3H4O4. Cu 288*: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn m t tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v kh i lng ca Z trong hn hp X ln lt l : A. HOOCCOOH v 42,86%. B. HOOCCOOH v 60,00%. C. HOOCCH2COOH v 70,87%. D. HOOCCH2COOH v 54,88%. Cu 289*: t chy hon ton 29,6 gam hn hp X gm CH3COOH, CxHyCOOH, v (COOH)2 thu c 14,4 gam H2O v m gam CO2. Mt khc, 29,6 gam hn hp X phn ng hon ton v i NaHCO3 d thu c 11,2 lt (ktc) kh CO2. Gi tr ca m l : A. 33 gam. B. 48,4 gam. C. 44 gam. D. 52,8 gam.
Cu 290: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H2 hon ton th kh i lng sn phm cu i cng l : A. 11,1 gam. B. 7,4 gam. C. 11,2 gam. D. 11,0 gam. Cu 291: A l axit cacboxylic n chc cha no (1 ni i C=C). A tc dng vi brom cho sn phm cha 65,04% brom (theo khi lng). Vy A c cng thc phn t l : A. C3H4O2. B. C4H6O2. C. C5H8O2. D. C5H6O2. Cu 292: Cho 3,15 gam hn hp X g m axit axetic, axit acrylic, axit propionic va lm mt mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dung dch NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l : A. 35,24%. B. 45,71%. C. 19,05%. D. 23,49%. Cu 293: Cho 10 gam hn hp X gm HCHO v HCOOH tc dng vi lng (d) dung dch AgNO3/NH3 c 99,36 gam bc. Thnh phn trm v khi lng HCHO trong hn hp X l : A. 54%. B. 69%. C. 64,28%. D. 46%. Cu 294: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung d ch NH3, un nng. Sau khi cc phn ng xy ra hon ton, kh i lng Ag t o thnh l : A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 295: Oxi ha 1,8 gam HCHO thnh axit vi hiu sut H% thu c h n hp X. Cho X tham gia phn ng trng gng thu c 16,2 gam Ag. Gi tr ca H l : A. 75. B. 60. C. 62,5. D. 25. Cu 296: Oxi ho 25,6 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn bng nhau Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va vi 100 ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l : A. 64,8. B. 32,4. C. 129,6. D. 108. Cu 297: C mt lng anehit HCHO c chia lm 2 phn bng nhau, m i phn cha a mol HCHO. - Phn 1: Cho tc dng vi lng d dung dch AgNO3/NH3 thu c m gam Ag. - Phn 2: Oxi ha bng Oxi thnh HCOOH vi hiu sut 40% thu c dung dch X. Cho X tc dng vi lng d dung dch AgNO3/NH3 thu c m gam Ag. T s m/m c gi tr bng ? A. 0,8. B. 0,2. C. 0,4. D. 0,6. Cu 298: Trung ho 8,2 gam hn hp g m axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn g i ca X l : A. Axit metacrylic. B. Axit acrylic. C. Axit propanoic. D. Axit etanoic. Cu 299: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l : B. CH3COOH, C2H5COOH. A. HCOOH, C3H7COOH. C. CH3COOH, C3H7COOH. D. HCOOH, C2H5COOH.
Cu 300: Mt hp cht hu c A (cha C, H, O), c 50% oxi v kh i lng. Ngi ta cho A qua ng ng 10,4 gam CuO nung nng chuyn ht A thnh 2 cht hu c. Sau phn ng lng cht rn cn li l 8,48 gam cht rn. Mt khc cho hn hp 2 cht hu c trn tc dng vi dung dch AgNO3 (d) trong NH3 to ra hn hp 2 mu i v 38,88 gam Ag. Kh i lng ca A cn dng l : A. 1,28 gam. B. 4,8 gam. C. 2,56 gam. D. 3,2 gam. Cu 301: t chy hon ton 0,1 mol cht X l mu i Na ca mt axit hu c thu c hi H2O, Na2CO3 v 0,15 mol CO2. CTCT ca X l : A. C3H7COONa. B. CH3COONa. C. CH3COONa. D. HCOONa. Cu 302: t chy hon ton a mol hn hp X gm 2 mu i ca hai axit no n chc l ng ng lin ti, cn 9,52 lt O2 (0oC, 2 atm). Phn cht rn cn li sau khi t cn nng 10,6 gam. CTPT ca hai mu i v s mol ca chng trong hn hp X l : A. CH3COONa (0,15 mol) v C2H5COONa (0,1 mol). B. CH3COONa (0,1 mol) v C2H5COONa (0,15 mol). C. C2H5COONa (0,05 mol) v C3H7COONa (0,15 mol). D. C2H5COONa (0,1 mol) v C3H7COONa (0,1 mol). Cu 303*: Hn hp X g m 0,01 mol HCOONa v a mol mu i natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO2, hi nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy kh i lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mu i natri l : A. C2H5COONa v C3H7COONa. B. C3H7COONa v C4H9COONa. C. CH3COONa v C2H5COONa. D. CH3COONa v C3H7COONa. Cu 304: Khi lng axit axetic thu c khi ln men 1 lt ancol etylic 8o l bao nhiu? Bit kh i lng ring ca ancol nguyn cht bng 0,8 g/ml v hiu sut phn ng t 92%. A. 76,8 gam. B. 90,8 gam. C. 73,6 gam. D. 58,88 gam. Cu 305: iu ch 13,5 gam axit lactic t h tinh bt bng cch ln men lactic. Bit hiu sut thy phn tinh bt v ln men lactic tng ng l 85% v 80%, khi lng tinh bt cn dng l : A. 22,33 gam. B. 21,02 gam. C. 17,87 gam. D. Kt qu khc. Cu 306: Thc hin phn ng oxi ha m gam ancol etylic nguyn cht thnh axit axetic (hiu sut phn ng t 25%) thu c hn hp Y, cho Y tc dng vi Na d thu c 5,6 lt H2 (ktc). Gi tr ca m l : A. 18,4 gam. B. 9,2 gam. C. 23 gam. D. 4,6 gam. Cu 307*: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng t o ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d, thu c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120 ml. Hiu sut phn ng oxi ho ancol etylic l : A. 42,86%. B. 66,7%. C. 85,7%. D. 75%. Cu 308*: Oxi ho 9,2 gam ancol etylic bng CuO un nng thu c 13,2 gam hn hp g m anehit, axit, ancol d v nc. Hn hp ny tc dng vi Na sinh ra 3,36 lt H2 ( ktc). Phn trm ancol b oxi ho l : A. 25%. B. 50%. C. 75%. D. 90%. o Cu 301*: Oxi ha 0,125 mol ancol n chc A bng 0,05 mol O2 (xt, t ) c 5,6 gam hn hp X gm axit cacboxylic, anehit, ancol d v nc. A c cng thc phn t l : A. CH4O. B. C2H6O. C. C3H6O. D. C3H8O.
Cu 310*: Oxi ha 6 gam ancol n chc A bng oxi khng kh (c xc tc v un nng) thu c 8,4 gam hn hp gm axit cacboxylic, anehit, ancol d v nc. Phn trm A b oxi ha l : A. 60%. B. 75%. C. 80%. D. 53,33%.
PHN 2 :
CHUYN 1 :
1B 11D 21A 31C 41B 51B 61A 71C 81A 91B 101B 111A 121B 131B 141C 151B 2A 12B 22B 32A 42B 52A 62C 72B 82B 92C 102D 112C 122D 132B 142A 152C 3B 13D 23B 33C 43D 53B 63C 73C 83A 93C 103A 113C 123B 133B 143B 153B
P N
I CNG HA HC HU C
4B 14C 24D 34C 44A 54B 64D 74C 84A 94C 104A 114A 124C 134D 144A 154B 5A 15C 25C 35A 45A 55A 65C 75B 85D 95A 105D 115C 125C 135D 145C 155C 6C 16D 26C 36D 46A 56D 66D 76D 86B 96C 106D 116C 126B 136C 146D 7B 17A 27C 37D 47C 57C 67D 77B 87C 97D 107A 117B 127C 137C 147C 8D 18B 28D 38C 48D 58B 68B 78C 88D 98B 108B 118D 128A 138B 148B 9B 19D 29D 39B 49A 59B 69A 79A 89C 99A 109B 119A 129C 139D 149B 10C 20D 30B 40C 50D 60B 70C 80C 90C 100B 110D 120B 130A 140A 150B
CHUYN 2 :
1D 11B 21A 31C 41B 51C 61B 71A 81A 91B 101B 111D 121D 131C 141C 2A 12B 22C 32D 42C 52B 62B 72B 82A 92D 102A 112DA 122C 132B 142D 3C 13C 23B 33B 43C 53B 63B 73C 83D 93A 103A 113B 123A 133B 143D 4B 14C 24D 34B 44D 54A 64C 74D 84A 94C 104B 114B 124B 134B
HIROCACBON NO
5D 15B 25B 35B 45C 55B 65A 75B 85D 95A 105D 115D 125B 135A 6D 16D 26B 36D 46A 56B 66D 76C 86A 96B 106BD 116A 126D 136B 7D 17A 27D 37B 47B 57D 67C 77D 87C 97A 107BD 117D 127D 137A 8A 18A 28C 38C 48D 58A 68B 78C 88B 98CC 108B 118B 128B 138C 9D 19B 29C 39A 49B 59D 69A 79A 89B 99C 109D 119B 129C 139B 10D 20D 30A 40D 50A 60B 70BC 80D 90C 100B 110D 120D 130D 140B
CHUYN 3 :
1B 11A 21A 31B 41B 51B 61A 71B 81A 91A 101C 111C 121A 131B 141D 151B 161C 171B 181C 191B 201C 211A 221B 231A 241B 251D 261D 271A 2B 12C 22C 32B 42C 52B 62A 72A 82AA 92D 102A 112B 122D 132C 142A 152C 162D 172C 182D 192B 202D 212D 222D 232B 242B 252B 262A 272A 3C 13D 23A 33A 43D 53A 63A 73A 83A 93B 103C 113D 123A 133C 143B 153C 163C 173C 183C 193C 203C 213C 223A 233A 243D 253C 263A 273C
HIROCACBON KHNG NO
4C 14C 24C 34A 44C 54C 64D 74BB 84A 94C 104C 114D 124C 134C 144B 154D 164D 174C 184D 194D 204C 214C 224D 234D 244A 254A 264C 274C 5D 15B 25A 35D 45B 55C 65C 75D 85C 95D 105B 115A 125A 135A 145C 155A 165C 175C 185C 195B 205C 215D 225C 235AC 245B 255C 265A 275A 6C 16A 26C 36C 46D 56A 66A 76D 86A 96B 106C 116D 126C 136A 146B 156C 166B 176C 186B 196B 206D 216A 226C 236D 246D 256B 266A 276D 7C 17A 27B 37D 47B 57A 67A 77C 87D 97A 107D 117A 127A 137B 147B 157D 167C 177A 187C 197D 207A 217C 227C 237A 247C 257DA 267D 8C 18D 28A 38D 48C 58D 68B 78D 88C 98C 108B 118C 128A 138A 148A 158B 168D 178D 188B 198B 208D 218A 228C 238A 248A 258C 268C 9D 19D 29B 39C 49B 59B 69B 79D 89A 99A 109D 119C 129C 139D 149B 159A 169A 179C 189B 199C 209C 219A 229A 239A 249C 259D 269A 10B 20C 30C 40B 50A 60B 70C 80B 90B 100C 110B 120A 130A 140B 150D 160B 170C 180D 190B 200C 210D 220D 230A 240D 250D 260A 270D
CHUYN 4 :
1B 11B 21B 31D 41C 51C 61D 71C 81A 91D 101B 111D 2A 12A 22B 32D 42B 52A 62A 72C 82C 92D 102D 112C 3C 13C 23A 33A 43D 53B 63D 73D 83D 93B 103B 113C 4D 14C 24C 34B 44D 54C 64D 74A 84B 94A 104D 114A
HIROCACBON THM
5D 15D 25C 35D 45A 55A 65D 75C 85C 95C 105C 115A 6D 16A 26D 36A 46D 56D 66D 76A 86C 96B 106A 116A 7B 17C 27D 37B 47B 57A 67B 77D 87B 97B 107AC 8D 18C 28D 38A 48D 58C 68B 78A 88C 98A 108C 9C 19A 29C 39C 49A 59A 69D 79A 89A 99A 109C 10C 20C 30A 40D 50B 60C 70B 80B 90A 100B 110D
CHUYN 5 : DN XUT HALOGEN PHENOL ANCOL

1B 11BA 21D 31B 41D 51B 61D 71C 81B 91D 101C 111D 121C 131C 141B 151C 161D 171C 181A 191B 201A 211A 221A 231B 241D 251A 261A 271A 281D 291D 301C 311B 2C 12B 22D 32D 42B 52B 62D 72B 82C 92D 102A 112A 122C 132A 142B 152B 162C 172B 182A 192C 202A 212B 222C 232A 242A 252B 262D 272B 282C 292D 302A 312C 3B 13D 23D 33C 43D 53C 63C 73B 83A 93D 103B 113A 123B 133B 143D 153D 163B 173A 183D 193D 203C 213B 223A 233A 243D 253A 263A 273B 283D 293D 303B 313A 4B 14A 24D 34B 44D 54A 64C 74B 84D 94A 104A 114D 124C 134B 144D 154D 164C 174BA 184D 194C 204D 214C 224C 234A 244C 254C 264C 274B 284B 294D 304C 314C 5A 15D 25D 35A 45C 55A 65B 75B 85B 95D 105C 115A 125B 135D 145D 155B 165D 175B 185D 195A 205C 215A 225B 235B 245B 255B 265D 275B 285D 295B 305D 6D 16A 26C 36B 46C 56C 66A 76D 86D 96B 106C 116A 126C 136A 146A 156D 166B 176C 186C 196B 206D 216B 226C 236D 246D 256C 266A 276D 286C 296B 306B 7A 17D 27B 37B 47A 57D 67B 77C 87C 97D 107C 117D 127C 137D 147D 157D 167D 177D 187C 197C 207C 217B 227C 237D 247A 257A 257D 277B 287D 297C 307C 8B 18D 28D 38C 48D 58A 68A 78B 88D 98D 108A 118A 128C 138D 148B 158A 168C 178A 188D 198A 208D 218A 228C 238D 248B 258C 268B 278D 288D 298C 308C 9C 19A 29A 39C 49C 59C 69A 79C 89D 99C 109A 119D 129C 139B 149A 159C 169D 179D 189C 199D 209A 219C 229C 239D 249C 259C 269D 279A 289D 299B 309A 10C 20C 30B 40A 50B 60C 70B 80D 90BBA 100D 110D 120D 130C 140A 150C 160B 170D 180A 190B 200A 210C 220A 230B 240C 250B 260ACB 270B 280D 290C 300D 310B
CHUYN 6 : ANEHIT XETON AXIT CACBOXYLIC

1B 11D 21C 31D 41A 51C 61B 71B 81B 91A 101C 111B 121D 131C 141D 151D 161A 171D 181D 191B 201B 211B 221C 231D 241D 251B 261D 271BA 281C 291B 301B 2A 12DA 22C 32C 42A 52A 62C 72A 82A 92A 102B 112B 122B 132C 142B 152C 162D 172D 182A 192B 202DAD 212D 222B 232C 242D 252D 262C 272A 282A 292C 302D 3D 13A 23C 33D 43D 53A 63B 73B 83C 93C 103A 113D 123A 133D 143A 153D 163B 173C 183D 193D 203C 213B 223C 233C 243A 253A 263B 273C 283B 293A 303A 4C 14B 24A 34D 44D 54D 64A 74A 84A 94BB 104C 114D 124C 134B 144C 154A 164D 174C 184D 194B 204D 214D 224A 234B 244A 254D 264A 274B 284D 294C 304A 5B 15C 25A 35BD 45A 55CC 65C 75D 85B 95B 105C 115AB 125B 135CA 145D 155D 165A 175C 185B 195C 205D 215D 225D 235C 245D 255A 265B 275C 285B 295A 305C 6A 16D 26B 36D 46C 56AD 66D 76A 86B 96C 106B 116A 126A 136C 146A 156A 166B 176A 186D 196A 206A 216B 226B 236B 246B 256D 266D 276A 286C 296D 306A 7C 17D 27D 37B 47A 57B 67A 77C 87A 97A 107B 117D 127D 137C 147C 157C 167C 177B 187D 197A 207C 217B 227D 237D 247C 257B 257A 277D 287D 297A 307D 8C 18B 28A 38C 48D 58B 68A 78C 88B 98C 108C 118A 128B 138C 148A 158B 168C 178C 188B 198B 208C 218B 228B 238B 248D 258C 268C 278C 288A 298B 308C 9C 19C 29D 39C 49D 59D 69C 79A 89C 99D 109C 119B 129A 139A 149C 159B 169C 179D 189D 199D 209C 219BA 229D 239B 249C 259B 269A 279B 289C 299D 309A 10C 20C 30A 40B 50B 60A 70B 80D 90B 100B 110C 120B 130A 140B 150C 160B 170C 180D 190C 200D 210B 220D 230CB 240D 250D 260A 270A 280B 290A 300A 310C

6 Chuyen de Hoa Huu Co 11

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6 Chuyen de Hoa Huu Co 11

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Bin son v ging dy : Gio vin Nguyn Minh Tun T Ha Trng THPT Chuyn Hng Vng Ph Th

Li gii thiu Phn 1: Gii thiu cc chuyn ha hu c 11

2 3 134 3 17 18 32 33 57 58 68 69 102 103 134 135 139

PHN 1: GII THIU CC CHUYN HA HU C 11

Cht ng ng ca benzen l : A. I, II, III. B. II, III.

D. II, III, IV.

C 2H5 | Cu 14: Ankan CH 3 C CH 2 CH CH 2 CH 3 c tn l : | | CH 3 CH 3

Cu 16: Tn gi ca cht hu c X c CTCT : CH 3 CH CH CH 2 CH 3 l : | | NO2 CH3 A. 4-metyl-3-nitropentan. C. 2-metyl-3-nitropentan. B. 3-nitro-4-metylpetan. D. 2-nitro-3-metylpentan.

C. III < II < I.

D. II < III < I.

CH3 | CH 3 C CH3 (II) | CH3

C. III < II < I.

D. II < III < I.

CH3CH2CH2CH2CH2CH3 (II) CH3 CH2 CH CH3 (IV) | CH3

Cu 59: Trong cc phng trnh ha hc : Al4C3 C4H10 + 12H2O

(1) (2) (3) (4)

CaO, t CH4 + Na2CO3 CaO, t CH4 + 2Na2CO3

BI TP TRC NGHIM V XICLOANKAN

CHUYN 3 : HIROCACBON KHNG NO

B. BI TP TRC NGHIM V ANKAIEN V TECPEN

BI TP TRC NGHIM V ANKIN

Cu 185: C chui phn ng sau:

(1) (2) (3) (4)

t + AgNO3 + NH3 CH3CCAg + NH4NO3

t , xt (2) C2H4 + H2 t , xt (4) 3C2H2

(5) C2H2 + AgNO3/NH3 S phn ng l phn ng oxi ho kh l : A. 2. B. 3.

t , xt (6) Propin + H2O

BI TP TRC NGHIM V BENZEN, ANKYLBENZEN V MT S HIDROCACBON THM KHC

CH3 CH3 CH3 CH3 CH3

B. metyletylbenzen. D. p-metyletylbenzen. B. n-propylbenzen. D. imetylbenzen. C. Cumen. D. Xilen.

Tn gi ca hirocacbon trn l : A. m-etyltoluen. C. 1-etyl-3-metylbenzen. Cu 27: Cho hirocacbon thm :

Tn gi ca ca hirocacbon trn l : A. m-vinyltoluen. C. m-metylstiren. Cu 28: Cht

CH2 CH2 CH2 CH3

CH3 CH2 CH3 A. 1-butyl-3-metyl-4-etylbenzen. C. 1-etyl-2-metyl-4-butylbenzen.

CH3 CH3 CH2

Nhm X, Y ph hp s trn l : A. X(CH3), Y(NO2). C. X(NH2), Y(CH3). Cu 48: Cho s :

B. X(NO2), Y(CH3). D. A, C u ng.

AlCl3 , t A. C6H6 + CH3Cl C. Tch hiro t metylxiclohexan.

xt,t Cu 66: A toluen + 4H2. Vy A l : A. metylxiclohexan. C. n-hexan.

H Cu 67: Benzen + X etylbenzen. Vy X l : A. axetilen. B. etilen. C. etyl clorua.

CHUYN 5 : DN XUT HALOGEN PHENOL ANCOL

Cu 39: Cho s phn ng sau:

KOH, H 2O Cl2 + Cl2 A glixerol B C3H6 as, 500 o C to

C. C3H5(OCOR)3 + 3NaOH D. C A, B, C. Cu 42: Cho s phn ng sau :

NaOH n/c, to, p

BI TP TRC NGHIM V ANCOL

(2) ... O H ... O H... | | H CH3 (4) ... O H ... O H... | | H H

CH3 | D. CH3 - CH 2 - C - OH | CH3

H2O (1) (2) (3) (4) D. (2) (4).

Cu 105: Cho cc phn ng :

+ H2O (1) (2) (3) (4)

H2 SO4 c C 2H5OC2H5 140 0 C H2 SO4 c C2H4 170 0 C

(1) (2) (3)

H 2CH 3 CH CH 2 | | OH OH + Cu(OH)2 (4) CH 2 O] O CH 2 | | Cu ^ O CH + 2H 2 O CH O | | H CH 3 CH 3

CH3 | B. CH3 C OH | CH3

Cu 127: Sn phm ca phn ng sau y l cht no ?

B. butan-1-ol. D. propan-1-ol. (2) CH 3 C(CH 3 ) 2 OH (4) CH 3 CH CH 2 CH 2 OH | OH

BI TP TRC NGHIM V PHENOL V BI TP TNG HP CHUYN 5

Cu 245: Gi tn hp cht c cng thc cu to nh sau :

CHUYN 6 : ANEHIT XETON AXIT CACBOXYLIC

BI TP TRC NGHIM AXIT CACBOXYLIC V BI TP TNG HP CHUYN 6

CH3 CH CH 2 CH COOH | | C2H5 C 2H 5

B. CH3CH(OH) COOH. D. HOOCCH2COOH. B. CH3CH(OH) COOH. D. HOOCCH2COOH. B. HOOCCH=CHCOOH. D. CH3(CH2)7CH=CH(CH2)COOH.

CO2 + 2Ag + H2O (HCOO)2Cu + H2O