volume

0
1
2
3
4
5
6
6.5
7
7.5
8
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7

ph
4.34
4.47
4.5
4.56
4.63
4.75
5.19
5.04
5.11
5.21
5.3
5.31
5.31
5.32
5.34
5.36
5.37
5.38
5.43
5.44
5.45
5.48
5.49
5.52
5.56
5.6
5.65
5.7
5.8
5.82
5.88
5.99
6.15
6.38
6.78
7.53
8.09
8.59
8.85
8.94
9
9.1
9.06
9.08
9.13
8.15
9.18
9.2

E
256.928
264.624
266.4
269.952
274.096
281.2
307.248
298.368
302.512
308.432
313.76
314.352
314.352
314.944
316.128
317.312
317.904
318.496
321.456
322.048
322.64
324.416
325.008
326.784
329.152
331.52
334.48
337.44
343.36
344.544
348.096
354.608
364.08
377.696
401.376
445.776
478.928
508.528
523.92
529.248
532.8
538.72
536.352
537.536
540.496
482.48
543.456
544.64

dE
7.696
1.776
3.552
4.144
7.104
26.048
-8.88
4.144
5.92
5.328
0.592
0
0.592
1.184
1.184
0.592
0.592
2.96
0.592
0.592
1.776
0.592
1.776
2.368
2.368
2.96
2.96
5.92
1.184
3.552
6.512
9.472
13.616
23.68
44.4
33.152
29.6
15.392
5.328
3.552
5.92
-2.368
1.184
2.96
-58.016
60.976
1.184

NaOH - Asam Oksalat

dV
d E/d V
1
1
1
1
1
1
0.5
0.5
0.5
0.5
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1

7.696
1.776
3.552
4.144
7.104
26.048
-17.76
8.288
11.84
10.656
5.92
0
5.92
11.84
11.84
5.92
5.92
29.6
5.92
5.92
17.76
5.92
17.76
23.68
23.68
29.6
29.6
59.2
11.84
35.52
65.12
94.72
136.16
236.8
444
331.52
296
153.92
53.28
35.52
59.2
-23.68
11.84
29.6
-580.16
609.76
11.84

d (d E/d V)/d V

-5.92
1.776
0.592
2.96
18.944
-43.808
52.096
7.104
-2.368
-9.472
-59.2
59.2
59.2
5.68434E-12
-59.2
0
236.8
-236.8
-5.68434E-12
118.4
-118.4
118.4
59.2
0
59.2
-2.62901E-11
296
-473.6
236.8
296
296
414.4
1006.4
2072
-1124.8
-355.2
-1420.8
-1006.4
-177.6
236.8
-828.8
355.2
177.6
-6097.6
11899.2
-5979.2

11.8
11.9
12
12.5
13
13.5
14
15
16
17
18
19
20

9.23
9.23
9.24
9.31
9.39
9.42
9.46
9.55
9.59
9.61
9.62
9.63
9.67

546.416
546.416
547.008
551.152
555.888
557.664
560.032
565.36
567.728
568.912
569.504
570.096
572.464

1.776
0
0.592
4.144
4.736
1.776
2.368
5.328
2.368
1.184
0.592
0.592
2.368

0.1
0.1
0.1
0.5
0.5
0.5
0.5
1
1
1
1
1
1

17.76
0
5.92
8.288
9.472
3.552
4.736
5.328
2.368
1.184
0.592
0.592
2.368

59.2
-177.6
59.2
23.68
2.368
-11.84
2.368
1.184
-2.96
-1.184
-0.592
1.13687E-13
1.776

kurva utama naoh oksalat

700
600
500
400
300

200
100
14000
0
12000
0
10000
8000
6000
4000
2000
0
-2000 0
-4000
-6000
-8000

10

85782977629

konsentrasi NaOH
0.0875
konsentrasi ch3cooh
0.0840

va utama naoh oksalat

s
E

15

20

25

derivat 1
800
600
400
200
0

d E/d V
0

10

15

20

25

-200

-400
-600
-800

derivat 2

10

15

20

d (d E/d V)/d V
25

volume
0
1
2
3
4
5
6
7
8
9
9.5
10
10.5
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4
12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5
13.6
13.7
13.8
13.9
14
14.1

ph
2.39
2.39
2.36
2.38
2.4
2.43
2.48
2.5
2.59
2.66
2.71
2.79
2.91
3.1
3.1
3.14
3.19
3.23
3.27
3.32
3.38
3.42
3.47
3.52
3.55
3.59
3.64
3.68
3.71
3.76
3.78
3.82
3.85
3.87
3.92
3.94
3.97
4
4.04
4.06
4.08
4.1
4.12
4.15
4.17

E
141.01
141.01
139.24
140.42
141.6
143.37
146.32
147.5
152.81
156.94
159.89
164.61
171.69
182.9
182.9
185.26
188.21
190.57
192.93
195.88
199.42
201.78
204.73
207.68
209.45
211.81
214.76
217.12
218.89
221.84
223.02
225.38
227.15
228.33
231.28
232.46
234.23
236
238.36
239.54
240.72
241.9
243.08
244.85
246.03

dE

dV

d E/d V

NaOH - Asam Asetat

d (d E/d V)/d V

0
-1.77
1.18
1.18
1.77
2.95
1.18
5.31
4.13
2.95
4.72
7.08
11.21
0
2.36
2.95
2.36
2.36
2.95
3.54
2.36
2.95
2.95
1.77
2.36
2.95
2.36
1.77
2.95
1.18
2.36
1.77
1.18
2.95
1.18
1.77
1.77
2.36
1.18
1.18
1.18
1.18
1.77
1.18

1
1
1
1
1
1
1
1
1
0.5
0.5
0.5
0.5
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1

0
-1.77
1.18
1.18
1.77
2.95
1.18
5.31
4.13
5.9
9.44
14.16
22.42
0
23.6
29.5
23.6
23.6
29.5
35.4
23.6
29.5
29.5
17.7
23.6
29.5
23.6
17.7
29.5
11.8
23.6
17.7
11.8
29.5
11.8
17.7
17.7
23.6
11.8
11.8
11.8
11.8
17.7
11.8

-1.77
2.95
0
0.59
1.18
-1.77
4.13
-1.18
1.77
7.08
9.44
16.52
-44.84
236
59
-59
2.84217E-12
59
59
-118
59
-2.84217E-12
-118
59
59
-59
-59
118
-177
118
-59
-59
177
-177
59
3.19744E-13
59
-118
8.52651E-12
-7.78044E-12
7.78044E-12
59
-59
118

800

700

14.2
14.3
14.4
14.5
14.6
14.7
14.8
14.9
15
15.5
16
16.5
17
18
19
19.5
20
20.5
21
21.1
21.2
21.3
21.4
21.5
21.6
21.7
21.8
21.9
22
22.1
22.2
22.3
22.4
22.5
22.6
22.7
22.8
22.9
23
23.1
23.2
23.3
23.4
23.5
23.6
23.7
23.8

4.21
4.22
4.25
4.26
4.29
4.31
4.33
4.35
4.37
4.43
4.52
4.58
4.65
4.85
5.03
5.12
5.25
5.42
5.57
5.73
5.83
5.88
5.96
6.02
6.13
6.48
7.21
7.35
7.85
8.87
9.78
10.14
10.42
10.51
10.61
10.74
10.81
10.88
10.96
11.01
11.06
11.08
11.12
11.15
11.18
11.2
11.25

248.39
248.98
250.75
251.34
253.11
254.29
255.47
256.65
257.83
261.37
266.68
270.22
274.35
286.15
296.77
302.08
309.75
319.78
328.63
338.07
343.97
346.92
351.64
355.18
361.67
382.32
425.39
433.65
463.15
523.33
577.02
598.26
614.78
620.09
625.99
633.66
637.79
641.92
646.64
649.59
652.54
653.72
656.08
657.85
659.62
660.8
663.75

2.36
0.59
1.77
0.59
1.77
1.18
1.18
1.18
1.18
3.54
5.31
3.54
4.13
11.8
10.62
5.31
7.67
10.03
8.85
9.44
5.9
2.95
4.72
3.54
6.49
20.65
43.07
8.26
29.5
60.18
53.69
21.24
16.52
5.31
5.9
7.67
4.13
4.13
4.72
2.95
2.95
1.18
2.36
1.77
1.77
1.18
2.95

0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.5
0.5
0.5
0.5
1
1
0.5
0.5
0.5
0.5
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1

23.6
5.9
17.7
5.9
17.7
11.8
11.8
11.8
11.8
7.08
10.62
7.08
8.26
11.8
10.62
10.62
15.34
20.06
17.7
94.4
59
29.5
47.2
35.4
64.9
206.5
430.7
82.6
295
601.8
536.9
212.4
165.2
53.1
59
76.7
41.3
41.3
47.2
29.5
29.5
11.8
23.6
17.7
17.7
11.8
29.5

-177
118
-118
118
-59
6.43041E-12
-3.58824E-12
2.84217E-12
-47.2
7.08
-7.08
2.36
7.08
-1.18
-1.7053E-13
9.44
9.44
-4.72
153.4
-354
-295
177
-118
295
1416
2242
-3481
2124
3068
-649
-3245
-472
-1121
59
177
-354
3.33955E-12
59
-177
2.18492E-11
-177
118
-59
-1.13687E-11
-59
177
-177

600

500

400

300

200

100

0
0

700
600
500
400
300
200
100
0
0
-100

23.9
24
24.1
24.2
24.3
24.4
24.5
24.6
24.7
24.8
24.9
25
25.5
26
26.5
27
28
29
30
31
32

11.27
11.31
11.32
11.34
11.35
11.38
11.4
11.41
11.43
11.46
11.47
11.48
11.54
11.58
11.65
11.69
11.75
11.81
11.86
11.91
11.95

664.93
667.29
667.88
669.06
669.65
671.42
672.6
673.19
674.37
676.14
676.73
677.32
680.86
683.22
687.35
689.71
693.25
696.79
699.74
702.69
705.05

1.18
2.36
0.59
1.18
0.59
1.77
1.18
0.59
1.18
1.77
0.59
0.59
3.54
2.36
4.13
2.36
3.54
3.54
2.95
2.95
2.36

0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.5
0.5
0.5
0.5
1
1
1
1
1

11.8
23.6
5.9
11.8
5.9
17.7
11.8
5.9
11.8
17.7
5.9
5.9
7.08
4.72
8.26
4.72
3.54
3.54
2.95
2.95
2.36

118
-177
59
-59
118
-59
-59
59
59
-118
1.34648E-11
11.8
-4.72
7.08
-7.08
-2.36
0
-0.59
1.13687E-13
-0.59
-2.36

kurva utama ch3cooh naoh

10

15

20

25

30

kurva derivat 1

d E/d V

10

15

20

25

30

35

derivat 2
4000
3000
2000
1000
0
-1000
-2000
-3000

10

15

20

25

30

-3000
-4000

Ka=antilog a
ka= 8.3984 X 10-5
% kesalahan = 2415,72 %

35

d (d E/d V)/d V
35

Standarisasi naoh

oksalat yang ditimbang 0,63 g

Normalitas Oksalat
0.1000
0.1000

volume
konsentrasi
ulangan
awal
akhir
terpakai
volume titrat
1
0
10.1
10.1
0.0990
10
2
10.1
20.2
10.1
0.0990
10
X
0.0990
0.0990
titrasi naoh ch3cooh-hcl
indikator
JM
pp
pp-jm
JM
pp
pp-jm

volume

ulangan

awal
1

27.4
0

40
21.4

0
0

12.5
21.3

catatan:
volume pp-jm = vol ch3cooh
vol jm= vol hcl
volume TE potensio oksalat
utama
turunan 1 turunan 2
10.5
10.5
10.5
volume te

akhir

volume TE kondukto oksalat

10.3
12.1
21.6

alat yang ditimbang 0,63 g

volume

konsentrasi
terpakai
12.6
21.4
8.8
12.5
21.3
8.8

0.1248 hcl
0.0871 ch3cooh
0.1238 hcl
0.0871 ch3cooh

X HCl
X Ch3cooh
0.124257
0.0871

titrasi hcl-ch3cooh
NaOH (mL)
0
1
2
3
4
5
6
7
8
9
9.5
10
10.5
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4
12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5
13.6
13.7
13.8
13.9
14

suhu : 29.7 C
Konduktan (S)
3190
3100
2840
2780
2540
2270
2120
1960
1714
1574
1357
1244
1151
1058
1018
1000
987
982
978
968
964
962
958
954
954
952
952
954
954
956
958
960
962
964
966
970
972
976
980
985
987
989
992
993

V terkoreksi
1
1.01
1.02
1.03
1.04
1.05
1.06
1.07
1.08
1.09
1.095
1.1
1.105
1.11
1.111
1.112
1.113
1.114
1.115
1.116
1.117
1.118
1.119
1.12
1.121
1.122
1.123
1.124
1.125
1.126
1.127
1.128
1.129
1.13
1.131
1.132
1.133
1.134
1.135
1.136
1.137
1.138
1.139
1.14

L (mho)
0.00319
0.0031
0.00284
0.00278
0.00254
0.00227
0.00212
0.00196
0.001714
0.001574
0.001357
0.001244
0.001151
0.001058
0.001018
0.001
0.000987
0.000982
0.000978
0.000968
0.000964
0.000962
0.000958
0.000954
0.000954
0.000952
0.000952
0.000954
0.000954
0.000956
0.000958
0.00096
0.000962
0.000964
0.000966
0.00097
0.000972
0.000976
0.00098
0.000985
0.000987
0.000989
0.000992
0.000993

L terkoreksi
0.0032
0.0031
0.0029
0.0029
0.0026
0.0024
0.0022
0.0021
0.0019
0.0017
0.0015
0.0014
0.0013
0.0012
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011
0.0011

14.1
14.2
14.3
14.4
14.5
14.6
14.7
14.8
14.9
15
15.5
16
16.5
17
18
19
19.5
20
20.5
21
21.1
21.2
21.3
21.4
21.5
21.6
21.7
21.8
21.9
22
22.1
22.2
22.3
22.4
22.5
22.6
22.7
22.8
22.9
23
23.1
23.2
23.3
23.4
23.5
23.6
23.7

999
1001
1007
1009
1011
1014
1022
1029
1032
1034
1038
1059
1064
1086
1125
1162
1187
1192
1214
1227
1251
1253
1259
1266
1278
1288
1321
1323
1326
1333
1341
1345
1356
1361
1365
1378
1385
1406
1414
1424
1442
1441
1455
1462
1483
1492
1513

1.141
1.142
1.143
1.144
1.145
1.146
1.147
1.148
1.149
1.15
1.155
1.16
1.165
1.17
1.18
1.19
1.195
1.2
1.205
1.21
1.211
1.212
1.213
1.214
1.215
1.216
1.217
1.218
1.219
1.22
1.221
1.222
1.223
1.224
1.225
1.226
1.227
1.228
1.229
1.23
1.231
1.232
1.233
1.234
1.235
1.236
1.237

0.000999
0.001001
0.001007
0.001009
0.001011
0.001014
0.001022
0.001029
0.001032
0.001034
0.001038
0.001059
0.001064
0.001086
0.001125
0.001162
0.001187
0.001192
0.001214
0.001227
0.001251
0.001253
0.001259
0.001266
0.001278
0.001288
0.001321
0.001323
0.001326
0.001333
0.001341
0.001345
0.001356
0.001361
0.001365
0.001378
0.001385
0.001406
0.001414
0.001424
0.001442
0.001441
0.001455
0.001462
0.001483
0.001492
0.001513

0.0011
0.0011
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0012
0.0013
0.0013
0.0014
0.0014
0.0014
0.0015
0.0015
0.0015
0.0015
0.0015
0.0015
0.0016
0.0016
0.0016
0.0016
0.0016
0.0016
0.0016
0.0016
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0018
0.0019

23.8
23.9
24
24.1
24.2
24.3
24.4
24.5
24.6
24.7
24.8
24.9
25
25.5
26
26.5
27
28
29
30
31
32

1523
1529
1541
1549
1557
1578
1585
1599
1614
1618
1627
1629
1638
1641
1672
1789
1824
1851
1894
2000
2170
2240

1.238
1.239
1.24
1.241
1.242
1.243
1.244
1.245
1.246
1.247
1.248
1.249
1.25
1.255
1.26
1.265
1.27
1.28
1.29
1.3
1.31
1.32

0.001523
0.001529
0.001541
0.001549
0.001557
0.001578
0.001585
0.001599
0.001614
0.001618
0.001627
0.001629
0.001638
0.001641
0.001672
0.001789
0.001824
0.001851
0.001894
0.002
0.00217
0.00224

0.0019
0.0019
0.0019
0.0019
0.0019
0.0020
0.0020
0.0020
0.0020
0.0020
0.0020
0.0020
0.0020
0.0021
0.0021
0.0023
0.0023
0.0024
0.0024
0.0026
0.0028
0.0030

kurva titrasi konduktometri hcl

0.0035
0.003
0.0025
0.002
0.0015
0.001
0.0005
0
0

10

15

20
Series1

25

30

35

titrasi oksalat
0
1
2
3
4
5
6
6.5
7
7.5
8
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5

suhu 26,1
1117
1111
931
720
573
468
449
456
481
494
534
560
571
575
591
594
597
599
609
618
620
521
509
640
656
660
671
681
690
697
702
705
715
720
730
737
752
763
779
790
801
812
822
838
859
870

1
1.01
1.02
1.03
1.04
1.05
1.046
1.065
1.07
1.075
1.08
1.081
1.082
1.083
1.084
1.085
1.086
1.087
1.088
1.089
1.09
1.091
1.092
1.093
1.094
1.095
1.096
1.097
1.098
1.099
1.1
1.101
1.102
1.103
1.104
1.105
1.106
1.107
1.108
1.109
1.11
1.111
1.112
1.113
1.114
1.115

0.001117
0.001111
0.000931
0.00072
0.000573
0.000468
0.000449
0.000456
0.000481
0.000494
0.000534
0.00056
0.000571
0.000575
0.000591
0.000594
0.000597
0.000599
0.000609
0.000618
0.00062
0.000521
0.000509
0.00064
0.000656
0.00066
0.000671
0.000681
0.00069
0.000697
0.000702
0.000705
0.000715
0.00072
0.00073
0.000737
0.000752
0.000763
0.000779
0.00079
0.000801
0.000812
0.000822
0.000838
0.000859
0.00087

0.0011
0.0011
0.0009
0.0007
0.0006
0.0005
0.0005
0.0005
0.0005
0.0005
0.0006
0.0006
0.0006
0.0006
0.0006
0.0006
0.0006
0.0007
0.0007
0.0007
0.0007
0.0006
0.0006
0.0007
0.0007
0.0007
0.0007
0.0007
0.0008
0.0008
0.0008
0.0008
0.0008
0.0008
0.0008
0.0008
0.0008
0.0008
0.0009
0.0009
0.0009
0.0009
0.0009
0.0009
0.0010
0.0010

0.0025

0.002

0.0015

0.001

0.0005

0
0

11.6
11.7
11.8
11.9
12
12.5
13
13.5
14
15
16
17
18
19
20

876
881
889
899
906
967
987
1024
1056
1200
1300
1347
1572
1651
1784

1.116
1.117
1.118
1.119
1.12
1.125
1.13
1.135
1.14
1.15
1.16
1.17
1.18
1.19
1.2

0.000876
0.000881
0.000889
0.000899
0.000906
0.000967
0.000987
0.001024
0.001056
0.0012
0.0013
0.001347
0.001572
0.001651
0.001784

0.0010
0.0010
0.0010
0.0010
0.0010
0.0011
0.0011
0.0012
0.0012
0.0014
0.0015
0.0016
0.0019
0.0020
0.0021

kurva titrasi konduktometri oksalat

Series1

10

15

20

25

0.0035

0.003

0.0025

0.002

0.0015

0.001

0.0005

0
0

10

kurva titrasi konduktometri hcl

15

Series1

20

25

30

35