I HC QUC GIA H NI THI TUYN SINH SAU I HC NM 2012 T I MN THI: C S L THUYT HA HC V CU TO CHT Cu 1: Cho cn bng: N2O4(k) 2NO2(k) Kp,303K

K = 0,124

( Khng mu) ( mu nu ) 1. Cho 0,125 mol N2O4 vo bnh chn khng v gi nhit 303K. Hi dung tch bnh phn ng phi bng bao nhiu (lit) khi cn bng c 80% lng N2O4 ban u chuyn thnh NO2.? 2. Xt du ca i lng Go, So, Ho ca phn ng thun nhit ni trn. 3. Nu tng nhit v gi th tch ca bnh phn ng th mu sc v p sut trong bnh thay i th no? V sao? Cu 2: Bit 25oC, TAgCH3COO= 2.10-3 v pKa= 4,75. 1. Tnh tan ca bc axetat (mol/l) trong n c v pH ca dung d!ch bo ha bc axetat, coi Ag+ thy phn khng dng k. 2. Ng"i ta cho 0, mol AgCH3COO vo 1 lit n c. Cn phi a pH ca dung d!ch n gi tr! no ha tan ht lng mu#i trn. Cu 3: Xt phn ng (1) 25oC: H3AsO4 + 3I- + 2H+ H3AsO3 + I3- + H2O (1)

1. Xc !nh chi$u ca phn ng i$u kin tiu chu%n. 2. Xc !nh chi$u ca phn ng pH = 2, n&ng ca cc cht vn bng 1M. 3. Nu ch' thay i pH ca dung d!ch, xc !nh pH ca dung d!ch m ti phn ng (1) i chi$u. 4. Tnh hng s# cn bng ca phn ng (1). Cho: EoH3AsO4/H3AsO3 = 0,559V, EoI3-/I- = 0,536V Cu 4: 1. D(a vo s( xen ph ca cc obital nguyn t), hy m t cu to ca phn t) CO v N2. 2. Cc kh CO v N2 c tnh cht vt l t*ng #i gi#ng nhau $u c nng lng lin kt l n, nhng nng lng lien kt ca CO (1070 kJ/mol) l n h*n N2 (946 kJ/mol). Hy gii thch.

Cu 5: 1. D(a vo quy tc Huckel v$ tnh th*m, hy cho bit cc h e+ vng sau y, th h no b$n, ti sao? C3H3, C3H3+, C4H4, C5H5, C5H5-, C6H6, C7H7, C7H7+, C8H8, C8H82-. 2. p d,ng m hnh hp th 1 chi$u, hy tnh nng lng ra kJ/mol ca 6 e+ khng !nh c trong phn t) hexatrien v i chi$u di L = 8,4 Angtron, bit 6e+ chim 3 mc nng lng thp nht. Tnh s# song (cm-1) ca bc x hp th, ng v i b c chuyn d!ch e t- t- mc nng lng b! chim cao nht n mc nng lng cha b! chim thp nht. Cu 6: Bc kim loi t&n ti th rn, tinh th lp ph*ng tm din. 1. Hy v. mng c* s. 2. C bao nhiu nguyn t) mng c* s. 3. Kh#i lng ring ca Ag l 10,5 gam/cm3. Hy xc !nh chi$u di ca mng c* s theo Angtron. 4. Tnh bn knh nguyn t) Ag trong tinh th. Cho: ZC = 6, ZO = 8, h = 6,625.10-34J.s; me = 9,1.10-31 kg; NA = 6,02.1023; c = 3.108 m/s; MAg = 108 ------H/T-----(Cn b coi thi khng gii thch g thm)