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Oxidarea poate si se producd I temperatura sc&zuts ca, de exemply, in eazul biofiltri, sau la temperatura ridicatd, ca la oxidare termic& si cataitiet, obiectul acestui capitol nto oxidare completd, I“temperaturs ridicats, are loc © coaversie a poluantilor in CO}, H0 si alte produse de oxidare; poluantul reprezinta combustibitul si oxigent! din aerul poluat reprezinta comburantul {n functie de conjinutul de poluant din aerul de tratat si puterea lui calorica, {in genera, este nevoie si se fac’ apel fie la un combustibil suplimentar, fie la aer de dilute . Pentru a objine o eficacitate satisficdtoare a tratamentului trebuie si se {nceap& cu analiza problemelor pe care le ridica un astfel de tratament si anume: — caracterizarea poluanflor de tratat (compozitia fizieo-chimics, temperatura, presiunea); ~stabilirea produilor de combustie, in ipoteza cA ate loc 0 combustie completd, i a influentei diferitilor parametri asupra deplasirii echilibrelor existente; ~calculul de bitan temic, luind in considerare aportul calorie al peluantilor, = abordarea aeraulicd a sistemului (timp de contact, turbulent). Primele doud etape conduc la caracterizarea compozitie efluentului, pentru @ stabili daca este nevoie sau nu de un post tratament, si ultimele doud stabilese necesarul de un adaos ce combustibil si de o eventuala recuperare de energie. In functie de raspunsul la aceste patra probleme se pot stabili dous solu: oxidare termicd sau oxidare catalticd, prin aplicarea lor practic& sub forma recuperativa sa sub forma regenerativa, dupa modul cum se prevede recuperarea cAlduri acd se consideri ci tratamentul prin oxidare (incinerare sau combustie) este ‘numai o obligatie ecologica,rentabilitatea procesului poate fi negativa. Procesul se poate rentabliza daca intalaile de tratare sunt urmate de un sistem de recuperare 50 Metode feico-chimice de tratare @poluantilor industria atmesferici Incinerarea_policlorofenolilor si a policlorobifenililor (PCB) are loc la temperatura de dstrugere a dioxinelor, deoarece acestea rezulta in urma procesului de ardere, in anumite conditi (temperatur, presiune, cantitae de aer et.) reactia de ‘oxidare poate fi incompleti, cénd au loc echilibre chimice, in care produsii de reactie coexists cu reactan{ii (CO/CO;, ClyHCl, NOJN,). Sunt prezentate in continuare cAteva exemple de echilibre intélnite in procesele de combustie: CO+2O==—=2CO, AN <0 0 CO+HO==200, +H, aH<0 @ ~ 0 crestere de temperaturi deplaseaz& echilibrul (1) spre stinga, dar un exces

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