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    Mfcdpia - 2 127 237

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    nastase_gabriela_2
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    Copyright:

    Attribution Non-Commercial (BY-NC)
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    of 110
    Adrorbie wr 124, Mocho P., Le Cloies ., Regeneration ty induction heatiog of granular activated carbon losted ‘with volatile organique compounds, Water Supply, 14 (1994), 283. 125. Rodriguez-Reinoso F, Pastor A.C., Marsh HL, Martinez M.A., Peparator of activated carbon ‘slots from viscous rayon. Par I: physical activation processes, Carbon, 38 (2000), 379, 126. Bianchi D, Joly TP, Logeiel de itement des données acquises par spectometre de masse pour les dudes quanttatves des phénoménes transitires en catalyse hétrogéne, Bulletin dela Socitéchinigue de France, 4 (198), 68 127, Bianchi D, ‘ly J.P, Systeme daequistion des données d'un speciroméve de masse pour ls tudes des phéooménes transtoires en phase guzeuse, Bulletin de ta société chimique de France, (1985), 664. 128. Caroll W. F, Berger T. C, Borel. E, Lewis J. W, Characteisation of emissions of dioxins ‘and furans from ethylene dichloride (EDC), vinyl chloride monomer (CM), aad pelyvinyl ‘chloride (PVC) facilities inthe United States. Pat 3, Oxychlorinaton cays, rgavonslogen Compa. 4 (1999), 133. 129, Evans M.'J. 3, Halli E., MacDonald J, A. F., The production of chemicaly-activated carbon, Carbon, 3: (1999), 26. 130. Subrenat A, Baleo IN, Le Clore P, Blane PF, Electrical behavior of ativated cerbor cloth heated by the joule effet: desorption application, Carbon 39 (2001), 707, 131, Debasish Das,Wivekanand Gaur, Nishith Verma, Removal of volatile oganie compound by activated carbon fiber, Carbon, 42 (2004), 2949. 132, Ania C.0., Menéndez J.A. Para 1B, Pis JJ, Microwave-induced regeneration of activated ‘arbons plluted with phenol, A comparison with conventional thermal egenerting, Carbon 422004), 1383, ~ 153. Gullet KB. Natshe F.D,, Bice’ RK, Thennal teatement of 1,23 4-etrachlorodibenzo-p- sioxin by veaction with Cacbased sorbent la 23-300°C, Brviron Set. Techrol, 3) (1997), 1855, 134. Popescu Maia, Popescu Miron, Ecologie aplicata. Matrix Rom Bucuregi, (2000), 310 p. 1BS. Black MS, Worthan AW., Emissions fom office equipment, Provedings of the 3° International Conference on Indoor Air Quality and Climate held in Edirburgh, Scola, 8-13 angus, 1999, 136. Ao CH, Lee S.C, Indoor air purification by photocatalyst TIO; immobilized on an activated ‘carbon filler installed in an ai leaner, Chemical Engineering Science, 60(2005),103. 137, Zhisht Guo, Review of indoor emission source models. Part I. Oveniew., Environmental olution, 120 (2002), $33, 138, Zhishi Guo, Review of indoor emission source models, Part 2, Parameter estimation, Environmental Potution, 120 (2002), 581 139. Kawasaki N, Kinoshita H,, Que T,, Nakamure T., Tanada $., Study on adsorption kinetic of tomate droearbons onto setivated carbon in gaseous flow method. Jaurnal of Colloid ant Interface Science, 295 2004), 40, 140. Hernindez M. A, Velasco J. A. Asomoza M., Solis S, Rojas F., Lara V. H., Adsorption of Tenzene, toluene, and p-xyens on microporous SiO, Ind. ng. Chem. Ret, 43 (2001), 1779. 5.OXIDARE $I REDUCERE TERMICA SUSAU CATALITICA 5.1. OXIDAREA TERMICA SU/SAU CATALITICA (INCINERARE, COMBUSTIE) Oxidarea termica si/sau cataliticd sti la baza depoluarii poluantilor tip COV si mirosurilor, far reducerea temic’ s/sau catalitica a poluantilor tip NO,. Oxidarea poate si se producd I temperatura sc&zuts ca, de exemply, in eazul biofiltri, sau la temperatura ridicatd, ca la oxidare termic& si cataitiet, obiectul acestui capitol nto oxidare completd, I“temperaturs ridicats, are loc © coaversie a poluantilor in CO}, H0 si alte produse de oxidare; poluantul reprezinta combustibitul si oxigent! din aerul poluat reprezinta comburantul {n functie de conjinutul de poluant din aerul de tratat si puterea lui calorica, {in genera, este nevoie si se fac’ apel fie la un combustibil suplimentar, fie la aer de dilute . Pentru a objine o eficacitate satisficdtoare a tratamentului trebuie si se {nceap& cu analiza problemelor pe care le ridica un astfel de tratament si anume: — caracterizarea poluanflor de tratat (compozitia fizieo-chimics, temperatura, presiunea); ~stabilirea produilor de combustie, in ipoteza cA ate loc 0 combustie completd, i a influentei diferitilor parametri asupra deplasirii echilibrelor existente; ~calculul de bitan temic, luind in considerare aportul calorie al peluantilor, = abordarea aeraulicd a sistemului (timp de contact, turbulent). Primele doud etape conduc la caracterizarea compozitie efluentului, pentru @ stabili daca este nevoie sau nu de un post tratament, si ultimele doud stabilese necesarul de un adaos ce combustibil si de o eventuala recuperare de energie. In functie de raspunsul la aceste patra probleme se pot stabili dous solu: oxidare termicd sau oxidare catalticd, prin aplicarea lor practic& sub forma recuperativa sa sub forma regenerativa, dupa modul cum se prevede recuperarea cAlduri acd se consideri ci tratamentul prin oxidare (incinerare sau combustie) este ‘numai o obligatie ecologica,rentabilitatea procesului poate fi negativa. Procesul se poate rentabliza daca intalaile de tratare sunt urmate de un sistem de recuperare 50 Metode feico-chimice de tratare @poluantilor industria atmesferici Incinerarea_policlorofenolilor si a policlorobifenililor (PCB) are loc la temperatura de dstrugere a dioxinelor, deoarece acestea rezulta in urma procesului de ardere, in anumite conditi (temperatur, presiune, cantitae de aer et.) reactia de ‘oxidare poate fi incompleti, cénd au loc echilibre chimice, in care produsii de reactie coexists cu reactan{ii (CO/CO;, ClyHCl, NOJN,). Sunt prezentate in continuare cAteva exemple de echilibre intélnite in procesele de combustie: CO+2O==—=2CO, AN <0 0 CO+HO==200, +H, aH<0 @ ~ 0 crestere de temperaturi deplaseaz& echilibrul (1) spre stinga, dar un exces

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