General instructions 1. All question are compulsory 2.

Question number 01 to 05 are very short answer questions and carries 1 mark each 3. Question number 06 to 10 are MCQs having one correct answer and carries 1 mark each 4. Question number 11 to 13 are long answer type and carries 5 marks each 5. NO NEGATIVE MARKING.

01Q. 02Q. 03Q. 04Q. 05Q.

Define expanded octet rule Draw Lewis dot structure of HNO3 Formal charge on each Oxygen atom in O3 Shape of is?

Arrange the following molecules in decreasing order of bond angle H2O, H2S, H2Se, H2Te

06Q.

Molecule having net dipole moment a) b) SnCl2 ClF3 c) d) PF3Cl2 All

07Q.

Which of the following is (are) drawback(s) of octet theory a) b) c) d) This theory doesnt account for the shape of the molecule Doesnt explain the stability of the molecule Chemical inertness is completely based on noble gas configuration All

08Q.

Incorrect match with a given parameter a) b) c) d) [Bond Energy] [Bond length] [Electronegativity] Bond Order of N2 and CO+ is same

09Q.

Stable resonating structure of [ONCN] is a)

10Q. a) b) 11Q.

exist in solid state as

c) d)

. Hybridization of each ion is?

Draw orbital diagram of the following molecule

H C Cl C C C H F

12Q.

Draw molecular orbital diagram for homodiatomic molecules having electrons greater than 14. Calculate bond order of the following molecules

13Q.

Explain Hydrogen bonding (including inter and intra). Why water has maximum density at 4C? Arrange the following molecules in the decreasing order of boiling point

OH

OH

O C H

C H O