CNG HA X HI CH NGHA VIT NAM

QCVN 12 : 2008/BTNMT

QUY CHUN K THUT QUC GIA V NC THI CNG NGHIP GIY V BT GIY
National technical regulation on the effluent of pulp and paper mills

H NI 2008

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Li ni u QCVN 09 : 2008/BTNMT do Ban son tho quy chun k thut quc gia v cht lng nc bin son, Tng cc Mi trng v V Php ch trnh duyt v c ban hnh theo Quyt nh s /2008/Q-BTNMT ngy thng nm 2008 ca B trng B Ti nguyn v Mi trng.

QCVN 12 : 2008/btnmt

QUY CHUN K THUT QUC GIA V NC THI CNG NGHIP GIY V BT GIY National technical regulation on the effluent of pulp and paper mills

1. QUY NH CHUNG 1.1. Phm vi iu chnh Quy chun ny qui nh gi tr ti a cho php ca cc thng s nhim trong nc thi cng nghip giy v bt giy khi thi ra mi trng. 1.2. i tng p dng Quy chun ny p dng i vi t chc, c nhn li n quan n hot ng thi nc thi cng nghip giy v bt giy ra mi trng. 1.3. Gii thch thut ng Trong Quy chu n ny, cc thut ng di y c hiu nh sau: 1.3.1. Nc thi cng nghip giy v bt giy l dung dch thi t nh my, c s s dng cc quy tr nh cng ngh sn xut ra cc sn phm giy v bt giy. 1.3.2. H s lu lng/dung tch ngun n c tip nhn nc thi Kq l h s tnh n kh nng pha long ca ngun nc tip nhn n c thi, tng ng vi lu lng dng chy ca sng, sui, knh, mng, khe, rch v dung tch c a cc h, ao, m n c. 1.3.3. H s lu lng ngun thi K f l h s tnh n tng lng thi ca c s sn xut giy v bt giy, tng ng vi lu lng nc thi khi thi vo cc ngun nc tip nhn n c thi. 1.3.4. Ngun nc tip nhn n c thi l ngun nc mt hoc vng nc bin ven b , c mc ch s dng xc nh, ni m nc thi cng nghip giy v bt giy thi vo. 1.4. Tiu chun vin dn:

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- TCVN 7732 : 2007 Cht lng nc Tiu chun nc thi cng nghip sn xut giy v bt giy. - TCVN 5945 : 2005 - Cht lng nc - Nc thi cng nghip - Tiu chun thi. 2. QUY NH K THUT

2.1. Gi tr ti a cho php cc thng s nhim trong n c thi cng nghip giy v bt giy Gi tr ti a cho php ca cc thng s nhim trong n c thi cng nghip giy v bt giy khi thi vo ngun nc tip nhn n c thi khng vt qu gi tr C max c tnh ton nh sau: C max = C x Kq x K f Trong : C max l nng ti a cho php ca thng s nhim trong n c thi cng nghip giy v bt giy khi thi vo ngun nc tip nhn n c thi, tnh bng miligam tr n lt nc thi (mg/l); C l gi tr nng ca thng s nhim quy nh ti mc 2.2. Kq l h s lu lng/dung tch ngun nc tip nhn nc thi quy nh ti mc 2.3. K f l h s lu lng ngun thi quy nh ti mc 2.4. Khng p dng cng thc tnh nng ti a cho php trong n c thi cho thng s pH. 2.2. Gi tr C ca cc thng s nhim l m c s tnh ton gi tr ti a cho php Gi tr C ca cc thng s nhim l m c s tnh ton gi t r ti a cho php C max trong nc thi cng nghip giy v bt giy khi thi vo cc ngun nc tip nhn nc thi c quy nh ti Bng 1.
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Bng 1: Gi tr cc thng s nhim l m c s tnh ton gi tr ti a cho php Gi tr C B C s ch sn xut giy (B1) 1 2 3 COD pH BOD 5 20 O C C s mi C s ang hot ng mg/l mg/l 6-9 30 50 5,5 - 9 50 150 C s c sn xut bt giy (B2) 5,5 - 9 100 200

STT

Thng s

n v

mg/l

80

200

300

4 5

Tng cht rn l lng (TSS) C s mi mu C s ang hot ng

mg/l Pt-Co

50 20

100 50

100 100

Pt-Co

50

100

150

Halogen hu c d b hp th (AOX)

mg/l

7,5

15

15

Trong : - Ct A quy nh gi tr C ca cc thng s nhim lm c s tnh ton gi tr ti a cho php trong nc thi cng nghip giy v bt giy khi thi vo cc ngun nc c dng cho mc ch cp n c sinh hot (c cht lng nc tng ng ct A1 v A2 ca Quy chun k thut quc gia v cht lng nc mt).
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- Ct B quy nh gi tr C ca cc thng s lm c s tnh ton gi tr ti a cho php trong nc thi ca c s ch sn xut giy (khng sn xut bt giy) hoc c s sn xut bt giy, li n hp sn xut giy v bt giy khi thi vo cc ngun nc khng dng cho m c ch cp n c sinh hot (c cht lng nc tng ng ct B1 v B2 ca Quy chun k thut quc gia v cht l ng nc mt hoc vng nc bin ven b) . - i vi thng s COD v mu, cc c s ang hot ng trc ngy Quy chun ny c hiu lc thi hnh c p dng gi tr cao h n n ht ngy 31/12/2014. K t ngy 01/01/2015, p d ng gi tr quy nh cho c s mi i vi tt c cc c s sn xut giy v bt giy. Ngoi 06 thng s quy nh ti Bng 1, tu theo y u cu v mc ch kim sot nhim, gi tr C ca cc thng s n him khc p dng theo quy nh ti ct A hoc ct B ca Bng 1 Ti u chun quc gia TCVN 5945:2005 - Cht lng nc Nc thi cng nghip Tiu chun thi. 2.3. Gi tr h s lu lng/dung tch ngun n c tip nhn nc thi Kq 2.3.1. Gi tr h s Kq i vi ngun n c tip nhn n c thi cng nghip giy v bt giy l sng, sui, knh, mng, khe, r ch c quy nh ti Bng 2 d i y. Bng 2: Gi tr h s Kq ng vi l u lng dng chy ca sng, sui, knh, mng, khe, rch tip nhn nc thi Lu lng dng chy ca ngun nc tip nhn nc thi (Q) n v tnh: mt khi/giy (m 3 /s) Q 50 50 < Q 200 200 < Q 1000 Q > 1000
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Gi tr h s Kq

0,9 1 1,1 1,2

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Q c tnh theo gi tr trung b nh lu lng dng chy ca sng, sui, knh, mng, khe, r ch tip nhn ngun nc thi 03 thng kh kit nht trong 03 nm li n tip (s liu ca c quan Kh tng Thu vn quc gia). Trng hp cc sng, sui, knh, mng, khe, r ch khng c s liu v lu lng dng chy th p dng gi tr Kq = 0,9 hoc S Ti nguyn v Mi trng ch nh n v c t cch php nhn o lu lng trung bnh 03 thng kh kit nht trong n m xc nh gi tr h s Kq. 2.3.2. Gi tr h s Kq i vi ngun tip nhn n c thi l h, ao, m c quy nh ti B ng 3 di y. Bng 3: Gi tr h s Kq ng vi dung tch h, ao, m tip nhn nc thi Dung tch ngun nc tip nhn nc thi (V) n v tnh: mt khi ( m 3 ) V 10 x 10 6 10 x 10 6 < V 100 x 10 6 V > 100 x 10 6 Gi tr h s Kq

0,6 0,8 1,0

V c tnh theo gi tr trung b nh dung tch h, ao, m tip nhn n c thi 03 thng kh kit nht trong 03 nm li n tip (s liu ca c quan Kh tng Thu vn quc gia). Trng hp h, ao, m khng c s liu v dung tch th p dng gi tr h s Kq = 0,6 hoc S Ti nguyn v Mi trng ch nh n v c t cch php nhn o dung tch trung bnh 03 thng kh ki t nht trong nm xc nh gi tr h s Kq. 2.3.3. i vi ngun tip nhn n c thi l vng nc bin ven b th gi tr h s Kq = 1,3. i vi ngun tip nhn n c thi l vng nc bin ven b dng cho mc ch bo v thu sinh, th thao v gii tr di nc th gi tr h s Kq = 1.
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2.3. Gi tr h s lu lng ngun thi K f Gi tr h s lu lng ngun thi Kf c quy nh ti Bng 4 di y. Bng 4: Gi tr h s K f ng vi lu lng nc thi. Lu lng ngun nc thi (F) n v tnh: mt khi /ng y m (m 3 /24 h) F 50 50 < F 500 500 < F 5000 F > 5000 Gi tr h s K f

1,2 1,1 1,0 0,9

3. PHNG PHP XC NH Phng php xc nh gi tr cc thng s nhim trong n c thi cng nghip giy v bt giy thc hin theo hng dn ca cc ti u chun quc gia hoc tiu chun phn tch t ng ng ca cc t chc quc t : - TCVN 6492 : 1999 Cht lng nc Xc nh pH; - TCVN 6001 : 1995 (ISO 5815 : 1989) Ch t lng nc - Xc nh nhu cu oxy sinh ha sau 5 ng y (BOD 5). Phng php c y v pha long; - TCVN 6491 : 1999 (ISO 6060 : 1989) Ch t lng nc - Xc nh nhu cu oxy ha hc (COD); - TCVN 6625 : 2000 (ISO 11923 : 1997) Ch t lng nc - Xc nh cht rn l lng bng cch lc qua ci lc si thy tinh; - TCVN 4558 : 1988 Cht lng nc Phng php xc nh mu v mi; - TCVN 6493 : 1999 (ISO 9562:1989) - Cht lng nc Xc nh cc halogen hu c d b hp th;

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Khi cn kim sot cc thng s khc, ph ng php xc nh theo cc tiu chun quc gia hin h nh hoc phng php phn tch t ng ng ca cc t chc quc t. 4. T CHC THC HIN

T chc, c nhn li n quan n hot ng ca c s sn xut giy v bt giy, d n u t c s sn xut giy v bt giy tun th quy nh ti Quy chun ny. C quan qun l nh nc v mi trng c trch nhim h ng dn, kim tra, gim st vic thc hin Quy chun n y. Trng hp cc ti u chun quc gia vin dn trong Quy chun n y sa i, b sung hoc thay th th p dng theo vn bn mi.