Este trong cc thi Cao ng i hc

Gv: Hunh Bo Lun D: 0906500083

ESTE TRONG CC THI CAO NG I HC

Cu 1: (CA-2007) un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng
t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l
D. 62,5%.
A. 50%.
B. 75%.
C. 55%.
Cu 2: (CA-2007)Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch
gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH
va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X
l
A. isopropyl axetat. B. etyl axetat.
C. metyl propionat.
D. etyl propionat.
Cu 3: (CA-2007)Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung
dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3
thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l
A. CH3COOCH=CH2.
B. HCOOCH=CH2.
C. HCOOCH3.
D. CH3COOCH=CH-CH3.
Cu 4: (CA-2008)Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml
dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc
cu to ca X l
A. CH2=CH-COO-CH2-CH3.
B. CH3 -COO-CH=CH-CH3.
D. CH3-CH2-COO-CH=CH2.
C. CH2=CH-CH2-COO-CH3.
Cu 5: (CA-2008)X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5
CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l:
C. 300 ml.
D. 150 ml.
A. 400 ml.
B. 200 ml.

Cu 6: (CA-2008)un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu
sut phn ng este ho bng 50%). Khi lng este to thnh l:
A. 8,8 gam.
B. 6,0 gam.
C. 5,2 gam.
D. 4,4 gam.
Cu 7: (CA-2009)Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung
dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca
X l
A. CH2=CHCH2COOCH3.
B. CH3COOCH=CHCH3.
C. C2H5COOCH=CH2.
D. CH2=CHCOOC2H5.
Cu 8: (CA-2010)Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip
nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c
5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l
B. HCOOC2H5 v 9,5
A. CH3COOCH3 v 6,7
C. HCOOCH3 v 6,7
D. (HCOO)2C2H4 v 6,6
Cu 9: (CA-2010)Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H2SO4 c), un
nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l
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Este trong cc thi Cao ng i hc

A. 62,50%

B. 50,00%

Gv: Hunh Bo Lun D: 0906500083

C. 40,00%

D. 31,25%

Cu 10: (HA-2007)Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai
loi axit bo. Hai loi axit bo l
A. C15H31COOH v C17H35COOH.
B. C17H33COOH v C15H31COOH.
C. C17H31COOH v C17H33COOH.
D. C17H33COOH v C17H35COOH.
Cu 11: (HA-2007)X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng
xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l
A. 8,56 gam.
B. 3,28 gam.
C. 10,4 gam.
D. 8,2 gam.
Cu 12: (HA-2007)Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn
hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut
ca cc phn ng este ho u bng 80%). Gi tr ca m l
B. 6,48.
C. 8,10.
D. 16,20.
A. 10,12.
Cu 13: (HA-2007) Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este
ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol
CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
B. 2,925.
C. 2,412.
D. 0,456.
A. 0,342.
Cu 14: (HB-2008) Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc
dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng
thc cu to thu gn ca X l
A. CH3OOC(CH2)2COOC2H5.
B. CH3COO(CH2)2COOC2H5.
C. CH3COO(CH2)2OOCC2H5.
D. CH3OOCCH2COOC3H7.
Cu 15: (HB-2008) X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn
dung dch sau phn ng thu c khi lng x phng l
A. 17,80 gam.
B. 18,24 gam.
C. 16,68 gam.
D. 18,38 gam.
Cu 16: (HB-2008)Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100
ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton
lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi
lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5.
B. C2H5COOH v C2H5COOCH3.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
Cu 17: (HB-2008)Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc
(c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung
dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 27,75.
B. 24,25.
C. 26,25.
D. 29,75.
Cu 18: (HA-2008)Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn
t cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
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Este trong cc thi Cao ng i hc

Gv: Hunh Bo Lun D: 0906500083

A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
B. Cht Y tan v hn trong nc.
C. Cht X thuc loi este no, n chc.
D. un Z vi dung dch H2SO4 c 170oC thu c anken.
Cu 19 : (HA-2009)X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3
bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400C,
sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l
A. 18,00.
B. 8,10.
C. 16,20.
D. 4,05.
Cu 20: (HA-2009) X phng ha hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c
2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc
ca hai este l
B. C2H5COOCH3 v C2H5COOC2H5.
A. HCOOCH3 v HCOOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. CH3COOCH3 v CH3COOC2H5.
Cu 21: (HA-2009)Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung
dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc
ca X l
B. HCOOC(CH3)=CHCH3.
A. CH3COOC(CH3)=CH2.
C. HCOOCH2CH=CHCH3
D. HCOOCH=CHCH2CH3.
Cu 22: (HB-2010)Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai
ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
Cu 23: (HB-2010) Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn
40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2
(ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005.
Cu 24: (HA-2010)t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn
3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu
kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y
thu c 12,88 gam cht rn khan. Gi tr ca m l
A. 10,56.
B. 7,20.
C. 8,88.
D. 6,66.
Cu 25: (HA-2010)Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch
NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit
l
A. HCOOH v C2H5COOH.
B. HCOOH v CH3COOH.
C. C2H5COOH v C3H7COOH.
D. CH3COOH v C2H5COOH.
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