Professional Documents
Culture Documents
Smart Materials SP2009 376437327X Re
Smart Materials SP2009 376437327X Re
8 | preace
8marl maleras s a realvey hew lerm or maleras ahd producls lhal have chahgeabe prop-
erles ahd are abe lo reversby chahge lher shape or coour h respohse lo physca ahd/or
chemca huehces, e.g. ghl, lemperalure or lhe appcaloh o ah eeclrc ed. Nohsmarl
maleras have ho such speca properles, semsmarl maleras are holabe or lher ably, or
exampe, lo chahge lher shape h respohse lo ah huehce ohce or a ew lmes. Wlh smarl
maleras lhese chahges are repealabe ahd reversbe.
8emsmarl maleras ahd smarl maleras are whal we mghl ca uhcloha maleras. The
lerm malera, as l s used here, hcudes subslahces rom whch hlermedale producls cah
be made, as we as lhe geherc maleras lhemseves. The lerms hleror archleclure ahd
archleclure have beeh used h paces bul esewhere archleclure cah be read lo cover
bolh.
8marl maleras are oleh descrbed as adaplve or hlegehl maleras. Whsl mosl o lhe
smarl maleras khowh loday may aso be descrbed as adaplve maleras because o lher
properly lo ad|usl lhemseves, lhe descrploh hlegehl maleras s lo be cohsdered as
cooqua. Ths descrploh s hcorrecl as hlegehce aso has assocalohs wlh compuler
scehce, ahd lhe maleras ahd producls khowh lo dale are hol geheray sulabe or uhl how
have hol beeh used h such a cohlexl.
A chahge h ohe properly o smarl maleras may oleh be accompahed by chahges h olher
properles. Cerlah pholochromc compouhds (FC) chahge coour reversby h respohse lo ghl
ahd lo lemperalure chahges. Ahd hversey l may be lhe case lhal severa properles chahge
al ohce aler slmualoh by a shge huehce. For exampe, maghelorheoogc uds (MFF) uh-
der lhe huehce o a maghelc ed, h addloh lo chahghg lher ow properles, aso chahge
lhe eeclrca, lherma, acouslc ahd oplca properles o lher suspehsohs al lhe same lme.
8ome smarl maleras aso exhbl lhe hverse behavour by makhg chahges h bolh dreclohs.
Fezoeeclrc smarl maleras are abe lo geherale eeclrc charges rom lhe eecl o compres-
soh or lehsoh ahd h reverse chahge lher shape oh appcaloh o ah eeclrc ed. ll s occa-
sohay possbe lo combhe severa maleras or producls wlh smarl properles logelher lo
creale compex chahge behavours.
The use o maleras wlh chahghg properles s hol ah hvehloh o moderh lmes. From ear-
esl hslory mah has poured hol waler over wood lo hduce l lo swe ahd spl rock. Fhe cohes,
hleslhes ahd ohg bohde humah har have beeh used lo hdcale moslure h lhe ar ahd as
aclualors h ar humdy gauges. The chahge h ehglh o lwo derehl melas |ohed lo ohe ah-
olher was used rom lhe beghhhg o lhe hduslra revouloh h lhermoeeclrc swlches.
The oowhg physca ahd chemca huehchg varabes may acl as lrggerhg slmu or
chahges h smarl maleras:
Wlh speca lhahks lo:
The publisher
and the following people
Dr. Aexahder Kral, Dr. KarHehz Heckher,
Cesmal CmbH, Berh, Cermahy
Dr. Arho 8eebolh, Frauhhoer lhsllul ur Ahgewahdle
Foymerorschuhg (lAF), FolsdamCom, Cermahy
Fro. Chrslha Kubsch, Hoppegarleh, Cermahy
Erhard Keh, Caere Keh, Bad Muhsleree,
Cermahy
Euh 8ook Lee, Korea
Dr. Cerhard 8pah, 8AM 8pah ahd Mayrhoer KEC,
Wallehs, Auslra
Dr. Harlmul 8chuberl, OKEFCheme CmbH, Cermahy
Fro. Dr. Norberl Hampp, FhppsUhversll,
Marburg, Cermahy
Dp. Masch.lhg. ETH Falrck Lochmaller, Edge
hosssche Malerapruuhgsuhd Forschuhgsahslal
(EMFA), Dubehdor, 8wlzerahd
Fulh Hahdschh, Zurch, 8wlzerahd
and the following companies
Deulsche 8lehzeug Cremer & Breuer AC,
8chwarzehed, Cermahy
C.B.C. Lld., Oxordshre, Ehgahd
James Fobhsoh Lld., Huddersed, Ehgahd
Mcropel CmbH, Freburg, Cermahy
Novaed AC, Dresdeh, Cermahy
Fl Ceramc CmbH, Lederhose, Cermahy
Frhz Oplcs CmbH, 8lromberg, Cermahy
Tayo Europe CmbH, Muhch, Cermahy
9 | preace
LIGHT, UV LIGHT
The vsbe ahd ulravoel parl o eeclromaghelc radaloh.
TEMPERATURE
The lherma slale o a physca syslem, e.g. a body.
PRESSURE
The ralo o orce lo area.
ELECTRIC FIELD
The ed h lhe vchly o ah eeclrc charge.
MAGNETIC FIELD
The ed h lhe vchly o a maghel or movhg eeclrca charge, e.g. a wre carryhg ah
eeclrc currehl.
CHEMICAL ENVIRONMENT
The presehce o cerlah chemca eemehls ahd/or compouhds, e.g. waler.
The chapler oh lrehds ahd deveopmehls hlroduces lhe sub|ecl ahd gves a rsl ook hlo eds
olher lhah archleclure, whsl hhovalve maleras ahd producls gve ah overvew o currehl
deveopmehls h malera research ahd producl deveopmehl. lh order lo make lhe dslhcloh
lhey are compared wlh olher hhovalve hoh ahd semsmarl maleras.
The mah parl o lhe book deas wlh lhe derehl lypes o smarl maleras, ushg descrplohs
comprshg combhalohs o ad|eclves mahy rom lhe Creek. For exampe, ah huehce such
as ghl has beeh expressed as pholo ahd a chahghg properly such as coour as chromc.
lh lhe above case lhe u descrploh s pholochromc smarl maleras. The uslralohs ahd
egehds are hormay reerred lo rom lop el lo bollom ahd lheh rom lop rghl lo bollom. The
uslralohs h lhe hlroducloh lo lhe hdvdua groups o smarl maleras are hormay lakeh
rom lhe pro|ecls presehled h lhe respeclve group.
lh lhe sequehce ahd dvsoh o lhe smarl maleras showh here some speca pohls had lo be
lakeh hlo accouhl. Casscaloh h accordahce wlh huehchg aclors ahd chahghg proper-
les does hol make lhhgs absouley cear, as wlh some smarl maleras chahges may be lrg-
gered by lwo, lhree or more derehl huehces or h olher cases slmualoh by a shge hu-
ehce cah resul h severa properles chahghg al lhe same lme. Thereore lhe maleras have
beeh derehlaled oh a case by case bass rom lhe pohl o vew o lher mporlahce h lhe
cohlexl o reased or ulure archleclura appcalohs. The maleras choseh oer ah overvew
o lhe smarl maleras mosl sulabe al lhe currehl lme or use h archleclure, hleror arch-
leclure ahd desgh.
eccIcg|caI arcH|tecture
Maleras ahd producls used h lhs ed hcude lhose lhal cah be recyced or are mahuaclured
rom wasle. lh mahy cases lhs s al lhe deveoper's owh rsk, as usuay ho cohslrucloh ap-
prova has beeh grahled. Fre saely or loxcly or bolh are oleh lhe mah cohcerhs lhal make
l more dcul or lhese maleras ahd producls lo become eslabshed h horma use.
Ah exampe o how a budhg cah lrahsorm mechahca ehergy hlo eeclrca ehergy s lhe
pro|ecl Hybrid Muscle by lhe Frehch archlecls F&8e.: a 3 l couhlerweghl paced h a budhg
was rased by a whle buao ahd provded ehough eeclrcly rom a dyhamoeeclrc geheralor
or lhe ghlhg, a aplop ahd a leephohe syslem.
There are aso a ew hslahces where lhe ehergy comes rom humahs, or exampe by cohverlhg
lher movemehls hlo eeclrca ehergy; lhs coud be durhg sporl or whsl wakhg. A currehl
hlerprelaloh aohg lhe hes o lhs lheme s provded by lhe archlecl Mlche Joachm wlh
hs dea o a oalhg lhess sludo. The sporlhg musce power o lhe peope ushg lhe gym s
cohverled by sulabe meahs hlo eeclrca ehergy ahd used lo drve lhe RiverGym NY, whch
shelered agahsl lhe wealher by a lrahsparehl proleclve cupoa s abe lo chahge ls sur-
rouhdhgs agah ahd agah.
Two works by lhe aulhor, Dynaf l e x p01 ahd Anthrogena, show lhal ehergy oblahed rom peope
cah be used drecly lo chahge lhe geomelry o archleclohc space h a purey mechahca way.
Dynaf l e x p01 s a weghlcohlroed oadbearhg slruclure, whch hcreases h ehglh h re-
spohse lo lhe verlca deecloh o parls o lhe slruclure, caused by peope wakhg over l (see
eeclrclygeheralhg smarl maleras, pp. 162 . [1|). By cohlrasl, h Anthrogena, h addloh
lo spreadhg h wdlh h respohse lo oad, lhe slruclure deorms ahd s slabsed by lhe lrahser
o voumes o ar.
c-cHageabIe/c-cHag|g
arcH|tecture
Depehdhg oh lher geographca ahd lopographc ocaloh, budhgs are sub|ecl lo ahd musl
somelmes be prolecled rom varous almospherc, oca ahd ahlhropoogca huehces. 8e
ceahhg maleras have beeh deveoped or lhs purpose ahd are hcorporaled hlo budhg ee-
mehls such as roo les, membrahes ahd hlo acades h order lo keep lhem permahehly ceah.
8eheahg coalhgs ahd seas have beeh deveoped lhal resea lhemseves h lhe evehl o
damage lo reslore lher proleclve eecl ahd make cosly repars uhhecessary. Hghy resslahl
maleras ahd coalhgs are aso behg deveoped, or exampe ushg hahomelrescae parlces,
lo creale suraces wlh parlcuary hgh scralch, raclure or healresslahce (see p. 42 ahd l-
lahumdoxde (TO
2
), pp. 100 .). These deveopmehls are o parlcuar hleresl or budhgs
lhal have lo wlhslahd exlreme cmalc cohdlohs ahd/or are expecled lo remah h use or a
very ohg lme.
ARCHITECTURE
Trehds ahd deveopmehls emerge al derehl rales h
lhe ed o archleclure, depehdhg oh lhe commerca
ahd polca cohdlohs, geographc ocaloh, halura
ahlhropogehc ehvrohmehl, ahd lechhoogca ahd -
hahca possbles. lhhovalve maleras have a recur-
rhg ahd cruca roe lo pay here.
Hybrid Muscle wlh harhessed
whle buao: F&8e. archlecls. |
Vew rom oulsde. | lhleror vew.
treds ad deveIcpmets
11 | lrehds ahd deveopmehls
Arshp hahgar Morphyt nt h lhe cosed slale, rear vew. | Fah o hahgar. | Vew
rom above o a mode o lhe weghlcohlroed oadbearhg slruclure Anthrogena. |
8de vew. | RiverGym NY h acloh. | 8evera RiverGyms NY oh lhe New York
skyhe.
cHageabIe/cHag|g arcH|tecture
Archleclure cah be desghed lo chahge or be chahged h specc ways. lhslead o loeralhg
or couhleraclhg hvouhlary chahges h budhgs caused by halura ahd/or ahlhropoogca h-
uehces, some archlecls are seekhg lo use lhese eecls as a orma eemehl h lher pro|ecls.
lh recehl years more work has beeh dohe oh socaed adaplve budhg ehveopes, whch, h
lhe dea case, are abe lo reacl lo lher mmedale ahd ad|acehl surrouhdhgs h a mahher qule
uhke earer slruclures. Depehdhg oh lher desgh ahd sehsory syslems, ahd lher passve ahd
aclve slruclures ahd compohehls, lhey are abe lo reacl reversby lo lher surrouhdhgs over
a ohg perod o lme. Ths lask requres maleras ahd producls wlh reversbe properles.
Froperlydelermhhg paramelers reevahl lo archleclure lhal cah be desghed as chahghg
or chahgeabe hcude:
SHAPE COLOUR/APPEARANCE SOUND (NOISE) ODOUR (SCENT)
SHAPE
For varous reasohs l may be worlhwhe ahd hepu or lhe shape o a parl or lhe whoe o a
budhg lo have lhe capacly o behg chahged or chahghg lse. 8ocaed cohverlbe roos,
.e. roos capabe o odhg or wlh seclohs lhal sde over ohe aholher, ahd cohsslhg o sl
ahd/or exbe suraceormhg cohslruclohs, have beeh hcreashgy used shce lhe 1970s as
lemporary wealher prolecloh h lhe orm o roohg or slada or swmmhg poos. Ah hhovalve
cohcepl or a pheumalcay cohverlbe roo was deveoped by lhe aulhor as parl o a desgh
or ah arshp hahgar h whch lhe hahgar was covered wlh a bvaehl oadbearhg slruclure
cohsslhg o a lhreeayer halabe membrahe. Wheh lhe hahgar s cosed, a sghl overpres-
sure slabses lhe budhg skh, ushg lhe prhcpe o a pheumalc slruclure. To opeh lhe
hahgar, ar s hlroduced hlo lhe hlay al vods h lhe membrahe so lhal lhe haled vods
become pressursed arches lo lake over lhe oadbearhg roe. The cohlracloh o lhe hahgar
skh oh hg wlh ar opehs lhe gale.
U8Amercah dECO Archlecls deveoped ah hleraclve khelc wa, lhe Aegs Hyposurace.
A humber o pheumalc reaclve aclualors were bul hlo a basc slruclura rame. The aclua-
lors were mechahcay cohhecled lo a surace made up o rows o dagohay dvded, movabe
les oh lhe oulsde o lhe slruclure. The wa reacls lo varous slmu such as ghl, souhd ahd
movemehl. 8peca solware causes lhe surace lo chahge spalay. The spohlaheous move-
mehls o lhe les gve ah amosl haluraookhg smualoh o movhg waves, amohg olher
eecls.
Aegis Hyposurface h acloh. | opposite: CycleBowl
12 | lrehds ahd deveopmehls
13 | lrehds ahd deveopmehls
CycleBowl | Dufttunnel al lhe Car Cly h
Wosburg.
COLOUR/APPEARANCE
Fealvey hgh cosl ahd hadequale ohglerm slably meah lhal seaclhg coourchahghg
maleras are sl sedom used or exlerha suraces. The slualoh s derehl hsde budhgs,
where lhere have aready beeh a humber o derehl appcalohs; lhese are descrbed h more
dela h lhe seclohs beow.
Oplcay swlchabe ayers h budhg ehveopes cah be desghed lo provde bolh a lemporary
prvacy screeh ahd cohlroed darkehhg o a room. lh addloh lo speccay sehslve maler-
as lhal swlch rom opaque lo lrahsparehl al cerlah lemperalures or wheh ah eeclrc ed s
apped, lhere have aso beeh varous mechahca syslems deveoped h lhe pasl. Ohe syslem
capabe o exerlhg a varyhg huehce oh lhe lrahsparehcy o lhe oulsde skh o a budhg s
lhe ETFE m wa o lhe CycleBowl, whch archlecls Aleer Bruckher o 8lullgarl, Cermahy,
deveoped or Expo 2000 h Hahover. The lrpeayer pows each comprse lhree sheels; ohe
wlh a poslve prhl, ohe wlh a hegalve prhl ahd ohe el lrahsparehl. Uhder pheumalc coh-
lro lhe prhled mdde sheel coud be pressed agahsl lhe reverseprhled ouler sheel or agahsl
lhe uhprhled hher sheel lo make lhe acade appear al al cerlah lmes ahd lhreedmehsoha
al olhers. Furlhermore, lhe hlerha space coud aso be seaed overhead agahsl suhghl by
pheumalcay cohlroed halabe lubes hlegraled h lhe roo.
SOUND (NOISE)
There are allempls lo make cohslrucloha eemehls such as was ahd whdows souhdhsua-
lve by lhe aclve supermposloh o souhd waves. Ah arrvhg souhd wave s ahaysed ahd lheh
heulrased by lhe sehdhg oul o ah opposle souhd wave. For lhs a pezoeeclrc souhd coh-
verler cah be used (see pezoeeclrc ceramcs/poymers, pp. 154 .).
ODOUR (SCENT)
Mahuaclurers h Chha have succeeded h deveophg maleras wlh embedded scehls, whch,
wheh used as oor coverhgs ahd waked oh, are abe lo reease scehl moecues hlo lhe room
ar. Ah accessbe scuplure wlh ah exlerha skh cohsslhg compeley o rows o polled ra-
grahl pahls was crealed by Dahsh/lceahdcborh bul Cermahdomced arlsl Oaur Eassoh
h hs work Dufttunnel or lhe Car Cly h Wosburg 2004. The lhree hked luhhe seclohs
are kepl cohlhuousy rolalhg lo adequaley suppy lhe pahls wlh halura ghl ahd lo hlehsy
lhe eecl o lhe scehl. The ragrahl pahls are repaced every sx weeks wlh hew ohes durhg
lhe perod o dspay h lhe summer mohlhs o Apr lo 8eplember.
A urlher possbly or ushg odours h archleclure s h lhe area o perume markelhg.
14 | lrehds ahd deveopmehls
15 | lrehds ahd deveopmehls
|teII|get arcH|tecture
The TRON Intelligent House, lhe rsl budhg we woud cohsder hlegehl by loday's slahd-
ards, was desghed h 1988 by Keh 8akamura h Nsh Azuba, Japah. Coslhg 1 boh yeh al
lhal lme, lhe uy aulomaled budhg cohlahed a lola o 380 compulers, whch were hel-
worked wlh lhe TFON archleclure. A exlerha hormaloh receved, or exampe, rom leev-
soh, rado ahd leephohe, ahd a hlerha hormaloh, exchahged or exampe va ah audovs-
ua syslem, coud be caed up oh mohlors hslaed h every room.
Teh years aler h 1998, B Cales had a smarl house bul, whch, wlh lhe hep o hlegra
sehsors ahd assocaled solware, s capabe o recoghshg peope ahd, depehdhg oh user
preerehces, produces a chahge h lhe ehvrohmehl, so lhal, or exampe, wheh a persoh ehlers
a room a avourle mage s dspayed oh a mohlor.
A cohsorlum o severa Frauhhoer lhsllules ahd prvale compahes coordhaled by lhe Frauh-
hoer lhsllule or Mcroeeclrohc Crculs ahd 8yslems (lM8) deveoped lhe InHaus, whch was
erecled h 2001 h Dusburg, Cermahy. lh addloh lo deveophg ahd helworkhg lhe lechhca
equpmehl, lhe pro|ecl's purpose s lhe hlegraloh o lhs equpmehl hlo a moderhhome
aeslhelc, ergohomy, comorl ahd eslye. The 8marlerWohhehNFW hlalve, whch s cur-
rehly Europe's argesl aclve smarlvhg pro|ecl, w creale 1000 pol homes h Norlh Fhhe
Weslphaa, agah wlh lhe parlcpaloh o severa Frauhhoer lhsllules.
lh prhcpe, hlegehl budhgs cah aso be crealed lhrough lhe use o smarl maleras. These
budhgs woud requre slruclures capabe o recevhg ahd processhg a mullude o compex
dala, preeraby hvovhg eeclrca syslems. l such a slruclure remahs depehdehl oh a smpe
maller o slmuus ahd reacloh, lheh a syslem cahhol be descrbed as hlegehl.
deccrat|ve arcH|tecture
Decoralve eemehls cah lake oh olher uhclohs, or exampe h order lo acheve weghl reduc-
loh or lo aow vews hlo a space by removhg lhe hegalve orm rom a surace. Furlher uhc-
lohs are lhose o soar prolecloh or a prvacy screeh, oleh h lhe orm o prhled or sahd
basled gass suraces. lh lhs cohlexl lhere are a humber o derehl eecls lhal cah be crealed
by lhe use o hew lypes o coourchahghg ahd oplcay swlchabe maleras ahd producls.
For exampe, hlay severeookhg, mohochrome suraces cah be suddehy ehvehed by lhe
eecl o cerlah slmu. Ths may be lhrough lhe use o a lrahsparehl, mosluresehslve pahl
apped over cerlah areas lo revea a pallerh wheh rah as upoh l.
Ohe such use s demohslraled by lhe aulhor's 1995 work hydrophil-hydrophob. By appyhg a
qud, scohebased, lrahsparehl dampproohg agehl lo cerlah parls o lwo caslslohe pah-
es, l was possbe lo produce lhe desred cohlraslhg ghldark eecl.
hydrophil-hydrophob II (2006) beore
ahd aler lhe eecl o waler.
tet|Ie des|g
lh earer lmes lexles geheray had ohy ohe or lwo permahehl properles. Today more ahd
more lexles wlh chahghg properles are behg deveoped, .e. lhey cah chahge lhemseves h
respohse lo ohe or more huehchg aclors. Ths s made possbe by maleras ahd lher prod-
ucls wlh hherehl sechahghg properles, socaed smarl maleras. These smarl maleras
may be aready avaabe, hewy hlroduced oh lo lhe markel, or lhey may be hewy deveoped
producls. They cah be used oh lher owh or h combhaloh wlh hohsmarl or semsmarl
maleras.
The oowhg secloh deas wlh lexle desgh ohy h realoh lo colhhg, as lexles used or
archleclura purposes are descrbed h lhe mah parl o lhs book.
lh addloh lo humerous expermehla desgh pro|ecls, recehl years have seeh lhe emergehce
o varous lexle maleras h uhcloha colhhg, hcudhg socaed hlegehl colhhg. 8ome
exampes o colhhg, aready avaabe or al lhe prololype slage, reeclhg lhese lrehds h
whch smarl maleras pay a ma|or roe are descrbed beow. 8ome o lher properles ahd
speca quales cah aso be used or archleclura purposes, be l h lhe orm descrbed here
or h a derehl modcaloh.
DIRT-REPELLENT CLOTHING INCORPORATING NANOPARTICLES
8EMl8MAFT MATEFlAL8
To prolecl suls rom waler or slubborh slahs such as kelchup ahd coee, Bugall, a Cermah
mahuaclurer o hghprced meh's colhhg, made lhem rom a speca abrc lhal dsposes o
drl by meahs o a seceahhg eecl due lo hcorporaled hahomelrescae parlces.
SHAPE-CHANGING CLOTHING INCORPORATING SHAPE-MEMORY ALLOY (SMA)
8MAFT MATEFlAL8
The llaah colhhg compahy Corpo Nove, lhrough ls spho rm Crado Zero Espace, mahu-
aclured a ohgseeved shrl oul o a abrc hcorporalhg a shapememory aoy (8MA), h lhs
case, Nlho. Depehdhg oh how l has beeh preprogrammed, lhe abrc orms lse hlo der-
ehl shapes h respohse lo lhe ambehl lemperalure. The shrl wlh lhe hame Oricalco ros up
ls owh seeves. Wheh lhe room lemperalure exceeds a cerlah vaue, lhe abrc h lhe seeves
orms ods ahd lhe seeves shorleh h ehglh. The shrl cah aso be compressed hlo ls smaesl
possbe voume, or exampe or lrahsporl. By aowhg l lo reach a preprogrammed lempera-
lure, e.g. by lhe hlroducloh o warm ar rom a hardryer, l regahs ls orgha shape.
DESIGN AND ART
Texles, aulomobes ahd urhlure have lo salsy hgh
requremehls beore lhey ehler seres producloh. How-
ever, hew, hhovalve maleras ahd producls cah some-
lmes be hlroduced more qucky h lhese hduslres
lhah h archleclure, ahd eveh more so lhah h lhe coh-
slrucloh eds. lh cerlah crcumslahces, maleras
ahd producls lesled h lhese olher eds cah aso be
moded lo be used h archleclura appcalohs. ll s
hol uhusua or arlsls, wlh lher sehslvly ahd peas-
ure h expermehlaloh, lo be lhe rsl lo use hhovalve
maleras ahd producls, ahd deveop some uhusua ap-
pcalohs or lhem.
8eceahhg suls or meh. | opposite: Oricalco
shrl: compele vew. | Fodhg shorlehs lhe
seeves. | Coseup pholograph o lhe lexle.
16 | lrehds ahd deveopmehls
17 | lrehds ahd deveopmehls
COLOUR-CHANGING CLOTHING WITH THERMOCHROMIC DYES
8MAFT MATEFlAL8
Fouhded h llay as ah hleraclve desgh cohsulahcy ahd research aboralory, Cule Crcul has
deveoped ahd mahuaclured severa chahgeabe colhhg lexles, hcudhg lhe skrl Skirteleon,
whch cah chahge ls coour ahd pallerh depehdhg oh lhe aclvles ahd mood o lhe persoh
wearhg l. lh lhe morhhg al work, lhe skrl s bue; by ale alerhooh, or exampe wheh meelhg
rehds, ah ahma mol appears; ahd h lhe evehhg al a reslaurahl l lakes oh ah eegahl Japa-
hese pallerh.
LIGHT-EMITTING CLOTHING INCORPORATING ELECTROLUMINESCENT CABLE (EL CABLE)
8MAFT MATEFlAL8
Cule Crcul's back, Vclorahhspred KineticDress reacls lo lhe physca aclvly o lhe wearer.
ll has a pallerh o eeclroumhescehl rhgs lhal respohd lo lhe hlehsly o body movemehls
by emllhg derehl hlehsles o ghl. Wheh lhe wearer s hvoved h peaceu aclvles such
as readhg, lhe garmehl ooks back. Lesurey movemehl, such as wakhg, produces sghly
umhaled bue rhgs. Wlh more slrehuous movemehl, such as dahchg, lhe rhgs become uy
umhaled.
CLIMATE-REGULATING CLOTHING INCORPORATING SHAPE-MEMORY POLYMER (SMA)
8MAFT MATEFlAL8
Aholher producl rom Crado Zero Espace s a ealher |ackel wlh severa uhcloha ayers. The
appcaloh o ordhary cgarelle paper lo lhe ealher ehabes lhe ealher lse lo be kepl ex-
lremey lhh. The |ackel aso has a moslure ahd healregualhg cmalc membrahe made rom
a shapememory poymer (8MF), whch cohlros lhe permeably lo perspraloh ahd ow o
heal, h respohse lo body lemperalure. A serous search or archleclohc uses o 8MFs s cur-
rehly uhderway.
CLIMATE-REGULATING CLOTHING INCORPORATING PELTIER ELEMENTS (PE)
8MAFT MATEFlAL8
The same compahy aso deveoped aclvey coohg uhdercolhes or rachg car drvers. The uh-
derwear hcorporales Feler eemehls (FE), whch cah be cohslrucled ke lhermoeeclrc geh-
eralors (TEC) (see lhemoeeclrc geheralors (TEC), pp. 148 .), bul uhke TECs lhey are abe
lo cohverl eeclrc currehl hlo heal ahd cod. A smar aclvey coohg lexle was deveoped
al lhe Uhversly o Mhho h Forluga. Here as we, lhe coohg eecl s based oh lhermoeec-
lrc cohversoh.
Skirteleon skrl: coseup pholograph
o lhe lexle wlh lhe ahma mol
vsbe. | KineticDress durhg varous
aclvles. | Coseup pholograph o
lhe lexle wlh umhaled rhgs
made rom EL cabes.
18 | lrehds ahd deveopmehls
19 | lrehds ahd deveopmehls
Jackel wlh moslure ahd healregualhg
cmale membrahe. | Aclvey coohg
Tshrl. | Absolute Frontier |ackel. |
No-contact |ackel.
SCENT-CHANGING CLOTHING INCORPORATING CYCLODEXTRINS
8EMl8MAFT MATEFlAL8
To prevehl lhe budup o odour, abrcs or cerlah suls made by Bugall, Cermahy, hcorpo-
rale hohloxc haluray absorbehl cycodexlrhs, whch lake up smoke, sweal or al h lher hy-
drophobc hoow hlerors.
SUPERINSULATIVE CLOTHING INCORPORATING AEROGEL
NON8MAFT MATEFlAL8
For exlreme cod, Corpo Nove desghed lhe Absolute Frontier |ackel, whch uses lhe lhermay
hsualve malera aeroge. Deveoped aready h 1930, aeroge s lhe besl healhsualve male-
ra avaabe oh lhe markel, secohd ohy lo vacuumsed producls. lh lhe hear ulure we coud
see colhhg ohy 3 mm lhck behg adequaley hsualve dowh lo 50C. Aeroge s aso used
h archleclure, or exampe as a healhsualve malera belweeh gass pahes.
DEFENSIVE CLOTHING WITH ELECTRON-EMITTING TEXTILES AND LEDs
8MAFT MATEFlAL8
The No-Contact |ackel desghed by lhe U8Amercah compahy o lhe same hame s hlehded lo
deehd lhe wearer agahsl allack. Frmary markeled or lhe prolecloh o womeh, lhe wearer
rsl aclvales lhe |ackel wlh a key. Ah LED els lhe wearer khow lhs has beeh dohe. lh lhe evehl
o ah allack, lhe wearer presses a cohlro bulloh h elher o lhe seeves lo reease a pusalhg
eeclrca currehl o ow amperage bul al a volage o 80,000 vols, whch ows lhrough lhe
surace o lhe |ackel. The |ackel creales vsua ahd audbe eeclrc arcs belweeh lhe shouders
ahd coar lo warh o ah approachhg allacker.
COMMUNICATING CLOTHING WITH INTEGRATED MP3 PLAYER
8EMl8MAFT MATEFlAL8
A |ackel wlh ah hlegraled MF3 payer has beeh deveoped by lhheoh h coh|uhcloh wlh sys-
lem parlhers. Ths s ah exampe o socaed wearabe eeclrohcs. Earer eeclrohc compo-
hehls coud hol be uy hlegraled hlo colhhg because lhey woud be rehdered hohuhcloha
by washhg. Here lhe compahy deveoped a souloh h whch a our compohehls (audochp,
power modue, mcrophohe ahd cohlros) o lhe syslem were uy ehcapsualed lo prolecl lhem
agahsl moslure, ahd had hghqualy, adequaley resslahl seas. Fhe wres were woveh hlo
lhe abrc lo lrahser lhe eeclrca sghas. The power was supped al rsl rom lhumoh
poymer rechargeabe balleres, whch h lhe aler seres producloh phase woud be repaced
by lhermogeheralor chps (see lhermoeeclrc geheralors (TEC), pp. 148 .). These chps woud
geherale ah eeclrc currehl wlh ah oulpul o more lhah 1.0 W/cm ahd a volage o 5 V/cm
rom lhe sma lemperalure derehce belweeh skh ahd colhhg. lh mosl cases lhs s ade-
quale or ow power compohehls such as sehsors ahd mcrochps. However, up lo how ho prod-
ucls hcorporalhg lhermogeheralor chps have beeh broughl oh lo lhe markel.
COMMUNICATING CLOTHING INCORPORATING BLUETOOTH TECHNOLOGY
8EMl8MAFT MATEFlAL8
Ohe sulabe lechhoogy or commuhcalhg over a dslahce s Bueloolh, whch Cule Crcul
rom llay hcorporaled h ls 2004 F+R Hugs shrl syslem h order lo lrahsml dala aboul coh-
lacl evehls. The syslem, aready avaabe loday, cohssls o a shrl equpped wlh Bueloolh,
sehsors ahd aclualors, a mobe phohe ahd speca solware. Cohlacl wlh lhe appropraley
cooured sehslve areas oh lhe shrl creales eeclrc volages; lhese are pcked up by lhe sys-
lem's mobe leephohe ahd lrahsmlled by rado, h lhe orm o eeclromaghelc waves, lo lhe
mobe leephohe parlher o lhe wearer's choce; lhere agah lhey are cohverled, by aclvaloh
o lhe aclualors h lhe parlher's shrl, hlo smar movemehls.
LIGHT-EMITTING HANDBAG INCORPORATING ELECTROLUMINESCENT FILM (EL FILM)
8MAFT MATEFlAL8
The Cermah compahy BFEE produced a hahdbag wlh ah hleror ghl cohsslhg o a lhree
dmehsoha, deormabe umhescehl m (EL m), whch was deveoped by Bayer, Cermahy,
ahd a 8wss eeclrohcs specasl. The uhorm eve o ghl emlled over ah area ghls up lhe
u hleror o lhe hahdbag.
F+R Hugs shrl syslem | Hahdbag wlh aclvaled EL m lled
oh lhe sde: vews rom oulsde ahd hlo lhe bag. | Jackel wlh
hlegraled MF3 payer ahd olher eeclrohc compohehls.
20 | lrehds ahd deveopmehls
21 | lrehds ahd deveopmehls
Senso: coour chahges possbe wlh EL ms. | Maybach 62: the
hlegra eeclrolrahsparehl pahoramc roo vewed rom lhe hsde. |
Mini Concept: vew o lhe dashboard ahd lhe scehl oulel hozze
hlegraled hlo lhe Apar.
autcmcb|Ie des|g
Aulomobe desgh, whch has dslhgushed lse lme ahd lme agah lhrough parlcuary h-
hovalve, somelmes speclacuar deveopmehls, cah lake lhe credl or a humber o hew smarl
maleras worlhwhe mehlohhg lhal coud aso be o hleresl or archleclura appcalohs.
Varous prololypes ahd seres producloh vehces h whch smarl maleras have beeh used ahd
hhovalve cohcepls reased are descrbed beow.
COLOUR-, SOUND- AND SCENT-CHANGING AUTOMOBILE WITH
ELECTROLUMINESCENT FILMS (EL FILMS) AND SCENT GENERATOR
8MAFT MATEFlAL8
Ah aulomobe wlh a humber o sehsory ables was deveoped by lhe 8wss desgh ahd coh-
cepl powerhouse Fhspeed h coh|uhcloh wlh severa syslem parlhers. The Senso mode, pre-
sehled al lhe 2005 molor show h Ceheva, has a syslem or deleclhg ahd huehchg lhe emo-
loha slale o lhe drver. The poslve slmu emahalhg rom lhe vehce are hlehded lo make
lhe drver drve more saey. The aulomobe has a bomelrc walch, whch measures lhe drver's
puse, ahd a mobe eye camera, whch records hs drvhg behavour. Ah ohboard compuler
evauales lhe coecled dala ahd oers lhe drver derehl vsua, acouslc ahd oaclory slmu,
depehdhg oh hs currehl slale o mhd: a lola o our LCD mohlors ahd hleror hshes whch
cah be umhaled h derehl coours creale orahge ghl lo excle, bue lo cam ahd greeh
pallerhs or lhe evehy baahced slale. The hleror hshes are made rom eeclroumhescehl
ms (EL ms) ahd gve o a uhorm area ghl. As smarl surace lechhoogy lhs was lher
rsl appcaloh h ah aulomobe (see lhck m eeclroumhescehce/eeclroumhescehl ma-
leras (EL), pp. 130 .); specay composed lohes are payed as acouslc supporl lo lhe drver
ahd scehls are reeased lhrough lhe vehce vehlaloh syslem, elher ah hvgoralhg clrus
graperul or a camhg vahamahdarh (see p. 41).
OPTICALLY CHANGING AUTOMOBILE WITH ELECTROOPTICAL COMPONENTS
8MAFT MATEFlAL8
lh lhe uxury mode cass, lhe Maybach 62 has lhe oploh o behg lled wlh ah hlegra eec-
lrolrahsparehl pahoramc roo, whch swlches reversby belweeh lrahsparehl ahd opaque lo
provde soar prolecloh or lo darkeh lhe hleror.
SCENT-CHANGING AUTOMOBILE WITH SCENT GENERATOR
8EMl8MAFT MATEFlAL8
A sophslcaled scehl cohcepl was deveoped as parl o a sludy or ah eslale versoh o lhe
Mh, lhe Mini Concept, whch how has beeh bul hlo a humber o varahls: a mohlor mouhled
cehlray oh lhe dashboard cah dspay a humber o derehl drvhg sceharos, each assocaled
wlh a specc scehl. A devce h lhe ehghe comparlmehl hlroduces lhe scehl hlo lhe vehce
hleror lhrough a vehlaloh oulel oh lhe drver's sde.
fur|ture des|g
As urhlure used hsde rooms s exposed lo ho or ohy sghly demahdhg cmalc cohdlohs,
much ess expehsve maleras ahd producls cah be used.
COLOUR-CHANGING FURNITURE WITH THERMOCHROMIC DYES
8MAFT MATEFlAL8
Coourchahghg urhlure s realvey easy lo produce by ushg lexles wlh lhe approprale
properles. lh lhe lwo chars tictac, a work desghed ahd mpemehled al lhe lhleraclve lhsl-
lule h 8wedeh as parl o lhe 8TATlCl pro|ecl, lhe lop suraces used or deposlhg lems are
equpped wlh voel ahd red lemperaluresehslve coourchahghg abrc. Al horma room
lemperalures lhe surace s mohochrome, whsl above a cerlah lemperalure, depehdhg oh
lhe lhermochromc compohehls used, a coour chahge occurs. Ths coud be caused by cohlacl
wlh hol suraces or by warm room ar.
LIGHT-EMITTING FURNITURE INCORPORATING PHOSPHORESCENT GLAZE
8MAFT MATEFlAL8
Cass labes lhal umhesce h lhe dark have beeh deveoped by lhe hleror ahd producl desgh-
ers Cruppe FE, based h Cooghe, Cermahy. A lop coal o phosphorescehl gassceramc pahl
slores dayghl ahd arlca ghl ahd reeases l agah h darkhess. The lop coal, whch cah be
apped by a humber o derehl processes hcudhg screeh prhlhg, s baked lo creale a
slrohg bohd belweeh lhe gaze ahd lhe gass surace.
LIGHT-EMITTING FURNITURE INCORPORATING LUMINATING FABRIC
8EMl8MAFT MATEFlAL8
The llaah compahy Lumhex has a umhalhg lexle h ls rahge o producls. ll s a composle
abrc made rom cohvehloha lhreads ahd ghlcohduclhg lhreads, ahd cah be umhaled h
derehl coours. Arlcay crealed ghl s cohducled lo each separale lhread ehd o lhe ghl
cohduclhg parl o lhe abrc ahd reecled al lhe hher suraces so lhal lhe ma|or proporloh
o ghl s reemlled. Ohe possbe use or lhese umhalhg lexles coud be as coverhg or
seals.
tictac chars, wlh areas o
coour chahge.
22 | lrehds ahd deveopmehls
23 | lrehds ahd deveopmehls
8eals wlh derehl coours o umhalhg ghl
cohduclhg abrcs. | Lumhescehl gass labe
by day ahd al hghl.
art
There are mahy hslahces o lhe use o speca, hew ahd hhovalve maleras, producls ahd
smarl malera appcalohs h lhe ed o arl. ll s hol uhusua or arlsls, wlh lher sehslvly,
lher eehg or soca ssues, hdvdua ahayss ahd peasure h expermehlaloh, lo search oul
hlereslhg melhods o expressoh hol prevousy expoled.
COLOUR-CHANGING ART USING SILVER NITRATE
8EMl8MAFT MATEFlAL8
By lhe slarl o lhe 1970s, lhe Cermah arlsl 8gmar Foke was aready expermehlhg ahd
pahlhg wlh maleras lhal were capabe o chahghg lhemseves. lh severa o hs earer pc-
lures he used varous pholographc maleras such as ghlsehslve sver hlrale, whch lurhs
back over lme wheh sub|ecled lo ghl. Ths process was hol reversbe. For Foke lhe auloho-
mous crealoh o lhese pclures was ah hlereslhg phehomehoh, because he coud hol oresee
al lhe oulsel whal lhe ha eecls woud be (aler [2|). lh addloh lo hohreversbe sver hlrale
lhe arlsl aso expermehled wlh reversbe, lemperalure (see lhermochromc/lropc maler-
as (TC, TT) p. 80) ahd mosluresehslve pahls.
COLOUR-CHANGING ART USING COBALT CHLORIDE PAINTS
8MAFT MATEFlAL8
For lhe XLll Behhae h Vehce, llay, h 1986, Foke covered lhe hsde o lhe cohch oh lhe pa-
voh o lhe Federa Fepubc o Cermahy wlh a hygro/hydrochromc pahl cohsslhg o a
walerbouhd cobal chorde souloh. The pahl chahged ls coour, depehdhg oh lhe degree o
ar humdly, rom avehderbue (uhsaluraled slale) lhrough purpe ahd rosered oh lo red
(saluraled slale).
LIGHT-EMITTING ART USING PHOSPHORESCENT PAINT
8MAFT MATEFlAL8
The Schattenwand mit Blitzelektronik compeled by lhe Cermah arlsl Kohrad Lueg h 1968 s
a very eary arlslc work h whch phosphorescehl pahl was used. Wheh lrggered by a ashguh,
lhe lhreeparl, 200 cm x 341.50 cm screeh was excled ahd phosphoresced. l ob|ecls or peo-
pe passed belweeh lhe screeh ahd lhe ashguh, lhey woud remah as shadows or a
momehl.
Fhosphorescehl maleras sl hspre a greal humber o arlsls lo use lhem or pahlhgs ahd
hslaalohs. Fhosphorescehl pahls do hol aways have lo be apped over lhe whoe o a sur-
ace. Ths s showh by lhe hslaaloh Tips, sel up h 1998 by lhe New York arlsl 8haroh Loudeh.
For her hslaaloh, Loudeh used slee wre lo weave ah ehormous humber o sulaby lrealed
dehla colloh pugs hlo a lhreedmehsoha carpelke lexlure, ah dea lhal coud cohcevaby
be adapled hlo a acade desgh. Uhder ghl, lhe 150 cm x 400 cm hslaaloh ooks ke a sol,
whle carpel wlh yeowsh ahd back hcusohs; h lhe dark lhe back parls dsappear ahd lhe
mpressoh s ohe o a umhalhg meadow.
Hygrowall: rghl ha o lhe cohch wlh apped
hygro/hydrochromc pahl h lhe uhsaluraled
slale (avehderbue) ahd lhe amosl saluraled
slale (rosered). | opposite: Tips: overa vew by
day ahd al hghl. | Coseup pholograph by day
ahd al hghl.
24 | lrehds ahd deveopmehls
25 | lrehds ahd deveopmehls
Depehdhg oh lher characlerslcs, lher slruclure ahd olher properles, maleras ahd sub-
slahces loday cah be geheray derehlaled as oows:
RECYCLABLE MATERIALS
These maleras are mahuaclured mahy rom crushed ahd ceahed wasle. Uhess lhe raw
malera s sorled h advahce lo separale oul lhe vauabe raclohs, lhe resulhg producls
are usuay o ower qualy lhah lhe orghay used maleras.
BIODEGRADABLE MATERIALS
Maleras, e.g. rom vegelabe slarches, lhal are decomposed ahd compeley brokeh dowh
by mcroorgahsms vhg h lhe so.
BIOMATERIALS
Faslcs ahd olher maleras made rom rehewabe sources. Ohe currehl research ocus, or
exampe, s lhe use o speca CO
2
cohsumhg baclera h lhe producloh o bodegradabe
paslcs.
NONVARIABLE MATERIALS
These maleras are argey uhaecled by physca ahd chemca huehces, e.g. chahges h
ambehl lemperalures. Ohe such malera s lhe mela aoy lhvar.
FUNCTIONAL SUBSTANCES
A gehera lerm or mohouhcloha ahd muluhcloha subslahces.
SMART MATERIALS
Beohg lo lhe uhcloha subslahces. These maleras, subslahces ahd producls have chahge
abe properles ahd are abe lo reversby chahge lher shape or coour h respohse lo physca
ahd/or chemca huehces, e.g. ghl, lemperalure or lhe appcaloh o ah eeclrca ed.
They cah be derehlaled hlo hohsmarl maleras, semsmarl maleras ahd smarl
maleras.
HYBRID MATERIALS
These maleras are mahuaclured by combhhg al easl lwo derehl compohehls, e.g. bo-
ogca wlh syhlhelc compohehls.
FUNCTIONALLY GRADIENT MATERIALS
Composle maleras wlh graduay merghg ayers. Ths resuls h a cohlhuous chahge h
malera properles.
NANOMATERIALS
Maleras made rom hahomelrescae subslahces. They cah be used as coalhgs or h pro-
ducl mahuaclure, or exampe.
The oowhg secloh hghghls severa recehl lrehds h maleras ahd producls, some o whch
are o parlcuar hleresl h lhe ed o archleclure bul al lmes aso h olher areas o desgh
aclvly such as producl desgh, or exampe.
|cvat|ve mater|aIs ad prcducts
There are a greal humber o maleras ahd producls
currehly behg deveoped lhal are cose lo markel h-
lroducloh or aready avaabe. 8ome have beeh deve
oped speccay or use h lhe ed o archleclure;
olhers were orghay hlehded or use h producl de-
sgh, e.g. h lexles or aulomobes, ahd are ohy oered
lo archlecls sporadcay or hol al a lhrough lher usu-
a producl suppers. l archlecls are h lhe posloh lo
hcorporale lhese maleras ahd producls drecly or h
moded orm hlo lher works, lheh a ood o hew, h-
lereslhg possbles or budhg desgh ahd cohslruc-
loh cah ehsue. Crealve archlecls especay deveop
lher owh hhovalve maleras ahd producls or specc
appcalohs, or lhey deveop hew appcalohs ahd lhe
assocaled maleras ahd producls, whch lhey subse-
quehly arrahge lo have mahuaclured. Thus hol hre-
quehly lhe archlecl may be lhe desgher, deveoper
ahd mahuaclurer.
durabIe mater|aIs ad prcducts
Ohe approach lo makhg budhgs hsehslve lo cerlah exlerha huehces, or exampe so lhal
lhey cah wlhslahd exlreme cohdlohs, s lo use parlcuary durabe (resslahl) maleras ahd
producls. Aholher approach s lo use maleras ahd producls, al lmes eveh cohslruclohs, lhal
are abe lo repar lhemseves, chahge lher uhclohs or slrehglheh lhemseves. Exampes o
such maleras ahd producls hcude:
DURABLE (RESISTANT) NON- AND SEMI-SMART MATERIALS
Ohe exampe s spder sk, a malera lhal above a s assocaled wlh ulure lexles ahd ds
lhgushes lse by speca easlcly ahd slrehglh. Aler decades o research l s how capabe
o behg mahuaclured syhlhelcay h adequale qualy ahd h arge, .e. ecohomcay vabe,
quahlles. Cahadah ahd U8Amercah scehlsls were lhe rsl lo succeed h soalhg spder
gehes ahd hserlhg lhem hlo ces rom hamslers ahd cows. Nowadays goals are used whose
mk yeds syhlhelc spder proleh. Markeled uhder lhe commerca hame o Boslee, ohe o
lhe uses o lhs sk s h buelproo vesls. The mahuaclure o syhlhelc spder lhreads h arge
boreaclors cah be lraced back lo a Cermah research leam who rsl dehled ahd lrahserred
lhe spder gehe, so mporlahl lo lhe producloh o sk, hlo baclera ces. lh addloh lo lhe
use o arlcay crealed sk h lexles, appcalohs h lhe eds o paper ahd cohslrucloh
maleras are behg lesled; here sk coud be used as rehorcemehl. ll woud be cohcevabe
lo cohslrucl mpacl or buelproo lexle budhg ehveopes, or exampe, lo be used as roos
or sporlhg arehas ahd olher slruclures.
SELF-HEALING NON- AND SEMI-SMART MATERIALS
As lhs s a realvey youhg area o research, lhere are ohy a ew maleras ahd producls ava-
abe wlh lhs uhcloh. The greal polehla or use o lhese producls ahd lhe ahlcpaled eco-
homc success meah lhal work oh hew ahd urlher deveopmehls s ohgohg h mahy derehl
hduslres.
Depehdhg oh reusably ahd reproducbly, lhere are syslems h whch lhe seheahg pro-
cesses may be reversbe or hohreversbe.
8eheahg hohsmarl maleras, or exampe geolexles wlh behlohle (see mhera ad/ab-
sorbehls (MAd, MAb), pp. 175 .) cah be cassed as smarl maleras ahd w be deal wlh h
lhe mah secloh o lhs book. Here ohy syslems wlh mled smarl properles w be ds-
cussed. A good exampe are lhe seheahg paslcs lhal are behg deveoped al lhe Uhversly
o lhos (UlUC), U8A. The syslem s descrbed by lhe uhversly's researchers as ah aulo-
homc heahg syslem or seheahg syslem. ll cohssls o a shapegvhg epoxy poymer
malrx, h whch evehy dslrbuled calaysls ahd mcrocapsues ed wlh a heahg medum
are embedded. l a break h lhe epoxy poymer occurs, lhe heahg medum cohlahed h lhe
mcrocapsues lhal have beeh raclured s reeased ahd lhe sle o lhe break s ed. Cohlacl
wlh lhe calaysl resuls h poymersaloh: lhe raclure s lheh permahehly seaed.
27 | hhovalve maleras ahd producls
8eheahg pahl s especay hlereslhg lo lhe aulomobe hduslry because wlh lhs syslem
lhy scralches, such as lhose occurhg durhg a vsl lo lhe car wash or oroad drvhg, are au-
lomalcay seaed. To acheve lhs, a hghy easlc resh s used, whch spreads lse oul evehy
over lhe surace ahd seas sma hoes. The rsl producloh he use o such a pahl has recehly
beeh mpemehled by a Japahese aulomobe mahuaclurer oh ah oroad vehce. lh lhe hear
ulure lhe use o lhs malera s key lo be exlehded lo scralchprohe lems such as exlerha
mrrors ahd bumpers.
lh archleclure l woud be possbe lo use such maleras or exampe or hghgoss suraces
h hahdra ahd baseboard areas where ohy sghl scralch damage s expecled ahd compele
pahled suraces are desred, bul have hol beeh easbe so ar.
Mahy peope are uhaware o lhe acl lhal ohe o lhe reasohs hslorc slruclures such as Fomah
aqueducls or Colhc churches have asled so ohg are lhe hherehl seheahg properles o
lhe bhder used. Ths seheahg eecl s evdehl h ohe parlcuar 18lh cehlury brdge h
Amslerdam; here waler dssoves oul lhe cacle rom lhe porous cay brcks ahd lrahsporls l
hlo ahy cracks, where l permahehly seas lhem [3|. The socaed seheahg cohcreles loday
have bres added lo lhem lhal break al a parlcuar oad ahd reease ah eeclve er. A hew
approach presehly behg examhed al lhe Del Uhversly o Techhoogy, Nelherahds, s lhe
addloh o cacleormhg baclera lo cohcrele.
SELF-REINFORCING NON- AND SEMI-SMART MATERIALS
A realvey hew area o research s examhhg lhe possbles o maleras wlh serehorchg
properles, whch coud aso be o hleresl or ulure budhg cohslrucloh. For exampe, lhe
Techhca Uhversly o Causlha, Cermahy, has carred oul research oh serehorchg poy-
mers based oh poypropyehe (FF). The researchers ouhd oul lhal ah axay slrahed FF, sur-
rouhded by a ready owabe FF lo orm a lwocompohehl FF, exhbls a derehl behavour
wheh slrahed or sub|ecled lo lemperalure eecls compared wlh ordhary poymers [4|.
Techhoogy by UlUC: schemalc represehlaloh o lhe cohslruc-
loh ahd uhclohhg o lhe aulohomc heahg syslem. |
8pecay shaped malera sampe or lesl purposes. | 8EM
pholograph o a brokeh mcrocapsue. | Coseup pholograph o
lhe aulohomc heahg syslem. | Embedded mcrocapsues.
28 | hhovalve maleras ahd producls
cHageabIe/cHag|g mater|aIs ad
prcducts
Sensitive and reactive materials, products and constructions are required to help buildings re-
act dynamically to various influences for reasons of stability and energy absorption, for exam-
ple. Variable/changing materials and products can be of use in this context. They are capable
of changing their properties themselves or their properties being changed by external influ-
ences such as the effect of light, temperature, force and/or the application of an electrical field.
These influences may lead to changes directly without conversion, or indirectly with conversion.
For example, a force may, without conversion into any other form of energy, produce reversible
plastic or elastic changes in materials or products, or a temperature increase may be converted
into force, which in turn produces irreversible plastic changes in the shape of materials or
products.
These materials and products can be divided into different groups depending on their ability to
change their properties or have them changed by outside influences.
SHAPE-CHANGING NON- AND SEMI-SMART MATERIALS
Depending on the material, its thickness and final required shape, tools and machinery are
normally required to deform solid metal sheets in three dimensions. Conventional metal can
only be deformed using relatively little force if the metal is woven or stamped in advance into
a more reshapable structure. Expanded metal is one such material, but it can only be deformed
in three dimensions to a limited extent.
A relatively new perforated sheet made from aluminium behaves in a different way. It can be
easily worked by hand, stretched or upset. In this example, a pattern of Y-shaped holes (in the
Formetal product) allows the material to be easily deformed in three dimensions.
Heat-shrinkable materials in the form of film or sleeves are among those materials and pro-
ducts that change their shape plastically and irreversibly in response to increased temperature.
Examples of their use include the manufacture of packaging and cable sleeves to protect items
from moisture and hold them in position.
Under certain circumstances it is worthwhile using materials or products that partially or fully
dissolve after a preset period of time or at the end of their useful lives. They could be temporary
materials used for example during the manufacture of a component and then decomposed later
by some external influence; or components in their own right that decompose themselves after
they are no longer in use. Although these processes are not reversible, they promise a variety
of interesting applications in architecture.
Lamp in the shape of a bear, yellow plastic body with a shaped
Formetal perforated sheet. | Audi-Kreationsei in a pavilion at the
Volkswagen Car City in Dresden, skin made from Formetal. |
Sections of heat-shrinkable sleeve before and after heat
treatment.
29 | innovative materials and products
Maleras ahd producls wlh lhe properly o decomposloh have beeh mahy deveoped wlh
lhe am o wasle prevehloh. 8ocaed bodegradabe maleras are deveoped ahd broughl oh
lo lhe markel or a rahge o appcalohs, e.g. or use as package hgs, packaghg, aslood
culery elc. For such uses, maleras based oh mhera os are processed hlo poyeslers; vege-
labebased maleras hlo slarches, poyaclc acds, ceuose acelales; ahd lhe mxlures mah
uaclured rom lhem hlo slarch behds amohg olhers. These producls are compeley brokeh
dowh by baclera or uhga allack.
lh cohlrasl lo lhe above lhere are aso maleras lhal decompose oh cohlacl wlh waler aohe.
The producls made rom lhem hcude cod, warm ahd hol waler degradabe ms, whch cah
be urlher processed hlo bags ahd cod waler degradabe eeces. Foyvhy acoho (FVAL)bas
ed ms were hlroduced as delergehl packaghg h 1961. Today lhey are aso used as lempo-
rary slehhg hserls or lexles lhal are lo be sllched e.g. wlh gree pallerhs, whch h lurh
are aler removed by washhg. Or lhey are used h producl areas where lher cohlehls are hlehd
ed lo be reeased by cohlacl wlh waler. lh archleclure lhey coud be used as lemporary pro-
leclve packaghg or sma moslurehsehslve cohslrucloh eemehls. The proleclve packa-
ghg s desghed lo decompose h cohlacl wlh hol waler aler lrahsporl lo sle, bul hol wlh
rahwaler.
lh addloh lo lhe above, lhere s a urlher orm o dshlegraloh ahd decomposloh lhal has
hol beeh sucehly hveslgaled ahd deveoped al lhe momehl ahd coud have a roe h lhe u-
lure: lhe use o maleras lled wlh a speca swlch lo lrgger lhe decomposloh process aler
a perod o lme ahd/or h respohse lo a parlcuar slmuus. ll woud be possbe lo use gehe
lechhoogy here lo mody cohvehloha maleras h ah approprale way.
COLOUR- AND OPTICALLY CHANGING NON- AND SEMI-SMART MATERIALS
8uraces lhal chahge coour depehdhg oh lhe ahge o vew are hol smarl maleras bul are o
hleresl h lhe ed o archleclure. These lypes o malera hcude dyes wlh specaeecl
pgmehls.
Dchrolc ahd hoographc oplca maleras ahd producls made rom lhem are urlher exam
pes. Dchrolc maleras ahd producls have lhe ably lo appear lo chahge coour wheh vewed
rom derehl ahges. Ths eecl s caused by lhe ghl ahg upoh lhem behg decomposed
hlo reecled ahd lrahsmlled radaloh speclra. Dchrolc lers apped lo gazhg are o par-
lcuar hleresl lo archlecls. These lers cohssl o syslems o perhaps 10 lo 20 alerhaley
ow ahd hghreraclhg ayers o varous lhckhesses. The lypca lhckhess o lhese ayers s
belweeh 45 hm ahd 110 hm. The ayers are apped ushg lhe 8oCe process. Thereore lhey
are sulabe or appcaloh oh suraces curved h lwo dmehsohs, bul oh suraces ahd bodes
wlh lhreedmehsoha curvalure l s hol usuay possbe lo acheve ah adequaley eveh
coalhg.
Biophan m made rom poyaclc acd (FLA).
8ush calerhg dshes made rom MalerB
(slarch malera).
30 | hhovalve maleras ahd producls
Eecl pahl oh bodes wlh smoolh, spherca suraces (Coorslream:
Laps 8uhghl, Tropc 8uhrse). | Corrugaled sheel wlh eecl pahl
(Coorslream). | Eecl pahl oh ah ob|ecl wlh ah rreguary shaped
surace (Xrac Cosmc Turquose).
31 | hhovalve maleras ahd producls
Dchrolc lers oh gass, apped h a rghl ahge lo a whle paper
subslrale lo make lhe reecloh ahd lrahsmssoh coours vsbe. l
Dchrolc lers oh gass lube seclohs. | Delas o HooFro.
32 | hhovalve maleras ahd producls
Lobby o lhe Copehhageh Opera House wlh lhree chahdeers.
The gass suraces are coaled wlh dchrolc lers. | Vew rom
beow hlo ohe o lhe lhree gass bodes.
33 | hhovalve maleras ahd producls
Facade wlh hoographc gazhg: Augenfeuer,
Mchae Beyehberg. | opposite: Augenfeuer.
34 | hhovalve maleras ahd producls
35 | hhovalve maleras ahd producls
Berhdomced arlsl Oaur Eassoh, workhg wlh A. F. Mer ahd Chaslhe McKhhey o lhe
Mer Fouhdaloh, desghed a 2.9 m dameler, spherca chahdeer made rom 1480 lrahges
o amhaled saely gass lled wlh dchrolc lers or lhe Copehhageh Opera House. Three
o lhese ob|ecls were hslaed h 2004 h lhe opera house obby.
Orghay used lo drecl ghl lhrough oplcs, hoographc oplca eemehls (HOE) were urlher
deveoped al lhe lhsllule o Lghl ahd Cohslrucloh Techhoogy al lhe Cooghe Uhversly o
Apped 8cehces h Cermahy as a polehlay hew meahs o dreclhg ghl lhrough gass a-
cades. The resuls o lhs research provded lhe bass or a hew compahy lhal specases h
lhe mahuaclure o lrahsparehl pro|ecloh suraces capabe o showhg vdeo pro|eclohs wlh
dayghl brghlhess. Ah mporlahl parl o HooFro ahd Hoo8gh, lhe aller behg a varahl de-
rved rom HooFro whch s used lo dspay permahehl graphcs, s a hoographc m embed-
ded belweeh lwo lrahsparehl subslrales (e.g. gass or FMMA) oh whch a mullude o lhese
HOEs are apped cose lo ohe aholher ushg a speca process.
lh addloh lo some purey arlslc appcalohs, Hoo8gh has aready ouhd uses h lhe ed o
archleclure. Workhg wlh lhe lhsllule o Lghl ahd Cohslrucloh Techhoogy, lhe Cooghe
based arlsl Mchae Beyehberg used lhs producl h 2000 h lhe acade o a hew exlehsoh lo
lhe Cermah Fesearch Fouhdaloh (DFC) h Bohh. The 5 m x 13 m work Augenfeuer cohlahs
graphca eemehls h varous coours, lher oplca presehce ahd coour depehdhg oh lhe ahge
o vew ahd soar posloh. Dracloh ahd hlererehce o lhe ghl ahg oh lhe hoographc
ayer creale lhe ve coours red, orahge, yeow, greeh ahd bue.
O urlher hleresl h lhs cohlexl are hew lrahsparehl cohslrucloh eemehls lhal cohssl o a
mullude o passve umhalhg paslc bre oplc cabes hlerhked oh ah rreguar bass. lh
lhs way lhe paces where ghl as ahd s emlled are hol poslohed drecly over ohe aholher,
whch meahs lhal ghl ahd shadow appear h olher lhah lhe expecled paces. These eemehls
coud be hlegraled h lhe orm o bocks or pahes hlo acades.
opposite: 8how room (XBox) wlh bre oplc cabe
pahes (8ehsTe) hlegraled hlo lhe labes. | Coseup
pholograph. | Varous lrahsparehl ahd cooured bre
oplc cabe pahes (8ehsTe).
36 | hhovalve maleras ahd producls
37 | hhovalve maleras ahd producls
VISCOSITY-CHANGING SEMI-SMART AND SMART MATERIALS
These smarl maleras hcude maleras ahd producls lhal are abe lo reversby chahge lher
ow properles h respohse lo ohe or more slmu, or exampe lhe huehce o mechahca
ehergy (e.g. lehsoh) or lhe appcaloh o ah eeclrca ahd/or maghelc ed.
Thxolropc uds (TF), eeclrorheoogc uds (EFF) ahd maghelorheoogc uds (MFF) are o
hleresl or archleclura appcalohs, bul so ar lhere have beeh ew mpemehlalohs. TFs or
exampe are mxlures o waler ahd sahd lhal quey wheh sub|ecl lo abrupl movemehls. Uhke
EFFs ahd MFFs ho cohversoh o lhe hlroduced ehergy lakes pace, hehce lhey are cohsdered
as semsmarl maleras.
EFFs are slabe suspehsohs o mhule, eeclrcay poarsabe parlces h a hoheeclrcay
poarsabe carrer qud. By appyhg ah eeclrca ed, lher vscosles cah be hhley var-
aby ahd reversby chahged h msecohds. The suspehsohs geheray cohssl o mhera or
scoh os.
lh cohlrasl, MFFs are slabe suspehsohs o mhule, maghelcay poarsabe parlces h a
hohmaghelc carrer qud. By appyhg a maghelc ed, lher vscosles as we cah be h
hley varaby ahd reversby chahged h msecohds. lh addloh lo rheoogca behavour, lhe
eeclrca, lherma, acouslc ahd oplca properles o lhe suspehsohs chahge al lhe same lme.
They cohssl o mhera or syhlhelc os, waler or gyco, h whch are suspehded up lo 20 lo
40 o e.g. roh parlces wlh a dameler o 3 lo 10 mcrohs.
lh bolh uds lhe parlces are rahdomy dslrbuled h lhe carrer qud. Wheh sub|ecled lo ah
eeclrca or maghelc ed, lhey orm ohg chahs capabe o carryhg mechahca oads lo a
grealer or esser exlehl, whch cah be lheh deormed or brokeh by oulsde huehces.
8marl Damphg 8lraleges or 8esmc Frolecloh o Urbah 8lruclures, a pro|ecl headed by
B. F. 8pehcer, Froessor al lhe Uhversly o lhos, ahd mahaged by lhe U8AmercahJapahese
Urbah Earlhquake Dsasler Mlgaloh Fesearch lhlalve, cohcehlraled oh lhe deveopmehl o
shock absorbers hcorporalhg MFFs or use h hohmlary budhgs. The resul was a arge
scae sesmc shock damper, lwo exampes o whch were mahuaclured or hslaaloh h lhe
hew NhohKagakuMrakah budhg h Tokyo Bay, Japah. The dampers were hcorporaled as
ah hlegra compohehl o lhe mah oadbearhg slruclure by a ever mechahsm beow a V
shaped brachg belweeh lhe 3rd ahd 5lh oors. Bolh dampers are ohy a shorl heghl o lhe
oor ahd are lhereore cohvehehl lo hspecl, easy lo mahlah ahd, hecessary, repace.
lh lhe evehl o horzohla movemehl o lhe budhg hduced by sesmc movemehls o lhe
Earlh's surace, lhe lwo brachgs dspace lhe pslohs h lhe dampers by meahs o lhe ever
mechahsms lo provde lhe desred shock damphg eecl h lhe adaplve syslem.
luslraloh o lhe eeclrorheoogc eecl
(comparabe lo lhe maghelorheoogc eecl). |
Techhoogy by Lord: lypca MFF. | Varous
producls hcorporalhg MFFs. | 8ma shock
absorber hcorporalhg MFF. | Techhoogy by
Fudcoh: Frololypes o aclualhg ahd
poslohhg drves hcorporalhg EFFs.
38 | hhovalve maleras ahd producls
Large-scale seismic shock damper: Vshaped brachg ormhg parl
o lhe mah oadbearhg slruclure wlh lhe ever mechahsm.
39 | hhovalve maleras ahd producls
Lumhalhg lexle wlh a pallerh h varous coours. l
Lumhalhg lexle as a bhd.
40 | hhovalve maleras ahd producls
LIGHT-EMITTING NON- AND SEMI-SMART MATERIALS
Nol a ghlemllhg maleras ahd producls cah be cassed as smarl maleras. Ah mporlahl
crleroh or lhs s lhal mosl o lhe avaabe ehergy, e.g. h lhe orm o ghl or eeclrc currehl,
s used h lhe emssoh o cod ghl. Cohsequehly, maleras ahd producls lhal eml a arge
amouhl o heal h addloh lo ghl are hol cassed as smarl maleras.
A realvey hew deveopmehl h lhs cohlexl are umhalhg lexles h whch pro|eclors are h-
corporaled lo umhale ghlcohduclhg bres. The ghl sources h lhe pro|eclors are sodum
vapour amps, whch deveop a ol o heal.
MATTER-EMITTING NON- AND SEMI-SMART MATERIALS
lh addloh lo lakhg h maller (see mallerexchahghg smarl maleras, pp. 174 .), or exampe
by lhe adsorploh or absorploh o subslahces (compohehls), whch cah be used or room ar
mprovemehl amohg olher uhclohs, lhe reease o maller by cerlah subslahces may aso be
desrabe. Aparl rom lhe horma ahd permahehl exchahge o subslahces belweeh room or
urhshhg suraces ahd lhe room ar, cerlah olher maleras lhal gve o scehls wheh louched,
healed or due lo olher huehces are aso o hleresl. These maleras hcude pahls, oleh h
lhe orm o hks, cohlahhg mcroehcapsualed scehls. They cah be apped by screeh prhlhg
oh paper, cardboard ahd olher sulabe suraces. As lhey become exhausled over a perod o
lme, lhey cahhol be cohsdered lo be smarl maleras.
ELECTRICITY-GENERATING MATERIALS AND PRODUCTS
8cohbased soar ces are lhe mah lype o eeclrclygeheralhg maleras ahd producls lhal
have ouhd praclca appcalohs, some h lhe ed o archleclure. Thhm ahd orgahc soar
ces are realvey hew deveopmehls. lh addloh lo lhese, dye soar ces (D8C), lhermoeeclrc
geheralors (TEC) ahd syslems based oh pezoeeclrc maleras are avaabe or varous uses
ahd are deal wlh h lhe mah parl o lhs book.
Hybrd poysmarl syslems lhal cohssl o soar ces wlh hlegraled ghlemllhg dodes
(LED) are aso o hleresl here. They geherale eeclrcly by day, used by lhe syslem lo provde
ghl durhg lhe hghl.
41 | hhovalve maleras ahd producls
Solare Schiller-Zitat-Tafel (8oar 8cher
quolaloh board) oh lhe cly wa h Marbach am
Neckar, Cermahy, cohsslhg o hhe modues
1.20 m x 1.20 m | Techhoogy by 8harp:
Kalsurag pahl al hghl | ldea or a membrahe
lhal uses haholraloh lo keep a dwehg
poulahlree: Youve Gotta Have Faith,
Dahe Feos, 2005.
HYBRID MATERIALS AND PRODUCTS
By combhhg hdvdua maleras lo orm hybrd maleras ahd producls, hghpower muluay
ehhahchg syslems, ke lhe soar ceLED syslem descrbed above, cah be crealed. 8ome h-
sualoh syslems lhal uy acheve lher exlraordhary properles ohy wheh combhed wlh
olher maleras are o hleresl or archleclura appcalohs. These producl lypes hcude va-
cuum hsualoh pahes (VlF), whch are aready oh lhe markel, ahd lhe yellobehlroduced
swlchabe lherma hsualoh (8Tl) deveoped al lhe Bavarah Apped Ehergy Fesearch Cehlre
(ZAE Bayerh) h Cermahy. The aller producl s based oh VlF lechhoogy wlh lhe addloh ahd
hlegraloh o a mela hydrde, whch chahges lhe lherma cohduclvly o lhe pahes h re-
spohse lo lhe lakhgup ahd reease o sma quahlles o hydrogeh.
NANOMATERIALS AND NANOPRODUCTS
The deveopmehl ahd mahuaclure o maleras ahd producls rom hahomelrescae subslahces
has opehed up possbles or hew ahd hhovalve uhclohs. These hhovalohs hcude ayers
o hahoparlces whch cah make gazhg especay walerrepeehl or speclrumseeclve, or
pahls ahd paslcs exlremey scralchresslahl. Cazhg cah hcorporale sulaby lhh dchrolc
ler ayers. Nahoparlces cah aso be used h gypsum waboard lo mprove room ar qualy.
Exampes o hahoparlces used here are llahum doxde (TO
2
) ahd zeole (see mhera ad/
absorbehls (MAd, MAb), pp. 175 .). lh a smar cohlexl, membrahes wlh hahomelrescae
pores are currehly behg deveoped lo be used as parl o acades wlh lhe ably lo ceah po-
uled cly ar.
Alhough lhe possbles o lhese hahomelrescae subslahces seem uhmled, lher use has
hol beeh lolay wlhoul opposloh. There are cohcerhs aboul lher polehlay hazardous e-
ecls oh healh, whch have beeh rased by research hlo exlremey sma parlces.
Aholher deveopmehl are lhe socaed poymorphc smarl maleras based oh programmabe
mechahca uhls. Ther mhule sze o ohy a ew hahomelres, lher ably lo chahge lher geo-
melry ahd recohgure lher hks wlh ohe aholher meahs lhey cah lake up a wde rahge o
physca ahd oplca slales. Ohe o lhese poymorphs s lhe vsohary smarl malera Utility Fog,
cohceved by J. 8lorrs Ha al lhe beghhhg o 1990s. The Utility Fog cohssls o a mullude
o rouhd hahomelrc robols, socaed hahobols, wlh cohheclhg arms ahd descrbed by 8lorrs
Ha as ogels. By gvhg lhem leescopc arms lhal cah arlcuale ahd cohhecl h derehl ways,
lhe ogels woud be abe, accordhg lo lhe scehlsl, lo smulaheousy creale gaseous, qud
ahd sod maleras wlh varous reversbe properles.
Amohg lhe orgahsalohs currehly workhg oh lhe reasaloh o lhs lechhoogy s lhe lhsllule
or Moecuar Mahuaclurhg h Fao Alo, U8A, as s demohslraled by lhe work o Jalhah
Kochar. Kochar, who, ke Dahe Feos, s a sludehl al lhe Fulure 8ludo o lhe Fhode lsahd
8choo o Desgh, Frovdehce, U8A, worked uhder Fro. Feler Yeadoh ahd ooked hlo lhe pos-
sbe dahgers Ully Fog mghl presehl. He ehvsohed a sceharo h whch a gahl Ully Fog
dome proleclhg Lower Mahhallah rom hegalve almospherc eecls as ahd coapses.
42 | hhovalve maleras ahd producls
Tes parlay coaled wlh hydrophobc hahomelrescae parlces
lo creale graphcs ahd characlers whch appear h reacloh
lo moslure: Hydrophobic Nanotiles, Feler Yeadoh, 2004. | Foy
morphc smarl malera cohsslhg o hahomelrescae rod
eemehls: nBot Nanorobotic Environments, Feler Yeadoh, 2005. |
8mualoh o a coapsed Utility Fog dome above lhe ower parl
o Mahhallah lsahd. | 8abs o debrs ahd peces o lhe Utility
Fog as polehla backdrop or ah uhdergrouhd lhealre group:
Dystopic Scenarios, Jalhah Kochar, 2005.
smart mater|aIs
MATERIALS, PRODUCTS, PROJECTS
45 | thermal expansion materials (TEM) / expansion materials (EM)
prcpertq-cHag|g smart mater|aIs
Shape-changing smart materials include materials and products that are able to reversibly
change their shape and/or dimensions in response to one or more stimuli through external in-
fluences, the effect of light, temperature, pressure, an electric or magnetic field, or a chemical
stimulus. Among these, there are materials and products that are able to change their shape
without changing their dimensions, and other materials and products that retain their shape
but change their dimensions. Some are also able to change both parameters at the same
time.
The inherent properties of these smart materials depend on the different principles behind their
deformation. Depending on the distribution and arrangement of the sensitive components and
a basic geometric shape, changes may take place in all dimensions to equal or unequal extents.
Smart materials that have a single active sensitive component generally expand or contract
evenly; the same applies to smart materials that are composed of a passive component, e.g.
the carrier material (matrix), and an evenly distributed active component. If on the other hand
the passive and active components are unevenly distributed, for example if two differently sensi-
tive components are arranged in layers one on top of the other, then the material or product
will deform on one side only.
The currently available shape-changing materials can be differentiated according to their trig-
gering stimuli as follows
PHOTOSTRICTIVE SMART MATERIALS
Excited by the effect of light (electromagnetic energy).
THERMOSTRICTIVE SMART MATERIALS
Excited by the effect of temperature (thermal energy).
PIEZOELECTRIC SMART MATERIALS
Excited by the effect of pressure or tension (mechanical energy).
ELECTROACTIVE SMART MATERIALS
Excited by the effect of an electric field (electrical energy).
MAGNETOSTRICTIVE SMART MATERIALS
Excited by the effect of a magnetic field (magnetic energy).
CHEMOSTRICTIVE SMART MATERIALS
Excited by the effect of a chemical environment (chemical energy).
Thermostrictive, piezoelectric, electroactive and chemostrictive smart materials are those that
are currently of the greatest interest in the field of architecture, due to their availability, pre-
dicted long-term stability and other factors. Assuming successful further development and
market placement, the near future could see other smart materials gaining in importance, in-
cluding photostrictive and magnetostrictive ones. Piezoelectric smart materials are discussed
elsewhere (see piezoelectric ceramics/polymers (PEC, PEP), pp. 154ff.)
sHape-cHag|g smart mater|aIs
Documentation Centre at the Former Concentra-
tion Camp, Hinzert: inner ring structure with
kinetic cladding transmitting variable amounts
of light, outer ring structure made from
transparent thermal insulation | BalnaeNY:
variously deformed sauna walls with EAP,
projecting into the street space
tHermaI epas|c mater|aIs (xam) /
epas|c mater|aIs (am) mater|aIs
Thermal expansion materials (TEM) are materials with a coefficient of thermal expansion that
is markedly positive or negative or one that is almost zero. They are referred to accordingly as
positive thermal expansion materials (PTEM), negative thermal expansion materials (NTEM)
and zero thermal expansion materials (ZTEM).
Expansion materials (EM) classed as PTEMs are suitable for use as pressure-controlling media,
e.g. to operate piston-controlled working elements (linear actuators). Depending on the mate-
rial, the phase change may have different effects. Some materials undergo a continuous change
in volume in response to a continuous change in temperature, whilst other EMs undergo a dis-
continuous, sudden (i.e. at particular points) volume change in response to a continuous tem-
perature change. Certain EMs can also be used as latent heat storage. They are called phase
change materials (PCM) (see phase change materials (PCM), pp. 165ff.).
Thermometers were one of the first applications of gaseous and liquid EMs. Galileo Galilei is
credited with inventing the first temperature gauge (1592-98), which used an air-filled glass
bulb, the extended open end of which was immersed in coloured water. The enclosed air ex-
pands depending on the prevalent air temperature and determines the height of the column of
water. By the middle of the 17th century, liquid media such as ethyl alcohol and mercury were
also in use. The sprinkler system invented by American Henry S. Parmalee in 1874 first used
fusible links, which melted under thermal load and triggered the release of the extinguishing
water. Glass ampoules containing thermally sensitive EMs were later developed for this role. For
a period of several decades EMs have been used as pressure media in working elements.
Materials and components generally used include among others:
ALKANES (EXPANSION WAX)
n-alkanes, paraffin oils, paraffin waxes.
ALCOHOLS
Glycerine.
OTHERS
Tetrachloroethylene, 1.3-dioxolane.
THERMOSTRICTIVE SMART MATERIALS >
MATERIALS, PRODUCTS, PROJECTS
Thermostrictive smart materials have inherent proper-
ties that enable them to react to ambient temperature
changes by reversibly changing their shape and/or di-
mensions. The temperature changes may have a pas-
sive effect by which the material continually adjusts its
internal thermal state to its natural surroundings
through its surface. They may also have an active effect,
for example by heating or cooling. Active heating may
be either direct heating by the application of an electri-
cal field or indirect heating by heat conduction or
radiation.
In the field of architecture the following thermostric-
tive smart materials among others are currently of
interest:
THERMAL EXPANSION MATERIALS (TEM)/EXPANSION
MATERIALS (EM)
THERMOBIMETALS (TB)
SHAPE MEMORY ALLOYS (SMA)
Other thermostrictive smart materials are:
THERMOBICOMPOSITE MATERIALS
SHAPE MEMORY POLYMERS (SMP)
SHAPE MEMORY FOAMS
SHAPE MEMORY CERAMICS
BIOLOGICAL SYSTEMS WITH SHAPE MEMORY EFFECT
47 | thermal expansion materials (TEM) / expansion materials (EM)
48 | shape-changing smart materials
The following EMs are among those of interest in architecture:
N-ALKANES C10 TO C18
Colourless hydrocarbons, liquid at +20C, are used for EM working elements at low
temperatures.
Market presence, can be made in large quantities, many years of practical use, can be
used in low temperatures (16C to +40C), insensitive to mechanical vibrations,
maintenance-free, long replacement life.
Major leakages may be hazardous to ground water, may convert or break down into water
and carbon dioxide on contact with air or oxygen, inflammable gases may form in contact
with air.
PARAFFIN OIL, PARAFFIN WAX
Depending on the state, colourless to whitish-yellow hydrocarbons, liquid to solid at +20C;
used for EM working elements with continuous linear or discontinuous sudden (i.e. at
particular points) expansion behaviour.
Can be used in medium to high temperatures (0C to +180C), paraffin waxes solid at
+20C cannot liquidise in the presence of air. Otherwise as above.
As above.
tHermaI epas|c mater|aIs (xam) /
epas|c mater|aIs (am) prcducts
Since their first use in a thermometer, expansion materials (EM) have been developed into a
wide range of products and brought on to the market for a wide range of applications. Com-
paratively sluggish reaction times have resulted in the EM working elements being increasingly
replaced in some sectors with quicker and more precisely reactive working elements, for exam-
ple with electrorheologic fluids (see p. 38). New, previously unexploited possibilities are appear-
ing for some applications, including some in the field of architecture.
EMs in glass ampoules are still used today as components in sprinkler systems. Another appli-
cation is as a working medium in EM working elements, e.g. for operating valves, controlling
gases and liquids. The main areas of use are in automobile construction and building technical
services, e.g. in heating thermostats. EM working elements are sometimes used as actuator or
positioner drives in greenhouses and building facades in energy-autonomous, decentralised
room ventilation systems.
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Among the first users of SMAs was NASA, who developed a satellite dish that folded out under
the influence of solar radiation. Today SMAs are used in air and space travel as decoupling
mechanisms and tube connectors, e.g. for fuel pipes in satellites. Other fields of application
include medicine, where stents are used to widen blood vessels, microsystem technology, meas-
urement and control technology, electrical and automobile engineering. They have also found
their first uses in the consumer goods sector and in functional textiles (see p. 16). In household
electronic appliances these alloys are already replacing some TB components.
Plastics have also been developed that display similar behaviour when stimulated by light or
temperature changes. Future research is likely to involve light-stimulated shape memory plas-
tics (memory polymers), in particular in medical devices.
No market-ready products with SMAs have been developed for use in architecture yet, although
the number of designs involving smart materials produced by universities has been on the in-
crease for years. The following is an overview of the currently available semifinished products.
Raw or end products made from SMAs currently available include:
Wires and rods made from SMAs
FULL-SECTION SMA WIRES AND RODS
Nickel-titanium alloy wire is available in diameters of approx. 0.018mm to 5mm from
stock, copper-zinc-aluminium alloy wire in diameters of approx. 1mm upwards. They can
be clamped at one or both ends, installed as endless, and weaved manually or mechani-
cally, depending on the diameter and mesh size.
Depending on the shape memory effect they can be used as actuating and positioning
drives to provide continuous, almost linear or discontinuous, sudden movements, can
be used as active components in drives to create rotational movements and in textiles,
as elastic elements/components and as structural components, relatively long actuator
paths compared with piezoelectrically operated actuating and positioning drives; may
have bending-, tension-, compression-, torsion- and shape-changing properties, silent.
Otherwise as for alloys above.
Relatively sluggish reaction times compared with e.g. piezoelectrically operated actuating
and positioning drives. Otherwise as for alloys above.
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POLYTHIOPHENE DERIVATES
Electrically conductive polymers that can be made by the electrochemical polymerisation
of thiophene (derivates). Solid at +20C. They can be used e.g. as cathodic colouring
compounds in electrochromic layers (films). React to the influence of a DC electrical field
by electrochemical reduction with the simultaneous taking-in of charge-neutralising cations
(e.g. H+, Li+), changing colour from red to blue. Other colours are possible depending on
the derivate. Reversing the polarity reverses the colour change. Thiophene is available in
powder form.
Market presence, can be made in large quantities, can be used in low to high tempera-
tures (< 40C to > +120C), relatively large number of cycles of possible changes of
colour (> 105), non-toxic.
Only reversibly colouring between two oxidation stages, cannot form neutral colours (red
and blue are considered less suitable for some applications), relatively poor lightfastness
compared with inorganic electrochromic compounds based on metal oxides.
TUNGSTEN OXIDE (WO
3
)
A metal oxide that can be made by the oxidation of the heavy metal tungsten with pure
oxygen and by heating tungstic acid. Solid at +20C. It can be used e.g. as cathodic
colouring compound in electrochromic layers (films). It reacts to the influence of a DC
electrical field by electrochemical reduction with the simultaneous taking-in of charge-
neutralising cations (e.g. H+, Li+), changing colour from transparent to blue. Reversing the
polarity reverses the colour change. Available as a yellow powder.
Market presence, can be made in large quantities, even by the user himself, can be used
in low to high temperatures (< -40C to > +120C), relatively large number of possible
cycles of colour change (> 105), relatively good lightfastness compared with organic
electrochromic compounds based on polymers, non-toxic.
Only reversibly colouring between two oxidation stages, cannot form neutral colours (blue
is considered less suitable for some applications).
NIOBIUM OXIDE (NB
2
O
5
)
A metal oxide that can be made by the oxidation of the heavy metal niobium with pure
oxygen. Solid at +20C. Reacts by changing from transparent to brown. Available as a
powder. Is being currently tried as a replacement for tungsten oxide. Otherwise as above.
Can form a neutral colour (brown). Otherwise as above.
Only reversibly colouring between two oxidation stages. Otherwise as above.
STILBENE-DERIVATES (C
14
H
12
)
Aromatic hydrocarbons with the isomer forms cis- and trans-stilbenes.
Market presence, can be used in low to high temperatures (< 20C to > +100C).
Not known.
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TiO
2
powder.
100 | adhesion-changing smart materials
101 | titanium dioxide (TiO2)
t|ta|um d|c|de (x|c
a
) prcducts
One of the successful areas of application of titanium dioxide (TiO
2
), especially in Japan and
also in Germany, is in photocatalytic paper, which uses the UV light to oxidise organic molecule
pollutants and odours in the air and convert them into substances such as carbon dioxide and
water. The cellulose in the paper is hygroscopic and adsorbs water vapour; therefore the prod-
uct has no significant self-cleaning properties. Photocatalytic papers are expected to be further
developed for the European market, for example as wallpaper. In Japan it has occasionally been
incorporated in coverings for room dividers for domestic use.
TiO
2
can also be used, with the help of sunlight, to purify water, e.g. breaking down pesticides
and pharmaceutical residues. In the 1970s American scientist A. Heller and Japanese scientists
A. Fujishima and K. Honda described the photocatalytic process as follows: When UV light
strikes the surface of the TiO
2
anatase crystal, it releases negatively charged electrons from
the surface leaving behind positively charged holes. In the presence of water, OH-groups are
adsorbed on the TiO
2
surface. The bond is so strong that further layers of H
2
O on the monomo-
lecular OH-layer are physically adsorbed and other substances repelled from the surface, creat-
ing an easy-to-clean, hydrophilic surface. Water droplets immediately spread on the hydrophilic
surface and form a compact film with the result that the contact angle is very low. (after [10])
Various products with surfaces made of TiO
2
and capable of changing reversibly their adhesion
in response to UV light have been developed for architectural applications. The most important
products developed over recent years are those in which the anatase modification has been ap-
plied insolubly using the Sol-Gel process, preferably on to smooth surfaces. The first marketable
product was developed in Japan in the form of ceramic slabs which had self-cleaning properties
and were able to break down pollutant gases. From this have followed construction membranes,
glass panes and other products for various applications. In addition there are various products
on the market that use TiO
2
solely for breaking down organic pollutants. By the choice of com-
ponents used the products have no overall light-dependent hydrophilic properties but show a
permanent hydrophobic effect. Silicones are used to achieve this effect in certain photocatalytic
facade paints. Further similar products with a photocatalytic effect are interior paints and
plasters.
Illustration of the self-cleaning effect. | Illustration of the
photocatalytic conversion of organic pollutants.
102 | adhesion-changing smart materials
Below are described some products specifically developed for architectural uses and equipped
with the ability to change reversibly their adhesion in response to UV light:
CERAMIC SLABS WITH TiO
2
Ceramic slabs with a surface coating of baked-on TiO
2
, preferably the anatase modification,
currently available as facade slabs (e.g. with dimensions 592mm x 284mm x 15mm) and
as wall and floor tiles, can be handled and used like conventional facade slabs and tiles.
They are intended for use where their self-cleaning properties and their ability to improve
the air quality by breaking down organic pollutants are important.
Market presence, can be made in large quantities, applicable in conjunction with
conventional facade substructures, largely maintenance-free, long replacement life, fire-
resistant, relatively inexpensive compared with conventional ceramic slabs. Otherwise as
above for the anatase modification.
Only a few manufacturers, reactivation by additional cleaning is required where there is
severe dirt contamination (e.g. bird droppings, tar). Otherwise as above for the anatase
modification.
CONSTRUCTION MEMBRANES WITH TiO
2
Textile membranes fully coated with plastic (e.g. PVC, PTFE) with a TiO
2
surface coating,
preferably the anatase modification. Available in rolls in various dimensions depending on
the manufacturer, extensive cutting to shape required, can be prefabricated to suit the
customers requirements as conventional construction membranes, best suited for use
where self-cleaning is desirable (no knowledge of its suitability for air quality improvement
by breaking down organic pollutants; the release of volatile components from the plastic
shortly after installation and at high temperatures may present problems).
Market presence, can be made in large quantities, can be used for a wide range of
applications and integrated into various membrane construction types, largely mainte-
nance-free, long replacement life. Otherwise as above for the anatase modification.
Only a few manufacturers, reactivation by additional cleaning is required where there is
severe dirt contamination (e.g. bird droppings, tar), may have a plastic odour, possible
release of toxic components in the event of fire. Otherwise as above for the anatase
modification.
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121 | phosphorescence
122 | light-emitting smart materials
Ruth Handschin, Germany
Light installation | Hotel Teufelhof, Basel, Switzerland
(1994)
At the Teufelhof Hotel in Basel, Monica and Dominique
Thommy-Kneschaurek seek to provide a gastronomic as well
as a cultural experience to their guests. In addition to the
gastronomy area there is a theatre, a gallery hotel, and an
art hotel. In the latter each one of the eight rooms is made
into a walk-in work of art. The rooms are completely rede-
signed roughly every three years. For the redesign in July and
August 1994 the artist Ruth Handschin provided one of the
rooms with various light drawings, turning it into a Leucht-
zimmer (Luminous Room).
The drawings were created using a mixture of fluorescent
and phosphorescent pigments, which were applied as paint
with an acrylic binder in thin lines on the ceiling, wall and
floor. The large format motifs depict the outlines of leaves
and extend over several surfaces. By the addition of various
types of luminescent pigments the motifs emit light both
day and night. They use the ultraviolet radiation contained
in natural light over the day, and at night give up, after a de-
lay, the natural and/or artificial light taken in during the
day.
Leuchtzimmer: luminous drawings by day. | Luminous drawings at night.
Lum|cus =ccm
Polysmart materials | Monosmart application
Light-emitting smart materials:
PAINT WITH FLUORESCENT AND PHOSPHORESCENT
PIGMENTS
Fluorescent and phosphorescent wall, ceiling and floor
surfaces
Juliet Quintero, Great Britain
Luminous wallpaper | Great Britain (2004)
Everything around her was different. The house, the coun-
tryside, the people. She had entered a fairytale world that
would become more and more real for her.
Alice in Wonderland was the unusual design theme of Juliet
Quintero, who in 2004 studied with Jonathan Hill at the Bar-
tlett School of Architecture, UCL, London. Equally unusual
was the material that was to contribute to the transforma-
tion of her work, which was called Alices House: sugar.
Everything possible in Alices House was to be made com-
pletely or in part from sugar: the walls, the wallpaper, the
panes of glass, the curtains, the mirror. It was to be left to
change over time in the London mist, smog, rain and/or light
and in this way undergo a transformation. Instead of tradi-
tional building materials, the artificial stone was made out
of caramelised sugar and the glass from invert sugar. Cur-
tains were given more materiality by stiffening and thus be-
came more immediate. This was achieved by filling the sewn
curtain materials with sugar, which was then crystallised out
by moistening and drying.
Filigree Wallpaper is based on a wallpaper design by William
Morris. The paint was a sugar solution made of egg white
mixed with royal icing sugar, hot water and phosphorescent
pigments, which was applied to a sheet of glass following
the wallpaper pattern. Contrary to expectations, the addition
of pigments and the egg white component did not have any
moisture-stabilising effect. The sugar component did not
lose its inherent hygroscopic property, which means the
paint has remained extremely sensitive so that Filigree Wall-
paper is mainly suitable for interiors and the paint for indoor
application.
The properties of the added phosphorescent pigments on
the other hand were successfully preserved: Filigree Wallpa-
per luminesced after 15 minutes of excitement by natural
light.
Filigree Wallpaper by day and at night.
123 | phosphorescence
r|I|gree maIIpaper
Monosmart material | Monosmart application
Light-emitting smart material:
PAINT (SUGAR SOLUTION) WITH PHOSPHORESCENT
PIGMENTS
Phosphorescent wall surface
Hannaliisa Hailahti, Finland
Luminous fabric | Finland (2005)
Finnish designer Hannaliisa Hailahti developed a fine lumi-
nous fabric made from phosphorescent and metallic silver
reflective threads. The designer sought a vision for energy-
autonomous lighting elements with the aim of creating a
more appealing nocturnal atmosphere and allowing safe
movement around the house at night without the use of fur-
ther light sources; at the same time she wanted to avoid
complete darkness.
In the dark, the light emitted from the phosphorescent
threads is reflected by the adjacent metallic threads to in-
crease the luminous effect. The bending stiffness of the met-
al allows the fabric to be hand-formed into different shapes.
Depending on the cut and the dimensions, this kind of fabric
can be used as lights, room dividers or curtains.
Shush as an unfolded room divider at night and closed by day. |
Shush as a luminous source.
124 | light-emitting smart materials
sus |gHt I|gHts
Monosmart material | Monosmart application
Light-emitting smart material:
MIXED FABRIC WITH PHOSPHORESCENT THREADS
Phosphorescent lights, room dividers and curtains
|ject|c eIectrcIum|escece i
I|gHt-em|tt|g d|cdes (Lac) mater|aIs
Injection electroluminescence is the fundamental principle behind semiconductor light sources
such as light-emitting diodes (LED), in which the charge carriers are introduced from outside
by a so-called injection current and light is emitted by the recombination of electrons and
holes.
Doped gallium arsenide acts as the lumninescent material in LEDs. It is embedded between
two electrodes which are encapsulated by light-transparent plastic to separate them from their
surroundings. For a long time only red, yellow and green LEDs were available, but with the de-
velopment of blue LEDs, which has only recently extended the range of possible light colours,
now even white LEDs can be produced by combinations of different light colours.
French scientist Georges Destriau discovered electroluminescence (EL) as early as 1936. It re-
mained in the laboratory however until the late 1960s. The aim had been to develop an alterna-
tive to incandescent bulbs as a light source; this was not an initial success.
Electroluminescent materials or components in the field of injection electroluminescence
include:
INORGANIC COMPOUNDS
Doped gallium arsenide, other gallium compounds.
The following is currently of interest to architecture:
DOPED GALLIUM ARSENIDE
This semiconductor is doped with different metals. The method used for production,
crystal growth, is expensive.
Market presence, many years of practical use, high brilliance and intensity of colour, in
its encapsulated version free of toxic substances, versatile range of applications;
depending on type, resistance to particular chemicals and high temperatures, also
available in small quantities.
Only manufactured by a few specialist factories, limited number of available light colours.
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Bentonite swelling.
As there are many natural materials such as wood, pa-
per, leather, raffia among the ranks of organic adsorb-
ents (OAd) and they are able to adsorb only relatively
small quantities of water in the form of vapour, they will
not be dealt with further here. In this context it should
be mentioned that the hygroscopic property of paper
in conjunction with a photocatalyst is used in Japan
among other places; this so-called photocatalytic paper
cleans the room air of pollutants with the help of light
(see titanium dioxide (TiO
2
), pp. 100ff.).
The use of mineral absorbents (MAb) to waterproof
buildings has become part of the current state of the
art. As they can also be used for other purposes, these
smart materials will be considered only to a limited ex-
tent here. Bentonite in particular is one of these materi-
als in which both the take-up and take-in mechanisms
can occur, and therefore mineral ad- and absorbents
(MAd, MAb) will be brought together in one chapter.
These smart materials are classed as inorganic ad- and
absorbents (IAd, IAb).
176 | matter-exchanging smart materials
CALCIUM BENTONITES
Natural clay mineral, available as powder or granulate, which can be further processed in
various ways, suitable for use in bentonite suspensions e.g. for sealing soil layers. They can
be regenerated in the presence of air.
Relatively long replacement life (> 10 regeneration cycles), usable over a comparatively
large temperature range (< 30C to > +80C), uses include desiccants, moisture buffers
and seals (due to their moisture-sensitive volume change), can be processed into clay
bricks or clay render among others. Otherwise as above.
Volume changes may be undesirable for certain applications. Otherwise as for silica gels
above.
ACTIVATED BENTONITES, NATURAL SODIUM BENTONITES
Clay minerals with mainly sodium ions in the intermediate layers, activated bentonites,
natural sodium bentonites are used e.g. for sealing soil layers. They can be regenerated in
the presence of air.
Relatively long replacement life (> 10 regeneration cycles), usable over a comparatively
large temperature range (< 30C to > +80C), uses include moisture buffers and seals
(due to their moisture-sensitive volume change).
Not suitable or only suitable under certain conditions for processing into clay bricks or
render.
LOAMS
Mixtures composed of various ratios of clay, sand and other components.
Usable over a relatively large temperature range (< 30C to > +80C), suitable as
moisture buffers, can be processed e.g. into clay bricks or render, non-hazardous.
Otherwise as for silica gels above.
Relatively poor adsorption capacity, lower adsorption speed compared with silica gels,
calcium bentonites and zeolites.
ZEOLITES
Natural and synthetic alumino-silicates with a well-defined cluster structure. Natural
zeolites can be used, among others, as heat-emitting smart materials, synthetic zeolites
for drying gases (e.g. air), available as powder and granulate, which can be further
processed in various ways. They can be regenerated at temperatures of +250C to +400C
or under negative pressures (evacuation).
Relatively long replacement life (> 10 regeneration cycles), can be used over a compara-
tively large temperature range (< 30C to > 400C) as desiccant or filtration media,
catalyst for conversion of pollutant gases and as a heat-emitting smart material.
Otherwise as for silica gels above.
Relatively high regeneration temperatures required. Otherwise as for silica gels above.
As the hygroscopic effect of gypsum is well known it will not be discussed further here.
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189 | sources
CATALOGUES, WHITE PAPERS, BROCHURES
Dehnstoffarbeitselemente mit PTC; company publication by
Behr Thermot-tronic GmbH, Kornwestheim
EunSook Lee, catalogue of exhibition at Republic of Korea
Embassy, 26 November to 5 December 2003, Berlin
Frderpreis zum 3. Studentenwettbewerb Textile Strukturen
fr neues Bauen 1995, white paper published by
Techtextil-Symposium, Arbeitskreis Textile Architektur
und der Messe Frankfurt,1995, Frankfurt
Gelsenkirchen-Stiftung (Editor): Kinetische Kunst Die
Sammlung des Stdtischen Museums Gelsenkirchen,
Edition Braus: Heidelberg, 1998
GLASSX verwandelt die Glasfassade in ein Klimatisierungse-
lement mit nachhaltiger Energiebilanz, company
publication by GlassX AG, Zurich, Switzerland
Heckner, Karl-Heinz: Intelligente Glser im Energiemanage-
ment von Gebuden Fenster mit variablen optischen und
thermischen Eigenschaften, in: conference paper at
GLAS Innovationsforum fr Glasvarianten, Haus der
Technik, Berlin, on 03.06.1999
Nitz, Peter: Sonnenschutz mit thermotropen Schichten,
white paper for the 1st Leobener Symposium Polymeric
Solar Materials, Leoben, 2003
Optimal gekoppelt: Akustik und Raumluftqualitt Call
Center im Industriedenkmal die Fabrik in Cottbus, press
release by Knauf Gips KG, Iphofen, 2005
Piezokeramische Materialien und Bauelemente, company
publication by PI Ceramic GmbH, Lederhose, Germany
Sigmar Polke, catalogue of exhibition at Muse dArt
Moderne de la Ville de Paris, ARC, Paris, from 20 October
to 31 December 1988
SmartWrap; company publication by KieranTimberlake
Associates, 2003
Thermobimetalle Grundlagen, Berechnungen, Gestaltung,
Auswahl; company publication by G. Rau GmbH,
Pforzheim, 1989
Toyoda, Hiroshi; Nakata, Takayuki; Abe, Kazuhiro:
Photocatalytic properties of membrane materials treated
with titanium dioxide for architectural membrane
structures, company publication by Taiyo Kogyo Corp.,
Osaka, Japan
Verbundprojekte, in: Ergebnisse aus Forschung und
Entwicklung, ZAE Bayern, 2003, pp. 4853
Wie das Auge in der Bleistiftzeichnung herumspaziert, so
meldet das Hirn..., leaflet by Ruth Handschin about the
light installation at Knstlerhaus Bethanien, Berlin, 1990
INFORMATION SOURCES ON THE INTERNET
http://www.art-site.de/ruth.handschin
http://www.autonomic.uiuc.edu
http://www.bayermaterialscience.de
http://www.bine.info
http://www.chempage.de
http://www.dyesol.com
http://www.eamex.co.jp
http://www.e-ink.com
http://www.el-licht.de
http://www.el-technik.de
http://www.emfit.com
http://www.empa.ch
http://www.enocean.com
http://www.functionalpolymers.basf.com
http://www.innovations-report.de
http://www.inhaus-duisburg.de
http://www.ise.fhg.de
http://www.oled.at
http://www.photochromics.co.uk
http://www.privalite.com
http://www.rinspeed.com
http://www.sam-tetec.com
http://www.seilnacht.com
http://www.storelite.com
http://www.tagesleuchtfarben.ch
http://www.tii.se/static.htm
http://www2.uni-jena.de/chemie/institute/oc/weiss.htm
http://www.we-make-money-not-art.com
http://wikipedia.org
UNIVERSITIES, INSTITUTIONS
Eidgenssische Materialprfungs- und Forschungsanstalt
(EMPA), Dbendorf
Forschungszentrum Jlich (FZ Jlich), Jlich
Fraunhofer Institut Angewandte Polymerforschung (IAP),
Potsdam-Golm
Fraunhofer Institut fr Solare Energiesysteme (ISE),
Freiburg
Fraunhofer Technologie Entwicklungsgruppe (TEG),
Stuttgart
Philipps-Universitt, Marburg
Technische Universitt Berlin, Physikalische und Theo-
retische Chemie, Berlin
Universitt des Saarlandes, Fachbereich Organische
Chemie, Saarbrcken
LECTURES ON THE SUBJECT BY THE AUTHOR
Huser mit IQ Die smarten Eigenschaften des Wassers als
Auslser komplexer Vernderungen am Haus, invited
lecture to the 3rd Students Congress at the Fachhoch-
schule Suderburg, 05.06.1994
Sich verndernde Huser als Ergebnis biologischer Prozesse
auf Natursteinflchen, invited lecture to the 4th Students
Congress at the Fachhochschule Nrtingen, 14.05.1995
Gewichtsgesteuerte Phnomene, invited lecture at the
Institut fr leichte Flchentragwerke (IL) of the Univer-
sitt Stuttgart as part of an international symposium,
28.05.1998
Smarte Materialien fr eine neue Architektur, invited lecture
at the Fachhochschule Koblenz, 09.06.2004
PUBLICATIONS RELEVANT TO THE SUBJECT BY THE
AUTHOR
Airship hangar wins textiles design prize, publication of a
design for a pneumatically convertible airship hangar
with a bivalent load bearing structure Luftschiffhalle
Friedrichshafen, in: Technical Textiles International,
November 1995
Airship hangar designed with textile structure, publication
of a design for a pneumatically convertible airship
hangar with a bivalent load bearing structure Luftschiff-
halle Friedrichshafen, in: High Performance Textiles,
November 1995
Publication of a design for a pneumatically convertible
airship hangar with a bivalent load bearing structure
Luftschiffhalle Friedrichshafen, in: Techtextil-Telegramm,
December 1995
A pneumatic convertible, publication of a design for a
pneumatically convertible airship hangar with a bivalent
load bearing structure Luftschiffhalle Friedrichshafen,
in: fabrics & architecture, 0102 1995
Dreilagige Textilhlle von 157m Lnge, publication of a
design for a pneumatically convertible airship hangar
with a bivalent load bearing structure, in: Techniker-
Magazin, June 1995
Publication of a design for a weight-controlled building by
the Kinetic Design Group at the Massachusetts Institute
of Technology (MIT), at: http://kdg.mit.edu/Matrix/
matrix.html, since December 1999
Publication of a design for a reactive mechanical mem-
brane, in: Wallpaper*, December 2002
Publication of a competition design for a building with a
reactive mechanical facade capable of changing its
textural and light transmission properties, by: Exhibition
by the Aufsichts- und Dienstleistungsdirektion Trier at the
Electors Palace, Trier; Exhibition by the Verbandsge-
meinde Verwaltung Hermeskeil, Hermeskeil, October
2003
NOTES ON THE TEXT
[1] http://kdg.mit.edu/Matrix/matrix.html
[2] Hofmeister, Sabine: Der beabsichtigte Zufall und
die gewollten Vernderungen im malerischen
Werk Sigmar Polkes, Diplomarbeit, Institut fr
Technologie der Malerei, Stuttgart, May 1993
[3] van Hees, Rob: Laboratory Profile: Conservation
Techniques, at: http://www.tudelft.nl/~
[4] E-mail from Herbert Enzler, technical assistant at
the Institut fr Polymerwerkstoffe und Kunststoff-
technik of the TU Clausthal dated 14.11.2005
[5] Schmidt-Mende, P.: Aktoren mit Formgedchtnis-
legierungen, in: Jendritza, Daniel J. et al.:
Technischer Einsatz Neuer Aktoren Grundlagen,
Werkstoffe, Designregeln und Anwendungs-
beispiele, 2nd ed., expert-Verlag: Renningen-
Malmsheim, 1998
[6] E-mail from Dipl. Masch.-Ing. ETH Patrick
Lochmatter, Eidgenssische Materialprfungs-
und Forschungsanstalt (EMPA), Dbendorf dated
22.06.2006
[7] Bouas-Laurent, H.; Drr, H.: Organic Photo-
chromism, in: Angewandte Chemie, No. 116,
2004, pp. 34043418
[8] Helioseal Clear Chroma farbverndernd,
transparent, sthetisch, company publication by
Ivoclar Vivadent AG, Schaan, Lichtenstein
[9] Stephan, Jrg: Beitrag zum Greifen von Textilien,
Dissertation, Fachbereich 11 Maschinenbau und
Produktionstechnik der Technischen Universitt
Berlin, Berlin, February 2001
[10] Keramische Fliesen mit Hydrotect Oberflchen-
Veredelung, company publication by the
Deutsche Steinzeug Cremer & Breuer AG, Bonn
[11] Blasse, Grabmeier, 1994
[12] Mann, Martin: ... und es leuchten die Wnde, in:
hobby Das Magazin der Technik, No. 8, August
1957, pp. 7477
[13] Elektronik, 12/2002
ILLUSTRATION CREDITS
AGROB BUCHTAL: 99 top, 106, 107
(photos: Pez Hejduk)
Alsa: 82, 85
Anja-Natalie Richter: 64
atelier brckner: 13, 14 top
(all photos: Thomas Mayer)
Autostadt: 14 bottom
Axel Ritter: 11 left (photos: Axel Ritter); 15, 46 top
(graphic: Axel Ritter); 52 (graphic: Axel Ritter); 57,
58 (photos: Axel Ritter); 76 left 1
st
, 2
nd
and 3
rd
from
top; 81; 91; 100; 113 (photo: Axel Ritter); 162, 163
(photos: Axel Ritter); 174 (photo: Axel Ritter); 177
2nd from top (photo: Axel Ritter); 183; 187
(photos: Axel Ritter)
BASF: 165; 167 left, right 1
st
from top; 170
Bayer: 20 2
nd
and 3
rd
from top
Behr Thermot-tronik: 49, 50
BMW Group: 21 right
Bryan Boyer: 46 bottom; 71
Bugatti: 16
Christina Kubisch: 116
Christopher Glaister, Afshin Mehin, Tomas Rosen: 88
CLOUD 9 (Enric Ruiz Geli): 128; 129
2006 Cute Circuit: 18; 20 1
st
from top
DaimlerChrysler: 21 left 4
th
from top
Daniel Pelosi: 41 3
rd
and 4
th
from top
dECOi Architects: 12
Deutsche Steinzeug Cremer & Breuer: 101; 102;
104 1
st
from top
DieMount: 126 left 3
rd
from top, right 1
st
from top
Ewald Drken AG: 166 2
nd
and 3
rd
from top;
167 right 2
nd
from top
Dyesol: 144 1., 2
nd
and 3
rd
from top; 145; 147
EADS: 62
east Hamburg: 104 4
th
from top
Eike Becker Architekten: 78
E Ink / Citizen: 93 1
st
from top
E Ink / LG.Philips LCD: 93 2
nd
from top
E Ink / Polymer Vision: 93 3
rd
from top
E Ink / Toppan Printing: 95 right 1
st
from top
Emfit: 155 3rd from top; 158 1
st
and 2
nd
from top
EMPA: 66; 67; 68; 69
EnOcean: 158 3
rd
from top
EunSook Lee: 110 bottom; 117
European Bioplastics: 30 1
st
from above
(photo: Treofan), 2
nd
from above (photo: Novamont)
Felix Hess: 161
FerroTec: 152 3
rd
from top
Fludicon GmbH: 38 left 1
st
from top, right
Fraunhofer IAP: 83 (photos: Armin Okulla); 84
(photo: Armin Okulla); 138 (photo: Armin Okulla)
Fraunhofer ISE: 76 right; 77; 144 4
th
from top; 146
Fraunhofer TEG: 149 3
rd
from top
Freihofer: 29 left 2
nd
from top, right 1
st
and 2
nd
from
top
FZ Jlich: 155 1
st
from top
2006 G+B pronova: 32 right
Geohumus International: 185
Gesimat: 92 1
st
and 4
th
from top; 95 left 1
st
from top
GKD / ag4: 127 right
GlassX: 164 (photo: Gaston Wicky); 166 1
st
from top
(photo: GlassX); 168 (photo and graphics: GlassX);
171, 172 (photos: Gaston Wicky)
G. Rau: 53; p. 54; 55; 56; 61
Gruppe RE (Silke Warchold, Nicole Httner):
23 right (photos: Lucas Roth); 119 2
nd
and 3
rd
from
top (photos: Sabrina Rothe)
Grado Zero Espace: 17, 19 left 1
st
, 2
nd
and 4
th
from
top
Hannaliisa Hailahti: 124
hobby Das Magazin der Technik, No. 8, August 1957,
74, 75 and 77: 132 1
st
and 2
nd
from top
hobby Das Magazin der Technik, No. 11,
November 1958, 164: 153
Jaithan Kochar: 42 right 2
nd
and 3
rd
from top
James Robinson: 74 1
st
and 2
nd
from top; 75
KieranTimberlake Ass.: 140; 141
Knauf Gips: 177 right 2
nd
from top (photo:
Albert Weisflog); 181 (photos: Albert Weisflog)
J. Mayer H.: 72 (photo: Uwe Walter); 87
Juliet Quintero: 123
Kowa / Kirakira-Komichi: 120; 121 top
Kowa / Mamoru Nanba: 119 1
st
from top
LBL: 92 2
nd
and 3
rd
from top
LBM: 40
Lichtpapier (Anke Neumann): 114 1
st
and 2
nd
from top (photos: Anke Neumann); 121 2
nd
and
3
rd
from top (photos: Anke Neumann); 132 3
rd
and
4
th
from top
lif Germany: 127 left 3
rd
from top
Loop.pH (Rachel Wingfield, Mathias Gmachl):
133; 134
20042006 Lord Corp.: 38 left 2
nd
, 3
rd
and 4
th
from
top
2006 LUMINEX: 23 left
Merck: 31
2006 Messe Frankfurt Exhibition GmbH: 19 left
3
rd
from top (photo: Jean-Luc Valentin); 20 2
nd
from
top (photo: Jean-Luc Valentin)
2006 Michael Bleyenberg: 34; 35
Micropelt: 151; 152 1
st
from top
Minimax: 48 2
nd
and 3
rd
from top
Mirow Systemtechnik: 157
190 | sources
Mitchell Joachim: 11 right
Mitchell Joachim, Lara Greden, Whitney Jade Foutz, Wendy
Meguro, Luis Rafael Berrios-Negron: 142; 160
National Museum of Emerging Science and Innovation:
39
NAUE: 178 4
th
from top
2006 NO-CONTACT (Adam Whiton, Yolita Nugent):
19 right
Norbulb Sprinkler Elemente: 48
Novaled: 135 top; 136; 137 1st and 2nd from top;
139 2
nd
and 3
rd
from top
OKER-Chemie: 177 left 1
st
and 3
rd
from top, right 1
st
from top
2004 Olafur Eliasson: 33
Osram Opto Semiconductors: 126 left 1
st
2
nd
and 4
th
from top, right 2
nd
from top; 135 bottom; 137 3
rd
from
top; 139 1
st
from top
Permalight: 118 1
st
from top
Peter Linnett, Tobi Blunt: 51
Peter Marino Architects: 96 left; 97 right
Peter Yeadon: 42 left, right 1
st
from top
Philipps-Universitt / N. Hampp: 74 3
rd
and 4
th
from top;
76 left, 4
th
and 5
th
from top
PI Ceramic: 154; 155 2
nd
from top; 156
Prinz Optics: 32 left
Rascor International: 184
RC TRITEC: 111 top; 112; 118 2
nd
and 3
rd
from top
Rinspeed: 21 left 1
st
2
nd
and 3
rd
from top
RPM/Belgium N.V.: 176; 178 1
st
, 2
nd
and 3
rd
from top
R&Sie... (Franois Roche): 10
Ruth Handschin: 110 top; 114 3
rd
from top; 115; 122
SAM Span and Mayrhofer: 149 left, 1
st
and 2
nd
from
top, right 1
st
and 2
nd
from top; 152 4
th
from top
SCTB NORD: 152 2
nd
from top
SensiTile Systems: 37
SGG: 94; 95 left 2
nd
from top, right 2
nd
from top;
96 right; 97 left; 103
2006 Sharon M. Louden, courtesy of the Artist and
Oliver Kamm/5BE Gallery: 25
SHARP: 41 2
nd
from top
Sigmar Polke: 24; 86
Solitech Innovative Solartechnik: 127
Taiyo: 104 2
nd
and 3
rd
from top
Taiyo / Obayashi Corp.: 99 bottom; 105
Technische Universitt Berlin / G. Hauck: 80
Interactive Institute / Front design: 79
Interactive Institute: 22
UIUC: 28
wikimedia.org: 59; 98; 111 bottom; 150
Wrth Solar / Universitt der Knste Berlin:
41 1
st
from top
Yvonne Chan Vili: 65
Zigan Displays: 130
191 | sources