, 2010- 08- 25, 20( 4) : 43~ 45

CH IN A

EL A ST O M ERICS

SiO2

, *

( , 570228)

: KH - 560 SiO2 ,

, KH - 560 SiO 2 ,
, pH= 8~ 9, SiO2 1% ,
6 h , ( ) 0. 229 3%
: K H- 560; SiO 2 ; ;
: T Q 331. 2

: A

( NRL ) , ,
[ 1]

: 1005- 3174( 2010) 04- 0043- 03

; : , ;

: , ;

NRL ( WSP )

: , ; : ,

[ 2, 3]

, ( L PNRL)

; : ;

: ,

[ 4~ 6]

L PNRL

1. 2

, , ;
[ 7] ,

; DK- S24 :

L PNRL

; CS101- 1AB :

; - BS2235( 0. 001

, KH - 560 SiO 2

: AGT - 10 , ;

, ,

DGF30/ 14- BADC :

,
L PNRL

; JJ- 1 - :

; Spect rum one -

1. 1
-
( KH 560) : ,
; SiO 2 : ,
: 2010- 06- 27
: ( 1982- ) , , , ,

SH Z - DS :

~ 220 g) : ;

; F S- 150 :
: P er kin- Elm er ;
Avant iJ- 25 :

1. 3 KH- 560 SiO2

3. 0 g 24 h SiO 2 30
mL , 10 min, 1. 5 mL
KH 560, , 110

8 h,

SiO2 SiO2

44

20

, 75
, , [ 8]

SiO 2 ,

1. 4 SiO2

, ,

SiO 2 ,

3 340 cm

- 1

1 652 cm

- 1

OH

20 min, pH ,
, ,
0. 7% , [ 9]

1. 5
Spect rum o ne
SiO 2
, 4 cm - 1 , 4 000~ 500
cm - 1
/ cm - 1

a- ; b-
2 SiO2

2. 1
2. 1. 1 SiO2

2. 2 SiO2 NRL

1 SiO 2
- 1

1 , , 908. 23 cm
[ 10]

, 2 941
cm - 1 , 2 858 cm - 1
[ 11] , 3 400 cm - 1
- 1

1 640 cm
KH 560 SiO 2

2. 2. 1 SiO2
3 SiO2
3 : SiO 2
,
SiO 2 1%
, 0. 276 0% ;
SiO 2 1% ,
,

/ cm - 1
a- S iO2 ; b - S iO2
1 SiO2

w ( SiO 2 ) / %

2. 1. 2 SiO2

3 SiO2

2 SiO2
2 , SiO2
- 1

908 cm ,
1 577 cm
[ 10]

- 1

1 350 cm

- 1

2. 2. 2
4
4 , ,

, ,

6 h ,

NRL

0. 261 8%

, . SiO 2

45

KH 560 SiO2
,
, NRL SiO2
, NRL
pH = 8~ 9, SiO 2
1% , 6 h,
4

2. 2. 3 pH
[ 12] ,
pH , ,
5 pH
, , pH

0. 229 3%

. [ M ] . : , 1992. 6.

[ 2]

, .
[ J ] . , 1998, ( 1) : 69~ 72.

[ 3]

RR IM

A S TM [ J ] . , 2001, ( 2 ) : 35 ~
39.
[ 4]

. , [ J] .
, 1992, ( 3) : 51.

[ 5]

, pH ,

[ 1]

,
, pH 8~ 9 , ,
0. 229 3% ; pH ,

. [ J] . , 1984, ( 1) :
6.

[ 6]

. [ J] . , 1995,
( 3) : 391.

[ 7]

, .
[ J ] . , 2006, 16( 1) : 155.

[ 8]

, , .
[ J ] . ,
2007, 35( 1) : 31~ 36.

[ 9]

. [ M ] . :
, 1999. 12.

[ 10] , , , . [ M ] . :
, 2005. 441~ 450.
[ 11] .
[ J ] . , 2008, 12( 39) : 2 072~ 2 078.
5 pH

[ 12] , , , . [ M ] . :
, 1993. 324.

Surface epoxide modification of SiO2 and its application in protein

adsorption and separation of NR latex
WANG Jun, GU I H ong- xing
( S chool of Materi al s & Chemi cal E ngi neer ing , H ai kou Uni ver sit y , H aik ou 570228, China)
Abstract: U sing the surf aces of epo xide gro up KH - 560 t o t he surf ace modificat ion o f t he SiO2 ,
and t he ef fects o n t he nit rog en co nt ent of NR lat ex w ere also invest igat ed on t his paper. T he results
show ed t hat KH - 560 w as linked t o the surf ace of SiO2 by chem ical bond, and t he nit rog en cont ent of
NR lat ex w as reduced to 0. 229 3% by adding KH - 560 modif ied SiO 2 . When pH = 8~ 9, t he m odif ied
SiO 2 granule amount used is 1% , t he pro cess t ime is 6 hour, the nit rog en cont ent of r ubber lat ex w as
reduced to 0. 229 3% .
Key words: KH - 560; SiO 2 surf ace mo dification; natural rubber lat ex ; nitro gen co nt ent