TRNG THPT PHAN NH PHNG K THI CHN HC SINH GII CP TRNG

.. LP 12 THPT NM HC 2010-2011

Mn: HO HC
P N


CU 1: (2im)

2(2 ) 2(2 ) 164
4 4 2 2 52
23
2 1 7 2(2 1)
M M X X
M X M X
M M X X
M M X X
Z N Z N
Z Z N N
Z N Z N
Z N Z N
+ + + =

+ =

+ = + +

+ = + +

Gii ra ta c:

M
X
Z =19(K)
Z = 8(O)

1im



1im
CU 2: (3im)

C
2
H
5
OH C
4
H
6
(A) C
4
H
10
(B)
C
4
H
10
CH
4
(D) C
2
H
2
(E) C
6
H
6
C
6
H
5
Cl(G) C
6
H
5
ONa(H)
C
6
H
5
OH

C
4
H
10
C
3
H
6
(I) C
2
H
3
CH
2
Cl(K) C
2
H
3
CH
2
OH(L)
C
2
H
3
CHO(M) C
2
H
3
COOH (N) CH
2
=CHCOOCH
3
polime

C
3
H
6
CH
3
CH(OH)CH
3
CH
3
COCH
3


0,5 im

1im

1im


0,5 im
CU 3:(3im)
a. Fe
2
O
X
3
HNO
Fe(NO
3
)
3
+ NO +NO
2
Da vo bi tnh c n
NO
= n
NO
2
= 0,0625 mol
Fe Fe
+3
+3e N
+5
+3e NO
x mol 3xmol 0,1875 mol 0,0625 mol
O
2
+4e 2O
-2
N
+5
+e NO
2

y mol 4y mol 0,0625 mol 0,0625 mol
3x 4y = 0,25
56x + 32y = 10
x= 0,15 mol m
Fe(NO
3
)
3
=36,3g
b. 4Fe(NO
3
)
3
2Fe
2
O
3
+ 12NO
2
+ 3O
2

0,15 mol 0,45mol 0,1125 mol
4NO
2
+ O
2
+ 2H
2
O 4HNO
3

0,45 mol 0,45 mol
[H
+
] =0,1 M suy ra pH = 1

0,5 im

1,5im










1im



CU 4:(2im)

MCO
3
CO
2

n
Ba(OH)
2
=0,133 mol , n
NaOH
= 0,01 mol , n
BaCO
3
= 0,126 mol

TH1: OH
-
d CO
2
BaCO
3

0,126 0,126 mol
n
MCO
3
=0,126 M = 40 (Ca) CaCO
3

TH2: OH
-
phn ng ht
CO
2
+ Ba(OH)
2
BaCO
3

0,126 0,126 0,126 mol
2CO
2
+ Ba(OH)
2
Ba(HCO
3
)
2

0,014 0,007 mol


1 im




1 im




CO
2
+ KOH KHCO
3

0,01 0,01 mol
n
MCO
3
= n
CO
2
= 0,15 mol M =24(Mg) MgCO
3












CU 5: (2im)

A: CH
2
OH-CHO
B:CH
3
COOH
C:HCOOCH
3
Ptp:
CH
2
OH-CHO+NaCH
2
ONa-CHO+ H
2

CH
3
COOH+Na CH
3
COONa + H
2
CH
3
COOH + NaHCO
3
CH
3
COONa + CO
2
+ H
2
O
HCOOCH
3
+ NaOH
0
t
HCOONa +CH
3
OH
CU 6:(3im)
R(OH)
n
+ nNa R(ONa)
n
+
n
2
H
2
n 1
= n =1, R'OH
2 2

Cng thc ca este: R(COOR)
m

R(COOR)
m
+ mNaOH
0
t
R(COONa)
m
+ mROH
R(COONa)
m

2 3
m
Na CO
2


'
0,1
0, 05 0,1
m
R OH
n mol =
C 1mol ROH vo bnh Na lm tng ROgam
0,1mol ROH vo bnh Na lm tng 4,5gam
' 2 5
45 ' 29( )
R O
M R C H = =
' 2 5
45 ' 29( )
R O
M R C H = =
m
( OOH)
este 3 2 5
2, 5.46
2, axit : RCOOH
M 88,
R C
M
m
CH COOC H
<
<
=
(m=1)
CU 7:(2im)


2 2
2 .
4 8
0, 75
(14 2).0, 75 14 .0, 25 2.0, 25
46, 4
1, 25
4,
n n
n n pu
C H H
C H
n n xmol
n xmol
n x n x x
M
x
n C H
= =
=
+ + +
= =
=


2
2
2
128.98
200
62, 72
200 128 72
4
d sau
H O
H O
m gam
m gam
n mol
= =
= =
=


4 8 2
4 C H H O
xmol 4 xmol
2 2
H H O
xmol xmol
4x + x = 4 x = 0,8
1, 25 1, 25.0,8 1
22, 4
A
A
n x mol
V lit
= = =
=


CU 8:(3im)

M
A
= 64
CO
2
CaCO
3

0,4 0,4 mol
2CO
2
Ca(HCO
3
)
2

0,2 0,1 mol
n
CO
2
= 0,6 mol
m
CO
2
+ m
H
2
O
+ m
ddCa(OH)
2
= m
+
+ m
dd
mui
m
H
2
O
= 4,32g (0,24 mol)
C
x
H
y
O
z
xCO
2
+ y/2H
2
O
0,12 mol 0,12x 0,06y
X= 5 v y =4 z = 0
CTPT C
5
H
4

C
5
H
4
C
5
H
4-x
Ag
x

0,05 mol 0,05 mol
64 + 107x = 171 suy ra x = 1. Vy X c 1 lin kt 3 u mch
CTCT CHC-CC-CH
3

CHC-CH=C=CH
2