S 15

TRNG THPT CHUYN H TNH THI TH I HC CAO NG Mn thi : Ho Hc Thi gian lm bi : 90 pht ! "#$ t%&" nghi'm : 50 "#$ ( thi ") 4 t%ang M, -( thi:

H , t ! t"# $%!":***************+ 001 S& 'o ()!":*****************

C*+ 1, Ch. l$/ng 0h1 H2 -i 3$a 4565gam MO 7M l 0im l.8i9 n$ng n)ng th$ -:;" 426<gam h=n h;p >+ Ch. h=n h;p > tan h?t t%.ng @$ng @A"h HNOB @:6 CDn phEm 0hF th$ -:;" l 565< l1t 7-0t"9 h=n h;p 0h1 G7g/m NO H NO29+ TI 0h!i "Ja G C. HKi H2 l 4L+ Cng thM" ph#n tF "Ja MO l: A+ C$O+ N+ OPO+ C+ QnO+ R+ CD A6N6C -($ Cai+ C*+ -, Ch. a gam h=n h;p OP6C$ 7t%.ng -) C$ "hi?m 55S H( 0h!i l:;ng9 H. TUUml @@ HNOB6 -$n n)ng+ a$ 0hi phDn Mng VDW %a h.n t.n th$ -:;" 565< l1t 7-0t"9 0h1 NO7CDn phEm 0hF @$W nhXt96 "hXt %&n ") 0h!i l:;ng U642a gam H @$ng @A"h >+ GiY t%A "Ja a l: A+ 4T+ N+ 2U+ C+ 2T+ R+ BU+ C*+ ., HZa tan h.n t.n 4[65 gam h=n h;p Al6OP6C$ ") C! m.l b\ng nha$ t%.ng @$ng @A"h HNOB+ a$ 0hi 0?t th" phDn Mng th$ -:;" T6] l1t 7-0t"9 0h1 NO 7CDn phEm 0hF @$W nhXt9 H @$ng @A"h >+ ^m 0h @$ng @A"h > th$ -:;" m gam m$!i 0han+ GiY t%A "Ja m l: A+ ]B6L+ N+ ][+ C+ ]U6<+ R+ [U64+ C*+ 4, N$ng 4B6] gam h=n h;p Mg6 OP t%.ng 0hng 0h1 m_t thi gian th$ -:;" h=n h;p > g/m "Y" .Vit ") 0h!i l:;ng 4L62gam+ ` hZa tan h.n t.n > "an b ml @@ HCl 4M t!i thi`$ l: A+ <UUml+ N+ ]UUml+ C+ TUUml+ R+ [UUml+ C*+ 5, !t "hYW h.n t.n m gam h=n h;p 2 %:;$ -/ng -cng lidn ti?p th$ -:;" U6BB gam CO2 H U622T gam H2O+N?$ ti?n hnh Vi h.Y m gam h=n h;p t%dn b\ng C$O the 0h!i l:;ng an@Phit t8. thnh t!i -a l: A+ U64<Tg N+ U62UTg C+ U64LTg R+ U624Tg C*+ /, ! -/ng ph#n Mng HKi "ng thM" ph#n tF "Ja C2H2ClO l A+ 2 N+ B C+ T R+ 5 C*+ 0, Ch. B aVit: aVit f.mi"6 aVit aVPti" H aVit a"%Wli"+ ` nhgn bi?t B aVit nW ta @hng:

A+ @@ AgNOBi NHB6 n:K" b%.m+ N+ @@ AgNOBi NHB6 3$j t1m C+ Na6 n:K" b%.m R+ N:K" b%.m6 3$j t1m C*+ 1, Hi-%."a"b.n > ") "ng thM" ph#n tF C<H4U 0hng lm mXt m$ @@ b%.m+ khi -$n n)ng > t%.ng @@ th$!" t1m t8. thnh h;p "hXt C[HTkO2 7G9+ Ch. G tY" @lng HKi @@ aVit "l.hi-%i" t8. thnh h;p "hXt C[H]O2+ Tdn "Ja > l: A+ 46Bm-imPtWlbPnnPn+ N+ PtWlbPnnPn+ C+ 465m-imPtWlbPnnPn+ R+ 462m-imPtWlbPnnPn+ C*+ 9, khi Cl" 0h1 "l. H. n:K" the th$ -:;" n:K" "l.+ N:K" "l. l h=n h;p g/m "Y" "hXt: A+ Cl2 H H2O N+ Cl26 HCl6 H2O H HClO C+ HCl6 HClOB H H2O R+ HCl H HClO+ C*+ 10, Ch. ]6Tgam Qn H. 42Uml @@ HNOB 4M H H2 O5 U6TM th$ -:;" NO 7CDn phEm 0hF @$W nhXt9 H @$ng @A"h "hMa V gam m$!i+ a$ -) -Pm " "8n @$ng @A"h -:;" W gam m$!i 0han6 the A+ V o W+ N+ V p W+ C+ VqW+ R+ CD A6N6C -($ Cai+ C*+ 11, Chia m gam 4 PCtP r thnh 2 phan b\ng nha$ shan 4 -!t "hYW h.n t.n th$ -:;" 5+5< l1t 0h1 CO2 7@0t"9 H B+] gam H2O shan 2 tY" @lng Hta -J HKi 4UUml @@ NaOH U+TM+ GiY t%A "Ja m l A+ B+] N+ 5+5 C+ [+2 R+ <6< C*+ 1-, !t "hYW h.n t.n U64 m.l h=n h;p g/m PtilPn H an".l -un "hM" > th$ -:;" 565< l1t 0h1 CO2 H 56T gam n:K"+ > th$_" l.8i A+ n.6 -un "hM"6 m8"h hv+ N+ 0hng n.6 -un "hM"6 m8"h hv+ C+ n.6 -un "hM"6 m8"h HZng R+ 0hng n.6 -un "hM"6 m8"h HZng+
H SO 6 6t C*+ 1., Ch. "#n b\ng h)a hw" Ca$: CHBCOOH x C2HTOH CHBCOOC2HT x H2O Nhgn Vyt n. -ng H( "#n b\ng t%dnz A+ Dn phEm "Ja phDn Mng t%dn ") tdn l PtWl aVPti" N+ ` "#n b\ng t%dn VDW %a thP. "hi($ th$gn ") th` @hng @: aVit aVPti" h.{" an".l PtWli" C+ AVit H2 O5 "hI gi| Hai t%Z V" tY"+ R+ Nh)m OH "Ja an".l 0?t h;p HKi H "Ja aVit t8. %a n:K"+ C*+ 14, khi -$n n)ng an".l > n.6 -un "hM"+ m8"h hv HKi aVit H 2 O5 th$ -:;" "hXt h|$ "u G+ TI 0h!i hui "Ja > C. HKi G b\ng U6]2+ Cng thM" ph#n tF "Ja > l : A+ CH5O+ N+ C2H]O+ C+ CBH<O+ R+ C5H4UO+
2 5 U

C*+ 15, !t "hYW h.n t.n [62 gam m_t aVit "a"b.VWli" > m8"h thcng th$ -:;" 4B62 gam CO2 H B6] gam H2O+ Cng thM" ph#n tF "Ja > l: A+ C2H5O2+ N+ CBH]O2+ C+ C]H<O5+ R+ C]H42O2+ C*+ 1/, l" 0h1 CO2 H. @$ng @A"h nat%i phPn.lat ta thXW ") hi'n t:;ng: A + R$ng @A"h H}n t%.ng C$!t @. 0hng VDW %a phDn Mng+ N + R$ng @A"h h)a -l" @. phPn.l Cinh %a 1t tan t%.ng n:K"+ C + R$ng @A"h h)a -l" @. ") NaHCOB Cinh %a+ R + Ji bwt 0h1 @. phDn Mng ") Cinh %a 0h1+ C*+ 10, O Ch. Cu -/ "h$W`n h)a Ca$: Tdn "Ja > l: C2H5 > A+ an@Phit aVPti"+ N+ aVit O aVPti"+ C+ PtWlPn gli".l+ R+ aVit .Vali"+ C*+ 11, T%_n 2UU ml @$ng @A"h g/m HCl U64M H H2 O5 U6UT M HKi BUU ml @$ng @A"h Na7OH92 a M th$ -:;" m gam 0?t tJa H TUU ml @$ng @A"h ") pHq4B+ CY" giY t%A a6 m t:ung Mng l: A+ U62T H 56]] N+ U64T H 26BB C+ U64T H B65LT R+ U62 H 26BB C*+ 19, ChXt >: C2H[NO2+ A tY" @lng HKi @$ng @A"h HCl H @$ng @A"h NaOH+ > th$_" l.8i h;p "hXt A+ M$!i N+ Amin.aVit C+ CD A H N R+ TXt "D -($ sai Cu 7 NO 9 NaOH NaOH > + G + Q+ C*+ -0, Ch. Cu -/ phDn Mng Ca$: H2 + >6 G6 Q l "Y" h;p "hXt "hMa l:$ h$jnh+ >6G6Q l : A+ Na2 6 NaH 6 C$ 2+ N+ Na2 6 NaH 6 C$ + C+ NaH 6 Na2 6 C$ + R+ NaH 6 Na2 6 C$ 2+ HO + C*+ -1, Ch. Cu -/ phDn Mng Ca$: > H2 > l: A+ Na2 + N+ Ca + C+ Na2 2OB+ R+ Al2 B+ C*+ --, Ch. @$ng @A"h > "hMa U64 m.l OPCl26 U62 m.l OP O5+ Th` t1"h @$ng @A"h kMnO5 U6<M t%.ng H2 O5 l.,ng Hta -J -` .Vi h)a h?t "Y" "hXt t%.ng > l: A+ U6U[T l1t+ N+ U642T l1t+ C+ U6B l1t+ R+ U6UB l1t+ C*+ -., ` 0?t tJa h.n t.n hi@%.Vit ") t%.ng @$ng @A"h A "hMa U64 m.l OP O5 H U64 m.l C$Cl2 "an b ml @$ng @A"h Na7OH92 U64M x NaOH U62M th$ -:;" 0?t
B 2 2

tJa N+ N$ng N v nhi't -_ "a. -?n 0h!i l:;ng 0hng -~i the th$ -:;" "hXt %&n ") 0h!i l:;ng l: A+ 4T62 gam+ N+ BL6B gam+ C+ 4]6U gam+ R+ B<6T gam+ C*+ -4, Ni?t %\ng T6]]<gam "a. C$ N$nam phDn Mng Hta h?t HKi B65]2gam N%.m t%.ng @$ng mi CCl5+ TI l' C! m&t V1"h b$ta-iPn : Cti%Pn t%.ng "a. C$ N$nam l: A+ 4:2+ N+ 2:4+ C+ 2:B+ R+ 4:B+ C*+ -5, Hai hi-%."a"b.n >6G ") "hng "ng thM" ph#n tF CTH<+ > l m.n.mP @hng -` -i($ "h? "a.C$6 G ") m8"h "a"b.n ph#n nhYnh H tY" @lng HKi @@ AgNOB t%.ng NHB t8. 0?t tJa m$ Hng nh8t+ Tdn gwi "Ja >6G lan l:;t l: A+ iC.p%Pn H 2mmPtWlb$tinmB+ N+ iC.p%Pn H BmmPtWlb$tinm4+ C+ 2mmPtWlb$ta-iPnm46B H 2mmPtWlb$tinmB+ R+ iC.pPntan H BmmPtWlb$tinm4+ C*+ -/, Ch. h=n h;p g/m ]65gam C$ H T6]gam OP H. "!" -ng @$ng @A"h HCl l.,ng @:+ ` tY" @lng h?t HKi "Y" "hXt ") t%.ng "!" Ca$ phDn Mng HKi @$ng @A"h HCl 7CDn phEm 0hF @$W nhXt l NO96 "an 1t nhXt 0h!i l:;ng NaNOB l A+ <6Tgam+ N+ 4[gam+ C+ T6[gam+ R+ 26<gam+ C*+ -0, Ch. 4<6B2 gam aVit pi"%i" H. m_t benh -ng b\ng gang ") @$ng t1"h 0hng -~i T]U"mB70hng ") 0hng 0h196 %/i g#W n~ v 4L44UC+ p C$Xt t%.ng benh t8i nhi't -_ -) l s atm6 bi?t %\ng CDn phEm n~ l h=n h;p CO6 CO26 N26 H2 H Yp C$Xt th" t? nh hun Yp C$Xt l th$W?t <S+ s ") giY t%A l A+ 2U[6B]T+ N+ 2446L]<+ C+ 2U46UUU+ R+ 22B6]BT+ C*+ -1, Th" hi'n phDn Mng PCtP h)a gi|a %:;$ b$tant%i.l 46265 H h=n h;p 2 aVit CHBCOOH H HCOOH the th$ -:;" t!i -a @}n V$Xt "hI "hMa "hM" PCtP l A+ T N+ ] C+ [ R+ < C*+ -9, ChXt n. Ca$ -#W 0hi phDn Mng HKi H2O 0hng t8. %:;$ PtWli" A+ C2HTONa+ N+ C2H5+ C+ CHBCOOC2HT+ R+ C2H2+ x x m C*+ .0, R$ng @A"h A "hMa a m.l Na 6 bm.l NH5 6 " m.l HCOB 6 @ m.l COB2m6 P m.l O52m+ Thdm @an @an @$ng @A"h Na7OH92 f M -?n 0hi 0?t tJa -8t giY t%A lKn nhXt the @hng h?t b ml @@ Na7OH92+ C "8n @$ng @A"h Ca$ 0hi "h. b ml @@ Na7OH92 t%dn the th$ -:;" C! gam "hXt %&n l: A+ BTb gam+ N+ 5Ua gam+ C+ 2Ua gam+ R+ "D A6N6C -($ Cai+ C*+ .1, Ch. 4 m.l kOH H. @@ "hMa m gam HNOB H U62 m.l Al7NOB9B+ ` th$ -:;" [6< gam 0?t tJa the giY t%A "Ja m l: A+ 4<6Lgam+ N+ 4L6<gam+ C+ 4<6L gam h.{" 5564 gam+ R+ 4L6<gam h.{" 5564gam+ C*+ .-, OVi h)a 56] gam h=n h;p hai %:;$ n. -un "hM" m8"h hv thnh an@Phit the @hng h?t < gam C$O+ Ch. t.n b_ an@Phit tY" @lng HKi Ag2OiNHB @: th$ -:;"

B265 gam Ag 7hi'$ C$Xt phDn Mng l 4UUS9+ Cng thM" "Ja hai %:;$ l: A+ CHBOH H C2HTOH+ N+ C2HTOH H CHBCH2CH2OH+ C+ CBH[CH2OH H C5HLCH2OH+ R+ CHBOH H C2HTCH2OH C*+ .., R$ng @A"h A "hMa U6U2m.l OP7NOB9B H U6Bm.l HCl ") 0hD nng hZa tan -:;" C$ HKi 0h!i l:;ng t!i -a l: A+ [62Ugam+ N+ ]65Ugam+ C+ T6[]gam+ R+ [6<5gam+ C*+ .4, M_t h=n h;p > g/m Cl2 H O2+ > phDn Mng Hta h?t HKi L6]gam Mg H 4]62 gam Al t8. %a [564 gam h=n h;p m$!i Cl.%$a H .Vit+ Thnh phan S thP. th` t1"h "Ja Cl2 t%.ng > l A+ TUS+ N+ TT6T]S+ C+ ]]6][S+ R+ 55655S+ C*+ .5, N$ng n)ng h=n h;p g/m U6Tm.l N2 H 46Tm.l H2 t%.ng benh 01n 7") V" tY"9 %/i -:a H( nhi't -_ tUC thXW Yp C$Xt t%.ng benh l" nW l s4+ a$ -) "h. m_t l:;ng @: H2 O5 -{" H. benh 7nhi't -_ l" nW t%.ng benh l tUC9 -?n 0hi Yp C$Xt ~n -Anh the thXW Yp C$Xt t%.ng benh l" nW l s2 7s4 q 46[Ts29+ Hi'$ C$Xt t~ng h;p NHB l: A+ ]TS+ N+ [US+ C+ TUS+ R+ ]US+ C*+ ./, M_t h=n h;p > g/m hai "hXt h|$ "u+ > phDn Mng Hta -J HKi 2UUml @@ kOH TM Ca$ phDn Mng th$ -:;" h=n h;p hai m$!i "Ja hai aVit n. -un "hM" H m_t %:;$ n. -un "hM" G+ Ch. G tY" @lng HKi Na @: th$ -:;" ]6[2 l1t H2 v -0t"+ Hai "hXt h|$ "u t%.ng > l A+ m_t aVit H m_t %:;$+ N+ hai PCtP+ C+ m_t PCtP H m_t %:;$+ R+ m_t aVit H m_t PCtP+ C*+ .0, HXp thl 565< l1t 7-0t"9 0h1 CO2 H. U6T l1t @$ng @A"h NaOH U65M H kOH U62M the th$ -:;" @@ >+ Ch. > tY" @lng HKi U6T l1t @@ G g/m NaCl2 U6BM H Na7OH92 U6U2TM+ k?t tJa th$ -:;" l A+ 4L6[UU gam+ N+ BL65UU gam+ C+ 256]2Tgam+ R+ B26U4Bgam+ C*+ .1, Ch. b_t Ag ") l}n OP H C$+ ` tY"h Ag tinh 0hi?t 7") 0h!i l:;ng 0hng thaW -~i C. HKi ban -a$9 %a 0hi h=n h;p ban -a$ the "an @hng @$ng @A"h l: A+ HNOB @: N+ H2 O5 -{"6 @:+ C+ AgNOB @:+ R+ OPClB @: C*+ .9, M_t PCtP t!i -a ba "hM" -:;" t8. %a tt m_t aVit H %:;$ -un "hM"+ khi thJW ph#n PCtP nW th$ -:;" 4625 gam h=n h;p hai %:;$ -/ng -cng+ khi h)a hui 4625 gam h=n h;p hai %:;$ the th` t1"h th$ -:;" b\ng th` t1"h "Ja U6L] gam O2 v "hng -i($ 0i'n+ Hai %:;$ t%.ng h=n h;p l: A+ ") th` l CHBOH H C2HTOH h.{" CHBOH H CBH[OH+ N+ ChI ") l CHBOH H C2HTOH+ C+ ") th` l CHBOH H C2HTOH h.{" C2HTOH H CBH[OH+ R+ ChI ") l CHBOH H CBH[OH+ C*+ 40, HZa tan h.n t.n 24 gam h=n h;p hai 0im l.8i 7Al H m_t 0im l.8i

0i(m M9 H. n:K" @: the th$ -:;" @@ N H 4462 l1t 0h1 H2 v -0t"+ Ch. tt tt @@ HCl H. @@ N thXW th$ -:;" 0?t tJa lKn nhXt l 4T6]gam+ kim l.8i M l: A+ Na+ N+ ^i+ C+ CC+ R+ k+ C*+ 41, HZa tan h?t U6Bm.l OP b\ng m_t l:;ng @@ HNOB th$ -:;" b l1t 0h1 NO l CDn phEm 0hF @$W nhXt v -0t"+ b ") giY t%A nh nhXt l: A+ 4B655+ N+ 565<+ C+ <6L]+ R+ ]6[2+ C*+ 4-, Ch. b!n "hXt >6G6Q6T ") "ng thM" l C2H2On 7n U9+ >6 G6 Q -($ tY" @lng -:;" @@ AgNOBiNHB Q6 T tY" @lng -:;" HKi NaOH > tY" @lng -:;" H2O+ >6 G6 Q6 T t:ung Mng l A+ HOOCmCOOH CHCH OHCmCOOH OHCmCHO+ N+ OHCmCHO CHCH OHCmCOOH HOOCmCOOH+ C+ OHCmCOOH HOOCmCOOH CHCH OHCmCHO+ R+ CHCH OHCmCHO OHCmCOOH HOOCmCOOH+ C*+ 4., M_t h=n h;p > g/m m_t Hi@%."a"b.n m8"h hv 7A9 ") hai lidn 0?t t%.ng ph#n tF H H2 ") tI 0h!i C. HKi H2 b\ng 56<+ N$ng n)ng > HKi V" tY" Ni -` phDn Mng VDW %a h.n t.n ta th$ -:;" h=n h;p G ") tI 0h!i C. HKi H2 b\ng <+ Cng thM" H thnh phan S thP. th` t1"h "Ja 7A9 t%.ng > l A+ CBH5 <US+ N+ CBH5 2US+ C+ C2H2 2US+ R+ C2H2<US+ C*+ 44, Ch. "Y" "hXt Ca$: H2NmCH2COOCHB Al7OH9B H2NCH2COOH 7NH592COB+ ChXt khng phDi l "hXt l:ng t1nh l: A+ 7NH592COB+ N+ H2NCH2COOH+ C+ Al7OH9B+ R+ H2Nm CH2COOCHB+ C*+ 45, Ch. "Y" @$ng @A"h Ca$: 749: @@ C]HTNH2 729: @@ CHBNH2 7B9: @@ H2NmCH2COOH 759: @@ C]HTONa 7T9: @@ Na2COB 7]9: @@ NH5Cl+ R$ng @A"h lm Vanh 3$j t1m l: A+ 729 7T9+ N+ 7B9 759 7]9+ C+ 729 759 7T9+ R+ 749 729 759 7T9+ C*+ 4/, M_t aVit ") "ng thM" -un giDn nhXt C2HBO2 the ") "ng thM" ph#n tF l: A+ C2HBO2+ N+ C5H]O5+ C+ C]HLO]+ R+ C<H42O< C*+ 40, > l "hXt lng 0hng m$6 0hng lm -~i m$ "hXt "hI thA phPn.lphtalPin+ > tY" @lng -:;" HKi @@ Na2COB6 @@ NaOH H @@ AgNOBiNHB+ > ") "ng thM" "X$ t8. l: A+ HCHO+ N+ HCOOCHB+ C+ CHBCOOH+ R+ HCOOH+ C*+ 41, Gi|a a""a%.nu H gl$".nu ") -{" -i`m gi!ng nha$ l: A+ ($ -:;" lXW tt "J "Di -:ng+ N+ ($ ") t%.ng bi't @:;" h$W?t thanh ngwt C+ ($ bA .Vi h)a bvi @@ Ag2OiNHB+ R+ ($ hZa tan C$7OH92 v nhi't -_

th:ng "h. @@ m$ Vanh lam+ C*+ 49, Ch. "Y" "hXt Ca$: CHBCOOH6 CH2qCHCOOH6 CH2qCHOOCCHB6 CH2OHmCH2OH6 CHClB6 HOOC7CH295COOH6 HCHO+ ! "hXt ") th` t8. thnh p.limP b\ng phDn Mng t%hng h;p h.{" t%hng ng:ng l: A+ [+ N+ ]+ C+ T+ R+ 5+ C*+ 50, ` ph#n bi't "Y" "hXt %&n %idng bi't Ca$: OP 6 OP 26 OPCOB6 OP2OB ta ") th` @hng: A+ @@ HNOB+ N+ @@ H2 O5 -{" n)ng+ C+ @@ HCl+ R+ @@ NaOH+