S GD T NGH AN

TRNG THPT QUNH LU 1

M thi 132

KIM TRA CHT LNG N THI I HC - LN 1 - 2011

MN HO HC
Thi gian lm bi: 90 pht; 60+10+10 cu trc nghim

PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)

Cu 1: un 12,00 gam axit axetic vi 13,80 gam ancol etylic (c axit H2SO4 c lm xc tc). n khi phn
ng dng li thu c 11,00 gam este. Hiu sut ca phn ng este ho l :
A. 60,0%.
B. 62,5%.
C. 75,0%.
D. 41,67%.
Cu 2: Cho s chuyn ho :
H 2O ,H 2 SO4 dd

Br2

+ H 2O / OH

+ CuO / t 0

X3
ixeton
(X) C4H10O X1 X2
Cng thc cu to ca X c th l:
A. CH3CH(CH3)CH2OH
B. CH3C(CH3)2OH
C. CH3CH(OH)CH2CH3
D. CH2(OH)CH2CH2CH3
Cu 3: Ly 12 gam hn hp 2 mui sunfat ca kim loi kim M v kim loi kim th N (M,N thuc 2 chu k lin
tip nhau) tc dng vi dung dch BaCl2 d thu c 23,3 gam kt ta. M c th l?
A. Li hoc Na.
B. K.
C. Na hoc K.
D. Na.
Cu 4: Hp th hon ton V lt CO2 (ktc) vo 400ml dung dch NaOH a M th thu c dng dch X. Cho t t
v khuy u 150ml dung dch HCl 1M vo X thu c dung dch Y v 2,24 lt kh (ktc). Cho Y tc dng vi
Ca(OH)2 d xut hin 15 gam kt ta. Xc nh a?
A. 1M.
B. 1,5M.
C. 0,75M.
D. 2M.
Cu 5: Cho dy chuyn ha:

CH3COONa

T
H2SO, 180oC

+ NaOH, CaO, t

1500oC

+ H2O

Pht biu no sau y l ng ?

+ H2

N Pd/PbCO O
3
+ H2O

+ KOH/C2H5OH, t

A. X l CaC2
C. Z l CH3CH2Cl

B. Y l CH3CH2OH
D. T l Al4C3

Cu 6: t chy hon ton 13,4 gam hp cht hu c X bng khng kh va (cha 80% N2 v 20% O2 v
th tch), thu c 22 gam CO2, 12,6 gam H2O v 69,44 lt N2 (ktc). Xc inh CTPT ca X bit CTPT trng
vi CTGN.
B. C5H14O2N
C. C5H14ON2
D. C5H14O2N2
A. A. C5H14N2
Cu 7: Hn hp X gm 2 axit no X1 v X2. t chy hon ton 0,3 mol X thu c 11,2 lt kh CO2 (ktc).
trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. Cng thc cu to ca 2 axit l:
A. HCOOH v HOOC-COOH
B. CH3COOH v C2H5COOH
3
2
C. CH COOH v HOOCCH COOH
D.HCOOH v C2H5COOH
Cu 8: Ly 1 mu Al d cho vo dung dch NaOH v NaNO3 c nng bng nhau, khi phn ng hon ton
th thu c dung dch X v hn hp kh gm H2 v NH3. Trong X cha nhng ion no?
B. Na+, AlO2-, OH-.
C. Na+, AlO2-, NO3-.
D. Na+, Al3+, NH4+.
A. Na+, Al3+, NO3-.
Cu 9: Ly m gam K cho tc dng vi 500ml dung dch HNO3 thu c dung dch M v thot ra 0,336 lt hn
hp N (ktc) gm 2 kh X v Y. Cho thm vo M dung dch KOH d th thy thot ra 0,224 lt kh Y. Bit rng
qu trnh kh HNO3 ch to mt sn phm duy nht. Xc nh m?
A. 3,12 gam.
B. 7,8 gam.
C. 12,48 gam.
D. 6,63 gam.
Cu 10: Cho 1,52g hn hp hai amin n chc no X, Y (c trn vi s mol bng nhau) tc dng va vi
200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc?
A. Tn gi 2 amin l imetylamin v etylamin
B. Nng dung dch HCl bng 0,2 (M).
C. S mol mi cht l 0,02 mol
D. Cng thc ca amin l CH5N v C2H7N
Cu 11: Cho 1,76 gam mt este ca axit cacboxylic no, n chc v mt ru no n chc phn ng va
ht vi 40ml dung dch NaOH 0,50M thu c cht X v cht Y. t chy hon ton 1,20 gam cht Y cho
2,64gam CO2 v 1,44 gam nc. Cng thc cu to ca este l :
C. HCOOCH2CH2CH3
D. .CH3COOCH2CH2CH3
A. CH3CH2COOCH3 B. CH3COO-CH3
Cu 12: Khi vt bng gang, thp b n mn in ho trong khng kh m, nhn nh no sau y ng?
A. Tinh th cacbon l catot, xy ra qu trnh oxi ho.
B. Tinh th st l anot, xy ra qu trnh oxi ho.
C. Tinh th cacbon l anot, xy ra qu trnh oxi ho.
D. Tinh th st l anot, xy ra qu trnh kh.
Cu 13: Cho Cu (d) tc dng vi dung dch Fe(NO3)3 c dung dch X. Cho AgNO3 d tc dng vi X c
dung dch Y. Cho Fe (d) tc dng vi Y c hn hp kim loi Z. S phng trnh phn ng xy ra l?
A. 5.
B. 6.
C. 4.
D. 7.

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Cu 14: Cn trn dung dch X cha HCl 0,1M v H2SO4 0,1M vi dung dch Y cha NaOH 0,3M v Ba(OH)2
0,1M theo t l th tch nh th no thu c dung dch c pH = 13.
A. VA/VB = 1/3.
B. VA/VB = 1/2.
C. VA/VB = 2/1.
D. VA/VB = 1/1.
Cu 15: Cho dung dch NaOH d vo 100 ml dung dch X cha ng thi Ba(HCO3)2 0,5M v BaCl2 0,4M th
thu c m gam kt ta. Gi tr ca m l?
A. 9,85.
B. 19,7.
C. 14,775.
D. 17,73.
Cu 16: Hn hp X gm mt s hirocacbon l l ng dng k tip c tng khi lng phn t l 252, trong
khi lng phn t ca hirocacbon nng nht c khi lng phn t nng gp 2 ln khi lng phn t
ca hirocacbon nh nht. Cng thc phn t ca hirocacbon nh nht trong X l
B. C3H8.
C. C2H6.
D. C3H6.
A. C2H2.
Cu 17: Khi tng p sut chung ca h phn ng, cn bng no sau y khng thay i?
A. 2CO(k) +O2(k)
2CO2(k)
B. H2(k) + I2(k)
2HI(k)
C. N2(k) +3H2(k)
2NH3(k)
D. 2SO2(k) + O2(k)
2SO3(k)
Cu 18: Cc cht ha c n chc Z1,Z2,Z3 c CTPT tng ng l CH2O, CH2O2, C2H4O2 . Chng thuc cc
dy ng dng khc nhau. Cng thc cu to ca Z3 l
A. HCOOCH3
B. CH3-O-CHO
C. HO-CH2-CHO
D. CH3COOCH3
Cu 19: Cho mt hn hp X cha NH3, C6H5NH2 v C6H5OH. X c trung ho bi 0,02 mol NaOH hoc 0,01
mol HCl. X cng phn ng va vi 0,075 mol Br2 to kt ta. Lng cc cht NH3,C6H5NH2 v C6H5OH ln
lt bng
A. 0,005 mol ; 0,02 mol v 0,005 mol
B. 0,01mol ; 0,005 mol v 0,02 mol
C. 0,01 mol ; 0,005 mol v 0,02 mol
D. 0,005mol ; 0,005 mol v 0,02 mol
Cu 20: Cho 2,5 (kg) glucoz cha 20% tp cht ln men thnh ru etylic. Trong qu trnh ch bin ru b
hao ht mt 10%. Khi lng ru thu c l
A. 920 (g)
B. 92,5 (g)
C. 925 (g)
D. 92 (g)
Cu 21: Chiu tng dn tnh baz ca dy cht sau C6H5OH, C6H5NH2, NH2CH3, NaOH l:
A. C6H5NH2, C6H5OH, NH2CH3, NaOH
B. NH2CH3,C6H5OH, C6H5NH2, NaOH
C. C6H5OH, NH2CH3, C6H5NH2, NaOH
D. C6H5OH, C6H5NH2, NH2CH3, NaOH
Cu 22: Polime no di y c cng cu trc mch polime vi nha bakelit?
A. xenluloz
B. amiloz
C. cao su lu ha
D. Glicogen
Cu 23: Dung dch cha cc ion Na+, Ca2+, Mg2+, Ba2+, H+, Cl. Phi dng dung dch cht no sau y loi
b ht cc ion Ca2+, Mg2+, Ba2+, H+ ra khi dung dch ban u?
A. Na2SO4.
B. K2CO3.
C. NaOH.
D. AgNO3.
Cu 24: Cho cc cht: Na2SO3, CaSO3, Na2S, Fe(HCO3)2, NaHSO3, FeS. C bao nhiu cht khi tc dng vi
H2SO4 c nng c th to kh SO2?
A. 4.
B. 6.
C. 3.
D. 5.
Cu 25: Mt nguyn t X c tng s ht l 76. Trong X, s ht mang in nhiu hn s ht khng mang in
l 20. trng thi c bn, X c s electron c thn l?
A. 4.
B. 5.
C. 3.
D. 6.
Cu 26: Cho cc nguyn t sau: 13X, 19Y v 20Z. S sp xp ng vi tnh baz gim dn ca cc hiroxit l?
A. X(OH)3 > Z(OH)2 > YOH.
B. YOH > Z(OH)2 > X(OH)3.
D. Z(OH)2 > YOH > X(OH)3.
C. Z(OH)2 > X(OH)3 > Y(OH)2.
Cu 27: T toluen v cc cht phn ng trong mi th nghim l HNO3/H2SO4 (1); Br2/Fe, to (2), KMnO4/H2SO4
(3), ngi ta c th iu ch c axit 2-brom-4-nitrobenzoic. Th t tin hnh cc phn ng l
A. (1), (2), (3).
B. (3), (1), (2).
C. (3), (2), (1).
D. (2), (1), (3).
Cu 28: Ha tan hon ton hn hp X gm 0,11 mol Al v 0,15 mol Cu vo dung dch HNO3 th thu c
1,568 lt (ktc) hn hp Y gm 2 kh (trong c 1 kh khng mu ha nu ngoi khng kh) v dung dch Z
cha 2 mui. Xc nh s mol HNO3 tham gia phn ng
A. 0,63 mol.
B. 0,7 mol.
C. 0,77 mol.
D. 0,76 mol.
Cu 29: Dy cc kim loi iu ch c bng phng php thu luyn l?
A. Ag, Ba, Ca, Zn
B. Ag, Cu, Fe, Ni
C. Ag, Al, Cu, Ba
D. Ba, Ca, Na , Mg
Cu 30: Cho 0,2 mol Zn vo dung dch X gm: 0,2 mol Fe(NO3)3, 0,1mol Cu(NO3)2, 0,1 mol AgNO3. Khi lng
cht rn thu c sau khi phn ng kt thc l
A. 14 gam.
B. 16,4 gam.
C. 10,8 gam.
D. 17,2 gam.
Cu 31: Cho dy bin ho sau, bit A l 1 anhit a chc, mch thng v Y l ru (ancol) bc 2:
C4H6O2 + O2 C4H6O4 + X C7H12O4 + Y C10H18O4 + H2O B + X + Y
H2SO4
H2SO4
H+
xt

(A)

Tn gi ca X l
A. propenol.

(B)

B. propinol.

C. propan-2-ol.

D. propan-1-ol.

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Cu 32: em t chy 0,1mol hai ru no n chc, l ng ng lin tip. Dn ton b sn phm qua 1,0lit
dung dch Ba(OH)2 0,3M thu c 53,19gam kt ta trng v dung dch X. Bit X c kh nng lm
phenolphtalein chuyn mu. Vy hai ru trn c s nguyn t ccbon l:
A. 4 v 5
B. 2 v 3
C. 1 v 2
D. 3 v 4
Cu 33: in phn c mng ngn dung dch NaCl (dung dch X) th thu c dung dch X. in phn c
mng ngn dung dch Na2SO4 (dung dch Y) th thu c dung dch Y. Kt lun no sau y ng?
A. pH(X) >pH(X) v pH(Y)>pH(Y).
B. pH(X) >pH(X) v pH(Y)=pH(Y).
C. pH(X) <pH(X) v pH(Y)=pH(Y).
D. pH(X) <pH(X) v pH(Y)<pH(Y).
Cu 34: Ly 19,2 gam Cu v m gam Fe(NO3)2 cho vo 2 lt dung dch H2SO4 long aM khuy u thy to ra
sn phm kh NO duy nht v dung dch X ch cha 2 mui. Xc nh m v a?
A. 18 gam v 0,2 M.
B. 18 gam v 0,2M hoc 21,6 gam v 0,24M.
C. 21,6 gam v 0,24M.
D. 18 gam v 0,24M hoc 27 gam v 0,28M.
Cu 35: Cho hai mui X, Y tho mn iu kin sau:

khng xy ra phn ng.

X+Y

khng xy ra phn ng.

X + Cu

khng xy ra phn ng.

xy ra phn ng.
X + Y + Cu
Y + Cu
X v Y l mui no di y?
A. Mg(NO3)2 v KNO3.
B. NaNO3 v NaHSO4. C. Fe(NO3)3 v NaHSO4.
D. NaNO3 v NaHCO3.
Cu 36: Cho s sau:
o
CH2=CH2 + X p, t Y H2 o
Ni, t
X v Y ln lt l
A. etilen v xiclohexen.
B. axetilen v xiclohexin.
C. buta-1,3-ien v xiclohexen.
D. buta-1,3-ien v xiclohexin.
Cu 37: Dy sp xp cc dung dch long c cng nng mol/lt theo th t pH tng dn l?
A. KHSO4, HF, H2SO4, Na2CO3.
B. H2SO4, HF, KHSO4, Na2CO3.
D. HF, H2SO4, Na2CO3, KHSO4.
C. H2SO4, KHSO4, HF, Na2CO3.
Cu 38: Cho s phn ng sau:
dd Br 2

KOH / Ancol

Y
Z
T
Anilin.
C2H4 X
Tn gi ca Y v Z tng ng l
A. axetilen v benzen.
B. etylenglycol v nitrobenzen.
C. etylenglycol v axetilen.
D. benzen v nitrobenzen.
Cu 39: Nhm cht ch c tnh oxi ho l
A. CO2; CuO; O2.
B. Fe2O3; HNO3; SO2.
C. S, Fe2(SO4)3, SO2. D. CuSO4; HNO3; HCl.
Cu 40: Dung dch cha 12,2 gam cht ng ng ca phenol n chc tc dng vi nc brom (d) thu
c 35,9gam hp cht cha ba nguyn t brom trong phn t. Gi thit phn ng hon ton, cng thc
phn t cht ng ng l :
A. (CH3)2C6H3-OH.
B. CH3 -C6H4-OH.
C. C6H5-CH2-OH.
D. C3H7-C6H4-OH.

PHN RING: Hc sinh chn mt trong 2 phn sau

Phn I. Theo chng trnh chun ( t cu 41 n cu 50)
Cu 41: Cho hn hp gm cc kim loi M, X vo dung dch cha Cu(NO3)2 khuy u cho cc phn ng xy
ra hon ton thu c kt ta gm 2 kim loi l M, Cu v dung dch cha 2 mui M(NO3)2 v X(NO3)2. Th t
sp xp theo chiu tng dn tnh kh ca cc kim loi l
A. X, Cu, M.
B. Cu, X, M.
C. Cu, M, X.
D. M, Cu, X.
Cu 42: Khi bo qun dung dch FeSO4 trong phng th nghim, ngi ta ngm vo dung dch mt inh st
sch ?
A. Fe kh mui st (III) thnh mui st (II).
B. Fe tc dng vi cc tp cht trong dung dch.
C. Fe tc dng ht kh O2 ha tan trong dung dch mui.
D. Fe tc dng vi dung dch H2S trong khng kh.
Cu 43: Cho hn hp gm 0,1 mol HCOOH v 0,2 mol HCHO tc dng ht vi dung dch AgNO3 trong NH3 th
khi lng Ag thu c l bao nhiu?
A. 64,8 gam
B. 10,8 gam
C. 216 gam
D. 108 gam
Cu 44: Cho 10,4 gam hn hp Mg, Co, Al vo cc ng 600 ml dung dch HCl 1M (va ). Sau khi phn
ng kt thc, thm dn dung dch NaOH vo cc kt ta ln nht. Lc kt ta v nung nng nhit cao
n khi lng khng i c m gam cht rn. Gi tr ca m l?
A. 15,2.
B. 13,2.
C. 20,6.
D. 18,1.
Cu 45: Trong bnh kn cha 0,5 mol CO v m gam Fe3O4. un nng bnh cho ti khi phn ng xy ra hon
ton thy kh trong bnh c t khi so vi kh CO lc u l 1,457. Gi tr ca m l?
A. 21,5.
B. 23,2.
C. 16,8.
D. 22,8.
Cu 46: Cho -amino axit mch thng X c cng thc H2NR(COOH)2 phn ng va vi 0,1 mol NaOH to
9,55 gam mui. X l:
A. axit 2-aminobutanioic
B. axit 2-aminopropanioic
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C. axit 2-aminohexanioic
D. axit 2-aminopentanioic
Cu 47: Khi in phn dung dch hn hp MgCl2, FeCl3, CuCl2 th th t b kh ti catt l?
A. Fe3+, Cu2+, Fe2+, Mg2+
B. Cu2+, Fe3+, Mg2+, H2O
3+
2+
2+
C. Fe , Cu , Fe , H2O
D. Fe3+, Cu2+, Mg2+, H2O
Cu 48: Mt cacbohirat (Z) c cc phn ng din ra theo s chuyn ha sau:
t0

Cu(OH) 2 /NaOH

kt ta gch.
Z dung dch xanh lam
Vy Z khng th l
A. Fructoz.
B. Glucoz.
C. Saccaroz.
D. mantoz
Cu 49: Thy phn este E c cng thc phn t C4H8O2 (c mt H2SO4 long) thu c hai sn phm hu c
X, Y (ch cha cc nguyn t C, H, O). T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn
gi ca X l
A. etyl axetat
B. ancol etylic.
C. axit fomic.
D. axit axetic.
Cu 50: Khi chun 25,0g huyt tng mu ca mt ngi li xe c ung ru, cn dng 20 ml dung dch
K2Cr2O7 0,010M. Xc nh % v khi lng C2H5OH c trong mu ca ngi li xe . Cho bit phng trnh
phn ng l: C2H5OH + K2Cr2O7 + H2SO4 CH3COOH + K2SO4 + Cr2(SO4)3 + H2O.
A. 0,0552%
B. 0,046%
C. 0,092%
D. 0,138%
Phn II. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Tin hnh chun 100ml dung dch HCl 0,100M bng dung dch NaOH 0,100M. Khi thm 99,9ml v
100,1ml dung dch NaOH vo dung dch HCl th chnh lch gi tr pH ti 2 thi im cui l
A. 2,0
B. 5,4
C. 4,3
D. 9,7
Cu 52: Cho cc dy chuyn ha:
+ NaOH

+ HCl

+ HCl

+ NaOH

X
B Y
Glixin
Glixin A
X v Y ln lt l:
A. u l ClH3NCH2COONa
B. ClH3NCH2COOH v ClH3NCH2COONa
C. ClH3NCH2COONa v H2NCH2COONa
D. ClH3NCH2COOH v H2NCH2COONa
Cu 53: phn bit glucoz, saccaroz, tinh bt v xenluloz, c th dng cc cht no?
A. Dung dch AgNO3/NH3 , dd I2.
B. Dung dch AgNO3/NH3 , H2O ,dd I2.
C. H2O ,dd I2, giy qu.
D. Dung dch AgNO3/NH3 , H2O.
Cu 54: Pin in ho M-X c sut in ng chun l E01; Pin in ho Cu-X c sut in chun l 1,10V; Pin
in ho M-Cu c sut in ng chun l 0,46V. Vy gi tr ca E01 l?
A. 1,56V.
B. 0,18V.
C. 0,64V.
D. 0,78V.
Cu 55: Cho m gam hn hp X gm 2 ancol no, n chc, k tip nhau trong dy ng ng tc dng vi
CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75).
Cho ton b Y phn ng vi mt lng d Ag2O/NH3, t0C, sinh ra 64,8 gam Ag. Gi tr ca m l:
A. 8,8
B. 9,2
C. 7,4
D. 7,8
Cu 56: Cho 0,13 mol hn hp X gm CH3OH, HCOOH, HCOOCH3 tc dng va vi 0,05 mol NaOH un
nng. Oxi ha ru sinh ra thnh anehit, cho lng anehit ny tc dng ht vi Ag2O/NH3 (d) c 0,4 mol
Ag. S mol ca HCOOCH3 l:
A. 0,02
B. 0,05
C. 0,04
D. 0,08
Cu 57: un hai ru n chc vi H2SO4 c 1400C c hn hp 3 ete. Ly 0,72(g) mt trong ba ete em
t chy hon ton thu c 1,76(g) CO2 v 0,72(g) H2O. Hai ru l ?
A. CH3OH v C2H5OH
B. CH3OH v C3H5OH
C. C2H5OH v C4H9OH
D. C2H5OH v C3H7OH
Cu 58: m mt lp bc ln b mt mt vt bng ng ngi ta lm th no?
A. in phn dung dch mui ng v vt cn m ng vai tr cc m
B. in phn dung dch mui ng v vt cn m ng vai tr cc dng
C. in phn dung dch mui bc v vt cn m ng vai tr cc m
D. in phn dung dch mui bc v vt cn m ng vai tr cc dng
Cu 59: Hn hp X gm: Fe2O3, Cr2O3, Al2O3. Cho 20,7 gam X vo dung dch NaOH c (d), sau khi kt thc
phn ng thu c 8 gam cht rn. Mt khc kh hon ton 20,7 gam X cn 5,4 gam Al. Khi lng Cr2O3
trong 20,7 gam X l?
A. 11,4 gam.
B. 15,2 gam.
C. 7,6 gam.
D. 2,28 gam.
Cu 60: toC tc phn ng ha hc l V. tc phn ng trn l 16V th nhit cn thit l (bit rng
c tng nhit ln 10oC th tc phn ng tng ln 2 ln)
B. (t + 200)oC.
C. (t + 20)oC.
D. (t + 40)oC.
A. (t + 100)oC.
(Cho K=39 ; O=16 ; H=1 ; N=14 ; Al=27 ; Cu=64 ; C=12 ; Fe=56 ; Na=23 ; Cl=35,5 ; Cr= 52; Zn=65 ;
Ag=108 ; S=32 ; Ba=137 ; Co= 59)
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P N M 132 THI TH H MN HA
Cu
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

M 132
B
C
D
C
C
D
A
C
D
A
C
B
A
D
D
D
B
A
D
A
D
C
B
B
D
B
A
D
B
A

Cu
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60

M 132
D
B
C
B
B
C
C
A
A
A
C
A
D
A
B
D
C
C
B
A
B
D
B
A
D
A
B
C
C
D

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Trng THPT Qunh Lu 1
http://ebook.here.vn Th vin thi trc nghim - 5 -