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練習問題2 (後期)
練習問題2 (後期)
()()
Tbp
bpd =
bpd
(
bpd
=RTbp ln x
bpd
= RTbp x
)
V
= S
T P
RTbp2
Tbp =
H vap
= S
Tbp ,
= S
Tbp
Tbp
(1)
x + x = 1,
x << 1
(
)
(2)
S S =
bpd
RTbp ln x
bpd
= RTbp x
Tbp
S vap
S vap =
H va p / T
()()
AS (
AS
( )), k / k = K (
k , k
()(
)()) P
(1- )
Langmuir
(1) Langmuir
(2) ()(a)(b) P
( g ) , S
voff
= k 1 [
S]
von = k1 [ ( g ) ][ S ]
voff
= von
Clausius-Clapayron
H vap
d G = d G
Maxwell
d G = V dP SdT
V dP S dT = V dP S dT
d (ln P )
H vap
=
d (1 / T )
R
Clausius-Clapayron
H vap 1
ln P =
+ const .
R
T
ln P
1
T
H vap
(-)()
C x
( A,B (
)
)
1 C x
2
A + B C
C A0 ,
t = 0
C B0
()>>()( C >> C ) 1
S E (- ES)
S0
E0
k1
k2
P E + S ES , ES P
k 1
KM
v=
k 2C E 0
1 + K M CS 0
KM =
C C
k1 + k2
= E S
k1
C ES
()
( v )