Contents

1.
2.
3.
4.


1. ?

2.
Nikel
.

3. Nikel Langmuir

.



-
.

- 3
.
-
.

-
.
- .

- .
- .

R SO3 H

R COOH

pH

1~14

5~14

SiO

pH

1~14

0~9


<Langmuir >


(selectivity)
.

()-SO3
KM =

k1
k2

-H+

M +X-

[()-SO3-M+][H+]

[M+][()-SO3-H+]

k1

()-SO3-M+ + H+Xk2

qMCH
C Mq H

nMmH
mMnH

yMxH
xMyH



qM =

1
qM

KM - 1

QKM

Q=qM+qH
C0=CM+CH

QKMCM
Co + (KM 1)CM
Co

QKMCM

KM - 1
QKM

QKMxM

1 / qM vs Co / CM(=1 / xM) plot Q KM


100ml 8

Magnetic stirrer & bars ( & )

UV spectrophotometer ( )


: NH4OH

: 35.05
: 25 NH3
46.2%, NH4OH 52.4%,

NH4+ 1.4%
: , ,
, ,


: C6H8O7

: 192
: .
1

, .
:, ,


: Ni(NO3)2

: 182.73

- 100%

-,


() - 25
- sulfone

8 100mL 1g .
Ni(NO3)26H20 1M 200mL .
0.01M, 0.02M, 0.05M, 0.06M, 0.08M,
0.1M, 0.2M, 0.5M Ni(NO3)2 .

.
2 .
5mL Citam 5mL
.


UV spectrophotometer 620nm .
standard curve Nikel .
Nikel
.
(q VS. C) plot.

1/q VS, C0/C plot .

(4) K.





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