TRNG THPT CHUYN NGUYN TT THNH ( thi gm c 05 trang)

THI TH I HC LN I NM HC 2012 - 2013 MN: HO HC; KHI A, B Thi gian: 90 pht, khng k thi gian giao
M : 061

H v tn th sinh: ................................................................. SBD:........................Lp:........................ Cho bit nguyn t khi ca cc nguyn t : H=1; He=4; Li=7; Be=9; C=12; N=14; O=16; F=19; Na=23; Mg=24; Al=27; S=32; Cl=35,5; K=39; Ca=40; Cr=52; Mn=55; Fe=56; Ni=58,7; Cu=64; Zn=65; Br=80; Rb=85; Sr=88; Ag=108; Sn=119; Cs=133; Ba=137; Pb=207, Cr=52; Sn=119; Cu 1: Th mt vin bi b ng st hnh cu nng 5,6 gam vo 200 ml dung d ch HCl cha bit nng . Sau khi ng knh vin cn li bng 1/2 so vi ban u th kh ngng thot ra (gi s vin bi b mn u t mi pha). Nng (mol/lt) ca dung dch HCl l A. 0,500. B. 0,875. C. 0,125. D. 1,376.
- 2+ 2+ Cu 2: Cho cc ion:HSO 4 , NO 3 , C6H5O , OCO-CH2-NH 3 , CH3NH 3 , Cu , Ba , Al(OH) 4 , HCO 3 .

Tng s ion c vai tr axit v tng s ion c vai tr lng tnh l A. 2 v 1 B. 2 v 2 C. 3 v 2

D. 1v 2

Cu 3: Cho cc monome sau: stiren, toluen, metylaxetat, vinylaxetat, metylmetacrylat, metylacrylat, propilen, benzen, axit etanoic, axt -aminocaproic, caprolactam, etilenoxit. S monome tham gia phn ng trng hp l: A. 6 B. 5 C. 8 D. 7 Cu 4: in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l A. 4,48. B. 5,60. C. 11,20. D. 22,40. Cu 5: Cho axeton tc dng vi HCN thu c cht hu c X. Thy phn X trong mi trng axit thu c cht hu c Z. hirat ha Z thu c axit cacboxylic Y. Vy Y l cht no sau y? A. CH2=CH-COOH B. CH3CH=CHCOOH C. CH2=C(CH3)COOH D. CH2=CHCH2COOH Cu 6: Cho cc cht v dung d ch sau: toluen, stiren, etilen, xiclopropan, isopren, vinyl axetat, etyl acrylat, ivinyl oxalat, foocmon, axeton, dung dch glucoz, dung dch Fructoz, dung dch mantoz, dung d ch saccaroz. S cht v dung dch c th lm mt mu dung dch Br2 l: A. 8 B. 11. C. 10 D. 9 Cu 7: t chy hon ton a mol mt este no, n chc mch h X, cn b mol O2, to ra c mol hn hp CO2 v H2O. Bit c = 2(b - a). S ng phn este ca X l A. 2. B. 6. C. 4. D. 3. Cu 8: X l dung dch AlCl3 Y l dung dch NaOH 2M .Cho 150ml dung dch Y vo cc cha 100 ml dung dch X, khuy u n khi phn ng hon ton thy trong cc c 7,8 g kt ta. Nu thm tip vo cc 100 ml dung dch Y kt thc phn ng c 10,92 g kt ta. Nng mol ca dung dch X l : A. 3,2 M B. 2,0 M C. 1,0 M D. 1,6 M Cu 9: Cho 2 dung dch H2SO4 v HCOOH c cng nng mol/l v c cc gi tr pH tng ng l x v y. Thit lp mi quan h gia x v y bit rng c 50 phn t HCOOH th c 1 phn t HCOOH phn ly. A. y = x - 1 B. y = 10x C. y = x + 2 D. y = 2x Download ebook, ti liu, thi, bi ging ti : http://diendan.shpt.info
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Cu 10: Cho cc cht c cng thc cu to nh sau: HO-CH2-CH2-OH (X); HO-CH2-CH2-CH2-OH (Y); HO-CH2-CH(OH)-CH2-OH (Z); CH3-CH2-O-CH2 -CH3 (R); CH3-CH(OH)-CH2-OH (T). Nhng cht tc dng vi Cu(OH)2 to phc mu xanh lam l A. X, Y, R, T B. X, Z, T C. X, Y, Z, T D. Z, R, T Cu 11: Cho phng trnh phn ng: Mg + HNO3 Mg(NO3)2 + NO + N2O + H2O. T kh i ca h n hp NO v N2O i vi H2 l 19,2. T l s phn t b kh v b oxi ha trong phn ng trn l: A. 8 : 15 B. 6 : 11 C. 11 : 28 D. 38 : 15 Cu 12: Cho 1 mol axit axetic tc dng vi 1mol etanol (xt H2SO4 c) ngi ta thu c 0,5 mol etyl axetat. Hy cho bit nu ly 1 mol axit axetic tc dng vi 3 mol etanol (cc iu kin khc c gi khng i) th s mol este thu c l: A. 0,80 mol B. 0,60 mol C. 0,75 mol D. 0,50 mol Cu 13: Nguyn t khi trung b nh ca Cu l 63,54. Cu c 2 ng v bn 63Cu v 65Cu. Thnh phn phn trm v khi lng ca 63Cu trong Cu2S l: A. 57,49 B. 73 C. 21,82 D. 57,82 Cu 14: Thc hin cc th nghim sau: (I) Cho saccaroz tc dng vi dung dch AgNO3 trong NH3. (II) Nhit phn AgNO3. (III) Cho Fe(NO3)2 tc dng vi dung dch AgNO3. (IV) Cho fructoz tc dng vi dung dch AgNO3 trong NH3. (V) AgCl ngo i nh nng. C. 4. D. 1. Cu 15: Cho cn b ng sau: 2SO2(k) + O2(k) 2SO3(k) H = -96,23 kJ/mol. Hy cho bit tc ng no sau y i vi cn bng lm cho cn b ng chuyn dch theo chiu thun? A. Tng nhit . B. Tng p sut chung ca h. C. Tng th tch bnh. D. Tng nng SO3. Cu 16: X l hn hp cc mui Cu(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 59,6% v khi lng. Cho dung dch KOH (d) vo dung dch cha 100 gam mui X. Lc kt ta thu c em nung trong khng kh n khi lng khng i thu c m gam oxit. Gi tr ca m l A. 39,20 B. 17,65 C. 47,36 D. 32,95. Cu 17: Cho X, Y, Z, R, T l nm nguyn t lin tip nhau trong bng tun hon cc nguyn t ho hc c tng s in tch ht nhn l 90 (X c s in tch ht nhn nh nht). Pht biu no sau y khng ng ? A. Bn knh cc ht gim: X2 > Y > Z > R+ > T2+ . B. Cc ht X2 , Y, Z , R+ , T2+ c cng cu hnh electron 1s22s22p63s23p 6. C. Trong phn ng oxi ho - kh, X2 v Y ch c kh nng th hin tnh kh. D. m in ca Y nh hn m in ca R. Cu 18: Pht biu no sau y ng? A. axit glutamic HOOC-CH2-CH2-CH(NH2)-COOH c tnh lng tnh B. Trong mt phn t tripeptit mch h c 3 lin kt peptit. C. Cc hp cht peptit bn trong mi trng baz v mi trng axit. D. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho dung dch mu tm xanh Cu 19: C cc nhn nh sau y: 1)Nguyn tc sn xut gang l kh st bng CO nhit cao. 2)Nguyn tc sn xut thp l kh cc tp cht trong gang. 3)Tnh cht ha hc ca Fe2+ l tnh kh v tnh oxi ha. 4)Nc cng l nc c cha ion Ca2+, Mg2+ di dng mui Cl-, HCO3-, SO42-,... S nhn nh ng l Download ebook, ti liu, thi, bi ging ti : http://diendan.shpt.info
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S th nghim to ra bc kim loi l A. 2. B. 3.

A. 1.

B. 2.

C. 3.

D. 0.

Cu 20: Ho tan m gam Na vo dung d ch cha 0,1 mol Ca(OH)2 thu c dung dch X. Hp th hon ton 4,48 lt (ktc) kh CO2 vo dung d ch X thu c 5,0 gam kt ta. Gi tr ca m l: A. 4,6 B. 2,3 C. 3,45 D. 1,15 Cu 21: X l tetrapeptit Ala Gly Val Ala; Y l tripeptit Val Gly Val. un nng m gam hn hp cha X v Y (trong t l mol ca X v Y tng ng l 1 : 3) vi dung dch NaOH va . Phn ng hon ton thu c dung dch Z, c cn dung dch Z thu c 25,328 gam cht rn khan. Gi tr ca m l A. 19,455 gam B. 18,160 gam C. 34,105 gam D. 17,025 gam Cu 22: Cng thc ho hc ca amophot, mt loi phn bn phc hp l: A. (NH4)2HPO4 v Ca(H2PO4)2. B. NH4H2PO4 v Ca(H2PO4)2. C. Ca(H2PO4)2. D. NH4H2PO4 v (NH4)2HPO4. Cu 23: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 8,64. B. 2,16. C. 10,8. D. 9,72. Cu 24: Cho dy cc cht v ion : Fe, Cl2, SO2, NO2, C, Al, Mg2+, Na+, Fe2+, Fe3+. S cht v ion va c tnh oxi ha, va c tnh kh l: A. 4 B. 5 C. 8 D. 6 Cu 25: Khi lng oleum cha 71% SO3 v khi lng cn ly ha tan vo 100 gam dung d ch H2SO4 60% th thu c oleum cha 30% SO3 v khi lng l: A. 312,56 gam B. 539,68gam C. 506,78gam D. 496,68gam Cu 26: Thc hin cc th nghim sau: (1) Cho dung d ch Na2CO3 vo dung d ch Al2(SO4)3. (2) Cho dung d ch hn hp HCl v NaNO3 vo dung d ch FeCl2. (3) Cho dung d ch HCl vo dung dch Fe(NO3)2. (4) Cho dung d ch NaHCO3 vo dung dch BaCl2. (5) Cho dung d ch NaHCO3 vo dung dch NaHSO4. S trng hp xy ra phn ng l A. 4. B. 5. C. 3. D. 2.

Cu 27: Cho hn hp X gm CH4, C 2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th
khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung d ch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l

A. 40%.

B. 50%.

C. 25%.

D. 20%.

Cu 28: Ln men m gam glucoz vi hiu sut 60%. Lng CO2 sinh ra c hp th vo dung dch Ca(OH)2 thu c 20 gam kt t a v khi lng dung d ch gim 6,8 gam. Gi tr ca m l A. 16,2 B. 45 C. 15 D. 30 Cu 29: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch Brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 32,0. D. 8,0. Cu 30: X c cng thc phn t l C4 H8 Cl2. Thy phn X trong dung dch NaOH un nng thu c cht hu c Y n chc. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 3 C. 4 D. 5 Cu 31: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,15 mol Y, thu c tng khi lng CO2 v H2O bng 82,35 gam. t chy hon ton 0,1 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l Download ebook, ti liu, thi, bi ging ti : http://diendan.shpt.info
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A. 40

B. 30

C. 80

D. 60

Cu 32: Mt dung dch c cha HCO3-; 0,2 mol Ca2+; 0,8 mol Na+; 0,1 mol Mg2+; 0,8 mol Cl-. C cn dung d ch n khi lng khng i th lng mui thu c l A. 75,2 gam B. 72,5 gam C. 96,6 gam D. 118,8 gam Cu 33: Cho cc dung dung dch sau: (1): natri cacbonat; (2): st (III) clorrua; (3): axit sunfuric long; (4): axit axetic; (5): natri phenolat; (6): phenyl amoni clorua; (7): imetyl amoni clorua. Dung dch metylamin tc dng c vi dung dch: A. 2, 3, 4, 5 B. 1, 2, 4, 5 C. 3, 4, 6, 7 D. 2, 3, 4, 6 Cu 34: Tin hnh cc th nghim sau: Cho l Fe vo dung d ch gm CuSO4 v H2SO4 long t dy Fe trong b nh ng kh O2; Cho l Cu vo dung dch gm Fe(NO3)2 v HNO3; Cho l Zn vo dung dch HCl; S th nghim c xy ra n mn in ha l A. 2 B. 3 C. 1 D. 4

Cu 35: Cho cc cht sau: HCl; NaOH; Na3PO4; Na2CO3; Ca(OH)2. S cht ti a c th lm mm nc cng tm thi l A. 4. B. 5. C. 3. D. 2. Cu 36: ng vi cng thc phn t C7 H8O c bao nhiu ng phn l dn xut ca benzen v s ng phn u tc dng c vi cc cht: K, KOH, (CH3CO)2O: A. 5 v 2 B. 4 v 2 C. 5 v 3 D. 4 v 3 Cu 37: Cht hu c M c mt nhm amino, mt chc este. Hm lng oxi trong M l 35,96 %. X phng ha a gam cht M c ancol. Cho to n b hi ancol i qua CuO d, to thu andehit Z. Cho Z phn ng vi dung dch AgNO3/NH3 d, thu c 16,2 gam Ag. Gi tr ca a l: ( hiu sut phn ng 100%) A. 3,8625 gam B. 6,675 gam C. 7,725 gam D. 3,3375 gam Cu 38: Dung dch X cha hh gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dd HCl 1M vo 100 ml dd X, sinh ra V lt kh (ktc). un nng c cn dung dch sau phn ng thu c m (g) mui khan. Gi tr ca m l: A. 25,6g B. 30,1 g C. 23,9 g D. 18,2g Cu 39: Cho 3 kim loi X,Y, Z bit E0 ca 2 cp oxihoa kh X2+/X = - 0,76V v Y2+/Y = +0,34V. Khi cho Z vo dung dch mui ca Y th c phn ng xy ra cn khi cho Z vo dung dch mui X th khng xy ra phn ng. Bit Eo ca pin X-Z = +0,63V th E0 ca pin Z - Y bng : A. +1,73V B. +2,49V C. +0,47V D. +0,21V Cu 40: t chy hon ton 29,6 gam hn hp X gm CH3COOH,CxHyCOOH,v (COOH)2 thu c 14,4 gam H2O v m gam CO2.Mt khc, 29,6 gam hn hp X phn ng ho n ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Tnh m A. 44g B. 33 gam C. 48,4 gam D. 52,8 g Cu 41: t chy ho n ton m gam cht bo X (cha triglixerit ca axit stearic,axit panmitic v cc axit bo t do ). Sau phn ng thu c 13,44 lt CO2 (ktc) v 10,44 gam nc. X phng ho m gam X (H=90%) th thu c khi lng glixerol l: A. 0,92 gam B. 1,656 gam C. 0,828 gam D. 2,484 gam Cu 42: Cho cc phn ng: 1) SO2 + H2S 2) Na2S2O3 + H2SO4 3) HI + FeCl3 4) H2S + Cl2 5) H2O2 + KNO2 6) O3 + Ag 7)Mg + CO2 8) KClO3 + HCl () C. 8 9) NH3 + CuO D. 9
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S phn ng to ra n cht l: A. 7 B. 6

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Cu 43: Nung nng AgNO3 c cht rn X v kh Y. Dn kh Y vo cc nc c dung dch Z. Cho ton b X vo Z thy X tan mt phn v thot ra kh NO duy nht. Gi thit cc phn ng xy ra hon ton. Phn trm khi lng ca X khng tan trong Z l A. 25%. B. 30%. C. 20%. D. 40%. Cu 44: Cho hn hp Na, Al vo nc d thu c 4,48 lit H2 (ktc) v dung dch X ch cha 1 cht tan. Sc CO2 d vo dung dch X th thu c bao nhiu gam kt ta ? A. 10,4 gam B. 7,8 gam C. 3,9 gam D. 15,6 gam Cu 45: Trong s cc cht: phenylamoni clorua, natri phenolat, vinyl clorua, anlyl clorua, benzyl clorua, phenyl clorua, phenyl benzoat, t nilon-6, propyl clorua, ancol benzylic, alanin, tripeptit Gly-Gly-Val, mcrezol, s cht phn ng c vi dung dch NaOH lo ng, un nng l: A. 9 B. 10 C. 7 D. 8 Cu 46: Khi trn nhng th tch bng nhau ca dung dch A c pH = 13 v dung dch B c pH = 2 th thu c dung dch c pH b ng A. 1,05 B. 1,35 C. 12,95 D. 12,65 Cu 47: Cho 32,25 gam mt mui c cng thc phn t l CH7O4NS tc dng ht vi 750 ml dung dch NaOH 1M un nng thy thot ra cht kh lm xanh qu tm m v thu c dung dch X ch cha cc cht v c. C cn dung dch X thu c bao nhiu gam cht rn khan? A. 45,5 B. 30,0 C. 35,5 D. 50,0 Cu 48: Nhng cht no sau y va l mt mu dung d ch brom, va lm mt mu dung dch thuc tm (nhit thng hoc khi un nng): pentan, xiclopropan, butaien, toluen, ancol alylic, anehit axetic. A. xiclopropan, butaien, toluen. B. xiclopropan, butaien, ancol alylic. C. butaien, ancol alylic, anehit axetic. D. butaien, toluen, ancol alylic. Cu 49: Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s este c th iu ch trc tip bng phn ng ca axit v ancol tng ng (c H2SO4 c lm xc tc) l: A. 2 B. 3 C. 5 D. 4 Cu 50: Ho tan hon ton hn hp gm MgO, Zn(OH)2 , Al, FeCO3, Cu(OH)2, Fe trong dung d ch H2SO4 long d , sau phn ng thu c dung dch X. Cho vo dung dch X mt lng Ba(OH)2 d thu c kt ta Y. Nung Y trong khng kh n khi lng khng i c hn hp rn Z, sau dn lung kh CO d ( nhit cao) t t i qua Z n khi phn ng xy ra hon ton thu c cht rn G. Thnh phn cc cht trong G l A. MgO, BaSO4, Fe, Cu. B. BaO, Fe, Cu, Mg, Al2O3. C. MgO , Al2O3, Fe, Cu, ZnO. D. BaSO4, MgO, Zn, Fe, Cu
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P N THI TH I HC LN I - MN HA HC 12
cauhoi 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 061 B C D B C C C D C B A C D C B D D A B D B D A B C A B B A B D A D C A C D

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38 39 40 41 42 43 44 45 46 47 48 49 50

C C A C C A B A D A C B A

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