$%

:1

( K (aq) + NO (aq) )
+

,- C ,
. NO = 7,14.10

$%

C = 10 mol / L

$%

! 1 -D

" E1

( NH +4 (aq) + Br (aq) ) " * 7 " 1

"

!"3
* 57

. C = 10mol / m3
" *
" 2
1 25C

" /

* 4" : 2
1 9 : /

./*

1 1

"( Na + (aq) + C (aq)) 5 @ %

F /" H I

* 56 mol / m3

: S.m2 .mol1

BC* - (Na + (aq) + HO (aq)) 5 @

.

$%

K + = 7,35.10

. = 25mS / m

.
( * ) *= 56

25C

25C

!"

H I 1 * 4
3

/C

$ %

1 2

. C = 8, 2 103 mol / L

25C
. Br = 7,81 NH+ = 7,34 : mS.m .mol
2

" 25C

./*

mol / L ( Li (aq) + Br (aq) ) K

L*

1 25C

" 1

$%

. = 58, 4mS / cm
. Br = 7,81 Li+ = 3,86 : mS.m .mol
2

1 25C

./*

5
3

. K = 5, 0.10 m :
2

C = 1, 0.10 mol / $ %

V J 25C L

MN

"

Q1 4*

O H .1 3

4 , I" R4

. G = 0, 76.10 S : W
$ %

* 56 i

* 57

Z 1

. 25C
4

"

"

.L

4 "\ -* H

. C = 1, 00.102 mol / $ %
:

!^

./5 . G

B 4* FK 3

+
Haq
+ C aq

NH+4aq + C

Haq
+ NO3aq

8,23.10-3
S3

2,82.10-3
S2

8,12.10-3
S1

Z 1 C = 1, 00.102 mol / $ %

NH+4aq + NO3aq
" * 7

S4

. G4

Allal mahdade

"

"^

H
2

1]

BC* - 3

J 4

2
1

H^
6

O BC*

J *
Q*

"I

.
J
* 56
* 57

. S4 ,S3,S2,S1 3

" I 1 HF ^
. S4

" G4 I G1,G2,G3 Z 1

www.chimiephysique.ma

./*
3

" ]F] W

(S)

'()
. 3

4"
/ Y 1

C = 76.10 S.m .mol , K+ = 74.10 S.m .mol

2

2
3

Page 1

( Ag

" . C1 = 1, 00.10 mol / $ %

, I" $

" . C 2 = 1, 00.103 mol /

. AgI

$ %

gC 5

( Na

+
aq

+ NO

3 aq

+ I ) 5 @

S2

- j F* I

I5, Y O

gC

S1

" I" 20m

. G 2 = 5, 65.104 S

Ag + I AgI ( s ) :
1

aq

, I"

Na + = 5.10 Sm mol , I = 7, 68.10 Sm mol , NO = 7,14.10 Sm mol

2

. G1 = 5,93.10 4 S

" I" 80, 0m E ,% 5

+
aq

/"

./*

. 0,141S.m 1 .

5 C = 10, 0mol / m3 $ %

. G = 6, 41.103 S

:*

"

41

" 1 :
: \

. .4

J HCOONa ( s )

@ 5 * @ K " I" 68mg

.C:3 /

. mol / m3
o! @9

O /

1 5

1
. I"

4
O
!-

. R C@ /1

1l1

1]

2

1
2

! " I" 100m g *

. 1, /"
$%

% 1
2

* 57 $ % Y % D5 5 * @ K " 1 m
3

J
* 57 $ %
Z 1

" / Y 4
I" $
" 41 4* p 7
W .4 I"
% n g* 5
. U = 1V, I = 2, 47mA : :* I U p H B 4* ( L = 1cm,S = 3, 21cm 2 )

. HCOO

. 5 :

"^
p] G


. 5 :
J
* 57 $ %

. 7
W g p: ^

= 5,5.103 S.m 2 mol. Na + = 5.103 S.m 2 mol1 . 25C
: ./*
3
. S2 S1 I

(K

C1 = 1, 08.10 mol / $ % V1 = 100m L :

. . mol / m

aq

+ Br

( Na

C1 = 9,51.104 mol / $ % V1 = 200m L :

+
aq

+
aq

1 L

+ I aq

. Y 9

" $ 1 4* 25C

"

!"

" S1

5 @

!"

" S2

J 5 3D
.Y 9
- $" 3 H S2 S1 I

. C2 C1 V2 V1 2 1 Y 9
. S2 I" V2 = 300m S1 I" V1 = 50m I" HF.* L
: 25C

Na +

3@

Y 9

* 57
1

= 50,1.10 S.m .mol ,

D$%

( Pb 2 + (aq) + 2C (aq) )

Allal mahdade

$%

/
^
2 1

" I 1 HF/

= 76,3.104 S.m 2 .mol1 ,

. Cm = 1, 06g / L

. Y 9 p: V /*

% /
1

" 5 3D

. Y 9
.

" 5

K+

Br

:
4

J
$%

www.chimiephysique.ma

!"

* 56
. 25C

/C

./*

= 73,5.10 S.m .mol1 ,

2

= 76,8.104 S.m 2 .mol 1

4

2
3
4

$%

$ %^
2

"
3
3 4

Page 2


yM * . wD H

O7 , W n g* . / V"
D5 25C
. = 462mS / m : J
M
" B 4* Y
M J
* 57
$% ^
1
. 25C

% * 1^
2

% 1
.

Pb2+ = 14, 0mS.m 2 .mol 1 ; C = 7, 63mS.m 2 .mol1 25C

H . 1 n 3" /

H 5

5 * . CaC 2 , nH 2 O I" 1g W

10mL

zJ I" 1

, n 9"

" L C : ./5 .
C(mmol/L)
G(mS)

D %
1
0,53

"$%
2,5
1,32

J *
5
2,63

J
7,5
3,95

G = f (C) W
3 H $ %

p] nC9

$%

G = 2, 24mS

H^

. n

H^

. 1

0, 46mol / L 7

25C

(H O

:JL

" CaCO 3 (s)

" nC9* 2

$%

C = 1102 mol / L $ %
/ 1
3O 3

E5 5 D

3 C , * .
+

2 : :

n = 6 3
:6

D *1 %I13 C
:

J 3O * t = 0 =
:
! D

O ^5
10
5,21

. n C9
D
3

D D m

-.

YO 1

4, 6 103 mol / L nC9

$%

(aq) + C (aq) E5 5 D

" B 4* " 100 1

CaC 2 , nH 2 O

./*

5
D %

Jw/

.
.3

5
9
5
5

1 : $: *

" I" V = 100mL :

D * 1 % I" 40mg

J
1

@*

2+

CaCO 3 (s) + 2H 3 O (aq) Ca (aq) + CO 2 (g) + 3H 2 O()

F C
! %
1
3 C 4
C : V* 2
. x max W@H7 4
3 C
J

" -D

. V*
.

k * 5 C (aq) * 5
,

t I"$

$ %
. - H

J -

34

= 12,0mS.m 2 .mol 1 ;

H 3O +

.
C Y

* 57 " 1 3
/ Y 2 3

J
* 57 " 3 3
* 57 ,-
%

/
4 3
f

" . n % 5 3
I 1 HF/ I 1 4

(S/m)

HF/ /
* 57

= 35, 0mS.m 2 .mol1 ;

www.chimiephysique.ma

1 %w 5
:

./*

= 7,5mS.m 2 .mol 1

M(O) = 16g / mol;M(C) = 12g / mol;M(Ca) = 40g / mol :

Allal mahdade

ID 5 3

f 0 p 4 I" 41
: 25C

Ca 2 +

3 C 5 -*

$ % ^
H
. 3 C 5 -*

= 0, 425 580x

. . , 3 3 C , FO
D5 t = J x 4

3DV W
(3)

" 41 3 C ,\

3 C 5 1 3 H
. 3 C 5 1 3 H

. :

Z 1

Page 3