Marking Scheme

Chemistry
Delhi- SET (56/1/3)
1 2 $ & ( ) + * , 1.= ( l / 0 ) %ell constant! l/0 = ./ = . = .esistance 1 %ond ctivity =(1(-- ) 1 (-.1&) 1 1-#$ S cm#1) = -.21, cm#1 11 12 1$ 1& 1( 1) 1+ 1* '., Set 2 '.1) Set 1 '.1+ Set 1 '., Set 1 '.1- Set 1 '.1* Set 1 '.1& Set 1 '.1( Set 1 1 1 In which the alignment of domains (moments) is in a compensatory way to give zero net moment. m = where m is molar cond ctivity ! is cond ctivity c c is concentration in mol "#1 %hemisorption '.( Set 1 '.& Set 1 '.* Set 1 '.) Set 1 '.+ Set 1 '.11 Set 2 1 1 1 1 1 1 1 1 2

2 2 2 2 2 2 2 2

1, 11$=$

)12=$

221

'.2- Set 1

(i) (ii) (iii)

Zone refining: 3his method is 4ased on the principle that the imp rities are more sol 4le in the melt than in the solid state of metal. Va o!r hase refining: In this method! the metal is converted into its volatile compo nd and collected elsewhere. It is then decomposed to give p re metal. Ele"trolyti" refining: In this method! the imp re metal is made to act as anode. 0 strip of the same metal in p re form is sed as cathode. 3hey are p t in a s ita4le electrolytic 4ath containing sol 4le salt of the same metal.3he more 4asic metal remains in the sol tion and the less 4asic ones go to the 11$=$ anode m d 5erric hydro1ide sol is positively charged. 6y adding potassi m chloride! the e1cess chloride ions ne tralize its positive charge and ca se it to "oag!late# 3he dispersed phase and dispersion medi m migrate towards oppositely charged electrodes (electrophoresis). 3he 4eam of light is scattered 4y colloidal particles(3yndall effect).

22

(i) (ii) (iii)

11$=$

2$ 2& 2( 2)

'.2+ Set 1 '.2) Set 1 '.2& Set 1 '.2( Set 1

$ $ $ $

2+ 2* 2, $-

'.2$ Set 1 '.2, Set 1 '.2* Set 2 '.$- Set 1

$ ( ( (