Bi 1 Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacb n, A v B !u " th# kh$ " !ktc% &hi ch ',() *$t kh$ X +!

ktc, !i -ua n./c B0 m 1., kh2i *.ng b3nh b0 m t4ng *n ),5g6 th# t$ch kh$ c7n *8i ch9 b:ng );< th# t$ch hn hp X ban !=u% >?@? cAa A, B v kh2i *.ng cAa hn hp X * A. >BCDE , ><C'6 F,5g%B. ><C5 , >)CB 6 F,5g% C. >BCDE , ><C' 6 D),5g% D. ><C5 , >)CB 6 DD,'g% Bi 2 Mt hn hp X gm ankan A v mt anken B c cGng H2 nguyn t > v !u " th# kh$ " !ktc% >h hn hp X !i -ua n./c B0) 1. th3 th# t$ch kh$ I c7n *8i b:ng na th# t$ch X, c7n kh2i *.ng I b:ng DF;)J kh2i *.ng X% >?@? A, B v thnh ph=n K the th# t$ch cAa hn hp X * A. BEK >)C' v 'EK >)CB B. FEK ><C5 v FEK ><C' C. FEK >BCDE v FEK >BC5 D. FEK >)C' v FEK >)CB Bi 3 Cn hp X gm metan v D *eLin% >h DE,5 *$t hn hp X -ua 1ung 1Mch b0 m 1. thNy c D chNt kh$ bay 0a, !2t chOy h n t n kh$ ny thu !.c F,FBBg >P)% ?hnh ph=n K v th# t$ch metan v *eLin t0 ng hn hp X A. )'%D<K v (<%5(K% B. <'%FK v '<%FK% C. )EK v 5EK% D. (<%JK v )'%DK% Bi 4 >h hi!0 cacb n X phQn Rng v/i b0 m +t0 ng 1ung 1Mch, the t9 *S m * D T D, thu !.c chNt hUu c I +chRa (B,E5K B0 v kh2i *.ng,% &hi X phQn Rng v/i CB0 th3 thu !.c hai HQn phVm hUu c khOc nhau% ?n gWi cAa X * A. butXDXen% B. butX)Xen% C. @0 pi*en% D. Xic* p0 pan% Bi 5 >h hn hp X gm eti*en v C) c t9 kh2i H v/i C) b:ng B,)F% YZn X -ua bt niken nung nng +hiSu HuNt phQn Rng (FK, thu !.c hn hp I% ?9 kh2i cAa I H v/i C) +cOc th# t$ch ! " cGng !iu kiSn, * A. F,)<% B. <,)F% C. F,<F% D. DE,B'% Bi 6 >h C) v D *eLin c th# t$ch b:ng nhau -ua [iken !un nng ta !.c hn hp A% Bi\t t9 kh2i hi cAa A !2i v/i C) * )<,)% CiSu HuNt phQn Rng hi!0 h O * (FK% >]ng thRc ph^n t *eLin * A. >)CB% B. ><C'% C. >BC5% D. >FCDE% Bi 7 Cn hp kh$ X gm C) v mt anken c khQ n4ng cng CB0 ch HQn phVm hUu c 1uy nhNt% ?9 kh2i cAa X H v/i C) b:ng J,D% _un nng X c `ac tOc [i, Hau khi phQn Rng `Qy 0a h n t n, thu !.c hn hp kh$ I kh]ng *m mNt mu n./c b0 m6 t9 kh2i cAa I H v/i C) b:ng D<% >]ng thRc cNu t8 cAa anken * A. >C<X>Cb>CX>C% B. >C)b>CX>C)X>C<% C. >C)b>+>C<,)% D. >C)b>C)% Bi 8 >h hn hp X gm anken v hi!0 c t9 kh2i H v/i he*i b:ng <,<<% >h X !i -ua bt niken nung nng !\n khi phQn Rng `Qy 0a h n t n, thu !.c hn hp I c t9 kh2i H v/i he*i * B% >?@? cAa X * A. >)CB% B. ><C'% C. >BC5% D. >FCDE% Bi 9 Cn hp kh$ X gm C) v >)CB c t9 kh2i H v/i Ce * <,(F% YZn X -ua [i nung nng, thu !.c hn hp kh$ I c t9 kh2i H v/i Ce * F% CiSu HuNt cAa phQn Rng hi!0 h O * A. )EK% B. )FK% C. FEK% D. BEK% Bi 11 _2t chOy h n t n a gam hn hp eten, p0 pen, butX)Xen c=n 1Gng vca !A b *$t `i +" !ktc, thu !.c ),B m * >P) v ),B m * n./c% diO t0M cAa b * A. J),B *$t% B. JB,) *$t% C. 5E,'B *$t% D. )B,J *$t% Bi 10 _2t chOy h n t n E,D m * hm hp gm >CB, >BCDE v >)CB thu !.c E,DB m * >P) v E,)<m * C)P% e2 m * cAa ankan v anken t0 ng hn hp *=n *.t * A. E,EJ v E,ED% B. E,ED v E,EJ% C. E,E5 v E,E)% D. E,E) v E,E5% Bi 12 Mt hn hp kh$ gm D ankan v D anken c cGng H2 nguyn t > t0 ng ph^n t v c cGng H2 m *% fNy m gam hn hp ny th3 *m mNt mu vca !A 5E gam 1ung 1Mch )EK B0) t0 ng 1ung m]i >>*B% _2t chOy h n t n m gam hn hp ! thu !.c E,' m * >P)% Ankan v anken ! c c]ng thRc ph^n t * A. >)C' v >)CB% B. >BCDE v >BC5% C. ><C5 v ><C'% D. >FCD) v >FCDE% Bi 13 >hia hn hp gm ><C', >)CB, >)C) thnh hai ph=n !u nhau% @h=n DT !2t chOy h n t n thu !.c ),)B *$t >P) +!ktc,% @h=n )T Ci!0 h O 0i !2t chOy h\t th3 th# t$ch >P) thu !.c +!ktc, * ba nhiug A. D,D) *$t% B. ),)B *$t% C. B,B5 *$t% D. <,<' *$t% Bi 14 >h E,) m * hn hp X gm etan, p0 pan v p0 pen -ua 1ung 1Mch b0 m 1., thNy kh2i *.ng b3nh b0 m t4ng B,)g% f.ng kh$ c7n *8i !em !2t chOy h n t n thu !.c ',B5g n./c% hiy K th# t$ch etan, p0 pan v p0 pen *=n *.t * A. <EK, )EK, FEK% B. )EK, FEK, <EK% C. FEK, )EK, <EK% D. )EK, <EK, FEK% Bi15 : YZn D,'5 *$t hn hp kh$ X gm hai hi!0 cacb n v b3nh !jng 1ung 1Mch b0 m +1.,% eau khi phQn Rng `Qy 0a h n t n, c B gam b0 m !k phQn Rng v c7n *8i D,D) *$t kh$% [\u !2t chOy h n t n D,'5 *$t X th3 Hinh 0a ),5 *$t kh$ >P)% >]ng thRc ph^n t cAa hai hi!0 cacb n * +bi\t cOc th# t$ch kh$ !u ! " !ktc, A. >CB v >)CB% B. >CB v ><CB% C. >CB v ><C'% D. >)C' v ><C'%

Bi 16 _2t chOy h n t n E,D m * anken X thu !.c >P) v hi n./c% CNp thl h n t n HQn phVm b:ng DEE gam 1ung 1Mch [aPC )D,')K thu !.c 1ung 1Mch m/i t0 ng ! nng ! cAa [aPC ch9 c7n D',FK% >]ng thRc ph^n t !ang cAa X * A. >)CB% B. ><C'% C. >BC5% D. >FCDE% Bi 17 _em !2t chOy h n t n E,D m * hn hp X gm ) anken * !ng !mng k\ ti\p nhau thu !.c >P) v n./c c kh2i *.ng hn knm nhau ',(' gam% >?@? cAa ) anken ! * A. >)CB v ><C'% B. ><C' v >BC5% C. >BC5 v >FCDE% D. >FCDE v >'CD)% Bi 18 X *ao h]pn hqp g]om hi!0 cacb n A vao P ) +tir *q m * t.ng .sng DTDE,% _]st chasy h aon t aon X !.qc h]pn hqp I% Y^pn I -ua bionh C)ePB !4qc 1. !.qc h]pn t c s tir kh]si H vsi hi!0 *ao DJ% A c s c]ng th.sc ph^n t.r *ao A. >)C'% B. >BC5% C >BC'% D. ><C'% Bi 19 C]pn hqp X g]om ><C5 vao ><C' c s tir kh]si H vsi hi!0 *ao )D,5% _]st chasy hst F,' *ist X +!ktc, thio thu !.qc ba nhiu gam >P) vao ba nhiu gam C)Pg A. <<g vao D(,Dg% B. ))g vao J,Jg% C. D<,)g vao (,)g% D% <<g vao )D,'g% Bi20 : Cn hp X c t9 kh2i H v/i C) * )D,) gm p0 pan, p0 pen v p0 pin% &hi !2t chOy h n t n E,D m * X, tung kh2i *.ng cAa >P) v C)P thu !.c * A. D5,'E gam% B. D5,J' gam% C. )E,BE gam% D. D',5E gam% Bi 21 X *ao h]pn hqp >BC5 vao P) +tir *q m * t.ng .sng DTDE,% _]st chasy h aon t aon X !.qc h]pn hqp I% Y^pn I -ua bionh C)ePB !4qc 1. !.qc h]pn t% ?ir kh]si cAa t H vsi hi!0 *ao A.D5% B. DJ% C. )E% D. )D% Bi 22 _2t h n t n 5,'gam mt hn hp gm ankan v mt anken c cGng H2 m *% eau phQn Rng ta thu !.c HQn phVm gm >P) v n./c% YZn HQn phVm !i -ua b3nh !jng C )ePB !vc 1. th3 thu !.c D<,BB *$t kh$% XOc !Mnh hai hi10 cacb n t0n% Bi 23 ?i\n hnh t0Gng hp Dm * eti*en " !iu kiSn th$ch hp, !em HQn phVm Hau t0Gng hp tOc 1lng v/i 1ung 1Mch b0 m th3 *.ng b0 m phQn Rng * <' gam% CiSu HuNt phQn Rng t0Gng hp v kh2i *.ng p *i eti*en +@w, thu !.c * A. 5FK v )<,5 gam B. ((,F K v )),B gam C. ((,FK v )D,( gam D. (EK v )<,5 gam Bi 24 Cn hp kh$ X gm C) v mt anken c khQ n4ng cng CB0 ch HQn phVm hUu c 1uy nhNt%?9 kh2i cAa X H v/i C) b:ng J,D% _un nng X c `ac tOc [i, Hau khi phQn Rng `Qy 0a h n t n, thu!.c hn hp kh$ I kh]ng *m mNt mu n./c b0 m6 t9 kh2i cAa I H v/i C) b:ng D<% >]ng thRc cNut8 cAa anken * A. >C) b>+>C<,)% B. >C) b>C) % C. >C)b>CX>C)X>C<% D. >C<X>Cb>CX>C< Cu 38: Mt hn hp gm D ankan v D anken% YZn hn hp ! -ua 1ung 1Mch b0 m thNy 1ung 1Mch b0 m nh8t mu v kh2i *.ng b3nh t4ng ),5 gam, Hau phQn Rng thNy th Ot 0a <,<' *it mt hn hp kh$ +!ktc,% _2t chOy h n t n hn hp kh$ bay 0a thu !.c 5,5 gam >P ) v F,B gam n./c% hiy c]ng thRc cAa anken v ankan *=n *.t *T A. >CB v >)CB B. >)C' v >)CB C. >)C' v ><C' D. >CB v ><C' % Bi 25 Cn hp kh$ X gm mt ankan v mt anken% ?9 kh2i cAa X H v/i C ) b:ng DD,)F% _2t chOy h n t n B,B5 *$t X, thu !.c ',() *$t >P) +cOc th# t$ch kh$ ! " !ktc,% >]ng thRc cAa ankan v anken *=n *.t * A. >CB v >)CB% B. >)C' v >)CB% C. >CB v ><C'% D. >CB v >BC5 Bi 26 Mt hn hp kh$ X chRa E,DF m * C) v E,D m * >)CB% >h hn hp X -ua bt [i nng ta !.c hn hp kh$ I% >h I -ua 1ung 1Mch b0 m thNy c E,5g B0) tham gia phQn Rng% 1. ?$nh hiSu HuNt phQn Rng hi!0 ha% 2. ?$nh t9 kh2i cAa hn hp I !2i v/i P)% Bi 27 >h hn hp A gm >)CB v C) -ua [i, !.c hn hp B c 1B;C) b B,F% [\u ch A -ua 1ung 1Mch B0) 1. th3 kh2i *.ng b3nh b0 m t4ng E,DBg% >Oc phQn Rng `Qy 0a h n t n% 1. ?$nh kh2i *.ng cOc chNt t0 ng A% 2. ?$nh th# t$ch 1ung 1Mch b0 m E,FM t2i thi#u c=n 1Gng% Bi 28 eau khi c0acking butan ta thu !.c D hn hp A cOc hi!0 cacb n% >h )),B *$t hn hp -ua b3nh !jng 1ung 1Mch b0 m th3 c7n *8i D<,BB *$t% fNy D,'5 *$t kh$ c7n *8i !em !2t chOy thu !.c B,E' *$t >P)% >Oc th# t$ch ! !ktc% 1. ?$nh K cOc kh$ t0 ng hn hp A the th# t$ch% 2. &h2i *.ng b3nh b0 m t4ng hay giQm ba nhiug 3. CiSu HuNt phQn Rng c0acking% Bi 29 >h J,5g hn hp hai anken *in ti\p t0 ng 1ky !ng !mng tOc 1lng v/i D *$t 1ung 1Mch b0 m E,BM% eau khi phQn Rng `Qy 0a h n t n nng ! 1ung 1Mch b0 m giQm !i FEK% 1. XOc !Mnh ) anken t0n v K m tcng chNt t0 ng hn hp ban !=u%

2. hi\t tNt cQ c]ng thRc cNu t8 !ng ph^n m8ch h" cAa ) anken v ch bi\t c]ng thRc cNu t8 n khi cng n./c ch D HQn phVm 1uy nhNt Bi 30 _2t chOy h n t n a gam chNt hUu c A c=n 1Gng ',() *$t P) +!ktc,% eQn phVm chOy *=n *.t -ua b3nh @)PF thNy b3nh t4ng <,' gam 0i -ua b3nh n./c v]i t0 ng 1. thNy `uNt hiSn )E gam k\t tAa t0xng% 1. ?$nh ag 2. fip c]ng thRc thjc nghiSm 0i Huy 0a c]ng thRc ph^n t cAa A, bi\t t9 kh2i hi cAa A H v/i nit * )% 3. hi\t c]ng thRc cNu t8 c th# c, Huy 0a c]ng thRc !ang cAa A, bi\t A cng C)P ch D HQn phVm 1uy nhNt% Bi 31 >h C) v D anken c th# t$ch b:ng nhau -ua [i nung nng thu !.c hn hp A% Bi\t 0:ng t9 kh2i hi cAa A !2i v/i C) * )<,)% CiSu HuNt phQn Rng hy10 ha * (FK% 1. ?3m c]ng thRc v gWi tn anken% 2. _2t h *$t +!ktc, hn hp A ni t0n 0i ch t n b HQn phVm chOy -ua D)5g 1ung 1Mch C)ePB J5K Hau th$ nghiSm nng ! 1ung 1Mch C)ePB * '),()K% ?$nh h Bi 32 Cn hp A v B * hai anken c kh2i *.ng D),'g t0n the t9 *S m * * DTD tOc 1lng vca !A v/i <)g b0 m% [\u t0n hn hp t0n the t9 *S kh2i *.ng * DTD th3 D',5g hn hp tOc 1lng vca !A v/i E,'g C)% ?3m c]ng thRc ph^n t cAa A v B, bi\t MA y MB% Bi 33 Mt hn hp gm C), mt ankan v mt anken + c cGng H2 nguyn t cacb n v/i ankan,% &hi !2t DEE m* hn hp thu !.c )DE m* kh$ >P)% Mvt khOc khi nung nng DEEm* hn hp v/i [i th3 Hau phQn Rng c7n *8i (Em* mt hi!0 cacb n 1uy nhNt% 1. ?3m c]ng thRc ph^n t cAa ankan v anken% 2. _Mnh K th# t$ch cAa ankan v anken% 3. ?$nh th# t$ch P) c=n !# !2t chOy DEm* hn hp Bi 34 Mt hn hp X gm ankan A v anken B, H2 nguyn t hi!0 t0 ng ph^n t A b:ng H2 nguyn t cacb n t0 ng B% &hi !2t chOy <gam hn hp X th3 thu !.c F,B gam n./c% XOc !Mnh c]ng thRc ph^n t A, B v t$nh K th# t$ch cOc kh$ t0 ng hn hp A% Bi 35 >h ),)B *$t mt hn hp kh$ A +!ktc, gm etan, p0 pan, p0 pi*en Hlc -ua 1ung 1Mch b0 m 1., thNy kh2i *.ng b3nh t4ng thm ),Dgam% [\u !2t chOy kh$ c7n *8i thu !.c mt *.ng >P) v <,)B gam C)P% ?$nh thnh ph=n K th# t$ch mi kh$% Bi 36 &hi !2t chOy mt th# t$ch hi!0 cacb n A c *in k\t !]i t0 ng ph^n t c=n ' th# t$ch `i v Hinh 0a B th# t$ch >P)+>Oc th# t$ch kh$ ! cGng !iu kiSn, Bi\t 0:ng A c th# tOc 1lng v/i hi!0 t8 thnh mt hi!0 cacb n n m8ch nhOnh% XOc !Mnh c]ng thRc cNu t8 cAa A v vi\t cOc ph.ng t03nh phQn Rng