I.Q.

Toms Eduardo Chvez Miyauchi

Pgina 1 de 3

Ecuaciones Condensadas para Reacciones Reversibles

Mtodo Integral para Reacciones Reversibles de Primer Orden

Reaccin Constante de Equilibrio Ecuacin Integrada

aA
rR
k
1
k
2

Ae
Ae RA
x
x
a
r
M
k
k
K

+
= =
1
2
1

t k
a
r
k
C C
C C
t k
a
r
k
x x
x
A A
Ae A
A Ae
Ae
|

\
|
+ =
|
|

\
|

\
|
+ =
|
|

\
|

2 1
0
0
2 1
ln
ln


Mtodo Integral para Reacciones Reversibles de Segundo Orden

Ecuacin General
( )
t m t m
x x
x x x
K x
A Ae
Ae A Ae
Ae
= =
(

+ 2 1
ln

Reaccin
Constante
de Equilibrio
K
Conversin al
Equilibrio x
e

m
xe
m
K


sS rR bB aA + +

0
/
0 0
= =
=
S R
BA
C C
a b M

( )
2
2
1
Ae
Ae
x ab
rsx

( )
( ) ( )
2
1
2
1
2
1
abK rs
abK
+

( )
Ae
Ae A
x
x
a
C bk 1 2
0 1

( )
2
1
2
1
2
3
0 1
2
K
brs
a
C k
A


sS rR aA +

0
0 0
= =
S R
C C
( )
2 2
2
1
Ae
Ae
x a
rsx

( )
2
1
2
1
2
1
aK rs
aK
+

( )
Ae
Ae
A
x
x
C k
1
2
0 1

( )
2
1
2
1
0 1
2
aK
rs
C k
A


rR aA

0
0
=
R
C
( )
2 2
2 2
1
Ae
Ae
x a
x r

2
1
2
1
aK r
aK
+

( )
Ae
Ae
A
x
x
C k
1
2
0 1

2
1
0 1
2
aK
r
C k
A


rR bB aA+

0
/
0
=
=
R
BA
C
a b M

( )
2
2 2
1
Ae
Ae
x ab
x r

( )
( )
2
1
2
1
abK r
abK
+

( )
Ae
Ae A
x
x
a
C bk 1 2
0 1

2
1
2
1
2
3
0 1
2
K
b
a
r C k
A







I.Q. Toms Eduardo Chvez Miyauchi
Pgina 2 de 3

Mtodo Integral para Reacciones Reversibles con Ordenes Combinados

AC B 4
2
>
( )( )
( )( )
(

+ +
+ +
=
1 1
1 1
1
1
2
2
ln
1
D B D B Ax
D B D B Ax
t D
k
A
A
donde AC B D 4
2
1
=

AC B 4
2
<
(

|
|

\
|

|
|

\
| +
=

2
1
2
1
2
1
tan
2
tan
2
D
B
D
B Ax
t D
k
A
donde
2
2
4 B AC D =
AC B 4
2
=
( )
(

+
=
B Ax A
Ax
t
k
A
A
2
4 1
1


Reaccin
Modelo
Cintico
K ! C
rR aA
( )
2
2 1 R A A
C k C k r =

A
A RA A
x
x
a
r
M C

\
|
+
1
0

K a
C r
A
2
0
2

aK
C rM
A RA 0
2
1

K
C M
A RA 0
2
1


rR aA


( )
R A A
C k C k r
2
2
1
=

( )
2
0
1
A A
A RA
x C
x
a
r
M

+

0 A
C

aK
r
C
A

0
2

K
M
C
RA
A

0


rR bB aA+

( )
R B A A
C k C C k r
2 1
=

( ) |

\
|

+
A BA A A
A RA
x
a
b
M x C
x
a
r
M
1
0

0 A
C
a
b
aK
r
M
a
b
C
RA A
|

\
|
+
0

K
M
M C
RA
BA A

0


sS rR aA +


( )
S R A A
C C k C k r
2 1
=

A
A SA A RA A
x
x
a
s
M x
a
r
M C

\
|
+ |

\
|
+
1
0

K a
rsC
A
2
0

( )
SA RA
A
rM sM
aK
C

0
1

K
C M M
A SA RA 0
1











I.Q. Toms Eduardo Chvez Miyauchi
Pgina 3 de 3

Mtodo Integral para Reacciones Reversibles de Segundo Orden con limentacin "o
Estequiomtrica
AC B 4
2
>
( )( )
( )( )
(

+ +
+ +
=
1 1
1 1
1
1
2
2
ln
1
D B D B Ax
D B D B Ax
t D
k
A
A
donde AC B D 4
2
1
=

AC B 4
2
<
(

|
|

\
|

|
|

\
| +
=

2
1
2
1
2
1
tan
2
tan
2
D
B
D
B Ax
t D
k
A
donde
2
2
4 B AC D =
AC B 4
2
=
( )
(

+
=
B Ax A
Ax
t
k
A
A
2
4 1
1


Reaccin
Modelo
Cintico
K ! C

sS rR bB aA + +

( )
S R B A A
C C k C C k r
2 1
=
0 ; 0
/
0 0

S R
BA
C C
a b M


( ) |

\
|

|

\
|
+ |

\
|
+
A BA A
A SA A RA
x
a
b
M x
x
a
s
M x
a
r
M
1

|

\
|
+
K a
rs
a
b
C
A 2 0
|

\
| +
+ +
aK
rM sM
M
a
b
C
SA RA
BA A0

|

\
|

K
M M
M C
SA RA
BA A0


sS rR aA +


( )
S R A A
C C k C k r
2
2
1
=

0 ; 0
0 0

S R
C C

( )
2
1
A
A SA A RA
x
x
a
s
M x
a
r
M

\
|
+ |

\
|
+

|

\
|
+
K a
rs
C
A 2 0
1


|

\
| +
+
aK
rM sM
C
SA RA
A
2
0




|

\
|

K
M M
C
SA RA
A
1
0



rR aA

( )
2
2
2
1 R A A
C k C k r =

0
0

R
C

( )
2
2
1
A
A RA
x
x
a
r
M

\
|
+

|
|

\
|
+
K a
r
C
A 2
2
0
1

|

\
|
+
aK
rM
C
RA
A
1 2
0

|
|

\
|

K
M
C
RA
A
2
0
1

rR bB aA+

( )
2
2 1 R B A A
C k C C k r =

0
/
0

R
BA
C
a b M

( ) |

\
|

|

\
|
+
A BA A
A RA
x
a
b
M x
x
a
r
M
2
2
1

|
|

\
|
+
K a
r
a
b
C
A 2
2
0

|

\
|
+ +
aK
rM
M
a
b
C
RA
BA A
2
0

|
|

\
|

K
M
M C
RA
BA A
2
0