Trng THPT Chuyn Nguyn Hu

THI TH
( thi c 5 trang)
H v tn:.....................................................
S bo danh:..............

THI TUYN SINH I HC NM 2014

Mn: HA HC; Khi A
Thi gian lm bi: 90 pht, khng k thi gian pht
M 209

Cho bit nguyn t khi ca cc nguyn t:

H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; Ca = 40; Cr =
52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba =137.
Cu 1: Cho 1,5 gam kh hidrocacbon X tc dng vi lng d dung dch AgNO 3/NH3 thu c 7,92
gam kt ta vng nht. Mt khc 1,68 lt kh X ( ktc) c th lm mt mu ti a V lt dung dch Br 2
1M. Gi tr V l
A. 0,2.
B. 0,25.
C. 0,3.
D. 0,15.
3+
3
Cu 2: Ion X c cu hnh electron l [Ar]3d . V tr ca X trong bng tun hon l
A. 22 chu k 4 nhm IIIA.
B. 23 chu k 3 nhm IIIA.
C. 24 chu k 4 nhm VIB.
D. 25 chu k 4 nhm VA.
Cu 3: Nung mt hn hp rn gm a mol FeCO 3 v b mol FeS2 trong bnh kn cha khng kh (d).
Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l
Fe2O3 v hn hp kh. Bit p sut hn hp kh trc v sau phn ng bng nhau. Mi lin h gia a
v b l:
A. a=2b.
B. a=0,5b.
C. a=b.
D. a=4b.
Cu 4: Cho cc cht sau: Glucoz, xiclopropen, tinh bt, triloein, anilin, saccaroz, fructoz,
xenluloz, cumen, phenol, glixerol, axit linoleic. Chn kt lun ng trong cc kt lun sau:
A. C 6 cht lm mt mu nc brom v 5 cht tc dng c vi Cu(OH)2 nhit thng.
B. C 4 cht lm mt mu nc brom v 5 cht tc dng c vi Cu(OH)2 nhit thng.
C. C 6 cht lm mt mu nc brom v 4 cht tc dng c vi Cu(OH)2 nhit thng.
D. C 4 cht lm mt mu nc brom v 4 cht tc dng c vi Cu(OH)2 nhit thng.
Cu 5: Cho 5,6 gam hn hp NaOH v KOH (c thnh phn thay i) ha tan vo nc c dung
dch Z. Cho dung dch Z phn ng vi dung dch cha 0,04 mol AlCl 3, khi lng kt ta thu c ln
nht v nh nht l:
A. 3,12g v 2,6g.
B. 3,12g v 1,56g.
C. 1,56g v 3,12g.
D. 2,6g v 1,56g.
Cu 6: Cho cc tnh cht sau:
(1) Tc dng vi nc nhit thng.
(2) Tc dng vi dung dch NaOH.
(3) Tc dng vi dung dch AgNO3.
(4) Tc dng vi dung dch HCl c ngui.
(5) Tc dng vi dung dch HNO3 c nng.
(6) Tc dng vi Cl2 nhit thng.
(7) Tc dng vi O2 nung nng.
(8) Tc dng vi S nung nng.
Trong cc tnh cht ny, Al v Cr c chung
A. 4 tnh cht.
B. 2 tnh cht.
C. 3 tnh cht.
D. 5 tnh cht.
Cu 7: Hp th 6,72 lt SO2 (ktc) vo 200 ml dung dch KOH 1M, NaOH 0,85M, BaCl 2 0,45M sau
cho tip 300ml dung dch Ba(OH)2 0,1M thu c m gam kt ta. Gi tr m l
A. 26,04 g.
B. 19,53 g.
C. 28,21 g.
D. 13,02 g.
Cu 8: Qu trnh tng hp supephotphat kp din ra theo s sau
+ Ca 3 ( PO 4 ) 2
+ H 2SO 4
Ca3(PO4)2
Ca(H2PO4)2

H3PO4
Tnh khi lng dung dch H2SO4 70% dng iu ch c 351 kg Ca(H 2PO4)2 theo s bin
ha trn. Bit hiu sut ca qu trnh l 70%.
A. 600 kg.
B. 800kg.
C. 420kg.
D. 500kg.
Cu 9: Cho hn hp cht rn gm CaC2, Al4C3 v Ca vo nc thu c hn hp X gm 3 kh, trong
c hai kh cng s mol. Ly 8,96 lt hn hp X (ktc) chia lm hai phn bng nhau. Phn 1: cho vo
dung dch AgNO3 trong NH3 (d), sau phn ng hon ton thy tch ra 24 gam kt ta. Phn 2 cho qua
Ni, un nng thu c hn hp kh Y. Th tch O2 va (ktc) cn dng t chy hon ton Y l:
A. 5,6 lt.
B. 8,4 lt.
C. 8,96 lt.
D. 16,8 lt.

Cu 10: t chy hon ton 0,02 mol tripeptit X to t amino axit mch h A cha mt nhm -COOH
v mt nhm -NH2 thu c 4,032 lit CO2 (ktc) v 3,06 gam H2O. Thy phn hon ton m gam X
trong 100ml dung dch NaOH 2M, ri c cn thu c 16,52 gam cht rn. Gi tr ca m l:
A. 7,56
B. 6,93
C. 5,76
D. 9,24
Cu 11: Thy phn mt lng mantoz, trung ha dung dch sau phn ng bng phng php thch
hp, tch thu c 71,28 gam hn hp X, ri chia thnh hai phn bng nhau. Phn mt phn ng vi
H2 d thu c 29,12 gam sobitol. Phn hai tc dng vi mt lng d dung dch AgNO 3/NH3 thu
c m gam Ag. Gi tr ca m l:
A. 38,88 g.
B. 43,20 g.
C. 69,12 g.
D. 34,56 g.
Cu 12: Tch nc hon ton 16,6 gam hn hp A gm 2 ancol X, Y (M X < MY) thu c 11,2 gam 2
anken k tip nhau trong dy ng ng. Tch nc khng hon ton 24,9 gam hn hp A (140 oC, xc
tc thch hp) thu c 8,895 gam cc ete. Hiu sut ca phn ng to ete ca X l 50%. Hiu sut
phn ng to ete ca Y l
A. 40%.
B. 50%.
C. 60%.
D. 70%.
Cu 13: Cho cc dung dch sau: Na 2CO3; BaCl2; Na3PO4; Ca(OH)2; HCl; CH3COONa; (NH4)2SO4;
AlCl3; K2SO4; NaCl; KHSO4; K2CO3. Chn kt lun ng trong cc kt lun sau:
A. C 4 dung dch lm mm c nc cng tm thi v 4 dung dch cho pH > 7.
B. C 3 dung dch lm mm c nc cng tm thi v 4 dung dch cho pH > 7.
C. C 4 dung dch lm mm c nc cng tm thi v 5 dung dch cho pH > 7.
D. C 3 dung dch lm mm c nc cng tm thi v 5 dung dch cho pH > 7.
Cu 14: in phn (in cc tr, mng ngn xp, hiu sut 100%) dung dch cha ng thi 0,3 mol
CuSO4 v 0,1 mol NaCl, kim loi thot ra khi in phn hon ton bm vo catot. Khi catot khi
lng tng ln 12,8 gam th anot c V lt kh thot ra. Gi tr ca V l
A. 2,8 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 5,6 lt.
Cu 15: bo v thp, ngi ta tin hnh trng ln b mt thp mt lm mng thic. Hy cho bit
phng php chng n mn kim loi trn thuc vo phng php no sau y?
A. phng php to hp kim khng g.
B. phng php in ha.
C. phng php cch ly.
D. phng php dng cht km hm.
Cu 16: Cho cc dung dch sau: Na2CO3, NaNO3, HCl, FeCl2 v NaOH. Hy cho bit khi trn cc cht
trn vi nhau theo tng i mt c bao nhiu cp xy ra phn ng?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 17: Thc hin cc phn ng sau y:
(1) Nhit phn (NH4)2Cr2O7;
(2) K2MnO4 + H2O2 + H2SO4;
(3) NH3 + Br2
(4) MnO2 + KCl + KHSO4
(5) H2SO4 + Na2S2O3;
(6) H2C2O4 + KMnO4 + H2SO4;
(7) FeCl2 + H2O2 + HCl;
(8) Nung hn hp Ca3(PO4)2 + SiO2 + C
S phn ng to ra n cht l
A. 4.
B. 3.
C. 6.
D. 5.
Cu 18: Cc cht kh X, Y, Z, R, S, T ln lt to ra t cc qu trnh tng ng sau:
(1) Thuc tm tc dng vi dung dch axit clohidric c.
(2) Sunfua st tc dng vi dung dch axit clohidric.
(3) Nhit phn kaliclorat, xc tc manganioxit.
(4) Nhit phn qung olomit.
(5) Amoniclorua tc dng vi dung dch natri nitrit bo ha.
(6) Oxi ha qung pirit st.
S cht kh lm mt mu dung dch nc brom l
A. 5.
B. 2.
C. 3.
D. 4.
Cu 19: Pht biu no sau y sai
A. CO2 tan trong nc nhiu hn SO2 cng iu kin nhit , p sut.
B. SO2 c tnh kh, CO2 khng c tnh kh.
C. SO2 c dng chng nm mc cho lng thc, thc phm; cn "nc kh" (CO 2 rn) dng
bo qun thc phm.
D. SO2 l phn t phn cc, CO2 l phn t khng phn cc.

Cu 20: Hp cht hu c X c CTPT C 3H5Br3. Cho X tc dng vi dung dch NaOH long (d) un
nng ri c cn dung dch thu c th cn li cht rn trong c cha sn phm hu c ca Na. X
c tn gi l
A. 1,1,2-tribrompropan.
B. 1,2,3-tribrompropan.
C. 1,1,1-tribrompropan.
D. 1,2,2-tribrompropan.
Cu 21: Hidrat ha hon ton propen thu c hai cht hu c X v Y. Tin hnh oxi ha X v Y
bng CuO thu c hai cht hu c E v F tng ng. Trong cc thuc th sau: dung dch
AgNO3/NH3 (1), nc brom (2), H2 (Ni; to) (3), Cu(OH)2 nhit thng (4), Cu(OH)2/NaOH
nhit cao (5) v qu tm (6). Cc phn ng xy ra hon ton. S thuc th dng phn bit c E
v F ng trong hai l mt nhn khc nhau l
A. 5.
B. 2.
C. 4.
D. 3.
Cu 22: Cho 6,9 gam mt ancol n chc phn ng vi CuO un nng, thu c cht rn A v 9,3
gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi
lng d dung dch AgNO3/NH3, un nng, thu c m gam Ag. Gi tr m l
A. 16,2 g.
B. 64,8 g.
C. 32,4 g.
D. 24,3 g.
Cu 23: Hn hp A gm hai anken ng ng k tip c t khi hi i vi H 2 l 17,5. Hirat ha
hon ton hn hp A thu c 8,48 gam hn hp ancol B, trong t l khi lng gia acol bc nht
v bc hai tng ng l 29:24. Oxi ha ton b hn hp B bng CuO ri cho ton b sn phm to
thnh tc dng vi mt lng d dung dch AgNO3/NH3 thu c a gam Ag. Gi tr ca a l
A. 34,560 g.
B. 20,736 g.
C. 30,240 g.
D. 108,288 g.
Cu 24: Cho cc phn ng sau:
to
to

(1) Fe(OH)2 + HNO3 c

(2) CrO3 + NH3
(3) Glucoz + Cu(OH)2
(4) SiO2 + HF
to
(5) KClO3 + HCl
(6) NH4Cl + NaNO2bo ha

to
to
(7) SiO2 + Mg
(8) KMnO4

(9) Protein + Cu(OH)2 / NaOH

S phn ng oxi ha kh xy ra l
A. 7.
B. 6.
C. 4.
D. 5.
Cu 25: T cc cht no sau y c th iu ch c etyl metyl xeton bng phn ng cng hp
nc?
A. CH3CH2CH = CH2.
B. CH3CH2C CCH3 .
C. CH3CH2CH = CHCH3.
D. CH3CH3C = CH.
Cu 26: iu no sau y khng ng?
A. Ozon c nhiu ng dng nh ty trng bt giy, du n, cha su rng, st trng nc.
B. Nc Javen dng ph bin hn clorua vi.
C. iu ch nc Javen trong cng nghip bng cch in phn dung dch NaCl khng c mng ngn
xp.
D. Axit H2SO4 l hp cht v c c dng nhiu nht trong cng nghip ha cht.
Cu 27: Cho m gam hn hp Cu v Fe3O4 vo dung dch H2SO4 long (d), khuy u cho cc phn
ng xy ra hon ton thy c 3,2 gam kim loi khng tan v dung dch X. Cho NH 3 ti d vo dung
dch X, lc ly kt ta, nung trong khng kh n khi lng khng i cn li 16 gam cht rn. Gi tr
ca m l
A. 19,23 g.
B. 22,933 g.
C. 25,66 g.
D. 32 g.
Cu 28: Thy phn cc cht sau trong mi trng kim : CH3-CHCl2 (1), CH3COO-CH=CH CH3 (2),
CH3COOC(CH3)=CH2 (3), CH3CH2CCl3 (4), CH3COOCH2OOCCH3 (5), HCOOC2H5 (6). Nhm cc
cht no sau khi thy phn cho sn phm c kh nng tham gia phn ng trng gng l :
A. (1),(4),(5),(6).
B. (1),(2),(3),(6).
C. (1),(2),(3),(5).
D. (1),(2),(5),(6).
Cu 29: Ha tan hon ton 4,41 gam hn hp Na 2O v NaNO3 t l mol 1:1 vo nc d thu c
dung dch X. Cho 2,43 gam Al vo dung dch X. Th tch kh ktc ti thiu c th thu c l (bit
cc phn ng xy ra hon ton):
A. 1,344 lt.
B. 1,008 lt.
C. 2,016 lt.
D. 0,672 lt.
Cu 30: C nguyn t cc nguyn t: X(Z=17), Y (Z=19), R (Z=9), T (Z=20) v cc kt lun sau:
(1) Bn knh nguyn t: R<X<T<Y.
(2) m in: R<X<Y<T.

(3) Hp cht to bi X v Y l hp cht ion.

(4) Hp cht to bi R v T l hp cht cng ha
tr.
(5) Tnh kim loi: R<X<T<Y
(6) Tnh cht ha hc c bn X ging R.
S kt lun ng l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 31: Cho 1,38 gam X c cng thc phn t C 2H6O5N2 (l mui ca -aminoaxit vi HNO 3) phn
ng vi 150ml dung dch NaOH 0,2M. Sau phn ng c cn thu c m gam cht rn Y. Gi tr m l:
A. 2,14 g.
B. 2,22 g.
C. 1,13 g.
D. 2,62 g.
Cu 32: C 12 gam bt X gm Fe v S (c t l s mol l 1:2). Nung hn hp X trong iu kin khng
c khng kh, thu c hn hp Y. Ha tan hon ton Y trong dung dch HNO 3 c, nng d thy ch
c mt sn phm kh Z duy nht. Th tch Z (ktc) thu c ln nht l
A. 33,6 lt .
B. 44,8 lt.
C. 11,2 lt.
D. 3,36 lt.
Cu 33: Trong cc polime: polistiren, amiloz, amilopectin, poli(vinyl clorua), t capron, poli(metyl
metacrylat) v teflon. Nhng polime c thnh phn nguyn t ging nhau l:
A. T capron v teflon.
B. Amiloz, amilopectin, poli(vinyl clorua), t capron, poli(metyl metacrylat).
C. Polistiren, amiloz, amilopectin,t capron, poli(metyl metacrylat).
D. Amiloz, amilopectin, poli(metyl metacrylat).
Cu 34: S m t no sau y khng ng hin tng ha hc?
A. Cho t t dung dch CH3COOH long vo dung dch Na2CO3 v khuy u, lc u khng thy
hin tng g, sau mt thi gian thy c si bt kh..
B. Cho propilen vo nc brom, thy nc brom b mt mu v thu c mt dung dch ng nht
trong sut.
C. Cho qu tm vo dung dch propylamin, thy qu tm chuyn sang mu xanh.
D. Cho t t anilin vo dung dch HCl, thy anilin tan dn vo dung dch HCl.
Cu 35: Cho cn bng ha hc: 2SO2 (k) + O2 (k) 2 SO3 (k) (H < 0). Pht biu ng l:
A. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng..
B. Cn bng chuyn dch theo chiu thun khi tng nhit .
C. Cn bng chuyn dch theo chiu nghch khi gim nng d SO3.
D. Cn bng chuyn dch theo chiu nghch khi gim nng O2.
Cu 36: C cc nhn xt sau:
(1) Cht bo thuc loi este.
(2) T nilon-6,6, t capron, t nilon-7 ch iu ch bng phn ng trng ngng.
(3) Vinyl axetat khng iu ch c trc tip t axit v ru tng ng.
(4) Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen.
(5) Toluen phn ng vi nc brom d to thnh 2,4,6-tribrom clorua toluen. Nhng cu ng l:
A. (1),(3),(4).
B. (1),(2),(3),(4),(5).
C. (1),(2),(3),(4).
D. (1),(2),(4).
Cu 37: Dy cc cht u c kh nng phn ng trng hp l:
A. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen.
B. buta-1,3-ddien; cumen; etilen; trans-but-2-en.
C. 1,1,2,2-tetrafloeten; propilen; stiren; vinylclorua.
D. Stiren; clobenzen; isopren; but-1-en.
Cu 38: T anehit no n chc A c th chuyn trc tip thnh ancol B v axit T tng ng iu
ch este E t B v T. Hy xc nh t s d = ME/MS.
A. 2/1.
B. 2/3.
C. 3/2.
D. 1/2.
Cu 39: em oxi ha hon ton 7,86 gam hn hp 2 anehit n chc k tip nhau trong dy ng
ng bng oxi thu c hn hp 2 axit cacboxylic. trung ha lng axit cn dng 150ml dung
dch NaOH 1M. Cng thc cu to ca hai anehit l?
A. CH3CH2CHO v CH3CH2CH2CHO.
B. CH3CHO v CH3CH2CHO.
C. CH2 = CHCHO v CH3CH = CH
D. HCHO v CH3CHO.
Cu 40: Trong dung dch mui icromat lun c cn bng
Cr2O72 (da cam) + H2O 2 CrO 24 + 2H+
Nu thm dung dch axit HBr c v d vo dung dch K2Cr2O7 th dung dch chuyn thnh:
A. mu da cam.
B. mu vng.
C. mu xanh lc.
D. khng mu.

Cu 41: Ha tan hon ton 7,68 gam Cu vo dung dch 0,48 mol HNO 3, khuy u thu c V lt hn
hp kh NO2, NO (ktc) v dung dch X cha hai cht tan. Cho tip 200ml dung dch NaOH 2M vo
dung dch X, lc b kt ta, c cn dung dch ri nung n khi lng khng i thu c 25,28 gam
cht rn. Cc phn ng xy ra hon ton. Gi tr V l
A. 3,584 lt.
B. 5,376 lt.
C. 2,688 lt.
D. 1,792 lt.
Cu 42: Nung 8,13 gam hn hp X gm hai mui natri v 2 axit cacboxylic (mt axit n chc v mt
axit hai ch) vi vi ti xt d thu c 1,68 lt kh metan (ktc). Hy cho bit nu t chy hon ton
hn hp X bng oxi th thu c bao nhiu gam Na2CO3?
A. 3,795 gam.
B. 4,77 gam.
C. 5,565 gam.
D. 6,36 gam.
Cu 43: Khi thy phn mt triglyxerit thu c Glixerol v mui ca cc axit stearic, oleic, panmitic.
S CTCT c th c ca triglyxerit l
A. 15.
B. 3.
C. 6.
D. 4.
Cu 44: Thy phn hon ton 1 mol pentapeptit X mch h th thu c 3 mol glyxin, 1 mol alanin v
1mol valin. Khi thy phn khng hon ton X th trong sn phm thy c cc ipeptit Ala-Gly, GlyAla v tripeptip Gly-Gly-Val. Phn trm khi lng ca N trong X l:
A. 15%.
B. 11; 2%.
C. 20; 29%.
D. 19; 5%.
Cu 45: Tin hnh nhit phn hon ton m gam hn hp X gm Cu(NO 3)2 v Cu trong mt bnh kn,
thu c cht rn Y c khi lng (m 7,36) gam. Cho ton b cht rn Y tc dng vi dung dch
H2SO4 c nng d n khi phn ng xy ra hon ton thu c 0,672 lt SO 2 (ktc) l sn phm kh
duy nht. Gi tr m l
A. 19,52 g.
B. 20,16 g.
C. 22,08 g.
D. 25,28 g.
Cu 46: Dy no sau y gm cc ion tn ti ng thi trong mt dung dch

2
A. Ag+, Fe3+, H+, Br , NO3 , CO3
B. Ca2+, K+, Cu2+, OH-, Cl-.
+

C. Na+, NH 4 , Al3+, SO 4 , OH-, Cl-.

D. Na+, Mg2+, NH 4 , SO 4 , Cl-, NO3 .
Cu 47: Hp cht X c to ra t ancol n chc v aminoaxit cha mt chc axit v mt chc
amin. X c CTPT trng vi cng thc n gin nht. t chy hon ton 0,89 gam X cn va
1,2 gam O2 v to ra 1,32 gam CO2, 0,63 gam H2O. Khi cho 0,89 ham X tc dng vi 200ml dung dch
NaOH 1M ri c cn th khi lng cht rn khan thu c l:
A. 1,37 g.
B. 8,57 g.
C. 8,75 g.
D. 0,97 g.
Cu 48: Ha tan hon ton m gam hn hp 3 kim loi bng HNO 3 thu c V lt hn hp kh D (ktc)
gm NO v NO2. T khi ca D so vi H2 l 18,2. Gi thit khng c phn ng to NH4NO3. Tng
khi lng mui trong dung dch tnh theo m v V l
A. (m+8,749V) g.
B. (m+6,089V) g.
C. (m+8,96V) g.
D. (m+4,48V) g.
Cu 49: A l hp cht c to ra t 3 ion c cng cu hnh electron l 1s 22s22p6. Hp cht A l thnh
phn chnh ca qung no sau y?
A. photphorit.
B. olomit.
C. Xirit.
D. Criolit.
Cu 50: Cho 10,6 gam hp cht hu c X c CTPT C 3H10N2O2 phn ng vi mt lng va dung
dch NaOH un nng, thu c 9,7 gam mui khan v kh Y bc 1 lm xanh qu m. Cng thc cu
to ca X l
A. NH2COONH2(CH3)2.
B. NH2CH2CH2COONH4.
C. NH2COONH3CH2CH3.
D. NH2CH2COONH3CH3.