CNG TY CP K THUT CNG NGH HON CU HOANCAU TECHNOLOGY TECHNIQUE CORP

428 CMT8, phng 11, qun 3, TP H Ch Minh Tel.: (+84-8) 450 45606 Fax: (+84-8) 450 45607

CH PHM M KM LNH
@ ZINC-RICH COLD GALVANIZING COMPOUND
--- GII PHP CHNG R ST & N MN HIU QU --THAY TH M KM NHNG NNG

WORLDTECH CORP. TP.HCM 07/2009

NOI DUNG
PHN 1 I. II. TNG QUT 3

VN R ST V N MN ................................................................................................... 3 GII PHP CNG NGH ........................................................................................................ 3 II.1. GII PHP & NGUYN L CHNG N MN ................................................................. 3 II.2. C IM CA CC GII PHP: ................................................................................... 3

PHN 2 I.

CNG NGH M KM LNH

GII THIU SN PHM ............................................................................................................ 5 I.1. I.2. I.3. CNG NGH ...................................................................................................................... 5 NH SN XUT .................................................................................................................. 5 TIU CHUN SN XUT, TH NGHIM ........................................................................ 5

II.

SN PHM M KM LNH ZRC WORLDWIDE ................................................................... 6 II.1. C IM .......................................................................................................................... 6 II.2. CHC NNG CHNG N MN CATOT CA ZRC......................................................... 6 II.3. C TNH K THUT ....................................................................................................... 6 II.4. NG DNG ........................................................................................................................ 7

III.

PHNG PHP THI CNG ....................................................................................................... 7 III.1. V SINH B MT ............................................................................................................... 7 III.2. THIT B PHUN ................................................................................................................. 8 III.3. YU CU K THUT ......................................................................................................... 8 III.4. K THUT PHUN ............................................................................................................... 8 III.5. AN TON ............................................................................................................................. 9

IV.

SO SNH M KM LNH ZRC V GII PHP TRUYN THNG ..................................... 9 IV.1. SO SNH ZRC V M KM NHNG NNG .................................................................... 9 IV.2. SO SNH ZRC V SN CHNG R TRUYN THNG .................................................. 10

SN M KM LNH

ZRC WORLDWIDE www.zrcworldwide.com

PHN 1
I.

TNG QUT

VN R ST V N MN

Hng nm, gn mt na sn lng km trn th gii c dng vo vic bo v thp trc mt k th hung c nht - l s han g m hng nm nu t mt hng chc triu tn st thp. Cc quc gia phi tiu tn chi ph rt ln cho cng tc chng n mn cho cc cng trnh. cc nc cng nghip pht trin, chi ph cho cng tc bo v, chng n mn chim bnh qun khong 4% GDP hng nm. Di tc dng ca mi trng, kim loi b xm thc, n mn trong khng kh, trong t hay trong vng ngp nc lm cho tui th cng trnh b xung cp nhanh chng. Lp r khng ng u, nguy him nht l cc dng r im, r l lm gim kh nng chu ti ca kt cu. Cng cn nhiu quan nim cho rng cc kt cu b tng ct thp khng b n mn, nhng t l thuyt n thc t, cc kt cu b tng ct thp b hng nng do ct thp b n mn, gy trng n, tng th tch bn trong, mt lin kt gia ct thp v b tng gim kh nng chu ti. Cc cng trnh do nc ngoi u t th cc bin php bo v chng n mn rt c ch v coi trng. nc ta, c hi ph cho b o v - chng n mn cn rt t v thng chi ph cho cc phng php sn chng r bnh thng. Do vy khng t cc cng trnh sau vi nm s dng phi nng cp, bo dng. Do vy, cc ch u t cn mnh dn s dng cc gii php tin tin ko di tui th cng trnh, mc d chi ph u t ban u cao hn so vi cc phng php p dng truyn thng, nhng xt kha cnh di hn th chi ph rt b v hiu qu cao hn. II. GII PHP CNG NGH II.1.

GII PHP & NGUYN L CHNG N MN

Gii php chnh: S dng cc loi vt liu t b mi trng xm thc. Cc loi vt liu ny thng c gi thnh cao. S dng cc loi vt liu thng dng, km cc bin php bo v. Kt hp cc gii php trn. Hai nguyn l chnh chng xm thc ca mi trng: Mt l: Ngn cch vt liu ca cng trnh vi mi trng nh: sn ph, m, bc, v.v Hai l: Gim tc ca qu trnh n mn bng cc phng php bo v in ha, ha hc nh bo v catot, bo v anot. Trong bo v catot c 2 phong php: Dng anot hy sinh (protector) v trm anot.

Hin ti, cc cng trnh thng kt hp c 2 nguyn l trn. Nh cc vng ngoi khng kh dng cc loi sn chng r, vng ngp nc ngp bn dng cc bin php bo v catot, vng mc nc thay i kt hp c 2 bin php. II.2.

C IM CA CC GII PHP:

Sn ph: Trong cc phng php bo v kt cu bng lp ph, ngi ta thng s dng cc loi sn chng r truyn thng nh epoxy, ankit Ngoi ra, cn kt hp c hai loi l sn ln b mt kt cu c ph km ko di tui th. im quan trng trong phng php ny l qu trnh v sinh b mt kim loi phi tht k v tht sch. Thng thng dng phun ct v phun sn loi b r st. Qu trnh s n tun th theo quy nh nghim ngt ca cc hng sn.

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Lp sn b n mn nhanh chng v d bong trc khi va p, to iu kin cho n mn tn cng vt nt v bn di lp sn, nhanh chng ph hy kim loi. M km nhng nng, in phn: Gii php m km thng dng hin nay, s dng cng ngh m km in phn v m km nhng km nng. Mi cng ngh thch ng cho tng loi kt cu v vt liu khc nhau. M km in phn n gin, d thc hin, nhng vi cc kt cu c kch thc ln v c hnh dng c bit th c phn phc tp hn. bm cao, chiu dy km 20-40 m. M km nhng km nng chng minh tnh nng chng n mn u vit qua hn 100 nm qua, l phng php c hiu qu cho cc chi ti t khng ln v khi lng nhiu. Cc kt cu phi c ty sch trc khi cho vo b km nng chy. Kt cu c ph mt lp km dy 30-100 m (micron). Phun km lnh (m km lnh):

Phun km l s dng p lc kh nn thi vo cc git kim loi lng thnh chm cc ht km bn vo b mt kt cu v sinh b mt. Lp mng cha ng km sau khi kh vi hm lng ty thuc vo sn phm ca cc nh sn xut. Hm lng km cng cao th gi thnh sn phm cng cao. Tuy nhin, c c chc nng chng n mn catot th hm lng km phi cao hn 92% trong lp ph sau khi kh theo tiu chun UL. Lp phun c bm tt, thng thng phi phun 2 lp t n dy t 60-80 m (micron).

Gii php chng n mn Catot: Bo v catot s dng bn cht ca qu trnh n mn in ha xy dng mt h in ha gia catot (kt cu cn bo v) v anot (vt liu n mn hy sinh) anot b n mn thay th cho kt cu. Dng in bo v trong h xut pht t s chnh lch in th gia hai kim loi khc nhau hoc do b p t t ngun in mt chiu bn ngoi. Anot thng l hp kim nhm, km hay magi v Catot l kt cu st thp cn c bo v. Phng php bo v catot thng dng v c cc nc trn th gii p dng c hiu qu t lu. Ton b cc dn khoan bin, cc h thng ng dn nc, cu cng bin u c h thng bo v catot. H thng bo v catot lm vic lu di t nht l 10 nm tu theo vic la chn phng php v vt liu anot.

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SN M KM LNH

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PHN 2 CNG NGH M KM LNH

I. I.1.

GII THIU SN PHM

CNG NGH

Qua hn 1 th k, km chng minh kh nng chng r st v n mn rt hiu qu cho kim loi v ngy nay c hng ta thy km c s dng mi ni trn th gii . Cng ngh m km lnh l s phi hp ca hai nguyn l bo v kim loi. Th nht l chc nng bo v th ng (passive protection) hnh thnh lp mng chn nh cc loi sn truyn thng; v th hai l chc nng bo v ch ng (active protection) c lp bo v bng m km nhng nng (hotdip galvanization), t c chc nng chng n mn cathode (Cathodic protection). Cng ngh c th c gi bng cc tn khc nhau nh: M km lnh, Sn m km, Sn km 95% Zn. Sn m km lnh c thi cng nh cc loi sn truyn thng l c th phun, qut hay ln v hnh thnh nn lp ph c hai nguyn l bo v tng t nh c tnh ca lp ph c m km nhng nng vi tui th lp ph trn 20 nm. Thi gian gn y, lp m bng km m rng phm vi hot ng bo v ca mnh l c trng ln b mt cc kt cu kim loi chu lng ti nhit ln. Chng hn, cc kt cu ca t hp thit b khi ng dng phng cc con tu v tr thng gim bn theo thi gian do chng b t qu nng. Hin nay, trnh iu , ngi ta ph ln chng mt lp km. Do c nhit si thp nn trong thi gian din ra cn st khi ng, lp km bc hi rt nhanh,hp th mt lng nhit ln, v nh vy m gi cho kt cu kim loi khng b qu nng. I.2.
NH SN XUT

ZRC Worldwide l nh sn xut hng u th gii v cng ngh m km lnh vi b dy kinh nghim trn 50 nm. Nh sn xut c hai dng sn phm mang nhn hiu l ZRC v Galvilite. Hai dng sn phm ny hon ton ging nhau v c im k thut v tnh nng bo v, ch khc nhau v mu sc. ZRC c mu xm truyn thng v Galvilite c mu xm sng. ZRC Worldwide l nh sn xut cc ch phm m km lnh duy nht trn th gii c chng nhn bi tiu chun UL. I.3.

TIU CHUN SN XUT, TH NGHIM ZRC c cng nhn bi tiu chun UL MH7035, v c kim chng li hng nm bi UL. ZRC vt qua th nghim Preece Test ASTM Des A239 ca m km nhng nng. ZRC vt qua 3.000 gi th nghim hi mui m khng h hng, theo chun ASTM-B117-73. ZRC p ng vt tri DOD-P-21035A, tiu chun sa cha lp m km ca Cc phng v (M). ZRC p ng vt tri chun qun s MIL-P-26915A, tiu chun v cht liu km ca USAF. ZRC p ng vt tri tiu chun ca Canada 1-GP-181A v sa cha lp m km nhng nng. ZRC p ng vt tri tiu chun ASTM Des. A-780 v sa cha lp m km nhng nng h hng. ZRC p ng vt tri chun SSPC-Paint 20, tiu chun cho ch phm giu km lm sn lt. ZRC p ng vt tri chun SSPC-Paint 29, tiu chun cho ch phm giu km lm anode hy sinh. Ch phm chng n mn ZRC c chp thun bi B nng nghip M (USDA). ZRC c php s dng lm lp ph cho cc thng cha tip xc vi thc phm, 21CFR 175.390.

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SN M KM LNH

ZRC WORLDWIDE www.zrcworldwide.com

II. SN PHM M KM LNH ZRC WORLDWIDE II.1.

C IM

ZRC v Galvilite l hp cht hu c giu km, mt thnh phn. Cha ng n 95% km trong lp ph sau khi kh. p ng cc tiu chun UL, ASTM, MIL, DOD, SSPA, USDA. Thi cng ti mt t, trn cao, trong xng hay ti chn cng trnh. Tui th cao, tnh nng tng t nh m km nhng nng.
CHC NNG CHNG N MN CATOT CA ZRC

II.2.

ZRC giu km cha ng n 95% km to dng in lin tc trn lp m, cung cp chc nng chng n mn catot. Khi c s hin din ca cht in phn do m t, km tr thnh anode hy sinh do km c in th chuyn dch electron cao hn st thp. Cc ion km phn tn gii phng electron to dng in chy qua st thp lm cn tr s phn tn ca cc ion thp v bt u chu k in ha. Qu trnh phn ng to ra hydro cc b nt km v cc mui km khc to nn lp mng mi khng thm nc, ngn cn nc v thi tit tn cng lm dng qu trnh n mn in ha. Lp mng by gi ng vai tr bo v th ng nh cc loi sn truyn thng. Ngoi ra, nu lp mng bo v ny b h hng th cc phn t km sn sng tham gia vo qu trnh chng n mn in ha mi.
Lp m b hng do try hay khoan l

Ngay c khi lp m km b try xc th s n mn cng khng th thc hin c to g ca mnh do qu trnh phn ng xy ra tng t nh trn, gip bo v cho kim loi khng b n mn v t hn gn im try xc. Chng no trn b mt ca chi tit lm bng thp cn li d ch l vi ht km nh thi th st vn khng b ph hy. V im ny, cc loi sn truyn thng hay sn km khc c hm lng km di 92% khng th c c. Do vy, khi b mt l thng rt nh, bng du chm thi, cng cc tc nhn xm thc c ng t nhp vo st, lm cho st bt u b r nhanh chng.
C TNH K THUT

II.3.

Ch phm: Hm lng km: dn ca lp ph kh dy 76m: Trng lng ring: Thnh phn cht rn trong dung dch: long (Viscosity): Nhit vn hnh: Mu sc:

Hp cht hu c giu km, mt thnh phn 95% km trong lp ph sau khi kh 75 mili ohm 2,797 kg/lt (ASTM D-1963) 86% theo trng lng, 52% theo th tch 2500 cps (Brookfield spindle #5 @ at 100 RPM, 25oC) Ngn hn: 399oC, lin tc: 177oC ZRC: mu xm truyn thng, Galvilite: mu xm sng

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SN M KM LNH

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II.4.

NG DNG

Thay th m km nhng nng: Sn sa lp m km nhng nng b h hng do hn, ct, khoan l. Sn ti to b mt m km nhng nng b mi trng n mn theo thi gian. M km ti cng trng hay ni sn xut m khng phi a vo xng m. Sn lt cho kt cu kim loi bt k kt hp vi loi sn truyn thn g ph ngoi cng c c mu sc nh mong mun. Lnh vc ng dng: Tr in, thp truyn ti, tr n chiu sng, anten parabol, i radar. Kt cu thp cng trnh, cu cng, nh xng, thit b ngoi khi, bn b, ng ng. Bo tr thit b, ph kin trong cc h thng phn phi, truyn ti, trm bin p in lc. Cng trnh in lc, du kh, giao thng, thy sn, ho cht, ng tu, x l nc thi

Tt c kt cu kim loi v c bit hiu qu trong cc mi trng n mn cao nh vng bin, ha cht.

III. PHNG PHP THI CNG III.1. V SINH B MT

Ging nh tt c cc loi sn khc, bm dnh ca Sn ph thuc vo nhm v sch ca b mt vt liu do vt liu cn phi sch, kh v khng dnh du m to bm dnh tt nht. bm dnh ca Sn km ZRC xy ra xuyn sut trong qu trnh kt cu b tc ng bi mi trng (chc nng chuyn dch ca electron km). Do trong cng nghip ta nn s sng phng php phun ct, phun bi lm cho b mt vt liu tr ra bn ngoi tip xc trc tip vi Sn km ZRC nhm tng tnh lin kt phn t gia cc electron km v electron kim loi. Tnh trng b mt Dnh du m R nh X l b mt V sinh lp du m, dng cn cng nghip hoc dung mi xylene lau sch. Dng bn chi st ch sch lp r, nh giy nhm ln cui cho sch b mt v dng gi lau hoc chi qut sch bi r trn b mt kt cu. Dng dao co sch r, hoc my nh cc cm tay nh sch lp r. Hoc phun ct theo tiu chun SA 2

R nng

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SN M KM LNH

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M km nhng nng b n mn Cc mi hn Lp sn c b bong trc

Dng bn chi st ch sch lp r v cc mui km trn b mt. nh vng lp s ti mi hn, ri dng bn chi st ch sch mi ni. G b ht cc lp sn b phng ln sao cho l b mt kim loi ra, dng bn chi st nh hoc phun ct cho sch r bn trong.

ZRC v Galvilite i hi mc v sinh b mt l ti thiu so vi bt k loi sn truyn thng no do c chc nng chng n mn catot, ngn chn n mn di lp m.

III.2. THIT B PHUN Sng phun c ng knh l phun t 0.4 0.6 mm, gc m rng t 10o n 50o ty vo kch c v hnh dng kt cu cn sn ph. Nu sng phun c l nh th i hi p sut t 40-60psi, l ln hn th p sut ln hn 60-80psi. My nn kh c p sut nn khong 10kg/cm2, lu lng kh 1.5m3/pht. ng dn kh c ng knh trong khong 12mm. C th s dng cc loi sng phun ph bin trn th trng.

III.3. YU CU K THUT ZRC v Galvilite l cc ch phm lng, khng cn pha ch thm, c th thi cng trong nh hoc ngoi tri bng cch phun, qut hay ln.

dy lp ph sau khi kh yu cu > 76m (0.076mm), s cho tui th trn 20 nm. Ch cn sn ph 2 lp l c th t c dy yu cu trn. Mi kg ZRC, Galvilite sn ph c khong 2,0m2 vi dy l 76m, tnh hao ht trong qu trnh thi cng. Trng hp s dng ZRC, Galvilite lm sn lt th ch cn sn 1 lp, sau 24 gi th tip tc sn lp ngoi cng bng cc loi sn truyn thng khc c c mu sc nh mong mun. S dng dung mi Xylol hoc Xylene pha long (nu cn). Khng thi cng trong mi trng c ma, sng m, nhiu bi. Khuy tht u dung dch trc khi phun. Thao tc phun di chuyn sng phun t tri sang phi. Lun di chuyn sng trong khi bp c phun vi tc di chuyn u nhau. Di chuyn sng phun song song v cch b mt phun khong 15-20cm, u sng thng gc vi mt phng cn phun. iu chnh mt sn thot ra tp trung nhm hn ch tht thot. Thi gian kh b mt c th chm tay trong vng 20-30 pht. Thi gian sn lp th 2 sau 10 -12 gi. S dng dung mi Xylol hoc Xylene v sinh dng c thi cng.

III.4. K THUT PHUN

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SN M KM LNH

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III.5. AN TON

Lu tr nhit < 40oC, trnh cc ngun nhit trc tip. ZRC v Galvilite dng bnh xt cha dung mi d chy, nn khng thi cng gn ngn la. ZRC v Galvilite dn in tt, nn khng thi cng vo nhng phn ang mang in. Khng dng ZRC v Galvilite lm sn lt cho cc loi sn Alkyd hoc Lacquer. Trang phc bo h khi thi cng, n ngay c s y t nu c triu chng bt thng do sn tip xc vo mt. ngoi tm tay ca tr em.

IV. SO SNH M KM LNH ZRC V GII PHP TRUYN THNG IV.1. SO SNH ZRC V M KM NHNG NNG So snh chung chung v chi ph ca m km nhng nng v m km lnh th s rt khp khin v chi ph m km nhng nng tnh theo kg, trong khi sn m km lnh th ph thuc vo din tch b mt cn sn ph. Do vy, cn so snh da trn kt cu c th sao cho c th xc nh c trng lng v din tch b mt. Ngoi ra khng tnh n chi ph vn chuyn, khi lng ln v thi gian ch i mang vo xng m nhng nng. Sau y l mt s t vn la chn gii php ti u v kinh t m km: Qui cch, hnh dng ca kt cu cn ph km Kt cu thp c lp t nh tr thp, ng ng Kt cu thp c lp t b h hng cn sa cha Bn b cha Kt cu thp di > 9.2m Cc chi tit v ph kin nh, hnh dng phc tp Thp cng trnh dy < 4mm Thp cng trnh dy 4mm ng thp, ph bn ngoi ng thp, ph bn trong v ngoi ng thp ng knh < 114mm ng thp ng knh 114mm M km lnh M km nhng nng

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IV.2. SO SNH ZRC V SN CHNG R TRUYN THNG

PAINT No Cc loi sn truyn thng hay sn cha hm lng km di 92% th u khng cung cp chc nng chng n mn cathode hay chng n mn in ha.

Bo v ch ng (Active protection)

Sn 95% Km (ZRC) Yes ZRC cung cp chc nng bo v rt quan trng l chng n mn cathode, tc lp ph n 95% km sau khi sn s tr thnh anode hy sinh tng t nh lp m km nhng nng, mang li tui th rt cao cho cng trnh trong cc mi trng n mn khc nghit nht.

PAINT Yes Cung cp mng chn ngn chn n mn tn cng trc tip vo kim loi. (Barrier protection)

Bo v th ng (Passive protection)

Sn 95% Km (ZRC) Yes Cung cp mng chn ngn chn n mn tn cng trc tip vo kim loi.

PAINT Yes C th sn phun, qut hay ln

Thi cng d dng

Sn 95% Km (ZRC) Yes Thi cng tng t nh sn truyn thng. Thi cng ti xng hay ti cng trng m khng cn phi mang i m km nhng nng.

PAINT No Lp sn b n mn nhanh chng, c bit ti cc v tr sn b try xc, bong trc th r st s lan ra nhanh chng v ph hy kim loi

Mi trng m t v n mn cao

Sn 95% Km (ZRC) Yes Rt thch hp, s thy ngay tnh nng chng r vt tri so vi sn truyn thng, do c chc nng chng n mn cathode.

PAINT Yes i hi phi v sinh b mt tht k to bm dnh tt.

n mn tn cng di lp sn

Sn 95% Km (ZRC) No V sinh b mt l ti thiu so vi sn truyn thng v n mn khng th tn cng bn di lp ph, do lp m km l anode hy sinh.

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10

SN M KM LNH

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PAINT No Mi lp sn s polyme ho v khng lin kt phn t vi lp sn trc

S lin kt gia cc lp

Sn 95% Km (ZRC) Yes Cc lp ph s lin kt phn t vi nhau, thm ch lp sn mi c ph ln lp c sau hn 20 nm.

PAINT No Lp sn d bong trc khi va p, to iu kin cho n mn tn cng nhanh chng vo vt nt

Chng bo mn v va p

Sn 95% Km (ZRC) Yes Lp ph l kim loi km nn kh nng chng bo mn v va p hn hn bt k loi sn no.

PAINT No Chu nhit di 93oC

Kh nng chu nhit

Sn 95% Km (ZRC) Yes Chu nhit ngn hn ln n 399oC

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11

CTY CP K THUT CNG NGH HON CU HOAN CAU TECHNOLOGY TECHNIQUE CORP
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HNG DN THI CNG SN M KM LNH

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I. PHNG PHP THI CNG I.1. V SINH B MT

Ging nh tt c cc loi sn khc, b mt vt liu cn phi sch, kh v khng dnh du m to bm dnh tt. Tnh trng b mt Dnh du m R nh X l b mt V sinh lp du m, dng cn cng nghip lau sch. Dng bn chi st ch sch lp r, nh giy nhm ln cui cho sch b mt v dng gi lau hoc chi qut sch bi r trn b mt kt cu, Dng dao co sch r, hoc my nh cc cm tay nh sch lp r.

R nng

M km nhng nng b n mn Dng my nh cc cm tay nh sch lp r v cc mui km trn b mt. Cc mi hn Lp sn c b bong trc nh vng lp s ti m i hn, ri dng bn chi st ch sch mi ni. G b ht cc lp sn b phng ln sao cho l b mt kim loi ra, dng bn chi st nh sch r bn trong

ZRC v Galvilite i hi mc v sinh b mt l ti thiu so vi bt k loi sn truyn thng no do c chc nng chng n mn catot, ngn chn n mn di lp m.

bm dnh ca ZRC xy ra xuyn sut trong qu trnh chu s tc ng ca mi trng, mi trng cng tn cng th kh nng bm dnh cng cao. Do ngi ta thng ti nc vo kt cu khi cng trnh hon thnh sau 24 gi.

- cng ca ZRC khng ging nh M km nhng nng ( cng ca M km nhng nng l do khi km c nung chy chng tr thnh mui km), do thnh phn ca ZRC l 95% km tinh khit nn khi b mi trng bn ngoi tn cng, phn ng ho hc chng n mn in ho xy ra to thnh mn mui km bo v b mt kim loi. Do cng cng nh bm ca ZRC ch tt nht khi b mi trng bn ngoi tn cng theo thi gian.
I.2. THIT B PHUN

Sng phun c ng knh l phun t 0.4 0.6 mm, gc m rng t 10o n 50o ty vo kch c v hnh dng kt cu cn sn ph. Nu sng phun c l nh th i hi p sut t 40 -60psi, l ln hn th p sut ln hn 60-80psi. My nn kh c p sut nn khong 10kg/cm 2, lu lng kh 1.5m3/pht. ng dn kh c ng knh trong khong 12mm.

C th s dng cc loi sng phun sn ph bin trn th trng.

I.3. YU CU K THUT ZRC v Galvilite l cc ch phm lng, c th thi cng trong nh hoc ngoi tri bng cch phun, qut hay ln. - d dng thi cng bng sng phun th c th dng dung mi Xylene pha long theo t l th tch: (6 phn sn pha vi 1 phn Xylene.)

dy lp ph sau khi kh yu cu > 76m (0.076mm), s cho tui th trn 20 nm. Ch cn sn ph 2 lp l c th t c dy yu cu trn. Mi kg ZRC, Galvilite sn ph c khong 2,0 m2 vi dy l 76m, tnh hao ht trong qu trnh thi cng. Trng hp s dng ZRC, Galvilite lm sn lt th ch cn sn 1 lp, sau 24 gi th tip tc sn lp ngoi cng bng cc loi sn truyn thng khc c c mu sc nh mong mun. Khng thi cng trong mi trng c ma, sng m, nhiu bi. Khuy tht u dung dch trc khi phun. Thao tc phun di chuyn sng phun t tri sang phi. Lun di chuyn sng trong khi bp c phun vi tc di chuyn u nhau. Di chuyn sng phun song song v cch b mt phun khong 15-20cm, u sng thng gc vi mt phng cn phun. iu chnh mt sn thot ra tp trung nhm hn ch tht thot. Thi gian kh b mt c th chm tay trong vng 20-30 pht. Thi gian sn lp th 2 sau 4-6 gi. S dng dung mi Xylol hoc Xylene v sinh dng c thi cng. Lu tr nhit < 40oC, trnh cc ngun nhit trc tip. ZRC v Galvilite dng bnh xt cha dung mi d chy, nn khng thi cng gn ngn la. ZRC v Galvilite dn in tt, nn khng thi cng vo nhng phn ang mang in. Khng dng ZRC v Galvilite lm sn lt cho cc loi sn Alkyd hoc Lacquer. Trang phc bo h khi thi cng, n ngay c s y t nu c triu chng bt thng do sn tip xc vo mt. ngoi tm tay ca tr em.

I.4. K THUT PHUN

I.5. AN TON

www.zrcworldwide.com

ZRC

Cold Galvanizing Compound

The original Cold Galvanizing Compound! Providing superior zinc coating protection for over 50 years!

Enjoy the following great benefits with ZRC Cold Galvanizing Compound: 95% zinc in the dry film using only Type III ultra pure ASTM-D-520 zinc Meets and exceeds Fed. Spec. DOD-P-21035A (Galvanizing Repair Spec); MIL-P-26915A (USAF Zinc Dust Primer); ASTM Des. A-780 (Standard Practice for Repair of Damaged Hot-Dip Galvanized Coatings; SSPC-Paint 20 (Specification for Zinc-Rich Primer) Passes 3,000 hours salt spray testing without failure (ASTM Des. B117) Passes Preece Test (ASTM Des. A239) for hot-dip galvanizing Low VOC approved in all 50 states ISO 9001 registration assures the highest quality consistently For specification assistance, application assistance, test reports and product selection please contact our customer support at (800) 831-3275 or our website www.zrcworldwide.com.

APPLICATIONS
Field applied galvanizing Repairing hot-dip galvanizing Rust proofing welds Repairing inorganic zinc Re-galvanizing of worn hot-dip Metal fabrication Construction Manufacturing/OEM Antenna Towers Petrochemical Plants Roads & Bridges Tanks Industrial Maintenance Water Treatment Marine & Offshore Cooling Towers Hundreds more!

THE ZRC DIFFERENCE

The ZRC difference is made possible by ZRC's high zinc content (95% by weight in the dried film) of ultra pure (ASTM D 520 Type III) zinc dust, ensuring that more metallic zinc is available for superior galvanic protection against corrosion. This high purity zinc dust is compounded with a tenacious non-encapsulating binder using a highly controlled trade secret process in our state-of-the-art manufacturing facility. The result is a self-healing galvanic film that does not require sandblasting for most applications, providing both up-front labor savings and extendCompetitor ed longevity of corrosion protection. We offer a Certificate of Compliance to these exacting material standards and a copy of our most recent ISO Registration Certificate. The Proof is in the Photos These scanning electron microscope photos illustrate the difference between the true galvanic protection of ZRC and a competitors low percentage zinc coating.

ZRC

TESTING & SPECIFICATION CONFORMANCE DATA

Meets and exceeds Fed. Spec. DOD-P-21035A, formerly MIL-P-21035 (Galvanizing Repair Spec.) Meets and exceeds Fed. Spec. MIL-P-26915A (USAD Zinc Dust Primer) Passes 3,000 hours salt spray testing without failure** (ASTM Des. B117) Passes Preece Test (ASTM Des. A239) for hot-dip galvanizing Resists intermittent dry-heat temperatures up to 750F Meets and exceeds ASTM Des. A-780 (Standard Practice for Repair of Damaged Hot-Dip Galvanized Coatings) Meets and exceeds SSPC-Paint 20 (Specification for Zinc-Rich Primer) AVAILABILITY/COST Immediately available off the shelf, ZRC Cold Galvanizing Compound is offered directly from the manufacturer, or through a worldwide distribution network. The initial cost of ZRC is more than offset by substantial maintenance savings and the increased service life of protected surfaces. Contact ZRC Worldwide for current pricing and further information. TYPE THEORETICAL COVERAGE METALLIC ZINC CONTENT FLASH POINT VOC CONTENT WEIGHT PER GALLON SOLIDS CONTENT VISCOSITY MAXIMUM SERVICE TEMP - Intermittent MAXIMUM SERVICE TEMP - Constant ELECTRICAL CONDUCTIVITY IMPACT RESISTANCE ABRASION RESISTANCE POT LIFE SHELF LIFE PACKAGING DRY TIME RECOAT TIME TOPCOATING

Technical Data
Single pack, premixed, ready to apply, liquid organic zinc compound 400 ft/gal @ 1.5 mil dry film thickness 95% by weight in dry film 111F (44C) (SETA method, ASTM D3278) 3.3 lbs/gal (385 gms/ltr) (ASTM D3960) 24 lbs. (ASTM D1475) 86% (by weight)/52% (by volume) 1900 cps. Brookfield spindle #5 @ 100 RPM, @ 25C 750F (399)C 350F (177)C 73 million ohms per square @ 3 mils dry (resistivity) Greater than 30 inch-lbs. (extrusion) per ASTM-D2794 11.5 liters per dry mil (tested @ 3 dry mils) per ASTM-D98-51 At least 24 hrs. Liquid - 3 yrs.; Aerosol - 1 yr. 3.5 gallon pails, gallon, quart, and aerosol cans Set to touch. When ambient air dried, 20-30 min. @ 1.5 mil (38) thickness 12 hrs. Under certain conditions, recoat time can be reduced. Please contact manufacturer for specifics. After 24-48 hrs., topcoat with acrylic, epoxy, urethane or vinyl type products. DO NOT USE alkyd, alkyd-modified acrylic, or lacquer type products. Consult our Guide to Topcoating for detailed instructions.

MATERIALS/FINISHES
A unique formulation of 95% pure zinc metal as a liquid coating, ZRC Cold Galvanizing Compound is manufactured to exacting standards in our own state-of-the-art manufacturing facility.

SUGGESTED SPECIFICATION
Organic Zinc-Rich coating containing 95% metallic zinc, by weight in the dried film; recognized under the Component Program of Underwriters Laboratories, Inc. as an equivalent to hot-dip galvanizing; conforming to Federal Specification DOD-P-21035A (formally MIL-P-21035A) for repair of hot-dip galvanizing and meeting the requirements of Military Specification MIL-P-26915A USAF Specification for Zinc-Rich Paints; as manufactured by ZRC Worldwide, Marshfield, MA or other facility having been registered to the International Organization for Standardization ISO 9001 standard for quality. For areas and industries with more stringent VOC restrictions specify ZRC 221. BRUSH/ROLLER/AEROSOL ** Copy of reports available upon request

Surface Preparation
Dependant upon surface condition and intended service. Typical examples include: GREASE & OILS RUST SCALE MILL SCALE WATER IMMERSION Solvent clean to SSPC-SP1 Power tool clean to SSPC-SP3 or SSPC-SP11 Sandblast to SSPC-SP6 (commercial) (100F maximum) Sandblast to SSPC-SP10 (near-white)

Application
Apply as received in container 50 lbs/in = 3.5 kg/cm 15-20 lbs/in = 1.1-1.4 kg/cm 0.080 inches (0.20 cm) 4:1 ZRC:XXX Thinner -OR- 16:1 ZRC:Xylol/Xylene 30:1 1/2 (1.3 cm) (I.D.) 60-0.026 inches (0.07 cm) Tungsten carbide, reversing Complete removal is recommended. However, if screens are employed, use no less than 30 mesh. No reduction required Connect hose directly to pump, without filter assembly, ensuring a hose length of 50 ft. max. Use in-pot agitator or continuous recycling. Use least pressure possible. Start at 1500 lbs/in = 105 kg/cm and increase as required for good spraying. ZRC XXX Thinner* or Xylol/Xylene

SPRAY (low pressure compressor type) Atomized air pressure Fluid pressure Orifice of tip Viscosity reduction SPRAY (airless type) Pump Orifice of tip Hose Type of tip Filter screens Viscosity Recommended procedure

CLEAN UP * XXX Thinner is our special solvent.

145 Enterprise Drive, Marshfield, MA 02050-2132 Tel: 800.831.3275 or 781.319.0400 Fax: 781.319.0404 www.zrcworldwide.com E-mail: info@zrcworldwide.com

ZRC Worldwide has been registered by Underwriters Laboratories, Inc., to the International Organization for Standardization ISO 9000 Series Standards for Quality. The fact that ZRC is registered by UL to ISO 9001 assures our customers that the zinc-rich coatings manufactured in our facility are designed and manufactured according to the most stringent quality control standards, so you can rely on their consistency.

05030 METAL FINISHES/09800 SPECIAL COATINGS

05030 METAL FINISHES/09800 SPECIAL COATINGS COLD GALVANIZING COMPOUND By ZRC Worldwide 145 Enterprise Drive, Marshfield, MA 02050 Tel: 781-319-0400; Fax: 781-319-0404; E-mail: info@zrcworldwide.com Web: www.zrcworldwide.com PART 1 - GENERAL 1.01 SECTION INCLUDES A. Cold Galvanizing of structural steel members, assemblies and metal fabrications. 1.02 RELATED SECTIONS A. Section 05100 Structural Metal Framing; B. Section 05200 Metal Joists; C. Section 05300 Metal Decking; D. Section 05400 Cold-Formed Metal Framing; E. Section 05500 Metal Fabrications; F. Section 05580 Sheet Metal Fabrications; G. Section 05700 Ornamental Metal; H. Section 05900 Hydraulic Structures; 1.03 REFERENCES A. SPECIFICATION CONFORMANCE DATA Federal Specification DOD-P-21035A (formerly MIL-P-21035) Galvanizing Repair Specification; Federal Specification MIL-P-26915A(USAF Zinc Dust Primer); Federal Specification TT-P-460 (Type I, Zinc Dust); Canadian Government Specification 1-GP-181A (Zinc Coating). B. REFERENCE STANDARDS 1. American Society for Testing and Materials (ASTM): A 239 Locating the Thinnest Spot in a Zinc (Galvanized) Coating in Iron or Steel Articles by the Preece Test (Copper Sulfate Dip); A 780 Repair of Damaged Hot-Dip Galvanizing: B 117 Salt Spray (Fog) Testing; D 520 Type III Specification for Zinc Dust (Metallic Zinc Powder); E 376 Measuring Coating Thickness by Magnetic-Field or Eddy Current (electromagnetic) Test Methods. 2. Steel Structures Painting Council (SSPC)

All contents 2005, ZRC Worldwide. All rights Reserved.

05030 METAL FINISHES/09800 SPECIAL COATINGS

SSPC-PS 12.00 Guide to Zinc-Rich Coating Systems. SSPC Paint 20 Zinc-Rich Primers, Type II, Organic. SSPC-SP1 Surface Preparation Specification No. 1, Solvent Cleaning. SSPC-5P3 Surface Preparation Specification No. 3, Power Tool Cleaning. SSPC-5P6 Surface Preparation Specification No. 6, Commercial Blast Cleaning. SSPC-SP1O Surface Preparation Specification No. 10, Near White Blast Cleaning.

1.04 DEFINITIONS A. Cold Galvanizing: A method of applying a zinc coating to structural steel members, assemblies and fabrications at ambient temperatures to achieve long-term corrosion protection. B. Cathodic Protection: Reduction or prevention of corrosion of a metal surface by making it a cathode in an electrolytic cell. C. Galvanic Action: When two dissimilar metals come into electrical contact with each other in the presence of an electrolyte, the less noble metal (zinc) will sacrifice itself (corrode) to protect the more noble metal (steel, iron, or aluminum). 1.05 SYSTEM DESCRIPTION A metallic zinc coating, containing 95% zinc in the dried film, that imparts cathodic protection to ferrous and nonferrous metals through it's galvanic action and is recognized by Underwriter's Laboratories, Inc. as an equivalent to commercial hot-dip galvanizing. This coating, in it's dry form, is non-toxic and essentially free of such heavy metals as lead, cadmium, barium, antimony, arsenic, chromium, copper, mercury, molybdenum, selenium, silver and tellurium. 1.06 SUBMITTALS A. Subcontractor shall furnish the architect/engineer with certification that the materials furnished under this specification meet or exceed the requirements herein. B. Subcontractor shall furnish the architect/engineer with certification that surface preparation of the substrate to be coated has been performed satisfactorily, as herein specified. 1.07 DELIVERY, STORAGE AND HANDLING A. PACKING AND SHIPPING: Aerosols (12 oz.), quarts (6 lb.), gallons (24 lb.) or 3.5 gallon (84 lb.) containers of types suitable to prevent leakage of contents. B. ACCEPTANCE AT SITE: Material shall be accepted at site providing no damage deleterious to products' function is visible and applicable material safety data sheets are present.

All contents 2005, ZRC Worldwide. All rights Reserved.

05030 METAL FINISHES/09800 SPECIAL COATINGS

C. STORAGE AND PROTECTION: Do not store containers above 104 degrees F. Store containers out of sunlight and away from heat and sparks. Keep containers away from children. 1.08 PROJECT/SITE CONDITIONS A. Drying time of coating is dependent upon temperatures, but product has no application temperature limit. B. Surface temperature of the substrate to be coated shall be at least 50 above the dew point to avoid possible condensation. C. Humidity shall be less than 85% R.H. PART 2 - PRODUCTS 2.01 MANUFACTURERS ZRC Worldwide, 145 Enterprise Drive, Marshfield, Massachusetts 02050, Tel. 781-319-0400 Fax. 781-319-0404 Toll Free. 1-800-831-3275, Email: info@zrcworldwide.com Product Names: Z.R.C. Galvilite Cold Galvanizing Compound

2.02 MATERIALS A. SPECIFICATIONS: Type -Single pack, premixed, ready to apply, U.L. recognized, liquid organic zinc compound. Finish - Shiny light gray. Theoretical coverage -450 square feet per gallon at 1.5 mil dry film thickness. Metallic zinc content -95% by weight in dry film. Flash point -104 degrees F (SETA method, ASTM D-3278). Weight per gallon -24 lbs. Solids content -52% by volume (ASTM D-2832). VOC content -385 g/l (3.3 lbs/gal) (ASTM D-1475). Viscosity -1900 cps. - Brookfield spindle #6 at 100 RPM at 25 degrees C (ASTM D-2196). Maximum service temp. -750 degrees F (ASTM D-2485).
All contents 2005, ZRC Worldwide. All rights Reserved.

05030 METAL FINISHES/09800 SPECIAL COATINGS

Specific gravity -2.797 (ASTM D-1963) Electrical conductivity -73 million ohms per 3 mil dry.(Resistivity). Impact resistance -Greater than 30 inch lbs. (extrusion per ASTM D-2794). Abrasion resistance -11.5 liters per dry mil (tested at 3 dry mils per ASTM D-968). Pot life -At least 24 hours. Shelf life -Bulk type, 3 years minimum. Aerosol type, l year minimum. Dry time -(Set to touch) When ambient air dried, 20-30 minutes (ASTM D-1640). Recoat time -(Second coat) After 12 hrs. Under certain conditions, recoat time can be reduced. Please contact manufacturer for specifics. B. SUBSTRATE ACCEPTABLE FOR COATING: 1. Substrates shall be of iron, steel or aluminum including structural shapes, pipe, sheet, fabrications and assemblies. 2. Substrates of iron, steel or aluminum may be satisfactorily coated regardless of carbon, phosphorus, manganese or silicon inclusion. 2.03 EQUIPMENT A. Coating shall be applied by brush, roller, low pressure compressor-type spray or airlesstype spray. B. Refer to Section 3.03B for specific equipment information. 2.04 MIXES A. Coating herein specified is a one-component, premixed, ready to apply compound. B. Contents of containers shall be stirred well upon opening and during application to ensure homogeneous mix. PART 3 - EXECUTION 3.01 EXAMINATION A. Iron, steel, or aluminum surfaces to be coated shall be clean; i.e. devoid of grease, oil, mill scale, oxidation, loosely adherent rust, paint, etc. B. Coating shall be applied directly to metal surface to be galvanically active. 3.02 PREPARATION A. Surface preparation is dependent upon substrate condition and intended service.
All contents 2005, ZRC Worldwide. All rights Reserved.

05030 METAL FINISHES/09800 SPECIAL COATINGS

B. Typical examples are as follows: Grease and Oils - Solvent clean to SSPC-SP1 Rust scale or easy to remove paint - Power tool clean to SSPC-SP3 Mill scale or firmly adhered paint - Sandblast to SSPC-SP6 (commercial) Water immersion - (100 degrees F maximum) Sandblast to SSPC-SP10(near-white) 3.03 APPLICATION A. GENERAL APPLICATION INFORMATION 1. The coating shall be applied at sufficient wet film thickness to achieve a minimum dry film build of 2.5 - 3.5 mils, using manufacturer's recoat time directions. 2. The coating has good brushing properties and is suitable for spray application, when such application is specified. 3. Thinning with appropriate thinners as recommended by the manufacturer is allowed provided film thickness requirements can be maintained and other properties of the coating remain uncompromised. 4. The coating shall be well stirred before use so that it is completely homogeneous during application. 5. Continuous agitation (by means of an in-pot power mixer) is strongly recommended to ensure the continuous application of a completely homogeneous material at all times. 6. Omit coating of surfaces to be welded in the field. 7. Material partially used at the end of any day shall be protected from skinning by placing thin blanket of solvent over remaining coating followed by careful closing of containers. Coating may be reused on the following day after total rehomogenization.

B. SPECIFIC APPLICATION INFORMATION 1. APPLICATION BY BRUSH OR ROLLER: Apply as received in container. 2. APPLICATION BY LOW-PRESSURE COMPRESSOR TYPE SPRAY: Atomized air pressure - 50 lbs. Fluid pressure - 15-20 lbs. Orifice of tip 80/1000ths (.80). Viscosity reduction - 4 parts Coating to 1 part XXX Thinner or 16 parts Coating to 1 part Xylol/Xylene. 3. APPLICATION BY AIRLESS TYPE SPRAY: Pump - 30:1. Hose - 1/2" (I.D.) Airless type. Orifice of tip - 600 - 26/1000 ths. (.026).

All contents 2005, ZRC Worldwide. All rights Reserved.

05030 METAL FINISHES/09800 SPECIAL COATINGS

Type of tip - Tungsten carbide, reversing (self-cleaning). Filter screens - Complete removal is recommended. If screens are employed, use no less than 30 mesh. Viscosity - No reduction required. Recommended procedure - Connect hose directly to pump without filter assembly, ensuring a hose length of 50 feet maximum. Use least pressure possible. Start at 1500 lbs. and increase as required for good spraying properties. C. CLEAN-UP 1. Use XXX Thinner (from ZRC Worldwide) or Xylol/Xylene. 3.04 FIELD QUALITY CONTROL A. Inspect installed galvanized materials, fabrications and assemblies for coating thickness in accordance with ASTM E-376. 3.05 ADJUSTING A. After erection, on all uncoated areas, prepare and apply coating per Section 3.03 above. B. Touch-up any areas where shop coat has been damaged in accordance with ASTM A-780. 3.06 PROTECTION A. Only if desired, after 24-48 hours, cold galvanizing coating can be top-coated with acrylic, chlorinated rubber, epoxy, urethane or vinyl type products. B. DO NOT TOP-COAT with alkyd or lacquer type products. PART 4 - MEASUREMENT 4.01 MEASUREMENT A. Measurement for METAL FINISHES will be made on a contract lump sum basis including surface preparation, application of coating specified and the installation and removal of all items of public health and environmental protection required.

All contents 2005, ZRC Worldwide. All rights Reserved.

Report No. 001081-2

ZRC Worldwide

AN EVALUATION OF THE PERFORMANCE OF GALVILITE GALVANIZING REPAIR COMPOUND AS WELDING REPAIR PER ASTM A 780 ON G90 HOT-DIP GALVANIZED STEEL IN 5% SALT SPRAY

Date: March 4, 2009

Report No. 001081-2

ZRC Worldwide

-2

EXECUTIVE SUMMARY Galvilite Galvanizing Repair Compound, as manufactured by ZRC Worldwide, Marshfield, MA, has been tested in salt spray for its ability to protect welded areas of G90 hot-dip galvanized steel surfaces from corrosion, after application according to ASTM A-780, Standard Practice for Repair of Damaged and Uncoated Areas of Hot-Dip Galvanized Coatings. The results of this evaluation illustrate that Galvilite Galvanizing Repair Compound affords outstanding protection against corrosion to welded and/or damaged areas of G90 hot-dip galvanized steel. Figure 2 shows the condition of the Galvilite Galvanizing Repair Compound coated test piece after 2000 hours of ASTM B117 Salt Fog Testing. Figure 1 shows the galvanized control test piece without Galvilite applied.

Figure 1 Showing the control test piece after 2000 hours ASTM B 117 Salt Fog Testing.

Figure 2 Showing test piece with Galvilite applied after 2000 hours ASTM B 117 Salt Fog Testing.

Report No. 001081-2

ZRC Worldwide

OBJECT OF STUDY: To evaluate the use of Galvilite Galvanizing Repair Compound as a repair compound for welded areas on G90 specified hot-dip galvanized steel in 5% salt spray as defined in ASTM B 117. PROCEDURES: In this experiment, 11 gauge panels of G90 specified hot-dip galvanized steel (ASTM A 526) were obtained from Ledford Steel Company, Winchester, KY and employed as the substrate. Two panels of the substrate were MIG-welded together to create the test area. Figure 3 shows the test piece after welding. The welded area was then Power Tool Cleaned (SSPC-SP 11). The surrounding area was Hand Tool Cleaned (SSPC-SP 2). The surface of the whole test piece was then Solvent Cleaned (SSPC-SP 1) using MEK. Figure 4 illustrates the test piece after cleaning.

Figure 3 Showing a representative test piece after MIG welding.

Figure 4 Showing Galvilite test piece after surface preparation.

Report No. 001081-2

ZRC Worldwide

Two coats of Galvilite were applied from a randomly chosen can (after stirring) by brush to a total dry film thickness of 3.6 mils (recorded with a Positector 6000 series magnetic film thickness gauge, per SSPC-PA 2), allowing a 24-hour dry time at 25C between coats. ZRC was overlapped 1.5 inches over the galvanized surface on either side of the weld. Figure 5 shows the panel after Galvilite application.

Figure 5 Showing test piece after application of Galvilite.

The above substrate preparation and coating application was done according to the requirements of ASTM A 780, Standard Practice for Repair of Damaged and Uncoated Areas of Hot-Dip Galvanized Coatings. The test piece was allowed two weeks to dry under laboratory conditions (25C, 50% relative humidity), before being exposed to 5% salt spray as per ASTM B 117 for 2000 hours, after which time the test was terminated, the test piece visually inspected and corrosion and blistering resistance evaluated using ASTM D 610 and ASTM D 714, respectively. DATA: Figure 1 shows the condition of our control test piece, which received no surface preparation before testing. After 2000 hours of salt fog testing, it has formed copious amounts of zinc salt on its surface as a result of the galvanic reaction caused when zinc sacrifices itself to protect the underlying substrate. However, it has also begun to exhibit a significant amount of red rust across its surface, ASTM D 610 Rust Grade 2-G. The weld itself is totally corroded.

Report No. 001081-2

ZRC Worldwide

Figure 2 shows the condition of the Galvilite Galvanizing Repair Compound coated test piece. On the uncoated area of the hot-dip galvanizing, similar to the control test piece, this panel has also formed copious amounts of zinc salt, accompanied by red rust, ASTM D 610 Rust Grade 2-G. However, where Galvilite has been applied to the weld and surrounding area, there is no rust, only light formation of zinc hydroxycarbonate salt, typical of bonafide zinc rich coatings. The weld shows no corrosion at all. No blistering was observed on the weld itself and the surrounding area where the galvanizing had been removed. However, llight blistering was observed where Galvilite was applied over the hot-dip galvanizing, ASTM D 714 4-MD.

Figure 1 Showing the control test piece after 2000 hours ASTM B 117 Salt Fog Testing.

Figure 2 Showing test piece with Galvilite applied after 2000 hours ASTM B 117 Salt Fog Testing.

Report No. 001081-2

ZRC Worldwide

CONCLUSION: The results of this evaluation illustrate that Galvilite Galvanizing Repair Compound, when applied according to ASTM A 780, Standard Practice for Repair of Damaged and Uncoated Areas of Hot-Dip Galvanized Coatings, affords outstanding protection against corrosion to welded and/or damaged areas of G90 hot-dip galvanized steel. Prepared and Respectfully Submitted,

Steven P. Collins Vice-president

General panel evaluations are expressed on a scale of 0-10 as per ASTM D 610. The rating scale advances numerically with decreasing corrosion. Rust distribution is expressed with the following designations: P Pinpoint, G General, S Spot. For the evaluation of size and distribution, the Standard includes photographic reference standards. Blistering evaluations are made according to ASTM D 714. Evaluations are made for both the Size and the Frequency of blister. Blistering size is expressed on a scale of 0-10, advancing numerically with decreasing blister size. A reading of 8 indicates the smallest blister size easily seen by the unaided eye. Frequency is expressed with the following designations: D Dense, MD Medium Dense, M Medium and F Few. For both evaluations of size and frequency, the Standard includes photographic reference standards.

GALVILITE GALVANIZING COMPOUND (LIQUID)

MATERIAL SAFETY DATA SHEET

NFPA HAZARD RATING

-=========================================================================================
SECTION 1 - PRODUCT IDENTIFICATION
Product Identifier: GALVILITE Galvanizing Repair Compound Product Class: Esterified Epoxy Based Zinc-Rich Metal
Primer

SECTION

2 - HAZARDOUS INGREDIENTS
% (wt) LEL ACGIH TLV ppm (mg/M) OSHA PEL ppm (mg/M)

FIRE 2 TOXICITY REACTIVITY 2 1 SPECIAL -

HAZARDOUS INGREDIENTS

VP MMHG@20C

Product Identification Number (PIN): 20011-20014 Manufacturer's Name: ZRC Worldwide Street Address: 145 Enterprise Drive, Marshfield, MA 02050 Emergency Telephone No.: 781-319-0400 Business Hrs. Chemtrec 24 hrs. 1-800-424-9300 Date of Preparation: January 1, 2008

*Zinc (CAS # 7440-66-6) Zinc Oxide (CAS # 1314-13-2) Petroleum Distillates (CAS # 8052-41-3) *Aromatic Petroleum Distillates (CAS # 64742-95-6)
Aluminum Flake (CAS # 7429-90-5)

77 2 12

na na 0.7

Not Established TWA (RF) (2) STEL (RF) (10) TWA 100 Not Established

TWA (RF) 15 mppcf (5) TWA (TD) 50 mppcf (15) TWA (RF) (5) TWA (TD) (15) TWA 500 (2900) Not Established

na na 2.0 6.0

1.3 1.0

1.1

na

TWA (10)

TWA (RF) (5) TWA (TD) (15)

na

RF = Respirable Fraction TD = Total Dust *This CAS No. is subject to the reporting requirements of Section 313 of SARA Title III and of 40 CFR 372.

SECTION 3 - PHYSICAL DATA - FIRE AND EXPLOSION DATA

Physical State: Liquid Water Solubility: Insignificant Odor and Appearance: Grey with Odor of Petroleum Distillates Vapor Pressure: 6 @ 20C Vapor Density: Heavier than Air Evaporation Rate: Slower than Ether Boiling Range: 144-207 C Flash Point: 111 F SETA Specific Gravity: 2.88 @ 25 C Percent Volatile: 47(vol) Weight per Gallon: 24 Lbs @ 25 C. Autoignition Temp.: not determined VOC: 385 g/l (3.3 lb/gal) Reactivity in Water: See Sec.4 Flammability Limits in Air: UEL 7% (vol) LEL 0.9% (vol) Flammability Classification: DOT UN #1263 Paint - Combustible Liquid Class 3 / OSHA- Combustible Liquid Class II / OSHA Class 29 CFR-1910-106a Extinguishing Media: Approved Class B Fire Extinguisher, foam or dry chemical. DO NOT USE WATER! Combustion in a limited amount of air can generate toxic Carbon Monoxide. Use full protective equipment and self-contained breathing apparatus for respiratory protection in fighting fires in enclosures. In a fire situation or when the material is heated, it becomes a highly flammable liquid with a moderate explosion hazard. Once ignited, this product will burn readily in air. Unusual Fire and Explosion Hazards: Keep containers closed tightly. Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. Zinc and aluminum present in a finely divided form are hazardous when atomized in air and, if sparked, explosion is possible. Application to hot surfaces requires special precautions. During emergency conditions, overexposure to decomposition products (gaseous oxides of Carbon and Nitrogen) may cause health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Heavier than air vapors may flow along surfaces to distant ignition sources and flash back. Moisture and acid contamination can result in Hydrogen gas evolution, causing cans to bulge with increased pressure. Cans so deformed should not be moved, opened or punctured. Call (617) 328-6700. See also Sections 4 and 5. Special Fire Fighting Procedures: DO NOT USE WATER IN ANY FORM. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat, but care should be taken to prevent water access to wet paint and spray residues. See also Section 7.

SECTION 4 PHYSICAL HAZARDS

Stability: Stable Hazardous Polymerization: Will not occur Materials and Conditions to Avoid: This material is considered to be stable under its normal handling and storage conditions. It can react violently with strong oxidizing agents such as chlorine and oxygen, as well as water, weak acids and concentrated acids. Store in dry areas away from oxidizing agents (chlorine, oxygen), all acids, alkalies and water. Avoid dusting and accumulations of spray residues. Hazardous Combustion Products: Water and alkali contact will produce hydrogen with additional risks of explosion and fire. May produce fumes of zinc and aluminum oxides and the oxides of carbon and nitrogen when heated to decomposition. Sensitivity to Impact: Impact w/sparking may produce discharge of contents with fire or explosion hazard. Sensitivity to Static Discharge: Yes. Electrically interconnect and ground containers for transfer of liquids to avoid static sparks.

SECTION 5 HEALTH HAZARD DATA

Threshold Limit Value: 100 ppm OSHA PEL: Mixture (See Section 2) Routes of Entry: Skin Contact, Skin Absorption, Eye Contact, Inhalation and Ingestion. Medical Conditions Generally Aggravated by Exposure: Respiratory conditions, dermatitis and other skin afflictions, conditions of the central nervous system. Effects of Acute Exposure to Product: Solvents contained in this mixture are central nervous system depressants. Symptoms of overexposure include drowsiness, dizziness, headache, slurred speech, intoxication with euphoria and/or depression leading to stupor and unconsciousness. Nose, throat and lung irritation may occur from inhalation. Skin contact may cause defatting and dermatitis. Eye contact with the liquid causes tears, burning, irritation, conjunctivitis. Ingestion will cause poisoning and may be fatal; avoid aspiration if ingested. Do not induce vomiting. Lung contact may cause chemical pneumonitis. During welding and burning operations hazardous decomposition products may be evolved from the dried film, these may include but not be limited to Zinc and Aluminum Oxides, as well as gaseous oxides of Carbon and Nitrogen. Excessive inhalation of these fumes may produce symptoms known as "Fume Fever" and "Zinc Shakes" among other effects. Consult Physician.

GALVILITE GALVANIZING COMPOUND (LIQUID)

MATERIAL SAFETY DATA SHEET

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Effects of Chronic Overexposure to Product: Reports have associated repeated and prolonged overexposure to solvents with permanent damage to the brain and central nervous system. Irritancy of Product: Eye, Skin, Nose, Throat and Lung irritant. Sensitization to Product: May cause allergic skin reaction. Carcinogenicity: None Teratogenicity: None Mutagenicity: None Reproductive Toxicity: None Synergistic Products: None known EMERGENCY AND FIRST AID PROCEDURES: Inhalation: Remove to fresh air. Keep warm and quiet. Give artificial respiration if required. Get medical assistance. Eyes: Wash eyes immediately with large amounts of water for at least 15 minutes. Take to physician for medical attention. Skin: Wash contact area promptly with soap and water. Promptly remove paint-wet clothing. Consult physician if irritation persists. Ingestion: Do not induce vomiting without medical advice. Contact a physician, emergency room or Poison Center immediately. Observe all rules of good hygiene during and after use. Wash thoroughly before smoking or eating.

SECTION 6 SPECIAL PROTECTION INFORMATION

Personal Protective Equipment: Gloves: Neoprene gloves and aprons should be used to prevent prolonged or repeated skin contact. Use protective creams when skin contact is likely. Respirator: In outdoor or open areas, wear only properly fitted, NIOSH/MSHA approved respirators capable of filtering dust particulates during and after application unless air monitoring demonstrates vapor/mist levels are below acceptable limits. In areas of restricted ventilation, wear only properly fitted, NIOSH/MSHA approved respirators designed to remove a combination of organic vapors and dust particulates during and after application unless air monitoring demonstrates vapor/mist levels are below acceptable limits. In confined areas, use approved air line type respirators or hoods. Follow respirator manufacturer's directions for respirator use. Eye: Safety goggles with unperforated side shields or face shield should be used where splashing into eyes is possible. An eye wash fountain should also be available in areas where splashing is possible. When large amounts of material are used, a safety shower should be available. Footwear: Wear chemical resistant boots with steel toes. Clothing: Wear neoprene apron over well fitting clothes. Loose fitting clothes should not be worn. Remove and wash or discard contaminated clothing. Ventilation Engineering Controls: Work place areas require exhaust ventilation in accordance with OSHA regulation 29 CFR Part 1910.107d to maintain vapor levels below the TLV (especially during spraying, misting or heating). Use an approved high efficiency respirator of the full face canister type (for limited time and concentrations), air supplied type of self-contained respirators (for extended exposures involving high or unknown vapor concentrations or for non-routine or emergency conditions). Exhaust levels should be maintained at least at 100 lfm. All ventilation equipment should be explosion-proof, and any tools used in the area should be of the non-sparking type.

SECTION 7 SPECIAL PRECAUTIONS SPILL OR LEAK PROCEDURES

Leak and Spill Procedure: For massive spills, evacuate the area. For all spills, eliminate ignition sources. Dike and contain spills with dry, inert materials (sand, earth, etc.). Eliminate all sources of moisture and do not use water in clean-up operations. Recover as much of the free liquid as possible for disposal and use an absorbent to pick up the residue. Avoid discharging paint directly into a sewer or surface waters. Do not flush spills with water. Use non-sparking tools only. Spilled material may be slippery on floors. Waste Disposal: Dispose of the absorbed material or the free waste liquid in dry containers according to Local, State and Federal regulations for Hazardous Wastes. Dispose of all materials including empty cans according to Local, State and Federal regulations. Do not incinerate. Do not flush into sewers. Containers may explode if heated even when empty. It is recommended that solid waste be landfilled only at approved hazardous disposal sites using approved contractors. Handling Procedures and Equipment: Electrically interconnect and ground containers for transfer of liquids to avoid fire caused by static discharge. Use only nonsparking tools. Areas of use should have good ventilation and all sources of open flame and high heat should be excluded. Prohibit smoking in these areas. Ensure sufficient ventilation to prevent accumulation of heavy vapors in low lying areas of sumps. Material is electrically conductive. Do not apply by electrostatic spray equipment unless equipment has been designed for use with such coatings by the equipment manufacturer. Storage Requirements: This combustible liquid should be stored in a cool, clean, dry, well-ventilated, fire resistant storage room or in a solvent storage cabinet that meets OSHA requirements. Store only in totally closed cans with identifying labels that indicate the flammability of the material. Store large quantities only in buildings in compliance with OSHA 1910.105. Areas of storage for this material should have good ventilation and all sources of open flame and high heat should be excluded. Prohibit smoking in these areas. Ensure sufficient ventilation to prevent accumulation of heavy vapors in low lying areas or sumps. Do not store above 40 C. Do not puncture, drag or slide container. Other Precautions: Any deformed cans should not be moved, opened or punctured. Call (781) 319-0400. Do not take internally. Keep away from children. Empty container may contain extremely flammable residues and explode if heated.

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Disclaimer: While the data and suggestions contained herein are based on information we believe to be reliable, it is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers. Use of this product on inappropriate surfaces or in inappropriate applications may create other unanticipated hazards.

THIS PRODUCT IS A MIXTURE. MSDS FILES ON THE INDIVIDUAL COMPONENTS WERE USED TO DERIVE THE INFORMATION CONTAINED HEREIN.