2.1.2.

CC CHT CH TH Calcon Solochrom dark blue; Mordant black 17; Natri 2-Hydroxy-1-(2-hydroxy-1-naphthylazo)-naphthalen-4sulfonat C20H13N2NaO5S = 416,4 Dng loi tinh khit ha hc. Bt mu en nu c nh tm. Tan trong nc v ethanol. Trong mi trng kim, to mu ta vi ion calci . Khi khng c mt ion kim loi v d tha mt lng nh trilon B, dung dch c mu xanh lam. Hn hp calcon Nghin , trn u 0,1 g calcon (TT) vi 9,9 g natri sulfat khan (TT). nhy: Ho tan 0,2 g hn hp calcon (TT) trong 5 ml nc . Ly 1 ml dung dch thu c, thm 50 ml nc , 10 ml dung dch natri hydroxyd 1 N (C) v 1 ml dung dch magnesi sulfat 1% (kl/tt), dung dch c mu xanh lam. Thm 0,1 ml dung dch calci clorid 0,15% (kl/tt), mu chuyn sang ta. Thm 0,1 ml dung dch trilon B 0,01 M (C), mu li chuyn sang mu xanh lam. Da cam methyl Helianthin; Natri 4-dimethylaminoazobenzen-4-sulfonat C14H14N3NaO3S = 327,3 Dng loi tinh khit ha hc. Bt hay tinh th mu vng cam.. D tan trong nc n ng, khng tan trong ethanol. Vng chuyn mu: pH 3,0 () n pH 4,4 (vng). Dung dch da cam methyl Ho tan 0,1 g da cam methyl (TT) trong 80 ml nc, thm ethanol 96% (TT) va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,1 ml dung dch da cam methyl (TT), dung dch c mu vng. Khi thm khng qu 0,1 ml dung dch acid hydrocloric 0,1 N (C), mu phi chuyn sang . Da cam xylenol Tetranatri 3,3- (3H - 2, 1 - benzoxathiol - 3 - yliden) bis [(6 - hydroxy - 5 - methyl - 3, 1 - phenylen) methyleneiminobisacetat] S, S - dioxid. C31H28N2Na4O13S = 761,0 Dng loi tinh khit ha hc. Bt kt tinh mu nu . D t an trong nc, khng tan trong ethanol. Trong cc dung dch kim, to mu tm vi ion thu ngn, ch, km v mt s ion kim loi khc . Khi khng c mt cc ion kim loi v d trilon B, dung dch c mu vng. Hn hp da cam xylenol Nghin , trn u 1 phn da cam xylenol (TT) vi 99 phn kali nitrat (TT). Th nhy: Thm 50 mg hn hp da cam xylenol (TT) vo hn hp gm 50 ml nc , 1 ml acid acetic 2 M (TT) v 0,05 ml dung dch ch nitrat (TT). Thm va mt lng hexamin (TT) lm chuyn mu t vng sang tm, thm 0,1 ml dung dch trilon B 0,1 M (C), mu chuyn sang vng. Dung dch da cam xylenol ( TT) Ha tan 0,1 g da cam xylenol (TT) trong nc va 100 ml v lc nu cn. . Diclorofluorescein 2,7-Diclorofluorescein; Acid 2-(2,7-Dicloro-6-hydroxy-3-oxo-3H-xanthen-9-yl) benzoic C20H10Cl2O5 = 401,2 Dng loi tinh khit ha hc. Bt mu nu vng n cam vng. t tan trong nc, d tan trong ethanol v cc dung d ch hydroxyd

kim long , thc t khng tan trong ether. en eriocrom T Mordant black 11; Natri 2- hydroxy-1-[(1-hydroxynaphth-2-yl)azo]-6-nitronaphthalen-4-sulfonat C20H12N3NaO7S = 461,4 Dng loi tinh khit ha hc. Bt mu en nu , c nh kim loi . Tan trong nc v ethanol. Trong mi trng kim, to mu vi ion calci, magnesi, km v mt s kim loi khc . Khi khng c mt cc ion kim loi v d tha mt lng nh trilon B, dung dch c mu xanh lam. Dung dch en eriocrom T Ho tan 0,1 g en eriocrom T (TT) trong ethanol 96 % (TT) va 100 ml. Dung dch ch pha khi dng. Hn hp en eriocrom T (TT) Nghin , trn u 1 phn en eriocrom T (TT) vi 99 phn natri clorid (TT). nhy: Ho tan 0,05 g hn hp en eriocrom T (TT) trong 100 ml nc , dung dch c mu tm nu. Thm 0,3 ml dung dch amoniac 10% (TT), dung dch chuyn thnh mu xanh lam, thm tip 0,1 ml dung dch magnesi sulfat 1%, mu phi chuyn sang tm. congo Dinatri (biphenyl-4,4-diyl-bis-2,2-azo)bis(1-aminonaphthalen-4-sulfonat) C32H22N6Na2O6S2 = 697,0 Dng loi tinh khit ha hc. Bt mu nu. Tan trong nc. Vng chuyn mu: pH 3,0 (lam) n pH 5,0 (hng ). Dung dch congo Ho tan 0,1 g congo (TT) trong 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,2 ml dung dch congo (TT) v 0,3 ml dung dch acid hydrocloric 0,1 N (C), dung dch c mu xanh lam. Khi thm khng qu 0,3 ml dung dch natri hydroxyd 0,1 N (C), mu phi chuyn sang hng . cresol o-Cresolsulfonphthalein; 4,4'-(3H-2,1-benzoxathiol-3-yliden) di-o-cresol S,S-dioxyd C21H18O5S = 382,4 Dng loi tinh khit ha hc. Bt kt tinh mu nu . t tan trong nc, D tan trong ethanol v dung dch nat rri hydroxxyd. Vng chuyn m u: pH 7,0 (vng) n pH8,8 ( ). Dung dch cresol (CT) Ha tan bng cch un nng nh 0,1 g cresol (TT) vi hn hp gm 2,65 ml dung dch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,1 ml dung dch cresol ( TT) v 0,15 ml dung dch natri hydroxyd 0,02 N (C), dung dch c mu ta . Khi thm khng qu 0,15 ml dung dch acid hydrocloric 0,02 N (C), mu phi chuyn sang vng. methyl Acid 2-(4-dimethylaminophenylazo)benzoic C15H15N3O2 = 269,3 Dng loi tinh khit ha hc. Tinh th mu tm hay bt mu sm . Thc t khng tan trong nc, t an trong ethanol v acid acetic. Vng chuyn mu: pH 4,4 () n pH 6,0 (vng). Dung dch methyl

Ho tan 50 mg methyl (TT) trong hn hp gm 1,86 ml dung dch natri hydroxyd 0,1 N (TT) v 50 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,05 ml dung dch acid hydrocloric 0,02 N (C) v 0,1 ml dung dch methyl (TT), dung dch c mu . Khi thm khng qu 0,1 ml dung dch natri hydroxyd 0,02 N (C), mu phi chuyn sang vng. Dung dch hn hp methyl Ho tan 0,1 g methyl (TT) v 0,05 g xanh methylen (TT) trong ethanol 96% (TT) va 100 ml. phenol Phenolsulfonphthalein; 4,4'-(3H-2,1-Benzoxathiol-3-yliden) diphenol S,S-dioxyd C19H14O5S = 354,4 Dng loi tinh khit ha hc. Bt mu . Rt k h tan trong nc, kh tan ethanol, d tan trong cc dung dch kim . Vng chuyn mu: pH 6,8 (vng) n pH 8,4 ( ). Dung dch phenol ( TT1) Ho tan 0,1 g phenol (TT) trong hn hp gm 2,82 ml dung dch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,1 ml dung dch phenol ( TT), dung dch c mu vng. Khi thm khng qu 0,1 ml dung dch natri hydroxyd 0,02 N (C), mu phi chuyn sang tm . Dung dch phenol ( TT2) Dung dch 1: Ho tan 33 mg phenol (TT) trong 1,5 ml dung dch natri hydroxyd 2 M (TT), thm nc va 100 ml. Dung dch 2: Ho tan 25 mg amoni sulfat (TT) trong 235 ml nc, thm 105 ml dung dch natri hydroxyd 2 M (TT) v 135 ml dung dch acid acetic 2 M (TT). Thm 25 ml dung dch 1 vo dung dch 2. Nu cn , iu chnh pH ca hn hp ti 4,7. ta bromocresol 3,3-Dibromo-o-cresolsulfonphthalein; 4,4'-(3H-2,1-Benzoxathiol-3-yliden)bis(6-bromo-o-cresol) S,Sdioxyd C21H16Br2O5S = 540,2 Dng loi tinh khit ha hc. Bt kt tinh mu hng. Thc t k hng tan trong nc, ta n trong ethanol v cc dung dch kim long . Vng chuyn mu: pH 5,2 (vng) n pH 6,8 (lam). Dung dch ta bromocresol Ho tan 0,05 g ta bromocresol (TT) trong hn hp gm 0,92 ml dung dch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,2 ml dung dch ta bromocresol (TT) v 0,05 ml dung dch natri hydroxyd 0,02 N (C), dung dch c mu tm xanh. Khi thm khng qu 0,20 ml dung dch acid hydrocloric 0,02 N (TT), mu phi chuyn sang vng. ta cresol m-Cresolsulfonphthalein

C21H18O5S = 382,4
Dng loi tinh khit ha hc. Bt kt tinh mu lc nu. Kh tan trong nc, tan trong methanol, ethanol v acid acetic bng. Vng chuyn mu: pH 1,2 () n pH 2,8 (vng); pH 7,4 (vng) n pH 9,0 ( ta ). Dung dch ta cresol Ho tan 0,1 g ta cresol (TT) trong 13 ml dung dch natri hydroxyd 0,01 N (TT), thm nc va 100

ml. ta pht halein Metalphtalein; (1,3-Dihydro-3-oxo-isobenzofuran-1-yliden)bis[(6-hydroxy-5-methyl-3,1-phenylen) bis(methylen eimino)diacetic acid] C32H32N2O12 + nc Dng loi tinh khit ha hc. Bt mu trng kem n nu. Thc t khng tan trong nc, tan trong ethanol . nhy: Ho tan 10 mg ta phthalein (TT) trong 1 ml amoniac 13,5 M (TT), pha long thnh 100 ml vi nc . Ly 5 ml dung dch thu c , thm 95 ml nc , 4 ml amoniac 13,5 M (TT), 50 ml ethanol 96% (TT) v 0,1 ml dung dch bari clorid 0,1 M (C); dung dch c mu tm lam . Thm 0,15 ml dung dch trilon B 0,1 M (C), dung dch mt mu. trung tnh Basic red 5; 2 - Methyl -3- amino -7- dimethylaminophenazin hydroclorid C15H17ClN4 = 288,8 Dng loi tinh khit ha hc. Bt mu nht. t tan trong nc v ethanol. Vng chuyn mu: pH 6,8 ( ) n pH 8,0 (da cam). Dung dch trung tnh Ho tan 0,1 g trung tnh (TT) trong ethanol 50% va 100 ml. Eosin Acid 87 . C20H6Br4Na2O5 = 691,9 Dng loi tinh khit ha hc. Bt mu . D t an trong nc , t tan trong ethanol. Dung dch eo sin Ha tan 0,5 g eosin (TT) trong nc va 100 ml . Ethoxycrysoidin hydroclorid 4-[(4-Ethoxyphenyl]diazenyl]phenylen-1,3-diamin hydroclorid C14H16N4O. HCl = 292,8 Dng loi tinh khit ha hc. Bt mu . Tan trong nc v ethanol . Dung dch ethoxycrysoidin Ha tan 0,1 g ethoxycrysoidin hydroclorid (TT) trong ethanol 96% (TT) va 100 ml . nhy: Thm 0,05 ml dung dch brom 0,0167 M (TT) vo hn hp gm 0,05 m l dung dch ethoxycrysoidin hydroclorid (TT) v 5 ml acid hydrocloric 2 M (TT). Mu ca dung dch chuyn t sang vng nht trong vng 2 pht. Lc bromocresol 3,3,5,5-Tetrabromo-m-cresolsulfonphthalein; 4,4'- (3H-2,1-Benzoxathiol-3-yliden) bis dibromo- m-cresol) S,S-dioxyd C21H14Br4O5S = 698,0 Dng loi tinh khit ha hc. Bt mu trng nu hay vng nht. t tan trong nc, tan trong ethanol v cc dung dch kim long. Vng chuyn mu: pH 3,6 (vng) n pH 5,2 (lam). (2,6-

Dung dch lc bromocresol (T T1) Ho tan 0,05 g lc bromocresol (TT) trong hn hp gm 0,72 ml dung dch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml.

 nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,2 ml dung dch lc bromocresol (TT), dung dch c mu xanh lam. Khi thm khng qu 0,2 ml dung dch acid hydrocloric 0,02 N (C), mu phi chuyn sang vng . Dung dch lc bromocresol (T T2) Nghin k 0,2 g lc bromocresol (TT) vi 2,8 ml dung dch natri hydroxyd 0,1 N (TT), pha long thnh 200 ml vi nc v lc nu cn. Dung dch lc bromocresol methyl (Dung dch xanh bromocresol methyl) Hoa tan 0,15 g lc bromocresol (TT) v 0,1 g methyl (TT) trong 180 ml ehanol (TT), pha long vi nc thnh 200 ml. Lc malachit Victoria green; [4-[[4-Dimethylamino)phenyl]phenylmethylen]cyclohexan-2,5-dien-1-yliden] dimethy lamoni clorid C23H25ClN2 = 364,9 Dng loi tinh khit ha hc. Tinh th mu lc, c nh kim loi. Rt d tan trong nc, tan trong ethanol v methanol. Dung dch 0,001% (kl/tt) trong ethanol 96 % (TT) c hp th cc i 617nm. Dung dch lc malachit 0,5% Ho tan 0,5 g lc malachit (TT) trong acid acetic khan (TT) va 100 ml. Murexid Mui monoamoni 5,5-nitrilobis(pirimidin-2,4,6(1H,3H,5H)trion) C8H8N6O6. H2O = 302,20 Dng loi tinh khit ha hc. Bt tinh th mu nu . Kh tan trong nc lnh, tan trong nc nng v ethanol. Tan trong cc dung dch kali hydroxyd v natri hydroxyd , cho mu xanh lam. Dung dch murexid Ho tan 0,25 g murexid (TT) trong nc va 100 ml . Dung dch ch pha khi dng. Hn hp murexid Nghin , trn u 0,25 g murexid (TT) vi 25 g natri clorid (TT). 1-Naphtholbenzein -Naphtholbenzein; Phenylbis(4-hydroxynaphthyl)methanol C27H20O3 = 392,5 Dng loi tinh khit ha hc. Bt mu nu . Thc t khng tan trong nc, tan trong ethanol v acid acetic bng. Dung dch 1-naphtholbenzein Ho tan 0,2 g 1-naphtholbenzein (TT) trong 100 ml acid acetic khan (TT). nhy: Ly 50 ml acid acetic khan (TT), thm 0,25 ml dung dch 1-naphtholbenzein (TT), dung dch c mu vng nu. Khi thm khng qu 0,05 ml dung dch acid percloric 0,1 N (C), mu phi chuyn sang xanh lc . O-Phenanthrolin 1,10 - Phenanthrolin hydroclorid C12H8N2. HCl. H2O = 234,7 Dng loi tinh khit ha hc. Bt trng hoc gn nh trng. D tan trong nc, tan trong ethanol. im chy: Khong 215 OC km phn hu.

Dung dch feroin sulfat Ho tan 0,7 g s t (II) sulfat (TT) v 1,76 g O-phenanthrolin (TT) trong 70 ml nc . Thm nc va 100 ml. Phenolphtalein 3,3' - Bis (4 - hydroxyphenyl) phthalid C20H14O4 = 318,3 Dng loi tinh khit ha hc. Bt mu trng hay trng ng . Thc t khng tan trong nc, ta n trong ethanol. Vng chuyn mu: pH 8,2 (khng mu) n pH 10,0 ( ). Dung dch phenolphtalein Ho tan 0,1 g phenolphtalein (TT) trong 80 ml ethanol 96% (TT) v thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,1 ml dung dch phenolphtalein (TT), dung dch khng mu. Khi thm khng qu 0,2 ml dung dch natri hydroxyd 0,02 N (C), phi xut hin mu hng. Qu L sc t mu chm chit t cc loi a y nh Rocella, Lecanora v.v.... Mnh nh mu lc thm. Tan trong nc v ethanol. Vng chuyn mu: (pH 5,0 ) n xanh lam (pH 8,0). Giy qu xanh un si 10 phn qu (TT) tn thnh bt th vi 100 phn ethanol 96% (TT) di sinh hn trong 1 gi. G n b phn ethanol. Thm hn hp gm 45 phn ethanol 96% (TT) v 55 phn nc vo cn. yn 2 ngy, gn ly p hn dch trong (dch chit A). Tm dch chit A vo cc mnh giy lc, kh. nhy: Nhng mnh giy qu xanh, kch thc 10 mm x 60 mm , vo hn hp gm 100 ml dung dch acid hydrocloric 0,002 N (TT) v 90 ml nc. Lc nh, giy phi chuyn mu sang trong vng 45 giy. Giy qu Ly dch chit A trong iu ch Giy qu xanh, thm tng git dung dch acid hydrocloric 2 N (TT) cho n khi mu xanh chuyn thnh . Tm dung dch thu c vo cc m nh giy lc, kh . nhy: Nhng mnh giy qu , kch thc 10 mm x 60 mm , vo 100 ml dung dch natri hydroxyd 0,002 N (TT). Lc nh, giy phi chuyn mu sang xanh trong vng 45 giy. Dung dch qu un si 25 g qu (TT) tn thnh bt th vi 100 ml ethanol 90% d i sinh hn trong 1 gi. Gn b phn dch trong, lp li qu trnh ny 2 ln , mi ln vi 75 ml ethanol 90%. Ho lng qu c chit vo 250 ml nc , lc. St (III) amoni sulfat Phn st amoni; Amoni st (III) sulfat FeNH4(SO4)2. 12H2O = 482,2 Dng loi tinh khit phn tch. Tinh th mu trng ti tm nht. D t an trong nc, thc t khng tan trong ethanol. Dung dch st (III) amoni sulfat Ho tan 30 g st (III) amoni sulfat (TT) trong 40 ml acid nitric (TT) v thm nc va 100 ml. Nu dung dch c th phi lc hoc ly tm. Dung dch st (III) amoni sulfat 10% Ho tan 10 g st (III) amoni sulfat (TT) trong nc va 100 ml. Thymolphtalein 3,3-Bis (4-hydroxy-5-isopropyl-2-methylphenyl) phthalid C28H30O4 = 430,5

Dng loi tinh khit ha hc. B t mu trng . Thc t khng tan trong nc, tan trong ethanol v cc dung dch kim long. Vng chuyn mu: khng mu (pH 9,3) n xanh lam (pH 10,5). Dung dch thymolphtalein Ho tan 0,10 g thymolphtalein (TT) trong ethanol 96% (TT) va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,2 ml dung dch thymolphtalein (TT), dung dch khng mu. Khi thm khng qu 0,05 ml dung dch natri hydroxyd 0,1 N (C), phi xut hin mu xanh lam. Tm pyrocatechin Pyrocatechinsulfonphthalein; Tm catechol; 4,4'-(3H-2,1-Benzoxanthiol-3-yliden) dipyrocatechol S,Sdioxyd C19H14O7S = 386,38 Dng loi tinh khit ha hc. Bt kt tinh mu nu vi nh kim loi. D tan trong nc v ethanol. Trong mi trng acid (pH 2 3) to mu xanh lam vi ion bismut h v khi khng c mt ion ny, dung dch c mu vng. Trong mi trng kim to mu lam lc vi ion magnesi v ion km, k hi khng c mt cc ion ny, dung dch c mu tm . Dung dch tm pyrocatechin Ho tan 0,1 g tm pyrocatechin (TT) trong nc va 100 ml. Tm tinh th Gentialviolet ; Hexamethyl-p-rosanilin clorid C25H30ClN3 = 408,0 Dng loi tinh khit ha hc. Bt kt tinh hay tinh th mu lc thm , c nh kim loi . Tan trong nc, ethanol v acid acetic khan. Khi dng chun trong mi trng k han, mu chuyn t tm (kim) qua lc lam (trung tnh) n lc vng (acid). Dung dch tm tinh th Ho tan 0,50 g tm tinh th (TT) trong acid acetic khan (TT) va 100 ml. nhy: Ly 50 ml acid acetic khan (TT), thm 0,1 ml dung dch tm tinh th (TT), dung dch c mu tm. Thm 0,10 ml dung dch acid percloric 0,1 N (C), mu ca hn hp phi chuyn sang lc lam. Tinh bt Bt rt mn, khng mi, khng v. Dng loi tinh khit. Dung dch h tinh bt Nghin 1 g tinh bt (TT) vi 5 ml nc, ri va v a khuy vo 100 ml nc s i. un si tip cho n khi thu c cht lng ch hi c. Pha trc khi dng. nhy: Ly 5 ml dung dch h tinh bt (TT), pha long thnh 100 ml vi nc , thm 2 git dung dch iod 0,1 N (C), dung dch phi c mu xanh lam. Dung d ch h tinh bt c kali iodid Ho tan 0,5 g kali iodid (TT) vo 100 ml dung dch h tinh bt ( TT) mi pha. Dung dch ny ch dng trong 24 gi. Giy h tinh bt c iodid Tm t giy lc vi dung dch h tinh bt c kali iodid ( TT), kh ch t i khng c hi acid. Ct giy thnh nhng b ng di 50 mm, rng 6 mm. Khi nh 1 git dung dch acid hydrocloric 0,1 N (C) vo bng giy ch th, khng c xut hin mu xanh lam ngay lp tc.

Bo qun trong l thu tinh mu nu, nt mi. nhy: Trn 0,05 ml dung dch natri nitrit 0,1 M (C) v 4 ml acid hydrocloric (TT), thm nc va 10 0 ml. Nh 0,05 ml dung dch thu c ln bng giy ch th, phi xut hin mu xanh lam ngay tc khc . Vng alizarin 4-Nitro-4'-oxyazobenzen-3'-natri carboxylat C13H8N3NaO5 = 309,2 Dng loi tinh khit ha hc. Bt kt tin h mu nu hay nu vng. t tan trong nc v ethanol. Vng chuyn mu: pH 10,1 (vng) n pH 12,1 (tm hng ). Dung dch vng alizarin un cch thu ho tan 0,1 g vng alizarin (TT) tn nh tr ong mt t nc , ngui v thm nc va 100 ml. Vng metanil Natri 3-[4-(phenylamino) phenylazo] benzensulphonat. C18H14N3NaO3S = 375,4 Dng loi tinh khit ha hc. Bt mu vng nu. Tan trong nc v ethanol , rt t tan trong ether. Khi dng chun trong mi trng khan, mu chuyn t vng (kim) sang ta (acid). Dung dch vng metanil Ha tan 0,1 g vng metanil (TT) trong methanol (TT) va 100 ml. nhy: Thm 0,1 ml dung dch vng metanil (TT) vo 50 ml acid acetic khan (TT), dung dch c mu hng. Thm 0,05 ml dung dch acid percloric 0,1 M (C), mu chuyn sang tm Vng chuyn mu: pH 1,2 ( ) n pH 2,3 (vng cam). Vng titan Thiazol yellow Dinatri 2,2-[(1-triazen-1,3-diyl)di-4,1-phenylen] bis-[6-methylbenzothiazol-7-sulfonat] C28H19N5Na2O6S4 = 696,0 Dng loi tinh khit ha hc. Bt mu nu vng. D tan trong nc v ethanol . Dung dch vng titan Ha tan 0,05 g vng titan (TT) trong nc va 100 ml . nhy: Thm 0,1 ml dung dch vng titan (TT) vo hn hp gm 10 ml nc , 0,2 ml dung dch magnesi mu 10 phn triu (TT) v 1,0 ml natri hydroxyd 1 M (C). Dung dch c mu h ng, thy r khi so snh vi dung dch i chiu c chun b tng t , nhng khng c dung dch magnesi mu 10 phn triu (TT). Giy vng titan Tm giy lc bng dung dch vng titan ( TT), ri kh nhit phng. Xanh bromophenol 3,3-5,5 Tetrabromophenolsulfonphthalein 4,4' - (3H-2,1-Benzoxathiol-3-yliden) bis (2,6-Dibromo-phenol) S,S-dioxyd. C19H10Br4O5S = 670,0 Dng loi tinh khit ha hc. Bt mu vng cam. Rt kh tan trong nc, kh tan trong ethanol, d tan cc dung dch kim hydroxyd long.

Vng chuyn mu: pH 2,8 (vng) n pH 4,6 (tm lam). Dung dch xanh bromophenol Ho tan 0,1 g xanh bromophenol (TT) trong hn hp gm 1,5 ml dung d ch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT),, thm nc va 100 ml. nhy: Ly 20 ml nc khng c carbon dioxyd (TT), thm 0,05 ml dung dch xanh bromophenol (TT) v 0,05 ml dung dch acid hydrocloric 0,1 N (C), dung dch c mu vng. Khi thm khng qu 0,10 ml dung dch natri hydroxyd 0,1 N (C), mu phi chuyn sang tm lam . Dung dch xanh bromophenol trong ethanol. Ho tan 0,1g xanh bromophenol (TT) trong ethanol 20% va 100 ml. Dung dch xanh bromophenol (T T1). Ho tan 50 mg xanh bromophenol (TT) bng cch un nng nh vi 3,73 ml dung dch natri hydroxyd 0,02 N (TT), pha long vi nc va 100 ml. Xanh bromothymol 3,3-Dibromothymolsulfonphthalein 4,4 - (3H-2,1-Benzoxathiol-3-yliden) bis (2-bromo-thymol) S,S-dioxyd. C27H28Br2O5S = 624 Dng loi tinh khit ha hc. Bt kt tinh mu hng hay nu. Thc t khng tan trong nc , tan trong ethanol v cc dung dch kim long Vng chuyn mu: pH 6,0 (vng) n pH 7,6 (xanh lam). Dung dch xanh bromothymol Ho tan 50 mg xanh bromothymol (TT) trong hn hp gm 4 ml dung dch natri hydroxyd 0,02 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,3 ml dung dch xanh bromothymol (TT), dung dch c mu vng. Khi thm khng qu 0,10 ml dung dch natri hydroxyd 0,02 N (C), mu phi chuyn sang xanh lam. Xanh thymol Thymolsulfonphthalein 4,4-(3H-2,1-Benzoxathiol-3-yliden) dithymol S,S-dioxyd C27H30O5S = 466,6 Dng loi tinh khit ha hc. Bt kt t inh mu lam lc n lc nu. Kh tan trong nc, tan trong ethanolv cc dung dch kim long. Vng chuyn mu: pH 1,2 ( ) n pH 2,8 (vng); pH 8,0 (lc nu) n pH 9,6 (lam). Dung dch xanh thymol Ho tan 0,1 g xanh thymol (TT) trong hn hp gm 2,15 ml dung dch natri hydroxyd 0,1 N (TT) v 20 ml ethanol 96% (TT), thm nc va 100 ml. nhy: Ly 100 ml nc khng c carbon dioxyd (TT), thm 0,1 ml dung dch xanh thymol (TT) v 0,2 ml dung dch natri hydroxyd 0,02 N (C), dung dch c mu xanh lam. Khi thm khng qu 0,1 ml dung dch acid hydrocloric 0,02 N (C), phi chuyn sang vng. Dung dch xanh th ymol trong dimethylformamid Ho tan 1 g xanh thymol (TT) trong dimethylformamid (TT) va 100 ml. Dung dch xanh t hymol trong methanol Ho tan 0,3 g xanh thymol (TT) trong methanol (TT) va 100 ml. Lc, nu cn.

Khong pH v mu chuyn ca cc cht ch th Ch th cresol Xanh thymol Tropeolin 00 Da cam methyl Xanh bromophenol congo Lc bromocresol methyl ta bromocresol Xanh bromothymol trung tnh phenol Xanh thymol Phenolphtalein Thymolphtalein Vng alizarin Khong pH 0,2 1,8 7,0 8,8 1,2 2,8 1,3 3,2 3,0 4,4 2,8 4,6 3,0 5,0 3,6 5,2 4,4 6,0 5,2 6,8 6,0 7,6 6,8 8,0 6,8 8,4 8,0 9,6 8,2 10,0 9,3 10,5 10,1 12,1 Mu chuyn - Vng Vng - Vng - Vng - Vng Vng Tm lam Lam Hng Vng - Lam - Vng Vng Tm lam Vng - Lam - Da cam Vng Tm Lc nu - Lam Khng mu Khng mu - Lam Vng Tm hng

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