K thut cm bin

Cm bin t pht ngun

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Hin tng in th cc: khi nhng mt kim

loi vo dung dch th gia in cc v dung
dch s xut hin mt hiu in th.
Khi nng dung dch nh cc ion kim loi i
vo dung dch v kim loi c in th m hn
dung dch.
Khi nng dung dch cao th ngc li.

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Hin tng ny cn ng vi c cc kim (v

d nh Hidro). y l in cc chun.

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Dung dch A-xt hay Base ha tan trong nc

u phn ly ra cc I-on H+ v OH- .Nng
cc I-on H+ v OH- c trng cho tnh hot
ng ca dung dch in phn .

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

pH c tnh bng:

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

pH c o bng cch s dng in cc

pH ( thng l in cc thy tinh ) v mt
in cc chun ( thng s dng in cc
Calomen)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Mi quan h gia hiu in th gia hai in

cc vi pH ti c biu din theo cng
thc sau:
E pH

RT
= E 0 + 2.303
pH
nF

Trong :
- R hng s cht kh.
- T nhit Kelvin
- n Ha tr ca I-on
- F l hng s Faraday
o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Trong E0 cng ph thuc vo nhit v

ta c th vit li cng thc trn nh sau:

E pH = E + SLOPE(T ) pH
'
0

( pH trong khong t -7 pH n 7 pH )

o c Thnh - BM K thut o v THCN

T
[

0C]

Saturated KCl
[V]

0.2598

0.2569

10

0.2542

15

0.2510

20

0.2478

25

0.2444

30

0.2411

35

0.2376

40

0.2341

45

0.2304

50

0.2268

55

0.2230

60

0.2191

65

0.2151

70

0.2110

75

0.2069

80

0.2026

85

0.1982

90

0.1938

o c Thnh - BM K thut o v THCN

95
0.1892

100

0.1846

T
[

0C]

SLOPE
[ mV/pH ]

54.20

55.19

10

56.18

15

57.17

20

58.17

25

59.16

30

60.15

35

61.14

40

62.13

45

63.13

50

64.12

55

65.11

60

66.10

65

67.09

70

68.09

80

70.07

90

72.05

100

74.04

135

o c Thnh - BM K thut o v THCN

81.00

Cm bin in th cc (pH)

o c Thnh - BM K thut o v THCN

Cm bin in th cc (pH)
z

Cm bin o pH ca cc dung dch xc

nh tnh ct ca dung dch .

o c Thnh - BM K thut o v THCN

Mch o

o c Thnh - BM K thut o v THCN

Mch o
z
z

z
z

Yu cu c R vo ln.
B thay i do nhit gy ra vi E0 v
Slope.
Chng nhiu
chng dng r.

o c Thnh - BM K thut o v THCN

Mch o

o c Thnh - BM K thut o v THCN

Mch o

o c Thnh - BM K thut o v THCN

Mch o

o c Thnh - BM K thut o v THCN