.1, .1, .1, .

2
1,

C12H10-nCln (n 1-10
Cl- ) 209
. () ,
, ,

, , , ,
1920-1978 [1].


[2].
, ,
,


[3].
1- . -

, , ,
. ,
, , ,
[3].
- , , ()

- ,
2 ,

,
- 1242, 1254 1260
.

. , 1242 - 12
, 42
[7].

50 ppm 1242, 1254,
1260
.
.
-
5 m
, 5-50
m

, 50-500 m
, 500
m-

[10].
Archlor1260

239 -
, 40%
, 14 % - , 42 %
, 4% .
40% - , 46
% .

- 48%
- 21%
- 10%
- 20%

, , , , .

4%

LD50

2-10 /
.

113-118
/
.

0.0006 /

.
5,8-15 /

21 2 ,
, 6 .
10
7
15
150
10-12
32
7.8-132
20-60

,
Aligent GC 7890A

(, )

GC/ECD

( 30, C209 )

Chemstation vB.0403

-
(C209, C30)
-Isooctane
-H2SO4
-
Arochlor 1242
Arochlor 1254
Arochlor 1260

(DB-5)

5% - (0,25 ),
(60 x 0,320 )

: H2,1 /,
22,3 /,
: N2, 60 /

()

: 1200C (2 )
1: 1200C 250C / 1700C (4 )
2: 1700C 20C / 2000C (19 )
3: 2000C (11 ) 50C / 3000C (50 )
(ECD) Ni63, 3400

Dexsil- 239
.
,
(- Sigma-Aldrich, Merck) .
-30, -209 , 1242,
1254 1260 (Accusstandard, )-
. 0.04-0.08 , 5 ,
2.5 , 150 20

30 , .

, .
Agilent 7890A GC/ECD (
)
CEI EN 61619 [6]
(1- ) .

40%
42%

5 < 50
50 < 500
500 <

14%
- , ppm

-
,
- .
239 40%
, 14% - , 42%
- , 4% .
46%
(50 ppm) .
,
,
.

-

.

[1]. K.Ballschmiter, M.Zel, Analysis of Polychlorinated Biphenyls (PCB) by Glass Capillary Gas Chromatography., Fresenius Z.Anal.Chem.302., 1980., 20-31p.
[2]. I.A.R.Gray, Guide for polychlorinated biphenyl (pcb) management of insulating oil in south Africa., 2004., 1-18p.
[3]. ., ., 2010., 1-22.
[4]. ., ., .,
//02/024 ., ., 2003.
[5]. Guidelines for environmental management. Determination of polychlorinated biphenyls (pcbs) in waste oils by gas chromatography with electron capture
detector, Publication 886.1, ISBN 0730676293, 2003., 1-27p.
[6]. CEI EN 61619., International standard., Insulating liquids - Contamination by polychlorinated biphenyls (PCBs) - Method of determination by capillary
column gas chromatography., 1997.
[7]. Bogdevich O.P., Cadocinicov O.P., PCBs determination in transformer oil by spe and gas chromatography analysis., Moldavian Journal of the Physical
Sciences, Vol.3, N2, 2004., 226-235p.
[8]. Teresa Bernhard., Steve Petron., Analysis of PCB Congeners vs. Arcolors in Ecological Risk Assessment., Issue Papers., 2001., 1-7p.
[9]. Hector Alfredo Robles Martinez., German Cuevas Rodriguez., Daniel Hernandez Castillo., Determination of PCBs in Transformers Oil Using Gas
Chromatography with Mass Spectroscopy and Aroclors (A1254:A1260)., J.Mex. Chem. Soc. 2005, 49(3), 263-270p.
[10]. .., - , - ,
, 2008., .