Writing anything except Roll Number on question paper will be deemed as an act of indulging in

unfair means and action shall be taken as per rules.

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Roll No._________________
End Semester Examination Summer 2014
B Sc Semester II
MODEL QUESTION PAPER
BSCH211- PHYSICAL CHEMISTRY
Time: 3 Hrs
Note:
1.

MM: 80

ALL questions are compulsory in section A. The answers of these questions are limited upto 30 words
each. Each question carries 2 marks.

2.

Attempt FIVE questions in all from Section B, selecting ONE question either A or B from each question.
Answer of each question shall be limited upto 250 words. Each question carries 6 marks.

3.

Attempt THREE questions in all from section C. Answer of each question shall be limited upto 500 words.
Each question carries 10 marks.

SECTION A
1.

a. Evlaute the following:

d
3
x
(4x +e +sin x)
dx
b. Calculate the maximum and minimum value of the following function:
:

f(x)=x3+2x
c. Deduce Boyles law from kinetic gas equation.

d. Define compressibility factor. Also write the value of z for ideal and real

gases.

? z
|

e. Define surface tension and surface energy and prove that both the properties

are equivalent.

f. Define viscocity and viscocity coefficient . Give its unit.

|

g.
| |
Page 1 of 4

h. Define anisotropy, space lattice and unit cell.

, |
i.

Give the law of constancy of interfacial angles.

j.

Give any two methods for prepration of colloidal solution.

k. Write the example and definition of positive and negative colloids.

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SECTION B
2.

A.

(6.204) * (70.65)
with the help of logarithm.
8.653
(6.204) 2 * (70.65)

|
8.653
Find the value of

OR
B. Evlauate:

( x 2 1) 2
dx
x

( x 2 1) 2
x dx
3.

A.

a)
b)

Derive the vander waals equation of state .

Explain the behavior of real gases on the basis of vander waals
eqations.

a)

b)

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OR

B.

a)

Explain Maxwell distribution law of molecular velocities. Give relation

between them.

4.

b)

Calculate the root mean square velocity of oxygen molecule at 300 K.

a)

b)

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300 K |

A. Write short notes on the following:

a)

Formation of bubble
Page 2 of 4

b)

Capillary action.

|
a)

b)

OR

B. What are liquid cryctals? Explain the types of liquid crystal.

? |
5.

A.

a)

Explain the various symmetry elements in cubic unit cell.

b)

A face centered cubic element has a cell edge of 400 pm. What is its
density )molar mass 60 gm/mol).

a)

b)

400 PM |
| ( 60 / )
OR

B.

6.

a)

Derive Braggs equation for crystals structure.

b)

Represent the following Weiss indices in miller symbol c indices:

(i)

3a : 2b : c

(ii)

a : b : 3c

a)

b)

(i)

3a : 2b : c

(ii)

a : b : 3c

A. Define gold number and explain the coagulation of colloid.

|
OR
B. Explain DLVO theory of hydrophobic colloids.
DLVO |
SECTION C

7.

Explain the following:

(a) Probability

(b) Partial Differection

(c) Maxima and Minima

(d) Linear curves and its slopes

:
Page 3 of 4

8.

(a)

(b)

(c)

(d)

(a) Derive the realtion between critical constant and Vander Waals
Constants.
(b) Calculate Vc and Tc for CO2 gas. The value of Vander Waals constant
for CO2 are 4. X10-2 litre mol-1 and 3.60 litre2 atm mol-2.
( ) |
() CO2 Vc Tc |
4.2 x 10-2 -1 3.60 2 -2 |

9.

Explain the following:

(a) Gas saturation method.
(b) Stokes falling sphere method.
(c) Drop weight and number method.
:
()
( )
( )

10.

(a) Explain the rotating crystal and powder diffraction method of crystal
structure.
(b) When a monochromatics X ray radiation of 1.745 A 0 is passed from a
crystal than first order diffraction is obtained at 100 than calculate
distance between plane of lattics.
() |
( ) 1.745 A0 x
100 | |

11.

Differentiate among the following :

a)

Electrophoresis and Electrosmosis

b)

Lyophilic and Lyophobic colloids.

c)

Oil in water and water in Oil emulsion.

:
)
)
)

Page 4 of 4